Title of Invention	A METHOD FOR OPERATING A FUEL CELL SYSTEM.
Abstract	There is disclosed a method for operating a fuel cell system (10) comprising at least one fuel cell stack (12), the stack comprising at least one fuel cell, the fuel cell system (10) also comprising a reactant supply system, the reactant supply system comprising a fuel passage for directing a fuel stream through the stack (12) and an oxidant passage for directing an oxidant stream through the stack (12), the method comprising : supplying the oxidant stream to the oxidant passage at an oxidant supply pressure ; and supplying the fuel stream to the fuel passage at a fuel supply pressure ; wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply pressure when a fuel sid of the reactant supply system is closed.

Title of Invention

A METHOD FOR OPERATING A FUEL CELL SYSTEM.

Abstract

There is disclosed a method for operating a fuel cell system (10) comprising at least one fuel cell stack (12), the stack comprising at least one fuel cell, the fuel cell system (10) also comprising a reactant supply system, the reactant supply system comprising a fuel passage for directing a fuel stream through the stack (12) and an oxidant passage for directing an oxidant stream through the stack (12), the method comprising : supplying the oxidant stream to the oxidant passage at an oxidant supply pressure ; and supplying the fuel stream to the fuel passage at a fuel supply pressure ; wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply pressure when a fuel sid of the reactant supply system is closed.

Full Text	A METHOD FOR OPERATING A FUEL CELL SYSTEM BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to fuel cells and, more particularly, to a method of operating a fuel cell system having closed fuel supply systems. Description of the Related Art Electrochemical fuel cells convert fuel and oxidant to electricity. Solid polymer electrochemical fuel cells generally employ a membrane electrode assembly ("MEA") which comprises an ion exchange membrane or solid polymer electrolyte disposed between two electrodes typically comprising a layer of porous, electrically conductive sheet material, such as carbon fiber paper or carbon cloth. The MEA contains a layer of catalyst, typically in the form of finely comminuted platinum, at each membrane/electrode interface to induce the desired electrochemical reaction. In operation the electrodes are electrically coupled to provide a circuit for conducting electrons between the electrodes through an external circuit. Typically, a number of MEAs are serially coupled electrically to form a fuel cell stack having a desired power output. In typical fuel cells, the MEA is disposed between two electrically conductive fluid flow field plates or separator plates. Fluid flow field plates have at least one flow passage formed in at least one of the major planar surfaces thereof. The flow passages direct the fuel and oxidant to the respective electrodes, namely, the anode on the fuel side and the cathode on the oxidant side. The fluid flow field plates act as current collectors, provide support for the electrodes, provide access channels or passages for the fuel and oxidant to the respective anode and cathode surfaces, and provide passages for the removal of reaction products, such as water, formed during operation of the cell. Certain fuel cells are designed to operate in a closed mode on one or both reactants. Closed reactant supply systems include dead-ended configurations in which a reactant flow passage is generally closed, as well as systems employing closed-loop recirculation of the reactant exhaust stream from the fuel cell outlet to the fuel cell inlet and though the fuel cell with the addition of fresh reactant. In these situations the reactant used on the closed side is generally substantially pure. Typically a purge valve (which is normally closed in closed system operation) is provided somewhere in the reactant flow passage for periodic venting of accumulations of non-reactive components, which can build up in the reactant passages in closed system operation. In conventional fuel cell purge systems the purge valve is opened from time to time, for example, manually or at regular fixed time intervals. Alternatively a purge is triggered, for example, when the voltage or electrical output of one or more cells in a stack falls below a predetermined threshold value (see, for example, GB Patent No. 1 223 941), or when there is a predetermined decrease in electrical power output (see, for example, US Patent No. 3,553,026), or after the fuel cell has expended a preselected number of ampere-hours (see, for example, US Patent No. 3,697,325). The reactant flow path through the fuel cell stack can be configured so that non-reactive components tend to accumulate first in just one or a few fuel cells of the stack, rather than in the outlet region of each cell in the stack. The purge system may be controlled via a controller (see, for example, commonly assigned U.S. Patent Application Publication No. 2003/0022041). However, although purging can improve performance of fuel cells having closed reactant supply systems, it wastes valuable fuel and increases the parasitic load on the system since purging equipment is required. Furthermore, the release of hydrogen into the ambient environment may be undesirable. Accordingly, there remains a need for improved methods of operating fuel cells having closed reactant supply systems for which purging is not necessary. BRIEF SUMMARY OF THE INVENTION The present methods relate to fuel cells and, more particularly, to methods of operating fuel cells having closed fuel supply systems. In one embodiment, a method for operating a fuel cell system comprises at least one fuel cell stack, the stack comprising at least one fuel cell, the fuel cell system also comprising a reactant supply system, the reactant supply system comprising a fuel passage for directing a fuel stream through the stack and an oxidant passage for directing an oxidant stream through the stack, the method comprising : supplying the oxidant stream to the oxidant passage at an oxidant supply pressure: and supplying the fuel stream to the fuel passage at a fuel supply pressure; wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply pressure when a fuel side of the reactant supply system is closed. A person skilled in the art to which the present invention relates can select the oxidant supply pressure and fuel supply pressure depending on the oxidant and fuel supply used, taking care to see that the fuel supply pressure is at least 5 psig greater than the oxidant supply pressure when a fuel side of the reactant supply system is closed. In some embodiments, the fuel cell may be a solid polymer electrolyte fuel cell, and the reactant streams hydrogen and air. In some embodiments, during operation the fuel supply pressure is always at least 5 psig greater than the oxidant supply pressure, and may be between about 5 psig and 30 psig greater than the oxidant supply pressure. In other embodiments, the fuel supply pressure may be intermittently at least 5 psig greater than the oxidant supply pressure. In some embodiments, the fuel supply pressure may be varied, and the variation may be at a substantially constant frequency, or based on the power output fuel cell system, or based on a parameter indicative of fuel cell performance. In other embodiments, the fuel supply pressure may be varied during different operational phases, such as during shut-down and/or start-up of the fuel cell system. In some embodiments, the fuel side of the reactant supply system is always closed, such as by having a fuel side of at least one fuel cell dead-ended. In other embodiments, the fuel side of the reactant supply system comprises a recirculation loop for recirculating the fuel stream through the stack. In still other embodiments, the fuel side of the reactant supply system comprises a purge valve which may be periodically opened to discharge a portion of the fuel stream from the stack. In still other embodiments, the fuel side of the reactant supply system may be closed at a plurality of locations, such as having the fuel side of each fuel cell dead-ended. In still further embodiments, the fuel cell system comprises a primary stack and a secondary stack fluidly connected to receive the fuel stream in series downstream of the primary stack, wherein a fuel passage of the secondary stack is dead-ended at least some of the time. These and other aspects of the present methods will be apparent upon reference to the accompanying drawings and following detailed description. BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE ACCOMPANYING DRAWINGS In the figures, identical reference numbers identify similar elements or acts. The sizes and relative positions of elements in the figures are not necessarily drawn to scale. For example, the shapes of various elements and angles are not drawn to scale, and some of these elements are arbitrarily enlarged and positioned to improve figure legibility. Further, the particular shapes of the elements, as drawn, are not intended to convey any information regarding the actual shape of the particular elements, and have been solely selected for ease of recognition in the figures. Figure 1 is an isometric, partially exploded, view of a fuel cell system including a fuel cell stack and controlling electronics. Figure 2 is a schematic diagram representing fuel flow through a cascaded fuel cell stack of the fuel cell system of Figure 1. Figure 3 is a graph showing the cell voltage over time for a fuel cell stack operated with fuel overpressures from 0 to 30 psig. Figure 4 is a graph showing the voltage of the individual cells as well as the stack voltage versus the fuel overpressure. Figure 5 is a graph showing the average cell voltage of the fuel cells of a fuel cell stack operated with fuel overpressure according to one embodiment of the present methods. DETAILED DESCRIPTION OF THE INVENTION In the following detailed description, certain specific details are set forth in order to provide a thorough understanding of various embodiments of the invention. However, one skilled in the art will understand that the invention may be practiced without these details. In other instances, well known structures associated with fuel cell stacks and fuel cell systems have not been described in detail to avoid unnecessarily obscuring the descriptions of the embodiments of the invention. Unless the context requires otherwise, throughout the specification and claims which follow, the word "comprise" and variations thereof, such as "comprises" and "comprising" are to be construed in an open, inclusive sense, that is as "including but not limited to". Figure 1 shows a portion of a fuel cell system 10, namely, a fuel cell stack 12 and an electronic fuel cell control system 14. Fuel cell stack 12 includes; a number of fuel cell assemblies 16 arranged between a pair of end plates 18a, 18b, one of the fuel cell assemblies 16 being partially removed from fuel cell stack 12 to better illustrate the structure of fuel cell assembly 16. Tie rods (not shown) extend between end plates 18a, 18b and cooperate with fastening nuts 17 to bias end plates 18a, 18b together by applying pressure to the various components to ensure good contact therebetween. Each fuel cell assembfy 16 includes a membrane electrode assembly 20 including two electrodes, the anode 22 and the cathode 24, separated by an ion exchange membrane 26. Electrodes 22, 24 can be formed from a porous, electrically conductive sheet material, such as carbon fiber paper or cloth, that is permeable to the reactants. Each of electrodes 22, 24 is coated on a surface adjacent to ion exchange membrane 26 with a catalyst 27, such as a thin layer of platinum, to render each electrode electrochemically active. Fuel cell assembly 16 also includes a pair of separators or flow field plates 28 sandwiching membrane electrode assembly 20. In the illustrated embodiment, each of flow field plates 28 includes one or more reactant passages 30 formed on a planar surface of flow field plate 28 adjacent an associated one of electrodes 22, 24 for carrying fuel to anode 22 and oxidant to cathode 24, respectively. (Reactant passage 30 on only one of flow field plates 28 is visible in Figure 1.) Reactant passages 30 that carry the oxidant also carry exhaust air and product water away from cathode 24. As will be described in more detail below, fuel stack 12 is designed to operate in a closed fuel supply mode, thus substantially all of the hydrogen fuel supplied to it during operation is consumed, and little if any hydrogen is carried away from the stack 12 in normal operation of system 10. Each flow field plate 28 may include a plurality of cooling channels 32 formed on the planar surface of the flow field plate 28 opposite the planar surface having reactant passage 30. When the stack is assembled, the cooling channels 32 of each adjacent fuel cell assembly 16 cooperate so that closed cooling channels 32 are formed between each membrane electrode assembly 20. Cooling channels 32 transmit a coolant fluid through fuel cell stack 12. Cooling channels 32 may be straight and parallel to each other, and traverse each plate 28 so that cooling channel inlets and outlets are located at respective edges of plate 28. While the illustrated fuel cell system includes two flow field plates 28 in each fuel cell assembly 16, the system may alternatively include a single bipolar flow field plate (not shown) between adjacent membrane electrode assemblies 20. In such systems, a channel on one side of the bipolar plate carries fuel to the anode of one adjacent membrane electrode assembly 20, while a channel on the other side of the plate carries oxidant to the cathode of another adjacent membrane electrode assembly 20. In such systems, additional flow field plates 28 having channels for carrying coolant (e.g., liquid or gas, such as, cooling air) can be spaced throughout fuel cell stacks 12, as needed to provide sufficient cooling of stack 12. End plate 18a includes a fuel stream inlet port (not shown) for introducing a supply fuel stream into fuel cell stack 12. End plate 18b includes a fuel stream outlet port 35 for discharging an exhaust fuel stream from fuel cell stack 12 that comprises primarily water and non-reactive components and impurities. Fuel stream outlet port 35 is normally closed with a valve in closed fuel supply system operation. Each fuel cell assembly 16 has openings formed therein to cooperate with corresponding openings in adjacent assemblies 16 to form internal fuel supply and exhaust manifolds (not shown) that extend the length of stack 12. The fuel stream inlet port is fluidly connected to fluid outlet port 35 via respective reactant passages 30 that are in fluid communication with the fuel supply and exhaust manifolds, respectively. End plate 18b includes an oxidant stream inlet port 37 for introducing supply air (oxidant stream) into fuel cell stack 12, and an oxidant stream outlet port 39 for discharging exhaust air from fuel cell stack 12. Each fuel cell assembly 16 has openings 31, 34, formed therein to cooperate with corresponding openings in adjacent fuel cell assemblies 16 to form oxidant supply and exhaust manifolds that extend the length of stack 12. Oxidant inlet port 37 is fluidly connected to the oxidant outlet port 39 via respective reactant passages 30 that are in fluid communication with oxidant supply and. exhaust manifolds, respectively. As shown in Figure 2, fuel may be directed through fuel cell stack 12 in a cascaded flow pattern. A first set 11 of fuel cell assemblies 16 are arranged so that fuel flows within the set in a concurrent parallel direction (represented by arrows 13) that is generally opposite the direction of the flow of coolant through fuel cell stack 12. Fuel flow through a next set 15 of two fuel cell assemblies 16 is in series with respect to the flow of fuel in the first set 11, and in a concurrent parallel direction within the set 15 (in a direction represented by arrows 17) that is generally concurrent with the direction of the flow of coolaat through fuel cell stack 12. Fuel flow through a final set 19 of two fuel cells assemblies 16 is in series with respect to the first and second sets 11,15, and in a concurrent parallel direction within the set 19 (in a direction represented by arrow 21), generally opposite the flow of coolant through fuel cell stack 12. The oxidant is supplied to each of the fuel cells in parallel, in the same general direction as the flow of coolant through fuel cell stack 12. In an alternate configuration, rather than "dead-ending" fuel cell stack 12, the s)'stem may comprise a second fuel cell stack which is dead-ended and which is downstream (with respect to the direction of reactant flow), and is fluidly connected to, fuel cell stack 12. In yet another alternate configuration, rather than dead-ending fuel cell stack 12 at one location (e.g., by closing fuel outlet port 35) as shown in Figure 1, fuel cell stack 12 may be dead-ended at a number of locations along reactant passages 30. For example, some or all of the individual fuel cell assemblies 16 may be dead-ended or fuel cell stack 12 may be divided into a number of sections, each of which is supplied with fuel and is dead-ended separately. Each membrane electrode assembly 20 is designed to produce a nominal potential difference between anode 22 and cathode 24. Reactants (hydrogen and air) are supplied to electrodes 22, 24 on either side of ion exchange membrane 26 through reactant passages 30. Hydrogen is supplied to anode 22, where platinum catalyst 27 promotes its separation into protons and electrons, which pass as useful electricity through an external circuit (not shown). On the opposite side of membrane electrode assembly 20, air flows through reactant passages 30 to cathode 24 where oxygen in the air reacts with protons passing through the ion exchange membrane 26 to produce product water. With continuing reference to Figure 1, electronic control system 14 comprises various electrical and electronic components on a circuit board 38 and various sensors 44 and actuators 46 distributed throughout fuel cell system 10. Circuit board 38 carries a microprocessor or microcontroller 40 that is appropriately programmed or configured to carry out fuel cell system operation. Microcontroller 40 can take the form of an Atmel AVR RISC microcontroller available from Atmel Corporation of San Jose, California. Electronic control system 14 also includes a persistent memory 42, such as an EEPROM portion of microcontroller 40 or as a discrete nonvolatile controller-readable media. Microcontroller 40 is coupled to receive input from sensors 44 and to provide output to actuators 46. The input and / or output can take the form of either digital and / or analog signals. A rechargeable battery 47 powers the electronic control system 14 until fuel cell stack 12 can provide sufficient power to the electronic control system 14. Microcontroller 40 is selectively couplable between fuel cell stack 12 and battery 47 for switching power during fuel cell system operation and / or to recharge battery 47 during fuel cell operation. Without being bound by theory, the conditions existing in fuel cell assembly 16 operating on air and having a closed fuel supply are described. Assuming steady state conditions, there is no net diffusion of nitrogen across membrane 26. Near the inlet of anode 22 the mol fraction of nitrogen in the fuel stream is low as a relatively small amount of nitrogen diffuses across membrane 26 and enters the fuel passages. As fuel is consumed along the length of anode 22 the mol fraction of nitrogen increases. Due to convective mass flow of nitrogen and the consumption of fuel in fuel cell assembly 16, the mol fraction of nitrogen near the outlet of anode 22 may be greater than the mol fraction of nitrogen in cathode 24, in which case nitrogen will back- diffuse across membrane 26 to the cathode side. At steady state the integral of the nitrogen concentration gradient across the membrane times the cell area over the inlet of the cell (driving diffusion from cathode to anode) equals the integral of the corresponding nitrogen concentration gradient times the cell area over the outlet of the cell (driving diffusion from anode to cathode). In a dead-ended system without anode exhaust recycling, the mol fraction of nitrogen near the outlet of anode 22 will exceed the mol fraction of nitrogen in air. Thus, a. nitrogen concentration gradient will exist in anode 22. The magnitude of the concentration gradient is affected by factors including the fuel velocity in the anode flow field and the fuel stoichiometry. Increasing the fuel velocity in anode 22 will increase the convective mass flow of nitrogen toward i:he outlet of anode 22, increasing the concentration gradient. Fuel velocity increases with factors such as the pressure drop associated with anode 22, increased operating pressure of fuel cell assembly 16 and high loads. Decreasing the fuel stoichiometry also increases the nitrogen concentration gradient. Indeed, at a fuel stoichiometry of I, essentially all of the fuel in anode 22 is consumed and the mol faction of nitrogen near the outlet of anode 22 approaches unit}'. If the anode exhaust is recycled periodically, or a portion of the exhaust is recycled, then the nitrogen concentration gradient will be lessened, but the nitrogen concentration near the outlet of anode 22 may still be greater than the cathode nitrogen concentration. With continuous recycle of the anode exhaust, the concentration gradient may be substantially eliminated, but the nitrogen concentration in the anode flow field will equal the nitrogen concentration in the cathode flow field. Diffused nitrogen impedes the reaction at anode 22 (due to dilution of the fuel) and ultimately may cause the performance of the fuel cell assembly 16 to drop to an unacceptable level. By maintaining the fuel supply pressure at a sufficiently high level according to the present methods, the mol fraction of the nitrogen is well below the mol fraction of the fuel, and there is sufficient fuel (e.g., hydrogen) to sustain the anode reaction. According to the present methods, during at least some periods of operation the fuel is supplied at an overpressure (i.e. the fuel overpressure is equal to the difference between the fuel supply pressure and the oxidant supply pressure to the fuel cell assembly) of at least 5 psig. Overpressures greater than 5 psig may also be of further benefit and may improve the performance and reliability of fuel cell system 10 for reasons in addition to overcoming nitrogen diffusion across membrane 26. For example, increased fuel supply pressures are known to improve catalyst activity. The magnitude of the fuel overpressure to be used according to the present methods may be limited by the components and configuration of fuel cell system 10, particularly the tolerance of the seals and membrane 26 to increased fuel overpressure. Temperature and other operating conditions may be optimized for particular stack configurations. For example, by employing the present methods, it may be possible to operate fuel cell system 10 at higher operating temperatures than would be practical if fuel cell system 10 was to be operated without the present methods. Increased operating temperatures may improve the performance of fuel cell systems having a closed fuel supply system by improving water management at the anode. While the foregoing discussion has been related to the diffusion of nitrogen into the anode space of fuel cells, it is understood that the same principles apply in respect of other inert or non-reactive components present in the oxidant stream that diffuse across the fuel cell membrane. In one embodiment of the present methods, fuel is continuously supplied to stack 12 at an overpressure of greater than 5 psig. In other embodiments, the fuel supply pressure may be varied, so that fuel is sometimes supplied at an overpressure of greater than 5 psig, while at other times the fuel is not supplied at an overpressure of greater than 5 psig. In still other embodiments, the fuel overpressure may be varied between a 5 psig overpressure and a greater overpressure. The variations may be of a constant frequency or intermittent (variable frequency), and may be either independent of or dependent on the transient operating conditions of fuel cell system 10. For example, the overpressure may be varied at predetermined intervals from the start of operation. In another embodiment, the use or the magnitude of fuel overpressure may be controlled by microcontroller 40 depending on the input received by sensors 44. In one embodiment, sensors 44 monitor one or more parameters indicative of stack or cell performance, such as the voltage of one or more cells, to e.g. detect when fuel starvation is occurring. Similarly, the use of or magnitude of overpressure may also be different during various operating phases of fuel cell system 10, such as during start-up or shut-down of fuel cell system 10. Similarly, the use of or magnitude of overpressure may be varied depending on the load on or power output of fuel cell system 10, such as during no-load or partial load conditions. For example, the overpressure may be lesser during no-load or partial load conditions than during full-load conditions. In addition, the rate of change of the load conditions may affect the desired overpressure, e.g. during transient conditions. As discussed above, due to the flow of fuel through the fuel passages as the fuel is consumed, the non-reactive components tend to accumulate near the; location(s) where fuel cell stack 12 is dead-ended. This may lead to unacceptable performance of the fuel cell assemblies 16 in the location. Accordingly, in further alternate embodiments, system configurations described above, such as systems which comprise a second fuel cell stack which is dead-ended or systems in which fuel cell stack 12 is dead-ended at a number of locations along the fuel flow path, may be employed to mitigate such effects. For example, in a system comprising a second fuel cell stack, which is dead-ended and which is fluidly connected downstream (with respect to the direction of reactant flew) to the primary fuel cell stack, the non-reactive components will tend to accumulate in the second "dead- ended" fuel cell stack. In this way, the performance of the primary fuel cell stack will be preserved. As described above, according to the present methods, fuel cell system 10 may be operated without the need for intermittent purges by maintaining the fuel supply pressure at a level sufficiently greater than the oxidant pressure. Thus, a purging system is not a required component of fuel cell system 10. However, it may be desirable for fuel cell system 10 to retain the ability to purge, and accordingly, in alternate embodiments, fuel cell system 10 may include purging equipment. For example, the final set 19 of fuel cell assemblies 16 in Figure 2 may comprise a purge cell portion of the fuel cell stack in which non-reactive components, including nitrogen, may be vented by opening a purge valve. (Although fuel cell stack 12 is designed to consume substantially all of the hydrogen fuel supplied to it during operation, traces of unreacted hydrogen may also be discharged through the fuel stream outlet port 35 (Figure 1) during a purge of fuel cell stack 12.) Accordingly, in some embodiments of the present methods, purging may be used in conjunction with fuel overpressure. For example, the purging system may be activated periodically, or as necessary, depending on system performance. See, for example, commonly assigned U.S. Patent Application Publication No. 2003/0022041, which is incorporated herein by reference in its entirety. In yet another embodiment of the present methods, overpressure may be used in conjunction with a continuous small bleed of the fuel stream from the anode side of fuel cell stack 12. See, for example, U.S. Patent Application Serial No. 10/253,390, which is incorporated herein by reference in its entirety. The bleed location(s) can be selected such that they are in the vicinity of where nitrogen is most likely to accumulate, such as where the stack and/or individual cell(s) are dead-ended, as discussed above. The following examples have been included to illustrate different embodiments and aspects of the present methods but they should not be construed as limiting in any way. EXAMPLE 1 The cell voltage of the individual cells of a Ballard fuel cell stack (10 cells) was monitored. The stack was closed on the fuel side, and was operated at a coolant inlet temperature of about 70°C, with the fuel cell stack producing about 150 mA/cm2. Air was supplied to the stack as the oxidant at a constant pressure of apppxiimately 10 psig, a stoichiometry of approximately l.S and a relative humidity of approximately 73%. (Stoichiometry is the ratio of fuel or oxidant supplied to that consumed in the generation of electrical power in the fuel cell.) Substantially pure hydrogen was supplied to the stack at a stoichiometry of about 1.0 and a relative humidity of approximately 67%. The pressure of the hydrogen supplied was varied from about 10 psig (fuel overpressure ~ 0 psig) to about 40 psig (fuel overpressure ~ 30 psig). The stack was not purged during the test period. Figure 3 shows the voltage of the individual cells over time as the fuel overpressure was varied. As shown in Figure 3, the stack operated continuously, without the need for fuel purges, for approximately 2 hours so long as the fuel pressure was at least 5 psig greater than the oxidant pressure (time = 0 to time =120 minutes). As can be seen from Figure 3, although the voltage of half of the cells was lower than the others during that period, the performance of the lower voltage cells was nonetheless stable. However, once the fuel overpressure was reduced below about 5 psig, the performance of some of the cells started to drop significantly. Figure 4 is an extract from the Figure 3 data, showing the voltage of the individual cells and the stack at the various fuel overpressures. Again, as can be seen from the figure, the cells were able to operate without any stack purging when the fuel overpressure was greater than about 5 psig. Their performance began to drop significantly once the fuel overpressure was reduced below 5 psig. EXAMPLE 2 The cell voltage of a 47 fuel cell NEXA™ stack was monitored. The stack was closed on the fuel side, and was operated at a coolant inlet temperature of about 65°C, v/ith the fuel cell stack producing about 432 mA/cm2. Air was supplied to the stack as the oxidant at a constant pressure of approximately 2.25 psig, a stoichiometry of approximately 2.0 and a relative humidity of approximately 90-95%. Substantially pure unhumidified hydrogen was supplied to the stack at a pressure of approximately 14.25 psig and a stoichiometry of about 1.0 (fuel overpressure ~ 12 psig). After approximately 64 hours, the coolant inlet temperature was increased to about 75°C and the stack was operated for approximately 2 additional hours, after which the test was stopped. The stack was not purged during the test period. Figure 5 shows the average cell voltage over time during the above test period (i.e. closed fuel side operation with substantially constant fuel overpressure). As shown in Figure 5, the stack operated continuously, without the need for fuel purges, for over 63 hours al a coolant inlet temperature of 65°C, and an additional 2 hours at a coolant inlet temperature of 75°C. As can be seen from Figure 5, increasing the coolant inlet temperature improved the average cell voltage. It can be advantageous to use the above described methods, involving use of a fuel overpressure, in fuel cell systems that are dead-ended on the fuel side but have a fuel recirculation loop. In such configurations the accumulation of nitrogen and non-reactive components on the anode side (in the fuel loop) can be mitigated by use of a fuel overpressure. The various embodiments described above and in the applications and patents incorporated herein by reference can be combined to provide further embodiments. The described methods can omit some acts and can add other acts, and can execute the acts in a different order than that illustrated, to achieve the advantages of the invention. These and other changes can be made to the invention in light of the above detailed description. In general, in the following claims, the terms used should not be construed to limit the invention to the specific embodiments disclosed in the specification, but should be construed to include all fuel cell systems, controllers and processors, actuators, and sensors that operate in accordance with the claims. Accordingly, the invention is not limited by the disclosure, but instead its scope is to be determined entirely by the following claims. WE CLAIM : 1. A method for operating a fuel cell system comprising at least one fuel cell stack, the stack comprising at least one fuel cell, the fuel cell system also comprising a reactant supply system, the reactant supply system comprising a fuel passage for directing a fuel stream through the stack and an oxidant passage for directing an oxidant stream through the stack, the method comprising : supplying the oxidant stream to the oxidant passage at an oxidant supply pressure ; and supplying the fuel stream to the fuel passage at a fuel supply pressure ; wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply pressure when a fuel side of the reactant supply system is closed. 2. The method as claimed in claim 1, wherein said at least one fuel cell is a solid polymer electrolyte fuel cell. 3. The method as claimed in claim 2, wherein the fuel stream is hydrogen and the oxidant stream is air. 4. The method as claimed in claim I. wherein during operation the fuel supply pressure is always at least 5 psig greater than the oxidant supply pressure. 5. The method as claimed in claim 4, wherein : the fuel supply pressure is varied, so that the fuel is sometimes supplied at an overpressure greater than 5 psig, and at other times at an over pressure not greater than 5 psig. 6. The method as claimed in claim 5, wherein the fuel supply pressure is varied at a substantially constant frequency. 7. The method as claimed in claim 5, wherein the fuel supply pressure is varied based on the power output of the fuel cell system. 8. The method as claimed in claim 5, wherein the fuel cell system comprises at least one sensor, and varying the fuel supply pressure comprises varying the fuel supply pressure based on an output of the sensor. 9. The method as claimed in claim 5, comprising : monitoring a parameter indicative of fuel cell performance, wherein the fuel supply pressure is varied based on the parameter indicative of fuel cell performance. 10. The method as claimed in claim 1, wherein the fuel supply pressure is varied, the fuel supply pressure being intermittently at least 5 psig greater than the oxidant supply pressure. 11. The method as claimed in claim 10, wherein the fuel supply pressure is varied at a substantially constant frequency. 12. The method as claimed in claim 10, wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply pressure during at least one of a shut-down phase and a start-up phase of the fuel cell system. 13. The method as claimed in claim 10, wherein the fuel supply pressure is varied based on the power output of the fuel cell system. 14. The method as claimed in claim 10, wherein the fuel cell system comprises at least one sensor, and varying the fuel supply pressure comprises varying the fuel supply pressure based on an output of the sensor. 15. The method as claimed in claim 10, comprising : monitoring a parameter indicative of fuel cell performance, wherein the fuel supply pressure is varied based on the parameter indicative of fuel cell performance. 16. The method as claimed in claim 1, wherein the fuel side of the reactant supply system is always closed. 17. The method as claimed in claim 1, wherein the fuel side of the reactant supply system comprises a purge valve which is periodically opened to discharge a portion of the fuel stream from the stack. 18. The method as claimed in claim 1, wherein the fuel side of the reactant supply system also comprises a recirculation loop and the method comprises recirculating the fuel stream through the stack. 19. The method as claimed in claim 18, wherein the fuel side of the reactant supply system also comprises a purge valve, and the method comprises periodically opening the purge valve to discharge a portion of the fuel stream from the stack. 20. The method as claimed in claim 1, wherein the fuel side of the reactant supply system is closed at a plurality of locations. 21. The method as claimed in claim 1, wherein the stack comprises a plurality of fuel cells, and a fuel side of at least one fuel cell is dead-ended. 22. The method as claimed in claim 21, wherein the fuel side of each fuel cell is dead- ended. 23. The method as claimed in claim I, wherein the fuel cell system comprises a primary stack and a secondary stack fluidly connected to receive the fuel stream in series downstream of the primary stack, wherein a fuel passage of the secondary stack is dead- ended at least some of the time. 24. The method as claimed in claim 1, wherein the fuel supply pressure is between about 5 psig and 30 psig greater than the oxidant supply pressure. 25. The method as claimed in claim 1, wherein the fuel supply pressure is at least 10 psig greater than the oxidant supply pressure. There is disclosed a method for operating a fuel cell system (10) comprising at least one fuel cell stack (12), the stack comprising at least one fuel cell, the fuel cell system (10) also comprising a reactant supply system, the reactant supply system comprising a fuel passage for directing a fuel stream through the stack (12) and an oxidant passage for directing an oxidant stream through the stack (12), the method comprising : supplying the oxidant stream to the oxidant passage at an oxidant supply pressure ; and supplying the fuel stream to the fuel passage at a fuel supply pressure ; wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply pressure when a fuel sid of the reactant supply system is closed.

Full Text

A METHOD FOR OPERATING A FUEL CELL SYSTEM
BACKGROUND OF THE INVENTION
Field of the Invention
The present invention relates to fuel cells and, more particularly, to a method of
operating a fuel cell system having closed fuel supply systems.
Description of the Related Art
Electrochemical fuel cells convert fuel and oxidant to electricity. Solid polymer
electrochemical fuel cells generally employ a membrane electrode assembly ("MEA")
which comprises an ion exchange membrane or solid polymer electrolyte disposed
between two electrodes typically comprising a layer of porous, electrically conductive
sheet material, such as carbon fiber paper or carbon cloth. The MEA contains a layer of
catalyst, typically in the form of finely comminuted platinum, at each
membrane/electrode interface to induce the desired electrochemical reaction. In operation
the electrodes are electrically coupled to provide a circuit for conducting electrons
between the electrodes through an external circuit. Typically, a number of MEAs are
serially coupled electrically to form a fuel cell stack having a desired power output.
In typical fuel cells, the MEA is disposed between two electrically conductive
fluid flow field plates or separator plates. Fluid flow field plates have at least one flow
passage formed in at least one of the major planar surfaces thereof. The flow
passages direct the fuel and oxidant to the respective electrodes, namely, the anode on the
fuel side and the cathode on the oxidant side. The fluid flow field plates act as current
collectors, provide support for the electrodes, provide access channels or passages for the
fuel and oxidant to the respective anode and cathode surfaces, and provide passages for the
removal of reaction products, such as water, formed during operation of the cell.
Certain fuel cells are designed to operate in a closed mode on one or both
reactants. Closed reactant supply systems include dead-ended configurations in which a
reactant flow passage is generally closed, as well as systems employing closed-loop
recirculation of the reactant exhaust stream from the fuel cell outlet to the fuel cell inlet and
though the fuel cell with the addition of fresh reactant. In these situations the reactant used
on the closed side is generally substantially pure. Typically a purge valve (which is
normally closed in closed system operation) is provided somewhere in the reactant flow
passage for periodic venting of accumulations of non-reactive components, which can build
up in the reactant passages in closed system operation. In conventional fuel cell purge
systems the purge valve is opened from time to time, for example, manually or at regular
fixed time intervals. Alternatively a purge is triggered, for example, when the voltage or
electrical output of one or more cells in a stack falls below a predetermined threshold value
(see, for example, GB Patent No. 1 223 941), or when there is a predetermined decrease in
electrical power output (see, for example, US Patent No. 3,553,026), or after the fuel cell
has expended a preselected number of ampere-hours (see, for example, US Patent No.
3,697,325). The reactant flow path through the fuel cell stack can be configured so that
non-reactive components tend to accumulate first in just one or a few fuel cells of the stack,
rather than in the outlet region of each cell in the stack. The purge system may be
controlled via a controller (see, for example, commonly assigned U.S. Patent Application
Publication No. 2003/0022041).
However, although purging can improve performance of fuel cells having closed
reactant supply systems, it wastes valuable fuel and increases the parasitic load on the
system since purging equipment is required. Furthermore, the release of hydrogen into the
ambient environment may be undesirable. Accordingly, there remains a need for improved
methods of operating fuel cells having closed reactant supply systems for which purging
is not necessary.
BRIEF SUMMARY OF THE INVENTION
The present methods relate to fuel cells and, more particularly, to methods of
operating fuel cells having closed fuel supply systems.
In one embodiment, a method for operating a fuel cell system comprises at least
one fuel cell stack, the stack comprising at least one fuel cell, the fuel cell system also
comprising a reactant supply system, the reactant supply system comprising a fuel
passage for directing a fuel stream through the stack and an oxidant passage for directing
an oxidant stream through the stack, the method comprising : supplying the oxidant
stream to the oxidant passage at an oxidant supply pressure: and supplying the fuel stream
to the fuel passage at a fuel supply pressure; wherein the fuel supply pressure is at least 5
psig greater than the oxidant supply pressure when a fuel side of the reactant supply
system is closed.
A person skilled in the art to which the present invention relates can select the
oxidant supply pressure and fuel supply pressure depending on the oxidant and fuel
supply used, taking care to see that the fuel supply pressure is at least 5 psig greater than
the oxidant supply pressure when a fuel side of the reactant supply system is closed.
In some embodiments, the fuel cell may be a solid polymer electrolyte fuel cell,
and the reactant streams hydrogen and air.
In some embodiments, during operation the fuel supply pressure is always at least
5 psig greater than the oxidant supply pressure, and may be between about 5 psig and 30
psig greater than the oxidant supply pressure. In other embodiments, the fuel supply
pressure may be intermittently at least 5 psig greater than the oxidant supply pressure.
In some embodiments, the fuel supply pressure may be varied, and the variation
may be at a substantially constant frequency, or based on the power output fuel cell
system, or based on a parameter indicative of fuel cell performance. In other
embodiments, the fuel supply pressure may be varied during different operational phases,
such as during shut-down and/or start-up of the fuel cell system.
In some embodiments, the fuel side of the reactant supply system is always closed,
such as by having a fuel side of at least one fuel cell dead-ended. In other embodiments,
the fuel side of the reactant supply system comprises a recirculation loop for recirculating
the fuel stream through the stack. In still other embodiments, the fuel side of the reactant
supply system comprises a purge valve which may be periodically opened to discharge a
portion of the fuel stream from the stack. In still other embodiments, the fuel side of the
reactant supply system may be closed at a plurality of locations, such as having the fuel
side of each fuel cell dead-ended. In still further embodiments, the fuel cell system
comprises a primary stack and a secondary stack fluidly connected to receive the fuel
stream in series downstream of the primary stack, wherein a fuel passage of the secondary
stack is dead-ended at least some of the time.
These and other aspects of the present methods will be apparent upon reference to
the accompanying drawings and following detailed description.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE ACCOMPANYING
DRAWINGS
In the figures, identical reference numbers identify similar elements or acts. The
sizes and relative positions of elements in the figures are not necessarily drawn to scale.
For example, the shapes of various elements and angles are not drawn to scale, and some
of these elements are arbitrarily enlarged and positioned to improve figure legibility.
Further, the particular shapes of the elements, as drawn, are not intended to convey any
information regarding the actual shape of the particular elements, and have been solely
selected for ease of recognition in the figures.
Figure 1 is an isometric, partially exploded, view of a fuel cell system including a
fuel cell stack and controlling electronics.
Figure 2 is a schematic diagram representing fuel flow through a cascaded fuel
cell stack of the fuel cell system of Figure 1.
Figure 3 is a graph showing the cell voltage over time for a fuel cell stack
operated with fuel overpressures from 0 to 30 psig.
Figure 4 is a graph showing the voltage of the individual cells as well as the
stack voltage versus the fuel overpressure.
Figure 5 is a graph showing the average cell voltage of the fuel cells of a
fuel cell stack operated with fuel overpressure according to one embodiment of the present
methods.
DETAILED DESCRIPTION OF THE INVENTION
In the following detailed description, certain specific details are set forth in
order to provide a thorough understanding of various embodiments of the invention.
However, one skilled in the art will understand that the invention may be practiced without
these details. In other instances, well known structures associated with fuel cell stacks and
fuel cell systems have not been described in detail to avoid unnecessarily obscuring the
descriptions of the embodiments of the invention.
Unless the context requires otherwise, throughout the specification and
claims which follow, the word "comprise" and variations thereof, such as "comprises" and
"comprising" are to be construed in an open, inclusive sense, that is as "including but not
limited to".
Figure 1 shows a portion of a fuel cell system 10, namely, a fuel cell stack
12 and an electronic fuel cell control system 14. Fuel cell stack 12 includes; a number of
fuel cell assemblies 16 arranged between a pair of end plates 18a, 18b, one of the fuel cell
assemblies 16 being partially removed from fuel cell stack 12 to better illustrate the
structure of fuel cell assembly 16. Tie rods (not shown) extend between end plates 18a,
18b and cooperate with fastening nuts 17 to bias end plates 18a, 18b together by applying
pressure to the various components to ensure good contact therebetween.
Each fuel cell assembfy 16 includes a membrane electrode assembly 20
including two electrodes, the anode 22 and the cathode 24, separated by an ion exchange
membrane 26. Electrodes 22, 24 can be formed from a porous, electrically conductive
sheet material, such as carbon fiber paper or cloth, that is permeable to the reactants. Each
of electrodes 22, 24 is coated on a surface adjacent to ion exchange membrane 26 with a
catalyst 27, such as a thin layer of platinum, to render each electrode electrochemically
active.
Fuel cell assembly 16 also includes a pair of separators or flow field plates
28 sandwiching membrane electrode assembly 20. In the illustrated embodiment, each of
flow field plates 28 includes one or more reactant passages 30 formed on a planar surface
of flow field plate 28 adjacent an associated one of electrodes 22, 24 for carrying fuel to
anode 22 and oxidant to cathode 24, respectively. (Reactant passage 30 on only one of
flow field plates 28 is visible in Figure 1.) Reactant passages 30 that carry the oxidant also
carry exhaust air and product water away from cathode 24. As will be described in more
detail below, fuel stack 12 is designed to operate in a closed fuel supply mode, thus
substantially all of the hydrogen fuel supplied to it during operation is consumed, and little
if any hydrogen is carried away from the stack 12 in normal operation of system 10.
Each flow field plate 28 may include a plurality of cooling channels 32
formed on the planar surface of the flow field plate 28 opposite the planar surface having
reactant passage 30. When the stack is assembled, the cooling channels 32 of each adjacent
fuel cell assembly 16 cooperate so that closed cooling channels 32 are formed between
each membrane electrode assembly 20. Cooling channels 32 transmit a coolant fluid
through fuel cell stack 12. Cooling channels 32 may be straight and parallel to each other,
and traverse each plate 28 so that cooling channel inlets and outlets are located at
respective edges of plate 28.
While the illustrated fuel cell system includes two flow field plates 28 in
each fuel cell assembly 16, the system may alternatively include a single bipolar flow field
plate (not shown) between adjacent membrane electrode assemblies 20. In such systems, a
channel on one side of the bipolar plate carries fuel to the anode of one adjacent membrane
electrode assembly 20, while a channel on the other side of the plate carries oxidant to the
cathode of another adjacent membrane electrode assembly 20. In such systems, additional
flow field plates 28 having channels for carrying coolant (e.g., liquid or gas, such as,
cooling air) can be spaced throughout fuel cell stacks 12, as needed to provide sufficient
cooling of stack 12.
End plate 18a includes a fuel stream inlet port (not shown) for introducing a
supply fuel stream into fuel cell stack 12. End plate 18b includes a fuel stream outlet port
35 for discharging an exhaust fuel stream from fuel cell stack 12 that comprises primarily
water and non-reactive components and impurities. Fuel stream outlet port 35 is normally
closed with a valve in closed fuel supply system operation.
Each fuel cell assembly 16 has openings formed therein to cooperate with
corresponding openings in adjacent assemblies 16 to form internal fuel supply and exhaust
manifolds (not shown) that extend the length of stack 12. The fuel stream inlet port is
fluidly connected to fluid outlet port 35 via respective reactant passages 30 that are in fluid
communication with the fuel supply and exhaust manifolds, respectively.
End plate 18b includes an oxidant stream inlet port 37 for introducing
supply air (oxidant stream) into fuel cell stack 12, and an oxidant stream outlet port 39 for
discharging exhaust air from fuel cell stack 12. Each fuel cell assembly 16 has openings
31, 34, formed therein to cooperate with corresponding openings in adjacent fuel cell
assemblies 16 to form oxidant supply and exhaust manifolds that extend the length of stack
12. Oxidant inlet port 37 is fluidly connected to the oxidant outlet port 39 via respective
reactant passages 30 that are in fluid communication with oxidant supply and. exhaust
manifolds, respectively.
As shown in Figure 2, fuel may be directed through fuel cell stack 12 in a
cascaded flow pattern. A first set 11 of fuel cell assemblies 16 are arranged so that fuel
flows within the set in a concurrent parallel direction (represented by arrows 13) that is
generally opposite the direction of the flow of coolant through fuel cell stack 12. Fuel flow
through a next set 15 of two fuel cell assemblies 16 is in series with respect to the flow of
fuel in the first set 11, and in a concurrent parallel direction within the set 15 (in a direction
represented by arrows 17) that is generally concurrent with the direction of the flow of
coolaat through fuel cell stack 12. Fuel flow through a final set 19 of two fuel cells
assemblies 16 is in series with respect to the first and second sets 11,15, and in a
concurrent parallel direction within the set 19 (in a direction represented by arrow 21),
generally opposite the flow of coolant through fuel cell stack 12. The oxidant is supplied
to each of the fuel cells in parallel, in the same general direction as the flow of coolant
through fuel cell stack 12.
In an alternate configuration, rather than "dead-ending" fuel cell stack 12,
the s)'stem may comprise a second fuel cell stack which is dead-ended and which is
downstream (with respect to the direction of reactant flow), and is fluidly connected to, fuel
cell stack 12. In yet another alternate configuration, rather than dead-ending fuel cell stack
12 at one location (e.g., by closing fuel outlet port 35) as shown in Figure 1, fuel cell stack
12 may be dead-ended at a number of locations along reactant passages 30. For example,
some or all of the individual fuel cell assemblies 16 may be dead-ended or fuel cell stack
12 may be divided into a number of sections, each of which is supplied with fuel and is
dead-ended separately.
Each membrane electrode assembly 20 is designed to produce a nominal
potential difference between anode 22 and cathode 24. Reactants (hydrogen and air) are
supplied to electrodes 22, 24 on either side of ion exchange membrane 26 through reactant
passages 30. Hydrogen is supplied to anode 22, where platinum catalyst 27 promotes its
separation into protons and electrons, which pass as useful electricity through an external
circuit (not shown). On the opposite side of membrane electrode assembly 20, air flows
through reactant passages 30 to cathode 24 where oxygen in the air reacts with protons
passing through the ion exchange membrane 26 to produce product water.
With continuing reference to Figure 1, electronic control system 14
comprises various electrical and electronic components on a circuit board 38 and various
sensors 44 and actuators 46 distributed throughout fuel cell system 10. Circuit board 38
carries a microprocessor or microcontroller 40 that is appropriately programmed or
configured to carry out fuel cell system operation. Microcontroller 40 can take the form of
an Atmel AVR RISC microcontroller available from Atmel Corporation of San Jose,
California. Electronic control system 14 also includes a persistent memory 42, such as an
EEPROM portion of microcontroller 40 or as a discrete nonvolatile controller-readable
media.
Microcontroller 40 is coupled to receive input from sensors 44 and to provide output to actuators 46.
The input and / or output can take the form of either digital and / or analog signals. A rechargeable battery 47
powers the electronic control system 14 until fuel cell stack 12 can provide sufficient power to the electronic
control system 14. Microcontroller 40 is selectively couplable between fuel cell stack 12 and battery 47 for
switching power during fuel cell system operation and / or to recharge battery 47 during fuel cell operation.
Without being bound by theory, the conditions existing in fuel cell assembly 16 operating on air and
having a closed fuel supply are described. Assuming steady state conditions, there is no net diffusion of
nitrogen across membrane 26. Near the inlet of anode 22 the mol fraction of nitrogen in the fuel stream is low
as a relatively small amount of nitrogen diffuses across membrane 26 and enters the fuel passages. As fuel is
consumed along the length of anode 22 the mol fraction of nitrogen increases. Due to convective mass flow
of nitrogen and the consumption of fuel in fuel cell assembly 16, the mol fraction of nitrogen near the outlet
of anode 22 may be greater than the mol fraction of nitrogen in cathode 24, in which case nitrogen will back-
diffuse across membrane 26 to the cathode side. At steady state the integral of the nitrogen concentration
gradient across the membrane times the cell area over the inlet of the cell (driving diffusion from cathode to
anode) equals the integral of the corresponding nitrogen concentration gradient times the cell area over the
outlet of the cell (driving diffusion from anode to cathode).
In a dead-ended system without anode exhaust recycling, the mol fraction of nitrogen near
the outlet of anode 22 will exceed the mol fraction of nitrogen in air. Thus, a. nitrogen concentration
gradient will exist in anode 22. The magnitude of the concentration gradient is affected by factors
including the fuel velocity in the anode flow field and the fuel stoichiometry. Increasing the fuel
velocity in anode 22 will increase the convective mass flow of nitrogen toward i:he outlet of anode 22,
increasing the concentration gradient. Fuel velocity increases with factors such as the pressure drop
associated with anode 22, increased operating pressure of fuel cell assembly 16 and high loads.
Decreasing the fuel stoichiometry also increases the nitrogen concentration gradient. Indeed, at a fuel
stoichiometry of I, essentially all of the fuel in anode 22 is consumed and the mol faction
of nitrogen near the outlet of anode 22 approaches unit}'.
If the anode exhaust is recycled periodically, or a portion of the exhaust is
recycled, then the nitrogen concentration gradient will be lessened, but the nitrogen
concentration near the outlet of anode 22 may still be greater than the cathode nitrogen
concentration. With continuous recycle of the anode exhaust, the concentration gradient
may be substantially eliminated, but the nitrogen concentration in the anode flow field will
equal the nitrogen concentration in the cathode flow field.
Diffused nitrogen impedes the reaction at anode 22 (due to dilution of the
fuel) and ultimately may cause the performance of the fuel cell assembly 16 to drop to an
unacceptable level.
By maintaining the fuel supply pressure at a sufficiently high level
according to the present methods, the mol fraction of the nitrogen is well below the mol
fraction of the fuel, and there is sufficient fuel (e.g., hydrogen) to sustain the anode
reaction. According to the present methods, during at least some periods of operation the
fuel is supplied at an overpressure (i.e. the fuel overpressure is equal to the difference
between the fuel supply pressure and the oxidant supply pressure to the fuel cell assembly)
of at least 5 psig. Overpressures greater than 5 psig may also be of further benefit and may
improve the performance and reliability of fuel cell system 10 for reasons in addition to
overcoming nitrogen diffusion across membrane 26. For example, increased fuel supply
pressures are known to improve catalyst activity. The magnitude of the fuel overpressure
to be used according to the present methods may be limited by the components and
configuration of fuel cell system 10, particularly the tolerance of the seals and membrane
26 to increased fuel overpressure.
Temperature and other operating conditions may be optimized for particular
stack configurations. For example, by employing the present methods, it may be possible
to operate fuel cell system 10 at higher operating temperatures than would be practical if
fuel cell system 10 was to be operated without the present methods. Increased operating
temperatures may improve the performance of fuel cell systems having a closed fuel supply
system by improving water management at the anode.
While the foregoing discussion has been related to the diffusion of nitrogen
into the anode space of fuel cells, it is understood that the same principles apply in respect
of other inert or non-reactive components present in the oxidant stream that diffuse across
the fuel cell membrane.
In one embodiment of the present methods, fuel is continuously supplied to
stack 12 at an overpressure of greater than 5 psig. In other embodiments, the fuel supply
pressure may be varied, so that fuel is sometimes supplied at an overpressure of greater
than 5 psig, while at other times the fuel is not supplied at an overpressure of greater than 5
psig. In still other embodiments, the fuel overpressure may be varied between a 5 psig
overpressure and a greater overpressure. The variations may be of a constant frequency or
intermittent (variable frequency), and may be either independent of or dependent on the
transient operating conditions of fuel cell system 10. For example, the overpressure may
be varied at predetermined intervals from the start of operation. In another embodiment,
the use or the magnitude of fuel overpressure may be controlled by microcontroller 40
depending on the input received by sensors 44. In one embodiment, sensors 44 monitor
one or more parameters indicative of stack or cell performance, such as the voltage of one
or more cells, to e.g. detect when fuel starvation is occurring. Similarly, the use of or
magnitude of overpressure may also be different during various operating phases of fuel
cell system 10, such as during start-up or shut-down of fuel cell system 10. Similarly, the
use of or magnitude of overpressure may be varied depending on the load on or power
output of fuel cell system 10, such as during no-load or partial load conditions. For
example, the overpressure may be lesser during no-load or partial load conditions than
during full-load conditions. In addition, the rate of change of the load conditions may
affect the desired overpressure, e.g. during transient conditions.
As discussed above, due to the flow of fuel through the fuel passages as the
fuel is consumed, the non-reactive components tend to accumulate near the; location(s)
where fuel cell stack 12 is dead-ended. This may lead to unacceptable performance of the
fuel cell assemblies 16 in the location. Accordingly, in further alternate embodiments,
system configurations described above, such as systems which comprise a second fuel cell
stack which is dead-ended or systems in which fuel cell stack 12 is dead-ended at a number
of locations along the fuel flow path, may be employed to mitigate such effects. For
example, in a system comprising a second fuel cell stack, which is dead-ended and which is
fluidly connected downstream (with respect to the direction of reactant flew) to the primary
fuel cell stack, the non-reactive components will tend to accumulate in the second "dead-
ended" fuel cell stack. In this way, the performance of the primary fuel cell stack will be
preserved.
As described above, according to the present methods, fuel cell system 10
may be operated without the need for intermittent purges by maintaining the fuel supply
pressure at a level sufficiently greater than the oxidant pressure. Thus, a purging system is
not a required component of fuel cell system 10. However, it may be desirable for fuel cell
system 10 to retain the ability to purge, and accordingly, in alternate embodiments, fuel cell
system 10 may include purging equipment. For example, the final set 19 of fuel cell
assemblies 16 in Figure 2 may comprise a purge cell portion of the fuel cell stack in which
non-reactive components, including nitrogen, may be vented by opening a purge valve.
(Although fuel cell stack 12 is designed to consume substantially all of the hydrogen fuel
supplied to it during operation, traces of unreacted hydrogen may also be discharged
through the fuel stream outlet port 35 (Figure 1) during a purge of fuel cell stack 12.)
Accordingly, in some embodiments of the present methods, purging may be
used in conjunction with fuel overpressure. For example, the purging system may be
activated periodically, or as necessary, depending on system performance. See, for
example, commonly assigned U.S. Patent Application Publication No. 2003/0022041,
which is incorporated herein by reference in its entirety. In yet another embodiment of the
present methods, overpressure may be used in conjunction with a continuous small bleed of
the fuel stream from the anode side of fuel cell stack 12. See, for example, U.S. Patent
Application Serial No. 10/253,390, which is incorporated herein by reference in its entirety.
The bleed location(s) can be selected such that they are in the vicinity of where nitrogen is
most likely to accumulate, such as where the stack and/or individual cell(s) are dead-ended,
as discussed above.
The following examples have been included to illustrate different
embodiments and aspects of the present methods but they should not be construed as
limiting in any way.
EXAMPLE 1
The cell voltage of the individual cells of a Ballard fuel cell stack (10 cells)
was monitored. The stack was closed on the fuel side, and was operated at a coolant inlet
temperature of about 70°C, with the fuel cell stack producing about 150 mA/cm2. Air was
supplied to the stack as the oxidant at a constant pressure of apppxiimately 10 psig, a
stoichiometry of approximately l.S and a relative humidity of approximately 73%.
(Stoichiometry is the ratio of fuel or oxidant supplied to that consumed in the generation of
electrical power in the fuel cell.) Substantially pure hydrogen was supplied to the stack at a
stoichiometry of about 1.0 and a relative humidity of approximately 67%. The pressure of
the hydrogen supplied was varied from about 10 psig (fuel overpressure ~ 0 psig) to about
40 psig (fuel overpressure ~ 30 psig). The stack was not purged during the test period.
Figure 3 shows the voltage of the individual cells over time as the fuel
overpressure was varied. As shown in Figure 3, the stack operated continuously, without
the need for fuel purges, for approximately 2 hours so long as the fuel pressure was at least
5 psig greater than the oxidant pressure (time = 0 to time =120 minutes). As can be seen
from Figure 3, although the voltage of half of the cells was lower than the others during
that period, the performance of the lower voltage cells was nonetheless stable. However,
once the fuel overpressure was reduced below about 5 psig, the performance of some of the
cells started to drop significantly.
Figure 4 is an extract from the Figure 3 data, showing the voltage of the
individual cells and the stack at the various fuel overpressures. Again, as can be seen from
the figure, the cells were able to operate without any stack purging when the fuel
overpressure was greater than about 5 psig. Their performance began to drop significantly
once the fuel overpressure was reduced below 5 psig.
EXAMPLE 2
The cell voltage of a 47 fuel cell NEXA™ stack was monitored. The stack
was closed on the fuel side, and was operated at a coolant inlet temperature of about 65°C,
v/ith the fuel cell stack producing about 432 mA/cm2. Air was supplied to the stack as the
oxidant at a constant pressure of approximately 2.25 psig, a stoichiometry of approximately
2.0 and a relative humidity of approximately 90-95%. Substantially pure unhumidified
hydrogen was supplied to the stack at a pressure of approximately 14.25 psig and a
stoichiometry of about 1.0 (fuel overpressure ~ 12 psig). After approximately 64 hours, the
coolant inlet temperature was increased to about 75°C and the stack was operated for
approximately 2 additional hours, after which the test was stopped. The stack was not
purged during the test period.
Figure 5 shows the average cell voltage over time during the above test
period (i.e. closed fuel side operation with substantially constant fuel overpressure). As
shown in Figure 5, the stack operated continuously, without the need for fuel purges, for
over 63 hours al a coolant inlet temperature of 65°C, and an additional 2 hours at a coolant
inlet temperature of 75°C. As can be seen from Figure 5, increasing the coolant inlet
temperature improved the average cell voltage.
It can be advantageous to use the above described methods, involving use of
a fuel overpressure, in fuel cell systems that are dead-ended on the fuel side but have a fuel
recirculation loop. In such configurations the accumulation of nitrogen and non-reactive
components on the anode side (in the fuel loop) can be mitigated by use of a fuel
overpressure.
The various embodiments described above and in the applications and
patents incorporated herein by reference can be combined to provide further embodiments.
The described methods can omit some acts and can add other acts, and can execute the acts
in a different order than that illustrated, to achieve the advantages of the invention.
These and other changes can be made to the invention in light of the above
detailed description. In general, in the following claims, the terms used should not be
construed to limit the invention to the specific embodiments disclosed in the specification,
but should be construed to include all fuel cell systems, controllers and processors,
actuators, and sensors that operate in accordance with the claims. Accordingly, the
invention is not limited by the disclosure, but instead its scope is to be determined entirely
by the following claims.
WE CLAIM :
1. A method for operating a fuel cell system comprising at least one fuel cell stack,
the stack comprising at least one fuel cell, the fuel cell system also comprising a reactant
supply system, the reactant supply system comprising a fuel passage for directing a fuel
stream through the stack and an oxidant passage for directing an oxidant stream through
the stack, the method comprising :
supplying the oxidant stream to the oxidant passage at an oxidant supply
pressure ; and
supplying the fuel stream to the fuel passage at a fuel supply pressure ;
wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply
pressure when a fuel side of the reactant supply system is closed.
2. The method as claimed in claim 1, wherein said at least one fuel cell is a solid
polymer electrolyte fuel cell.
3. The method as claimed in claim 2, wherein the fuel stream is hydrogen and the
oxidant stream is air.
4. The method as claimed in claim I. wherein during operation the fuel supply
pressure is always at least 5 psig greater than the oxidant supply pressure.
5. The method as claimed in claim 4, wherein :
the fuel supply pressure is varied, so that the fuel is sometimes supplied at an
overpressure greater than 5 psig, and at other times at an over pressure not greater than 5
psig.
6. The method as claimed in claim 5, wherein the fuel supply pressure is varied at a
substantially constant frequency.
7. The method as claimed in claim 5, wherein the fuel supply pressure is varied
based on the power output of the fuel cell system.
8. The method as claimed in claim 5, wherein the fuel cell system comprises at least
one sensor, and varying the fuel supply pressure comprises varying the fuel supply
pressure based on an output of the sensor.
9. The method as claimed in claim 5, comprising :
monitoring a parameter indicative of fuel cell performance,
wherein the fuel supply pressure is varied based on the parameter indicative of
fuel cell performance.
10. The method as claimed in claim 1, wherein the fuel supply pressure is varied, the
fuel supply pressure being intermittently at least 5 psig greater than the oxidant supply
pressure.
11. The method as claimed in claim 10, wherein the fuel supply pressure is varied at a
substantially constant frequency.
12. The method as claimed in claim 10, wherein the fuel supply pressure is at least 5
psig greater than the oxidant supply pressure during at least one of a shut-down phase and
a start-up phase of the fuel cell system.
13. The method as claimed in claim 10, wherein the fuel supply pressure is varied
based on the power output of the fuel cell system.
14. The method as claimed in claim 10, wherein the fuel cell system comprises at
least one sensor, and varying the fuel supply pressure comprises varying the fuel supply
pressure based on an output of the sensor.
15. The method as claimed in claim 10, comprising :
monitoring a parameter indicative of fuel cell performance,
wherein the fuel supply pressure is varied based on the parameter indicative of
fuel cell performance.
16. The method as claimed in claim 1, wherein the fuel side of the reactant supply
system is always closed.
17. The method as claimed in claim 1, wherein the fuel side of the reactant supply
system comprises a purge valve which is periodically opened to discharge a portion of the
fuel stream from the stack.
18. The method as claimed in claim 1, wherein the fuel side of the reactant supply
system also comprises a recirculation loop and the method comprises recirculating the
fuel stream through the stack.
19. The method as claimed in claim 18, wherein the fuel side of the reactant supply
system also comprises a purge valve, and the method comprises periodically opening the
purge valve to discharge a portion of the fuel stream from the stack.
20. The method as claimed in claim 1, wherein the fuel side of the reactant supply
system is closed at a plurality of locations.
21. The method as claimed in claim 1, wherein the stack comprises a plurality of fuel
cells, and a fuel side of at least one fuel cell is dead-ended.
22. The method as claimed in claim 21, wherein the fuel side of each fuel cell is dead-
ended.
23. The method as claimed in claim I, wherein the fuel cell system comprises a
primary stack and a secondary stack fluidly connected to receive the fuel stream in series
downstream of the primary stack, wherein a fuel passage of the secondary stack is dead-
ended at least some of the time.
24. The method as claimed in claim 1, wherein the fuel supply pressure is between
about 5 psig and 30 psig greater than the oxidant supply pressure.
25. The method as claimed in claim 1, wherein the fuel supply pressure is at least 10
psig greater than the oxidant supply pressure.
There is disclosed a method for operating a fuel cell system (10) comprising at
least one fuel cell stack (12), the stack comprising at least one fuel cell, the fuel cell
system (10) also comprising a reactant supply system, the reactant supply system
comprising a fuel passage for directing a fuel stream through the stack (12) and an
oxidant passage for directing an oxidant stream through the stack (12), the method
comprising :
supplying the oxidant stream to the oxidant passage at an oxidant supply
pressure ; and
supplying the fuel stream to the fuel passage at a fuel supply pressure ;
wherein the fuel supply pressure is at least 5 psig greater than the oxidant supply
pressure when a fuel sid of the reactant supply system is closed.

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Patent Number

223378

Indian Patent Application Number

01816/KOLNP/2005

PG Journal Number

37/2008

Publication Date

12-Sep-2008

Grant Date

10-Sep-2008

Date of Filing

13-Sep-2005

Name of Patentee

BALLARD POWER SYSTEMS INC.

Applicant Address

4343 NORTH FRASER WAY, BURNABY, BRITISH COLUMBIA V5J 5J9

Inventors:

#	Inventor's Name	Inventor's Address
1	SUMMERS, DAVID	2851 WEST 7TH AVENUE, VANCOUVER, BRITISH COLUMBIA V6K 1Z5
2	HASS, HERWIG, R.	130-2050 SCOTIA STREET, VANCOUVER, BRITISH COLUMBIA V5T 4TI

PCT International Classification Number

H01M 8/04

PCT International Application Number

PCT/CA2004/000334

PCT International Filing date

2004-03-05

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	60/453,027	2003-03-07	U.S.A.