Title of Invention

"A STRUCTURE FOR SEMICONDUCTR CHIP FOR PROTECTION DURING BONDING PROCESS"

Abstract A method and structure for a semiconductor chip includes a plurality of layers of interconnect metallurgy, at least one layer of deformable dielectric material over the interconnect metallurgy', at least one input/output bonding pad, and a support structure that includes a substantially rigid dielectric in a supporting relationship to the pad that avoids crushing the deformable dielectric material.
Full Text METHOD AND STRUCTURE OF COLUMN INTERCONNECT BACKGROUND OF THE INVENTION
Field of the Invention
The present invention generally relates to semiconductor chips and more particularly to structures which protect the chip during bonding processes.
Description of the Related Art
The use of low dielectric potential (k) interlevel dielectric (ILD) materials (e.g., spin-on-glass (SOG), Hydrogensilsesquioxane(HSQ), Methylisilane (MSQ), Benzocyclobutene (BCB), etc.) has become very popular for input/output (I/O) and mechanical support structures which are applied to a previously fabricated semiconductor chip. Such I/O and support structures are formed after the logical function sections of the semiconductor chip have been completed. Therefore, such structures/processing are sometimes referred to as "back end of line" (BEOL) structures/processing because they are formed at the back end of the production line.
However, many low k materials are brittle or soft as compared to silicon dioxide and, when bonding forces are applied, the low k materials can be easily

damaged. More specifically, the forces applied during bonding processes (such as ultrasonic wirebonding) or during the formation of solderball (C4) connections, can damage the low k dielectric materials. Thus, the damage from ultrasonic energy (wirebonding), capillary pressure and temperature can weaken or collapse the low k insulator.
Also, ultra low dielectric constant materials (k Current activity with regard to the above problem includes enhancing the material properties of low k dielectrics (such as processes which increase strength and adhesion), integrating multiple metal films on the copper to provide for compatibility with current C4/wirebond processes, and silicidation of copper to improve nitride adhesion. A recent publication 1998 IEEE 38th Annual IRPS-Reno, NV, March 31, 1998, p. 225-231, by Mukul Saran et al. (incorporated herein by reference) describes the use of metal grids to provide for mechanical
reinforcement of the dielectric stack to eliminate bond-pad damage during wirebonding of Al or Au wires to aluminum pads.
SUMMARY OF THE INVENTION
It is, therefore, an object of the present invention to provide a structure and method for a semiconductor chip that includes a plurality of layers of interconnect metallurgy, at least one layer of defonnable dielectric material over the interconnect metallurgy, at least one input/output bonding pad, and a support structure that includes a substantially rigid dielectric in a supporting relationship to the pad that avoids crushing the defonnable dielectric material.
The support structure includes a cap over the deformable dielectric material, where the cap is co-planer with the patterned last metal layer or the cap has a thickness greater than that of the patterned last metal layer. The support structure may also include patterned metal layers separated by the rigid dielectric where the patterned metal layers are joined by a plurality of metal connections through the rigid dielectric or may include metallic leg structures extending from the last metal layer into the deformable dielectric material. The leg structures can be a plurality of metallic blocks formed at progressive levels within the deformable dielectric material. The metallic blocks can form a herringbone pattern in cross-section or a step-shaped structure in cross-section.
Another embodiment of the invention is an integrated circuit chip that includes logic circuitry, an external insulator covering the logic circuitry, and a contact over the insulator allowing electrical connection to the logic circuitry. The external insulator includes a first dielectric layer having a first dielectric constant and a support structure having a second dielectric constant higher than the first dielectric constant.
Yet another embodiment of the invention is an integrated circuit chip that includes logic circuitry, an external insulator covering the logic circuitry, and a contact over the insulator allowing electrical connection to the logic circuitry. The contact includes a metallic structure extending above the external insulators. The metallic structure has a pillar or pyramid shape.
Yet another embodiment of the invention is an integrated circuit chip that includes logic circuitry, an external insulator covering the logic circuitry, a contact over the insulator allowing electrical contact to the logic circuitry, and a lattice structure that includes a first dielectric having a first dielectric constant and a second dielectric having a second dielectric constant higher than the first dielectric constant. The lattice structure can be a crisscross pattern of the second dielectric in a layer of the first dielectric, an alternating layer of the first dielectric and the second dielectric, or sidewall spacers of the second dielectric between portions of the first dielectric.
Yet another embodiment of the invention is an integrated circuit chip that includes logic circuitry, an external insulator covering the logic circuitry, and a
contact over the external insulator allowing electrical contact to the logic circuitry. The external insulator includes support columns between the logic circuitry and the contact. The support columns are portions of metallization and via levels within the external insulator and can be hollow columns filled with an insulator. The support columns can include heat sinks, and are spaced to permit wiring to be positioned within the external insulator.
The invention overcomes the problems associated with conventional BEOL structures that are discussed above. More specifically, the invention comprises additional structures on top of or within the BEOL structure that add support to the inter-layer dielectric (ILD) during wire or C4 bonding processes.
BRIEF DESCRIPTION OF THE DRAWINGS
The foregoing and other objects, aspects and advantages will be better understood from the following detailed description of a preferred embodiment of the invention with reference to the drawings, in which:
Figure 1 is a schematic diagram of the inventive cap above last metal (LM) level;
Figure 2 is a schematic diagram of the inventive cap above LM level with Pad;
Figure 3 is a schematic diagram of the inventive cap at LM level coplanar with LM having a thickness equal to LM;
Figure 4 is a schematic diagram of the inventive cap coplanar with LM level with a thickness greater than that of LM;
Figure 5 is a schematic diagram of the inventive cap between LM-1 and LM and a rivet design;
Figure 6 is a schematic diagram of the inventive cap with legs;
Figure 7 is a schematic diagram of an inventive vertical stack;
Figure 8 is a schematic diagram of an inventive herringbone stack;
Figure 9 is a schematic diagram of an inventive staircase stack;
Figure 10 is a schematic diagram of an inventive bond pad containing a metal pillar;
Figure 11 is a schematic diagram of the structure shown in Figure 10 etched;
Figure 12 is a schematic diagram of a single level of mixed dielectric materials for the base and the lattice;
Figure 13 is a schematic diagram illustrating an inventive crisscross pattern of lattice;
Figure 14 is a schematic diagram illustrating single lines of different dielectrics;
Figure 15 is a schematic diagram of the beginning phase of building the inventive lattice;
Figure 16 is a schematic diagram of the inventive lattice structure formed;
Figure 17 is a schematic diagram of another phase of building the inventive lattice building;
Figure 18 is a schematic diagram of the last phase of building the inventive lattice;
Figure 19 is a schematic diagram of the beginning phase of fabricating inventive lattice structure;
Figure 20 is a schematic diagram of the inventive lattice structure;
Figure 21 is a schematic diagram of the inventive lattice structure;
Figure 22 is a schematic diagram of the inventive lattice structure;
Figure 23 is a schematic diagram of the inventive lattice structure;
Figure 24 is a schematic diagram illustrating the inventive metal columns;
Figure 25 is a schematic diagram illustrating the inventive bond pad column supports;
Figure 26 is a schematic diagram of the inventive bond pad column supports;
Figure 27 is an enlarged schematic diagram of the inventive bond pad column supports;
Figure 28 is a schematic diagram of the inventive bond pad column supports;
Figure 29 is a schematic diagram of the inventive bond pad column supports;
Figure 30 is a schematic diagram of the inventive bond pad column supports;
Figure 31 is a schematic diagram of a cross-section of the inventive bond pad column supports;
Figure 32 is an enlarged schematic diagram a cross-section of the inventive bond pad column supports;
Figure 33 is a schematic diagram showing an example of a structure with an additional metal layer between the copper pad and the last level of copper;
Figure 34 is a schematic diagram showing a structure which eliminates the additional metal layer shown in Figure 34;
Figure 35 is a schematic diagram of a top view of the spacing achieved between roots to provide wiring channels according to the invention; and
Figure 36 is a schematic diagram of a high adhesion structure according to the invention.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS OF THE INVENTION
The invention overcomes the problems associated with conventional BEOL structures that are discussed above. More specifically, the invention comprises additional structures on top of or within the BEOL structure that add support to the inter-layer dielectric (ILD) during wire or C4 bonding processes.
A first embodiment of the invention is illustrated in Figure 1 and includes a last metallization layer (LM) 11, a second to last metallization layer (LM-1) 13, a conductive via 12 connecting the two metallization layers 11, 13, and inter-layer dielectrics 14 which provide electrical insulation, but are too fragile to provide adequate mechanical support. In addition to the conventional structure, the invention includes a protective cap 10.
The invention adds the protective cap 10 above the last metallization (LM) layer 11. The thickness of the cap 10 is between 1 and 20 microns, and is preferably 10 microns thick. The cap 10 can be formed of, for example, silicon dioxide (SiO2), (spin-on-glass) SOG, silicon nitride, doped SiO2 (i.e. F, B, P), HSQ, MSQ or other similar protective substance. The preferred embodiment would comprise 50nm nitride, lum oxide, lum nitride, lOum oxide (nitride = SixNyHz an oxide = SiO2), but could be any similar structure. Note the initial 50nm of nitride is only required if the oxide has poor adhesion to the last metal and the last lOum of oxide could be any dielectric with good mechanical properties.
The cap 10 is deposited above the LM layer 11 using standard deposition techniques such as sputtering, chemical vapor deposition (CVD), etc. In addition, a conductor pad 20 can be deposited, as shown in Figure 2. The pad 20 comprises any standard metal, such as Al (99.5%) Cu (0.5%), which can be deposited and patterned. Preferably, the pad 20 will comprise a stack of 50nm
TaN, 3µm Al (99.5%) Cu (0.5%), and l00nm TIN. The structure is thus prepared for wirebonding or C4 bonding processes.
Standard final passivation oxide/nitride is typically under 1 µm thick while the cap, 10, is preferably greater than 10µm thick. The relatively thick cap layer, 10, provides a rigid surface to absorb the forces associated with wirebonding, solder bumping, packaging etc.
Another embodiment is shown in Figure 3. In this embodiment the cap 30 is formed at the LM 11 level. A damascene or other similar process could be used to build LM 11 into the cap 30. In this embodiment, the cap 30 becomes part of the last level dielectric. This embodiment adds a shock absorbing layer 30 co-planer to the last level of metal 11. Therefore, this embodiment could be used alone to produce a stronger structure which has the same topography or combined with the structure shown in Figure 2. The LM 11 level may be the same thickness as the cap 30 or thicker, as shown in Figure 4.
An additional embodiment, which is illustrated in Figure 5, includes a cap 51 located between LM-1 and LM. This is a "rivet" design where LM-1 is attached to LM with the conductive metal (stem) 12. The cap 51 layer is between the base 13 and head 11 of the rivet, as shown in Figure 5. A damascene process is preferably used to form the cap 51 and rivet 52 structure; however, as would be known by one ordinarily skilled in the art given this disclosure, any similar process could be used. The LM 11 and associated ILD 14 are preferably prepared
after forming the cap 51, using standard metal deposition techniques. This embodiment would allow the last metal, 12 to be fabricated in a low k dielectric.
Another embodiment of the invention comprises a cap and leg structure, as show in Figure 6. Support structures (legs) 60 are preferably formed of materials similar to the cap 61. The legs 60 may be formed by etching a deep via/hole and filling the hole with the cap 61 material. Alternatively, as illustrated in Figures 7-9 the legs 70, 80, 90 are formed by placing a stud of material at each level so as to build a stacked building block structure.
The building blocks may be stacked directly on top of one another (see Figure 7), in a herringbone pattern (see Figure 8), or as a step-like stack (see Figure 9). As would be known by one ordinarily skilled at in the art, the placement of the building blocks is controlled by modifying the deposition/etching process of each successive layer.
Using this embodiment, the leg structures 90 can be located anywhere that design requirements allow so as not to interfere with BEOL structures. The legs provide a rigid path from the last metal pad surface to the silicon substrate. This rigid "table" supports the last metal pads, which are fabricated over the low k dielectric.
Another embodiment of the invention comprises a design for a metal bond pad that dissipates the forces that develop during wirebonding or C4 joining that can damage fragile low k dielectric materials. As shown in Figure 10, this embodiment of the invention includes a structure 100 which may be a circular,
square or other shaped pillar of metal and is located above the LM or bond pad 11. Wirebonding or C4 bonding will occur at this structure 100 which will act to dissipate or absorb the forces associated with the bonding process.
More specifically, the pillar of metal 100 (e.g., copper, aluminum, or tungsten) is built onto the previously formed bond pad 11, as shown in Figure 10. An interface metal film/pad 102 may be deposited if necessary to attach the pillar 100 to the LM or bond pad 11.
The pillar 100 could be formed using any number of well-known process. For example, a film (e.g., 0.1 to 50µm thickness, preferably 10 µm) of sacrificial masking material 103 could be deposited. This masking material 103 may be a photoresist, polyimide, photo-polyimide, etc. Photolithographic and etching techniques (dry, wet) could be used to pattern the mask film 103 so as to expose the areas where the metal pillars 100 are to be located. The metal pillar 100 material is deposited using sputtering or evaporation techniques. The mask material 103 may be removed using wet chemical or dry etch techniques. An additional metal pad or interface metal 110 may be added to the top of the metal pillar 100 to allow for better adhesion to the bonding material, as shown in Figure 11. The pillar prevents probes from protruding into the low k dielectric through the next level 11.
The next embodiment, which is illustrated in Figure 12, includes a lattice structure 131 which is built into the BEOL structure 130. The lattice structure 131 comprises standard, higher k dielectrics (e.g., SiO2, P, B, F, etc. doped glass,
SixNyH2, SixCyH2) and may be designed into one or several levels of the BEOL. The invention can be mixed and matched with varying dielectric materials within the BEOL to maximize the desired properties of the ILD and support lattice. The lattice lines may be placed in any pattern. For example, Figure 13 illustrates a crisscross pattern of a lattice and Figure 14 illustrates single lines of different dielectric.
While the lattice structure 131 will increase the effective dielectric constant k of the BEOL structure, it also acts as a rigid frame to prevent damage to the fragile low k dielectric, 131, during subsequent processing, testing, wirebonding, solderball bumpint, packaging, etc.
This embodiment can be formed using a number of conventional processes, as would be known by one ordinarily skilled in the art given this disclosure. For example, a film of higher k 131 dielectric can be deposited, as shown in Figure 15. Using photolithographic or other similar techniques, the lattice structure could be defined, as shown in Figure 16. The low k material 130 is deposited and planarized (using, for example, chemical mechanical polishing (CMP)) or etched as shown in Figures 17 and Figure 18, respectively. Alternatively, the low k dielectric 130 can be patterned and the standard dielectric 131 can be deposited and planarized. Additionally, a hard mask may be used on top as an etch or CMP stop, if necessary.
Also, this embodiment may be formed by depositing and patterning the low k 130 dielectric (i.e. spin-on photoresist, pattern the photoresist, etch the
dielectric 131, strip the photoresist), as shown in Figure 19. A standard high k plasma CVD or PVD dielectric material 131 is deposited to conform to the pattern, as shown in Figure 20. Anisotropic dry etching etches the standard dielectric 131, leaving a sidewall 220 of standard dielectric which becomes the lattice, as shown in Figure 21. More low k dielectric 130 is redeposited to fill the pattern, as shown in Figure 22, followed by a planarization etch or CMP, as shown in Figure 23. Again, a hard mask may be used as an etch or CMP stop.
Another embodiment, which is illustrated in Figures 24, is a series of stacked metal fill shapes (e.g., columns) 250 which support a C4 251 or wirebond pad 256. These metal columns 250 include a series of metal studs which are formed at the contact 252, metal 253 and via levels 254. The initial stud formed at the contact level 252 is placed above the shallow trench isolation (STI) 255 or on the inorganic dielectric using tungsten vias/interconnects and/or local interconnects (i.e. BPSG, PSG, SiO2, SiNyHz, SixCyHz, etc.). The columns 250 continue to the final pad 256, providing mechanical stability of the pad structure. The columns are positioned in areas that would allow wires 259 to pass under the pad 256. Thus, the invention does not limit the ability of the wire 259, yet provides for a robust C4 structure 251, as shown in Figure 24.
The metal columns 250 are compatible with a dual damascene process. The vias associated with the metal column could be any size and are preferably 2 microns or larger in diameter. In addition to providing mechanical strength, metal runners 257 could be formed during the formation of the metal levels 253.
The runners gather heat and dissipate the heat through the C4 pad 251. The runners 257 are metal lines that extend beyond the columns 250 (where allowed by the design) to act as heat sinks. Further, bar bias (e.g., vias with length to width ratio greater than 2) could be employed to maximize the stabilizing area. As shown in Figure 25 the columns can be spaced appropriately so as to allow for adequate mechanical strength.
Another embodiment, shown in Figure 26 includes "composite" columns 270 which have a "staircase" structure formed using the methods discussed above. The "composite" columns 270 build a metal casing around a low k dielectric, 271, as part of the standard wire arid vias. The structure shown in Figure 27 is capped by a series of insulator layers, such as nitride layer 272, oxide layer 273 and nitride layer 274. Layer 275 could be another insulator, a resist, the pad, etc.
As shown in greater detail in Figure 27, each of the "stairs" of the composite columns 270 includes a metallic (e.g., Cu, Al, etc.) step portion 280 and a liner 281 (e.g., Ta, Ti, W, including nitridized or silicon doped alloys etc.), surrounded by alternating layers of a low k dielectric 282, a standard insulator (e.g., SiO2, SixNyHz, SixC ^ etc. 283) and Nitride, SixNyH2, SixCyHz, etc. 284. Note the inorganic insulators 283,284 are used in conjunction with a polymer low k dielectric and are not required for all low k dielectrics.
These composite column structures 270 could also be used as heat sinks. This is important if the low k dielectric is a poor thermal conductor. These
composite column structures 270 consume relatively small areas of the chip, as shown in Table 1.
Table 1

(Table Removed)
Figure 28 illustrates a resist 290 which is used to remove the low k dielectric from the region 291. Then, Figure 29 shows one example of the relative dimensions of the various structures shown in Figures 27 and 28. In Figure 29, the resist 290 and a portion of the nitride layer 274 are etched down to point 300. Then, in Figure 30, the opening 291 is filled with a rigid substance such as hard spin-on-glass 310 and a pad 311 is formed over the structure. The spin-on-glass (or other rigid material) adds to the mechanical strength of the column structure.
Figure 31 illustrates a top-view of a five column support 320, which can be any of the inventive columns mentioned above, such as those shown in Figure 26. The positioning of the columns 320 is selected to maximize the strength of the structure. While one example is shown in Figure 31, as would be known by one ordinarily skilled in the art in light of this disclosure, different patterns of columns may be used to alter the strength of the structure.
Figure 32 illustrates a top view of one of the columns (e.g., such as the columns shown in Figure 26). For example, the spin-on-glass portion 291 occupies the center, the copper portion 270 surrounds the spin-on-glass 291 and the low k dielectric 271 forms the outer portion.
Referring now to Figures 33 and 34, the use of the invention to eliminate an additional metal layer is illustrated. More specifically, the structure in Figure 34 includes a barrier dielectric 340 (such as a nitride dielectric), dielectric layers 341,342, a pad layer 343 (such as a copper pad), and a solderball C4 wiring layer 345. In addition, the structure shown in Figure 34 includes a metal layer 344 (e.g., aluminum) above the pad layer 343. The notched shape of the metal layer 344 helps maintain the pad 343 against the barrier dielectric 340. To the contrary, in Figure 34 the anchored structure 350 (e.g., last metallization and second to last metallization layer, which can be formed as discussed in Figure 5 above) replaces the pad 343 and the notched metallization layer 344. This simplifies the structure, makes it smaller and lighter, and reduces the processing time and complexity. In addition, the structure shown in Figure 34 includes an oxide layer 351 which further strengthens the structure. The "root" 352 lengths and orientation can be modified to achieve the desired adhesive strength for different pad structure topologies.
Referring now to Figures 35 and 36, another embodiment of the invention is illustrated. More specifically, Figure 35 illustrates a top view of the structure and Figure 37 illustrates a cross sectional view of the structure along lines A-A of
Figure 35. The C4 structure is shown as item 360, the last metallization layer is shown as item 361, the next to last metallization layer is shown as item 363, and the bar via connecting the last metallization layer 361 to the second to last metallization layer 363 is shown as item 362 in Figures 35 and 36. In addition, Figure 36 illustrates various dielectric insulating layers 364 which are utilized as discussed in the foregoing embodiments. As discussed in the previous embodiments, this structure provides a superior adhesion strength between the last metallization layer 361 and the adjacent dielectric.
Therefore, the invention provides many alternatives for increasing the adhesive strength between the last metallization layers and the adjacent dielectric. As would be known by one ordinarily skilled in the art given this disclosure, the invention is not limited to the structures disclosed above. Instead, the invention comprises any similar structure which utilizes any version of the supporting structure described above. Therefore, while the invention has been described in terms of preferred embodiments, those skilled in the art will recognize that the invention can be practiced with modification within the spirit and scope of the appended claims.




We Claim:
1. A semiconductor chip for protection during bonding process comprising:
a plurality of layers of interconnect metallurgy;
at least one input/output bonding pad connected to said
interconnect metallurgy, characterized in that;
at least one deformable dielectric layer is provided over said
interconnect metallurgy at least over one input/output bonding pad,
and
a support structure connected to said deformable dielectric in a
supporting relationship to said pad in order to avoid crushing said
deformable dielectric layer,
2. The semiconductor chip as claimed in claim 1, wherein said support
structure comprises a cap over said deformable dielectric material.
3. The semiconductor chip as claimed in claim 1 wherein said support
structure comprises a patterned last metal layer of said interconnect
metallurgy.
4. The semiconductor chip as claimed in claims 2 and 3, wherein said cap is
co-planer with said patterned last metal layer and said cap has a thickness
greater than said patterned last metal layer.
5. The semiconductor chip as claimed in claim 1, wherein said support
structure is metallic leg structure blocks formed at progressive levels
within said deformable dielectric material, and said metallic blocks form a
herringbone pattern in cross-section or step shaped structure in cross
section.

6. A semiconductor chip as claimed in claim 1, wherein said semi-conductor
chip is an integrated circuit chip and comprises:
logic circuitry;
an external insulator covering said logic circuitry; and
a contact over said insulator allowing electric connection to
said logic circuitry.
7. A semiconductor chip as claimed in claim 1, wherein said deformable
dielectric layer having a first dielectric constant and said support structure
having a second dielectric constant higher than first dielectric constant.
8. The semiconductor chip as claimed in claims 1, 3 and 5, wherein said
support structure comprises:
a second dielectric layer having said second dielectric constant and including a patterned last metal layer; and
9. The semiconductor chip as claimed in claims 1, 2 and 5 wherein said
support structure comprises a cap over said deformable dielectric layer
and said leg structures comprise a plurality of metallic blocks formed at
progressive levels within said deformable dielectric layer,
10. The semiconductor chip as claimed in claim 6, wherein said contact
comprises a metallic structure extending above said external insulator,
11. The semiconductor chip as claimed in claim 10 wherein said metallic
structure has a circular pillar shape or square pillar shape.
12. The structure as claimed in claim 6, wherein said external insulator has a
lattice structure including a first dielectric having a first dielectric constant
and a second dielectric having a second dielectric constant higher than
said first dielectric constant.

13. The structure as claimed in claim 12 wherein said lattice structure
comprises a crisscross pattern of said second dielectric in a layer of said
first dielectric.
14. The structure as claimed in claim 12, wherein said lattice structure
comprises sidewall spacers of said second dielectric between portions of
said deformable dielectric layer.

Documents:

196-del-2001-abstract.pdf

196-del-2001-claims.pdf

196-del-2001-correspondence-others.pdf

196-del-2001-correspondence-po.pdf

196-del-2001-description (complete).pdf

196-del-2001-form-1.pdf

196-del-2001-form-19.pdf

196-del-2001-form-2.pdf

196-del-2001-form-3.pdf

196-del-2001-form-4.pdf

196-del-2001-form-5.pdf

196-del-2001-gpa.pdf

196-del-2001-petition-137.pdf

196-del-2001-petition-others.pdf


Patent Number 220109
Indian Patent Application Number 196/DEL/2001
PG Journal Number 28/2008
Publication Date 11-Jul-2008
Grant Date 15-May-2008
Date of Filing 27-Feb-2001
Name of Patentee INTERNATIONAL BUSINESS MACHINE CORPORATION
Applicant Address
Inventors:
# Inventor's Name Inventor's Address
1 PREVITI-KELLY ROSEMARY A.
2 GEFFLEM RPNERT M.,
3 LANDIS HOWARD S.
4 ELLIS-MONAGHAN JOHN J
5 YANKEE SALLY J.
6 REUTER BETTE L.
7 STAMPER ANTHONY K.
8 FEENEY PAUL M.,
9 RETTEN MATTHEW J.
PCT International Classification Number H01L 23/58
PCT International Application Number N/A
PCT International Filing date
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 09/527,276 2000-03-17 U.S.A.