Title of Invention | PROCESS AND POLYOLEFIN COMPOSITION FOR IMPARTING LIGHT STABILITY AND FLAME RETARDANCY |
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Abstract | This invention relates to stabilized thermoplastic polymer, especially polyolefin compositions comprising a flame retardant selected from b1) melamin based flame retardants, or one of the compounds b2) bis-(hexachlorocyclopentadieno) cyclooctane, b3) tris-(2,3-dibromopropyl)-isocyanurate, b4) ethylene-bis-tetrabromophthalimide; b5) 1,2,5,6,9,10-hexabromo-cyclo-dodecan, b6) ethane-1 l2-bis(pentabromophenyl); and c) a sterically-hindered amine light stabilizer of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class and optional further components combine optimum outdoor weathering stability and good flame retardant properties. |
Full Text | Improved Weatherabilitv of Flame Retardant Polvolefin The instant invention pertains to a thermoplastic organic polymer, especially a polyolefin such as thermoplastic polyolefin (TPO), stabilized against the deleterious effects of light, oxygen and heat and containing a certain flame retardant, which contains a sterically hindered amine of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class and optionally further stabilizers, to the use of these flame retardants and sterically hindered amines for imparting both light stabilization and flame retardant properties, and to a corresponding process for improving light stability and flame retardancy of a thermoplastic organic polymer. United States Patent No. 5,393,812 does describe polyolefin compositions which are made flame retardant by addition of a halogenated hydrocarbyl phosphate or phosphonate ester flame retardant, and stabilized against weathering with a alkoxyamine functional hindered amine. EP-A-792911 proposes the use of a alkoxyamine functional hindered amine for improving the flame retardant properties of a polyolefin. The activity of alkoxyamine functional hindered amines alone as a flame retardant is disclosed in WO 99/00450. There is still need to improve flame retardant polymer compositions in order to obtain good stability against weathering. Now it has been found that optimum stabilization against UV light and weathering and good flame retardant properties, especially for outdoor applications, can be combined in a thermoplastic polymer, especially a polyolefin, polyolefin copolymer or blend thereof such as impact modified polyolefin or thermoplastic polyolefin (TPO), when certain hindered amine stabilizers are used in combination with a specific flame retardant. Thus, present invention pertains to the use of a combination of a flame retardant selected from b1) melamin based flame retardants and/or ammonium polyphosphate, b2) bis-(hexachlorocyclopentadieno) cyclooctane, b3) tris-(2,3-dibromopropyl)-isocyanurate, b4) ethylene-bis-tetrabromophthalimide, b5) 1,2,5,6,9,10-hexabromo-cyclo-dodecan, b6) ethane-1,2-bis(pentabromophenyl); and c) a sterically hindered amine light stabilizer of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class for imparting both weathering stability and flame retardancy to a thermoplastic polymer (a), provided that the flame retardant is not (b4) if the sterically hindered amine is of the hydroxyhydrocarbyloxy class. Detailed Disclosure The sterically hindered amine light stabilizer of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class of component (c) is characterized by its substituent E1-o-on the amino nitrogen atom (see formula below), wherein E1 is preferably c1-C18alky!, C5-C12cycloalkyl or C7-C15aralkyl in the sterically hindered amine of the hydrocarbyloxyamine class; and Ei is preferably C1-C18alkyl, C5-C12cycloalkyl or C7-C15aralkyl each of which is substituted in the aliphatic part by 1-3 OH groups in the sterically hindered amine of the hydroxyhydrocarbyloxyamine class. The latter type of compound, containing a reactive OH group, may also be used in the form of its reaction product. The sterically hindered amine light stabilizer of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class of component c usually is a compound containing a group of the formula where G1 and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene, and Ei is C1-C18alkyl, C5-Ci2cycloalkyl or C7-C15aralkyl; or E1 is CrC18alkyl, C5-C12cycloalkyl or C7-C15aralkyl each of which is substituted in the aliphatic part by 1-3 OH groups; or is a reaction product thereof. Preferred is a cyclic sterically hindered amine conforming to the formula wherein G1, G2 and E1 are as defined above; T is a divalent organic radical required to complete formula I to form, together with the hindered amine nitrogen atom and the two quaternary carbon atoms substituted by Gi and G2, a five- or six-membered aliphatic ring structure, especially a piperidine ring; or is an oligomeric or polymeric hindered amine molecule made from the reaction of a dialkyl ester or isocyanate with a compound of the formula (I) wherein E^ contains 1 OH group and T is -CH2-CH(OH)-CH2-; or is a simple diester or urethane derivative of a compound of the formula (I) wherein Ei contains 1 OH group and T is -CH2-CH(OH)-CH2-. In general, effective stabilizing amounts of a compound of component c used are from 0.01 to 10 %, preferably from 0.05 to 5% by weight, especially from 0.1 to 2 % by weight, based on the polymer component (a), of the stabilizer of component (c). Sterically hindered amines of present component (c) are largely known as light stabilizers (US-5004770; US-5096950; US-5204473; US-5096950; US-5300544; US-6117995; US-6271377). Flame retardants of component (b) are commercial compounds. Most preferred is tris-(2,3-dibromopropyl)-isocyanurate (b3). Halogen-free flame retardants b1 are usually employed in an amount from 1 to about 50 % by weight of the polymer (a), preferably in an amount from 5 to 50 % by weight of the polymer (a). The ratio b1 : c is most preferably in the range from 20 : 1 to 250 : 1. Halogenated flame retardants b2, b3, b4, b5 and/or b6 are usually employed in a total amount from 0.5 to 40 % by weight of the polymer (a); more preferably 3 to 40%, most preferably 5 to 35% by weight of polymer (a). Most preferred amounts of flame retardants (b) in the compositions of present invention are for b1) the melamin based flame retardant and/or ammonium polyphosphate 20 - 50 %; b2) bis-(hexachlorocyclopentadieno) cyclooctane 5 -20 %; b3) tris-(2,3-dibromopropyl)-isocyanurate 2-10 %; b4) ethylene-bis-tetrabromophthalimide 10-40 %; b5) 1,2,5,6,9,10-hexabromo-cyclo-dodecan 2-20 %; b6) ethane-1,2-bis(pentabromophenyl) 2-20 %; each amount denotes percent by weight, based on the weight of the polymer (a). Also of importance in the context of present invention is the use of the flame retardant tris(3-bromo-2,2-(bromomethyl)propyl) phosphate (b7; see below), which is most preferably employed in an amount of 2 - 20, especially 2-10, percent by weight, based on the weight of the polymer (a). The ratio of halogenated flame retardants b2, b3, b4, b5, b6 or b7 : c is most preferably in the range from 5:1 to 100 : 1. Advantageously, halogenated flame retardants such as b2, b3, b4, b5, b6 and/or b7 may be used in combination with an appropriatesynergist such as an antimon compound (often Sb2o3), which is commonly added in an amount of 0.5 to 20 % by weight of the polymer (a). Component a is frequently selected from the following thermoplastic polymers: 1. Polymers of monoolefins and diolefins, for example polypropylene (PP), polyisobutylene, polybut-1-ene, poly-4-methylpent-1-ene, polyisoprene or polybutadiene, as well as polymers of cycloolefins, for instance of cyclopentene or norbornene, polyethylene (which optionally can be crosslinked), for example high density polyethylene (HDPE), high density and high molecular weight polyethylene (HDPE-HMW), high density and ultrahigh molecular weight polyethylene (HDPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), (VLDPE) and (ULDPE). Polyolefins, i.e. the polymers of monoolefins exemplified in the preceding paragraph, preferably polyethylene and polypropylene, can be prepared by different, and especially by the following, methods: a) radical polymerisation (normally under high pressure and at elevated temperature). b) catalytic polymerisation using a catalyst that normally contains one or more than one metal of groups IVb, Vb, Vlb or VIII of the Periodic Table. These metals usually have one or more than one ligand, typically oxides, halides, alcoholates, esters, ethers, amines, alkyls, alkenyls and/or aryls that may be either Π- or σ-coordinated. These metal complexes may be in the free form or fixed on substrates, typically on activated magnesium chloride, titanium(lll) chloride, alumina or silicon oxide. These catalysts may be soluble or insoluble in the polymerisation medium. The catalysts can be used by themselves in the polymerisation or further activators may be used, typically metal alkyls, metal hydrides, metal alkyl halides, metal alkyl oxides or metal alkyloxanes, said metals being elements of groups la, lla and/or Ilia of the Periodic Table. The activators may be modified conveniently with further ester, ether, amine or silyl ether groups. These catalyst systems are usually termed Phillips, Standard Oil Indiana, Ziegler (-Natta), TNZ (DuPont), metallocene or single site catalysts (SSC). 2. Mixtures of the polymers mentioned under 1), for example mixtures of polypropylene with polyisobutylene, polypropylene with polyethylene (for example PP/HDPE, PP/LDPE) and mixtures of different types of polyethylene (for example LDPE/HDPE). 3. Copolymers of monoolefins and diolefins with each other or with other vinyl monomers, for example ethylene/propylene copolymers, linear low density polyethylene (LLDPE) and mixtures thereof with low density polyethylene (LDPE), propylene/but-1-ene copolymers, propylene/isobutylene copolymers, ethylene/but-1-ene copolymers, ethylene/hexene copolymers, ethylene/methylpentene copolymers, ethylene/heptene copolymers, ethylene/octene copolymers, propylene/butadiene copolymers, isobutylene/isoprene copolymers, ethy-lene/alkyl acrylate copolymers, ethylene/alkyl methacrylate copolymers, ethylene/vinyl acetate copolymers and their copolymers with carbon monoxide or ethylene/acrylic acid copolymers and their salts (ionomers) as well as terpolymers of ethylene with propylene and a diene such as hexadiene, dicyclopentadiene or ethylidene-norbornene; and mixtures of such copolymers with one another and with polymers mentioned in 1) above, for example polypropylene/ethylene-propyiene copolymers, LDPE/ethylene-vinyl acetate copolymers (EVA), LDPE/ethylene-acrylic acid copolymers (EAA), LLDPE/EVA, LLDPE/EAA and alternating or random polyalkylene/carbon monoxide copolymers and mixtures thereof with otr.er polymers, for example polyamides. 4. Blends of the aforementioned polymers (polyblends), for example PP/EPDM. In the following, the term polyolefin will be used for pure polyolefin homopolymers as well as copolymers and blends thereof. Preferably, the polyolefin or thermoplastic olefin or polyolefin (TPO) is the only organic polymer present in these compositions; mainly it is polyethylene (PE) or polypropylene (PP), especially LDPE, LLDPE or PP, or copolymers of PP and PE. Especially preferred as component (a) are polymers known as thermoplastic (poly)olefines (TPO), e.g. polypropylene or polyethylene containing an impact modifyer or elastomer component such as EPR etc., or heterophasic copolymers (see e.g. W. Neissl et al., Kunststoffe 83, No. 8, 1993). Examples of polymer compositions in which the instant compounds are effective include flame retardant polyolefins where acidic residues from the decomposition of the halogenated flame retardants deactivate hindered amines not having the N-OR group, roofing membranes, greenhouse films and agricultural mulch films where acidic residues from pesticides interfere with the activity of "normal" hindered amine stabilizers, and in thermoplastic polyolefins where pigment interactions with basic hindered amine stabilizers interfere with painting the substrate surfaces. Preferably, the compound of present component c is a cyclic sterically hindered amine containing a group of formula (II) and/or (III) in which G is hydrogen or methyl, and Gi and G2, independently of one another, are hydrogen, methyl or together are a substituent =0. Examples of sterically hindered amines of present component c are described below under classes (a') to (m'). in which n1 is a number from 1 to 4, G and Gi, independently of one another, are hydrogen or methyl, G11 is 0\ hydroxyl, c1-C18alkoxy, C5-C12cycloalkoxy, C7-C15phenylalkoxy; or G11 is d-c18alkoxy, C5-C12cycloalkoxy or C7-C15phenylalkoxy each of which is substituted in the aliphatic part by 1-3 OH groups; G11 preferably being c1-C12alkoxy or cyclohexyloxy or C2-C8hydroxyalkoxy, especially octyloxy, cyclohexyloxy or 2-hydroxy-2-methylpropoxy, and G12, if n1 is 1, is hydrogen, c1-c18alkyl which is uninterrupted or interrupted by one or more oxygen atoms, COO and/or CONH groups, or is cyanoethyl, benzoyl, glycidyl, a monovalent radical of an aliphatic, cycloaliphatic, araliphatic, unsaturated or aromatic carboxylic acid, carbamic acid or phosphorus-containing acid or a monovalent silyl radical, preferably a radical of an aliphatic carboxylic acid having 2 to 18 carbon atoms, of a cycloaliphatic carboxylic acid having 7 to 15 carbon atoms, or an a,p-unsaturated carboxylic acid having 3 to 5 carbon atoms or of an aromatic carboxylic acid having 7 to 15 carbon atoms, where each carboxylic acid can be substituted in the aliphatic, cycloaliphatic or aromatic moiety by 1 to 3 -COOZ12 groups, in which Z12is H, CrC20alkyl, C3-C12alkenyl, C5-C7cycloalkyl, phenyl or benzyl, G12, if n1 is 2, is C2-C12alkylene, C4-C12alkenylene, xylyiene, a divalent radical of an aliphatic, cycloaliphatic, araliphatic or aromatic dicarboxylic acid, dicarbamic acid or phosphorus-containing acid or a divalent silyl radical, preferably a radical of an aliphatic dicarboxylic acid having 2 to 36 carbon atoms, or a cycloaliphatic or aromatic dicarboxylic acid having 8-14 carbon atoms or of an aliphatic, cycloaliphatic or aromatic dicarbamic acid having 8-14 carbon atoms, where each dicarboxylic acid may be substituted in the aliphatic, cycloaliphatic or aromatic moiety by one or two -COOZ12 groups, G12, if n1 is 3, is a trivalent radical of an aliphatic, cycloaliphatic or aromatic tricarboxylic acid, which may be substituted in the aliphatic, cycloaliphatic or aromatic moiety by -COOZ12J of an aromatic tricarbamic acid or of a phosphorus-containing acid, or is a trivalent silyl radical, preferred radicals including triacyl radicals of nitrilo triacetic acid of benzene tricarboxylic acid, and G12, if n1 is 4, is a tetravalent radical of an aliphatic, cycloaliphatic or aromatic tetracarboxylic acid. The carboxylic acid radicals mentioned above are in each case taken to mean radicals of the formula (-CO)xR, where x is as defined above for n1, and the meaning of R arises from the definition given above. Alkyl with up to 20 carbon atoms is, for example, methyl, ethyl, n-propyl, n-butyl, sec-butyl, tert-butyl, n-hexyl, n-octyl, 2-ethylhexyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-hexadecyl or n-octadecyl. C1-C18alkoxy G11 is, for example, methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, pentoxy, isopentoxy, hexoxy, heptoxy, octoxy, decyloxy, dodecyloxy, tetradecyloxy, hexadecyloxy and octadecyloxy. C6-Ci2alkoxy, in particular heptoxy and octoxy, is preferred. C5-C12cycloalkoxy Gn is, for example, cyclopentoxy, cyclohexoxy, cycloheptoxy, cyclooctoxy, cyclodecyloxy and cyclododecyloxy. C5-C8cycloalkoxy, in particular cyclopentoxy and cyclohexoxy, is preferred. C7-C9phenylalkoxy is, for example, benzyloxy. Gn as CrC18alkoxy, C5-C12cycloalkoxy or C7-C15phenylalkoxy substituted in the aliphatic part by 1-3 OH groups is a radical formed by abstraction of an carbon-bonded hydrogen atom preferably from 2-methyl-2-propanol (tert.-butanol), 2-propanol, 2,2-dimethyM-propanol, 2-. methyl-2-butanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-nonanol, 1-decanol, 1-dodecanol, 1-octadecanol, 2-butanol, 2-pentanol, 2-ethyl-1-hexanol, cyclo-hexanol, cyclooctanol, ally! alcohol, phenethyl alcohol or 1-phenyl-1-ethanol; 1,2-ethanediol, 1,2-propanedial, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,2-dimethyl-1f3-propanediol, 1,2-cyclohexanediol, 1,3-cyclohexanediol or 1,4-cyclohexanediol; glycerol, 1,1,1-tris(hydroxymethyl)methane, 2-ethyl-2-(hydroxymethyl-1,3-propanediol, 1,2,4-butanetriol or 1,2,6-hexanetriol. More preferably, G11 is are formed from 2-methyl-2-propanol or cyclohexanol, 1,4-butanediol, 2,2-dimethyl-1,3-propanediol, 1,2-cyclohexanediol, 1,3-cyclohexanediol or 1,4-cyclohexanediol. Most preferred hydroxy substituted G11 is 2-hydroxy-2-methylpropoxy. Examples of several G12 radicals are given below. If G12 is a monovalent radical of a carboxylic acid, it is, for example, an acetyl, caproyl, stearoyl, acryloyl, methacryloyl, benzoyl or β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl radical. If G12 is a monovalent silyl radical, it is, for example, a radical of the formula -(CjH2j)-Si(Z')2Z", in which j is an integer in the range from 2 to 5, and T and Z", independently of one another, are c1-C4alkyl or Ci-C4alkoxy. If G12 is a divalent radical of a dicarboxylic acid, it is, for example, a malonyl, succinyl, glutaryl, adipoyl, suberoyl, sebacoyl, maleoyl, itaconyl, phthaloyl, dibutylmalonyl, dibenzylmalonyl, butyl(3,5-di-tert-butyl-4-hydroxybenzyl)malonyl or bicycloheptenedicarbonyl radical or a group of the formula If G12 is a trivalent radical of a tricarboxylic acid, it is, for example, a trimellitoyl, citryl or nitrilotriacetyl radical. If Gi2 is a tetravalent radical of a tetracarboxylic acid, it is, for example, the tetravalent radical of butane-1,2,3,4-tetracarboxylic acid or of pyromellitic acid. If Gi2 is a divalent radical of a dicarbamic acid, it is, for example, hexamethylenedicarbamoyl or 2,4-toluylenedicarbamoyl radical. Preference is given to compounds of the formula (1a) in which G and d are hydrogen, Gn is hydrogen or methyl, ni is 2 and G12 is the diacyl radical of an aliphatic dicarboxylic acid having 4-12 carbon atoms. in which n2 is the number 1, 2 or 3, and G, G1 and Gn are as defined under (a1), G13 is hydrogen, d-C12alkyl, C2-C5hydroxyalkyl, C5-C7cycloalkyl, C7-C8aralkyl, CrCiaalkanoyl, C3-C5alkenoyl, benzoyl or a group of the formula and G14, if n2 is 1, is hydrogen, CrC18alkyl, C3-C8aikenyl, C5-C7cycloalkyI, d-C4alkyl which is substituted by a hydroxyl, cyano, alkoxycarbonyl or carbamide group or group of the formula -CONH-Z, or G14 is glycidyl, a group of the formula -CH2-CH(OH)-Z or of the formula -CONH-Z, in which Z is hydrogen, methyl or phenyl or CH2-OZi4 with Zt4 being hydrogen or d-C18alkyl; GH, if n2 is 2, is C2-Ci2alkylene, C6-C12arylene, xylylene, a -CH2-CH(OH)-CH2 group or a -CH2-CH(OH)-CH2-0-D-0- group, in which D is C2-C10alkylene, C6-C15arylene, C6-C12cycloalkylene, or, provided that Gt3 is not alkanoyl, alkenoyl or benzoyl, G14 can alternatively be 1-oxo-C2-Ci2alkylene, a divalent radical of an aliphatic, cycloaliphatic or aromatic dicarboxylic acid or dicarbamic acid or alternatively the group -CO-, Gi4, if n2 is 3, is a group or, if n2 is 1, Gi3 and d4 together can be the divalent radical of an aliphatic, cycloaliphatic or aromatic 1,2- or 1,3-dicarboxylic acid. Some examples for the radicals G13, G14 and D are given below. Any alkyl substituents are as defined above for (a'). Any C5-C7cycloalkyl substituents are, in particular, cyclohexyL C7-C8aralkyl Gi3 is, in particular, phenyiethyl or especially benzyl. C2-C5hydroxyalkyl G13 is, in particular, 2-hydroxyethyl or2-hydroxypropyl. CrCi8alkanoyl G13 is, for example, formyl, acetyl, propionyl, butyryl, octanoyl, dodecanoyl, hexadecanoyl, octadecanoyl, but preferably acetyl, and C3-C5alkenoyl G13 is, in particular, acryloyl. C2-C8alkenyl G14 is, for example, allyl, methallyl, 2-butenyl, 2-pentenyl, 2-hexenyl or 2-octenyl. G14 as a hydroxy!-, cyano-, alkoxycarbonyl- or carbamide-substituted d-C4alkyl can be, for example, 2-hydroxyethyl, 2-hydroxypropyl, 2-cyanoethyl, methoxycarbonylmethyl, 2-ethoxycarbonylethyl, 2-aminocarbonylpropyl or 2-(dimethylaminocarbonyl)ethyl. Any C2-Ci2alkylene radicals are, for example, ethylene, propylene, 2,2-dimethylpropylene, tetramethylene, hexamethylene, octamethylene, decamethylene ordodecamethylene. Any C6-Ci5arylene substituents are, for example, o-, m- or p-phenylene, 1,4-naphthylene or 4,4'-diphenylene. C6-Ci2cycloalkylene is, in particular, cyclohexylene. G14 as 1-oxo-C2-Ci2alkylene is preferably a group (c') A compound of the formula (1c) in which n3 is the number 1 or 2, G, Gi and Gn are as defined under (a'), and G15 and G'15 if n3 is 1, are independently C1-C12 alkyl, C2-C12 alkenyl, C7-C12 aralkyl, or G15 is also hydrogen, or Gi5 and G'15 together are C2-C8alkylene, C5-C15alkenylene, C2-C8hydroxyalkylene or C4-C22acyloxyalkylene, and if n3 is 2, G15 and G'15 together are the (-CH2)2C(CH2-)2 group. C2-CQalkylene or C2-Cahydroxyalkylene G15 and G'15 is, for example, ethylene, 1-methylethylene, propylene, 2-ethylpropylene or 2-ethyl-2-hydroxymethylpropylene. C4-C22acyloxyalkylene G15 and G'15 is, for example, 2-ethyl-2-acetoxymethylpropylene. in which n4 is the number 1 or 2, Gf G, and Gn are as defined under (a'), Gi6 is hydrogen, d-C^alky!, ally!, benzyl, glycidyl or C2-C6alkoxyalkyl, and G17, if n4 is 1, is hydrogen, d-C^alkyl, C3-C5alkenyl, C7-Cgaralkyl, C5-C7cycloaIkyl, C2-C4hydroxyalkyl, C2-C6alkoxyalkyl, C6-Ci0aryl, glycidyl or a group of the formula -(CH2)p-COO-G or -(CH2)p-0-CO-Q, in which p is 1 or 2, and Q is CrC4alkyl or phenyl, and G17, if n4 is 2, is C2-C12alkylene, C4-Ci2alkenylene, C6-C12arylene, a group of the formula -CH2-CH(OH)-CH2-0-D,-0-CH2-CH(OH)-CH2-l in which D' is C2-C10a!kyiene, C6-C15arylene or C6-C12cycloalkylene, or a group of the formula -CH2CH(OD,l)CH2-(OCH2-CH(OD")CH2)2-, in which D" is hydrogen, Ci-Ci3alkyl, allyl, benzyl, C2-C12alkanoyl or benzoyl, Ti and T2, independently of one another, are hydrogen, CrCi8alkyl or unsubstituted or halogen- or CrC4alkyl-substituted C6-C10aryl or C7-Cgaralkyl, or Tt and T2 together with the carbon atom bonding them form a C5-C14cycloalkane ring. Any d-Ci2alkyl substituents are, for example, methyl, ethyl, n-propyl, n-butyl, sec-butyl, tert-butyl, n-hexyl, n-octyl, 2-ethylhexyl, n-nonyl, n-decyl, n-undecyl orn-dodecyl. Any CrCi8alkyl substituents can be, for example, the abovementioned groups and in addition, for example, n-tridecyl, n-tetradecyl, n-hexadecyl or n-octadecyl. Any C2-C6alkoxyalkyl substituents are, for example, methoxymethyl, ethoxymethyl, propoxymethyl, tert-butoxymethyl, ethoxyethyl, ethoxypropyl, n-butoxyethyl, tert-butoxyethyl, isopropoxyethyl or propoxypropyl. C3-C5alkenyl d7 is, for example, 1-propenyl, allyl, methallyl, 2-butenyl or2-pentenyl. C7-C9araikyl G17. Ti and T2 are, in particular, phenethyl or especially benzyl. If T1 and T2 together with the carbon atom form a cycioalkane ring, this can be, for example, a cyclo-pentane, cyclohexane, cyclooctane or cyclododecane ring. C2-C4hydroxyalkyl G17 is, for example, 2-hydroxyethyl, 2-hydroxypropyl, 2-hydroxybutyl or 4-hydroxybutyl. C6-Ci0aryl G17, T\ and T2 are, in particular, phenyl or a- or p-naphthyl, which are unsubstituted or substituted by halogen or CrC4alkyl. C2-Ci2alkylene Gt7 is, for example, ethylene, propylene, 2,2-dimethylpropylene, tetramethylene, hexamethylene, octamethylene, decamethylene or dodecamethylene. C4-Ci2alkenylene Gi7 is, in particular, 2-butenylene, 2-pentenylene or 3-hexenylene. C6-Ci2arylene Gi7 is, for example, o-, m- or p-phenylene, 1,4-naphthylene or 4,4,-diphenylene. C2-Ci2alkanoyl D" is, for example, propionyl, butyryl, octanoyl, dodecanoyl, but preferably acetyl. C2-C10alkylene, C6-Ci5arylene or C6-Ci2cycloalkylene D' have, for example, one of the definitions given for D under (b'). (e') A compound of the formula (1e) in which n5 is the number 1 or 2, and G18 is a group of the formula in which G and Gn are as defined under (a'), and Gi and G2 are hydrogen, methyl or, together, are a substituent =0, Eis-0-or-ND"A is C2-C6alkylene or -(CH2)3-0- and Xi is the number 0 or 1, D'" is hydrogen, Ci-C12alkyl, C2-C12alkylene-N(DV)2, C2-C5hydroxyalkyi or C5-C7cycloalkyl, where Dv, independently, is hydrogen or butyl, Gig is identical to G18 or is one of the groups -N(G2i)(G22), -OG23, -N(H)(CH2OG23) or -N(CH2OG23)2, G2oi if n5 = 1, is identical to da or G19 and, if n5 = 2, is an -E-DIV-E- group, in which DIV is C2-CQalkylene or C2-C8alkylene which is interrupted by 1 or 2 -NG21- groups, G2i is hydrogen, d-C^alkyl, cyclohexyl, benzyl or d-C4-hydroxyalkyl or a group of the formula G22 is Ci-C12alkyl, cyclohexyl, benzyl or Ci-C4hydroxyalkyl, and G23 is hydrogen, CrCi2alkyl or phenyl, or G2i and G22 together are C4-C5alkylene or C4-C5oxaaikylene, for example -CH2CH2-0-CH2CH2-, or a group of the formula -CH2CH2-N(G11)-CH2CH2-. Some examples of the several variables in the formula (le) are given below. Any CrCi2alkyl substituents are, for example, methyl, ethyl, n-propyl, n-butyl, sec-butyl, tert-butyl, n-hexyl, n-octyl, 2-ethylhexyl, n-nonyl, n-decyl, n-undecyl or n-dodecyl. Any hydroxyalkyl substituents are, for example, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, 2-hydroxybutyl or 4-hydroxybutyl. Any C5-C7cycloalkyl substituents are, for example, cyclopentyl, cyclohexyl or cycloheptyl. Cyclohexyl is preferred. C2-C6alkylene A is, for example, ethylene, propylene, 2,2-dimethylpropylene, tetramethylene or hexamethylene. If G21 and G22 together are C4-C5alkylene or oxaalkylene, they are, for example, tetramethylene, pentamethylene or 3-oxapentamethylene. wherein Gn is as defined under (a'). (g') Oligomeric or polymeric compounds whose recurring structural unit contains a 2,2,6,6-tetraalkylpiperidinyl radical, in particular polyesters, polyethers, polyamides, polyamines, polyurethanes, polyureas, polyaminotriazines, poly(meth)acrylates, poly(meth)acrylamides and copolymers thereof which contain such radicals. Examples of 2,2,6,6-polyalkylpiperidine compounds from this class are the compounds of the following formulae, rrn to m14 is a number from 2 to about 200, preferably 2 to 100, for example 2 to 50, 2 to 40, 3 to 40 or 4 to 10. ■ The meanings of the end groups which saturate the free valences in the oligomeric or polymeric compounds listed below depend on the processes used for the preparation of said compounds. The end groups can also in addition be modified after the synthesis of the compounds. wherein G24l G25, G26, G27 and G28, independently of one another, are a direct bond or d-Cioalkylene, Gn is as defined under (a') and mi7 is a number from 1 to 50. In the compound of the formula (1g)f the end group bonded to the >C=0 group can be, for example, and the end group bonded to the oxygen can be, for example X2 being d-dsaikyl, C5-Ci2cycloalkyl which is unsubstitutecl or substituted by 1, 2 or 3 d-dalkyl; phenyl which is unsubstituted or substituted by 1, 2 or 3 d-dalkyl or d-dalkoxy; C7-C9phenylalkyl which is unsubstituted or substituted on the phenyl by 1, 2 or 3 d-dalkyl; and the radicals X3 being independently of one another C2-C12alkylene; the radicals A are independently of one another -ORi3, -N(Ri4)(R15) or a group of the formula (2gm); R13, RH and R15, which are identical or different, are hydrogen, d-daalkyl, C5-d2cycloalkyl which is unsubstituted or substituted by 1, 2 or 3 d-C4alkyl; C3-C18alkenyl? phenyl which is unsubstituted or substituted by 1, 2 or 3 d-C4alkyl or d-dalkoxy; C7-C9phenylalkyl which is unsubstituted or substituted on the phenyl by 1, 2 or 3 d-C4a!kyl; tetrahydrofurfuryl or C2-dalkyl which is substituted in the 2, 3 or 4 position by -OH, d-C8alkoxy, di(d-C4alkyl)amino or a group of the formula (2glv); with Y being -0-, -CH2-, -CH2CH2- or >N-CH3, or -N(R14)(R15) is additionally a group of the formula (2glv); Xis-0-or>N-R16; R16 is hydrogen, d-Ci8alkyl, C3-dsaIkenyl, C5-d2cycloalkyl which is unsubstituted or substituted by 1, 2 or 3 d-C4alkyl; C7-C9phenylalkyl which is unsubstituted or substituted on the phenyl by 1, 2 or 3 d-dalkyl; tetrahydrofurfuryl, a group of the formula (2gv), or C2-C4alkyl which is substituted in the 2, 3 or 4 position by -OH, CrC8alkoxy, di(CrC4alkyl)amino or a group of the formula (2g,v); R11 has one of the definitions given for R16; and the radicals B have independently of one another one of the definitions given for A. 1) in which Gn is as defined under (a'), G29 and G32J independently of one another, are a direct bond or a -N(X1)-CO-X2-CO-N(X3)- group, where X^ and X3, independently of one another, are hydrogen, d-Cealkyl, C5-Ci2cycloalkyl, phenyl, C7-C9phenylalkyl or a group of the formula and X2 is a direct bond or Ci-C4alkylene, G30, G3i, G34 and G35) independently of one another, are hydrogen, Ci-C3oalkyl, C5-C12cycloalkyl or phenyl, G33 is hydrogen, Ci-C3oalkyl, C5-Ci2cycloaIkyIt C7-C9phenylalkyl, phenyl or a group of the formula (3g), and m19 is a number from 1 to 50. In the compounds of the formula (3g), the end group bonded to the 2,5-dioxopyrrolidine ring can be, for example, hydrogen, and the end group bonded to the -C(G34)(G35)- radical can be, for example, 4) A product obtainable by reacting an intermediate product, obtained by reaction of a polyamine of the formula (4g) with cyanuric chloride, with a compound of the formula (4g') in which m^o, ^"20 and mm2o, independently of one another, are a number from 2 to 12, G3e is hydrogen, Ci-C12alkyl, C5-Ci2cycloalkyl, phenyl or Cy-Cgphenylalkyl, and Gn is as defined under (a'). In general, the above reaction product can be represented for example by a compound of the following 3 formulae. It can also be in the form of a mixture of these three compounds: in which Gn is as defined under (a'), G37 is Ci-C10alkyl, C5-Ci2cycloalkyl, CrC4alkyl-substituted C5"C12cycloaikyl, phenyl or Crdoalkyl-substituted phenyl, G38 is C3-Ci0alkylene and m2i is a number from 1 to 50. In the compounds of the formula (5g), the terminal group bonded to the silicon atom can be, for example, (G37)3Si-0-, and the terminal group bonded to the oxygen can be, for example, -Si(G37)3. The compounds of the formula (5g) can also be in the form of cyclic compounds if m2i is a number from 3 to 10, i.e. the free valences shown in the structural formula then form a direct bond. 6) A compound of the formula (6g) where E is -O- or -ND'"- as defined under (e'), T3 is ethylene or 1,2-propylene, is the repeating structural unit derived from an aipha-olefin copolymer with an alkyl acrylate or methacrylate; preferably a copolymer of ethylene and ethyl acrylate, and where k is 2 to 100. wherein m is 1 to 100; G50 is straight or branched chain alkylene of 1 to 18 carbon atoms, cycloalkylene of 5 to 8 carbon atoms, cycloalkenylene of 5 to 8 carbon atoms, alkenylene of 3 to 18 carbon atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl of 1 to 4 carbon atoms, with the proviso that in formula (7g) successive hindered amine moieties can be oriented in either a head to head or head to tail fashion: G55 is a straight or branched chain alkylene of 1 to 18 carbon atoms, cycloalkylene or cycloalkenylene of 5 to 8 carbon atoms, phenylene or -NH-alkylene-NH- of 2 to 18 carbon atoms including 5-amino-1-aminomethyl-1,3T3-trimethylcyclohexane and -NH-xylylene-NH-; In the above shown oligomeric and polymeric compounds, examples of alkyl are methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, 2- ethylbutyl, n-pentyl, isopentyl, 1-methylpentyl, 1,3-dimethylbutyl, n-hexyl, 1-methylhexyl, n- heptyl, isoheptyl, 1,1,3,3-tetramethyIbutyl, 1-methylheptyl, 3-methylheptyl, n-octyl, 2-ethyl- hexyl, 1,1,3-trimethylhexyl, 1,1,3,3-tetramethylpentyl, nonyl, decyl, undecyl, 1-methylundecyl, dodecyl, 1,1,3,3,5,5-hexamethylhexyl, tridecyl, tetradecyi, pentadecyl, hexadecyl, heptadecyl, octadecyl, eicosyl and docosyl; examples of cycloalkyl are cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl; an example of C7-C9phenylalkyl is benzyl; and examples of alkylene are ethylene, propylene, trimethylene, tetramethylene, pentamethylene, 2,2-dimethyltrimethylene, hexamethylene, trimethylhexamethylene, octamethylene and decamethylene. in which n6 is the number 1 or 2, G and Gn are as defined under (a'), and Gu is as defined under (b1), but G14 cannot be -CONH-Z and -CH2-CH(OH)-CH2-0-D-0-. wherein the radicals G39, independently of one another, are a group of the formula (1i-1) in which G40 is d-C^alky! or C5-Ci2cycloalkyl, G4i is C2-Ci2alkylene and G42 is as defined for Gn above. Alkyl is for example d-dalkyl, in particular methyl, ethyl, propyl or butyl. Cycloalkyl is preferably cyclohexyl. Alkylene is for example ethylene, propylene, trimethylene, tetramethylene, pentamethylene, 2,2-dimethyltrimethylene or hexamethylene. Alkenyl is preferably allyl. Phenylalkyl is preferably benzyl. Acyl is preferably acetyl. (O A compound of the formula (1j) wherein G, Gu are as defined above and when n7 is 1, T7 is hydrogen, d-C^alky!, C3-C5alkenyl, C7-C9aralkyl, C5-C7cycloalkyl, C2-C4hydroxyalkyl, C2-C6alkoxyalkyl, C6-C10aryl, glycidyl, a group of the formula -(CH2)rCOO-Q or of the formula -(CH2)rO-CO-Q wherein t is 1 or 2, and Q is Ci-C4alkyl or phenyl; or when n7 is 2, T7is C2-C12alkylene, C6-C12arylene, a group -CH2CH(OH)-CH2-0-X-0-CH2-CH(OH)-CH2- wherein X is C2-Ci0alkylene, C6-C15arylene or C6-Ci2cycloalkylene, or a group -CH2CH(OZ')CH2-(OCH2-CH(OZ')CH2)2- wherein Z is hydrogen, CrC18a!kyl, allyl, benzyl, C2-C12alkanoyI or benzoyl. if n8 is 1, G51 is -G50-O-CO-G56; G52 is -0-CO-G56; and G53 is hydrogen; where G5e is alkyl or -NH-alkyl of 1 to 18 carbon atoms or -NH-cycloalkyl of 5 to 8 carbon atoms; if n8 is 2, G51 is alkylene of 1 to 18 carbon atoms, hydroxyalkylene of 3 to 18 carbon atoms, ■ cycloalkylene of 5 to 8 carbon atoms, cycloalkenylene or hydroxycycloalkylene of 5 to 8 carbon atoms, alkenylene of 3 to 18 carbon atoms, or a straight or branched chain alkylene of 1 to 4 carbon atoms or hydroxyalkylene of 2Tto 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl of 1 to 4 carbon atoms; or G51 is a divalent acyl radical of an aliphatic, cycloaliphatic, araliphatic or aromatic dicarboxylic acid or of a dicarbamic acid, preferably an acyl radical of an aliphatic dicarboxylic acid having 2-18 C atoms, of a cycloaliphatic or aromatic dicarboxylic acid having 8-14 C atoms, if n8 is 3, G51 is alkanetriyl of 1 to 18 carbon atoms, hydroxyalkanetriyl of 3 to 18 carbon atoms, cycloalkanetriyl of 5 to 8 carbon atoms, cycloalkenetriyl of 5 to 8 carbon atoms, alkenetriyl of 3 to 18 carbon atoms, a straight or branched chain alkanetriyl of 1 to 4 carbon atoms substituted by phenyl or by phenyl substituted by one or two alkyl of 1 to 4 carbon atoms; where Gn and G12 are as defined above under (a') if n^ is 1; G13 and Gu are as defined above under (b') if n2 is 1; G15 and G'15 are as defined above under (c') if n3 is 1; G18, Gig, A, E, DIV, XT are as defined above under (e'); T7 is as defined above under (j') if n7 is 1; G54 is as defined for G12 under (a') if r\^ is 2; G55 is as defined for G14 under (b') if n2 is 2; G5e is as defined forT7 under (j') if n7 is 2. Of special technical importance is a sterically hindered amine light stabilizer of the hydroxyhydrocarbyloxyamine class, wherein ET is preferably d-dsalkyl, C5-Ci2cycloalkyl or C7-Ci5aralkyl each of which is substituted in the aliphatic part by 1- 3 OH groups, especially 1 OH group. Thus, present invention also pertains to a flame retardant composition stabilized against deleterious effects of light and weathering comprising a) a polyolefin, and b) a flame retardant selected from b1) melamin based flame retardants and/or ammonium polyphosphate, b2) bis-(hexachlorocyclopentadieno) cyclooctane, b3) tris-(2,3-dibromopropyl)-isocyanurate, b4) ethylene-bis-tetrabromophthalimide; and c) a sterically hindered amine light stabilizer of the hydroxyhydrocarbyloxyamine class. Further, the instant invention pertains to a process for imparting light stability and flame retardancy to a thermoplastic polymer, which process comprises adding to said polymer a combination of the flame retardant tris-(2,3-dibromopropyl)-isocyanurate and a sterically hindered amine light stabilizer of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class. A flame retardant and light stabilized composition comprising a) a polyolefin, b) tris-(2,3-dibromopropyl)-isocyanurate as a flame retardant and c) a sterically hindered amine light stabilizer of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class is another preferred object of present invention. Preferred components a and c and amounts thereof in the novel process and novel compositions are as described above. Components b and c of the instant invention and optional further components may readily be incorporated into the polymer by conventional techniques, at any convenient stage prior to the manufacture of shaped articles therefrom. For example, the additives may be mixed with the polymer in dry powder form, or a suspension or emulsion of the stabilizer may be mixed with a solution, suspension, or emulsion of the polymer. The additives may be added to component (a), individually or mixed with one another. If desired, the individual components can be mixed with one another in the melt (melt blending) before incorporation into the material to be stabilized. Components b and/or c and optional further additives may be incorporated, for example, before or after molding or also by applying the dissolved or dispersed stabilizer mixture to the material to be stabilized, with or without subsequent evaporation of the solvent. The additives of component b and/or c as well as further ■ additives can also be added to the material to be stabilized in the form of a masterbatch which contains these components in a concentration of, for example, about 2.5 % to about 25 % by weight; in such operations, the polymer can be used in the form of powder, granules, solutions, suspensions or in the form of latices. Incorporation can take place prior to or during the shaping operation, or by applying the dissolved or dispersed compound to the polymer, with or without subsequent evaporation of the solvent. In the case of elastomers, these can also be stabilized as latices. A further possibility for incorporating the stabilizers of the invention into polymers is to add them before, during or directly after the polymerization of the corresponding monomers. In the case of addition prior to or during the polymerization, the stabilizers of the invention can also act as a regulator of the chain length of the polymers (chain terminator). Components b and c of the invention can judiciously be incorporated by the following methods: as emulsion or dispersion (e.g. to latices or emulsion polymers), as a dry mixture during the mixing in of additional components or polymer mixtures, by direct introduction into the processing apparatus (e.g. extruders, internal mixers, etc), as solution or melt. The additive combination of present components b and c is useful for many applications, especially outdoor applications, including the following: Thermoplastic olefins (TPO), e.g. paintable thermoplastic olefins Polypropylene molded articles Polyethylene film Molded polypropylene with brominated flame retardants Molded thermoplastic olefin with brominated flame retardants Polethylene film with brominated flame retardants Thermoplastic elastomers with other costabilizers Grease-filled wire and cable insulation Coatings over plastic substrates Polyolefin tanks or containers containing chemicals Polyolefin films with an antifog agent Polyolefin films with IR thermal fillers such as hydrotalcites, e.g. DHT4A Polyolefin films with an antistatic agent Flame-resistant molded polypropylene articles Flame-resistant molded thermoplastic olefins Flame-resistant polethylene film Pre-formed films for lamination to plastic substrates Electronic appliance Containers, boxes, bins for storage and transportation Automotive applications e.g. dashboard, back board Furniture e.g. stadion seats, public seats Roofing sheets Roofing membranes Flooring materials Liners Profiles, especially window and door profiles Geomembranes. The materials containing the stabilizers described herein can be used for the production of moldings, extruded articles, rotomolded articles, injection molded articles, blow molded articles, mono- and multilayer films, extruded profiles, surface coatings and the like. The resulting stabilized compositions of the invention may optionally also contain various conventional additives, preferably in amounts from 0.01 to 10%, more preferably from about 0.025 to about 2%, and especially from about 0.1 to about 1% by weight of component (a), such as the materials listed below, or mixtures thereof. 1. Antioxidants 1.1. Alkylated monophenols, for example 2,6-di-tert-butyl-4-methylphenol, 2-tert-butyl-4,6-di- methylphenol, 2,6-di-tert-butyl-4-ethylphenol, 2,6-di-tert-butyl-4-n-butylphenol, 2,6-di-tert-bu- tyl-4-isobutylphenol, 2,6-dicyclopentyl-4-methylphenol, 2-(a-methylcyclohexyl)-4)6-dimethyl- phenol, 2,6-dioctadecyl-4-methylphenol, 2,4,6-tricyclohexylphenol, 2,6-di-tert-butyl-4-meth- ■ oxymethylphenol, nonylphenols which are linear or branched in the side chains, for example 2,6-di-nonyl-4-methylphenol, 2,4-dimethyl-6-(1'-methylundec-1'-yl)phenol) 2,4-dimethyl-6-(1'-methylheptadec-1'-yl)phenol, 214-dimethyl-6-(1'-methyltridec-V-yl)phenol and mixtures thereof. 1.2. Alkylthiomethylphenols, for example 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4-dioctyl-thiomethyl-6-methylphenol, 2,4-dioctylthiomethyi-6-ethylphenol, 2,6-di-dodecylthiomethyl-4-nonylphenol. 1.3. Hydroquinones and alkylated hvdroquinones, for example 2,6-di-tert-butyl-4-methoxy-phenol, 2,5-di-tert-butylhydroquinone, 2,5-di-tert-amylhydroquinone, 2,6-diphenyl-4-octade-cyloxyphenol, 2,6-di-tert-butylhydroquinone, 2,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-bu-tyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyphenyl stearate, bis(3,5-di-tert-butyl-4-hy-droxyphenyl) adipate. 1.4. Tocopherols, for example a-tocopherol, (3-tocopherol, y-tocopherol, 5-tocopherol and mixtures thereof (vitamin E). 1.5. Hvdroxvlated thiodiphenyl ethers, for example 2,2'-thiobis(6-tert-butyl-4-methylphenol), 2,2'-thiobis(4-octyiphenol), 4,4'-thiobis(6-tert-butyl-3-methylphenol), 4,4'-thiobis(6-tert-butyl-2-methylphenol), 4,4'-thiobis(3,6-di-sec-amylphenol), 4,4'-bis(2,6-dimethyl-4-hydroxyphenyl)-disulfide. 1.6. Alkvlidenebisphenols, for example 2,2'-methylenebis(6-tert-butyl-4-nnethylphenol), 2,2'-methylenebis(6-tert-butyl-4-ethylphenol), 2,2'-methylenebis[4-methyl-6-(a-methylcyclohexyl)-phenol], 2,2'-methylenebis(4-methyl-6-cyclohexylphenol), 2,2,-methylenebis(6-nonyl-4-methylphenol), 2,2,-methylenebis(4,6-di-tert-butylphenol), 2,2'-ethylidenebis(4,6-di-tert-butyl-phenol), 2,2'-ethylidenebis(6-tert-butyl-4-isobutylphenol), 2,2'-methylenebis[6-(a-methylben-zyl)-4-nonylphenol], 2,2'-methylenebis[6-(a,a-dimethylbenzyl)-4-nonylphenol], 4,4'-methy-lenebis(2,6-di-tert-butylphenol), 4,4'-methylenebis(6-tert-butyl-2-methylphenol)1 1,1-bis(5-tert- butyl-4-hydroxy-2-methylphenyl)butane, 2,6-bis(3-tert-butyl-5-methyl-2-hydroxybenzyl)-4-methylphenol, 1,1,3-tris(5-tert-butyl-4-hydroxy-2-methylphenyl)butane, 1,1 -bis(5-tert-butyl-4-hydroxy-2-methylphenyl)-3-n-dodecylmercaptobutane, ethylene glycol bis[3,3-bis(3'-tert-butyl-4'-hydroxyphenyl)butyrate], bis(3-tert-butyl-4-hydroxy-5-methyI-phenyl)dicyclopenta-■ diene, bis[2-(3'-tert-butyl-2'-hydroxy-5'-methylbenzyl)-6-tert-butyl-4-methylphenyl]tereph late, 1,1-bis-(3,5HJimethyl-2-hydroxyphenyl)butane, 2,2-bis(3,5-di-tert-butyl-4-hydroxyphe-nyl)propane, 2,2-bis-(5-tert-butyl-4-hydroxy2-methylphenyl)-4-n-dodecylmercaptobutane, 1,1,5,5-tetra(5-tert-butyi-4-hydroxy-2-methylphenyl)pentane. 1.7. Q-, N- and S-benzvl compounds, for example 3,5,3',5'-tetra-tert-butyl-4,4'-dihydroxydi-benzyl ether, octadecyl-4-hydroxy-3,5-dimethylbenzylmercaptoacetate, tridecyl-4-hydroxy-3,5-di-tert-butylbenzylmercaptoacetate, tris(3,5-di-tert-butyl-4-hydroxybenzyl)amine, bis(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)dithioterephthalate, bis(3,5-di-tert-butyl-4-hydroxy-benzyl)sulfide, isooctyl-3,5-di-tert-butyl-4-hydroxybenzylmercaptoacetate. 1.8. Hydroxvbenzvlated malonates, for example dioctadecyi-2,2-bis(3,5-di-tert-butyl-2-hy-droxybenzyl)malonate, di-octadecyl-2-(3-tert-butyl-4-hydroxy-5-methylbenzyl)malonate, di-dodecylmercaptoethyl-2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate, bis[4-(1,1,3,3-tetra-methylbutyl)phenyl]-2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate. 1.9. Aromatic hvdroxvbenzvl compounds, for example 1,3,5-tris(3)5-di-tert-butyl-4-hydroxy-benzyl)-2,4,6-trimethyIbenzene, 114-bis(3,5-di-tert-butyl-4-hydroxybenzyl)-2,3,5,6-tetrame-thylbenzene, 2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)phenol. 1.10. Triazine compounds, for example 2,4-bis(octylmercapto)-6-(3,5-di-tert-butyl-4-hydroxy-anilino)-1,3,5-triazine, 2-octylmercapto-4J6-bis(3,5-di-tert-butyl-4-hydroxyanilino)-1)3,5-tri-azine, 2-octyimercapto-4,6-bis(3,5-di-tert-butyl-4-hydroxyphenoxy)-1,3,5-triazine, 2,4,6-tris-(S.S-di-tert-butyl^-hydroxyphenoxyJ-l^^-triazine, 1,3,5-tris(3,5-di-tert-butyI-4-hydroxyben-zyl)isocyanurate, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate, 2,4,6-tris-(3,5-di-tert-butyl-4-hydroxyphenylethyl)-1,3,5-triazine, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxy-phenylpropionyl)-hexahydro-1,3,5-triazine, 1,3,5-tris(3,5-dicyclohexyl-4-hydroxybenzyl)iso-cyan urate. 1.11. Benzvlphosphonates, for example dimethyl-2,5-di-tert-butyl-4-hydroxybenzylphospho-nate, diethyl-3,5-di-tert-butyl-4-hydroxybenzylphosphonate, dioctadecyl3,5-di-tert-butyl-4-hy- droxybenzylphosphonate, dioctadecyl-5-tert-butyl-4-hydroxy-3-methylbenzylphosphonate, the calcium salt of the monoethyl ester of 3,5-di-tert-butyl-4-hydroxybenzylphosphonic acid. 1.12. Acvlaminophenols, for example 4-hydroxylauranilide, 4-hydroxystearanilide, octyl N- • (3,5-di-tert-butyl-4-hydroxyphenyl)carbamate. 1.13. Esters of B-(3,5-di-tert-butvl-4-hvdroxvphenvl)propionic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethy-lene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hy-droxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylol-propane, 4-hydroxymethyl-1-phospha"2,6,7-trioxabicyclo[2.2.2]octane. 1.14. Esters of B-(5-tert-butvl-4-hvdroxv-3-methvlphenvl)propionic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanedi-ol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis-(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethyi-olpropane, 4-hydroxymethyl-1 -phospha-2,6,7-trioxabicyclo[2.2.2]octane; 3,9-bis[2-{3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.^ undecane. 1.15. Esters of p-(3,5-dicvclohexyl-4-hvdroxvphenvl)propionic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hydroxyethyl)ox-amide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hy-droxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane. 1.16. Esters of 3,5-di-tert-butvl-4-hvdroxvphenyl acetic acid with mono- or polyhydric alcohols, e.g. with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hydroxyethyl)ox- amide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hy-droxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane. 1.17. Amides of B-(3,5-di-tert-butvl-4-hvdroxyphenvl)propionic acid e.g. N,N'-bis(3,5-di-tert- ■ butyl-4-hydroxyphenylpropionyl)hexamethylenediamide, N,N'-bis(3,5-di-tert-butyl-4-hydroxy-phenylpropionyi)trimethylenediamide, N,N'-bis(315-di-tert-butyl-4-hydroxyphenylpropionyl)hy-drazide, N,N'-bis[2-(3-[3)5-di-tert-butyl-4-hydroxyphenyl]propionyloxy)ethyl]oxamide (Nau-gard®XL-1, supplied by Uniroyal). 1.18. Ascorbic acid (vitamin C) 1.19. Aminic antioxidants, for example N,N'-di-isopropyl-p-phenylenediamine, N,N'-di-sec-bu-tyl-p-phenylenediamine, N,N'-bis(1,4-dimethylpentyl)-p-phenylenediamine, N,N'-bis(1 -ethyl-3-methylpentyl)-p-phenylenediamine, N,N'-bis(1 -methylheptyl)-p-phenylenediamine, N,N'-dicy-clohexyl-p-phenylenediamine, N.N'-diphenyl-p-phenylenediamine, N,N'-bis(2-naphthyl)-p-phenyienediamine, N-isopropyl-N'-phenyl-p-phenylenediamine, N-(1,3-dimethylbutyl)-N'-phe-nyl-p-phenylenediamine, N-(1 -methylheptyl)-N'-phenyl-p-phenylenediamine, N-cyclohexyl-N'-phenyl-p-phenylenediamine, 4-(p-toluenesulfamoyl)diphenylamine, N,N'-dimethyl-N,N'-di-sec-butyl-p-phenylenediamine, diphenylamine, N-allyldiphenylamine, 4-isopropoxy-diphenylamine, N-phenyl-1-naphthylamine, N-(4-tert-octylphenyl)-1-naphthylaminef N-phe-nyl-2-naphthylamine, octylated diphenylamine, for example p.p'-di-tert-octytdiphenylamine, 4-n-butylaminophenol, 4-butyrylaminophenol, 4-nonanoylaminophenol, 4-dodecanoyl-aminophenol, 4-octadecanoylaminophenol, bis(4-methoxyphenyl)amine) 2,6-di-tert-butyl-4-dimethylaminomethylphenol, 2,4'-diaminodiphenylmethane, 4,4'-diaminodiphenylmethane, N.N.N'^'-tetramethyl^^'-diaminodiphenylmethane, 1,2-bis[(2-methylphenyl)amino]ethane, 1,2-bis(phenylamino)propane, (o-tolyl)biguanide, bis[4-(1 \3'-dimethylbutyl)phenyl]amine, tert-octylated N-phenyl-1-naphthylamine, a mixture of mono- and dialkylated tert-butyl/tert-octyldiphenylamines, a mixture of mono- and dialkylated nonyldiphenylamines, a mixture of mono- and dialkylated dodecyldiphenylamines, a mixture of mono- and dialkylated isopro-pyl/isohexyldiphenyiamines, a mixture of mono- and dialkylated tert-butyldiphenylamines, 2,3-dihydro-3,3-dimethyl-4H-1,4-benzothiazine, phenothiazine, a mixture of mono- and dialkylated tert-butyl/tert-octylphenothiazines, a mixture of mono- and dialkylated tert-octyl-phenothiazines, N-allylphenothiazine, NXN\NMetraphenyl-1t4 (2,2)6,6-tetramethyl-piperid-4-yl-hexamethylenediamine, bis(2,2,6,6-tetramethylpiperid-4-yi)-sebacate, 2,2,6,6-tetramethylpiperidin-4-one, 2,2,6,6-tetramethylpiperidin-4-ol. 2. UV absorbers and light stabilisers 2.1. 2-(2'-Hvdroxvphenyl)benzotriazoles, for example 2-(2'-hydroxy-5'-methylphenyl)benzo- triazole, 2-(3',5'-di-tert-butyl-2'-hydroxyphenyl)benzotriazoIe, 2-(5'-tert-butyl-2'-hydroxyphe- nyl)benzotriazole, 2-(2'-hydroxy-5'-(1,1,3,3-tetramethylbutyl)phenyl)benzotriazole, 2-(3\5'-di- tert-butyl-2'-hydroxyphenyl)-5-chlorobenzotriazole, 2-(3'-tert-butyl-2,-hydroxy-5'-methylphe- nyl)-5-chlorobenzotriazole, 2-(3'-sec-butyl-5'-tert-butyl-2'-hydroxyphenyl)benzotriazole, 2-(2'- hydroxy-4'-octyloxyphenyl)benzotriazole, 2-(3',5'-di-tert-amyl-2'-hydroxyphenyl)benzotriazole, 2-(3',5'-bis(a,a-dimethylbenzyl)-2'-hydroxyphenyl)benzotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'- (2-octyloxycarbonylethyl)phenyl)-5-chlorobenzotriazole, 2-(3'-tert-butyl-5'-[2-(2-ethylhexyl- oxy)carbonylethyl]-2'-hydroxyphenyl)-5-chlorobenzotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'-(2- methoxycarbonylethyl)phenyt)-5-chlorobenzotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'-(2-meth- oxycarbonylethyl)phenyl)benzotriazole, 2-(3,-tert-butyl-2'-hydroxy-5'-(2-octyloxycarbonyl- ethyl)phenyl)benzotriazole, 2-(3'-tert-butyl-5'-[2-(2-ethylhexyloxy)carbonylethyl]-2,-hydroxy- phenyl)benzotriazole, 2-(3'-dodecyl-2'-hydroxy-5'-methylphenyl)benzotriazote, 2-(3'-tert-butyl- 2'-hydroxy-5'-(2-isooctyioxycarbonylethyl)phenylbenzotriazole, 2J2l-methylenebis[4-(1,1,3,3- tetramethylbutyl)-6-benzotriazole-2-ylphenol]; the transesterification product of 2-[3'-tert-bu- tyl-5'-(2-methoxycarbonylethyl)-2,-hydroxyphenyl]-2H-benzotriazole with polyethylene glycol 300; [R-CH2CH—COO-CH2CH2-J- , where R - 3'-tert-butyl-4'-hydroxy-5'-2H-benzotri- azol-2-ylphenyl, 2-[2'-hydroxy-3,-(a,a-dimethylbenzyl)-5'-(1,1,3,3-tetramethylbutyl)phenyl]-benzotriazole; 2-[2'-hydroxy-3'-(1,1,3,3-tetramethylbutyl)-5'-(ata-dimethylbenzyl)phenyl]ben-zotriazole. 2.2. 2-Hvdroxvbenzophenones, for example the 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyl-oxy, 4-dodecyloxy, 4-benzyloxy, 4,2',4'-trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives. 2.3. Esters of substituted and unsubstituted benzoic acids, for example 4-tert-butyIphenyl salicylate, phenyl salicylate, octylphenyl salicylate, dibenzoyl resorcinol, bis(4-tert-butylben-zoyl)resorcinol, benzoyl resorcinol, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzo- ate, hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, octadecyl 3,5-di-tert-butyl-4-hydroxyben-zoate, 2-methyl-4,6-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate. 2.4. Acrvlates, for example ethyl a-cyano-p,p-diphenylacrylate, isooctyl a-cyano-p,p-diphe-nylacrylate, methyl a-carbomethoxycinnamate, methyl a-cyano-P-methyl-p-methoxycinna-mate, butyl a-cyano-p-methyl-p-methoxycinnamate, methyl a-carbomethoxy-p-methoxycin-namate and N-(P-carbomethoxy-p-cyanovinyl)-2-methylindoline. 2.5. Nickel compounds, for example nickel complexes of 2,2'-thiobis[4-(1,1,3,3-tetramethyl-butyl)phenol], such as the 1:1 or 1:2 complex, with or without additional ligands such as n-butylamine, triethanolamine or N-cyclohexyldiethanolamine, nickel dibutyldithiocarbamate, nickel salts of the monoalkyl esters, e.g. the methyl or ethyl ester, of 4-hydroxy-3,5-di-tert-butylbenzylphosphonic acid, nickel complexes of ketoximes, e.g. of 2-hydroxy-4-methylphe-nylundecylketoxime, nickel complexes of 1-phenyl-4-lauroyl-5-hydroxypyrazole, with or without additional ligands. 2.6. Conventional stericallv hindered amines, for example bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(2,2,6,6-tetramethyl-4-piperidyl)succinate, bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert-butyl-4-hydroxybenzylmalonate, the condensate of 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-tert-octylamino-2,6-dichloro-1,3,5-triazine, tris(2,2,616-tetramethyl-4-piperidyl)nitrilotriacetate, tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate, 1,1 '-(1,2-ethanediyl)-bis(3,3,5,5-tetrame-thylpiperazinone), 4-benzoyl-2,2,6,6-tetramethylpiperidine, 4-stearyloxy-2,2,6,6-tetramethyl-piperidine, bis(1,2,2,6,6-pentamethylpiperidyl)-2-n-butyl-2-(2-hydroxy-3,5-di-tert-butylbenzyl)-malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-tnazaspiro[4.5]decane-2,4-dione, linear or cyclic condensates of N1N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5-triazine, the condensate of 2-chloro-4,6-bis(4-n-butylamino-2,2,6,6-tetramethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, the condensate of 2-chloro-4,6-di-(4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 3-dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidine-2,5-dione, 3-dodecyl-1 -(1 t2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione, 5-(2- ethylhexanoyO-oxymethyl-S^.S-trimethyl^-morpholinone, 1,3,5-tris(N-cyclohexyl-N-(2,2,6,6-tetramethylpiperazin-3-on-4-yl)amino)-s-triazine, 1,3,5-tris(N-cyclohexyl-N-(1,2,2,6,6-pentamethylpiperazin-3-on-4-yl)amino)-s-triazine, a mixture of 4-hexadecyloxy- and 4-stearyloxy-2,2,6,6-tetramethylpiperidine, a condensate of N,N'-bis(2,2)6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-cyclohexylamino-2,6-dichloro-1,3,5-triazine, a condensate of 1,2-bis(3-aminopropylamino)ethane and 2,4,6-trichloro-1,3,5-triazine as well as 4-butylamino-2,2,6,6-tetramethylpiperidine (CAS Reg. No. [136504-96-6]); a condensate of 1,6-hexanediamine and 2,4,6-trichloro-1,3,5-triazine as well as N,N-dibutylamine and 4-butylamino^^.e.e-tetramethylpiperidine (CAS Reg. No. [192268-64-7]); N-(2,2,6,6-tetramethyl-4-piperidyl)-n-dodecylsuccinimide, N-(1,2,2,6,6-pentamethyl-4-piperidyl)-n-dodecylsuccinimide, 2-undecyl-7,7,9,9-tetramethyl-1 -oxa-3,8-diaza-4-oxo-spiro[4,5]decane, a reaction product of 7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaza-4-oxospiro-[4,5]decane and epichlorohydrin, 1,1-bis(1,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl)-2-(4-methoxyphenyl)ethene, N,N'-bis-formyl-N,N'-bis(2f2,6,6-tetramethyl-4-piperidyl)-hexamethylenediamine, a diester of 4-methoxymethylenemalonic acid with 1,2,2,6,6-pentamethyl-4-hydroxypiperidine, poly[methylpropyl-3-oxy-4-(2,2,6,6-tetramethyl-4-piperi-dyl)]siloxane, a reaction product of maleic acid anhydride-oolefin copolymer with 2,2,6,6-tetramethyl-4-aminopiperidine or 1 ,2,2,6,6-pentamethyl-4-aminopiperidine. 2.7. Oxamides. for example 4,4'-dioctyloxyoxanilide, 2,2'-diethoxyoxanilide, 2,2'-dioctyloxy-5,5'-di-tert-butoxanilide, 2,2'-didodecyloxy-5,5'-di-tert-butoxanilide, 2-ethoxy-2'-ethyloxanilide, N,N'-bis(3-dimethylaminopropyl)oxamide) 2-ethoxy-5-tert-butyl-2'-ethoxanilide and its mixture with 2-ethoxy-2'-ethyi-5,4'-di-tert-butoxanilide, mixtures of o- and p-methoxy-disubstituted oxanilides and mixtures of o- and p-ethoxy-disubstituted oxanilides. 2.8. 2-(2-Hvdroxyphenvl)-1,3,5-triazines, for example 2,4,6-tris(2-hydroxy-4-octyloxyphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2,4-dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2,4-bis(2-hydroxy-4-propyl-oxyphenyl)-6-(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(4-methylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-dodecyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)- 1,3,5-triazine, 2-(2-hydroxy-4-tridecyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-butyloxypropoxy)phenyl]-4)6-bis(2,4-dimethyl)-1,3,5-triazine] 2-[2-hydroxy-4-(2-hydroxy-3-octyloxypropyloxy)phenyl]-4,6-bis(2,4-dimethyl)-1,3,5-triazine, 2-[4-(dodecyloxy/tridecyloxy-2-hydroxypropoxy)-2-hydroxyphenyl]-4,6-bis(2,4-dimethylphenyl)1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-dodecyloxypropoxy)phenyl]-4,6- bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-hexyloxy)phenyl-4,6-diphenyl-1,3,5-triazine, 2-(2-hydroxy-4-methoxypheny!)-4,6-diphenyl-1,3,5-triazine, 2,4,6-tris[2-hydroxy-4-(3-butoxy-2-hydroxypropoxy)phenyl]-1,3,5-triazine, 2-(2-hydroxyphenyl)-4-(4-methoxyphenyl)-6-phenyl-1,3,5-triazine, 2-{2-hydroxy-4-[3-(2-ethylhexyl-1-oxy)-2-hydroxypropyloxy]phenyl}-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine. 3. Metal deactivators, for example N,N'-diphenyloxamide, N-salicylal-N'-salicyloyl hydrazine, N,N'-bis(salicyloyl)hydrazine, N,N,-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hydrazine, 3-salicyloylamino-1t2,4-triazole, bis(benzylidene)oxalyl dihydrazide, oxanilide, isophthaloyl dihydrazide, sebacoyl bisphenylhydrazide, N.N'-diacetyladipoyl dihydrazide, N,N'-bis(salicyl-oyl)oxalyl dihydrazide, N,N'-bis(salicyloyl)thiopropionyl dihydrazide. 4. Phosphites and phosphonites. for example triphenyl phosphite, diphenylalkyl phosphites, phenyldialkyl phosphites, tris(nonylphenyl) phosphite, trilauryl phosphite, trioctadecyl phosphite, distearylpentaerythritol diphosphite, tris(2t4-di-tert-butylphenyl) phosphite, diisodecyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite, bis(2,4-di-cumylphenyl)pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite, diisodecyloxypentaerythritol diphosphite, bis(2,4-di-tert-butyl-6-methylphenyI)-pentaerythritol diphosphite, bis(2,4,6-tris(tert-butyIphenyl)pentaerythritol diphosphite, tristea-ryl sorbitol triphosphite, tetrakis(2,4-di-tert-butylphenyl) 4,4'-biphenylene diphosphonite, 6-isooctyloxy^^^.lO-tetra-tert-butyl-^H-dibenztd^J-I.S^-dioxaphosphocin, bis(2,4-di-tert-butyl-6-methylphenyl)methyl phosphite, bis(2,4-di-tert-butyl-6-methylphenyl)ethyl phosphite, 6-fluoro-2,4,8,10-tetra-tert-butyl-12-methyl-dibenz[d,g]-1,3,2-dioxaphosphocin, 2,2',2"-nitrilo-[triethyltrisCS^'^.S'-tetra-tert-butyl-IJ'-biphenyl^^'-diyOphosphite], 2-ethylhexyl(3,3',5,5'-te-tra-tert-butyl-1,1'-biphenyl-2,2'-diyl)phosphite, 5-butyl-5-ethyl-2-(2,4,6-tri-tert-butylphenoxy)- 1,3,2-dioxaphosphirane. The following phosphites are especially preferred: Tris(2,4-di-tert-butylphenyl) phosphite (lrgafos®168, Ciba-Geigy), tris(nonylphenyl) phosphite, Hydroxylamines, for example N,N-dibenzylhydroxylamine, N,N-diethylhydroxylamine, N,N-dioctylhydroxylamine, N.N-dilaurylhydroxylamine, N,N-ditetradecylhydroxylamine, N,N-dihexadecylhydroxylamine, N,N-dioctadecylhydroxylamine, N-hexadecyl-N-octadecylhydrox-ylamine, N-heptadecyi-N-octadecylhydroxylamine, N,N-dialkylhydroxylamine derived from hydrogenated tallow amine. 6. Nitrones, for example N-benzyl-alpha-phenylnitrone, N-ethyl-alpha-methylnitrone, N-octyl-alpha-heptylnitrone, N-lauryl-alpha-undecylnitrone, N-tetradecyl-alpha-tridecylnitrone, N-hexadecyl-alpha-pentadecylnitrone, N-octadecyl-alpha-heptadecylnitrone, N-hexadecyl-al-pha-heptadecylnitrone, N-ocatadecyl-alpha-pentadecylnitrone, N-heptadecyi-alpha-hepta-decylnitrone, N-octadecyl-alpha-hexadecylnitrone, nitrone derived from N,N-dialkylhydroxyl-amine derived from hydrogenated tallow amine. 7. Thiosvnerg1sts, for example dilauryl thiodipropionate or distearyl thiodipropionate. 8. Peroxide scavengers, for example esters of (3-thiodipropionic acid, for example the lauryl, stearyl, myristyl or tridecyl esters, mercaptobenzimidazole or the zinc salt of 2-mercapto-benzimidazole, zinc dibutyldithiocarbamate, dioctadecyl disulfide, pentaerythritol tetrakis((3-dodecylmercapto)propionate. 9. Polvamide stabilisers, for example copper salts in combination with iodides and/or phosphorus compounds and salts of divalent manganese. 10. Basic co-stabilisers, for example melamine, polyvinylpyrrolidone, dicyandiamide, triallyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurethanes, alkali metal salts and alkaline earth metal salts of higher fatty acids, for example calcium stearate, zinc stearate, magnesium behenate, magnesium stearate, sodium ricinoleate and potassium palmitate, antimony pyrocatecholate or zinc pyrocatecholate. 11. Nucleating agents, for example inorganic substances, such as talcum, metal oxides, such as titanium dioxide or magnesium oxide, phosphates, carbonates or sulfates of, preferably, alkaline earth metals; organic compounds, such as mono- or polycarboxylic acids and the salts thereof, e.g. 4-tert-butylbenzoic acid, adipic acid, diphenylacetic acid, sodium succinate or sodium benzoate; polymeric compounds, such as ionic copolymers (ionomers). Especially preferred are 1t3:2)4-bis(3,,4'-dimethylbenzylidene)sorbitol, 1,3:2,4-di(paramethyldibenzyli-dene)sorbitol, and 1,3:2,4-di(benzylidene)sorbitol. 12. Fillers and reinforcing agents, for example calcium carbonate, silicates, glass fibres, glass beads, asbestos, talc, kaolin, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, wood flour and flours or fibers of other natural products, synthetic fibers. 13. Other additives, for example plasticisers, lubricants, emulsifiers, pigments, rheology additives, catalysts, flow-control agents, optical brighteners, flameproofing agents, antistatic agents and blowing agents. 14. Benzofuranones and indolinones, for example those disclosed in U.S. 4,325,863; U.S. 4,338,244; U.S. 5,175,312; U.S. 5,216,052; U.S. 5,252,643; DE-A-4316611; DE-A-4316622; DE-A-4316876; EP-A-0589839 or EP-A-0591102 or 3-[4-(2-acetoxyethoxy)-phenyl]-5,7-di-tert-butyl-benzofuran-2-one, 5,7-di-tert-butyl-3-[4-(2-stearoyloxyethoxy)phe-nyl]benzofuran-2-one, 3,3,-bis[5,7-di-tert-butyl-3-(4-[2-hydroxyethoxy]phenyl)benzofuran-2-one], 5,7-di-tert-butyl-3-(4-ethoxyphenyl)benzofuran-2-one, 3-(4-acetoxy-3,5-dimethylphe-nyl)-5,7-di-tert-butyl-benzofuran-2-one, 3-(3,5-dimethyl-4-pivaloyloxyphenyl)-5,7-di-tert-butyl-benzofuran-2-one, 3-(3,4-dimethylphenyl)-5,7-di-tert-butyl-benzofuran-2-one, 3-(2,3-di-methylphenyl)-5,7-di-tert-butyl-benzofuran-2-one. 15. Amine oxides, for example amine oxide derivatives as disclosed in U.S. Patent Nos. 5,844,029 and 5,880,191, didecyl methyl amine oxide, tridecyl amine oxide, tridodecyl amine oxide and trihexadecyl amine oxide. U.S. Patent Nos. 5,844,029 and 5,880,191 disclose the use of saturated hydrocarbon amine oxides towards the stabilization of thermoplastic resins. It is disclosed that the thermoplastic compositions may further contain a stabilizer or mixture of stabilizers selected from phenolic antioxidants, hindered amine light stabilizers, ultraviolet light absorbers, organic phosphorus compounds, alkaline metal salts of fatty acids and thiosynerg1sts. The co-use of amine oxides with other stabilizers towards stabilizing polyolefins is not exemplified. Further preferred compositions comprise, in addition to components (b) and (c) further additives, in particular phenolic antioxidants, light stabilizers or processing stabilizers. Particularly preferred additives are phenolic antioxidants (item 1 of the list), further sterically hindered amines (item 2.6 of the list), light stabilizers of the benzotriazole and/or o-hydroxyphenyltriazine class (items 2.1 and 2.8 of the list), phosphites and phosphonites (item 4 of the list) and peroxide-destroying compounds (item 5.) of the list. Additional additives (stabilizers) which are also particularly preferred are benzofuran-2-ones, such as described, for example, in US-A-4,325,863, US-A-4,338,244 or US-A-5,175,312. The instant composition can additionally contain another UV absorber selected from the group consisting of the s-triazines, the oxanilides, the hydroxybenzophenones, benzoates and the a-cyanoacrylates. Particularly, the instant composition may additionally contain an effective stabilizing amount of at least one other 2-hydroxyphenyl-2H-benzo-triazole; another tris-aryl-s-triazine; or hindered amine or mixtures thereof. Preferred are additional components selected from pigments, dyes, plasticizers, antioxidants, thixotropic agents, levelling assistants, basic costabilizers, further light stabilizers like UV absorbers and/or sterically hindered amines, metal passivators, metal oxides, organophosphorus compounds, hydroxylamines, and mixtures thereof, especially pigments, phenolic antioxidants, calcium stearate, zinc stearate, UV absorbers of the 2-(2'-hydroxyphenyl)benzotriazole and 2-(2-Hydroxyphenyl)-1,3,5-triazine classes, and sterically hindered amines. It is one of the findings of present invention that an especially improved performance, both in light stability and flame retardancy, may be obtained if the thermoplastic polymer contains, besides the flame retardant, a combination of a conventional sterically hindered amine of high molecular weight with a low molecular weight sterically hindered amine of the hydroxyhydrocarbyloxyamine class. Thus, present invention also pertains to a flame retardant composition stabilized against deleterious effects of light and weathering comprising A) a thermoplastic polymer, B) a flame retardant selected from ammonium polyphosphate, halogenated and/or melamin based flame retardants, and C) a combination of sterically hindered amine light stabilizers comprising C1) a low molecular weight sterically hindered amine of the hydroxyhydrocarbyloxyamine class, and C2) a conventional high molecular weight sterically hindered amine. Preferred polymers (A) in these compositions are as initially explained (a). The halogenated flame retardants useful as component (B) in compositions of present invention may be selected from organic aromatic halogenated compounds such as halogenated benzenes, biphenyls, phenols, ethers or esters thereof, bisphenols, diphenyloxides, aromatic carboxylic acids or polyacids, anhydrides, amides or imides thereof; organic cycloaliphatic or polycycloaliphatic halogenated compounds; and organic aliphatic halogenated compounds such as halogenated paraffins, oligo- or polymers, alkylphosphates or alkylisocyanurates. These components are largely known in the art, see e.g. US patents Nos. 4,579,906 (e.g. col. 3, lines 30-41), 5,393,812; see also Plastics Additives Handbook, Ed. by H. Zweifel, 5th Ed., Hanser Publ., Munich 2001, pp. 681-698. The halogenated flame retardant may be, for example, a chlorinated or brominated compound, e.g. selected from the following compounds: Chloroalkyl phosphate esters (ANTIBLAZE® AB-100, Albright & Wilson; FYROL® FR-2, Akzo Nobel), polybrominated diphenyi oxide (DE-60F, Great Lakes Corp.), decabromodiphenyl oxide (DBDPO; SAYTEX® 102E), tris[3-bromo-2,2-bis(bromomethyl)propyl] phosphate (PB 370®, FMC Corp.), bis(2,3-dibromopropyl ether) of bisphenol A (PE68), brominated epoxy resin, ethylene-bis(tetrabromophthalimide) (SAYTEX® BT-93), bis(hexachlorocyclopentadieno)cyclooctane (DECLORANE PLUS®), chlorinated paraffins, 1,2-bis(tribromophenoxy)ethane (FF680), tetrabromo-bisphenol A (SAYTEX® RB100), ethylene bis-(dibromo-norbornanedicarboximide) (SAYTEX® BN-451), bis-(hexachlorocyclopentadieno) cyclooctane, tris-(2J3-dibromopropyl)-isocyanurate, ethylene-bis-tetrabromophthalimide. Preferred as component (B) are brominated flame retardants. Most preferred filame retardants (B) in these compositions of the invention are B1) melamin based flame retardants and/or ammonium polyphosphate, B2) bis-(hexachlorocyclopentadieno) cyclooctane, B3) tris-(2,3-dibromopropyl)-isocyanurate, B4) ethylene-bis-tetrabromophthalimide, B5) 1,2,5,6,9,10-hexabromo-cyclo-dodecan, B6) ethane-1,2-bis(pentabromophenyl), B7) tris(3-bromo-2,2-(bromomethyI)propyl) phosphate. Especially preferred flame retardants (B) in these compositions of the invention are as initially explained for component (b). The flame retardant (B) is often contained in an amount from 0.5 to 50 % by weight of the polymeric substrate (A); more preferred dosages for the most preferred flame retardants (B) are as initially explained for component (b). The ratio (B): (C) in these compositions is preferably in the range from 20 : 1 to 250 : 1. The ratio (C.1): (C2) in these compositions is often in the range from 1 : 5 to 5 : 1. In case that the polymeric substrate (A) is a polyolefin, the low molecular weight component (C1) is preferably used in about the same or in a larger amount than (C2), e.g. 40 - 95 parts by weight of (C1) on 100 total parts by weight of component (C) consisting of (C1) and (C2). In a polyolefin with main component polyethylene, the low molecular weight part (C1) often will amount about half of the total amount of component (C), e.g. from 40 to about 70, more specifically from 45 to about 55 % by weight of total component (C). In a polyolefin with main component polypropylene, the low molecular weight part (C1) often will amount rather more than half of the total amount of component (C), e.g. from 50 to about 90, more specifically from 60 to about 85 % by weight of total component (C). Under such conditions in a polyolefin, the low molecular weight component (C1) may also be of the hydrocarbyloxyamine class. Thus, another object of the invention pertains to a composition comprising A) a polyolefin, B) a flame retardant selected from ammonium polyphosphate, halogenated and/or melamin based flame retardants, and C) a combination of sterically hindered amine light stabilizers comprising, on 100 parts by weight of total component (C), C1) 40 to 95 parts by weight a low molecular weight sterically hindered amine of the hydrocarbyloxyamine class, and C2) 5 to 60 parts by weight of a conventional high molecular weight sterically hindered amine. The low molecular weight sterically hindered amine of the hydroxyhydrocarbyloxyamine or, where appropriate, hydrocarbyloxyamine class (C1) usually is from the molecular weight range 200 to 1000 g/mol, especially 300 to 800 g/mol. It may be one compound or a mixture of compounds, each fulfilling the molecular weight condition. Especially preferred are, for example, 1-cyclohexyloxy-2,2,6,6-tetramethyl-4-octadecylaminopiperidine; bis(1 -octyioxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate; bis(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) adipate; 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine. The high molecular weight sterically hindered amine (C2) is of the conventional type containing 2,2,6,6-tetramethyl-4-piperidyl moieties whose nitrogen atoms are unsubstituted (secondary sterically hindered amine) or substituted by alkyl, especially methyl (alkylated tertiary sterically hindered amine) or are part of a polymeric backbone (polymeric tertiary sterically hindered amine). It usually is from the molecular weight range 1200 to 10000 g/mol, especially 1500 to 5000 g/mol. Examples for such compounds useful in the composition of the invention can be found among those listed under item 2.6 above, e.g. the following compounds: Examples for secondary sterically hindered amines of high molecular weight Especially preferred compounds of component (C2) are those containing 2,2,6,6-tetramethyl-4-piperidyl moieties whose nitrogen atoms are unsubstituted or alkyl, especially methyl substituted. Especially preferred compounds of component (C2) are also containing triazine moieties as structural backbones. In general, component (C) is contained in an amount from 0.01 to 10 %, preferably from 0.05 to 5% by weight, especially from 0.1 to 3 % by weight, based on the polymer component (A). The weight ratio (C1): (C2) preferably ranges from 1 : 10 to 10 : 1; most preferably from 1 : 1 to 10: 1. Further components optionally to be used in these compositions of the invention, and methods of using them, are as initially explained. The following examples are for illustrative purposes only and are not to be construed to limit the instant invention in any manner whatsoever. Room temperature depicts a temperature in the range 20-25°C. Percentages are by weight unless otherwise indicated. Abbreviations: v parts by volume w parts by weight 1Hnmr nuclear magnetic resonance (NMR) of 1H m/z mass spectrometry (atomic units) amu molecular weight in g/mol (= atomic units) Mn number average of molecular weight (usually determined by GPC) PP polypropylene PE polyethylene PE-LD low density polyethylene (LDPE) Sterically hindered amines of the hydrocarbvloxvamine or hvdroxvhvdrocarbvloxyamine class (present component c) for use in the examples are the compounds c2 mixture of compounds with main component of the formula R1NH-CH2CH2CH2NR2CH2CH2NR3CH2CH2CH2NHR4 wherein 3 of R1f R2, R3 and R4 are residues of formula (example 2 of US-6117995). Further stabilizers used in the examples are compounds of formulae A R-NH-(CH2)3-N(R)-(CH2)2-N(R)-(CH2)3-NH-R (CAS Reg1stry No. 106990-43-6) B poly [[6-[(1,1,3,3-tetramethyl butyl) amino]-1,3,5-triazine-2,4-diyl][[(2,2,6,6- tetramethyl-4-piperidyl) imino] hexamethylene [(2,2,6,6-tetramethyl-4-piperidyl) imino]] (CAS-No. 70624-18-9) C bis(2,2,6,6-tetramethylpiperidin-4-yl)-sebacate (CAS-No. 52829-07-9) D E F G Compounds c2, c3 and A-G are commercial stabilizers available from Ciba Specialty Chemicals. Example 1 Sample preparation: Polymer powder and stabilizers are pre-mixed (Henschel mixer, 800 rpm, room temperature), pigment powder and flame retardant are added as concentrate in PP and homogenized in a drum mixer. Further homogenization and granulation is achieved by extrusion (Collin® twin screw extruder, max 200°C, 100 rpm). Subsequently, the mixture is processed into a flat film by means of a single screw extruder (max 200°C, 70 rpm) equipped with a corresponding nozzle (sample dimension 2mm thickness, 10 cm width). Weathering: Punched samples are exposed to accelerated weathering (Atlas® WOM Ci 65, 0.35W/m2 (at 340nm), 102 min dry, 18 min water spray, 63°C black panel temperature. The effect of weathering on the surface is assessed in the following manner: Visual inspection of chalking (chalking indicates decomposition on the surface). Gloss: Minolta; degradation of surface reduces the reflection of polarized light (60° gloss as defined in DIN 67530). A E: Colour change (according to DIN 6174). Formulation: 84 parts by weight of polypropylene-ethylene copolymer (Novolen® PPG 1022), 15 parts by weight of a PE-based flame retardant masterbatch containing 51% by weight of ethylene-bis-tetrabromophthalimide (b4) and 17 % by weight of Sb203, 1 part by weight of Ti02 and 0.2 parts by weight of blue pigment (Cromophtal blue 4GNP) and stabilizers as shown in the following table (amounts g1ven in % by weight of the total formulation). The results are shown in the following table. Samples containing the combination of flame retardant and sterically hindered amine of present invention show no chalking, better gloss and distinctly less colour change than samples wherein present component c has been replaced by another sterically hindered amine. Example 2 Samples are prepared and subjected to accelerated weathering as described in example 1. Formulation: 89 parts by weight of polypropylene-ethylene copolymer (Novolen® PPG 1022), 10 parts by weight of a PE based flame retardant masterbatch containing 30% by weight of tris-(2,3-dibromopropyl)-isocyanurate (b3) and 15 % Sb203, 1 part by weight of Ti02 and 0.2 parts by weight of blue pigment (Cromophtal blue 4GNP) and stabilizers as shown in the following table (amounts g1ven in % by weight of the total formulation). The results are shown in the following table. Replacing compound c3 in the above example by the same^amount of c2 or c4 also leads to superior properties. Example 3 Sample preparation: Polymer powder, flame retardant and stabilizers are pre-mixed (Henschel mixer, 800 rpm, roopm temperature), pigment is added as concentrate in PE-LD and homogenized in a drum mixer. Further homogenization and granulation is achieved by extrusion (Berstorff® twin screw extruder (max 220°C, 100 rpm). Test samples (44 x 68 x 2 mm) are obtained by compression moulding (Engel) at a plastification temperature of max 200°C and a forming temperature of 50°C. Accelerated weathering and assessment of the samples is done as described in example 1. Formulation: 73 parts by weight of polypropylene-ethylene copolymer (Appryl ® 3060), 25 parts by weight of melamin polyphosphate (flame retardant b1, Melapur® P 46), 2 parts by weight of blue pigment masterbatch (10% Cromophtal blue 4GNP in PE-LD) 0.15 parts by weight of a commercial phenolic antioxidant (1 : 1 mixture of tris(2,4-di-t-butyiphenyi)phosphite and pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate], available from Ciba Specialty Chemicals) and stabilizers as shown in the following table (amounts g1ven in % by weight of the total formulation). The results are shown in the following table. Example 4 Sample preparation, accelerated weathering and assessment of the samples is done as described in example 3. Formulation: 82 parts by weight of polypropylene-ethylene copolymer (Appryl ® 3060), 12 parts by weight of bis-(hexachlorocyclopentadieno) cyclooctane (flame retardant b2, Dechloran Plus ®), 4 parts by weight of Sb203 2 parts by weight of blue pigment masterbatch (10% Cromophtal blue 4GNP in PE-LD) 0.15 parts by weight of a commercial phenolic antioxidant (1 : 1 mixture of tris(2,4-di-t-butylphenyl)phosphite and pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate], available from Ciba Specialty Chemicals) and stabilizers as shown in the following table (amounts g1ven in % by weight of the total formulation). The results are shown in the following table. Example 5 Sample preparation, accelerated weathering and assessment of the samples is done as described in example 3. Formulation is identical with the one of example 3 except that the melamin polyphosphate flame retardant is replaced by the same amount of ammonium polyphosphate (flame retardant b1; Exolith ® AP 752). Results are shown in the following table. Example 6 Sample preparation, accelerated weathering and assessment of the samples is done as described in example 3. Formulation: 92 parts by weight of polypropylene-ethylene copolymer (Appryl ® 3060), 4 parts by weight of tris(3-bromo-2,2-(bromomethyl)propyl) phosphat (flame retardant, FR 372 from Dead See Bromine), 2 parts by weight of Sb203 2 parts by weight of blue pigment masterbatch (10% Cromophtal blue 4GNP in PE-LD) 0.15 parts by weight of a commercial phenolic antioxidant (1 : 1 mixture of tris(2,4-di-t-butylphenyl)phosphite and pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate], available from Ciba Specialty Chemicals) and stabilizers as shown in the following table (amounts g1ven in % by weight of the total formulation). The results are shown in the following table. Example 7 Sample preparation, accelerated weathering and assessment of the samples is done as described in example 3. Formulation: 88 parts by weight of polypropylene-ethylene copolymer (Appryl ® 3060), 8 parts by weight of ethane-1,2-bis(pentabromophenyl) (flame retardant b6, Saytex®8010), 4 parts by weight of Sb203 2 parts by weight of blue pigment masterbatch (10% Cromophtal blue 4GNP in PE-LD) 0.15 parts by weight of a commercial phenolic antioxidant (1 : 1 mixture of tris(2,4-di-t-butylphenyl)phosphite and pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate], available from Ciba Specialty Chemicals) and stabilizers as shown in the following table (amounts g1ven in % by weight of the total formulation). The results are shown in the following table. WHAT IS CLAIMED IS: 1. A process for imparting light stability and flame retardancy to a thermoplastic polymer (a) by addition of a flame retardant (b) and a sterically hindered amine (c), which process is characterized in that the flame retardant (b) is selected from the group consisting of b1) melamin based flame retardants and/or ammonium polyphosphate, b2) bis-(hexachlorocyclopentadieno) cyclooctane, b3) tris-(2,3-dibromopropyl)-isocyanurate, b4) ethylene-bis-tetrabromophthalimide, b5) 1,2,5,6,9,10-hexabromo-cyclo-dodecan, b6) ethane-1,2-bis(pentabromophenyl); and the sterically hindered amine (c) is selected from sterically hindered amine light stabilizers of the hydrocarbyloxyamine and of the hydroxyhydrocarbyloxyamine class, provided that the flame retardant is not (b4) if the sterically hindered amine is of the hydroxyhydrocarbyloxy class. 2. Process of claim 1 for imparting outdoor weathering stability and flame retardancy to a thermoplastic polymer, which is a polyolefin. 3. Process of claim 1 wherein the sterically hindered amine light stabilizer of component c is a cyclic sterically hindered amine conforming to the formula wherein G1 and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene, and E1 is d-Ciaalkyl, C5-C12cycloalkyl or C7-C15aralkyl; or Et is CrC18alkyl, C5-C12cyclo-alkyl or C7-C15aralkyl each of which is substituted in the aliphatic part by 1-3 OH groups; T is a divalent organic radical required to complete formula (I) to form, together with the hindered amine nitrogen atom and the two quaternary carbon atoms substituted by G1 and G2, a five- or six-membered aliphatic ring structure, especially a piperidine ring; or is an oligomeric or polymeric hindered amine molecule made from the reaction of a dialkyl ester or isocyanate with a compound of the formula (I) wherein Et contains 1 OH group and T is -CH2-CH(OH)-CH2- or is a simple diester or urethane derivative of a compound of the formula (I) wherein E1 contains 1 OH group and T is -CH2-CH(OH)-CH2- 4. Process of claim 1, wherein component c is added in an amount of 0.01 to 10 % by weight, based on the weight of the polymer (a). 5. Process of claim 1. wherein component b1 is added in an amount from 1 to 50 % by weight, or one or more of components b2, b3, b4, b5, b6 in a total amount from 0.5 to 20 % by weight, each amount based on the weight of the polymer (a). 6. Process of claim 1 for imparting both weathering stability and flame retardancy to a polyethylene, polypropylene, or copolymer or blend thereof. 7. Process of claim 1 wherein one or more further components selected from the group consisting of pigments, dyes, plasticizers, antioxidants, thixotropic agents, levelling assistants, basic costabilizers, further light stabilizers, metal passivators, metal oxides, organophosphorus compounds, hydroxyiamines, and mixtures thereof, are also added. 8. Process of claim 7, wherein the further component is selected from the group consisting of pigments, phenolic antioxidants, calcium stearate, zinc stearate, sterically hindered amines, UV absorbers. 9. Process of claim 8, wherein the further component is selected from UV absorbers of the 2-(2'-hydroxyphenyl)benzotriazole, 2-(2-hydroxyphenyl)-1,3,5-triazine, 2-hydroxyphenylbenzophenone classes. 10. A flame retardant and light stabilized composition comprising a) a polyolefin, b) tris-(2,3-dibromopropyl)-isocyanurate as a flame retardant and c) a sterically hindered amine light stabilizer of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class. 11. A flame retardant and light stabilized composition comprising a) a polyolefin, and b) a flame retardant selected from b1) melamin based flame retardants and/or ammonium polyphosphate, b2) bis-(hexachlorocyclopentadieno) cyclooctane, b3) tris-(2,3-dibromopropyl)-isocyanurate, b5) 1,2,5,6,9,10-hexabromo-cyclo-dodecan, b6) ethane-1,2-bis(pentabromophenyl); and c) a sterically hindered amine light stabilizer of the hydroxyhydrocarbyloxyamine class. 12. A flame retardant and light stabilized composition according to claim 11 wherein component c contains a compound of the formula wherein G1 and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene, and E1 CrC18alkylf C5-C12cycloalkyl or C7-C15aralkyl each of which is substituted in the aliphatic part by 1-3 OH groups; T is a divalent organic radical required to complete formula (I) to form, together with the hindered amine nitrogen atom and the two quaternary carbon atoms substituted by G1 and G2, a five- or six-membered aliphatic ring structure, especially a piperidine ring; or is an oligomeric or polymeric hindered amine molecule made from the reaction of a dialkyl ester or isocyanate with a compound of the formula (I) wherein E1 contains 1 OH group and T is -CH2-CH(OH)-CH2-; or is a simple diester or urethane derivative of a compound of the formula (I) wherein E1 contains 1 OH group and T is -CH2-CH(OH)-CH2-. 13. A flame retardant and light stabilized composition according to claim 11 wherein .* component c contains a compound 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine. 14. A flame retardant composition stabilized against deleterious effects of light and weathering comprising a) a thermoplastic polymer, b) a flame retardant selected from ammonium polyphosphate, halogenated and/or melamin based flame retardants, and c) a combination of sterically hindered amine light stabilizers comprising ct) a low molecular weight sterically hindered amine of the hydroxyhydrocarbyloxyamine class, and c2) a high molecular weight secondary or alkylated or polymeric tertiary sterically hindered amine. 15. Composition according to claim 14, wherein component (a) is a polyolefin. 16. A flame retardant composition stabilized against deleterious effects of light and weathering comprising a) a polyolefin, b) a flame retardant selected from ammonium polyphosphate, halogenated and/or melamin based flame retardants, and c) a combination of sterically hindered amine light stabilizers comprising, on 100 parts by weight of total component (c), d) 40 to 95 parts by weight a low molecular weight sterically hindered amine of the hydroxyhydrocarbyloxyamine or hydrocarbyloxyamine class, and c2) 5 to 60 parts by weight of a high molecular weight secondary or alkylated or polymeric tertiary sterically hindered amine. 17. Composition according to claim 14 or 16, wherein component (b) is selected from b1) melamin based flame retardants and/or ammonium polyphosphate, b2) bis-(hexachlorocyciopentadieno) cyclooctane, b3) tris-(2,3-dibromopropyl)-isocyanurate, b4) ethylene-bis-tetrabromophthalimide, b5) 1,2,5,6,9,10-hexabromo-cyclo-dodecane, b6) ethane-1,2-bis(pentabromophenyl), b7) tris(3-bromo-2,2-(bromomethyl)propyl) phosphate. 18. Composition according to claims 14 or 16, wherein the low molecular weight sterically hindered amine of the hydrocarbyloxyamine or hydroxyhydrocarbyloxyamine class (c1) is from the molecular weight range 200 to 1000 g/mol, and the high molecular weight sterically hindered amine (c2) is from the molecular weight range 1200 to 10000 g/mol. 19. Composition according to claims 10 or 11 or 14 or 16 containing component (b) in an amount from 0.5 to 50 % by weight, and component (c) in an amount of 0.01 to 10 % by weight, each based on the weight of component (a). 20. Composition according to claims 10 or 11 or 14 or 16 additionally containing one or more further components selected from pigments, dyes, plasticizers, antioxidants, thixotropic agents, levelling assistants, basic costabilizers, metal passivators, metal oxides, organophosphorus compounds, hydroxylamines, further light stabilizers and mixtures thereof. 21. Composition according to claims 10 or 11 or 14 or 16 additionally containing one or more further components selected from pigments, phenolic antioxidants, calcium stearate, zinc stearate, sterically hindered amines, UV absorbers of the 2-hydroxy-benzophenone, 2-(2'-hydroxyphenyl)benzotriazole and/or 2-(2-hydroxyphenyl)-1,3,5-triazine classes. 22. Molded or extruded article comprising a composition according to claims 10 or 11 or 14 or 16. 23. A flame retardant and light stabilized composition substantially as herein described and exemplified. |
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0997-mas-2001 abstract-duplicate.pdf
0997-mas-2001 claims-duplicate.pdf
0997-mas-2001 description (complete)-duplicate.pdf
997-mas-2001-correspondence others.pdf
997-mas-2001-correspondence po.pdf
997-mas-2001-description complete.pdf
Patent Number | 224254 | |||||||||
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Indian Patent Application Number | 997/MAS/2001 | |||||||||
PG Journal Number | 47/2008 | |||||||||
Publication Date | 21-Nov-2008 | |||||||||
Grant Date | 10-Oct-2008 | |||||||||
Date of Filing | 11-Dec-2001 | |||||||||
Name of Patentee | CIBA HOLDING INC. | |||||||||
Applicant Address | KLYBECKSTRASSE 141, 4057 BASEL, | |||||||||
Inventors:
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PCT International Classification Number | C08K5/34 | |||||||||
PCT International Application Number | N/A | |||||||||
PCT International Filing date | ||||||||||
PCT Conventions:
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