Title of Invention

A METHOD OF MAKING A WEB

Abstract A method of making a web is disclosed. The method involves the steps of providing a web of softened material; depositing the web of softened material on a screen, subjecting the softened web to vacuum such that macro-protuberances are formed in the web, subsequent to subjecting the softened web to vacuum, contacting the web with a fluid with sufficient energy to cause the solid web to permanently deform without aperturing the web in locations overlaying the aberrations in the screen to form unapertured micro- protuberances; and removing the web from the screen.
Full Text A METHOD OF MAKING A WEB
FIELD OF THE INVENTION
The present invention relates to a method of making a web, and
more specifically, to an improved formed film for use in body contacting
absorbent and non-absorbent articles such as baby diapers, adult incontinent articles,
sanitary napkins or panty liners, facial wipes, body wipes, articles of clothing,
hospital bed sheets and the like. The absorbent articles usually include a liquid
pervious top sheet and a liquid impervious back sheet. At least one of the
components included in at least one of the top sheet or the back sheet comprises a
formed film of the invention. The invention is directed to the improved articles, the
improved films, the method of forming the formed films, and the apparatus used to
form the films.
DESCRIPTION OF RELATED ART
It is known to form three-dimensional films, or formed films, by causing a molten
polymer sheet to conform to the shape of a forming screen. Commonly utilized
apertured formed film top sheets are disclosed in for example, Thompson, U.S.
Patent Nos. 3,929,135, Mullane et al., U.S. Patent 4,324,246, Radel et al, U.S.
Patent 4,342,314, Raley et al., U.S. Patent No. 4,252,516, Thomas et al, U.S. Patent
No 4,535,020, Junker et al, U.S. Patent No. 5,591,510, U.S. Application Nos.
09/876440 filed June 6, 2001, and 60/346751 filed January 17, 2002, to Thomas and
U.S. Application No. 10/082040 filed February 20, 2002, to Copal, et al. The
disclosures of each of these documents are incorporated by reference herein in their
entirety. The top sheets disclosed in these documents utilize vacuum, to cause the
polymer sheet to conform to the screen and also to cool. A preferred feature of these
top sheets is that the polymer crystallizes, or "sets," after the molten polymer has
been formed into a three-dimensional shape. The resultant formed film therefore is
said to have "three-dimensional memory." After formation and cooling, the film
usually is wound into a roll.
When the roll is transported, particularly during summer transport and storage in
trucks or non-air conditioned warehouses, web tensions and heat tend to compress
the formed film causing it to temporarily lose some of its valuable three-
dimensionality. The film also is compressed after it is incorporated into an article
and the article is packaged. Three-dimensional memory enables the formed film to
regain its original shape after the non-deforming forces are removed, usually within a
few hours. This capability to resist deformation and to regain three-dimensional
shape is called "resiliency." A disadvantage of these vacuum formed films is that the
fiber-like wires that form the regulated pattern of apertures MAY exhibit a plastic-
like surface and feeling. The plastic-like surface and feeling is viewed negatively by
certain consumers that prefer nonwoven or woven cloth-like surface and feeling.
It also is known to utilize high pressure water jet systems to cause two-dimensional
polymeric webs to conform to forming structures in order to create three-dimensional
webs. U.S. Pat. Nos. 4,609,518, 4,629,643, 4,695,422, 4,778,644, and 4,839,216 to
Curro (referred to herein as "the Curro patents" and "the Curro process") describe a
multitude of web designs created by the combination of forming structures and high
pressure water jet systems. The disclosures of each of the Curro patents are
incorporated by reference herein in their entirety. In the Curro process, pressurized
water is ejected from nozzles projecting water onto the surface of a two-dimensional,
or flat, polymeric web causing the web to conform to the surface of an underlying
support screen. As the screen rotates, subsequent portions of the web pass under the
water jet causing subsequent portions of the web to conform to the screen. One
advantage of the high pressure water systems is that the energy, or work, employed
to force the un-molten web to conform to the screen is believed to soften the web,
therefore water formed films are perceived as being more cloth-like in appearance
and feeling than vacuum formed films.
In a preferred embodiment, Curro describes the use of a 1st stage water system that
utilizes a 1st screen comprising micro-apertures to create micro-protuberances in the
film that give the film a soft feeling texture. The micro-apertured or micro-bubbled
film is useful as a back sheet. Subsequently, the film can be passed through a 2nd
stage water system that utilizes a 2nd screen comprising macro-apertures to create
macro-protuberances in the film that give the firm liquid acquisition functionality. In
summary, the 1st stage provides softness and texture, and the 2nd stage provides
apertures for liquid acquisition functionality.
Films produced by the high pressure water jet systems described above are believed
to have several disadvantages, including primarily poor resiliency, or stated
differently, "flat film" memory. Because the precursor films used in high pressure
water jet systems are made flat and then are subsequently made to conform into
three-dimensional shapes, crystallization occurs while the webs are flat, and as a
result the films have flat film memory. Films with flat film memory tend to regain
their flat film shape over time, thereby losing the three-dimensional shape and its
benefits. Another disadvantage of two-stage water jet systems is that the second
stage jets spray water onto 1st stage holes micro-protuberances, thereby damaging
them.
Another disadvantage of the Curro process is that the 1st and 2nd stage system each
require water to penetrate through the screen to form the apertures, thereby requiring
an internal water removal system. These internal systems add complexity and cost,
and increase maintenance requirements, which in turn reduces equipment utilization.
Yet another disadvantage of the Curro process is that the two-stage high pressure
water jet systems are expensive to operate — each stage requiring construction of a
screen and procurement of high pressure water, each of which increases cost.
Where the formed films described above are used in a top sheet application, it is
common to incorporate in their formulation a, surfactant. The surfactant will bloom
to the surface of the film over time and will render the film hydrophilic, which is a
desirable property in films designed for fluid acquisition functions. One
disadvantage of the two-stage water process, described in U.S. Pat. Nos. 5,834,092,
5,792,412, and 6,228,462 to Yann-Per Lee, the disclosures of which are incorporated
by reference herein in their entirety, is that a significant amount of surfactant blooms
to the surface of the web before the web reaches the second stage and such surfactant
is therefore washed away by the water jet. Besides the obvious problems associated
with the loss of surfactant and the fact that there is an upper limit to the amount of
surfactant that can be incorporated in a film, there also is the problem that surfactant
washed away by the water jet builds up in the water system causing it to fail
prematurely or, alternatively, requiring additional cleaning and maintenance efforts.
Surfactant losses are made worse by the application of hot water during the 1st stage,
whereby the heated water increases molecular mobility which in turn accelerates the
blooming rate causing even more surfactant to wash away during the 2nd stage.
One proposed solution to the above problems is the formation of three-dimensional
apertures in nonwoven webs, such as, for example, by spunlacing, needle-
perforation, or embossing systems. Very soft webs can be formed by these
processes. However, the three-dimensional structures of such webs exhibit poor
resiliency because they lack three-dimensional memory.
U.S. Patent No.6,180,052 describes a method for converting a ribbon of
polyethylene film into an apertured formed film. The method includes applying
a high pressure fluid jet comprised of water or the like against one surface of
the film, while applying a vacuum adjacent the opposite surface of the film.
An alternative solution to the above problems is the lamination of nonwoven webs,
apertured or unapertured, or of staple fibers, to vacuum formed films. Such
combinations are described in U.S. Pat. Nos. 4,995,930, 5,591,510, 5,635,275,
5,635,276, 5,660,882, 5,698,054, 5,762,643, 5,733,628, 5,783,014, 6,242,074, and
6,303,208. The disclosures of each of these patents are incorporated by reference
herein in their entirety. Very soft and resilient webs can be formed by the lamination
process described therein. However, such webs are expensive to manufacture
because they require preparation of two precursor materials and their subsequent
lamination.
The description herein of disadvantages associated with previous products, methods,
and apparatus is in no way intended to limit the invention to embodiments that do
not include these products, methods, and apparatus. Indeed, certain embodiments of
the invention may include some or all of these previous products, methods, and
apparatus without suffering from the disadvantages noted herein.
SUMMARY OF THE INVENTION
It is a feature of an embodiment of the present invention to create a more effective
soft and resilient web. Another feature of an embodiment of the present invention is
to provide an economical method for production of the webs of the invention.
The present invention therefore is directed to an improved method for forming three-
dimensional polymeric webs, to the improved soft and resilient webs made thereby,
and to body-contacting articles comprising as one of their components the improved
soft and resilient webs.
In accordance with these and other features of various embodiments of the invention,
there is provided a single-stage forming, texturing and softening process for making
a soft and resilient formed film. In the process of the invention, a molten polymer
sheet, or a reheated precursor web, is placed in contact with an apertured rotating
screen under the influence of vacuum. The apertured rotating screen includes wires
that define a regulated pattern of apertures, whereby the wires are provided with
texture. The apertured rotating screen and the impetus of vacuum cause the molten
web to conform to the shape of the apertured rotating screen and, as air passes
through the apertures, cause the molten web to cool, thereby obtaining three-
dimensional memory. The vacuum also causes the molten web to come into contact
with the textured surface of the wires causing at least partial formation of a textured
pattern on the inner surface of the film. After application of vacuum and while the
apertured three-dimensional web remains in close contact with the rotating screen,
fluid is applied to the film to soften it and to cause it to conform even more to the
textured screen wires. The film then can be removed from the screen after
application of fluid, and dried if necessary.
Advantageously, a single-stage process eliminates the cost associated with a second
stage, and minimizes the distance and time the web must travel before contacting
fluid, thereby minimizing the amount of surfactant wash-off. Because there is no 2nd
water jet application stage, surfactant wash-off is reduced even more. Also
advantageously, because the single screen supports both the macro-protuberances
and the micro-protuberances while the fluid softening/texturing procedure takes
place, the damage caused by fluid to the 1st set of micro-protuberances in the Curro
process is eliminated. Yet another advantage of the process of the invention is that
by texturing around screen aberrations instead of micro-apertures, fluid does not
have to penetrate through micro-peforations in the screen of Curro to form the
texture thereby permitting use of an external water removal system. In addition to
the benefits of external versus internal systems, the use of a blower system to blow-
out water that may reside inside of the large vacuum formed apertures enhances
Agent's File Reference 44904.548PCT
dryness and permits the use of a smaller, less expensive, drying systems.
The resulting web of the invention has the resiliency of vacuum formed films and has
improved softness of water formed films, when compared to prior art vacuum
formed films.
Brief Description of the Accompanying drawings
Figure 1 is a schematic of a known vacuum forming system.
Figure 2 is a schematic of a known two-stage high pressure water jet forming system.
Figure 3 is a schematic of an embodiment of a single-stage forming system of the
invention.
Figure 4 is a schematic of another embodiment of a single-stage forming system of
the invention.
Figure 5 is a cross-section of a web made in accordance with the present invention.
Figure 6 is a cross-section of an absorbent article that includes a soft web of the
present invention.
Figure 7 is a cross-section of an exemplary screen enveloped in etch-resist coating.
Figure 8 is a cross-section of an exemplary screen enveloped in etch-resist coating
and covered with a photosensitive mask.
Figure 9 is a cross-section of an exemplary screen enveloped in etch-resist coating
after metal has been etched away to expose surface aberrations.
Figure 10 is a cross-section of an exemplary screen provided with texture by an
etching process.
Figure 11 is a cross-section of an exemplary film made by a known method.
Figure 12 is a cross-section of an exemplary film made by a known method.
Figure 13 is a cross-section of an exemplary film made by the novel method of the
invention.
DETAILED DESCRIPTION OF THE
EXEMPLARY EMBODIMENTS OF THE INVENTION
Set forth below are definitions of some of the terms and expressions used herein.
The term "substantially" means that a given property or parameter (such as the
surface angle) may vary by about 30% from the stated value.
The phrase "regulated pattern" means regions of protuberances in the film (and
therefore in the component(s) of the absorbent article which include the film) where
a selected property or selected properties of the capillaries are repeatably controlled,
i.e., the property or properties is or are controlled to achieve a desired pattern of the
selected property or properties. If a region comprises a regulated pattern of
capillaries, it does not necessarily mean that all capillaries in that region have exactly
the same property (or properties) which was selected to be controlled. It means that
the selected property is varied in a designed, prescribed manner (or pattern) to
substantially achieve a particular formula. Each region has only one regulated
pattern.
The term "permeability" refers to the permeability of vapor or liquid. The term
"coverstock" refers to the body contacting web which is part of a personal care
article. Coverstock webs can be film webs, nonwovens webs, laminate webs and
apertured laminate webs. The term "web" refers to a material capable of being
wound into a roll. Webs can be film webs, nonwoven webs, laminate webs,
apertured laminate webs etc. The term "sheet" refers to a curtain of extruded molten
polymer that has not solidified into a film.
The term "film" refers to a web made by extruding a molten sheet of polymeric
material by a cast or blown extrusion process and then cooling the sheet to form a
solid polymeric web. Films can be monolayer films, coextruded films, coated films,
and composite films. Coated films are films comprising a monolayer or coextruded
film that are subsequently coated (extrusion coated, impression coated, printed) with
a thin layer of the same or different material to which it is bonded, and after bonding,
is incapable of separation under normal use conditions. Composite films are films
comprising more than one film where the at least two films are bonded in a bonding
process. Bonding processes may incorporate adhesive layers between the film layers
or heat and/or pressure.
The term "fluid" is used herein to denote a flowable material, and preferably a
material whose flow rate can be increased by an increase in pressure. Exemplary
fluids include water, air, gels, and combinations thereof. Preferred fluids include
water and air.
The term "panel" means a square or rectangularly shaped sheet of steel or similar
material. The term "plate" means a bonded stack of panels. The term "perforation"
as used herein refers to an aperture in the screen.
The term "indentation" as used herein refers to a recess, or dcbossment, located at
least on the outermost surface of the screen. Indentations may connect the outermost
surface and the innermost surface of the screen to create perforations in the screen.
In other words, perforations are indentations but indentations are not necessarily
perforations.
The phrase "inner surface" when referring to the formed film means the flat film
surface that comes into contact with the screen surface. The phrase "inner surface"
when referring to the screen means the screen surface that does not come into
contact with the film and which is opposite the film-contacting surface of the screen.
The film-contacting surface of the screen is called the "outer surface" of the screen.
The term "aberration" as used herein refers to a three-dimensional member, or
embossment, with a base portion located on the outermost surface of the screen and
an apex projecting outwardly from the surface of the screen. Aberrations may form
regulated patterns or may be placed randomly on the screen surface.
The expression "minimum width" as used herein to describe apertures, perforations,
or indentations, means the minimum distance possible between any two edges
measured on the plane of the aperture (or perforation or indentation). The minimum
width of a circle is its diameter. The minimum width of an ellipse is the length of its
minor axis. The minimum width of a slot is the distance between its parallel long
edges.
The expression "maximum width" as used herein to describe apertures, perforations,
or indentations, means the maximum distance possible between any two edges
measured on the plane of the aperture (or perforation or indentation). The maximum
width of a circle is its diameter. The maximum width of an ellipse is the length of
its major axis. The maximum width of a slot is the distance between its edges
measured along a direction that is parallel to its length.
The term "mesh" as used herein to describe a regulated pattern means the square root
of the maximum number of polygonal shapes (such as first apertures or protrusions)
that can be inscribed in a flat square area measuring 1 inch (25,400 urn) on the side.
Mesh can also be defined by describing the manner in which the protrusions are
located in relation to each other as measured by their center-to-center distances. For
example, a tightly packed square pattern of protuberances with 0.1 inch center-to-
center distances is a 10 mesh square pattern. A tightly packed hexagonal pattern of
protuberances with 0.1 inch center-to-center distances is a 10.7 mesh hexagonal
pattern (hexagonal patterns being packed more tightly than square patterns). A
tightly packed hexagonal pattern of protuberances with 0.01 inch center-to-center
distances is a 107 mesh hexagonal pattern.
The term "screen" as used herein refers to a three-dimensional molding apparatus
comprising indentations used to form protuberances in films. In a particularly
preferred embodiment screens comprise tubular members, having a length and a
diameter, m alternative embodiments screens comprise belts having a width and a
length. The transverse direction is the direction parallel to the width of the screen.
The machine direction is the direction parallel to the direction of rotation of the
screen, and is perpendicular to the transverse direction.
The phrase "macro-protuberance" can be defined by reference to a three-dimensional
member comprising an apertured base portion located in the plane of the first surface
of the film and a sidewall portion extending generally in the direction of the second
surface of the film. Each base portion has a sidewall portion. Sidewall portions
terminate at an apex located in the plane of the second surface of the film. A
macro-protuberance is a relatively large protuberance extending from the first
surface to the second surface, and is comprised of the aperture in the base portion in
the first surface, the sidewalls, and the end in the second surface. The ends of the
protuberances may be apertured or unapertured. An apertured macro-protuberance
also is referred to herein as a macro-aperture.
The apertures in the base portions of the protuberances, also called "primary
apertures", are preferably in the shape of polygons, e.g., squares, hexagons,
pentagons, ellipses, circles, ovals, slots, etc., in a regulated or random pattern. The
protubered ends if apertured are called "secondary apertures", and are preferably in
the shape of polygons, e.g., squares, hexagons, pentagons, ellipses, circles, ovals,
slots, etc. Macro-protuberances in the film correspond to relatively large
indentations in the screen, and apertured macro-protuberances in the film correspond
to perforations in the screen.
The phrase "micro-protuberance" can be defined by reference to a three-dimensional
member comprising an apertured base portion located in the plane of the first surface
of the film and a sidewall portion extending generally in the direction of a third
surface of the film. Each base portion has a sidewall portion. Sidewall portions
terminate at an apex located in the plane of the third surface of the film. A micro-
protuberance is a relatively small protuberance extending from the first surface to a
third surface, and is comprised of an aperture in the base portion in the first surface,
the sidewalls, and the end in the third surface. The ends of the micro-protuberances
may be apertured or unapertured. An apertured micro-protuberance also is referred
to herein as a micro-aperture. The apertures in the base portions of the micro-
protuberances, also called "primary apertures", are preferably in the shape of
polygons, e.g., squares, hexagons, pentagons, ellipses, circles, ovals, slots, etc., in a
regulated or random pattern. Micro-protuberances in the film correspond to
aberrations in. the screen.
The prefix "macro" as used herein refers to structural features or elements that are
readily visible to a normal human eye when the perpendicular distance between the
viewer's eye and the plane of the web is about 30 centimeters (cm). Conversely, the
prefix "micro" is utilized to refer to structural features or elements that are not
readily visible to a normal human eye when the perpendicular distance between the
viewer's eye and the plane of the web is about 30 cm.
With regard to the protubered webs of the present invention, a given protubernace's
"amplitude" refers to the distance from the plane where the protuberance originates
to the surface where the protuberance terminates.
As used herein, the phrase "female side" denotes the side or surface of a web where
the protuberances being described originate. In contrast, the phrase "male side"
denotes the side or surface of a web where the protuberances being described
terminate. In the case of webs having both macro-protuberances and micro-
protuberances, where the macro and micro-protuberances extend in opposite
directions, the female side will be the side or surface of the web where the macro-
protuberances originate, and the male side will be the side or surface of the web
where the macro-protuberance terminates.
Typically, use of the phrase "micro-protuberance" refers to an protuberance having
as its maximum width a distance of not more than about 300 mm, preferably not
more than about 200 mm, still more preferably not more than about 100 mm. The
phrase "macro-protuberance" typically refers to an aperture having,a maximum
width of greater than about 300 mm.
As used herein, the phrase "migratable surfactant" refers to any surfactant that is
chemically incompatible with the thermoplastic polymer with which it is combined,
such that it will migrate to the film's surface over time to alter the fluid handling
dynamics of the polymer's surface. Representative materials useful as the surfactant
and the thermoplastic polymer are described below.
Figure 1 is a schematic of a known vacuum forming system. A polymer blend is
conveyed, mixed and blended in an extruder (not shown) and delivered to the
extrusion die 10, preferably a cast extrusion die 10. A molten polymer curtain 12, or
sheet, exits the die and is laid over a rotating apertured screen 14. The screen
conveys the polymer sheet over vacuum slot 16 where air is forced to pass through
the sheet and into the vacuum tube 18 forming apertures in the film that conform to
the apertures in the screen. The formed film 42 is taken off of rotating apertured
screen 14 at roller 40.
Such vacuum forming systems are described in, for example, U.S. Patent Nos.
3,929,135, 4,324,246, 4,342,314, 4,252,516, 4,535,020, 5,591,510, U.S. Application
Nos. 09/876440 filed June 6, 2001, 60/346751 filed January 17, 2002, and
10/082040 filed February 20, 2002, the disclosures of which are incorporated by
reference herein in their entirety. The fiber-like interconnecting wires that define
the apertures in the screen may be microtextured according to the teachings of Ahr,
U.S. Patent No. 4,465,045 ("Ahr"). Microtexture is defined by Ahr as aberrations
(e.g., micro-protrusions) whose amplitude is about 0.3 mils (7.5 mm). The
aberrations preferably are arranged in a hexagonally close packed pattern with at
most 4 mil (100 mm) center-to-center spacing between adjacent aberrations. Such a
regulated pattern of aberrations also can be described as a hexagonal 267 mesh
pattern. As disclosed by Ahr, the microtexture can be obtained by etching the outer
surface of the screen.
Figure 2 is a schematic of a known two-stage high pressure water forming system.
A polymer blend is conveyed, mixed and blended in an extruder and delivered to the
extrusion die. The molten polymer curtain, or sheet, exits the die and is laid over a
rotating two roll embossing system 100 where the web is pressed and cooled and
thereby acquires two-dimensional memory. The flat film is conveyed over a 1st stage
water forming station 102 and is caused to form micro-apertures by spraying high
pressure water on the film, that is supported by screen 104. Subsequently, the micro-
apertured film is conveyed over a 2nd stage water forming station 112 and is caused
to form macro-apertures by spraying high pressure water on the film that is
supported by screen 110. The formed film then is dried in drying apparatus 114.
One particularly important feature of this process is that the micro-apertures
terminating at a third surface formed by forcing film into micro-perforations in the
screen in the Is1 stage extend in opposite direction as the macro apertures terminating
at a 2nd surface, which are formed in the 2nd stage. In other words the third surface is
not intermediate the first and second surfaces. Another important feature of this
process is that the 2nd stage forming screen provides web support to the film but it
does not conform to the micro-perforation pattern of the lsl stage. Accordingly,
even though the web is supported, the 1st stage micro-apertures are not, and as a
result, the 2nd stage water jet deforms the 1st stage micro-apertures. This is evident
clearly by the observable variation in micro-apertured diameter shown in Figure 10
of U.S. Pat. No. 6,228,462, the disclosure of which is incorporated herein by
reference in its entirety, which figure is an image of a film made by this process.
Figure 3 is a schematic of a preferred embodiment of a single-stage vacuum and
fluid forming system of the invention. In general, the soft, resilient web can be made
using a single rotating screen, a vacuum section, and a fluid application section. In
accordance with the preferred method, a polymer blend first is conveyed, mixed and
blended in an extruder by means well known in the art and therefore not shown or
described in detail herein. The molten polymer can be delivered to an extrusion die
10. The molten polymer curtain 12, or sheet, exits the die and preferably although
not necessarily is immediately laid over a rotating screen 14. Preferably, the screen
14 is an aperture forming/texturing screen 14. As the screen rotates the molten
polymer is carried over vacuum block 16 where vacuum is applied to form macro-
protuberances, and to cool the molten sheet. During this cooling process, the film
crystallizes, either partially or fully, and acquires three-dimensional memory. The
vacuum at vacuum block 16 can be created by suctioning air at one or both ends of
vacuum tube 18, for example. Other techniques for creating a vacuum at vacuum
block 16 will be readily apparent to those skilled in the art, and can be used in the
context of the invention described and claimed herein.
The now resilient macro-protuberanced, preferably macro-apertured film and the
screen move together to a water jet nozzle 20. A water stream 22 impinges on the
film while the screen is supported by a support block 24. Applying the water
through water jet nozzle 20 serves to "work" the fiber-like wires of the film to soften
them, and also causes the film to adopt a mirror image of the texturing surface
present in the fiber-like wires of the screen. The texture of the screen was previously
impressed upon the inner surface of the film during the vacuum forming step and is
now more clearly impressed such that it is more clearly visible and palpable. The
additional texture enhances the perception of softness. The soft and resilient film
continues to travel as the screen continues to rotate, until it passes over a blower
block 26.
Air preferably is blown from one or both ends of a blown air tube 28 and exits the
tube through the blower block 26 and through the macro-apertures in the soft and
resilient film. As air passes through the hole it removes water droplets that might
have lodged inside the apertured film protrusions. Further water removal takes place
as the film passes over a support block and a water removal roller 30. Process water
is captured by an external drip pan 32, enabling its easy removal and further
treatment prior to disposal or recycle, if desired.
The soft and resilient film 42 then preferably is removed from the screen via removal
roller 40 and dried in a drying apparatus 44. The dried soft and resilient film 46 then
can subsequently be wound into a roll, if desired. Alternatively, the film 46 may be
slit, corona treated, or laminated to other materials prior to winding or slitting (not
shown). Alternatively the film or laminate may be die-cut and the cut components
may be boxed or packaged in roll form.
An additional preferred embodiment of the invention is illustrated in the schematic
of Figure 4. As shown in this embodiment, molten polymer is delivered to an
extrusion die 10 by an extruder or other mixing apparatus. The molten polymer
curtain 12, or sheet, exits the die and preferably although not necessarily is
immediately laid over a rotating screen 14. Preferably, the screen 14 is an aperture
forming/texturing screen 14. As the screen rotates the molten polymer is carried
over vacuum block 16 where vacuum is applied to form macro-protuberances, and to
cool the molten sheet. During this cooling process, the film crystallizes, either
partially or fully, and acquires three-dimensional memory. The vacuum at vacuum
block 16 can be created by suctioning air at one or both ends of vacuum tube 18, for
example.
The now resilient macro-protuberanced, preferably macro-apertured film and the
screen move together to an air knife 200, or other apparatus capable of delivering
pressurized air. An air stream 220 impinges on the film, preferably although not
necessarily, while the screen is supported by a support block 24. Applying the air
220 through air knife 200 serves to "work" the fiber-like wires of the film to soften
them, and also causes the film to adopt a mirror image of the texturing surface
present in the fiber-like wires of the screen. The texture of the screen was previously
impressed upon the inner surface of the film during the vacuum forming step and is
now more clearly impressed such that it is more clearly visible and palpable. The
additional texture enhances the perception of softness. The soft and resilient film
continues to travel as the screen continues to rotate, until it proceeds to removal
roller 40.
A variety of perforating screens have been developed over the years. A screen can
be constructed with an electroforming technique such as that described in Pruyn,
U.S. Patent 4,383,896, and in Morssinkhof, U.S. Patent 4,496,434, the disclosures of
which are incorporated by reference herein in their entirety. Briefly, in the method
disclosed in Pruyn, a screen skeleton is formed on a matrix in an electrolytic bath.
Thereafter the screen skeleton is stripped from the matrix and subjected to an
electrolysis in a second electrolytic bath in the presence of at least one brightener.
The second electrolytic bath is such that the growth of metal deposit on the screen
skeleton is primarily perpendicular to the surface of the screen skeleton, whereby the
metal deposited on the surface of the skeleton completes the wires that define a
regulated pattern of indentations. Various metals such as copper and nickel may be
used. In certain embodiments where the solid web is thicker and/or stronger (due to
its composition) than other webs, and therefore where water jet energy necessary to
texture the web is higher, a nickel screen will be preferred clue to its additional
strength, when compared to copper.
Radel, U.S. Patent 4,508,256, the disclosure of which is incorporated by reference in
its entirety, discloses a method of making a forming screen (the "PEL" method) by
etching flat metal panels and stacking those panels in a manner such that the
openings in the panels align to form passageways in the stack. The center axis of the
passageways is disposed at a 90 degree angle from a plane parallel to the surface of
the stack, m other words the passageways are aligned perpendicularly to the surface
of the stack. The stacked panels then are bonded, rolled, and welded to form a
cylindrical tube or screen. The passageways in the resulting screens also are aligned
perpendicularly to the surface of the screens. Screens produced by this method are
referred to as PEL screens. Rieker, U.S. Patent 5,562,932 and U.S. Patent
5,718,928, the disclosures of which are incorporated herein by reference in their
entireties, disclose an improved PEL method for producing screens capable of
forming angled or curved capillaries. The Rieker patents disclose constructing the
screen from multiple panels, each panel having openings that are positioned to form
passageways through the screen. By stacking the panels in a manner such that the
centers of the openings in each panel are offset from the centers of the openings in
the remaining panels it is possible to create passageways whose center axis is
disposed at an angle different than 90 degrees from a plane parallel to the surface of
the screen. In other words the passageways are aligned at a non-perpendicular angle,
or slanted.
Alternatively, a high energy beam perforation process can be used to form
perpendicular or angled passageways in a cylinder to form a screen, for example, by
the method described in Rose, WO 00/16726. The method and screen described in
the Rose patent application could be improved to produce screens and to form the
films and articles of the invention.
Ahr, U.S. Patent No. 4,465,045, the disclosure of which is incorporated by reference
in its entirety, discloses a formed film exhibiting a non-glossy visible surface. The
formed film is provided with a regularly spaced microscopic pattern of surface
protuberances that de-gloss the film surface. The micro-protuberances are
transmitted through the thickness of the web by application of vacuum to a semi-
molten web while it is in contact with a rotating screen with aberrations on its
surface. The aberrations project into the film causing it to protrude on the opposite
side thus forming micro-protuberances. Ahr teaches that to achieve de-glossing of
the film surface the micro-protuberances must be spaced in a regulated pattern, each
of the micro-protuberances in the pattern are free of planar areas that are large
enough to inscribe a four mil (100 mm) diameter circle and are so spaced relative to
all adjacent micro-protuberances that the maximum diameter of any circle which can
be inscribed on any planar surface intermediate said micro-protuberances and said
adjacent micro-protuberances is less than about four mils (100 mm).
A commonly used film marketed under the trademark "DRI-WEAVE"® by Procter
& Gamble Co. exhibits the characteristics taught by Ahr. DEI-WEAVE® film has a
215 mesh hexagonal pattern of micro-protuberances on its surface (the center-to-
center minimum distance between any two micro-protuberances is 5 mils (125 mm)).
The amplitude of such micro-protuberances is less than about 2 mils (50 mm). A
cross-section of the Ahr film as it is being formed on the screen is shown in Figure
11. Aberrations 604 of cylindrical shape, about 1 mil (25 mm) in length and 1 mil
(25 mm) in diameter are positioned on the surface of a perforated screen 601 on
about 5 mil (125 mm) center-to-center distance. Molten polymeric film conforms to
the peripheral surface of the aberration forming a micro-protuberance 614 .that
extends away from the planar surface of the film 611 — in other words a micro-
protuberance whose third surface is not intermediate the first and second surfaces of
the film where the 1st surface is the planar surface and the 2nd surface is the end of
the macro-protuberance.
Figures 7-10 illustrate an exemplary etching process used to create a regulated
pattern of aberrations on the surface of screen wires 601. The perforated screen
wires 601 are enveloped in a removable etch-resist coating 602 to provide a
texturing surface. The wires in the un-textured screen may be flattened by grinding
or turning to provide a useful flat surface. A photosensitive mask 603 consisting of
the desired texturing pattern is applied over the coating. The mask 603 and etch
resist coating 602 can be designed by those skilled in the art to effect the requisite
surface aberrations 604 depending on whether a positive or negative relief is formed.
An illumination source is applied to cure the coating in areas not covered by the
mask. The uncured coating is removed, and acid is subsequently applied to remove
metal in the areas coincident with the areas where uncured coating was removed.
Surface aberrations 604 are visible once the uncured coating is removed. The etch-
resist coating 602 then can be removed leaving behind a finished apertured screen
with surface aberrations 604. A laser process also can be utilized to provide surface
aberrations. In this process a high energy beam is traced over the un-textured
surface of a screen, thereby removing strips of metal of the desired depth and width.
Subsequent strips can be removed until the desired surface aberrations are formed.
In an alternative method, a laser beam can be used to trace and. burn-off etch-resist
coating. This method eliminates the need to create and apply the mask shown in
Figure 8. Those skilled in the art are capable of using any suitable method to form
the screen having the dimensions described herein, using the guidelines provided
herein.
The etching process controls the types of micro-protuberances that can be made.
One limitation of the etching process is the depth of etching possible in relation to
the etching area. The "etching aspect ratio" means the ratio of depth of etching to
the minimum etching surface between unetched surfaces. For instance, a screen
used to make DRI-WEAVE® film has a 215 mesh hexagonal aberrations pattern and
the aberrations measure about 1 mil in height by 1 mil in diameter. The depth of
etching is 1 mil and the minimum distance between un-etched surfaces is 4 mils.
The etching aspect ratio therefore is 1:4. If an aspect ratio of about 1.2:1 were used,
the maximum expected etched aberration height possible for 215 mesh hexagonal
patterns would be 4.8 mils. Wider separation between aberrations would therefore
enable the construction of greater height aberrations, and narrower separation would
limit the height of the aberrations. Increasing the diameter of the aberrations will
reduce their height. The disclosures of the Ahr, Morssinkhof, Pruyn, Rieker, Radel,
and Rose patents are incorporated herein by reference in their entireties. Using the
guidelines provided herein, those skilled in the art are capable of designing a screen
for use in forming films in accordance with this invention.
The soft, resilient webs of various embodiments of the present invention preferably
have three-dimensional memory and the perception of softness that is desired by
consumers who use the webs in body-contacting garments or articles. The webs of
the embodiments of the invention have improved softness, when compared to
vacuum formed films and improved resiliency, when compared to the conventional
two-stage high pressure water jet made films. While not intending on being bound
by any theory of operation, one reason for the improved softness is believed to be
attributable to the embodiment where water is used in the second processing to help
work the film (see, Figure 3).
A preferred soft, resilient web of the present invention is shown in Figure 5. As
shown therein, the webs 400 of embodiments of the present invention include a
plurality of macro-protuberances in the form of macro-apertures 410, preferably in
the shape of a pentagon, although they may have any shape and size, and a plurality
of micro-protuberances 420, preferably circular in cross-section. Again,
protuberances can have any cross-section. Figure 5 only shows some of the micro-
protuberances 420 that may be present in web for purposes of clarity. Other
commonly used shapes include hexagonal, square, and oval. Web 400 can be made
from any material that is capable of being deformed by vacuum and fluid.
Preferably, such deformable materials include those that, when stretched beyond
their elastic limit, will substantially retain its newly formed conformation. Preferred
materials for use in the invention include chemically homogeneous or heterogeneous
materials such as homopolymers and polymer blends, structurally homogeneous and
heterogeneous materials such as sheets and laminates, or any combinations thereof.
Particularly preferred materials include polymeric films of ethylene, propylene,
butylene, styrene, and butadiene, including homopolymers, copolymers, and blends
thereof. Polyethylene films include high density, low density, linear low density,
metallocene and conventional polyethylene polymers. As mentioned previously,
web 400 may be comprised of one polymeric film, or may be a plurality of films,
including co-extruded films and laminates.
The three-dimensional webs preferably have a loft, or height "h" of from about 0.100
to about 2.50 mm, preferably from about 0.100 to about 2.00 mm, and more
preferably from about 0.100 to about 1.50 mm. The dimensions of the macro-
apertures 410 of the invention can vary widely, depending on the desired look and
feel of the web, as well as the geometric design of the apertures (i.e., hexagonal,
pentagonal, heptagonal, circular, etc.). If pentagonal macro-apertures 410 are used
as shown in Figure 5, the following dimensions are preferred. The thickness "t" of
the ribs or wires of this particularly preferred embodiment of the invention can range
anywhere from about 0.04 to about 0.80 mm, preferably from about 0.06 to about
0.70 mm, and most preferably from about 0.08 to about 0.6 mm. The diameter "d"
of the macro-apertures 410, e.g., the distance from one side to the other, can be
anywhere from about 0.1 to about 2.5 mm, preferably from about 0.1 to about 2.0
mm, more preferably from about 0.1 to about 1.7 mm, more preferably from about
0.1 mm to about 1.55 mm, and most preferably from about 1.55 mm to about 2.0
mm. The macro-apertures of webs of the invention will vary significantly in their
structure depending on their intended use. For example DRI-IVEAVE® film has a
25 mesh pentagonal pattern of macro-apertures where each aperture has a maximum
width of about 0.8mm. Such a film is desirable for use as a top sheet or coverstock
in various absorbent articles. The dimensions of the micro-protuberances 420 also
will vary, as described in more detail below with reference to Figure 13.
Other films having different patterns may be produced by the method of various
embodiments of the invention. For example, a hexagonal 64 mesh pattern of macro-
protuberances, preferably macro-apertures, may be desirable for use as a breathable
backsheet or a breathable elastic side-panel. A 64 mesh hexagonal pattern may have
apertures spaced on 16.6 mil centers. Therefore, the diameters of the apertures could
be controlled to provide as much or as little permeability as desired. Less
permeability would require smaller apertures that correspondingly leaves more film
surface to be textured. The regulated pattern of macro-protuberances also could be
modified to have multiple zones of apertures, thereby providing a controlled way to
impart various types of elastic properties in films. Those skilled in the art will be
capable of varying any and all of the aforementioned aperture and protuberance
dimensions (macro 410 and micro 420) using the guidelines provided, herein, as well
as the design of the web 400 (e.g., continuous array of macro-apertures 410 and
micro-protuberances 420, a scattered configuration of apertures, or apertures
arranged to depict a graphical image, textual message or other identifying indicia).
When used in an absorbent article, the web 400 of the present invention preferably
has a body-contacting surface 430, (e.g., the first surface), and a garment or
absorbent core facing surface 440 (e.g., the second surface). As shown in Figure 5,
the ends of the micro-protuberances 420 terminate at a 3rd surface.
Referring back to Figure 3, the preferred process of the present invention will be
described in greater detail. The polymers that are to be used to form the film
preferably are fed, together with any processing additives and aids known to those
skilled in the art, to a melting and mixing apparatus, preferably an extruder. The
molten polymer curtain 12 exiting the extrusion die 10, or a co-extruded polymer
curtain 12 exiting multiple extrusion dies 10, contacts rotating aperture
forming/texturing screen 14. The molten polymer curtain 12 can be fed directly to
the rotating aperture forming/texturing screen 14, or it may be cooled (fully or
partially) prior to such contact. Polymer curtain 12 need not be fully molten
polymer, but rather can be a polymer curtain 12 that is at a temperature above the
softening point of the polymer(s) used to form the curtain 12. Rotating aperture
forming/texturing screen 14 can be made by any technique known in the art, and
preferably is an apertured nickel electroplated screen having the desired aperture
size, aberrations pattern and configuration. For example, the rotating aperture
forming/texturing screen 14 can be formed into the shape shown in Figure 5.
As the screen rotates, the polymer, which remains at a temperature preferably above
the softening point of the polymer(s) used to make the film, is carried over vacuum
block 16 where vacuum is applied to aperture, pre-texture, and cool the molten
sheet. During this cooling process, the film crystallizes, either partially or fully, and
acquires three-dimensional memory. The vacuum at vacuum block 16 can be
created by suctioning air at one or both ends of vacuum tube 18, for example. Other
techniques for creating a vacuum at vacuum block 16 will be readily apparent to
those skilled in the art, and can be used in the context of the invention described and
claimed herein. The amount of vacuum created by vacuum block 16 will vary
depending on the degree of deformation required, which typically is dependent upon
the particular apertured configuration as well as the temperature of the polymer
curtain 12. It is preferred in the present invention to direct molten polymer directly
from a cast extrusion die 10 to the rotating screen 14, and that the vacuum level be
from about 0 to about 500 mm Hg, more preferably from about 10 to about 250 mm
Hg, and most preferably from about 20 to about 200 mm Hg. Those skilled in the art
are capable of determining a suitable amount of vacuum to generate in vacuum block
16, using the guidelines provided herein.
After forming the film at the vacuum block 16, the film becomes resilient.
"Resilient" as it is used herein denotes a material that substantially retains its
conformation upon application of pressure and heat, with the exception of heating up
to its softening temperature. Substantially retaining its conformation denotes a
material that can "spring back" to up to 90%, preferably 95%, and more preferably
100% of its original conformation, after the temperature and/or pressure load have
been removed. The now resilient macro-apertured film and the screen move
together to a water jet nozzle 20. A water stream 22 impinges on the film while the
screen is supported by a support block 24. It is preferred that the water stream be
applied as a stream of water at room temperature or higher, preferably from about
40°C to about 90°C, more preferably from about 65°C to about 75°C. Preferred
water pressures range anywhere from about 10 N/cm2 to about 500 N/cm2, more
preferably from about 25 N/cm2 to about 350 N/cm2, and mosv preferably less than
about 300 N/cm2.
It is preferred in the present invention that water does not pass through the already
formed macro-apertures 410 (Fig. 5). Applying the water through water jet nozzle
20 (Fig. 3) serves to "work" the fiber-like wires of the film to soften them, and also
causes the film to adopt a mirror image of the texturing surface present in the fiber-
like wires of the screen. The texture of the screen was previously impressed upon
the inner surface of the film during the vacuum forming procedure and is now more
clearly impressed such that it is more clearly visible and palpable. The additional
texture enhances the perception of softness.
While it is preferred to use support block 24 and not to use vacuum during the water
spraying procedure, support block 24 need not be used. In addition, a vacuum may
be applied to assist in sucking the water through the macro-apertures 410, and to dry
the apertures. In this alternative embodiment, a water removal system would be
employed inside the rotating screen 14, such as those described in any of the Curro
patents.
The soft and resilient film of the present invention then continues to travel as the
screen 14 continues to rotate, until it preferably passes over a blower block 26.
Again, although blower block 26 is preferred in the invention,, a vacuum could be
employed in the same or similar manner as described above. In the preferred
embodiment of the invention, air is blown from one or both ends of a blown air tube
28 and exits the tube through the blower block 26 and through the macro-apertures
410 in the soft and resilient film 400. As air passes through the holes in the film, it
preferably removes water droplets that might have lodged inside the apertured film
protrusions. In this context, it is preferred to use heated dry air, and preferably air at
a temperature within the range of from about 40°C to about 90°C, more preferably
from about 65°C to about 75°C. Further water removal may optionally take place as
the film passes over a support block and a water removal roller 30. Process water
preferably is captured by an external drip pan 32, enabling its easy removal and
further treatment prior to disposal or recycle, if desired.
The soft and resilient film 42 then preferably is removed from the screen via removal
roller 40 and dried in a drying apparatus 44. The dried soft and resilient film 46 then
can subsequently be wound into a roll, if desired. Alternatively, the film 46 may be
slit, corona treated, or laminated to other materials prior to winding or slitting (not
shown). Alternatively the film or laminate may be die-cut and the cut components
may be boxed or packaged in roll form.
A cross-section of a non-performing film made by a known method is shown in
Figure 12. Non-performance is primarily due to the harsh feeling texture of the film
shown. Aberrations 604 of cylindrical shape, over about 2 mil (55 mm) in length and
1 mil (25 mm) in diameter are disposed on the surface of a perforated screen 601 in a
215 mesh hexagonal pattern. Molten polymeric film conforms to the peripheral
surface of the aberration forming a protuberance 614 that extends away from the
planar surface of the film 611. Without wishing to be bound by theory, the inventors
believe that the harsh texture results because the molten polymer envelops, the
aberration and crystallizes without it being worked sufficiently and without it
stretching sufficiently to properly form around the entire aberration and thereby
causing its side-portions to thin and soften.
A cross-section of a particularly preferred film of an embodiment of the
invention made by the methods described herein is shown in Figure 13.
Aberrations 604 of cylindrical shape, up to about 4 mil (100 am) in height and 1
mil (25 mm) in diameter are disposed on the surface of a perforated screen 601 in
a 215 mesh hexagonal pattern. Molten polymeric film partially conforms to the
peripheral surface in the presence of the first vacuum process (Fig. 3), and
subsequently is caused to substantially conform, in the presence of the second
fluid process, to the aberration forming a protuberance 614 thai; extends away
from the planar surface of the film 611. The aberrations 604 of the invention
preferably are from about 2 mils to about 5 mils in height, and from about 1 to about
3 mil in diameter, more preferably from about 1 to about 2 mil in diameter, when a
215 Mesh hexagonal pattern is used. More preferably, the height of aberrations 604
is from about 2.5 to about 4.8 mils, and most preferably, from about 3.0 to about 4.5
mils, and the diameter most preferably is about 1 mil. Those having ordinary skill in
the ait recognize how to vary the spacing between the aberrations 604, and
consequently, form aberrations 604 that have greater height and/or diameter than
those described above.
Webs of the invention can be made of any film forming polymers and the proper
selection of polymers will depend on the desired application of the film. Films with
macro-apertured patterns comprising mesh counts greater than 54 require easily
flowable polymers such as low density polyethylene with high melt indeces. Low
viscosity is desirable, which will also determine the choice of polymer. Elongatable
polymers are desired such that films can be formed by liquid pressure around the
aberrations without breaking, for example linear low density polyethylene or
metallocene catalyzed linear low density polyethylene. Clearly the size and shape of
the aberrations will dictate the minimum amount of elongatable polymer necessary.
A person skilled in the art will recognize that various polymers can be combined to
obtain the optimal formulation for each type of film produced.
After forming film 400, the film preferably can be used as one of the elements of a
body-contacting article, preferably an absorbent article. A particularly preferred
absorbent article is a diaper, and a typical diaper is shown in Figure (5, with the effect
of elastics removed for purposes of clarity. As used herein, the terms "absorbent
garment," "absorbent article" or simply "article" or "garment" refer to devices that
absorb and contain body fluids and other body exudates. More specifically, these
terms refer to garments that are placed against or in proximity to the body of a
wearer to absorb and contain the various exudates discharged from the body. A non-
exhaustive list of examples of absorbent garments includes diapers, diaper covers,
disposable diapers, training pants, feminine hygiene products, adult incontinence
products, surgical gowns, wound dressing, and the like. Such garments may be
intended to be discarded or partially discarded after a single use ("disposable"
garments). Such garments may comprise essentially a single inseparable structure
("unitary" garments), or they may comprise replaceable inserts or other
interchangeable parts.
The present invention may be used with all of the foregoing classes of absorbent
garments, without limitation, whether disposable or otherwise. The embodiments
described herein provide, as an exemplary structure, a diaper for an infant, however
this is not intended to limit the claimed invention. The invention will be understood
to encompass, without limitation, the use of the web 400 in all classes and types of
absorbent garments, including those described herein.
Throughout this description, the term "disposed" and the expressions "disposed on,"
"disposing on," "disposed in," "disposed between" and variations thereof (e.g., a
description of the article being "disposed" is interposed between the words
"disposed" and "on") are intended to mean that one element can be integral with
another element, or that one element can be a separate structure bonded to or placed
with or placed near another element. Thus, a component that is "disposed on" an
element of the absorbent garment can be formed or applied directly or indirectly to a
surface of the element, formed or applied between layers of a multiple layer element,
formed or applied to a substrate that is placed with or near the element, formed or
applied within a layer of the element or another substrate, or other variations or
combinations thereof.
Throughout this description, the terms "top sheet" and "back sheet" denote the
relationship of these materials or layers with respect to the absorbent core. It is
understood that additional layers may be present between the absorbent core and the
top sheet and back sheet, and that additional layers and other materials may be
present on the side opposite the absorbent core from either the top sheet or the back
sheet.
Figure 6 is a partially cut away depiction of an exemplary embodiment of an
absorbent garment 500 (preferably a disposable absorbent garment) of the present
invention. The embodiment shown in Figure 6 is an infant's diaper, however, this
depiction is not intended to limit the invention, and those skilled in the art appreciate
that the invention covers other types of absorbent articles. For simplicity, however,
the invention will be described with reference to an infant's diaper. The garment
500 of Figure 6 is depicted in a generally flattened position, with the body-facing
side facing down, and with the various elastic components depicted in their relaxed
condition with the effects of the elastics removed for clarity (when relaxed, the
elastics typically cause the surrounding material to gather or "shirr"), In the
flattened position, the garment 500 may have a generally hourglass shaped structure,
but it may also have any other shape suitable for the given application, such as a
rectangular shape, a trapezoidal shape, a "T" shape, and the like.
As used herein, the longitudinal axis 100 of the garment is the dimension of the
garment corresponding to the front-to-rear dimension of the user, and the lateral axis
102 of the garment is the dimension corresponding to the side-to-side dimension of
the user.
In use, the invention comprises a pant-like garment 500 having a waist-encircling
region and a crotch region. The waist-encircling region may comprise a first waist
region 512, disposed adjacent to, for example, the back waist region of a wearer's
body, and a second waist region 514, disposed adjacent to, for example, the front
waist region of a wearer's body. The first and second waist regions 512, 514, may
correspond to the front and back of the wearer's body, respectively, depending on
whether garment 500 is attached in front of or behind the subject wearer. The first
and second waist regions preferably are joined together at or near their lateral edges
518, causing the longitudinally distal edges 520 of the garment 500 to form the
perimeter of a waist opening. A crotch region 516 extends between the first and
second waist regions 512, 514, and the crotch edges 522 form the perimeter of a pair
of leg openings, when the garment 500 is placed on a subject wearer.
The garment 500 preferably comprises a top sheet 524, and a back sheet 526, which
may be substantially coterminous with the top sheet 524. When the garment 500 is
being worn, the top sheet 524 faces the wearer's body, and the back sheet 526 faces
away from the wearer. An absorbent core 528 preferably is disposed between at
least a portion of the top sheet 524 the back sheet 526.
An embodiment of the present invention may further comprise various additional
features. One or more pairs of elastic gathers 530 may extend adjacent the crotch
edges 522. The garment 500 may also comprise one or more waste containment
systems, such as inboard standing leg gathers 540, which preferably extend from the
second waist region 514 to the first waist region 512 along opposite sides of
longitudinal center line 100 (only one standing leg gather system 540 is shown in
Figure 5 for purposes of clarity). One or both of the first and second waist regions
512, 514 may also be equipped with strips of elastic or foam 532 or other elastically
extensible material, which help contract the garment around the wearer's waist,
providing improved fit and leakage prevention.
The absorbent garment 500 also preferably includes fastening elements to enable
attachment of the first waist region 512 to second waist region 514. Fastening
elements preferably include a pair of tabs 534 that extend laterally away from
opposite lateral edges 518 of the first waist region 512 of the garment 500. The tabs
534 may comprise an elastically extensible material (not shown), and may be
designed to stretch around a wearer's waist to provide improved fit, comfort, and
leakage protection. Such elasticized tabs 534 may be used in conjunction with, or in
lieu of, waist foam 532, or other elastically extensible materials 532.
At least one fastening mechanism 536 (collectively referred to as "fastener 536") is
attached to each tab 534 for attaching the tab to the second waist region 514, thereby
providing the garment 500 with a pant-like shape, and enabling garment 500 to be
fixed or otherwise fitted on the wearer. The fasteners 536 may attach to one or more
target devices 538 located in the second waist region 514.
The various parts of the garment 50 can be attached to one anovher, associated with
one another, or disposed adjacent or in between one another to form a structure that
preferably maintains its shape during the useful life of the garment 500. As used
herein, the terms "attached," "joined," "associated," and similar terms encompass
configurations whereby a first part is directly joined to a second part by affixing the
first part directly to the second part, by indirectly joining the first part to the second
part through intermediate members, and by fixing the relative positions of various
parts by capturing parts between other parts. Those skilled in the art will appreciate
that various methods or combinations of methods may be used to securely join the
respective parts of the garment 500 to one another.
The top sheet 524 and back sheet 526 may be constructed from a wide variety of
materials known in the art. The invention is not intended to be limited to any
specific materials for these components. The top sheet 524 and back sheet 526 can
be shaped and sized according to the requirements of each of the various types of
absorbent garment, or to accommodate various user sizes. In an embodiment of the
invention in which the garment 500 is a diaper or an adult incontinence brief, the
combination of top sheet 524 and back sheet 526, may have an hourglass shape, as
seen in Figure 1, or may have a rectangular, trapezoidal, "T" shape, or other shape.
Due to the wide variety of backing and liner sheet construction and materials
currently available, the invention is not intended to be limited to any specific
materials or constructions of these components. The back sheet 526 preferably is
made from any suitable pliable liquid-impervious material known in the art. Typical
back sheet materials include films of polyethylene, polypropylene, polyester, nylon,
and polyvinyl chloride and blends of these materials. For example, the back sheet
can be made of a polyethylene film having a thickness in the range of 0.02-0.04 mm.
The back sheet 526 may be pigmented with, for example, titanium dioxide, to
provide the garment 500 with a pleasing color or to render the back sheet 526
opaque enough that exudates being contained by the garment 500 are not visible
from outside the garment. In addition, the back sheet 526 may be formed in such a
manner that it is opaque, for example, by using various inert components in the
polymeric film and then biaxially stretching the film. Other back sheet materials
will be readily apparent to those skilled in the art. The back sheet 526 preferably has
sufficient liquid imperviousness to prevent any leakage of fluids. The required level
of liquid imperviousness may vary between different locations on the garment 500.
The back sheet 526 may be covered with a fibrous, non woven fabric such as is
disclosed, for example, in U.S. Patent 4,646,362 issued to Heran et al. Materials for
such a fibrous outer liner include a spun-bonded non woven web of synthetic fibers
such as polypropylene, polyethylene or polyester fibers; a non woven web of
cellulosic fibers, textile fibers such as rayon fibers, cotton and the like, or a blend of
cellulosic and textile fibers; a spun-bonded non woven web of synthetic fibers such
as polypropylene; polyethylene or polyester fibers mixed with cellulosic, pulp fibers,
or textile fibers; or melt blown thermoplastic fibers, such as macro fibers or micro
fibers of polypropylene, polyethylene, polyester or other thermoplastic materials or
mixtures of such thermoplastic macro fibers or micro fibers with cellulosic, pulp or
textile fibers.
It is preferred in the present invention that the top sheet 524 be comprised of one or
more apertured webs 400. When the apertured webs 400 are employed as the top
sheet, the body-facing surface 430 (Fig. 5) of the web 400 preferably faces into the
page in Figure 6 since the top sheet 524 is the lowest layer shown therein, and the
garment or absorbent core facing surface 440 of web 400 preferably faces out of the
page towards the absorbent core 528. Such an apertured film 400 typically is treated
with a surfactant to render it hydrophilic, and as described previously, the preferred
method of making the web 400 provides for less removal of the surfactant from the
surface of the top sheet 524. Use of the apertured film 400 of the present invention
provides a number of advantages, including the resiliency of vacuum-formed films
with the improved softness of water jet formed films.
[00101] The top sheet 524 and the back sheet 526 may be associated with one another using a
variety of methods known in the art. For example, the}- may be thermally,
ultrasonically, or chemically bonded to one another. They also may be joined using
lines of hot melt adhesive or mechanical fasteners, such as thread, clips, or staples.
The particular joining method may be dictated by the types of materials selected for
the top sheet 524 and back sheet 526.
[00102] The invention has been described with reference to particularly preferred
embodiments and examples. Those skilled in the art will appreciate, however, that
various modifications may be made to the invention without significantly departing
from the spirit and scope thereof.
WE CLAIM :
1. A method of making a web comprising:
i. providing a web of softened material such as described herein;
ii. depositing the web of softened material on a screen, the screen
comprising perforations and aberrations, the perforations forming a regulated pattern of
ribs;
iii. subjecting the softened web to vacuum such that macro-protuberances
are formed in the web, the macro-protuberances conforming substantially to the shape
of perforations in the screen, whereby the softened web is subjected to vacuum for
sufficient time to cause the softened web to begin to solidify;
iv. subsequent to subjecting the softened web to vacuum, contacting the web
with a fluid with sufficient energy to cause the solid web to permanently deform without
aperturing the web in locations overlaying the aberrations in the screen to form
unapertured micro-protuberances; and
v. removing the web from the screen.
2. The method as claimed in claim 1, wherein the fluid is pressurized water.
3. The method as claimed in claim 1, wherein the fluid is pressurized air.
4. The method as claimed in claim 3, wherein an air knife delivers the pressurized
air.
5. The method as claimed in claim 1, wherein the aberrations in the screen have a
cylindrical shape.
6. The method as claimed in claim 5, wherein the aberrations have a height within
the range of from 2 to 5 mils, and a diameter within the range of from 1 to 3 mil.
7. The method as claimed in claim 1, wherein the macro-protuberances are
apertured.
A method of making a web is disclosed. The method involves the steps
of providing a web of softened material; depositing the web of softened
material on a screen, subjecting the softened web to vacuum such that
macro-protuberances are formed in the web, subsequent to subjecting the
softened web to vacuum, contacting the web with a fluid with sufficient energy
to cause the solid web to permanently deform without aperturing the web in
locations overlaying the aberrations in the screen to form unapertured micro-
protuberances; and removing the web from the screen.

Documents:

1167-KOLNP-2005-FORM-27.pdf

1167-kolnp-2005-granted-abstract.pdf

1167-kolnp-2005-granted-assignment.pdf

1167-kolnp-2005-granted-claims.pdf

1167-kolnp-2005-granted-correspondence.pdf

1167-kolnp-2005-granted-description (complete).pdf

1167-kolnp-2005-granted-drawings.pdf

1167-kolnp-2005-granted-examination report.pdf

1167-kolnp-2005-granted-form 1.pdf

1167-kolnp-2005-granted-form 18.pdf

1167-kolnp-2005-granted-form 3.pdf

1167-kolnp-2005-granted-form 5.pdf

1167-kolnp-2005-granted-gpa.pdf

1167-kolnp-2005-granted-reply to examination report.pdf

1167-kolnp-2005-granted-specification.pdf

1167-kolnp-2005-granted-translated copy of priority document.pdf


Patent Number 224981
Indian Patent Application Number 1167/KOLNP/2005
PG Journal Number 44/2008
Publication Date 31-Oct-2008
Grant Date 29-Oct-2008
Date of Filing 17-Jun-2005
Name of Patentee TREDEGAR FILM PRODUCTS CORPORATION
Applicant Address 1100 BOULDERS PARKWAY, RICHMOND VA
Inventors:
# Inventor's Name Inventor's Address
1 COPAT, MARCELO, S 1481 WATER MARK COURT, TERRE HAUTE, IN 47803
2 TRIBBLE, JIM 5308 WEST TWIN BEACH ESTATES DRIVE, BRAZIL, IN 47834
3 SKOCHDOPOLE, TODD,R. 7482 WESTWOOD LANE, TERRE HAUTE, IN 47802
4 BOWER, SEAN, W. 1280 NORTH HUNTERS COURT STREET, TERRE HAUTE, IN 47803
5 GRAY, BRIAN, F. 565 WOODBROOK LANE, CINCINNATI, OHIO 45215
6 STONE, KEITH, J. 1923 AUGUSTA BLVD., FAIRFIELD, OH 45014
PCT International Classification Number A61F
PCT International Application Number PCT/US2004/007262
PCT International Filing date 2004-03-10
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 60/452,938 2003-03-10 U.S.A.