Title of Invention

AN IMPROVED WASTE-HEAT STEAM GENERATOR

Abstract The invention relates to an improved waste heat steam generator (1), in particular for a combined-cycle power plant, having a plurality of heating surfaces (2,3.4) heatable by means of flue gas (RG) and carrying a medium (SW) to be heated, said plurality of heating surfaces comprising an evaporator (3) having an inlet side, an outlet side and a plurality of evaporator tubes (30a,30b): a preheater (2) following said evaporator (3) on the flue gas side; and a superheater (4) preceding said evaporator (3) , said preheater (2), said evaporator (3) and said superheater (4) disposed on a al medium side in counter current to said flue gas (RG). The inlet side of said evaporator (3) is connected to said pre-heater (2) via an inlet distributor (8) to which each said first evaporator tube (30a) is connected via throttle (9). and in that a pressure-equalizing header (11,12) in the form of an equalizing tube (11) is connected to said evaporator (3).
Full Text Description
improved
The invention relates to an/waste-heat. ' steam
generator, in particular for a combined-cycle power plant, with a number of heating surfaces heatable by means of flue gas and carrying a medium to be heated.
Such a waste-heat steam generator or waste-heat boiler is usually part of a combined-cycle power plant, in which the heat contained in the expanded working medium from the gas turbine is used to generate steam for the steam turbine. The heat is transmitted by means of a number of heating surfaces which are arranged in the form of tubes or tube bundles in the waste-heat steam generator. These, in turn, are connected into the water/steam circuit of the steam turbine, the said circuit comprising at least one pressure stage. In this case, each pressure stage usually has, as heating surfaces, a preheater or economizer and a evaporator as well as a superheater. A connection having a first or high-pressure stage and having a second or low-pressure stage - a so-called two-pressure process - is known from EP 0 410 111 B1.
Due to the further development of the stationary gas turbine towards higher unit output and higher efficiency, in conjunction with an increased exhaust-gas temperature at the gas turbine outlet, it can be seen that it would also become necessary to adapt the fresh-steam parameters, namely the fresh-steam temperature and fresh-steam pressure, in order to achieve a further increase in plant efficiency. An increased exhaust-gas temperature of the gas turbine consequently results in an enhancement of the fresh-steam parameters, in order to achieve correspondingly high efficiency of the overall combined-cycle process.

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In a waste-heat steam generator of this type, designed as a drum boiler and working on the circulation principle, evaporation is ended by separating the steam from the not yet evaporated water at deflecting plates in the drum. This separation requires circulation. This circulation and the steam separation make it necessary to have, between the water and steam, an appreciable density difference which, in turn, presupposes an appreciable pressure deviation (> 50 to 60 bar) from the critical pressure (221 bar). Steam separation thus places an upper limit on the pressure, so that a drum boiler can work only below an operating pressure of 160 to 170 bar. Moreover, high steam pressures necessitate large wall thicknesses of the water/steam separating drum, thus sharply restricting the permissible rate of temperature change in the start-up and load-alternation modes undesirably.
In the forced once-through principle, in a fossil-fuelled once-through steam generator, as an alternative to this circulation or natural circulation principle, the heating of its evaporator tubes forming a combustion-chamber wall leads to complete evaporation of the flow medium in the evaporator tubes in a single pass. In this forced once-through principle, the end of evaporation and consequently, at the same time, the commencement of steam superheating occur as a function of the load and are not locally fixed. In this case, with a once-through steam generator of this type, a fresh-steam pressure above the critical water pressure may be implemented due to the absence of steam separation or water precipitation. A once-through steam generator of this type is known, for example, from EP 0 595 009 B1.
However, in conjunction with a gas turbine in a so-called combined-cycle power plant, a once-through steam generator of this type is usually not employed as a pure waste-heat steam generator. Instead, the oxygenous exhaust gas from the gas turbine serves merely as combustion air for the firing system of this

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fossil-fuelled steam generator. Disadvantages of a once-through steam generator of this kind are its high outlay in terms of connection and regulation and its high start-up losses due to so-called water ejection. This occurs when evaporation in the evaporator commences and the steam pushes out the downstream water quantity (water drops). Additional separating and monitoring components, provided in order to overcome the start-up losses caused thereby, additionally increase the technical outlay and consequently the investment costs which increase sharply with a desired implementation of high and very high steam pressures. Another essential disadvantage of the fired once-through steam generator, as compared with the pure waste-heat steam generator, is the comparatively uneven adaptation of the temperature profile of the heated medium (water/water-steam line) to the temperature profile of the heating medium (flue-gas line).
The obi_ect on which the invention is based is, therefore, to specify a waste-heat steam generator, in particular for a combined-cycle power plant, by means of which a critical or supercritical steam pressure can also be implemented, whilst at the same time it operates in a fluidically stable manner in all load ranges, in particular even in the part-load range.
This object is achieved, according to the invention, by means of the features of Claim 1. Provided for this purpose is a waste-heat steam generator which works on the forced once-through principle and the drum-free evaporator of which is connected, on the medium side, in countercurrent to the direction of flow of the flue gas. Expediently, its preheater which follows the evaporator on the flue-gas side and its superheater which precedes the evaporator on the flue-gas side are also designed to be connected in countercurrent on the medium side.
A once-through or forced once-through waste-heat steam generator of this type makes it possible to implement high steam states up to

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supercritical values, since the said generator is not subject to any pressure limitation. Furthermore, short start-up times and high rates of load change can be implemented by avoiding the use of thick-walled drums. This contributes, in turn, to a particularly favourable plant behaviour. Moreover, particularly high operational flexibility is achieved, on the one hand since it is possible for the fresh-steam temperature to be set solely by means of the medium throughput, and on the other hand since a variable medium throughput can be set at least within specific limits. A neutral chemical operating mode is also possible, with a result that the chemical consumption is reduced. In addition, on account of the neutral chemical operating mode, there is no need for blow-down when the plant is in operation. A considerable cost reduction is achieved by avoiding the use of water/steam separating drums and connecting pipelines necessary in this case as well as by the possibility of reduced boiler or steam generator dimensions. Stable operation in the once-through mode is ensured within a combined-cycle power plant, in particular even in low part-load ranges of the gas turbine.
In order to implement the once-through principle, the evaporator is connected, on the inlet side, virtually directly to the outlet of the preheater, without a water/steam separating drum being interposed. Connecting the evaporator in this case in countercurrent to the flue gas on the medium side leads advantageously to uniform temperature intervals between the flue-gas line and water/steam line, so that, altogether, a heating surface of relatively small size is required. Moreover, this countercurrent connection has the advantage of particularly low water ejection when the waste-heat steam generator is started up, since its side which is hot on the flue-gas side and which has appreciable steam-bubble formation is located only at the water-side end of the evaporator. Due to the short distance available for steam bubbles formed,

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these push only a small water content out of the evaporator.
In an advantageous refinement, the evaporator is connected on the inlet side to the preheater via an inlet distributor which is identical to an outlet header of the preheater. To achieve particularly stable operation of the evaporator, the latter is provided on the inlet side with a throttle arrangement, a throttle expediently being connected into the inlet of each individual evaporator tube. Increased pressure loss over a particularly wide load range is thereby achieved in the evaporator. This ensures a uniform flow through the evaporator tubes.
In a further advantageous refinement, instead of headers and distributors conventionally used, only a pressure-equalizing header is provided between the evaporator portions or evaporator parts. This header subdivides the entire evaporator virtually into two portions on the pressure side, since identical pressures prevail in each case at the ends of these evaporator portions. This increases the throughflow stability, whilst avoiding a further increase in the pressure losses. Expediently, this pressure-equalizing header comprises only a relatively thin tube for the connection of a tapping bore of each evaporator tube. This connecting tube of small dimensions influences the flow within the evaporator only insignificantly and therefore does not present any problems with regard to allocating to the evaporator tubes the two-phase mixture of the medium to be heated, the said mixture being established in the evaporator.
As regards the thermal design of the evaporator, this is expediently subdivided into two individual heating surfaces, that is to say into two evaporator parts. In this case, the medium-side first evaporator part has no outlet header. Likewise, the second evaporator part located downstream of this has no inlet distributor. At the same time, the number of parallel tubes of both individual heating surfaces or

evaporator parts is identical. Moreover, the first evaporator part is expediently composed of tubes having an inside diameter which is small, as compared with the second evaporator part. By virtue of this evaporator design, a cost saving is achieved because there is no need for headers. If the pressure loss is preferably at the start of flow and the flue velocity is kept within a preferred range along the entire evaporator, a stable flow is achieved. As a result, particularly good heat transmission from the flue gas to the medium flowing through the evaporator, along with low erosion, is achieved. Furthermore, possible temperature differences between the parallel tubes are kept low owing to a uniform steam-side throughflow.
In order to prevent water ejected during the start-up from passing into the superheater, the latter is preceded by a start-up bottle which follows the evaporator. In this case, the evaporator and the superheater are connected to the steam-side head end of the start-up bottle. The preheater and the evaporator are connected on the inlet side to a water-side bottom connection of the start-up bottle. The part streams conveyed into the evaporator and into the preheater can be set by means of actuating members. Feed water supplied to the preheater can thus be supplemented by this part stream from the start-up bottle or be at least partially replaced by the said part stream. Also, the water not required for operating the once-through waste-heat steam generator can be discharged in a controlled manner from the start-up bottle. For this purpose, a discharge conduit is provided at the water-side bottom end of the start-up bottle.
The steam supplied to the superheater via the start-up bottle and via an inlet distributor is discharged from the superheater as superheated steam (main steam stream) via an outlet header. In this case, the superheater is preferably composed of two individual heating surfaces which are connected in series on the medium side and, if the once-through

waste-heat steam generator is of vertical design, are
arranged one above the other on the flue-gas side, so
that two-stage steam superheating takes place.
The advantages afforded by the invention are,
in particular, that an especially stable operating mode
is achieved over a wide load range due to the
evaporator of a waste-heat steam generator being
designed as a once-through evaporator with a
countercurrent connection. As a result, whilst at the
same time a Tow water-side/steam-side pressure loss is
ensured, the drum-free evaporator is designed with a
large surface, in such a way that, in all the operating
states, it acts on the once-through principle as a part
economizer and evaporator and as a part superheater.
The feed water is therefore subcooled at each operating
point at the outlet of the preheater or of the
economizer heating surface, so that evaporation in the
economizer is reliably prevented. Since heating to
boiling temperature takes place in the evaporator
itself, acting as part economizer, the so-called
"approach point" is always zero. This results in an
evaporator heating surface which is small, as compared
with the drum boiler.
Exemplary embodiments of the invention are
described below with reference to the accompanying drawing in which:
Figure 1 _ shows diagrammatically a detail of a
once-through waste-heat steam generator, the heating
surfaces of which are connected into a water/steam
circuit and
Figure 2 shows an evaporator of the waste-heat steam
generator according to Figure 1, the said evaporator
being composed of two individual heating surfaces.
Parts corresponding to one another are given the same reference symbols in both figures.
The once-through waste-heat steam generator 1 illustrated, which is of vertical design, is, for example, part of a combined-cycle power plant and has hot flue gas RG from the gas turbine flowing through it on the primary side. The cooled flue gas RG leaves the

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waste-heat steam generator 1 in the direction of a chimney (not illustrated}. The waste-heat steam generator 1 comprises, as heating surfaces, a preheater or economizer 2 and an evaporator 3, as well as a superheater 4 of a pressure stage. The heating surface arrangement illustrated is used preferably both in the high-pressure part and in the medium-pressure part of the once-through waste-heat steam generator 1.
The preheater 2 has, on the inlet side, an inlet distributor 5 which is common to all the preheater tubes and into which is connected a feed-water conduit 6 having a motor-driven control valve 7. On the outlet side, the tubes of the preheater 2 open into a common outlet header 8 which is at the same time an inlet distributor of the evaporator 3 located downstream of the preheater 2 on the medium side. To achieve stable operation of the evaporator 3, the latter is preceded by a throttle arrangement. For this purpose, a throttle 9 is connected into the inlet of each parallel tube of the evaporator 3, with the result that an increased pressure loss is achieved over a wide load range in the evaporator 3. Provided in the region of a deflection 10 of the evaporator 3 is a pressure equalizing header 11 in the form of a relatively thin tube for the connection of a tapping bore 12 of each parallel tube of the evaporator 3. On the outlet side, the parallel tubes of the evaporator 3 open into an outlet header 13 which is connected to a start-up bottle 15 via a steam conduit 14. The connection of the steam conduit 14 is provided at the steam-side head end 15a of the start-up bottle, a further steam conduit 16 being connected to the said head end. The steam conduit 16 opens into an inlet distributor 17 of the superheater 4. The superheater 4, which is composed of a first part or individual heating surface 4a and of a second part heating surface 4b following the latter on the medium side and preceding it on the flue-gas side, has, on the outlet side, an

outlet header 18, to which a main steam conduit 19 is connected.
The start-up bottle 15 has, at its water-side bottom end 15b, a discharge conduit 20 having a motor-driven control valve 21. A branch 22 of this discharge conduit 20, a circulating pump 23 being connected into the said branch, leads to the feed-water conduit 6 via a control or throttle flap 24 and a motor-driven control valve 2 6 connected into a first part-stream conduit 25. A second part-stream conduit 27 of the branch 22 leads via a motor-driven control valve 28 to the inlet distributor or outlet header 8. The heating surfaces 2,3 and 4 of the once-through waste-heat steam generator 1 are connected into the water/steam circuit of a steam turbine of the combined-cycle power plant via the feed-water conduit 6 and the main steam conduit 19 in a way not illustrated in any more detail.
Figure 2 shows a preferred embodiment of the evaporator 3 having two individual heating surfaces. These are implemented by a first evaporator part 3a and a second evaporator part 3b following the latter on the medium side and preceding it on the flue-gas side. The inlet distributor 8 is connected to an inlet port 29 of the first evaporator part 3a. Both evaporator parts 3a and 3b are composed in each case of the same number of parallel tubes, only one parallel or evaporator tube 30a or 30b of which can be seen in each case. The pressure-equalizing header 11 is connected to the first evaporator part 3a, only one tapping bore 12 being visible.
The two evaporator parts 3a and 3b are connected to one another directly, that is to say without an outlet header or inlet distributor being interposed. In this case, the parallel tubes 30a of the first evaporator part 3a have an inside diameter d1 which is smaller than the inside diameter d2 of the parallel tubes 30b of the second evaporator part 3b (d1
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30a and 30b of the evaporator parts 3a and 3b is made in each case via a conically designed intermediate piece. This intermediate or connecting piece 31 is designed conically, preferably in the form of a cone frustum, in order to implement the widening in diameter. On the outlet side, the parallel tubes 30b of the second evaporator part 3b are connected to the outlet header 13.
When the once-through waste-heat steam generator 1 is in operation, condensed water, so-called feed water SW, flows out of the condenser (not shown) , located downstream of the steam turbine (not shown), via the feed-water conduit 6 and through the preheater 2 into the outlet header or inlet distributor 8. The preheated feed water SW flows from there, via the throttles 9, into the individual evaporator tubes 30a of the first evaporator part 3a of the evaporator 3. In this case, the connection between the preheater 2 and the evaporator 3 is peculiarly short and uncomplicated, whilst an especially small overall heating surface of the evaporator 3 is achieved at the same time.
The throttles 9 ensure an increased pressure loss in the evaporator 3 virtually over the entire load range of the waste-heat steam generator 1. The flow passes through the evaporator 3, that is to say both its first evaporator part 3a having the evaporator tubes 30a and its second evaporator part 3b following this and having the evaporator tubes 30b, on the medium side or water side in counter current to the direction of flow of the flue gas RG. In this case, a stable and uniform flow of the preheated feed water SW through the evaporator tubes 30a, 30b is achieved, whilst the boiling temperature corresponding to the respective pressure of the flow medium is established in the evaporator tubes 30a,30b.
With a corresponding throughput rate, steam D generated in the evaporator 3 is slightly superheated, at each operating point, at the outlet of the evaporator 3, that is to say in the outlet header 13

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and in the steam conduit 14 connected to it, as a result of the single pass or forced pass. Consequently, no water drops can pass into the downstream superheater 4. Damage to the heating surfaces of the superheater 4 as a result of inadmissible temperature gradients are thereby reliably avoided. By virtue of this design and organization of the evaporator 3, the latter can be operated with a sliding evaporation point over a wide load range. The steam D generated in the evaporator 3 can therefore be introduced directly into the superheater 4, the start-up bottle 15 coming into action only when the once-through waste-heat steam generator 1 is started up.
Since, during start-up, the ejection of water from the evaporator 3 is particularly low, it is necessary for the start-up bottle 15 to have only relatively small dimensioning in order to receive the ejected water. In this case, relatively small wall thicknesses of the start-up bottle 15 may be implemented, this being associated with correspondingly short start-up and load-alternation times. In the vertical design of the once-through waste-heat steam generator 1, as illustrated, this particularly low water ejection is achieved in that, in particular, in implementation of the countercurrent connection, the flow passes through the evaporator tubes 30a,30b from the top downwards on the medium side or water side. Evaporation therefore takes place essentially in the lower evaporator tubes 30b of the second evaporator part 3b and decreases in the direction of the upper evaporator tubes 30a of the first evaporator part 3a.
Whilst the steam D already generated during start-up and separated in the start-up bottle 15 is fed, for further superheating, through the superheater 4 and is fed from there, in the superheated state, to the steam turbine (not shown) as main steam or fresh steam FD and, from there, is introduced again as condensate into the water/steam circuit, the water from the start-up bottle 15, virtually extracted from the

13

water/steam circuit only during the start-up, is fed,
as required, to the evaporator 3 and/or to the
preheater 2. Expediently, however, for reasons of flow
stability, the essential fraction of this start-up
water from the start-up bottle 15 is admixed, via the
first part-stream conduit 25, with the feed water SW
before the latter enters the preheater 2. Start-up
water not required in the water/steam circuit can be
drawn off from the start-up bottle 15 via the discharge
conduit 20.
By means of this waste-heat steam generator 1
working on * the once-through principle, high steam
pressures can be implemented, even in the critical or
the supercritical range. For this purpose, the flow
passes through both evaporator parts 3a and 3b, and
consequently the entire evaporator 3, downwards on the
medium side, whilst the flue gas RG has an ascending
direction of flow. The once-through waste-heat steam
generator 1 achieves, altogether, fluidically
especially stable operation down to minimum load on the
once-through principle.

14. We Claim:
1. An improved waste heat steam generator (1), in particular for a combined -cycle
power plant, having a plurality of heating surfaces (2, 3, 4) heatable by means of
flue gas (RG) and carrying a medium (SW) to be heated, said plurality of heating
surfaces comprising:
- an evaporator (3) having an inlet side, an outlet side and a plurality of evaporator tubes (30a, 30b);
a preheater (2) following said evaporator (3) on the flue gas side; and a superheater (4) preceding said evaporator (3), said preheater (2), said evaporator(3) and said superheater (4) disposed on a medium side in counter current to said flue gas (RG), characterized in that said inlet side of said evaporator (3) is connected to said pre-heater (2) via an inlet distributor(8) to which each said first evaporator tube (30a) is connected via throttle (9), and in that a pressure-equalizing header (11, 12) in the form of an equalizing tube (11) is connected to said evaporator(3).
2. Wasteheat steam generator as claimed in claim 1, wherein said equalizing tube (11) is connected to a tapping bore (12) of each said first evaporator tube (30a).
3. The steam generator as claimed in claim 1 or 2 wherein said pressure equalizing header (11, 12) is connected to said evaporator(3) in a deflection region (10).
4. The steam generator as claimed in one of claims 1 to 3, wherein said evaporator (3) comprises a plurality of evaporator parts (3a, 3b) connected in series on the medium side.
5. The steam generator as claimed in claim 4, wherein said first evaporator part (3a) on the medium side is composed of said first evaporator tubes (30a) having a small inside diameter (d1) as compared to an inside diameter (d2) of said second evaporator tubes (30b) of said second evaporator part (3b), said second evaporator tubes (30b) being located downstream of said first evaporator tubes (30a).
6. The steam generator as claimed in claim 5, wherein said evaporator tubes (30a,30b) of the evaporator parts (3a,3b) are connected to one another directly via a conically designed connecting piece (31).
2.
15.
7. The steam generator as claimed in one of claims 1 to 6, wherein said evaporator
(3) is connected to an outlet side to the superheater(4) via a start up bottle (15). 9
8. The steam generator as claimed in claim 7, wherein said start up bottle (15) is connected on a water side to the preheater(2) via a circulating pump (23) having a 10 downstream control valve (26).
9. The steam generator as claimed in claim 7 or 8 wherein said start up bottle (15) is, connected on a water side to the evaporator (3) via a circulating pump (23) having a downstream control valve (28).
10. The steam generator as claimed in claim 8 or 9, wherein said circulating pump 12 (23) is followed by a throttle flap (24).
11. The steam generator as claimed in one of claims 7 to 10, wherein said start up bottle (15) is connected on the water side to a discharge conduit (20) having a 13 control valve (21).
12. The steam generator as claimed in one of claims 1 to 11, wherein said preheater
(2) is connected to an inlet side to a feed water conduit (6), into which a control 14 valve (7) is connected on an inlet side to a feed water conduit (6), into which a control valve (7) is connected.
13. The steam generator as claimed in one of claims 1 to 12, wherein said super 15 heater (4) has an inlet distributor (17) and an outlet header (18), to which a main steam conduit (19) is connected.
14. The steam generator as claimed in one of claims 1 to 13 , wherein said super 16 heater (4) has two part heating surfaces (4a, 4b) connected in series on the medium side.
15. A once through waste heat steam generator comprising a waste heat steam generator as claimed in claims 1 to 14.

OF L.S.DAVAR & CO APPLICANTS' AGENT
Dated this 17th day of June 1998
The invention relates to an improved waste heat steam generator (1), in particular for a combined-cycle power plant, having a plurality of heating surfaces (2,3.4) heatable by means of flue gas (RG) and carrying a medium (SW) to be heated, said plurality of heating surfaces comprising an evaporator (3) having an inlet side, an outlet side and a plurality of evaporator tubes (30a,30b): a preheater (2) following said evaporator (3) on the flue gas side; and a superheater (4) preceding said evaporator (3) , said preheater (2), said evaporator (3) and said superheater (4) disposed on a al medium side in counter current to said flue gas (RG). The inlet side of said evaporator (3) is connected to said pre-heater (2) via an inlet distributor (8) to which each said first evaporator tube (30a) is connected via throttle (9). and in that a pressure-equalizing header (11,12) in the form of an equalizing tube (11) is connected to said evaporator (3).

Documents:

01080-cal-1998 abstract.pdf

01080-cal-1998 claims.pdf

01080-cal-1998 correspondence.pdf

01080-cal-1998 description(complete).pdf

01080-cal-1998 drawings.pdf

01080-cal-1998 form-1.pdf

01080-cal-1998 form-2.pdf

01080-cal-1998 form-3.pdf

01080-cal-1998 form-5.pdf

01080-cal-1998 gpa.pdf

01080-cal-1998 priority document.pdf

1080-CAL-1998-(11-10-2012)-FORM-27.pdf

1080-CAL-1998-CORRESPONDENCE.pdf

1080-CAL-1998-FORM-27.pdf

1080-cal-1998-granted-abstract.pdf

1080-cal-1998-granted-claims.pdf

1080-cal-1998-granted-correspondence.pdf

1080-cal-1998-granted-description (complete).pdf

1080-cal-1998-granted-drawings.pdf

1080-cal-1998-granted-examination report.pdf

1080-cal-1998-granted-form 1.pdf

1080-cal-1998-granted-form 2.pdf

1080-cal-1998-granted-form 3.pdf

1080-cal-1998-granted-form 5.pdf

1080-cal-1998-granted-gpa.pdf

1080-cal-1998-granted-letter patent.pdf

1080-cal-1998-granted-priority document.pdf

1080-cal-1998-granted-reply to examination report.pdf

1080-cal-1998-granted-specification.pdf

1080-cal-1998-granted-translated copy of priority document.pdf

1080-CAL-1998-PA.pdf


Patent Number 195164
Indian Patent Application Number 1080/CAL/1998
PG Journal Number 30/2009
Publication Date 24-Jul-2009
Grant Date 02-Sep-2005
Date of Filing 17-Jun-1998
Name of Patentee SIEMENS AKTIENGESELLSCHAFT
Applicant Address WITTELSBACHERPLATZ 2, 80333 MUENCHEN
Inventors:
# Inventor's Name Inventor's Address
1 HERMANN BRÜCKNER BOGGASSE 3, D-91080 UTTENREUTH
2 WERNER SCHWARZOTT NEUE STR. 21, D-91091 GROβENSEEBACH
3 HELMUT STIERSTORFER SCHILLERSTR. 61, D-91054 ERLANGEN
PCT International Classification Number F22B 1/18
PCT International Application Number N/A
PCT International Filing date
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 19727721.7 1997-06-30 Germany