Title of Invention

A CONTINUOUS PROCESS FOR PRODUCING ALUMINA TRIHYDRATE

Abstract

This invention relates to a continuous process for producing alumina trihydrate comprising the step of subjecting an alumina monohydrate based bauxite to high temperature caustic digestion to form a slurry which is settled and filtered in order to separate an insoluble residue and a supersaturated sodium aluminate liquor to be crystallized in the presence of seeds, wherein (a) digesting the bauxite at a temperature higher than 200°C, by contact with a liquor with a caustic concentration above or equal to 160 g Na2O/liter and a A/C weight ratio between 0.45 and 0.75; (b) cooling and flashing the resulting slurry, then introducing alumina trihydrate in said slurry, at a temperature of less than 200°C, in order to obtain A/C of the aluminate liquor between 1.20 and 1.30 when at atmospheric pressure; (c) first diluting the slurry giving a caustic concentration between 160 and 175 g Na2O/liter; (d) settling of said slurry in order to separate the insoluble residue; (e) filtering the aluminate liquor; (f) lowering the aluminate liquor concentration to less than 160 g Na2O/liter, via a complementary dilution carried out before or during crystallization; (g) after separation by recycling the spent liquor as digestion liquor.

Full Text

This invention relates to the treatment, by alkaline digestion according to the Bayer process, of alumina monohydrate bauxite or boehmite, including the addition of alumina trihydrate or gibbsite. STATE OF THE ART The Bayer process, which is widely described in the literature, constitutes the essential production technique of alumina to be transformed by igneous electrolysis into aluminum, or to be used in the hydrate state or transition, calcinated, sintered or melted alumina states, in numerous applications in the technical alumina field. According to this process, the bauxite mineral is digested when hot by means of an aqueous liquor of sodium hydroxide at the appropriate concentration, thereby making the alumina*- soluble and obtaining a slurry made up of particles of non-digested residue (mud) in a sodium aluminate liquor referred to as "aluminate liquor". This slurry is then usually diluted so as to separate the mud from the aluminate liquor by settling. Once tlio liquor is "purged" of this mud, it is cooled to a temperature at which. it is in a state of strong supersaturation imbalance. At this stage it is referred to as "pregnant liquor". Particles of alumina trihydrate are then seeded in order to initiate the "crystallization" of the pregnant liquor, in other words the precipitation of the alumina in the form of alumina"trihydrate. Finally, the sodium aluminate liquor, depleted in alumina as a result of the precipitation and referred to as "spent liquor", is recycled towards the digestion stage after being concentrated by evaporation and, if appropriate, the addition of sodium hydroxide so as to constitute a liquor, known as "digestion liquor", whose concentration is adapted to the digestion of the mineral. Those skilled in the art are well aware that treatment: conditions must be adapted to the degree of hydration and the crystallographic structure of the alumina contained in the bauxite, and to the nature and level of the impurities which it contains. Bauxite containing alumina in the monohydrate state (boehmite, diaspore) is more difficult to digest than trihydrate bauxite and is treated according to the Bayer process at temperatures higher than 200° C, usually between 22 0 and 3 00° C. Bauxite containing alumina in the trihydrate state (gibbsite) is treated at temperatures below 200° C, usually between 100 and 170° C. The digestion yield is defined by the ratio between the quantity of alumina dissolved in the digestion liquor and the total quantity of alumina contained in the mineral. At the present time, a digestion yield in the region of 90% i ^ usually reached with monohydrate bauxites containing between 2 and 3% of silica. The chief factors acting on the digestion yield of bauxite are temperature and the concentration of "free" sodium hydroxide or caustic soda, i.e. capable of dissolving alumina. Caustic soda is usually expressed by the base group Na2© and its concentration given in Na20 grams per liter (g Na20/1). In addition, the saturation or stability state of the liquors is characterized by the weight ratio: concentration in dissolved AL2O3 (in g/1) h/C = '__ __ concentration in Na20 caustic soda (in g/1) With regard to bauxites which are rich in monohydrate, the dissolution kinetics falls sharply in the course of dissolution, to such an extent that, in economically viable treatment conditions, the quantity of extracted alumina remains appreciably less than what it could be with the same quantity of caustic soda digesting alumina trihydrate, Thus, the maximum A/C attained with a monohydrate bauxite is of the order of 1.20 while a ratio of 1.40 which can be reached with a trihydrate bauxite. This A/C weight ratio, characterising the saturation state in alumina dissolved in the liquor of the Bayer cycle, determines the productivity of the liquor during its crystallization. This productivity is defined by the quantity of alumina recovered, in the form of alumina trihydrate, after crystallization of the pregnant liquor, in relation to a given volume of pregnant liquor. The productivity is expressed in kilograms of alumina per cubic meter of liquor (kg Al203/m ) and is obtained by multiplying the A/C variation before and after crystallization by the caustic concentration of tthe pregnant liquor. This concentration is usually higher in European-type Bayer processes than in American-type processes and that is the reason why a productivity at the crystallization of the pregnant liquor is considered as good when it exceeds 70 kg A^C^/m for an American-type Bayer process and when it exceeds 80 kg Al203/m for an European-type Bayer process. ; In the case of monohydrate bauxite, productivity at crystallization could be increased if it were possible to raise the dissolved alumina level and thus the A/C weight ratio, for example by addition of alumina trihydrate and dissolution during the cooling of the liquor, before separation of the red mud. The trihydrate solubility is in fact good up to approximately 100° C in alkaline medium and such an operation would increase, at least in the first instance, the quantity of alumina dissolved to the extent that the A/C weight ratio could reach 1.25 and even 1.30. It has occurred that such a mode of liquor supersaturation, developed during the 1950s and referred to as "sweetening", is difficult to exploit on an industrial scale. In point of fact, it is known (YAMADA - Jl of Jap. Inst. of Light Metals - vol. 31 pp. 43-48 - January 1981) that in these extreme supersaturation conditions, part of the alumina reprecipitates inopportunely before or during the separation of the red mud and is evacuated with it: this reversion is a particularly unwelcome phenomenon which is to be avoided since it reduces the extraction yield of the alumina. Thus the sweetening implemented according to American patent 2 701 752, consisting in adding a certain quantity of trihydrate to the slurry during cooling after the high; temperature digestion of the monohydrate, limits the A/C after digestion to less than 1.08 with caustic concentrations not exceeding 12 0 g Na20/1 . While the risk of reversion is certainly minimized in these conditions, the productivity of the liquor suffers as a result and does not exceed 70 kg Al203/m . In such conditions, the sole interest of the sweetening mode lies in its ability to reduce the energy cost of the treatment, since it provides a trihydrate digestion which costs nothing in energy terms because it uses the heat supplied for the digestion of the monohydrate. It therefore emerges clearly that the various means of the prior art, designed to limit the unwelcome effects) of reversion on the extraction yield of alumina, are implemented at the expense of the productivity of .the liquor which A/C weight ratio can barely exceed 1.15. PROBLEM POSED Thus alumina producers are still concerned by the development of a an effective process for the treatment of i bauxites which are rich in monohydrates, particularly in view of the importance of this type of bauxites as a source of supply. Such a process must satisfy the following criteria: - total alumina digestion yield higher than 90%; - productivity of crystallization greater than 70, kg AI2O3/1U °f liquor, being capable of exceeding 90 kg Al203/m in a European-type Bayer process; reduction of the quantity of energy required to dissolve the same quantity of alumina. OBJECT OF THE INVENTION The process according to the invention developed by the applicant satisfies these criteria. For this purpose, a sweetening stage is included in the process but is implemented in an entirely different way. More specifically, the invention relates to a process for treating alumina monohydrate-based bauxite by caustic and high-temperature digestion of the ground bauxite so as to form a slurry which is settled and filtered in order to separate a sodium aluminate liquor to be crystallized in the presence of seeds and an insoluble residue, the process being characterized by the following series of operations: a) digesting the bauxite, preferably ground, at a temperature higher than 200° C, with shaking if required, with a liquor which caustic concentration is above or equal to 160 g Na20/liter and having an A/C weight ratio between , 0.45 and 0.75, for a contact time which is sufficient to extract the aluminate monohydrate and to give an A/C ratio between 1.10 and 1.20; b) cooling and flashing the resulting slurry, then introducing alumina trihydrate in said slurry, at a temperature of less than 200° C, in order to obtain an A/C ratio of the aluminate liquor between 1.20 and 1.30 when at atmospheric pressure, the temperature being slightly below boiling temperature; c) first diluting the slurry giving a caustic concentration between 160 and 175 g Na20/liter; | 1 d) settling of said slurry, preferably in the preserice of a flocculant, in order to separate the insoluble residue from a sodium aluminate liquor having an A/C ratio between 1.2 0 and 1.30. 1 e) filtering the aluminate liquor * f) lowering the aluminate liquor concentration to less than 160 g Na20/liter, via a complementary dilution carried out before or during crystallization, in which the alumina trihydrate precipitates, one part being recycled as seed and the other part being filtered and then washed; g) after separation of the alumina trihydrate by filtration, recycling of the spent liquor which, after concentration, for, example by evaporation and possible addition of sodium hydroxide, is reused as digestion liquor with a caustic concentration above or equal to 160 j g Na20/liter. Preferably, the alumina trihydrate in stage b) is introduced by injecting a pulp obtained by grinding, in the presence of an aliquot of the digestion liquor, an alumina trihydrate bauxite or waste containing the same. Also preferably, the complementary dilution of the liquor, which is carried out according to the inventibn after the settling stage, is performed with a previously filtered fraction of a diluted liquor resulting from the washing of the red mud, possibly containing the wash water of the alumina trihydrate produced. This takes place before or during crystallization and it is important to take steps to avoid any pollution by this wash water, for example by means of a preliminary filtration. The liquor may for example be diluted, filtered and then introduced in the chain of precipitators. Contrary to all expectations, the applicant observed that it was able to delay, at least partially, the dilution of the aluminate liquor until the start of its crystallization. This operating method, however, runs counter to the usual practice in . which the specialist dilutes the slurry by adding water so as to facilitate the settling of the mud. This dilution has the twin advantage of reducing its viscosity and allowing the addition of numerous flocculants which are unstable in liquors which are too concentrated. On the other hand, it increases alumina supersaturation which favors reversion. But the precipitation kinetics are slow when the A/C does not exceed 1.10-1.15 or even 1.20, so that this risk has always been considered as minimal provided that settling times are not too long. If settling is too lengthy, the fine particles of the non-digested residue present in the slurry may in fact initiate the precipitation and an intense reversion may still develop 5 or 6 hours after the start of settling. Dilution before separation of the mud has consequently always been considered as obligatory by the specialist because it shortens settling time and preserves the stability of the flocculants. It unexpectedly occurred to the applicant that, given the flocculants currently used - these are usually anionic polyelectrolytes, for example synthetic polyacrylates which may advantageously be combined with polysaccharide-based additive improving clarity - , it was possible to settle the insolubles in a concentrated aluminate liquor in ian acceptable lapse of time, despite a very high A/C, higher than 1.20, without reversion occurring. It emerges that the delaying effect of the reversion due to the high caustic level prevails over the accelerating effect due to a slight increase in the settling time. Moreover, the strong aluminate concentration appreciably increases its boiling temperature, thereby making it possible to settle at a higher temperature and to reduce still further the risk of reversion. In other words, despite a very high A/C, higher than 1.20, obtained by sweetening, the risk of reversion of the pregnant liquor during the separation of the insolubles is considerably reduced when the caustic concentration remains above or equal to 160 g Na20/1, due to the partial transfer of the dilution until after the settling stage. What matters here, in fact, is that part of the dilution has been postponed until after the settling. This complementary dilution of the aluminate liquor may be carried out at once, right at the start of crystallization. This simple procedure was chosen in our examples. But, with a view to further improving productivity, the crystallization chain may be arranged in such a way that dilution is carried out in several stages during crystallization. It is known (J.V, Sang et al. Light Metals 1989, pp. 33-39, Fig. 1) that the optimum caustic concentration with respect to productivity diminishes as the A/C falls. Since the A/C inevitably falls during crystallization, it is important to dilute gradually the liquor of the aluminate slurry circulating in the crystallization chain so that productivity remains constantly at an optimum level. A clearer understanding of the invention will emerge from the detailed description of its application based on the following figures: - Fig. l representing in diagram form the product flows in a digestion process according to the prior art - Fig.2 representing in diagram form the product flows in the basic process according to the invention IMPLEMENTATION OF THE INVENTION According to Fig. 1, representative of the prior art, the monohydrate bauxite 1 is submitted to a humid grinding Al in the presence of an aliquot 20a of digestion liquor 20 having an A/C ratio preferably between 0.5 and 0.7 and a caustic concentration between 160 and 220 g Na20/1. The whole is introduced, with the other aliquot 20b of the digestion liquor 20, in autoclaves so as to form a slurjry whicHfcMs heated to a temperature between 2 20 and 3 00° C for an sufficient length of time, generally between 0.2 and 1 hour, in order to extract the alumina monohydrate. The slurry 2 resulting from this pressurized digestion A2 is cooled and put to atmospheric pressure (Cooling/Flash Blj, then diluted (Dilution B2). The caustic concentration aftfer said dilution is less than 160 g Na20/1, preferably between 140 and 150 g Na20/1. The resulting slurry 3 is then settled CI in the presence of a flocculant and then to filtration C2 in order to separate the insoluble residues 5 from the aluminate liquor 4. After washing F with the water 7 and the wash water 13a resulting from the crystallization, the inert residues 5a, or mud, are evacuated for discharge G and the wash water 7a is used for dilution B2 of the slurry 3 before settling CI. The aluminate liquor 4, having an A/C ratio between 1.05 and 1.15 and a caustic concentration between 110 and 160 g Na20/1, is then cooled and crystallized between 80° C and 50° C (crystallization D) in the presence of fine particles of precipitate 10 recycled to act as seed. The grains of alumina trihydrate thus obtained are classified in such a way that the largest 11 are recovered, and after washing H with water 13, calcinated (calcination K) in order to produce the production alumina 12, while the finest 10 remain within the recycled seeds. The spent liquor 8, with an A/C ratio between 0.5 and 0.7, is then reconcentrated by evaporation E with a possible addition of sodium hydroxide 9 and becomes the digestion liquor 20. The basic procedure according to the invention illustrated in diagram form in Fig. 2 is implemented as follows: The same monohydrate bauxite 1, after a first humid grinding Al in the presence of an aliquot 20a of digestion liquor 20 having an A/C ratio preferably between 0.55 and 0.65 and a caustic concentration between 160 and 220 g Na20/1, is introduced with another aliquot 2 0b of the digestion liquor 20, in autoclaves so as to form a slurry which is heated to a temperature between 220 and 3 00° C for a sufficient length of time to extract the alumina monohydrate, between 0.2 and 1 hour. The slurry 2 resulting from this first pressurized digestion A2, with A/C between 1.05 and 1.20, is partially cooled and flashed (Cooling/Flashing Nl) . At a temperature of less than 200° C, a pulp 6 containing alumina trihydrate, resulting from the humid grinding L of trihydrate bauxite 13 with a third aliquot 20c of the digestion liquor 20, is injected under pressure (" Sweetening'1 N2) . Before being injected in the slurry 2, the ground pulp 6 is maintained for a dwell time of between 3 and 24 hours so as to produce a predesilicatation of said pulp. The injection preferably takes place between 190 and 130° C in the flash tank corresponding to this temperature and ensuring a dwell time of at least two minutes, 'the i slurry 3a, enriched in alumina as a result of the injection of the ground pulp 6, is then cooled and flashed to atmospheric pressure. It has an A/C ratio between 1.20 and 1.28 and its caustic concentration is between 180 and 220 g Na20/1. It is submitted to a first dilution by addition of a fraction 7b of diluted liquor resulting from washing of the mud. Its concentration is lowered to a value between 160 and 175 g Na20/1. It is then submitted, at a temperature slightly below - at most 5° C below - boiling temperature, to settling CI in the presence of a flocculant, and lastly to filtration C2 in order to separate the sodium aluminate liquor 4a from the insoluble residues 5. After countercurrent washing by the water 7 and the wash water 13a of the alumina trihydrate produced 11, these inert residues 5a, or mud, are discharged G. The aluminate liquor 4a is diluted (dilution M) with the filtered wash water 7c (filtration O) of the residues 5. The diluted liquor 4b has a caustic concentration between 140 and 155 g Na20/1. It is then cooled and crystallized (D) between 80° C and 50° C in the presence of fine particles of precipitate 10 serving as seed. The grains of alumina trihydrate thus obtained are classified in such a way that the largest 11 are recovered for washing H with water 13 and calcination K with a view to supplying the production alumina 21, while the finest remain within the recycled seeds 10. The spent liquor 8 is then reconcentrated by evaporation and possible addition of sodium hydroxide so as to reach a caustic concentration between 160 and 220 g Na20/1. Once concentrated, the liquor is used as digestion liquor 20. EXAMPLES OF APPLICATION . In examples 1 (according to the prior art) , 2 and 3 (according to the invention), a first monohydrate bauxite (diaspore) was digested according to an European-type Bayer process. In example 4, a monohydrate Australian bauxite (boehmite) was digested according to an American-type Bayer process. I EXAMPLE 1 | According to the prior art, a 100 ton batch of said bauxite was digested at 260° C for 1 hour with a digestion liquor concentrated at 210 g Na20/1. After flash, cooling, dilution and settling, we obtained the following results: Liquor before crystallization A/C: 1,15 Caustic concentration: 146 g Na20/1 Liquor after crystallization A/C: 0.58 Global digestion yield: 90.6% extracted alumina/total alumina Productivity at crystallization: 83 kg Al203/m Energy necessary for the digestion of 1 kg of alumina: 3.55 MJ EXAMPLE 2 Another 100 ton batch of the same bauxite was digested according to a first mode of the invention: Digestion at 260° C for 1 hour with a digestion liquor concentrated at 210 g Na20/1. Cooling to 160° C. The slurry being maintained shaken, 9.2 tons of an African bauxite rich in trihydrate (85%) was injected in slurry form, said bauxite having previously been ground in the presence of an aliquot of the digestion liquor. The trihydrate bauxite has the following ponderal This slurry is mixed with the principal slurry and the digestion is maintained for 5 minutes, the quantity of alumina dissolved is such that the A/C weight ratio of the pregnant liquor.reaches 1.25. After flash, a first dilution was carried out, leading to a concentration of 168 g Na20/1, then a settling at 104° C, in the presence of flocculant CYTEC® HX 400, at the rate of 600 g/ton of insoluble residue. After separation of the insoluble residues, the aluminate liquor was ag^iin i diluted to a concentration of 147 g Na20/1. I After dilution, we obtained the following results: Liquor before crystallization A/C: 1.21 Liquor after crystallization A/C: 0.585 Global digestion yield: 91.0% extracted alumina/total alumina Productivity at crystallization: 91.5 kg Al203/m Energy necessary for the digestion of 1 kg of alumina: 3.25 MJ EXAMPLE 3 Another 100 ton batch of the same bauxite was digested according to a second mode of the invention: Digestion at 2 60° C for 1 hour with a digestion liquor concentrated at 210 g Na20/1. Cooling to 130° C. The slurry being maintained shaken, 13 tons of a Brazilian bauxite rich in trihydrate was injected in slurry form, said bauxite having previously been ground in the presence of an aliquot of the digestion liquor. The quantity of alumina dissolved is such that the A/C weight ratio of the aluminate liquor reaches 1.27/1.28. After expansion and first dilution at 175 g Na20/1, settling took place at 108° C, . in the presence of f locculant CYTEC® HX 400, at the rate of 80 0 g/ton of insoluble residue. After separation of the residue, the liquor is diluted to a concentration of 146 g Na20/1. After dilution, we obtained the following results: Pregnant liquor before crystallization A/C: 1.23 Pregnant liquor after crystallization A/C: 0.59 Global digestion yield: 91.3% extracted alumina/total alumina Productivity at crystallization: 93 kg Al203/m Energy necessary for the digestion of 1 kg of alumina: 3.15 MJ EXAMPLE 4: Sweetening and partial transfer of dilution on an American-type Bayer process In this example, an Australian monohydrate bauxite (boehmite) having the following dry ponderal composition A batch of 100 tons of this Australian monohydrate bauxite was digested according to a third mode of the invention: Digestion at 265° C for 20 minutes with a digestion liquor concentrated at 180 g Na20/1. After partial flashing, a slurry containing 11 tons of African bauxite rich in trihydrate was injected in the slurry cooled to 180° C, said bauxite having previously been ground in a minimum of digestion liquor followed by desilicatation for 8 hours at 100° C. The quantity of alumina dissolved is such that the A/C weight ratio of the aluminate liquor reaches 1.23. A first dilution at 160° C Na20/1 is carried out before settling at 103° C in the presence of flocculant CYTEC© HX 400, at the rate of 500 g/ton of insoluble residue, and then the liquor is diluted to a concentration of 130 g Na20/1. After dilution, we obtained the following results : Liquor before crystallization A/C: 1.20 Liquor after crystallization A/C: 0.63 Global digestion yield: 88.4% extracted alumina/total alumina Productivity at crystallization: 74 kg AL2CO3/m Energy.necessary for the digestion of 1 kg of alumina: 3.35 MJ 1. Process for treating an alumina monohydrate-based bauxite (1) by high-temperature caustic digestion (A2) of the ground bauxite so as to form a slurry which is settled (CI) and filtered (C2) in order to separate an insoluble residue (5) and a supersaturated sodium aluminate liquor to be crystallized (D) in the presence of seeds (10), the process being characterized by the following series of operations: a) digesting (A2) the bauxite (1) at a temperature higher than 2 00° C, by contact with a liquor (20) with a caustic concentration above or equal to 160 g Na20/liter and a A/C weight" ratio between 0.45 and 0.75, during a contact time sufficient to extract the alumindite monohydrate and to give a A/C ratio between 1.10 and 1.^0; b) cooling and flashing (Nl) the resulting slurry, then introducing (N2) alumina trihydrate (6) in said slurry, at a temperature of less than 200° C, in order to obtain A/C of the aluminate liquor between 1.20 and 1.30 when at atmospheric pressure (N3) ,• c) first diluting (N4) the slurry giving a caustic concentration between 160 and 175 g Na20/liter; d) settling of said slurry (3a) in order to separate the insoluble residue (5) from a sodium aluminate liquor (4a) having a A/C ratio between 1.20 and 1.30; e) filtering the aluminate liquor (4a); f) lowering the aluminate liquor concentration to less than 160 g Na20/liter, via a complementary dilution (M) carried out before or during crystallization (D); g) after separation of the alumina trihydrate by filtration, recycling the spent liquor (8) which, after concentration (E) is reused as digestion liquor (20) with a caustic concentration above or equal to 160 g Ma20/liter. 2. Process for treating bauxite according to claim 1, characterized in that the caustic concentration of the digestion liquor is between 160 and 220 g Na20/1. 3. Process for treating bauxite according to either of claims 1 or 2, characterized in that the digestion of the monohydrate bauxite is carried out between 220° C and 300° C for 0.2 to 1 hour. 4. Process for treating bauxite according to any of claims of 1 to 3, characterized in that the introduction of alumina trihydrate in stage b) is carried out by injection of a pulp (6) obtained by grinding, in the presence of an aliquot of the digestion liquor (20c), an alumina trihydrate bauxite (13) or a waste containing same. 5. Process for treating bauxite according to any of claims of 1 to 4, characterized in that the introduction of the alumina trihydrate takes place between 130° C and 190° C in the slurry for at least two minutes, 6. Process for treating bauxite according to any of claims of 1 -to 5, characterized in that the slurry (3a) resulting from the sweetening (N2) is settled in the presence of a synthetic polyacrylate-type flocculant at a temperature at least equal' to boiling temperature minus 5 degrees Celsius. 7. Process f ox treating bauxite according to any of claims of 1 to 6, characterized in that the supersaturated sodium aluminate liquor (4a) obtained after settling ((j:i) and filtration (C2) has a A/C ratio between 1.20 and 1.28. 8. Process for treating bauxite according to any of claims of 1 to 7, characterized in that the complementary dilution (M) of the aluminate liquor (4a) is carried out after filtration (C2) of said liquor, with a previously filtered fraction (7c) of a diluted liquor resulting from the washing of the red mud possibly containing the wash water (13a) of the trihydrate produced. 9. Process for treating bauxite according to any of claims of 1 to 8, characterized in that the sodium aluminate liquor (4a) obtained after settling (CI) and filtration (C2) is diluted (M) to a caustic concentration between 140 and 155 g Na20/1, then crystallized between 80° C and 50° C. 10. Process for treating bauxite according to any of claims of 1 to 9, characterized in that the A/C of the liquor at the end of crystallization (D) is between 0.55 and 0.65.

Documents:

142-mas-1998-abstract.pdf

142-mas-1998-claims duplicate.pdf

142-mas-1998-claims original.pdf

142-mas-1998-correspondence others.pdf

142-mas-1998-correspondence po.pdf

142-mas-1998-description complete duplicate.pdf

142-mas-1998-description complete original.pdf

142-mas-1998-drawings.pdf

142-mas-1998-form 1.pdf

142-mas-1998-form 26.pdf

142-mas-1998-form 3.pdf

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