Title of Invention

HYDRAULIC FLUID

Abstract

A hydraulic fluid comprising a lubricant base oil in combination with (a) from 0.001 to 5 %wt of magnesium salicylate, (b) from 0.01 to 8 %wt of zinc dithiophosphate, and optionally (c) from 0.001 to 5 %wt of a dicarboxylic acid or its mono- or di-ester or its mono-amide or di-amide or imide containing in total between 4 and 70 carbon atoms; and an additive package comprising magnesium salicylate, zinc dithiophosphate and optionally a dicarboxylic acid or its mono- or di-ester or its mono-amide or di-amide or imide containing in total between 4 and 70 carbon.

Full Text

HYDRAULIC FLUID The present invention relates to a hydraulic fluid. Background of the Invention WO 93/03121 relates to hydraulic fluids having improved wet filterability and having increased resistance to loss of zinc when the oil is exposed to water. These compositions comprise (A) a combination of a metal salt selected from the group consisting of sulfonates, phenates, carboxylates and mixtures thereof, (B) an aliphatic carboxylic acid or anhydride, or carboxylic acid group containing derivative thereof, wherein the aliphatic group contains at least 20 carbon atoms, and optionally (C) a metal salt of (C)(I) at least one organic phosphorus acid or mixture of (C)(I) at least one organic phosphorus acid and (C) (II) at least one carboxylic acid group, and optionally (D) triazole. In one embodiment, the carboxylic acids of (A) are aromatic carboxylic acids. Zinc, calcium and magnesium salts of these aromatic carboxylic acids, and especially salicylic acids, are preferred. Although magnesium salicylate and zinc dithiophosphate are both mentioned per se, there is no teaching to use the combination of these compounds. WO 89/04358 relates to compositions comprising (A) a neutral or basic metal salt of an acidic organic compound, (B) a metal deactivator, preferably an optionally substituted benzotriazole, and (C) a sulfur and/or phosphorus-containing compound selected from the group consisting of (C-1) phosphorus-containing amide, (C-2) phosphorus-containing ester, (C-3) sulfur-coupled dithiocarbamate/ (C-4) sulfur-containing compound according to formula (I). Particularly preferred metals for the salts (A) are sodium, magnesium, calcium or mixtures of two or more thereof. In the extensive list of additional compounds which can be present, zinc dialkyl dithiophosphate is mentioned. Although magnesium salicylate and zinc dithiophosphate are both mentioned per se, there is no teaching to use the combination of these compounds - EP-A-604 218 describes functional fluids comprising a major amount of an oil of lubricating viscosity, at least one metal salt of thiophosphoric acid, a zinc salt of salicylic acid, and a rust inhibitor, which fluid contains less than about 1 %wt of dispersant and less than about 1 %wt of basic sulfonate salt. The thiophosphoric acid is most commonly a dihydrocarbyl dithiophosphoric acid; the metal is most preferably zinc. The teaching of the document is restricted to the use of zinc salicylate. In US-A-4,627,928, a process has been described, for preparing basic magnesium salicylates which can be characterised as having a magnesium content of at least 150% up to 500%, of the stoichiometrically equivalent amount of magnesium based on the amount of total acid present. The magnesium salts obtained are described to be suitable for use as additives in general, more specifically as additives for a variety of lubricating oils and fuels, e.g, gasoline and diesel fuels. It is mentioned that these specific magnesium salicylates can be used in combination with a wide range of other compounds. There is no disclosure or teaching to apply a combination of zinc dithiophosphate and magnesium salicylate in a hydraulic fluid. Hydraulic fluids need to meet special requirements as they both lubricate and transmit pressure. In order to meet these requirements, hydraulic fluids contain additives. Generally, hydraulic fluids contain antiwear/extreme pressure additives. The conditions for a hydraulic fluid are especially difficult in vane pumps where the vane tips slide against the casing at high speed under heavy load and at high temperature. Further, the increasingly high operating temperatures of modern hydraulic equipment requires the fluid to be thermally stable to avoid the formation of deposits and sludge and to resist the corrosion of both ferrous and non-ferrous metals. The requirement of good thermal stability in hydraulic fluids containing an anti-wear additive, means that these additives are often used in combination with detergents. However, the calcium salts of alkylbenzene sulphonateS/ alkyl-naphthalene sulphonates, petroleum sulphonates, alkylphenates, alkyl sulphurized phenates or alkylsalicylates which are usually applied, give, increased wear. The increased wear is especially mairked in vane pumps, more specifically under low load conditions- Low load conditions occur in practice when the pump, is idle. WO-A-97/10318 describes lubricants with improved acid neutralisation properties and excellent sludge' and wear performance in the Seq. BE test, said lubricants are formed using a detergent system comprising one or more alkali or alkaline earth metal salts of an oil soluble organic acid selected from the group consisting of sulfonic acids, phenols, sulfurised phenols and carboxylic acids (including salicylate acids) wherein at least one metal salt, is overbased and the ratio of inorganic to organic salt present in the detergent system expressed as TBN from inorganic salts (the overbasing) to the total molea of organic salt is at least 2500. US-A-5 558 802 describes multigrade crankcase lubricants that have, good low temperature pumpability and low volatility. US-A-5 558 8 02 states that neutral and overbased calcium' salts of organic acids have been found to ■ increase low-temperature high shear viscosity when measured in a cold cranking simulator (CCS). In order to produce lubricants with low CCS viscosities under high shear rates (i.e. to allow the engine to crank more easily at lower temperatures and thus improve engine staftability at those ambient temperatures), it is said in US-A-5 558 802 that these salts should be avoided altogether or used at a level not exceeding 0.0007 moles of calcium salt per 100 grams of lubricant. WO-A-96/37582 describes lubricating oil compositions for internal-combustion engines; automatic transmission gearboxes, dampers, power steering units and the like. Lubricating oils of described in WO-A-96/37582 comprise sulfoxymolybdenum dithiocarbamate having a specific alkyl group, zinc dialkyl dithiophosphate having a specific alkyl group, specific alkylsalicylate(s), and, if desired, succinimide containing boron, each in a predetermined amount intra lubricating oil base stock. US-A-446291B describes a lubricating oil composition comprising a major proportion of a lubricating oil and a minor proportion of each of a Group II metal dithiophosphate and a composition having the formula: R2O.C0,CR2(NR3R4) .CR6R7.CO.OR5, where R1 , R2, R3, R4, R5, R6 and R7are hydrogen or a hydrocarbon radical containing 1-30 carbon atoms, and wherein R or R are independently selected from hydrogen, hydrocarbon containing from 1 to 3 0 carbon atoms, and acyl containing from 1 to 30 carbon. finmmary of the Invention It has now surprisingly been found that hydraulic fluid containing a combination of magnesium salicylate and zinc dithiophosphate, gives improved performance at low load compared with a combination containing calcium salicylate. Additionally, it was found that this combination also provides greater thermal stability. Less sludge and deposits are formed when subjecting the hydraulic fluid of the present invention to the Cincinnati Milacron Thermal stability Test- The present invention provides a hydraulic fluid comprising a lubricant base oil in combination with (a) from 0.0 01 to 5 %wt of magnesium salicylate, (b) from 0.01 to 8 %wt of zinc dithiophosphate, which amounts are based on total weight of hydraulic fluid. Detailed description of the Invention The magnesium salicylate for use in the present invention can be either neutral or overbased. The expression "overbased" is equivalent to "basic", "superbased", "hyperbased" and '*high-metal containing salts". These magnesium salicylates contain an excess metal content compared to the amount of metal which would be present according to the scoichiometry of the metal and the salicylic acid reacted with the metal. Processes for making such neutral and basic metal salts are well known in the art. Neutral salts can be made by heating a mineral oil solution of an acidic organic compound with a stoichiometric equivalent amount of a metal neutralizing agent such as the metal oxide, hydroxide, carbonate, bicarbonate, or sulfide at a temperature above 50 °C and filtering the resulting mass. Basic salts are made similarly with the exception that a stoichiometric excess of the metal is used. Preferably, overbased magnesium salicylate is used. These compositions can be characterized by their total base number (TBN). The total base number is preferably at least 100 mg KOH/g, more preferably at least 2 00 mg KOH/g, most preferably at least 300 mg KOH/g. The total base number is preferably at most 6 00 mg KOH/g- Another method of characterising overbased magnesium salicylates is by the magnesium content relative to the stoichiometrically equivalent amount of magnesium based on the amount of total acid present. Overbased magnesium salicyclates for use in the present invention preferably have a magnesium content of more than 50 0% of the stoichiometrically equivalent amount of magnesium based on the amount of total acid present, more preferably at least 550%- The salicylate can be either substituted or unsubetituted- Suitable substituents include aliphatic groups containing from 1 to 40 carbon atoms and optionally containing one or more oxygen and/or nitrogen atoms, and hydroxy groups. Preferred substituents are alKyl' groups containing from e to 30 carbon atoms, preferably from 12 to 20 carbon atoms. Preferably, the substituents are linear. The salicylate can contain from 1 to 4 substituents, preferably from' l to 3, most preferably 1 or 2 substituents. Most preferably, the salicylate is substituted by 1 linear alkyl group containing from 14 to 18 carbon atoms. Generally, mono-alkyl salycylic acids are prepared by alkylation of phenol and subsequent carboxylation. Therefore, a small amount (generally at most 20 %mol) of dialkyl salicylate and unsubstituted salicylate can be present in the mono-alkyl salicylate. Magnesium salicylate which can be used in the present invention, is commercially available. A suitable commercial product i's SAP 007 (ex Infineum) . The magnesium salicylate will usually be supplied in combination with mineral oil. The amounts referred to in this document, relate to the compound per se without mineral oil. A process by which suitable magnesium salicylate can be prepared, has been described in US-A-4,52 7,928. in which R® and R^ can be either hydrogen or an aliphatic group. The aliphatic group is preferably a hydrocarbyl group. The hydrocarbyl group optionally contains an acid, a hydroxy and/or ari ester group. The hydrocarbyl group is preferably an alkyl containing up to 12 carbon atoms optionally further containing an . acid, a hydroxy and/or an ester group. The hydrocarbyl substituted dithiophosphate can contain i or 2 aliphatic groups, or it can be a mixture of dithiophosphatea having 1 aliphatic group and dithiophosphatea having 2 aliphatic groups. Preferably, the zinc dithiophosphate is a zinc dialkyl dithiophosphate. Substituted dithiophosphates can contain primary, secondary and/or tertiary aliphatic substituents, i.e. eubstituents which are attached to the oxygen atom via a carbon atom attached to one, two or three further carbon atoms, respectively. In the present invention, it is preferred that at least SO %wt of the aliphatic, preferably alkyl, substituents of the zinc dithiophosphate, are primary aliphatic substituents. More preferably at least 80 %wt of the aliphatic substituents are. primary aliphatic substituents. Suitable zinc dithiophosphates which are commercially available include Elco 108 (ex Elco Corporation), Lz 1375 {ex Lubrizol), OLOA 4269Q (ex Oronite) and HITEC 680 (ex Ethyl), The amount of magnesium salicylate which is present is preferably at most 1 %wt, based on total composition, more preferably at most 0,5 %wt, most preferably at most 0.3 %wt. The amount of magnesium salicylate which is present is preferably at least 0.001 %wt, more preferably at least 0*005 %wt more preferably at least 0.01 %wt, mo0t preferably at least 0.015 %wt. The amount of zinc dithiophosphate which -is present is preferably at most 5 %wt, based on total composition, more preferably at most 3 %wt, moat preferably at most 1 %wt. The amount of zinc dithiophosphate which is present is preferably at least 0.05 %wt, more preferably at least 0.7 %wt, most preferably at least 0.1 %wt- The hydraulic fluid can further comprise (c) from 0.001 to 5 %wt of a rust inhibitor based on total composition, preferably a carboxylic acid or ester or amide or imide containing compound, more preferably a dicarboxylic acid or its mono- or di-ester or its mono-amide or di"amide or imide, more preferably a dicarboxylic acid or its ester, amide or imide containing a total number of between 4 and 70 carbon atoms- More preferably, the number of carbon atoms of the compound is between 20 and 40. A preferred compound is an aliphatic succinimide or succinic diamide. Such compounds have been described in EP-A-776964. in which Ri and Rj are each hydrogen or alkyl or hydroxyalkyl of l to 30 carbon atoms; R3, R4 and R5 are each hydrogen or alkyl or hydroxyalkyl of 1 to 4 carbon atoms; X is CH or N and R1 and R, are each hydrogen/ ' alkyl or alkenyl of 1 to 30 carbon atoms, or an acyl group derived from a saturated or unsaturated carboxylic acid of up to 30 carbon atoms. Preferably, R1 and R2 are each an alkyl of from 3 to 6 carbon atoms, R1, R4 and R5 are each hydrogen, X ie N and R1 and R7 are each an alkyl of 15 to 20 carbon atoms or an acyl group derived from a saturated or unsaturated dicarboxylic acid containing 4 to 10 carbon atoms, at least one of Rg and R, being an acyl group. Especially preferred is aspartic acid, N-(3-carboxy-l-oxo-2-propenyl)-octadecyl-bis (2-methylpropyl)ester. Such aspartic acid esters are commercially available. Processes for preparing such ■ compounds having been described in EP-A'434 464. The weight ratio in which the compounds of the present invention are present:, can differ within wide ranges. Preferably, the hydraulic fluid comprises magnesium salicylate, zinc dithiophosphate and optionally a rust inhibitor in such quantities that the weight ratio of magnesium salicylate to sine dithiophosphate is from 1:5 to 1:100 and the weight The lubricant base oils present in the hydraulic fluid of the present invention, can be any base fluid which is suitable for use in hydraulic fluids. The base oil can be a natural or a synthetic lubricant base oil, or a mixture thereof. The natural oil can be an animal oil or vegetable oil, such as lard oil or castor oil, or a mineral oil such as liquid petroleum oils and solvent treated or acid treated mineral lubricating oil of the paraffinic, .naphthenic, or mixed paraffinic/naphthenic type which may be further refined by hydrocracking and hydrofinishing processes and/or dewaxing. Synthetic lubricating oils include hydrocarbon oils and halo-substituted hydrocarbon oils such as polymerised and interpolymerised olefins, A suitable base oil contains poly-alpha-olefins, .such as polydecene. Preferably, the base oil is a hydrocarbon base oil. More preferably, the base fluid is a mineral oil which contains less than 10 • % by weight of aromatic compounds, preferably less than 5 % by weight, most preferably less than 3.0 % by weight, measured according to DIN 513 78. It is further preferred that the base oil contains less than l.O %wt of sulphur, calculated as elemental sulphur, preferably less than D,l %wt, more preferably less than 0.05 %wt, measured according to ASTM D 4045, Such mineral oils can be prepared by severe hydroprocessing. Preferably, the lubricating oil has a kinematic viscosity in the range of from 5 to 220 cSt at 40 °C, more preferably of from 10 to 200 est, most preferably of from 20 to 100 cSt. The hydraulic fluid according to the present invention can contain further additives usually present in hydraulic fluids, such as pour point depressants, anti-foam agents and demulsifier. Pour point depressants generally are high molecular weight polymers such as alkylaromatic polymers and polymethacrylates. As anti-foam agents, silicone polymers and/or polymethacrylates are generally used. Demulsifiers which are generally applied are polyalkylene glycol ethers. Furthermore, further detergents such as sulphonates and phenates, metal deactivators, antioxidants such as phenolic compounds, diphenyl amines and phenyl naphthyl amines, ashless anti-wear agents and/or ashless dispersants, such as succinimides, can be present. The hydraulic fluids of the present invention contain magnesium salicylate. For specific applications, it can be advantageous that the fluids contain a combination of magnesium and calcium salicylate. The components of the present invention can be added per se to a lubricating oil, or they can be mixed into an additive package before being added to the lubricating oil. The- additive package for preparing the hydraulic fluid preferably contains magnesium salicylate, zinc dithiophosphate and optionally a dicarboxylic acid or its mono- or di-ester or its mono-amide or di-amide or imide containing in total between 4 and 70 carbon atoms,. wherein the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 * to 1:100 and the weight ratio of magnesium salicylate to dicarboxylic acid or Its mono- or di-estrer or its mono-amide or di-amide or' imide is from 1:0 to 1:50. EXAMPLES Pormulatioxis were prepared containing the following additives: Magnesium salicylate: highly overbased magnesium alkylealicylate having a total base number of 337 mg KOH/g (SAP 007 ex INFINEUM) and a magnesium content of about 750% of the stoichiometrically equivalent amount of magnesium based on the amount of total acicj, containing 40 %wt of mineral oil Calcium salicylate: overbased calcium alkylsalicylate having a total base number of ISB mg KOH/g (SAP 001 ex INFINEUM), containing 4 0 %wt of mineral oil. The amounts of metal salicylate mentioned in Table 1, are the amounts of metal salicylate per se, without mineral oil. Zinc dithiophosphate: zinc di(ethyl-hexyl)dithiophosphate (Elco IQS ex Elco corporation) Compound according to formula I: aspartic acid, N-(3-carboxy-l-oxo-2-propenyl)-N-octadecyl , bis(2-methylpropyl)ester. These compounds were added to a lubricant base oil containing less than 1.0 % by weight of aromatic compounds, less than 0.05 %wt of sulphur, calculated as elemental sulphur and having a kinematic viscosity in the range of 32 cSt (at 40 °) (ISO viscosity grade 32) . The compositions obtained are described in Table 1. The amounta are of the compounds per se, excluding the mineral oil. Compositions 1 and 2 were used in Vickera V104C vane pump tests. A new pump cartridge was used for each test. The test duration was 250 hours, performed at a fluid temperature of about S6 °C, at a fluid outlet pressure of 35 bar (3.5 MPa) and at a pump speed of 1450 revolutions per minute. The results are described in Table 1. Tablg 1 From Table 1 it is clear that better protection against wear is provided by a composition containing magnesium salicylate (1) , than by a composition containing calcium salicylate (2). The ring weight loss and total.weight loss incurred when using composition 1 is significantly less than that incurred when composition 2 is employed-The vane weight loss is similar for both compositions. REVISED C LAIMS 1- Use of a composition comprising a lubricant base oil in combination with (a) from 0-001 to 5 %wt of magnesium salicylate, (b) from 0.01 to 8 %wt of zinc dithiophosphate to give improved wear performance at low load in a hydraulic fluid. 2. Use of a composition according to claim 1, further comprising (c) from 0.001 to 5 %wt of a dicarboxylic acid or its mono- or di-ester or its mono-amide ordi- amide or imide containing in total between 4 and 70 carbon atoms. 3. Use of a composition according to claim 2, in which (c) is a compound according to the following formula I R3R4C-C06R1 I (formula I) R6R7X-CR5-COOR2 in which R1 and R2 are each hydrogen or alkyl or hydroxyalkyl of 1 to 3 0 carbon atoms; R3, R4 and R.5 are each hydrogen or alkyl or hydroxyalkyl of 1 to 4 carbon atoms; X is CH or N and Rg and R7 are each hydrogen, alkyl or alkenyl of 1 to 30 carbon atoms, or an acyl group derived from a saturated or unsaturated carboxylic acid of up to 30 carbon atoms. 4. Use of a composition according to any one of claims 1 to 3, comprising magnesium salicylate, zinc dithiophosphate and optionally a compound according to formula I in such quantities that the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to compound according to formula I is from 1:0 to 1:50. 5- Use of a composition according to any one of claims 1 to 4, which composition further comprises pour point depressant, anti-foam agent and/or demulsifier. 6. Use of an additive package comprising magnesium salicylate, zinc dithiophosphate and optionally a dicarboxylic acid or its mono- or di-ester or its mono-amide or diramide or imide containing in total between 4 and 70 carbon, wherein the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to dicarboxylic acid or its mono- or di-ester or its mono-amide or di-amide or imide is from 1:0 to 1:50, to prepare a hydraulic fluid with improved wear performance at low load. 7. A hydraulic fluid comprising a composition ae defined in Claim 1, with the proviso that the fluid further contains (c) from 0.001 to 5 %wt of a compound according to the following formula I R3R4C-COOR1 I (formula I) RgR7X-CR5-COOR2 in which R1 and R2 are each hydrogen or alkyl or hydroxyalkyl of 1 to 3 0 carbon atoms; R3, R4 and R5 are each hydrogen or alkyl or hydroxyalkyl of 1 to 4 carbon atoms; X is CH or N and R6 and R7 are each hydrogen, alkyl or alkenyl of 1 to 3 0 carbon atoms, or an acyl group derived from a. saturated or unsaturated carboxylic acid of up to 30 carbon atoms. a. A hydraulic fluid according to claim 7, comprising magnesium'salicylate, zinc dithiophosphate and a compound according to formula I in such quantities that the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to compound according to formula I is from 1:0 to 1:50. 9. A hydraulic fluid according to claim 7 or.B, which fluid further comprises pour point depressant, anti-foam agent and/or demulsifier. 10. Additive package for preparing a hydraulic fluid which additive package comprises magnesium salicylate, zinc dithiophosphate and a compound according to the following formula I in which R^ and R2 are each hydrogen or alkyl or hydroxyalkyl of 1 to 3 0 carbon atoms/ R3, R4 and R5 are each hydrogen or alkyl or hydroxyalkyl of 1 to 4 carbon atoms; X is CH or N and Rg and R7 are each hydrogen, alkyl or alkenyl of 1 to 3 0 carbon atoms, or an acyl group derived from a saturated or unsaturated carboxylic acid of up to 30 carbon atoms, wherein the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to compound according to formula I is from 1:0 to 1:50, REVISED C LAIMS 1- Use of a composition comprising a lubricant base oil in combination with (a) from 0-001 to 5 %wt of magnesium salicylate, (b) from 0.01 to 8 %wt of zinc dithiophosphate to give improved wear performance at low load in a hydraulic fluid. 2. Use of a composition according to claim 1, further comprising (c) from 0.001 to 5 %wt of a dicarboxylic acid or its mono- or di-ester or its mono-amide ordi- amide or imide containing in total between 4 and 70 carbon atoms. 3. Use of a composition according to claim 2, in which (c) is a compound according to the following formula I R3R4C-C06R1 I (formula I) R6R7X-CR5-COOR2 in which R1 and R2 are each hydrogen or alkyl or hydroxyalkyl of 1 to 3 0 carbon atoms; R3, R4 and R.5 are each hydrogen or alkyl or hydroxyalkyl of 1 to 4 carbon atoms; X is CH or N and Rg and R7 are each hydrogen, alkyl or alkenyl of 1 to 30 carbon atoms, or an acyl group derived from a saturated or unsaturated carboxylic acid of up to 30 carbon atoms. 4. Use of a composition according to any one of claims 1 to 3, comprising magnesium salicylate, zinc dithiophosphate and optionally a compound according to formula I in such quantities that the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to compound according to formula I is from 1:0 to 1:50. 5- Use of a composition according to any one of claims 1 to 4, which composition further comprises pour point depressant, anti-foam agent and/or demulsifier. 6. Use of an additive package comprising magnesium salicylate, zinc dithiophosphate and optionally a dicarboxylic acid or its mono- or di-ester or its mono-amide or diramide or imide containing in total between 4 and 70 carbon, wherein the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to dicarboxylic acid or its mono- or di-ester or its mono-amide or di-amide or imide is from 1:0 to 1:50, to prepare a hydraulic fluid with improved wear performance at low load. 7. A hydraulic fluid comprising a composition ae defined in Claim 1, with the proviso that the fluid further contains (c) from 0.001 to 5 %wt of a compound according to the following formula I R3R4C-COOR1 I (formula I) RgR7X-CR5-COOR2 in which R1 and R2 are each hydrogen or alkyl or hydroxyalkyl of 1 to 3 0 carbon atoms; R3, R4 and R5 are each hydrogen or alkyl or hydroxyalkyl of 1 to 4 carbon atoms; X is CH or N and R6 and R7 are each hydrogen, alkyl or alkenyl of 1 to 3 0 carbon atoms, or an acyl group derived from a. saturated or unsaturated carboxylic acid of up to 30 carbon atoms. a. A hydraulic fluid according to claim 7, comprising magnesium'salicylate, zinc dithiophosphate and a compound according to formula I in such quantities that the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to compound according to formula I is from 1:0 to 1:50. 9. A hydraulic fluid according to claim 7 or.B, which fluid further comprises pour point depressant, anti-foam agent and/or demulsifier. 10. Additive package for preparing a hydraulic fluid which additive package comprises magnesium salicylate, zinc dithiophosphate and a compound according to the following formula I in which R^ and R2 are each hydrogen or alkyl or hydroxyalkyl of 1 to 3 0 carbon atoms/ R3, R4 and R5 are each hydrogen or alkyl or hydroxyalkyl of 1 to 4 carbon atoms; X is CH or N and Rg and R7 are each hydrogen, alkyl or alkenyl of 1 to 3 0 carbon atoms, or an acyl group derived from a saturated or unsaturated carboxylic acid of up to 30 carbon atoms, wherein the weight ratio of magnesium salicylate to zinc dithiophosphate is from 1:5 to 1:100 and the weight ratio of magnesium salicylate to compound according to formula I is from 1:0 to 1:50,

Documents:

in-pct-2001-1404-che- abstract.pdf

in-pct-2001-1404-che- claims duplicate.pdf

in-pct-2001-1404-che- claims original.pdf

in-pct-2001-1404-che- correspondence others.pdf

in-pct-2001-1404-che- correspondence po.pdf

in-pct-2001-1404-che- descripition complete duplicate.pdf

in-pct-2001-1404-che- descripition complete original.pdf

in-pct-2001-1404-che- form 1.pdf

in-pct-2001-1404-che- form 19.pdf

in-pct-2001-1404-che- form 26.pdf

in-pct-2001-1404-che- form 3.pdf

in-pct-2001-1404-che- form 5.pdf

in-pct-2001-1404-che- pct.pdf