Title of Invention

"SEPARATOR FOR SEPARATING A ELEMENTAL PHOSPHORUS FROM A MIXTURE WITH OTHER SOLIDS AND METHODS OF SUCH SEPARATION"

Abstract

A separator for separating a meltable solid from a mixture with other solids has a tank for holding a fluid; a container at least partially inside the tank, made at least in part of a screen through which the fluid can pass and melted solids can flow, but through which the unmelted solid material will not flow; and a heater for heating the fluid above the melting point of the meltable solids. In a method of separating a meltable solid from a mixture with other solids the mixture of solids is placed in the container of the separator and the fluid is heated to a temperature above the melting point of the meltable solid, whereby the meltable solid flows through the screen out of the container, while the other solids remain within the container.

Full Text

This invention relates to an apparatus and a method for separating a solid that can be melted from a mixture with other solids. In particular, it relates to the separation of elemental phosphorus from phosphorus bearing sludges by melting the phosphorus in the sludge inside a screened container. In processing phosphate rock to obtain phosphorus for use in making fertilizers, detergents, and other products, vast quantities of unuseable sludge is also produced. Since this sludge contains elemental phosphorus, it must be stored in ponds to prevent the spontaneous ignition of the phosphorus in air. Maintaining the ponds is costly, creates legal and environmental problems, and is a loss of valuable phosphorus. The phosphorus in the ponds can be recovered using mobile sumps -large, open-bottomed tubes. The sumps are forced down into the pond sediment and steam is sparged into the sediment inside the sump, melting the phosphorus. The sediment is pumped out of the sump and the melted phosphorus is separated from the remaining solids by gravity settling and filtration. Summary of the Invention According to one aspect of this invention there is provided a separator comprising (A) a tank for holding a fluid; (B) a container at least partially inside said tank, made at least in part of a screen through which said fluid can pass and melted solids can flow, but through which unmelted solid material cannot pass; and (C) heater for heating said fluid above the melting point of said melted solids. Preferably said container is a cylinder. Conveniently the axis of said cylinder is at an angle a to the horizontal of about 0 to about 5 degrees. Preferably the apparatus includes means for relating said cylinder about its axis. According to another aspect of this invention there is provided a separator for separating a meltable solid from a mixture with other solids comprising (A) a tank holding a liquid; (B) a cylinder inside said tank, at least partly immersed in said liquid, made at least in part of a screen through which melted solids can flow, but through which unmelted solid material cannot pass, where the axis of said cylinder is at an angle a of about 0 to about 5 degrees to the horizontal; (C) A heater for heating said liquid to a temperature above the melting point of said meltable solid; and (D) means for rotating said cylinder about its axis. Conveniently said means for rotating said cylinder about its axis is an electric, hydraulic, or air motor or an engine. The container of the separator may include a screw flight on the inside of said container to convey unmelted solid material along said container. According to another aspect of this invention there is provided a separator for separating elemental phosphoms from a mixture with other solids comprising (A) a tank holding water; (B) a cylinder inside said tank, at least partly immersed in said water, made at least in part of a screen through which melted elemental phosphorus can flow, but through which unmelted solid material cannot pass, where the axis of said cylinder is at an angle a of about 0 to about 5 degrees to the horizontal; (C) a heater for heating said water to a temperature of at least 44.1 °C; and (D) an electric motor for rotating said cylinder about its axis at less than about 10 rpm. Preferably said cylinder has a diameter of about 0.6 to about 2.4 m and a length of about 3.7 to about 12m. Conveniently the openings in said screen cover diameter of about 0.2 to about 0.6 cm. The invention also relates to the method of separating a meltable solid from a mixture with other solids comprising (A) placing said mixture in said container of a separator according to any one of the preceding claims; and (B) heating said fluid to a temperature above the melting point of said meltable solid, whereby said meltable solid flows through said screen out of said container and said unmelted other solids do not. Preferably said meltable solid is elemental phosphorus and said fluid is heated to a temperature above 44.1°C. In order that the invention may be more readily understood, and so that further features thereof may be appreciated, the invention will now be described, by way of example, with reference to the accompanying drawing which is a diagrammatic side view showing a preferred embodiment of an apparatus in accordance with the invention. In the drawing, a separator 1 according to this invention has a tank 2 in which is placed a horizontal cylindrical container 3 having a screened portion 4. Tank 2 is filled to level 5 with a liquid 6, such as water, which can be heated by means of heater 7. The axis 8 of container 3 is at an adjustable angle a to the horizontal. Container 3 can be rotated about its axis 8 by means 9, such as an electric, hydraulic, or air motor, or engine. Sludge, sediment, or other mixtures of solids 10 can be admitted to the inside of container 3 through input 11. (An annular solid ring, not shown, over that end of container 3 prevents material from spilling out.) Melted solids 12 flow through the openings in screened portion 4 of container 3 and collect in cones 13, which can be opened using valves 14. Unmelted solids 15 gradually tumble down container 3 and are removed by means of dewatering screw conveyer 16. This invention can be used to treat any mixture of solids that contains at least one solid that melts at a lower temperature than the other solids from which it is to be separated (or the other solids may not melt). Examples of such mixtures include elemental phosphorus in phosphorus sludge and hydrocarbons in petrochemical sludge. The mixture preferably contains elemental phosphorus and various high melting or infusible solids. For example, the phosphorus can be in a mixture with dirt, furnace slag, rock, sand, clay, and debris. Water is usually also present to keep the phosphorus from spontaneously igniting. A typical mixture from the production of elemental phosphorus from phosphate rock contains about 1 to about 40 wt% elemental phosphorus. The screened container can have any shape suitable for holding unmelted solids while permitting melted solids to escape. A cylindrical shape is preferred as a cylinder is self-cleaning, but other shapes, such as that of a cone or a rotated ellipse or parabola, can also be used. The cylinder can be made of many flat panels for better mixing and easier repair. If a cylinder is used, its axis is preferably at an angle a of between about 0 and about 5 degrees to the horizontal, so that solids move down the cylinder as it rotates. Alternatively, the cylinder can be fitted with screw flights, which will move material along the cylinder as it is rotated. The cylinder can have any dimensions, but a cylinder about 0.6 to about 2.4 m (about 2 to about 8 feet) in diameter and about 3.7 to about 12 m (about 10 to about 40 feet) long is practical for many materials. The container can be made of a variety of materials, including aluminum and various plastics; steel is the preferred material due to its strength and durability. At least some portion of the container is screened (where the melted solid is to flow out) but other portions can be unscreened to provide mechanical support or for other reasons. The openings in the screened portion should be large enough that they do not plug frequently but small enough to minimize the size of the solid particles that pass through and must be handled by the downstream equipment. A practical range for many types of materials is about 0.2 to about 0.6 cm (about 0.06 to about 0.25 inches) in diameter. The openings in the screened portion can become larger or smaller along the length of the cylinder so that the distribution of the melted phosphorus and inert solids to the various cones is controlled. The container is preferably rotated or otherwise agitated to aid in separating the melted solids from the unmelted solids. To minimize splashing, wear, and vibration, the container is preferably rotated at less than 10 rpm. It can also be vibrated, but this is generally not necessary. The container is at least partially immersed in the liquid in the tank; the portion not immersed can be in an inert atmosphere to prevent the spontaneous ignition of the phosphorus. The mixture is heated to a temperature above the melting point of the meltable solid 01 solids that are to be separated, but below the melting point of any solids or solids that are not to be separated. If the meltable solid is elemental phosphorus, for example, the mixture should be heated to about 50°C as elemental phosphorus melts at 44.1°C Heating is most conveniently accomplished by placing the screened container in a bath of a hot fluid. While the fluid can be an inert gas, such as carbon dioxide or nitrogen, it is preferably a liquid, such as water or an organic solvent, e.g., methanol, or toluene. If phosphorus is the meltable solid, the liquid is preferably water as it is inexpensive, non-toxic, and easy to work with. If a heavy liquid such as brine is used, the phosphorus will float out of the container instead of sinking to the bottom. The mixture can be added to the screened container either in batches or continuously, but continuous addition and removal of the meltable solid is preferred as processing is easier, more efficient, and more economical. It is also possible to heat the mixture in one step, melting the meltable solid, then place the mixture into the screened container for separation in a separate step, but this is not preferred. In the present specification "comprise" means "includes or consists of and "comprising" means "including or consisting of. The features disclosed in the foregoing description, or the following claims, or the accompanying drawings, expressed in their specific forms or in terms of a means for performing the disclosed function, or a method or process for attaining the disclosed result, as appropriate, may, separately, or in any combination of such features, be utilised for realising the invention in diverse forms thereof. WE CLAIM: 1. A separator for separating a elemental phosphorus from a mixture with other solids, the separator comprising: (A) a tank holding a liquid; (B) a container inside said tank, made at least in part of a screen through which said fluid can pass and melted solid can flow, but through which unmelted solid material cannot pass, the container being at least partly immersed in said liquid, with any portion of the container not immersed in said liquid being in an inert atmosphere; the container having an input for the mixture, and means for removing un-melted solids; the container having an axis and means for rotating the container about the axis, the container having a screw flight on the inside of the container, and/or having said axis of between 0° and 5° to the horizontal to convey un-melted solid along said container; (C) a heater for heating said liquid above the melting point of the phosphorus . 2. A separator as claimed in Claim 1 wherein the container is a cylinder. 3. A separator as claimed in Claim 2 wherein the means for rotating the cylinder about its axis are adapted to rotate the cylinder about its axis at less than about 10 rpm. 4 A separator as claimed in anyone of Claim 2 or Claim 3 wherein the cylinder has a diameter of about 0.6 to about 2.4 m and a length of about 3.7 to about 12 m. 5. A separator as claimed in anyone of Claims 2 to 4 wherein the openings in the screened portion becomes larger or smaller along the length of the cylinder and a plurality of cones are provided into which melted solids flowing through the openings in the screened portion can collect. 6. A separator as claimed in anyone of the preceding Claims wherein the openings in said screen have a diameter of about 0.2 to about 0.6 cm. 7. A method of separating a phosphorus from a mixture with other solids comprising: (A) placing said mixture in said container of a separator according to anyone of the preceding Claims, and (B) heating said liquid to a temperature above 44.TC, whereby said phosphorus melts and flows through said screen out of said container and unmelted solids do not. 8. A method of separating a phosphorus from a mixture with other solids utilising a separator comprising: (A) a tank holding a liquid; (B) a container inside said tank, made at least in part of a screen through which said liquid can pass and melted solid can flow, but through which unmelted solid material cannot pass, the container being at least partly immersed in said liquid, with any portion of the container not immersed in said liquid being in an inert atmosphere; and (C) a heater for heating said liquid above the melting point of phosphorus, the method comprising the steps of: (D) placing said mixture in said container of the separator, and (E) heating said liquid to a temperature above 44.1 DC, whereby phosphorus melts and flows through said screen out of said container and unmelted solids do not. 9. A method as claimed in Claim 8 wi.erein the openings in said screen have a diameter of about 0.2 to about 0.6 cm. 10. A method as claimed in Claim 8 or 9 wherein the container is a cylinder. 11. A method as claimed in Claim 8 wherein the cylinder has a diameter of about 0.6 to about 2.4m and a length of about 3.7 to about 12m. 12. A method as claimed in anyone of Claims 10 or 11 wherein the cylinder has a screen portion, the openings in the screened portion becoming larger or smaller along the length of the cylinder, a plurality of cones being provided into which melted phosphorus flowing through the openings in the screened portion can collect. 13. A method as claimed in to anyone of Claims 10 to 12 comprising the step of rotating said cylinder about its axis, the axis of the cylinder being at an angle a to the horizontal of about 0 to about 5 degrees and/or a screw flight being provided on the inside of the cylinder to convey unmelted solid material along said cylinder on rotation thereof. 14. A method as claimed in Claim 13 wherein the cylinder is rotated about its axis at less than about 10 rpm. 15. A method as claimed in Claim 13 or Claim 14 wherein the angle a of the axis of the cylinder is adjustable.

Documents:

in-pct-2002-00471-del-abstract.pdf

in-pct-2002-00471-del-assignment.pdf

in-pct-2002-00471-del-claims.pdf

in-pct-2002-00471-del-correspondence-others.pdf

in-pct-2002-00471-del-correspondence-po.pdf

in-pct-2002-00471-del-description (complete).pdf

in-pct-2002-00471-del-drawings.pdf

in-pct-2002-00471-del-form-1.pdf

in-pct-2002-00471-del-form-19.pdf

in-pct-2002-00471-del-form-2.pdf

in-pct-2002-00471-del-form-3.pdf

in-pct-2002-00471-del-form-5.pdf

in-pct-2002-00471-del-gpa.pdf

in-pct-2002-00471-del-petition-137.pdf

in-pct-2002-00471-del-petition-138.pdf