Title of Invention

NOVEL POLYMERS AND OPTICAL DEVICES CONTAINING THE SAME

Abstract

The present invention relates to polymers comprising diazine, especially pyrimidine, containing repeating units. Optical devices, comprising the polymers of the present invention, can show significant advantages in color purity, device efficiency and/or operational lifetime. In addition, the polymers can have good solubility characteristics and relatively high glass transition temperatures, which facilitates their fabrication into coatings and films that are relatively thin, thermally stable, and relatively free of defects.

Full Text

Novel Polymers for Use in Optical Devices The present invention relates to novel polymers comprising pyrimidine containing repeating units and to their use in optical devices, such as an optical device comprising an electroluminescent device or a photovoltaic device. Derivatives of poly(p-phenylenevinylene) have been known for some time as electroluminescence (EL) materials (see, for example, WO90/13148). W098/11150 discloses triazine polymers of formula electroluminescence (EL) arrangements. US-A-5,876,864 relates to fluorene-based alternating polymers and and their use as electroluminescence materials. M. M. Koton et al., Vysokomolekulyarnye Soedin.; Seriya B: Kratkie Soobshcheniya, vol. 30, no. 10, 1978, 792-793 disclose polyimides on the basis of 2-phenyl-4,6-bis(p- E WO02/059121 discloses monomers having formula S, NR, RC-CR, or RC=CR, Ar is an aryl or heteroaryl group, and E is a reactive group capable of undergoing chain extension and their use for the production of polymers which can be used in optical devices (see also WO01/62869). DE-A-19651439 (US-A-6,323,373) relates to polymerizable biaryl derivatives of the formula where the symbols and indices have the following meanings: X: -CH2-Z, -CHO; Y\Y2,Y3:CH;N, Z: identical or different, I, CI, Br, CN, SCN, NCO, PO(OR1)2, PO(R2)2, P(R3)3+ A"; Aryl: an aryl group having from 6 to 14 carbon atoms; R', R": identical or different, CN, F, CI, a straight-chain or branched or cyclic alkyl or alkoxy group having from 1 to 20 carbon atoms, where one or more nonadjacent CH2 groups is optionally replaced by -0-, -S-, -CO-, -COO-, -0-CO-, -NR4-, -(NR5R6)+A" or -CONR7- and one or more H atoms is optionally replaced by F, or an aryl group having from 6 to 14 carbon atoms which may be substituted by one or more nonaromatic radicals R1; R\ R2, R3, R5, R6: identical or different, aliphatic or aromatic hydrocarbon radicals having from 1 to 20 carbon atoms; R4, R7: identical or different, hydrogen or aliphatic or aromatic hydrocarbon radicals having from 1 to 20 carbon atoms; A": a singly charged anion or its equivalent; m:0,1 or 2; n: 1, 2, 3, 4 or 5 and their use for the production of polymers. There are a number of challenges faced with the introduction of organic EL displays when their performance is compared with existing technologies. Obtaining the exact color coordinates required by specific guidelines (i.e. NTSC) has been problematic. The operational lifetime of the EL device is relatively lower when contrasted to the existing inorganic technology. In addition, producing a material with a pure blue color and a long lifetime is one of the greatest problems for this industry. Accordingly, it is the object of the present invention to provide novel materials, which show significant advantages in color purity, device efficiency and/or operational lifetime, when incorporated in optical devices. Said object, is solved by the polymers of the present invention comprising diazine, especially pyrimidine, containing repeating units. Optical devices, comprising the polymers of the present invention, can show significant advantages in color purity, device efficiency and/or operational lifetime. In addition, the polymers can have good solubility characteristics and relatively high glass transition temperatures, which facilitates their fabrication into coatings and films that are relatively thin, thermally stable, and relatively free of defects. If the polymers contain end groups which are capable of being crosslinked, the crosslinking of such groups after the films or coating is formed increases the solvent resistance thereof, which is beneficial in applications wherein one or more solvent-based layers of material are deposited thereon. Accordingly, the polymers of the present invention should have a glass transition temperature above 100°C, especially a glass transition temperature above 150°C. As used herein the term "polymer of the present invention" refers to polymers having repeating units of formula I, including formula la and lb, and/or II, including formula I la, lib and He. In a first aspect, the present invention relates to polymers comprising a repeating unit of the formula (I), wherein R1 and R* are independently of each other an organic substituent, especially C6-C30aryl or a C2-C26heteroaryl, which optionally can be substituted, n1, n2, n3, n4, n5, n6 and n7 are integers of 1 to 10, in particular 1 to 3, R6 and R7 are independently of each other H, CrC18alkyl, CrC18alkyl which is substituted by E and/or interrupted by D, C5-C12cycloaIkyl, C5-Ci2cycloalkyl, which is substituted by E, C6- C24aryl, C6-C24aryl which is substituted by E, QrC^heteroaryl, C2-G2oheteroaryi which is substituted by E, C2-C18alkenyl, C2-Ci8alkynyl, d-C18alkoxy, d-C18aIkoxy which is substituted by E and/or interrupted by D, C7-C2saralkyl, or -CO-R28, R8 is d-Ciaalkyl, Ci-C18alkyl which is substituted by E and/or interrupted by D, C6-C24 aryl, or C7-C25aralkyl, R9 and R10 are independently of each other CrCi8 alkyl, CrCi8alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, Ca-C^heteroaryl, CrC^heteroaryl which is substituted by E, CrCi8alkenyl, C2-Ci8alkynyl, Ci-Ci8alkoxy, Cr Ci8alkoxy which is substituted by E and/or interruptedly D, or C7-C25aralkyl, or R9 and R10form a ring, especially a five- or six-membered ring, which may optionally be substituted by R6, R14' and R15' are independently of each other H, d-Ciaalkyl, CrC18alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by Ef C2- C^heteroaryl, or d-C^heteroaryl which is substituted by E, D is -CO-; -COO-; -S-; -SO-; -S02-; -0-; -NR25-; -SiR^R31-; -POR32-; -CR^CR24-; or -C=C-; and E is -OR29; -SR29; -NR^R26; -COR28; -COOR27; -CONR25R26; -CN; -OCOOR27; or halogen; wherein R23, R24( R25 and R26 are independently of each other H; C6-Ci8aryl; C6-C18aryl which is substituted by d-Ci8alkyl, CrCi8aIkoxy; Ci-C18alkyl; or d-C18alkyI which is interrupted by- 0-;or R25 and R26 together form a five or six membered ring, in particular - ,or ~ , R27 and R28 are independently of each other H; C6-C18aryl; C6-d8aryl which is substituted by Ci-Ci8alkyl, or CrCi8alkoxy; d-C18alkyl; or CrC18alkyl which is interrupted by -0-, R29 is H; C6-C18aryl; C6-Ci8aryl, which is substituted by CrCi8alkyl, Ci-Ci8alkoxy; CrC18alkyl; or CrC18alkyl which is interrupted by -0-, R30 and R31 are independently of each other CrC18alkyl, C6-Ci8aryl, or C6-Ci8aryl, which is substituted by Ci-Ci8alkyl, and R32 is CrCi8aIkyI, C6-d8aryl, or drdsaryl, which is substituted by d-Ci8alkyl. Preferably, R6 and R7 are independently of each other H, CrC18alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-. hexyl, 2-ethylhexyl, or n-heptyl, d-Ci8alkyl which is substituted by E and/or interrupted by D, such as -CH2OCH3, -CH2OCH2CH3, -CH2OCH2CH2OCH3, or -CH20CH2CH20CH2CH3, C6-C24aryl, such as phenyl, naphthyl, or biphenyl, C5-Ci2cycloalkyl, such as cyclohexyl, C6-C24aryl which is substituted by E, such as -C6H40CH3, -C6H4OCH2CH3l -C6H3(OCH3)2) or -C6H3(OCH2CH3)2, -C6H4CH3, -C6H3(CH3)2) -C6H2(CH3)3l or -C6H4tBu. R8 is preferably H, d-C18alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, n-heptyl, or C6-C24aryl, such as phenyl, naphthyl, or biphenyl. Preferably, R9 and R10 are independently of each other H, d-C18alkyl, such as n-butyl, sec-butyl, hexyl, octyl, or 2-ethyl-hexyl, Ci-d8alkyl which is substituted by E and/or interrupted by D, such as -CH2(OCH2CH2)wOCH3, w = i, 2, 3, or 4, C6-C24aryl, such as phenyl, naphthyl, or biphenyl, C6-C24aryl which is substituted by E, such as -C6H4OCH3( -C6H4OCH2CH3, -C6H3(OCH3)2) -C6H3(OCH2CH3)2, -C6H4CH3, -C6H3(CH3)2, -C6H2(CH3)3| or -C6H4tBu, or R9 and R10 together form a 4 to 8 membered ring, especially a 5 or 6 membered ring, such as cyclohexyl, or cyclopentyl, which can optionally be substituted by Ci-C8alkyl. Preferably, R14' and R15' are independently of each other H, Ci-Ci8alkyl, such as as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, or sec-butyl, or C6-C24aryl, such as phenyl, naphthyl, or biphenyl. D is preferably -CO-, -COO-, -S-, -SO-, -S02-, -0-, -NR25-, wherein R25 is Ci-C18alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, or sec-butyl, or C6-C24aryl, such as phenyl, naphthyl, or biphenyl. E is preferably -OR29; -SR2*; -NR^R25; -COR28; -COOR27; -CONR^R25; or -CN; wherein R25, R27, R28 and R29 are independently of each other CrC18alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, hexyl, octyl, or2-ethyl-hexyl, or C6-C24 aryl, such as phenyl, naphthyl, or biphenyl. Among the above-mentioned groups X1 and X2 the following groups are preferred: , wherein the substituents are defined as above. R1 and R2 can in principal be any organic substituent, provided he does not have negative influence on the (electro)luminescent characteristics of the polymers. Examples of R1 and R2 are H, Ci-Ci8 alkyl, d-daalkyl which is substituted by E and/or interrupted by D, C2- CrC18alkoxy which is substituted by E and/or interrupted by D, or C7-C25aralkyl, X4 is CrCi8alkyl, CrC18alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, which optionally can be substituted, X5is CrCisalkyI, C6-C24aryl, C6-C24aryl substituted by -OCrC18alkyl or -OC6-C24aryl, R11, R12 and R13 are independently of each other H, CrC18 alkyl, d-Ci8alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, C2- Ci8alkenyl, C2-Ci8alkynyl, CrC18alkoxy, CrCi8aIkoxy which is substituted by E and/or interrupted by D, C7-C25aralkyl, and D, E, R6, R7, R8, R9, R10, R14' and R15' are as defined above. Preferably, R6 and R7 are independently of each other H, CrC18 alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, or n-heptyl, CrCi8alkyl which is substituted by E and/or interrupted by D, such as -CH2OCH3l -CH2OCH2CH3, -CH2OCH2CH2OCH3, or -CH2OCH2CH2OCH2CH3, C5-C12cycloalkyl, such as cyclohexyl, C6-C24aryl, such as phenyl, naphthyl, or biphenyl, C6-C24aryl which is substituted by E, such as -C6H4OCH3) -C6H4OCH2CH3, -C6H3(OCH3)2, or -C6H3(OCH2CH3)2, -C6H4CH3, -CeH3(CH3)2) -C8H2(CH3)3, or-Cel^tBu. R8 is preferably H, Ci-Ci8alkyt, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl,.t-butyl, 2-methylbutyI, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, and n-heptyl, or Ce-C^aryl, such as phenyl, naphthyl, or biphenyl. Preferably, R9 and R10 are independently of each other H, CrC1Qalkyl, such as n-butyl, sec-butyl, hexyl, octyl, and 2-ethyl-hexyl, CrC18alkyl which is substituted by E and/or interrupted by D, such as -CH2(OCH2CH2)wOCH3, w = 1, 2, 3, or 4, C6-C24aryl, such as phenyl, naphthyl, and biphenyl, C6-C24aryl which is substituted by E, such as -C6H4OCH3f -C6H4OCH2CH3, -C6H3(OCH3)2l -C6H3(OCH2CH3)2, -C6H4CH3( -C6H3(CH3)2, -C6H2(CH3)3) and -C6H4tBu, or R9 and R10 together form a 4 to 8 membered ring, especially a 5 or 6 membered ring, such as cyclohexyl, or cyclopentyl, which can optionally be substituted by d-C8alkyl. Preferably, R14' and R15' are independently of each other H, CrCi8alkyl, such as as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, and sec-butyl, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl. X4 is preferably CrCi8alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, hexyl, octyl, and 2-ethyl-hexyl, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl, and X5 is preferably d-CiaalkyI, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, hexyl, octyl, and 2-ethyl-hexyl, or C6-C24 aryl, such as phenyl, naphthyl, and biphenyl. Preferably, R1\ R12 and R13 are independently of each other H, CrC18alkyl, such as methyl, and ethyl, CrCi8alkyl which is substituted by E and/or interrupted by D, such as -CH2OCH3, -CH2OCH2CH3,-CH2OCH2CH2OCH3l and -CH2OCH2CH2OCH2CH3, C6-C24aryl, such as phenyl, naphthyl, and biphenyl, C6-C24aryl which is substituted by E, such as -C6H4OCH3, -C6H4OCH2CH3, -C6H3(OCH3)2, -C6H3(OCH2CH3)2, -C6H4CH3, -C6H3(CH3)2, -C6H2(CH3)3, and -CeH4tBu, C2-C18alkenyl, C2-Ci8alkynyl, Ci-C18alkoxy, CrCi8alkoxy which is substituted by E and/or interrupted by D, such as -OCH2OCH3, -OCH2OCH2CH3, CH2OCH2CH2OCH3) -OCH2CH2OCH3, -OCH2CH2OCH2CH2OCH3 and -OCH2CH2OCH2CH2OCH2CH3, methoxy, ethoxy, n-propoxy, iso-propoxy, n-butoxy, isobutoxy, sec-butoxy, hexoxy, octoxy, and 2-ethyl-hexyloxy, and C7-C25aralkyl. D is preferably -CO-, -COO-, -S-, -SO-, -S02-, -0-, -NR25-, wherein R25 is CrC18 alkyl, such as methyl, ethyl, n-propyl, iso-propyi, n-butyl, isobutyl, sec-butyl, t-butyl, hexyl, octyl, and 2-ethyl-hexyl, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl. E is preferably -OR29, -SR29, -NR25R25, -COR28, -COOR27, -CONR25R25, or -CN, wherein R25, R27, R28 and R29 are independently of each other CrCi8 alkyl, such as methyl, ethyl, n-propyl, iso-propyi, n-butyl, isobutyl, sec-butyl, hexyl, octyl, 2-ethyl-hexyl, or C6-C24 aryl, such as phenyl, naphthyl, and biphenyl. Preferably, at least one of R1 and R2 is C6-C24aryl or C2-C2oheteroaryl, which optionally can be substituted. In this case, R1 and R2 are preferably selected from R6, R7 and X6 are independently of each other H, CrCi8 alkyl, such as as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, hexyl, octyl, 2-ethyl-hexyl, CrC18alkyl which is substituted by E and/or interrupted by D, such as -CH2OCH3, -CH2OCH2CH3, -CH2OCH2CH2OCH3, and -CH2OCH2CH2OCH2CH3, C6-C24 aryl, such as phenyl, naphthyl, and biphenyl, C6-C24 aryl which is substituted by E, such as -C6H4OCH3, -C6H40CH2CH3, -C6H3(OCH3)2, -C6H3(OCH2CH3)2, -C6H4CH3l -C6H3(CH3)2, -C6H2(CH3)3) and -C6H4tBu, R8 is H, Ci-C18 alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, and sec-butyl, or C6-C24 aryl, such as phenyl, naphthyl, and biphenyl, and R9 and R10 are independently of each other H, CrC18alkyl, such as n-butyl, sec-butyl, hexyl, octyl, or 2-ethyl-hexyl, Ci-Ci8alkyl which is substituted by E and/or interrupted by D, such as -CH2(OCH2CH2)wOCH3l w = 1, 2, 3, or 4, C6-C24aryl, such as phenyl, naphthyl, or biphenyl, C6-C24aryl which is substituted by E, such as -C6H4OCH3, -C6H4OCH2CH3) -C6H3(OCH3)2, -C6H3(OCH2CH3)2) -C6H4CH3, -C6H3(CH3)2l -C6H2(CH3)3) or -C6H4tBu, or R9 and R10 together form a 4 to 8 membered ring, especially a 5 or 6 membered ring, such as cyclohexyl, or cyclopentyl. Most preferred, R2 is H and R1 is C6-C24aryl or C2-C20heteroaryl in formula la and lb. The polymer of the present invention comprise the repeating unit of the formula I in an amount of from 0.5 mol% to 100 mol%, especially in an amount of from 40 mol% to 60 mol%, wherein the sum of airrepeating units (monomers) is 100 mol%. Accordingly, the polymers of the present invention can comprise besides the repeating unit of the formula I co-momers in an amount of up to 99.5 mol%, especially in an amount of from 60 mol% to 40 mol%. In a preferred embodiment of the present invention the polymers are homopolymers, which comprise a repeating unit of formula R16 is H; C6-C18aryl, C6-Ci8aryl which is substituted by d-Ctaalkyi, Ci-CiaalkyI, Cr-Casaralkyl, or CrCi8alkyl which is interrupted by -0-; p is an integer from 1 to 10, especially 1, 2 or 3, q is an integer from 1 to 10, especially 1,2 or 3, s is an integer from 1 to 10, especially 1,2 or 3, R6, R7, R8, R9 and R10are as defined above, or R9 and R10together form a group of formula =CR100R10\ wherein R100 and R101 are independently of each other H, d-C^alky!, CrC18alkyl which is substituted by E and/or interrupted by D( C6-C24aryl, C6-C24aryl which is substituted by E, C2- C2oheteroaryl, or C2-C2oheteroaryl which is substituted by E, and R14 and R15 are independently of each other H, Ci-Ci8alkylf d-Ci8alkyI which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, C2-C^heteroaryl, or C2-C2oheteroaryl which is substituted by E. If R9 and R10 together form a group of formula =CR100R10\ T is preferably a group of formula , wherein R102 and R103 are independently of each other d-Ci8alkyl, CrCisalkoxy, C6-Cioaryl, C6-Ctoaryloxy, or di(CrC18alkyI)amino, wherein the aryl or aryloxy groups optionally can be substituted by CrC8aIkyl (cf. US-B-6,512,083). R6 and R7 are independently of each other H, CrCi8 alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyi, n-pentyl, isopentyl, n-hexyl, 2- ethylhexyl, or n-heptyl, CrCi8alkyl which is substituted by E and/or interrupted by D, such as -CH2OCH3l -CH2OCH2CH3, -CH2OCH2CH2OCH3l or -CH2OCH2CH2OCH2CH3) C5-C^cycloalkyl, such as cyclohexyl, C6-C24aryl, such as phenyl, naphthyl, orbiphenyl, C6-C24aryl which is substituted by E, such as -C6H4OCH3l -C6H4OCH2CH3, -C6H3(OCH3)2, or -C6H3(OCH2CH3)2) -C6H4CH3l -C6H3(CH3)2, -C6H2(CH3)3l or -C6H4tBu, R8 is H, CrC18alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, n-heptyl, or C6-C24aryl, such as phenyl, naphthyl, or biphenyl, and R9 and R10 are independently H, Ci-C18aikyl, such as n-butyl, sec-butyl, hexyl, octyl, or 2-ethyl-hexyl, CrC18alkyl which is substituted by E and/or interrupted by D, such as -CH2(OCH2CH2)wOCH3) w = 1, 2, 3, or 4, C6-C24aryl, such as phenyl, naphthyl, or biphenyl, C6-C24aryl which is substituted by E, such as -C6H4OCH3, -C6H4OCH2CH3l -C6H3(OCH3)2, -C6H3(OCH2CH3)2, -C6H4CH3, -C6H3(CH3)2, -C6H2(CH3)3, or -C6H4tBu, or R9 and R10 together form a 4 to 8 membered ring, especially a 5 or 6 membered ring, such as cyclohexyl, or cyclopentyl, which may be substituted with Ci-CisalkyI, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, or n-heptyl, CrCi8alkyl which is substituted by E and/or interrupted by D, such as -CH2OCH3, -CH2OCH2CH3( -CH2OCH2CH2OCH3, or-CH2OCH2CH2OCH2CH3, C6-C24aryl, such as phenyl, naphthyl, or biphenyl, Ce-C^aryl which is substituted by E, such as "C6H4OCH3, -C6H4OCH2CH3l -C6H3(OCH3)2i or -C6H3(OCH2CH3)2, -C6H4CH3, -C6n3(CH3)2l -C6H2(CH3)3) or -C6H4tBu. In a preferred embodiment the polymers comprise repeating units of formula la or lb, wherein R1 is a group of formula R2 is H, R8 and R7 are independently of each other H, CrCi2alkyl, cyclohexyl, or Ci-C12alkoxy, R8 is CrC18alkyl, Ci-Ci8alkyl interrupted by one or two oxygen atoms, or C6-Ci2aryl, which optionally can be substituted by d-C^alkyl, or Ci-C^alkoxy, * R9 and R10 are independently of each other d-C18alkylf especially C4-C12alkyl, which can be interrupted by one or two oxygen atoms, and X1, X2, T, x and y are as defined above. In said embodiment a co-monomer T can optionally be present, which is preferably selected from the group consisting of R9 and R10 are independently of each other CrC18alkyl, especially 04-C^lkyl, which can be interrupted by one or two oxygen atoms, or R9 and R10 form a five or six membered carbocyclic ring, which optionally can be substituted by CrC8alkyl. In the first aspect of the present invention polymers are particularly preferred, which comprise a repeating unit of formula R56 and R57 are independently of each other H; CrC18alkyl; CrCi8aIkyl which is substituted by E and/or interrupted by D; C5-C12cycloa!kyl, C5-C12cycloalkyl, which is substituted by E, C6-C24aryl; C6-C24aryl which is substituted by E; C2-Coheteroaryl; CrQ&heteroaryt which is substituted by E; C2-Ci8alkenyl; C2-Ci8alkynyl; CrCi8aIkoxy; CrC18alkoxy which is substituted by E and/or interrupted by D; or C7-C25aralkyl; R58 is H; d-Ci8alkyl; CrC18alkyl which is substituted by E and/or interrupted by D; C6- C24aryl; or Cy-C^aralkyl; R59 is H; Ci-Ci8 alkyl; CrCi8alkyl which is substituted by E and/or interrupted by D; C6- C24aryi; C6-C24aryl which is substituted by E; C2-C2oheteroaryl; Cr-C^heteroaryl which is. substituted by E; C2-Ci8alkenyl; CrC18alkynyl; CrCi8alkoxy; d-Ci8alkoxy which is substituted by E and/or interrupted by D; or Cr-C^aralkyl; R71 is H, CrCi8alkyl, -CsN, -CONR25R26or -COOR27, D is -CO-; -COO-; -OCOO-; -S-; -SO-; -S02-; -0-; -NR25-; -SiR^R31-; -POR32-; -CR23=CR24-; or -OC-; and E is -OR29; -SR29; -NR25R26; -COR28; -COOR27; -CONR25R26; -CN; -OCOOR27; or halogen; wherein R23; R24; R25 and R26 are independently of each other H; C6-C18aryl; C6-Ci8aryl which is substituted by Ci-Ci8alkyl; d-C^alkoxy; Ci-Ci8aikyl; or CrCi8alkyI which is interrupted by- 0-;or R27 and R28 are independently of each other H; C6-Ci8aryl; C6-C18aryl which is substituted by CrCi8alkyl, or CrC18all R29 is H; C6-C18aryl; C6-C18aryl which is substituted by d-Ci8alkyl, d-Ciaalkoxy; CrCi8alkyl; or CrC18alkyl which is interrupted by -0-, R30 and R31 are independently of each other CrCi8alkyl, C6-C18aryl, or C6-Ci8aryl, which is substituted by Ci-C18alkyl, and R32 is CrCi8alkyl, C6-C18aryl, or C6-C18aryl, which is substituted by CrCi8alkyl. In the second aspect of the present invention polymers comprising a repeating unit of formula lib, especially a repeating unit of formula lla, or lie are preferred, wherein X3 is a group of the formula f wherein the dotted line represent the bond to the pyrimidine ring and R71 is H, alkyl, -C=N, or -COOR27, wherein R27 is H, or Ci-C18alkyl, which optionally can be interrupted by one or more oxygen atoms, especially C4-C12alkyl, which can be interrupted by one or two oxygen atoms. R3, R4 and R5 can in principal be any organic substituent, provided it does not have negative influence on the (electro)luminescent characteristics of the polymers, especially H, Cr Ci8alkyl, CrCi8alkyl which is substituted by E and/or interrupted by D, C2-Ci8alkenyi, C2-Ci8alkynyl, Ci-C18alkoxy, Ci-Ci8alkoxy which is substituted by E and/or interrupted by D, C7- C18alkoxy, d-Ci8aIkoxy which is substituted by E and/or interrupted by D, or Cr-Casaralkyl, X4 is CrC18alkyl, CrCi8alkyl which is substituted by E and/or interrupted by D, C6-C24 aryl or C2-C2oheteroaryl, which can optionally be substituted, X5is CrCi8alkyl, C6-C24aryl, or C2-C2oheteroaryl, which can optionally be substituted by -Od- C18alkyl or -OC6-C24aryl, R61, R62 and R63 are independently of each other H, CrC18 alkyl, CrCi8alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, C2- Ci8alkenyl, 02-Ctsalkynyl, Ci-C18alkoxy, CrCi8alkoxy which is substituted by E and/or interrupted by Df or C7-C25aralkylf R64 and R^are independently of each other H, d-dsalkyl, CrCi8a!kyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, C2-C2oheteroaryl, or C2-C20heteroaryl which is substituted by E, and D, E, R56, R57, R58, R59 and R60 are as defined above. Preferably, R56 and R57 are independently of each other H, CrCi8alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, Sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, and n-heptyl, CrCi8alkyl, which is substituted by E and/or interrupted by D, such as -CH2OCH3, -CH2OCH2CH3l -CH2OCH2CH2OCH3. and -CH2OCH2CH2OCH2CH3, C5-Ci2cycloalkyl, such as cyciohexyl, C6-C24aryl, such as phenyl, naphthyl, and biphenyl, or C6-C24aryl, which is substituted by E, such as -C6H4OCH3, -C6H4OCH2CH3, -C6H3(OCH3)2) -C6H3(OCH2CH3)2, -C6H4CH3, -C6H3(CH3)2, -C6H2(CH3)3, and -C6H4tBu. R58 is preferably H, CrC18alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, and n-heptyi, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl. Preferably, R59 and R60 are independently of each other H, Ci-C18alkyl, such as n-butyl, sec-butyl, hexyl, octyl, and 2-ethyl-hexyl, CrC18alkyl which is substituted by E and/or interrupted by D, such as -CH2(OCH2CH2)wOCH3, w=1, 2, 3, or 4, C6-C24aryl, such as phenyl, naphthyl, and biphenyl, C6-C24 aryl which is substituted by E, such as -C6H4OCH3, -C6H4OCH2CH3, -C6H3(OCH3)2, -C6H3(OCH2CH3)2, -C6H4CH3) -C6H3(CH3)2, -C6H2(CH3)3l and -C6H4tBu, or R59 and R60 together form a 4 to 8 membered ring, preferably a 5 or 6 membered ring, such as cyciohexyl, and cyclopentyl. Preferably, R64 and R65 are independently of each other H, Ci-Ci8alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, and sec-butyl, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl. X4 is preferably CrCi8alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, hexyl, octyl, and 2-ethyl-hexyl, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl. X5 is preferably CrCi8alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, hexyl, octyl, and 2-ethyl-hexyl, CVC24aryl, such as phenyl, naphthyl, and biphenyl, or C6-C24aryl substituted by OR29, wherein R29 is H, C1-C18 alkyl, such as methyl, and ethyl, or C6-C24 aryl, such as phenyl. D is preferably -CO-; -COO-; -OCOO-; -S-; -SO-; -S02-; -0-; -NR25-; and E is preferably -OR29; -SR29; -NR25R26; -COR28; -COOR27; -CONR25R26; or -CN; wherein R25; R27; R28 and R29 are independently of each other H; Ci-d8alkyl; such as methyl; ethyl; n-propyl; iso-propyl; n-butyl; isobutyl; sec-butyl; hexyi; octyl; and 2-ethyl-hexyl; C6-C24aryl; such as phenyl; naphthyl; and biphenyl. Preferably, at least one of R\ R2 and R3 is C6-C24aryl or CrC^heteroaryl, which optionally can be substituted. In this aspect, polymers comprising repeating units of formula lla, wherein R4 is H and R3 and R5are independently of each other Ce-C^aryl, or C2-C^heteroaryl, or lie, wherein R3 is H and R4 and R5are independently of each other C6-C24aryl or C2-C2oheteroaryl, are preferred against those polymers having repeating units of formula lib, wherein R3, R4, and R5are independently of each other C6-C24aryi or C2-C^heteroaryl, wherein the C6-C24aryl or CrC^heteroaryl can optionally be substituted. The polymers of the present invention comprise the repeating unit of the formula II in an amount of from 0.5 mol% to 100 mol%, especially in an amount of from 40 mol% to 60 mol%, wherein the sum of all repeating units (monomers) is 100 mol%. Accordingly, the polymers of the present invention can comprise besides the repeating unit of the formula II co-momers in an amount of up to 99.5 mol%, especially in an amount of from 60 mol% to 40 mol%. J wherein p is an integer from 1 to 10, especially 1, 2 or 3, q is an integer from 1 to 10, especially 1, 2 or 3, s is an integer from 1 to 10, especially 1, 2 or 3, R^is H; C6-Ci8aryl; C6-C18aryl, which is substituted by CrCi8alkyl, or Ci-C18alkoxy; Ci- Ci8alkyl; or CrCi8alkyl, which is interrupted by -0-; R56, R57, R58, R59, R60, R64 and R^are as defined above, or R59 and R60 together form a group of formula =CR100R101, wherein R100 and R101 are independently of each other H, CrC18aIkyI, Ci-C18alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, or C2- C2oheteroaryl, or C2-C2oheteroaryl which is substituted by E, wherein D and E are defined as above. Preferably, R56 and R57 are independently of each other H, CrC18alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyl, and n-heptyl, CrC18alkyl, which is substituted by E and/or interrupted by D, such as -CH2OCH3) -CH2OCH2CH3, -CH2OCH2CH2OCH3, and -CH2OCH2CH2OCH2CH3, C5-Ci2cycloalkyl, such as cyclohexyl, C6-C24aryi, such as phenyl, naphthyl, and biphenyl, or C6-C24aryl, which is substituted by E, such as -C6H4OCH3> -C6H4OCH2CH3, -C6H3(OCH3)2, -C6H3(OCH2CH3)2, -C6H4CH3, -C6H3(CH3)2l -C6H2(CH3)3, and -C6H4tBu. R58 is preferably H, Ci-d8alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, sec-butyl, t-butyl, 2-methylbutyl, n-pentyl, isopentyl, n-hexyl, 2-ethylhexyi, and n-heptyl, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl. If R59 and R60 together form a group of formula =CR100R10\ T is preferably a group of formula , wherein R102 and R103 are independently of each other d-Ci8alkyl, Ci-C18alkoxy, C6-C10aryl, C6-Ci0aryloxy, or di(CrC18alkyl)amino, wherein the aryl or aryloxy groups optionally can be substituted by CrC8aIkyl (cf. US-B-6,512,083). Preferably, R59 and R60 are independently of each other H, CrCi8alkyl, such as n-butyl, sec-butyl, hexyl, octyl, and 2-ethyl-hexyl, Ci-C18alkyl which is substituted by E and/or interrupted by D, such as -CH2(OCH2CH2)wOCH3l w=1, 2, 3, or 4, C6-C24aryl, such as phenyl, naphthyl, and biphenyl, C6-C24 aryl which is substituted by E, such as -C6H4OCH3, -C6H4OCH2CH3, -C6H3(OCH3)2l -C6H3(OCH2CH3)2, -C6H4CH3, -C6H3(CH3)2, -C6H2(CH3)3, and -C6H4tBu, or R59 and R60 together form a 4 to 8 membered ring, preferably a 5 or 6 membered ring, such as cyclohexyl, and cyclopentyl. Preferably, R64 and R65 are independently of each other H, CrCi8alkyl, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, and sec-butyl, or C6-C24aryl, such as phenyl, naphthyl, and biphenyl. A preferred embodiment is directed to polymers comprising a repeating unit of formula lib, especially a repeating unit of formula lla, or lie, and a co-monomer , wherein x is in the range of 0.005 to 1, especially 0.4 to 0.6, and y is in the range of 0.995 to 0, especially 0.6 to 0.4, wherein the sum of x and y is 1, wherein 7 X3 is a group of the formula , ~. , wherein the dotted line represent the bond to the pyrimidine ring, R3, R4 and R5 are independently of each other a group of the formula especially ' , ' , or'l ' ■ , wherein s is i, or 2, t-rR57 and X6 are independently of each other CrCi8 alkyl, CrCi8alkyl, which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl, which is substituted by E, R59 and R60 are independently of each other d-C18alkyl, Ci-Ci8alkyl, which is substituted by -OR29 and/or interrupted by -0-, R71isH, -CONR25R25or -CN, wherein D is -0-, or -NR25-, E is -OR29, -SR29, or -NR25R25, wherein R25 is H, Ci-C18 alkyl, or C6-C24 aryl, and R29 is CrCis alkyl, C6-C24 aryl. A particularly preferred embodiment is directed to polymers, comprising a repeating unit of formula lib, especially a repeating unit of formula Ha, or lie, and a co-monomer wherein x is in the range of 0.005 to 1, especially 0.4 to 0.6, and y is in the range of 0.995 to 0, especially 0.6 to 0.4, wherein the sum of x and y is 1, The term "polymers" comprises according to the present invention oligomers having a weight average molecular weight of The polymers of this invention preferably have a weight average molecular weight of 50,000 Daltons or greater, more preferably 100,000 Daltons or greater, and most preferably 150,000 Daltons or greater; preferably 1,000,000 Daltons or less, more preferably 500,000 Daltons or less and most preferably 250,000 Daltons or less. Molecular weights are determined according to gel permeation chromatography using polystyrene standards. A further embodiment of the present invention is represented by the monomers of the formula R\ R2, R3, R4 and R5 are independently of each other an organic substituent, especially C2- Caoaryl or a C2-C2eheteroaryl, which optionally can be substituted, X1, X2, and X3are independently of each other a divalent linking group, and X11 is independently in each occurrence a halogen atom, or -B(OH)2, -B(OY1)2 or wherein Y1 is independently in each occurrence a d-Cioalkyi group and Y2 is independently in each occurrence a C2-C10alkylene group, such as -CY3Y4-CY5Y6-, or -CY7Y8-CY9Y10-CY11Y12-, wherein Y3, Y4, Y5, Y6, Y7, Y8, Y9, Y10, Y11 and Y12are independently of each other hydrogen, or a CrC10atkyl group, especially -C(CH3)2C(CH3)2-, or -C(CH3)2CH2C(CH3)2-, which are starting materials in the preparation of the polymers of formula I and II, with the proviso that 2-phenyI-4,6-bis(p-bromophenyl)pyrimidine (A. L Vais et al., Izv. Sib. Otd. Akad. Nauk. SSSR, vol. 6.1975, 144-146) and 2,4,6-tris(p-bromophenyl)pyrimidine (M. Bajic etal., Molecules, vol, 6, no. 5, 2001, 477-480) are excluded. The pyrimidine starting compounds are known or can be prepared according to or analogous to known procedures. The present pyrimidine compounds are for instance derivatives of known hydroxyphenyl pyrimidine compounds: US-A-3,442,898, US-A-5,597,854 and US-A-5,753,729, the relevant parts of which are hereby incorporated by reference. The present pyrimidine compounds can for instance be prepared according to or analogous to the following procedure: are as defined above and X11 is a halogen atom. An amidine hydrochloride is added to a 2-propen-1-one derivative in a Crd-alcohol, like methanol, ethanol, propanol or butanol. A base, for example, an alkali metal hydroxide or alkoxide, such as sodium methoxide or potassium hydroxide is added and the solution is stirred in the presence of oxygen, for example dry air (see, for example European patent application no. 03405047.6; example 8). The boron-containing compounds of formula (IV) may be prepared by any suitable method. An example of reaction conditions for preparing boron-containing compounds is described in Remmers etal., Macromolecular Rapid Communications, Vol. 17, 239-253 (1996). Compounds of formulas (IV), which are disubstituted by chlorine or bromine, are converted to the corresponding dilithio derivative by reaction with two equivalents of butyllithium. Reaction of the dilithio derivative with a trialkylborate followed by hydrolysis yields the diboronic acid derivative. Esterification of the diboronic acid derivative with an alkylenediol, such as ethylene glycol, gives the di(cyclic)boronate derivative. Halogen is fluorine, chlorine, bromine and iodine. CrCi8alkyl is a branched or unbranched radical such as for example methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, 2-ethylbutyl, n-pentyl, isopentyl, 1-methylpentyl, 1,3-dimethylbutyl, n-hexyl, 1-methylhexyl, n-heptyt, isoheptyl, 1,1,3,3-tetramethylbutyl, 1-methylheptyl, 3-methylheptyl, n-octyl, 2-ethyihexyl, 1,1,3-trimethylhexyl, 1,1,3,3-tetramethylpentyl, nonyl, decyl, undecyl, 1-methylundecyl, dodecyl, 1,1,3,3,5,5-hexamethylhexyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, oroctadecyl. CrCi8alkoxy radicals are straight-chain or branched alkoxy radicals, e.g. methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, sec-butoxy, tert-butoxy, amyloxy, isoamyloxy or tert-amyloxy, heptyloxy, octyloxy, isooctyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, tetradecyloxy, pentadecyloxy, hexadecyloxy, heptadecyloxy and octadecyloxy. C2-Ci8alkenyl radicals are straight-chain or branched alkenyl radicals, such as e.g. vinyl, allyl, methallyl, isopropenyl, 2-butenyl, 3-butenyl, isobutenyl, n-penta-2,4-dienyl, 3-methyl-but-2-enyl, n-oct-2-enyl, n-dodec-2-enyl, isododecenyl, n-dodec-2-enyl or n-octadec-4-enyl. C2-24alkynyl is straight-chain or branched and preferably C2-8alkynyl, which may be unsubstituted or substituted, such as, for example, ethynyl, 1-propyn-3-yl, 1-butyn-4-yl, 1-pentyn-5-yl, 2-methyl-3-butyn-2~yl, 1,4-pentadiyn-3-yl, 1,3-pentadiyn-5-yl, 1-hexyn-6-yl, cis-3-methyl-2-penten-4-yn-1 -yl, trans-3-methyl-2-penten-4-yn-1 -yl, 1,3-hexadiyn-5-yl, 1-octyn-8-yl, 1-nonyn-9-yl, 1-decyn-10-yl, or 1-tetracosyn-24-yl. C4-Ci8cycloalkyl is preferably C5-Ci2cycloaikyl, such as, for example, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, cyclododecyl. Cyclohexyl and cyclopentyl are most preferred. C2-C18alkenyl is for example vinyl, allyl, butenyl, pentenyl, hexenyl, heptenyl, or octenyl. Aryl is usually C6-C3(>aryl, preferably C6-C24aryl, which optionally can be substituted, such as, for example, phenyl, 4-methylphenyl, 4-methoxyphenyl, naphthyl, biphenylyl, 2-fluorenyl, phenanthryl, anthryl, tetracyl, pentacyl, hexacyl, terphenylyl orquadphenylyl. C7-C24aralkyl radicals are preferably C7-Ci5aralkyl radicals, which may be substituted, such as, for example, benzyl, 2-benzyl-2-propyl, J3-phenethyI, a,ct-dimethylbenzyi, co-phenyl-butyl, co-phenyl-octyl, co-phenyl-dodecyl or S-methyl-S^I'.l'^'.S'-tetramethyl-butyl^benzyl. C2.C26heteroaryl is a ring with five to seven ring atoms or a condensed rig system, wherein nitrogen, oxygen or sulfur are the possible hetero atoms, and is typically an unsaturated heterocyclic radical with five to 30 atoms having at least six conjugated 7t-electrons such as thienyl, benzo[b]thienyl, dibenzo[b,d]thienyl, thianthrenyl, furyl, furfuryl, 2H-pyranyl, benzofuranyl, isobenzofuranyl, dibenzofuranyl, phenoxythienyl, pyrrolyl, imidazolyl, pyrazolyl, pyridyl, bipyridyl, triazinyl, pyrimidinyl, pyrazinyl, pyridazinyl, indolizinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolizinyl, chinolyl, isochinolyl, phthalazinyl, naphthyridinyl, chinoxalinyl, chinazolinyl, cinnolinyl, pteridinyl, carbazolyl, carbolinyl, benzotriazolyl, benzoxazolyl, phenanthridinyl, acridinyl, perimidinyl, phenanthrolinyl, phenazinyl, isothiazoiyl, phenothiazinyl, isoxazolyl, furazanyl or phenoxazinyl, which can be unsubstituted or substituted. Examples of a five or six membered ring formed by R6 and R7 and R56 and R57, respectively are heterocycloalkanes or heterocycloalkenes having from 3 to 5 carbon atoms which can have one additional hetero atom selected from nitrogen, oxygen and sulfur, for example Possible substituents of the above-mentioned groups are CvC8alkyl, a hydroxy! group, a mercapto group, Ci-C8aIkoxy, CrC8alkylthio, halogen, halo-CrC8alkyi, a cyano group, an aldehyde group, a ketone group, a carboxyl group, an ester group, a carbamoyl group, an amino group, a nitro group or a silyl group. The term "haloalkyl" means groups given by partially or wholly substituting the above-mentioned alkyl group with halogen, such as trifluoromethyl etc. The "aldehyde group, ketone group, ester group, carbamoyl group and amino group" include those substituted by an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group or a heterocyclic group, wherein the alkyl group, the cycloalkyl group, the aryl group, the aralkyl group and the heterocyclic group may be unsubstituted or substituted. The term "silyl group" means a group of formula -SiR105R106R107, wherein R105, R106 and R107 are independently of each other a Cr C8alkyl group, in particular a C1-C4 alkyl group, a C6-C24aryl group or a C7-Ci2aralkylgroup, such as a trimethylsilyl group. If a substituent, such as, for example R6f R7, R56 and R57, occurs more than one time in a formula, it can be different in each occurrence. hours. Organic bases, such as, for example, tetraalkylammonium hydroxide, and phase transfer catalysts, such as, for exampleTBAB, can promote the activity of the boron (see, for example, Leadbeater & Marco; Angew. Chem. Int. Ed., 2003, 42, 1407 and references cited therein). Other variations of reaction conditions are given by T. I. Wallow and B. M. Novak in Journal of Organic Chemistry, Vol. 59, pp. 5034-5037 (1994); and M. Remmers, M. Schulze, and G. Wegner in Macromolecular Rapid Communications, Vol. 17, pp. 239-252 (1996). Polymerization processes involving only dihalo-functional reactants may be carried out using nickel coupling reactions. One such coupling reaction was described by Colon et al. in Journal of Polymer Science, Part A, Polymer Chemistry Edition, Vol. 28, p. 367 (1990), and by Colon et al. in Journal of Organic Chemistry, Vol. 51, p. 2627 (1986). The reaction is typically conducted in a polar aprotic solvent (e.g., dimethylacetamide) with a catalytic amount of nickel salt, a substantial amount of triphenylphosphine and a large excess of zinc dust. A variant of this process is described by loyda et al. in Bulletin of the Chemical Society of Japan, Vol. 63, p. 80 (1990) wherein an organo-soluble iodide was used as an accelerator. Another nickel-coupling reaction was disclosed by Yamamoto in Progress in Polymer Science, Vol. 17, p. 1153 (1992) wherein a mixture of dihaloaromatic compounds were treated with an excess amount of nickel (1,5-cyclooctadiene) complex in an inert solvent. All nickel-coupling reactions when applied to reactant mixtures of two or more aromatic dihalides yield essentially random copolymers. Such polymerization reactions may be terminated by the addition of small amounts of water to the polymerization reaction mixture, which will replace the terminal halogen groups with hydrogen groups. Alternatively, a monofunctional aryl halide may be used as a chain-terminator in such reactions, which will result in the formation of a terminal aryl group. In one embodiment, the polymers of the invention contain conjugated groups other than the pyrimidine groups described above. "Conjugated groups" refer to moieties containing double bonds, triple bonds and/or aromatic rings. Examples of such groups are the above mentioned co-monomers T. The incorporation of such groups into the polymer may be used to modify the light absorption, ionization potential, and/or electronic properties of the polymer. Such polymers may be prepared using the methods described above incorporating at least one conjugated compound different from the pyrimidine compounds described above. Such conjugated compounds, hereinafter referred to as "comonomers", have functional groups which permit them to copolymerize with the pyrimidine compounds. For example, dihalo-functional comonomers are preferably used in conjunction with dihalo-functional pyrimidine compounds in nickel-coupling polymerization reactions; dihalo-functional comonomers are preferably used in conjunction with pyrimidine-diboronic acids or pyrimidine-diboronates; and conjugated comonomers bearing diboronic acid or diboronate functionalities are preferably used in conjunction with dihalopyrimidines. For the purpose of preparing polymers of the invention, more than one diboronic acid/diboronate and more than one dibromide may be used in a Suzuki polymerization reaction so long as the total molar amount of diboronic acids/diboronates is essentially equivalent to the total amount of dibromides. Nickel-coupling polymerizations yield essentially random copolymers comprising pyrimidine group-containing units and units derived from other co-monomers, while Suzuki polymerizations yield alternating copolymers. It is possible to control the sequencing of the monomeric units in the resulting copolymer by controlling the order and composition of monomer feeds in the Suzuki reaction. For instance, a high molecular weight copolymer comprising mainly large blocks of pyrimidine homopolymers connected to short blocks of alternating pyrimidine co-monomer oligomers may be made by first introducing into the reaction reactants in the appropriate ratio to make the alternating pyrimidine-comonomer oligomers followed by the remainder of pyrimidine monomers so long as there is an overall balance of boronic and bromo groups. Usually the polymers of the present invention comprise end moieties E\ wherein E1 is hydrogen or an aryl moiety which may optionally be substituted with a reactive group capable of undergoing chain extension or crosslinking, or a tri(CrC18)alkylsiloxy group. As used herein, a reactive group capable of undergoing chain extension or crosslinking refers to any group which is capable of reacting with another of the same group or another group so as to form a link to prepare oligomers or polymers. Preferably, such reactive group is a hydroxy, glycidyl ether, acrylate ester, methacrylate ester, ethenyl, ethynyl, maleimide, nadimide, trifluorovinyl ether moiety or a cyclobutene moiety fused to the aromatic ring of E1. The polymers of the present invention, where E1 are reactive groups as defined above, are capable of crosslinking to form solvent resistant, heat-resistant films at 100°C or more, more preferably at 150°C or more. Preferably, such crosslinking occurs at 350°C or less, more preferably 300°C or less and most preferably 250°C or less. The crosslinkable polymers of the invention are stable at 100°C or more and more preferably 150°C or more. "Stable" as used herein means that such polymers do not undergo crosslinking or polymerization reactions at or below the stated temperatures. If a crosslinkable material is desired, E1 is preferably a vinylphenyl, an ethynylphenyl, or 4-(or 3-)benzocyciobutenyi radical. In another embodiment, E is selected from a group of phenolic derivatives of the formula -C6H4-0-Y, wherein Y is The end-capping agent E1-X (E1 is as defined above and X is either CI or Br) is incorporated into the polymers of the present invention under the condition in which the resulting polymers are substantially capped by the reactive group E1. The reactions useful for this purpose are the nickel-coupling and Suzuki reactions described above. The average degree of polymerization is controlled by the mole ratio of monomers to end-capping agent. Depending on the process of preparation the polymers of the present invention can be homopolymers, block copolymers, random copolymers, or alternating copolymers. Another aspect of this invention is related to polymer blends containing t to 99 percent of at least one pyrimidine containing polymers of this invention. The remainder 1 percent to 99 percent of the blend is composed of one or more polymeric materials selected from among chain growth polymers such as polystyrene, polybutadiene, poly(methyi methacrylate)h and poly(ethylene oxide); step-growth polymers such as phenoxy resins, polycarbonates, polyamides, polyesters, polyurethanes, and polyimides; and crosslinked polymers such as crosslinked epoxy resins, crosslinked phenolic resins, crosslinked acrylate resins, and crossiinked urethane resins. Examples of these polymers may be found in Preparative Methods of Polymer Chemistry, W. R. Sorenson and T. W. Campbell, Second Edition, Interscience Publishers (1968). Also may be used in the blends are conjugated polymers such as poly(phenylene vinylene), substituted poly(phenylene vinylene)s, substituted polyphenylenes and polythiophenes. Examples of these conjugated polymers are given by Greenham and Friend in Solid State Physics, Vol. 49, pp. 1-149 (1995). Another aspect of the invention is the films formed from the polymers of the invention. Such films can be used in polymeric light-emitting diodes. Preferably, such films are used as emitting layers. These polymers may also be used as protective coatings for electronic devices and as fluorescent coatings. The thickness of the coating or film is dependent upon the ultimate use. Generally, such thickness can be from 0.01 to 200 microns. In that embodiment wherein the coating is used as a fluorescent coating, the coating or film thickness is from 50 to 200 microns. In that embodiment where the coatings are used as electronic protective layers, the thickness of the coating can be from 5 to 20 microns. In that embodiment where the coatings are used in a polymeric light-emitting diode, the thickness of the layer formed is 0.05 to 2 microns. The polymers of the invention form good pinhole- and defect-free films. Such films can be prepared by means well known in the art including spin-coating, spray-coating, dip-coating and roller-coating. Such coatings are prepared by a process comprising applying a composition to a substrate and exposing the applied composition to conditions such that a film is formed. The conditions which form a film depend upon the application technique and the reactive end groups of the aryl moiety. In a preferred embodiment, the composition applied to the substrate comprises the pyrimidine polymers dissolved in a common organic solvent. Preferably, the solution contains from 0.1 to 10 weight percent of the polymers. This composition is applied to the appropriate substrate by the desired method and the solvent is allowed to evaporate. Residual solvent may be removed by vacuum and/or by heat. After removal of the solvent, the coating is then exposed to the necessary conditions to cure the film, if needed, to prepare a film having high solvent and heat resistance. The films are preferably substantially uniform in thickness and substantially free of pinholes. In another embodiment, the polymers may be partially cured. This is known as B-staging. A further embodiment of the present invention is directed to an optical device or a component therefore, comprising a substrate and a polymer according to the present invention. A device according to the present invention may be prepared in accordance with the disclosure of WO99/48160, the contents of which are incorporated by reference. Polymers according to the present invention may be present in the device as the sole light emitting polymer or as a component in a blend further comprising hole and/or electron transporting polymers. Alternatively, the device may comprise distinct layers of a polymer of the present invention, a hole transporting polymer and/or an electron transporting polymer. In one embodiment the optical device comprises an electroluminescent device, which comprises (a) a charge injecting layer for injecting positive charge carriers, (b) a charge injecting layer for injecting negative charge carriers, (c) a light-emissive layer located between the layers (a) and (b) comprising a polymer according to the present invention. The layer (a) may be a positive charge carrier transport layer which is located between the light emissive layer (c) and an anode electrode layer, or may be an anode electrode layer. The layer (b) may be a negative charge carrier transport layer which is located between the light emissive layer (c) and an cathode electrode layer, or may be an cathode electrode layer. Optionally, an organic charge transport layer can be located between the light emissive layer (c) and one of the charge carrier injecting layers (a) and (b). The EL device emits light below 520 nm, especially between 380 nm and 520 nm. The EL device has a NTSC coordinate of between about (0.12, 0.05) and about (0.16, 0.10), especially a NTSC coordinate of about (0.14,0.08). It will be appreciated that the light emissive layer may be formed from a blend or mixture of materials including one or more polymers according to the present invention, and optionally further different polymers. The further different polymers may be so-called hole transport polymers (i.e. to improve the efficiency of hole transport to the light-emissive material) or electron-transport polymers (i.e. to improve the efficiency of electron transport to the light-emissive material). Preferably, the blend or mixture would comprise at least 0.1 % by weight of a polymer according to the present invention, preferably from 0.2 to 50%, more preferably from 0.5 to 30% by weight. An organic EL device typically consists of an organic film sandwiched between an anode and a cathode such that when a positive bias is applied to the device, holes are injected into the organic film from the anode, and electrons are injected into the organic film from the cathode. The combination of a hole and an electron may give rise to an exciton, which may undergo radiative decay to the ground state by liberating a photon. In practice the anode is commonly an mixed oxide of tin and indium for its conductivity and transparency. The mixed oxide (ITO) is deposited on a transparent substrate such as glass or plastic so that the light emitted by the organic film may be observed. The organic film may be the composite of several individual layers each designed for a distinct function. Since holes are injected from the anode, the layer next to the anode needs to have the functionality of transporting holes. Similarly, the layer next to the cathode needs to have the functionality of transporting electrons. In many instances, the hole-(electron) transporting layer also acts as the emitting layer. In some instances one layer can perform the combined functions of hole and electron transport and light emission. The individual layers of the organic film may be all polymeric in nature or combinations of films of polymers and films of small molecules deposited by thermal evaporation. It is preferred that the total thickness of the organic film be less than 1000 nanometers (nm). It is more preferred that the total thickness be less than 500 nm. It is most preferred that the total thickness be less than 300 nm. It is preferred that the thickness of the active (light emitting) layer be less than 400 nanometers (nm). It is more preferred that the thickness is in the range of from 40 to 160 nm. The ITO-glass which serves as the substrate and the anode may be used for coating after the usual cleaning with detergent, organic solvents and UV-ozone treatment. It may also be first coated with a thin layer of a conducting substance to facilitate hole injection. Such substances include copper phthalocyanine, polyaniline and poly(3,4-ethylenedioxy-thiophene) (PEDT); the last two in their conductive forms by doping with a strong organic acid, e.g., poly(styrenesulfonic acid). It is preferred that the thickness of this layer be 200 nm or less; it is more preferred that the thickness be 100 nm or less. In the cases where a hole-transporting layer is used, the polymeric arylamines described in U.S. Pat. No. 5,728,801, may be used. Other known hole-conducting polymers, such as polyvinylcarbazole, may also be used. The resistance of this layer to erosion by the solution of the copolymer film which is to be applied next is obviously critical to the successful fabrication of multi-layer devices. The thickness of this layer may be 500 nm or less, preferably 300 nm or less, most preferably 150 nm or less. In the case where an electron-transporting layer is used, it may be applied either by thermal evaporation of low molecular weight materials or by solution coating of a polymer with a solvent that would not cause significant damage to the underlying film. Examples of low molecular weight materials include the metal complexes of 8-hydroxyquinoline (as described by Burrows et al. in Applied Physics Letters, Vol. 64, pp. 2718-2720 (1994)), metallic complexes of 10-hydroxybenzo(h)quinoline (as described by Hamada et al. in Chemistry Letters, pp. 906-906 (1993)), 1,3,4-oxadiazoles (as described by Hamada et al. in Optoelectronics-Devices and Technologies, Vol. 7, pp. 83-93 (1992)), 1,3,4-triazoles (as described by Kido et al. in Chemistry Letters, pp. 47-48 (1996)), and dicarboximides of perylene (as described by Yoshida et al. in Applied Physics Letters, Vol. 69, pp. 734-736(1996)). Polymeric electron-transporting materials are exemplified by 1,3,4-oxadiazole-containing polymers (as described by Li et al. in Journal of Chemical Society, pp. 2211-2212 (1995), by Yang and Pei in Journal of Applied Physics, Vol 77, pp. 4807-4809 (1995)), 1,3,4-triazole-containing polymers (as described by Strukelj et al. in Science, Vol. 267, pp. 1969-1972 (1995)), quinoxaline-containing polymers (as described by Yamamoto et al. in Japan Journal of Applied Physics, Vol. 33, pp. L250-L253 (1994), O'Brien et al. in Synthetic Metals, Vol. 76, pp. 105-108 (1996)), and cyano-PPV (as described by Weaver et al. in Thin Solid Films, Vol. 273, pp. 39-47 (1996)). The thickness of this layer may be 500 nm or less, preferably 300 nm or less, most preferably 150 nm or less. The metallic cathode may be deposited either by thermal evaporation or by sputtering. The thickness of the cathode may be from 100 nm to 10,000 nm. The preferred metals are calcium, magnesium, indium, and aluminum. Alloys of these metals may also be used. Alloys of aluminum containing 1 to 5 percent of lithium and alloys of magnesium containing at least 80 percent of magnesium are preferred. In a preferred embodiment, the electroluminescent device comprises at least one hole-transporting polymer film and a light-emitting polymer film comprised of the polymer of the invention, arranged between an anode material and a cathode material such that under an applied voltage, holes are injected from the anode material into the hole-transporting polymer film and electrons are injected from the cathode material into the light-emitting polymer films when the device is forward biased, resulting in light emission from the light-emitting layer. In another preferred embodiment, layers of hole-transporting polymers are arranged so that the layer closest to the anode has the lower oxidation potential, with the adjacent layers having progressively higher oxidation potentials. By these methods, electroluminescent devices having relatively high light output per unit voltage may be prepared. The term "hole-transporting polymer film" as used herein refers to a layer of a film of a polymer which when disposed between two electrodes to which a field is applied and holes are injected from the anode, permits adequate transport of holes into the emitting polymer. Hole-transporting polymers typically are comprised of triarylamine moieties. The term "light-emitting polymer film" as used herein refers to a layer of a film of a polymer whose excited states can relax to the ground state by emitting photons, preferably corresponding to wavelengths in the visible range. The term "anode material" as used herein refers to a semi-transparent, or transparent, conducting film with a work function between 4.5 electron volts (eV) and 5.5 eV. Examples are gold, silver, copper, aluminum, indium, iron, zinc, tin, chromium, titanium, vanadium, cobalt, nickel, lead, manganese, tungsten and the like, metallic alloys such as magnesium/copper, magnesium/silver, magnesium/aluminum, aluminum/indium and the like, semiconductors such as Si, Ge, GaAs and the like, metallic oxides such as indium-tin-oxide ("ITO"), ZnO and the like, metallic compounds such as Cul and the like, and furthermore, electroconducting polymers such polyacetylene, polyaniline, polythiophene, polypyrrole, polyparaphenylene and the like. Oxides and mixed oxides of indium and tin, and gold are preferred. Most preferred is ITO, especially ITO on glass as substrate. The term "cathode material" as used herein refers to a conducting film with a work function between 2.5 eV and 4.5 eV, Examples are alkali metals, earth alkaline metals, group 13 elements, silver, and copper as well as alloys or mixtures thereof such as sodium, lithium, potassium, calcium, lithium fluoride (LiF), sodium-potassium alloy, magnesium, magnesium-silver alloy, magnesium-copper alloy, magnesium-aluminum alloy, magnesium-indium alloy, aluminum, aluminum-aluminum oxide alloy, aluminum-lithium alloy, indium, calcium, and materials exemplified in EP-A 499,011, such as electroconducting polymers e.g. polypyrrole, polythiophene, polyaniline, polyacetylene etc. Preferably lithium, calcium, magnesium, indium, silver, aluminum, or blends and alloys of the above are used. In the case of using a metal or a metallic alloy as a material for an electrode, the electrode can be formed also by the vacuum deposition method. In the case of using a metal or a metallic alloy as a material forming an electrode, the electrode can be formed, furthermore, by the chemical plating method (see for example, Handbook of Electrochemistry, pp 383-387, Mazuren, 1985). In the case of using an electroconducting polymer, an electrode can be made by forming it into a film by means of anodic oxidation polymerization method onto a substrate, which is previously provided with an electroconducting coating. As methods for forming said thin films, there are, for example, the vacuum deposition method, the spin-coating method, the casting method, the Langmuir-Blodgett ("LB") method, the ink jet printing method and the like. Among these methods, the vacuum deposition method, the spin-coating method, the ink jet printing method and the casting method are particularly preferred in view of ease of operation and cost. in the case of forming the layers by using the spin-coating method, the casting method and ink jet printing method, the coating can be carried out using a solution prepared by dissolving the composition in a concentration of from 0.0001 to 90% by weight in an appropriate organic solvent such as benzene, toluene, xylene, tetrahydrofurane, methyltetrahydrofurane, N,N-dimethylformamide, dichloromethane, dimethylsulfoxide and the like. The organic EL device of the present invention has significant industrial values since it can be adapted for a flat panel display of an on-wall television set, a flat light-emitting device, a light source for a copying machine or a printer, a light source for a liquid crystal display or counter, a display signboard and a signal light. The polymers and compositions of the present invention can be used in the fields of an organic EL device, a photovoltaic device, an electrophotographic photoreceptor, a photoelectric converter, a solar cell, an image sensor, and the like. The following examples are included for illustrative purposes only and do not limit the scope of the claims. Unless otherwise stated, all parts and percentages are by weight. Example 1 Bis(1,5-cyclooctadiene)nickeI(0) (2.0 g, 7.27 mmol) and 2,2'-bipyridyl (1.14 g, 7.27 mmol) are dissolved in anhydrous toluene (7.0 ml) and stirred at 80°C for 1 hour under an argon atmosphere in the dark. Monomer 1 (0.85 g, 1.82 mmol) and 2,7-dibromo-9,9-dihexylfluorene (0.89 g, 1.82 mmol) are dissolved in anhydrous toluene (7.0 ml) and purged thoroughly with argon, then added to the solution of Ni complex and stirred at 80°C for 17 hours under argon in the dark. Anhydrous toluene (7.0 ml) is added and the reaction allowed to progress a further 5 hours. Bromobenzene (1 ml, 9.5 mmol) is added and the reaction stirred for a further 2 hours. The reaction mixture is poured into stirred methanol/c.HCI(aq) (10:1, 600 ml) and the resulting precipitate is stirred for 30 minutes and collected by filtration. The precipitate was redissolved in toluene (80 ml) and the precipitation repeated in acidic methanol. The precipitate is redissolved in chloroform (80 ml) and passed through a plug of silica, then washed through with chloroform (5 x 100mL). The combined chloroform phases are concentrated to ca. 80 ml and precipitated in stirred methanol (600 ml) and stirred for 30 minutes. The polymer is collected by filtration and dried. 0.674 g; 58% recovery of material; Mw = 650,000, PD = 2.21. The polymerisation of Example 1 may be used to produce either high Mw homopolymers or high Mw statistical co-polymers from the following monomer families: 1) Homopolymer; no momomer 2. Example 2 Monomer 1 (1.0 g( 2.15 mmol) and monomer 3 (1.38 g, 2.15 mmol) are suspended in toluene (15 ml) and purged by bubbling argon through for 10 minutes. Palladium catalyst (1 mol%) is added and the toluene phase purged for a further 10 minutes. Tetraethylammonium hydroxide (20% aq. solution; 8 ml) is added and the whole heated to reflux for 20 hours. Bromobenzene (0.2 ml) is added and the reaction allowed to proceed for a further hour, then phenylboronic acid added and the reaction stirred for another hour. On cooling the reaction mixture is diluted with toluene (20 ml) and poured into acidic methanol (10 ml 32% HCI(aq) in 500 ml MeOH) and filtered. The pale solid is redissolved in CHCI3 (100 ml) and filtered through a plug of silica (3cm), then washed through with CHCI3 (500 mi). The CHCI3 is removed and the residue redissolved in toluene (100 ml) and stirred vigorously with an aqueous solution of disodium EDTA (5%, 200 ml) for 1 hour. The toluene phase is separated, concentrated to ca. 50 ml and precipitated in MeOH (400 ml), filtered and dried. 875mg, 79% recovery. The polymerisation of Example 2 may be used to produce alternating copolymers of the following monomer families: Monomer 1 Monomer 3 Bis(1,5-cyclooctadiene)nickel(0) (2.0 g, 7.27 mmol) and 2,2'-bipyridyl (1.14 g, 7.27 mmol) are dissolved in anhydrous toluene (7.0 ml) and stirred at 80°C for 1 hour under an argon atmosphere in the dark. Monomer 3 (2.38 g, 3.3 mmol) is dissolved in anhydrous toluene (7.0 ml) and purged thoroughly with argon, then added to the solution of Ni complex and stirred at 80°C for 17 hours, under argon in the dark. Anhydrous toluene (7.0 ml) is added and the reaction allowed to progress a further 5 hours. Bromobenzene (1 ml, 9.5 mmol) is added and the reaction stirred for a further 2 hours. The reaction mixture is poured into stirred methanol/c.HCI(aq) (10:1, 600 ml) and the resulting precipitate is stirred for 30 minutes and collected by filtration. The precipitate is redissolved in toluene (80 ml) and the precipitation in acidic methanol repeated. The precipitate is redissolved in chloroform (80 ml) and passed through a plug of silica, then washed through with chloroform (5 x 100 ml). The combined chloroform phases were concentrated to ca. 80 ml and precipitated in stirred methanol (600 ml) and stirred for 30 minutes. The polymer is collected by filtration and dried. Example 4 Monomer 4 Monomer 4 (5.0 g, 14.95 mmol), AIBN (48 mg, 0.293 mmol) and chlorobenzene (12 g) are purged with argon, then heated to 150°C under an argon atmosphere for 2 hours. The hot solution was poured into stirred methanol (300 ml) and the resultant white precipitate filtered. The precipitate is redissolved in toluene (60 ml) and slowly dropped into an acidic methanol solution (2 ml c.HCI(aq) in 400 ml MeOH). The polymer is filtered, washed with methanol and dried at 40°C in vacuo overnight. Mass = 3.5 g, 70% recovery of materials; Mw = 20,000 (GPC, PS standards). Example 5 Br' Monomer 5 Bis(1l5-cyclooctadiene)nickei(0) (2.0 g, 7.27 mmol) and 2,2'-bipyridyl (1.14 g, 7.27 mmoi) are dissolved in anhydrous toluene (7.0 ml) and stirred at 80°C for 1 hour under an argon atmosphere in the dark. Monomer 5 (2.38 g, 3.3 mmol) is dissolved in anhydrous toluene (7.0mL) and purged thoroughly with argon, then added to the solution of Ni complex and stirred at 80°C for 17 hours, under argon in the dark. Anhydrous toluene (7.0 ml) is added and the reaction allowed to progress a further 5 hours. Bromobenzene (1 mi, 9.5 mmol) is added and the reaction stirred for a further 2 hours. The reaction mixture is poured into stirred methanol/c.HCI(aq) (10:1, 600 mi) and the resulting precipitate is stirred for 30 minutes and collected by filtration. The precipitate is redissolved in toluene (80 ml) and the precipitation in acidic methanol repeated. The precipitate is redissolved in chloroform (80 ml) and passed through a plug of silica, then washed through with chloroform (5 x 100 ml). The combined chloroform phases were concentrated to ca. 80 ml and precipitated in stirred methanol (600 ml) and stirred for 30 minutes. The polymer is collected by filtration and dried. monomer 7 Monomer 6 (2.0 g, 3.65 mmol) and monomer 7 (1.38 g, 3.65 mmol) are suspended in toluene (15 ml) and purged by bubbling argon through for 10 minutes. Palladium catalyst (1 mol%) is added and the toluene phase purged for a further 10 minutes. Tetraethylammonium hydroxide (20% aq. solution; 14 ml) is added and the whole heated to reflux for 20 hours. Bromobenzene (0.2 ml) is added and the reaction allowed to proceed for a further hour, then phenylboronic acid is added and the reaction stirred for another hour. On cooling the reaction mixture is diluted with toluene (20 ml) and poured into acidic methanol (10 ml 32% HCI(aq) in 500 ml MeOH) and filtered. The pale solid is redissolved in toluene (100 ml) and stirred vigorously with an aqueous solution of disodium EOTA (5%, 200 ml) for 1 hour. The toluene phase is separated, concentrated to ca. 50 ml and precipitated in MeOH (400 ml), filtered and dried. Monomer 6 (2.0 g, 3.65 mmol) and monomer 7 (1.98 g, 3.65 mmol) are suspended in toluene (15 ml) and purged by bubbling argon through for 10 minutes. Palladium catalyst (1 mol%) is added and the toluene phase purged for a further 10 minutes. Tetraethylammonium hydroxide (20% aq. solution; 14 ml) is added and the whole heated to reflux for 20 hours. Bromobenzene (0.2 ml) is added and the reaction allowed to proceed for a further hour, then phenylboronic acid is added and the reaction stirred for another hour. On cooling the reaction mixture was diluted with toluene (20 ml) and poured into acidic methanol (10 ml 32% HCI(aq) in 500 ml MeOH) and filtered. The pale solid is redissolved in toluene (100 ml) and stirred vigorously with an aqueous solution of disodium EDTA (5%, 200mL) for 1 hour. The toluene phase is separated, concentrated to ca. 50 ml and precipitated in MeOH (400 ml), filtered and dried. Application Example 1 The ITO-glass used for device fabrication has a nominal sheet resistance of 12 ohm/square. The hole injection conducting polymer when used is poly(3,4-ethylenedioxy-thiophene) (PEDT), the hole-transporting polymer when used is poly(4,4,-biphenylene-diyl-N'Nl-diphenyldiamino-1,4-phenylene) described in US-B-5.728,801, hereinafter abbreviated as "P3DA", and the electron-transporting layer when used is the aluminum complex of 8-hydroxy-quinoline hereinafter abbreviated as •Alq". Films of PEDT are formed by spin coating from aqueous solutions of the polymer obtained from Bayer Corporation. Films of P3DA are formed by spin coating from chlorobenzene solutions. Alq films are formed by thermal evaporation in high vacuum. Multi-layer devices are fabricated by laying, down the layers sequentially starting from the layer next to the ITO. After all the layers have been deposited, the appropriate metallic cathodes are then deposited on top of the organic film by thermal evaporation. Magnesium alloys in this instance are alloys of magnesium containing at least 85 percent of magnesium. The active polymer is deposited by spin-coating from organic solution (toluene). Claims A polymer comprising a repeating unit of the formula R\ R2, R3, R4 and R5 are independently of each other an organic substituent, especially C2-C30aryl or a Ca-C^heteroaryl, which optionally can be substituted, X1, X2 and X3are independently of each other a divalent linking group. 1. A polymer according to claim 1, wherein X1 and X2 are independently of each other a group of the formula = , in particular n1, n2, n3, n4, n5, n6 and n7 are integers of 1 to 10, in particular 1 to 3, R6 and R7 are independently of each other H, d-Ci8aIkyl, CrC18aIkyl which is substituted by E and/or interrupted by D, d-C^cycloalkyl, C5-C12cycioalkyl, which is substituted by E, C6-C24aryl, C6-C24aryl which is substituted by E, C2-C20heteroaryl, C2-C2oheteroaryl which is substituted by E, C2-d8alkenyI, C2-Ci8alkynyl, d-C18alkoxy, d-C18alkoxy which is substituted by E and/or interrupted by D, C7-C25aralkyl, or -CO-R28, R8 is d-d8alkyl, CrCi8alkyl which is substituted by E and/or interrupted by D, C6-C24 aryl, or C7-C25aralkyi, R9 and R10 are independently of each other d-C18alkyl, d-dsalkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, C2-C20heteroaryl, C2-C20heteroaryl which is substituted by E, C2-Ci8alkenyl, C2-d8alkynyl, d-C18alkoxy, d-Ci8alkoxy which is substituted by E and/or interrupted by D, or C7-C25aralkyi, or R9 and R10form a ring, especially a five- or six-membered ring, which may optionally be substituted by R6, R14' and R15' are independently of each other Hf d-Ci8alkyl, d-C18alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, d-C^heteroaryl, or CrC^heteroaryl which is substituted by E, D is -CO-, -COO-, -S-, -SO-, -S02-f -0-, -NR25-, -SiR30R31-, -POR32-, -CR23=CR24-, or - OC-, and E is -OR29, -SR29, -NR^R26, -COR28, -COOR27, -CONR^R26, -CN, -OCOOR27, or halogen, wherein R23, R24, R25 and R26 are independently of each other H, C6-C18aryl, C6-Ci8aryl which is substituted by d-d8alkyl, Ci-daalkoxy, d-C18alkyl, or d-C18alkyl which is interrupted by -0-, or R25 and R26 together form a five or six membered ring, in particular R27 and R28 are independently of each other H, C6-Ci8aryl, C6-d8aryl which is substituted by d-dsalkyl, or d-dsalkoxy, d-C18alkyl, or Ci-C18alkyl which is interrupted by -O-, R29 is H, C6-C18aryi, drdsaryl, which is substituted by d-daalkyl. d-d8alkoxy, d- Ci8alkyl, or CrCi8alkyl which is interrupted by -0-, R30 and R31 are independently of each other CrC18alkyI, C6-Ci8aryl, or C6-d8aryl, which is substituted by d-daalkyi, and R32 is CrCi8aIkyl, C6-C18aryl, or Ce-Cisaryl, which is substituted by CrC18alkyl. A polymer according claim 1 or 2, wherein R1 and R2 are independently of each other H, Ci-C18alkyl, C-rCi8aIkyI which is substituted by E and/or interrupted by D, C2-Ci8alkenyl, C2-Ci8alkynyl, d-daalkoxy, d-C18aIkoxy which is substituted by E and/or Ci8alkoxy, d-C^alkoxy which is substituted by E and/or interrupted by D, or C7- C25aralkyl, X4 is Ci-Ci8alkyl, CrCi8alkyl which is substituted by E and/or interrupted by D, C6- C24aryl, which optionally can be substituted, X5is CrC18alkyl, C6-C24aryl, C6-C24aryl substituted by -OCrCi8alkyl or -OCe-Qwaryl, R11, R12 and R13 are independently of each other H, CrCi8 alkyl, CrC18alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, C2-C18alkenyl, C2-C18alkynyl, Crdaalkoxy, CrCi8alkoxy which is substituted by E and/or interrupted by Dt or C7-G25aralkyl, and D( E, R6, R7, R8f R9, R10, R14' and R1ff are as defined in claim 2. A polymer according to any of claims 1 to 3, comprising a co-monomer T which is q is an integer from 1 to 10, especially 1, 2 or 3, s is an integer from 1 to 10, especially 1, 2 or 3, R6( R7, R8, R9 and R10are as defined in claim 2, or R9 and R10 together form a five or six membered ring that is substituted by R6, R9 and R10 together form a group of formula =CR100R10\ wherein R100 and R101 are independently of each other H, CrC18alkyl, d-C18alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, or C2-C2oheteroaryl, or C^C^heteroaryl which is substituted by E, and R14 and R15 are independently of each other H, CrCi8alkyl, CrCi8aIkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, or (VC^heteroaryl, CrCajheteroaryl which is substituted by E. A polymer according to any of claims 1 to 3, comprising repeating units of formula la or lb, wherein R1 is a group of formula wherein R2 is H, R6 and R7 are independently of each other H, CrC12alkyl, C5-C12cycloalkyl, especially cyclohexyl, C6-C24aryl, especially phenyl, naphthyl, or biphenyl, which can be substituted by -O-Ci-ChalkyI, or CrC18alkoxyt R8 is Ci-Ci8alkylf CrCi8alkyl interrupted by one or two oxygen atoms, or C6-C12aryl, which optionally can be substituted by CrC12aIkyl, or CrC12alkoxy, R9 and R10 are independently of each other H, CrC12alkyl, or CrCi2alkoxy, R9 and R10 are independently of each other CrC18alkyl, especially C4-Ci2alkyl, which can be interrupted by one or two oxygen atoms, and X1 and X2 are as defined in claim 1. A polymer according to claim 5, comprising a co-monomer T which is selected from the group consisting of R8 is d-Ciaalkyl, R9 and R10 are independently of each other CrC18alkyl, especially C4-C12alkyi( which can be interrupted by one or two oxygen atoms, or R9 and R10 form a five or six membered carbocyclic ring, which optionally can be substituted by Ci-C8alkyl. x is in the range of 0.005 to 1, especially 0.4 to 0.6, and y is in the range of 0.995 to 0, especially 0.6 to 0.4, wherein the sum of x and y is 1, , wherein the dotted line represent the bond to the pyrimidine ring, R3, R4 and R5 are as defined in claim 1, R56 and R57 are independently of each other H, d-Ci8alkyl, Ci-d8alkyl which is substituted by E and/or interrupted by D, C5-Ci2cycIoalkyl, C5-Ci2cycloaIkyl, which is substituted by E, Ce-C^aryl, C6-C24aryl which is substituted by E, C2-C2oheteroaryl, C2-C^heteroaryl which is substituted by E, C2-Ci8alkenyl, C2-C18alkynyl, Ci-d8alkoxy, Cr Ci8alkoxy which is substituted by E and/or interrupted by D, or C7-C2saralkyi, R58 is H, Ci-Ci8alkyl, CrC18alkyi which is substituted by E and/or interrupted by D, C6-C24aryl, or C7-C25aralkyl, R59 and R60 are independently of each other H, CrC18 alkyi, Ci-Ci8alkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, C2-C20heteroaryi, C2-C20heteroaryl which is substituted by E, C2-C18alkenyl, C2-C18alkynyl, CrC18alkoxy, CrCi8alkoxy which is substituted by E and/or interrupted by D, or C7-C25aralkyl, or R59 and Reform a ring, especially a five- or six-membered ring, R71 is H, CrC18alkyl, -C=N, -CONR^R^or -COOR27, D is -CO-; -COO-; -OCOO-; -S-; -SO-; -S02-; -0-; -NR25-; -SiR^R31-; -POR32-; -CR23=CR24-; or -C^G-; and E is -OR29; -SR29; -NR^R26; -COR28; -COOR27; -CONR25R26; -CN; -OCOOR27; or halogen; wherein R23, R24, R25 and R26 are independently of each other H; C6-Ci8aryl; C6-C18aryl which is substituted by d-dsalkyl, d-Ci8alkoxy; Ci-Ci8alkyl; or d-Ci8alkyl which is interrupted by -0-; or R27 and R28 are independently of each other H; C6-Ci8aryl; C6-Ci8aryl which is substituted by CrC18alkyl, or CrC18alkoxy; Ci-d8alkyl; or CrCi8aikyl which is interrupted by -0-, and R29 is H; C6-Ci8aryl; C8-d8aryl which is substituted by CrC18alkyl, CrCi8alkoxy; Ci- Ci8alkyl; or d-C^alky! which is interrupted by -0-, R30 and R31 are independently of each other Ci-Ci8aikyl, Ce-Cnsaryl, or C6-Ci8aryl, which is substituted by CrCisalkyi, and R32 is CrC^alkyl, C6-Ci8aryl, or Ce-Cisaryl, which is substituted by CrCi8alkyl. 9. A polymer according to claim 8, wherein R3, R4 and R5 are independently of each other H, CrC18 alkyl, Ci-Ci8alkyl which is substituted by E and/or interrupted by D, C2-Ci8alkenyl, Ca-Ciaalkynyi, CrC18alkoxy, CrC18alkoxy which is substituted by E and/or ml, m2, m3, m4, m5, m6 and m7 are integers of 1 to 10, in particular 1 to 3, X6 is H, Ci-Ci8alkylf d-d8alkoxy, CrC18aikyl which is substituted by E and/or interrupted by D, C6-C24aryl, which can optionally be substituted, substituted by E and/or interrupted by D, or C7-C25aralkylf X4 is CrC18alkyl, Ci-Ci8alkyl which is substituted by E and/or interrupted by D, C6-C24 aryl, or C2-C20heteroaryl, which can optionally be substituted, X5is CrCi8alkyl, C6-C24aryl, or CrC^heteroaryl, which can optionally be substituted by -Od-daalkyl or -OC6-C24aryl, R6\ R62 and R63 are independently of each other H. CrCi8alkyl, d-Ci8alkyl which is substituted by E and/or interrupted by D, Ce-C^aryl, C6-C24aryl which is substituted by E, C2-C18alkenyl, C2-Ci8alkynyl, CrC18aIkoxy, CrC18alkoxy which is substituted by E and/or interrupted by D, or Cz-C^araikyl, R64 and R^are independently of each other H, CrCi8alkyl, CrCiQalkyl which is substituted by E and/or interrupted by D, C6-C24aryl, C6-C24aryl which is substituted by E, or CrC^heteroaryl, C2-C2oheteroaryl which is substituted by Ef and D, E, R56, R57, R58, R59 and R60 are as defined in claim 8. wherein p is an integer from 1 to 10, especially 1, 2 or 3, q is an integer from 1 to 10, especially 1,2 or 3, s is an integer from 1 to 10, especially 1, 2 or 3, R72is H, C dealkyl; or d-dsalkyl which is interrupted by -0-; R56, R57, R58, R59, R60, R64 and R^are as defined in claim 8, or R59 and R60 together form a group of formula =CR100R10\ wherein 12. An optical device or a component therefore, comprising a substrate and a polymer according to any of claims 1 to 11. 13. An optical device according to claim 12, wherein the optical device comprises an electroluminescent device. 14. An optical device according to claim 13, wherein the electroluminescent device comprises (a) a charge injecting layer for injecting positive charge carriers, (b) a charge injecting layer for injecting negative charge carriers, (c) a light-emissive layer located between the layers (a) and (b) comprising a polymer according to any of claims 1 to 11. R\ R2, R3, R4 and R5 are independently of each other an organic substituent, especially C2-C3oaryl or a C2-C26heteroaryl, which optionally can be substituted, X1, X2, and X3 are independently of each other a divalent linking group, and X11 is independently in each occurrence a halogen atom, or -B(OH)2l -B(OY1)2 or wherein Y1 is independently in each occurrence a CrC10alkyl group and Y2 is independently in each occurrence a CrCioalkylene group, such as -CY3Y4-CY5Y6-, or ~CY7Y8-CYV°- CY1 V2-, wherein Y3, Y4, Y5, Y6, Y7, Y8, Y9, Y10, Y11 and Y12are independently of each other hydrogen, or a CrCi0alkyl group, especially -C(CH3)2C(CH3)2-, or -C(CH3)2CH2C(CH3)2- with the proviso that 2-phenyl-4,6-bis(p-bromophenyl)pyrimidine and 2,4,6-tris(p-bromophenyl)pyrimidine are excluded.

Documents:

1069-chenp-2005 abstract-duplicate.pdf

1069-chenp-2005 claims-duplicate.pdf

1069-chenp-2005-abstract.pdf

1069-chenp-2005-claims.pdf

1069-chenp-2005-correspondnece-others.pdf

1069-chenp-2005-correspondnece-po.pdf

1069-chenp-2005-description(complete).pdf

1069-chenp-2005-form 1.pdf

1069-chenp-2005-form 26.pdf

1069-chenp-2005-form 3.pdf

1069-chenp-2005-form 5.pdf

1069-chenp-2005-other documents.pdf

1069-chenp-2005-pct.pdf