Title of Invention

CONTINUOUS CLOSED-CIRCUIT DESALINATION APPARATUS WITH SINGLE CONTAINER

Abstract An apparatus for consecutive sequential closed-circuit desalination of a salt water solution by reverse osmosis having at least one circuit and a single container (CN), wherein the circuit includes at least one RO module (M1) connected in parallel.
Full Text BACKGROUND OF THE INVENTION
The present invention relates to a method and apparatus for the desalination of
Sea Water (SW) or Brackish Water (BW) by Reverse Osmosis (SWRO or
BWRO) in closed circuit.
Desalination by reverse osmosis (RO) occurs when salt water solution is
compressed against semi-permeable membranes at pressure higher than its
osmotic pressure. The "Plug Flow Desalination" (henceforth "PLD") method
involves the passing of pressurized feed flow through pressure vessels
(modules) with semi-permeable membrane elements, wherein it separates
continuously into none pressurized flow of desalted permeate and pressurized
flow of brine effluent. The SWRO or BWRO recovery of PFD relates to the
feed concentration, the applied pressure, the number of elements per module,
the staging of modules and the specifications of elements. Pressurized feed
flow in PFD is always greater than the permeate flow and 50% recovery
implies that pressurized feed flow is twice that of permeate. PFD may also
involve partial recycling to enhance recovery and this method is characterized
by the continuous flow of its three components; the pressurized feed, the
pressurized brine effluent and the permeate.
In contrast with PFD, Closed Circuit Desalination (henceforth "CCD") is a
batch process performed with solution recycling under hydrostatic pressue
with same rate of pressurized feed supply and permeate delivary. Intermal
flow in CCD is created by circulation means in order to minimize
concetrration polarization effects. The CCD technology was first reported

in the late eighties by Szuz et al. in U.S. Pat. No. 4,983,301 and by Bartt in
U.S. Pat. No. 4,814,086 and the making of such a such batch process
continuous was proposed by means of ".. two relatively large capacity
tanks .." that are alternately engaged in the closed circuit, thereby, allow
the recharge of the closed circuit with fresh feed without the stopping
desalination. Earlier patents from the late seveties, such as DE 26 22 461
A (1977) and JP 54 128985 A (1979), describe PFD with partial re-
circulation that is fundamentally different form CCD inspite of the
similarity of certain fitures (e,g,. circuit with membrane module(s), lines
for feed and for recycling, ciruclation means, pressurizing means, means
for effluent discharge, monitoring means, etc.). The distinction between
CCD and PLD is clear and unmistakable, since only the former process
involves the replacement of brine effluent with fresh feed at atmospheric
pressure, thereby avoiding the need for energy recovery from the
pressurized brine effluent that is essentail in the latter process.
In comparison with PLD, the CCD requires much smaller means for
pressurization fresh feed and proceeds with lower specific energy without
need of energy recovery. The CCD technology according to said patents is
a batch process made to operate continuously by means of consectuive
sequential steps involving two relatively large capacity containers and this
approach has not been considered economically favored for the design of
desalination plants.
The present invention describes both apparatus and methods whereby Closed
Circuit Desalination (CCD) may be performed continuously by means of a
relatively small single container, thereby, the making of this technology
economical feasible for diverse applications involving both sea water and/or
brackish water desalination.
SUMMARY OF THE INVENTION
The present invention proposes an apparatus and methods for desalination
of sea water, or brackish water, on the basis of reverse osmosis using a
closed circuit, wherein feed is. recycled through parallel desalination
modules by a circulation driving means and counter pressure is created by a
pressurizing means which also replaces the released permeate by fresh feed
supply. The volume of feed pressurized into the closed circuit during the
desalination sequence is monitored by means of a flow meter, this volume
at any given instance being equal to the volume of released permeate. The
circulation driving means is made to operate at low inlet-outlet pressure
difference under elements specifications of maximum element recovery and
flow ratio of concentrate to permeate, and the pressurizing means may be
made to deliver variable pressure as function of the recovery as monitored
by the flow of permeate and/or the flow of pressurized feed and/or the
changing concentrations during course of the desalination sequence.
Counter pressure of desalination at module inlets is maintained at a fixed
level above osmotic pressure during the entire desalination sequence.
The variable pressure closed circuit desalination apparatus may be made to
operate continuously by adding a single container which is actuated
intermittently to recharge the closed-circuit with fresh feed and at the same
time remove the consumed brine effluent from the system. While the
pressurized container with fresh feed is engaged with the closed circuit, the
desalination process is continued and the modules may be operated non-
stop at their specified permeate output.
The inventive method and apparatus of variable pressure closed circuit
desalination by reverse osmosis may be implemented by a simple apparatus

made of readily available commercial components and it allows low cost
desalination at highly significant savings in components including power
components and energy.
The inventive apparatus may be operated at constant pressure such that the
costs of the pressurizing means are considerably reduced while the energy
expenditure is still kept lower than in the methods of the prior art.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. IA Is a schematic drawing of an apparatus with six modules, each of
three elements, and a single container for continuous Closed Circuit
Desalination of sea water, or brackish water, describing the valves
positions during the closed-circuit desalination while the container
is being recharged with fresh sea water feed, in accordance with a
preferred embodiment of the present invention.
Fig. IB Is a schematic drawing of an apparatus with six modules, each of
three elements, and a single container for continuous Closed Circuit
Desalination of sea water, or brackish water, describing the valves
positions during the closed-circuit desalination and the
pressurization of the container which has been recharged with fresh
sea water feed, in accordance with a preferred embodiment of the
present invention.
Fig. IC Is a schematic drawing of an apparatus with six modules, each of
three elements, and a single container for continuous Closed Circuit
Desalination of sea water, or brackish water, describing the valves
positions during the recharge of the closed-circuit with fresh feed

and the simultaneous removal of the brine effluent through the
container, in accordance with a preferred embodiment of the
present invention.
DETAILED DESCRIPTION OF THE INVENTION
The present invention provides a solution to the problem of extensive
energy consumption and high costs involved in reverse osmosis
desalination processes of the prior art by proposing an apparatus and
method for consecutive sequential desalination of sea water, or brackish
water, by reverse osmosis comprised of a closed-circuit, wherein feed is
recycled through parallel desalination modules by a circulation pump, a
single container is used intermittently to recharge the closed-circuit with
fresh feed and remove the brine effluent, and counter pressure is created by
a pressurizing pump which also replaces the released permeate by fresh
feed supply.
In accordance with the inventive method, the volume of the feed
pressurized into the closed circuit during the desalination sequence is
monitored by means of a flow meter, this volume at any given instance
being equal to the volume of released permeate. The volume of released
permeate being directly proportional to the raise in osmotic pressure, the
monitoring of this volume provides the means to control the counter
pressure of desalination at modules' inlets such that it is kept at a fixed
level above osmotic pressure throughout the desalination sequence.
In accordance with the novel apparatus and method of the invention,
modules may comprise one, two, three or more membrane elements each
and this number dictates the module recovery per single recycling pass,
whereas, the ultimate recovery of the entire sequential process depends
only on the total number of recycling passes performed in the closed-circuit
under variable pressure conditions of fixed net driving pressure. In sharp

contrast, single pass desalination of. sea water by the CFD method of the
prior art requires modules of seven or eight elements and the overall
recovery remains low (40%-42%) if the maximum element recovery
specified by the manufacturers' of membrane elements under test
conditions (e.g. 10%) is not exceeded. In simple terms, the novel invention
allows the reaching of any desired desalination recovery without exceeding
the specified maximum element recovery under test conditions, whereas,
the recovery limits of the CFD method of prior art under such conditions
are in the range of 40%-42% .
The inventive method allow the attainment of high average recovery per
element without exceeding the specifications of maximum element
recovery under test conditions and this is not possible by the CFD method
of prior art.
The recovery of modules with 1, 2, 3, 4, 5, 6, 7 and 8 elements with
specified maximum element recovery of 10% under test conditions is
10.0(10)%, 18.1(9.05)%, 24.5(8.1)%, 29.7(7.4)%, 33.9(6.8)%, 37.3(6.2)%,
40.0(5.7)%, 42.1(5.3)%, respectively, with average recovery value per
element given in parenthesis. The much higher average element recovery
expected by the inventive method as compared with the CFD method of
prior art implies significant savings of membrane elements by the new
method.
The average flow per element under the specified test conditions of the
manufacturers is directly related to the average recovery per element, and
therefore, higher element recovery also implies faster permeate flow. Salt
passage of semi-permeable membrane element is inversely related to the
average element flow, and therefore, the inventive method is expected to

afford permeates of lower salt content and higher quality as compared with
the CFD method of prior art. In light of the aforementioned, the salt
passage by the inventive method is expected to decrease as function of
decreased number of elements per module. Accordingly, the better quality
permeates by the inventive method are received with modules of fewer
elements.
It is another advantage of the invention that by gradually increasing the
counter pressure of desalination such that it is kept at a fixed value above
the osmotic pressure of concentrate at modules' inlets, the mean counter
pressure of the entire process is significantly lower than the constant
counter pressure required by the CFD method of the prior art, and this
implies significant savings in power and energy by the inventive method.
In accordance with another advantage of the invention, the flow in the
closed circuit created by the circulation means can be controlled and
adjusted to minimize the concentration polarization effect by disturbing the
concentrate thin layer on the membrane surfaces.
The inventive method circumvents completely the need for expensive
energy recovery means which are the most tedious and troublesome
components in CFD apparatus of the prior art.
The novel apparatus and method of the invention eliminate the need for the
application of vast over-power as well as the need for excess power
recovery practice characteristic of the existing CFD methods.
In accordance with another advantage of the invention, the footprint of
desalination units is sharply reduced in comparison with existing CFD

methods due to the significant savings in power components, membrane
elements and energy as well as by eliminating completely the need for
energy recovery from the brine effluent.
Fig. IA is a schematic drawing of an apparatus that is one of the preferred
embodiments of the inventive apparatus. As seen in Fig. IA, the inventive
desalination apparatus comprises a pressurized sea water circuit which
feeds in parallel a plurality of desalination modules M1-M6 with said circuit
and modules constitute a Closed-Circuit (henceforth "CC") wherein
desalination takes place. It will be understood that the number of modules
is not limited to the six modules shown in Fig. IA and it may be smaller or
larger according to different design requirements. It is one of the
advantages of the inventive apparatus that it may be operated with the
commercial modules known from the prior art. It is also envisaged that
different kinds of modules may be designed to be applied in the inventive
apparatus, or the apparatus may be provided with commercial modules not
known at the time of this invention. The modules to be applied in the
inventive apparatus will generally comprise one or more elements within
housing. The concentrate from modules outlets is recycled back to the
modules inlets through the CC by means of a circulation pump CP that is
operated at low inlet-outlet pressure difference. The desired hydrostatic
pressure in the CC, including the modules M1-M6, is created by means of
a pressurizing pump PP that feeds sea water into the apparatus through line
L replacing the volume of released permeate, designated by an arrow A, by
fresh sea water supply designated by arrow E1. The volume of the sea water
supply is being monitored continuously by means of a flow meter FM. The
pressurizing pump PP is made to actuate either at constant pressure or at
progressively increased pressure as function of desalination recovery
manifested by monitored volume on the flow meter FM. The apparatus also

comprises lines L1 for conducting supply in the CC from the circulation
pump CP to the inlets of modules M1-M6 via secondary lines L1.1, L1.2,
L1.3, L1.4, L1.5, L1.6. The apparatus further comprises line L2 for the recycling
of partially desalinated sea water from the modules outlets via secondary
collecting lines L2.1, L2.2, L2.3, L2.4, L2.5, L2.6 driven by circulation pump CP.
The entire CC comprises of lines L1, L2 and the modules M1-M6 with their
inlets and outlets secondary lines. It will be understood that the design of
the desalination circuit and lines as shown in Fig. IA is schematic and
simplified and is not to be regarded as limiting the invention. In practice the
desalination apparatus may comprise many additional lines, branches,
valves and other installations or devices as necessary according to specific
requirements while still remaining within the scope of the invention and the
claims.
Referring again to Fig. IA, the desalination apparatus further comprises a
line AA for the collection of released permeate (desalted solution) from the
modules outlets A1, A2, A3, A4, A5, A6.
Referring again to Fig. IA, the desalination apparatus further comprises a
system for Feed Recharge (henceforth "FR"), whereby brine is replaced
with fresh feed in the CC at the end of each desalination sequence of
desired recovery. The FR system comprises the lines E2, B1, B2, and C, the
two-way valves V1-V5, the container CN, and the recharge pump RP. Fig.
IA describes desalination in progress in the CC system, while recharge in
progress takes place in the FR system. The CC and FR systems in Fig. IA
are disengaged since valve V1 is opened and valves V2 and V3 are closed.
During the recharge operation of the FR system, fresh feed is admitted
through valve V4 (opened) and line B2 to the top of the container CN, and at
the same time brine is removed from the bottom of the container CN to the

outside (arrow C) through line B1, valve V5 (opened) and line C, by
means of the recharge pump RP which is actuated at low pressure (~1.0
bar) under nearly laminar flow conditions.
Fig. IB describes the valves positions after the container recharge operation
completed and the FR system is being pressurized and made ready to
provide fresh feed supply to the CC system. The valves of the FR system at
this stage are closed, except for valve V3 though which pressurization is
taking place.
Fig. IC describes the valves positions when the FR system provides fresh
feed supply to the CC system and removes the brine effluent. If the CC and
FR systems are of the same intrinsic volume, one full FR container with
fresh feed is sufficient to complete the recharge of the entire CC system.
During the feed recharge operation, the desalination process is continued
non-stop.
The direction of flow in the inventive apparatus is indicated by light grey
arrows. Non-pressurized lines are indicated by dashed lines, lines which are
pressurized part of the time are indicated by dotted lines and lines of the CC
system which are continuously pressurized are indicated by continuous
lines. It will be understood that the lines, valves and pumps shown in Fig.
I(A-C) are but one way of implementing the invention and many other
installations may be envisaged for diverse embodiments of the invention.
It will be understood that the inventive apparatus and method can be
applied as non-modular or as modular systems, in the former case the
pressurizing means comprises a variable pressure pump(s) for feed provided
at atmospheric pressure, and in the latter case the pressurizing means

comprises a variable pressure booster pump(s) for feed already provided
under pressure. The non-modular inventive apparatus intended primarily
for autonomous desalination units, whereas the modular apparatus intended
as building blocks for large desalination plants wherein pressurized feed is
supplied to the units centrally from a main line and the variable pressure
booster pump of each unit in the system used for pressure adjustments as
required by the unit.
The apparatus according to the invention may be realized using a large
number of modules such that the modules are arranged in multiple parallel
lines, each line supplied in parallel with solution for desalination from the
main line of the apparatus and each module within each line also supplied
in parallel. In such an apparatus separate circulation means may be used for
each of the said lines respectively or a single circulation means may be used
for all of the said lines.
The pressurizing means or the circulation means or both may be
implemented by two or more pumps installed in parallel or any other design
according to specific requirements.
In accordance with the inventive apparatus, the container need not be a
vessel of large volume and it may be implemented as a pipe or duct section.
The desalination method of the invention involves the following steps,
described herein below with reference to the apparatus of Fig. I(A-C): (I)
the entire apparatus is filled with fresh sea water or brackish water supply;
(II) the pressurizing pump(s) is set to deliver constant pressurized feed flow
under the appropriate variable pressure conditions; (III) the circulation
pump CP is actuated at low inlet-outlet pressure difference such that flow

rate of concentrate to permeate is consistent with specifications of modules;
(IV) the sequential RO desalination in the CC system is performed by the
recycling of the process concentrate and its mixing with fresh pressurized
feed supplied to the CC during the course of the desalination sequence; (V)
concomitant with the completion of the desired sequential recovery in the
CC system, flow circulation is diverted intermittently through the FR
system until the CC system is recharged with a fresh feed supply and the
brine effluent removed; (VI) concomitant with the completion of the fresh
feed recharge of the CC system, the CC and FR systems are disengaged,
the former starts a new desalination sequence and the latter undergoes fresh
feed recharge combined with brine discharge followed by pressurization,
thus, made ready the next CC recharge operation.
It will be understood that in order to maintain constant permeate flow from
the modules of the inventive apparatus, the variable pressure in the CC
system should account for a constant, or nearly constant, net driving
pressure (henceforth "NDP"). It will be further understood that said NDP
in the context of the inventive method is the pressure difference between
the applied pressure, also referred to as counter pressure, and the osmotic
pressure of the recycled solution at the inlet to modules during the
continuous desalination process.
It will be obvious to those versed in the art that the desalination method of
the invention may be operated in desalination apparatus of different designs
as explained above in respect of the inventive apparatus as long as such an
apparatus comprises a closed circuit of conducting lines with a container,
one or more desalination modules of one or more membrane elements each
supplied in parallel, a pressurizing means, a circulating means, a flow
monitoring means and a conductance monitoring means.

Furthermore, it will be obvious to those versed in the art that single
inventive apparatus of said modular design of any preferred production
capacity can be joined together and made into a desalination plant of an
expanded production capacity in which the pressurized feed is centrally
generated and supplied to the individual units of the plant through
extensions from a single high pressure delivery line of fresh feed.
Example-I
The application of the new technology is exemplified in TABLE-I by sea
water desalination under progressively increased pressure conditions of
constant net driving pressure using an apparatus of the schematic design
shown in Fig. I(A-C) with six modules of three elements each and a single
container of 394 liter which is of the same intrinsic volume of the closed
circuit. The elements in this example are of a commercial type, or similar,
and their presumed specifications under test conditions are listed in
TABLE-I. The specified maximum element recovery of 10% that of the
head elements in the modules is not exceeded during the entire sequential,
or consecutive sequential, desalination operation described by the example.
The specified modules recovery of 24.5% cited in TABLE-I is that of a
three-element module under test conditions with maximum element
recovery being 10%. Permeate flow in the example under review is
presumed constant since the desalination process is performed under
constant, or nearly constant, net driving pressure (NDP) of ~30.4 bar which
is the specified NDP under test the conditions of the elements. Under the
conditions of constant NDP applied in the example, the pressurized feed
flow per module (37.4 lit/min) and the recycled concentrate flow per
module (115.3 lit/min) remain constant with the former being identical to
the permeate flow per module (37.4 lit/min). The constant flow parameters

for the exemplified apparatus of six modules is six time that cited in
TABLE-I per single module.
The presumed efficiency factors (f) of pumps in this example are fpp=0.88,
fcp=0.85 and fRP=0.80; wherein, fpp;fcp and fRP are the efficiency factors of
the pressuring pump (PP), the circulation pump (CP) and the feed recharge
pump (RP), respectively. In this example the presumed variable pressure
delivery of the PP is in the range of 54.9-70.8 bar (mean pressure, 62.8
bar), RP operates at 0.5 bar and the CP operates at an inlet-outlet pressure
difference(Ap) of 1.0 Bar (~15 psi).
The example under review in TABLE-I contains constant flow data per
module as expected of a system which operates under the cited variable
applied pressure (AP) of constant net driving pressure (NDP). The
constant flow is derived from the permeate flow equation (1) and the
applied pressure requirements expressed by (2); wherein, Qp stand for
permeate flow per element, A for permeability coefficient, S for
membranes surface area, TCF for temperature correction factor, FF for
fouling factor, NDP for net driving pressure, AP for applied pressure and
OP for osmotic pressure. Recovery in the sequential desalination process
under review is expressed by (3) and the sequential time period required to
attain a desired recovery expressed by (4); wherein, Rec stands for percent
recovery, V for the intrinsic volume of the closed circuit, v for the volume
of the pressurized feed added to the system or the volume of permeate
received, T for the sequential period for a specified recovery, Q for
permeate flow per module and n for the number of modules per apparatus.
Power data in the example under review obtained from the flow-pressure
expression (5); wherein, P stands for power in kW, Q for flow in liter

per minute, p for pressure, or pressure difference, in bar, and / for the
efficiency coefficient of the power components.
The mean specific energy data in TABLE-I is derived from power data, the
time elapsed (t) in the sequential period (T) for desired recovery and by
accounting for the permeate volume released.
(1) Qp = A*S* (TCF)*(FF)* (NDP)
(2) AP = (OP)+(NDP)
(3) Rcc(%)=100*v/(V+v)
(4) T= {1/(n*Q)}*{(Rec*V)/(100-Rcc) }
(5) P( kW)= (Q*p) / (592*f)
Other specific information disclosed in TABLE-I on the time coordinate (t,
min.) of the sequential process includes; the module recovery (REC.
24.5%), the recovery build up (DESL. REC.) during the process;
concentrate to permeate flow ratio (CONCEN. PERM. FLOW RATIO); the
number of recycled closed circuits (Number RCC); modules inlet
concentrations [CONC (%). t-0.25, inlet]; average concentrations of closed-
circuit [CONC (%), t], power demand per module; the osmotic pressure
(OP), applied pressure (AP) and net driving pressure (NDP) at modules
inlets; and the mean specific energy (Mean S.E. kWhm3).
The combining of sequential desalination steps into a continuous process of
consecutive sequences for continuous desalination is done by means of a
controlled system which actuates valves and other components in
compliance with on-line monitored information of concentrations and/or
pressures and/or flow of permeate and/or of pressurized feed. The follow-
up of the conductivity of the solution in the closed circuit is one of several

means by which such a desalination process can be effectively managed and
controlled.
According to the date in TABLE-I, the apparatus in this example operates
with a sequential period (T) for 50% recovery of 107 seconds (1.75
minutes) of which some 34 seconds are consumed for closed circuit
recharge with fresh feed through a container of 395 liters, the same volume
as that of the closed circuit itself. Therefore, the time difference of 73
seconds (107-34) between successive actuations of the recharge container is
the maximum period available for its recharge and pressurization.
In summary, the preferred embodiment of the inventive method and
apparatus is exemplified (Example-I) by a units for 323 m3/day capacity of
desalted sea water on the basis of 100% availability and 50% recovery
which requires a mean specific energy of 2.18 kWh/m3 under variable
counter pressure (54.9-70.8 bar) conditions or 2.38 kWwh/m3 under
constant applied pressure (70.8 bar) conditions.
TABLE-II
The performance of the non-modular desalination unit in Example-1 as
compared with a plant comprised often such modular units.
Items Compared M1E3 6[M1E3] 10{6[M1E3]}
Daily permeate production (m3/day) 53.9 323.3 3,233
Daily pressurize feed supply (m3/day) 53.9 323.3 3,233
Daily non-pressurized feed supply (m3/day) 53.9 323.3 3,233
Daily brine removed (m3/day) 53.9 323.3 3,233
Maximum element recovery (%) 10 10 10
Module recovery (%) 24.5 24.5 24.5
Minimum sequential pressure (bar) 54.9 54.9 54.9
Maximum sequential pressure (bar) 70.8 70.8 70.8
Average sequential pressure (bar) 62.8 62.8 62.8
Minimum power demand (kW) 4.17 25.0 250
Maximum power demand (kW) 5.77 34.6 346
Average power demand (kW) 4.97 29.8 298
Sequence duration (seconds) 107 107 107
Recovery (%) 50 50 50
Mean Specific Energy (kWh/m3) 2.18 2.18 2.18
Footprint estimated (m2) 6 6 60
M1E3: The three elements module used in Example-I as well as here.
6[M1E3]: The six modules non-modular desalination unit in Example-I.
10{6[MlE3]}: The joining of 10 modular units of the type in Example-I.
Example-II
The connecting of 10 desalination units of modular design analogous to that in
Example-I to a central pressurized feed supply line, with each unit equipped
with a variable pressure booster instead of a variable pressure pump,
exemplifies the modular apparatus application of the novel inventive method.
Some performance data of three elements desalination modules, a modular
unit with an analogous design to that in Example-I with 6 modules of 18
elements, and a desalination plant containing ten such modular units are
exemplified in TABLE-II
I CLAIM:
1. An apparatus for continuous consecutive sequential desalination
of a salt water solution by reverse osmosis that comprises:
at least of one closed circuit comprising one or more desalination
modules with their respective inlets and outlets connected in parallel by
conducing lines, each of said desalination modules comprising one or
more membrane elements;
at least one pressurizing means for creating sufficient counter
pressure to enable reverse osmosis desalination and replacement of
released permeate by fresh feed in said closed circuit;
at least one circulation means for recycling of said desalinated
solution through said one or more desalination modules of said closed
circuit;
at least one conducting line means for permeate collection from
said one or more desalination modules of said closed circuit;
a single container means to enable replacement of brine by fresh feed
in said closed circuit while desalination is continued;
at least one line for conducting said desalinated solution from said
closed circuit to said single container;
at least one line for conducting fresh feed solution to be desalinated
from said single container to said closed circuit;
at least one line for recharging said single container with fresh feed
solution to be desalinated;
at least one line for removing brine effluent from said single
container;
at least one valve means to enable the engagement and
disengagement of said single container form said closed circuit, the
replacement of brine by fresh feed from said single container, and the
compression and decompression of said single container; and
control means to enable continuous closed circuit desalination of
desired recovery proceed in consecutive sequential steps under variable
pressure, or constant pressure conditions.
2. An apparatus for closed-circuit desalination of a salt water solution by
reverse osmosis according to claim 1, wherein variable pressure applied
controllably during the said closed-circuit desalination sequences such
that the difference between applied pressure and osmotic pressure at
each stage during the said closed-circuit desalination process is
maintained constant or substantially constant.
3. An apparatus for closed-circuit desalination of a salt water solution by
reverse osmosis according to claim 1, wherein constant pressure is
applied during the said closed circuit desalination sequences with
difference between applied pressure and maximum osmotic pressure
during said desalination process maintained above a minimum
predefined level.
4. An apparatus for closed-circuit desalination of a salt water solution by
reverse osmosis according to any of the preceding claims wherein the
said means for monitoring the progress of desalination is a means for
monitoring the flow of fresh salt water feed into the said closed-circuit
and/or the flow of the desalted solution from the said closed-circuit.
5. An apparatus for closed circuit desalination of a salt water solution by
reverse osmosis according to any of the preceding claims wherein the
said means for monitoring the progress of desalination is a
concentration monitoring means.
6. An apparatus for closed circuit desalination of a salt water solution by
reverse osmosis according to any of the preceding claims wherein the
said modules comprise one or more semi-permeable membrane
elements within a housing.
7. An apparatus for closed circuit desalination of a salt water solution by
reverse osmosis according to any of the preceding claims wherein the
said modules are grouped in parallel batteries, each of the said parallel
batteries comprising a plurality of modules.
8. An apparatus for closed circuit desalination of a salt water solution by
reverse osmosis according to any of the preceding claims wherein the
said single container means are cylindrical conduit sections.
9. An apparatus for closed-circuit desalination of a salt water solution by
reverse osmosis according to any of the preceding claims wherein the
said pressurizing means comprises one or more pressurizing pumps,
actuated in parallel or in line.
10. An apparatus for closed circuit desalination of a salt water solution by
reverse osmosis according to any of the preceding claims wherein the
said circulation means is one or more circulation pumps actuated in
parallel or in line.
11. An apparatus according to any of the preceding claims for closed
circuit desalination of a salt water solution by reverse osmosis wherein
the said solution is sea water.
12. An apparatus according to any of the preceding claims for closed
circuit desalination of a salt water solution by reverse osmosis wherein
the said solution is brackish water.
13. An apparatus according to any of the preceding claims for closed circuit
desalination of a salt water solution by reverse osmosis wherein the said
solution is treated domestic effluent.
14. An apparatus according to any of the preceding claims for closed
circuit desalination of a salt water solution by reverse osmosis wherein
the said solution is an industrial effluent.
15. A method for consecutive sequential closed circuit desalination of a salt
water solution by reverse osmosis in a closed circuit with one or more
desalination modules connected in parallel to the said circuit, a single
container means to enable replacement of brine by fresh feed in said
closed circuit while desalination is continued; a line means for
connecting between the said modules and the said single container
means, a pressurizing means, a circulating means, a means for
monitoring the progress of the desalination process and a plurality of
valve means; the said method consisting of consecutive desalination
sequences and enables continuous desalination of salt water solution
non-stop by the following steps:
a. filling the said closed circuit and single container with fresh salt
water solution under atmospheric pressure, sealing the said
closed circuit and single container and pressurizing the said
fresh salt water solution within the said closed circuit and single
container;
b. recycling the pressurized salt water solution through the said
closed circuit desalination modules at a predefined flow rate by
means of the circulation means such that permeate is released
efficiently from the said modules;
c. controlling the duration of the desalination sequence and the
pressure applied during the said desalination sequence
according to the progress of desalination recovery as manifested
by the monitoring means;
d. collecting the desalinated solution from the said modules;
e. engaging said single container filled with fresh feed and
pressurized with said closed circuit at the desired recovery level
to enable the recharge of said closed circuit with fresh feed at
the end of each said desalination sequence and this without
stopping the said desalination process;
f. disengaging said single container from said closed circuit after
the said closed circuit is recharged with fresh salt water feed to
be desalinated, and
g. decompressing said disengaged single container filled with brine
effluent, replacing the brine effluent in the said single container
with fresh salt water solution feed at substantially atmospheric
pressure, sealing said single container after substantially
recharged with fresh feed completed, and the compression of
the said single container in readiness for the next engagement
with said closed circuit.
16. A method for sequential closed circuit desalination of a salt
water solution by reverse osmosis according to claim 15 wherein
the applied pressure output of the said pressurizing means is
gradually increased during the desalination sequence as a
function of the increase of desalination recovery monitored by
the said monitoring means, such that the ratio of applied pressure

to osmotic pressure is maintained above a predetermined
minimum value throughout the desalination sequence.
17. A method for sequential closed circuit desalination of a salt
water solution by reverse osmosis according to claim 15 wherein
constant counter pressure is applied throughout the desalination
sequence such that the said constant counter pressure is
maintained at a predetermined minimum ratio above the osmotic
pressure of the effluent solution discharged at the end of each
desalination sequence.
18. A method for sequential closed circuit desalination of a salt
water solution by reverse osmosis according to any of claims 15-
17 wherein the said monitoring means is a flow meter means that
monitors the volume of the desalted water or the volume of the
fresh salt water solution feed that is pressurized into the closed
circuit system.
19. A method for sequential closed circuit desalination of a salt
water solution by reverse osmosis according to any of claims 15-
17 wherein the said monitoring means is a concentration
monitoring means.
20. A method for consecutive sequential closed circuit desalination
of a salt water solution by reverse osmosis in a closed circuit
with one or more desalination modules connected in parallel to
the said circuit, the method comprising the steps of: engaging
said single container filled with fresh feed and pressurized with

said closed circuit at the desired recovery level to enable the
recharge of said closed circuit with fresh feed at the end of each
said desalination sequence and this without stopping the said
desalination process; disengaging said single container from said
closed circuit after the said closed circuit is recharged with fresh
salt water feed to be desalinated, and decompressing said
disengaged single container filled with brine effluent, replacing
the brine effluent in the said single container with fresh salt
water solution feed at substantially atmospheric pressure, sealing
said single container after substantially recharged with fresh feed
completed, and the compression of the said single container in
readiness for the next engagement with said closed circuit.
An apparatus for consecutive sequential closed-circuit desalination of a salt water
solution by reverse osmosis having at least one circuit and a single container (CN),
wherein the circuit includes at least one RO module (M1) connected in parallel.

Documents:

414-KOLNP-2006-(04-01-2013)-FORM-27.pdf

414-KOLNP-2006-(12-01-2012)-FORM 27.pdf

414-KOLNP-2006-(15-01-2013)-FORM-27.pdf

414-KOLNP-2006-CORRESPONDENCE 1.1.pdf

414-KOLNP-2006-CORRESPONDENCE 1.2.pdf

414-KOLNP-2006-CORRESPONDENCE 1.3.pdf

414-KOLNP-2006-FORM 16.pdf

414-KOLNP-2006-FORM 27 1.1.pdf

414-KOLNP-2006-FORM 27.pdf

414-kolnp-2006-granted-abstract.pdf

414-kolnp-2006-granted-claims.pdf

414-kolnp-2006-granted-correspondence.pdf

414-kolnp-2006-granted-description (complete).pdf

414-kolnp-2006-granted-drawings.pdf

414-kolnp-2006-granted-examination report.pdf

414-kolnp-2006-granted-form 1.pdf

414-kolnp-2006-granted-form 18.pdf

414-kolnp-2006-granted-form 2.pdf

414-kolnp-2006-granted-form 3.pdf

414-kolnp-2006-granted-form 5.pdf

414-kolnp-2006-granted-pa.pdf

414-kolnp-2006-granted-reply to examination report.pdf

414-kolnp-2006-granted-specification.pdf

414-kolnp-2006-granted-translated copy of priority document.pdf

414-KOLNP-2006-PA.pdf


Patent Number 222917
Indian Patent Application Number 414/KOLNP/2006
PG Journal Number 35/2008
Publication Date 29-Aug-2008
Grant Date 27-Aug-2008
Date of Filing 23-Feb-2006
Name of Patentee EFRATY, AVI
Applicant Address 4 MEVO HASHAKED STREET, 90836 HAR ADAR
Inventors:
# Inventor's Name Inventor's Address
1 EFRATY, AVI 4 MEVO HASHAKED STREET, 90836 HAR ADAR
PCT International Classification Number C02F 1/44
PCT International Application Number PCT/IL2004/000748
PCT International Filing date 2004-08-16
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 157430 2003-08-17 Israel