Title of Invention

"GLASS-LINED REACTION CONTAINER WITH BAFFLES SECURED TO THE INTERNAL WALL BY MEANS OF LOCAL CONNECTION"

Abstract

Glass-lined reaction container with one or more baffles secured to the internal glass-lined wall of the reaction container is equipped with a coolant circulation system, characterized in that each baffle is connected to the reactor internal wall (12), at a distance from said wall, by means of a local connection (15) whose greatest dimension is lower than the length of each baffle and in that the external surface of the baffle body and its connection are glass-lined, this local connection enables each baffle to be almost insensitive to the expansion of the rest of the container and forms a group of glass-lined surfaces with the internal lateral surface of the container.

Full Text

The present invention relates to glass-lined reaction container with baffles secured to the internal wall by means of local connection. The present invention relates to a baffle, secured preferably by welding, to the wall of an glass-lined or vitrified container, by means of a local connection. In the chemical industry, it is sometimes necessary to use or store particularly acid reagents or products or corrosives that make it impossible to use the traditional containers or tanks whose steel walls would be attacked and destroyed. A solution consists in using in this case a reactor tank or container or other containers whose internal wall is glass-lined. This inert and very resistant coating ensures the protection of the tank or container against the aggressive attack of the contained material. However, in order to avoid any risk of deterioration of the container and any risk of leakage ■ that would be dangerous for people, the material and the environment, the integrity of this glass-lined protective coating must be ensured at all times. The integrity of this glass-lined protective coating depends closely on the internal geometry of the container and its interior elements. Thus, angular zones, which are very difficult to enamel, must be avoided. On the contrary, smooth and curved surfaces are preferred. A sudden variation in temperature, either on the glass-lined or steel side can lead to the destruction of the glass-lined coating by thermal shock. The most dangerous thermal shocks are caused by projections of cold materials onto a hot glass-lined surface. Moreover, during the process of glass-lining, treated surfaces generally undergo heat treatment requiring heating to a temperature of VOO to 850°C, which induces significant thermal expansion. Such thermal expansion causes tension which in turn can damage or deteriorate the protective glass-lining. In addition, it is often necessary in the chemical industry to agitate the material in the container. This agitation is generally carried out by means of an agitator and it can be associated with one or more baffles. Conventionally, the tanks or containers equipped with an impeller, which is inserted through a nozzle in the tank or container, comprise one or more baffles. More rarely, the baffles can be secured over their entire length on the internal surface of the tank or container. A baffle is a device that allows a better agitation, in particular by creating additional turbulence in the agitated medium and by preventing the formation of a swirl or vortex. In the case of devices welded inside the tank or container to be glass-lined, the extent of the stresses is increased due to thermal expansion if these devices are welded along a critical length or along their entire periphery against the internal wall of the tank or container. The goal of the invention is to provide a baffle secured to the internal surface of an glasslined container or tank so that the glass-lining phase can be conducted in an easy, effective, and reliable way and that the coating layer is of a uniform, solid and durable nature. According to prior art described for example in US patent n° 4,172,877 in the name of Robert H. SCHWAIG, a baffle of low depth can be achieved by embossing the internal wall of the container or by welding a part which is brought back against this internal wall. This baffle is intended to be hollow and connected to a possible double walled construction of the container to, for example, allow the circulation of a heating or cooling liquid in the body of the baffle. The formation of the baffle by embossing the inner wall makes it difficult to ensure an easy and reliable glass-lining and does not allow the formation of a complex shape for the baffle. Moreover, this manufacturing process weakens the deformed part by making it thinner and it does not allow production of a baffle having a significant surface without reducing its rigidity in a critical way. According to the second embodiment of the baffle of SCHWAIG patent, the baffle is made of a metal plate whose edges are folded up and welded against the internal wall of the container onto the entire periphery or height of the baffle. However, the present inventors noted that it is difficult to glass-line such welding, due to its considerable length, extending along its entire periphery or height. Indeed, the mechanical tensions caused by the thermal expansion of the baffle are increased by the considerable length of this embodiment and can involve a serious deterioration of the glass-lined coating. Moreover, with a baffle welded along its entire periphery or height, the control of the industrial manufacturing process is very difficult. The results are random and the process is not reproducible at industrial production speeds. For these various reasons, the solutions disclosed in US patent n° 4,172,877 are not satisfactory. Thus, the goal of this invention is to provide a baffle of any size or form, which can be secured to the internal surface of a container, so that the unit can then be glass-lined in a simple, effective, reliable and durable way. Preferentially, according to the present invention, the baffle can be solid or hollow and in communication with the possible space created between the double wall of the container. The word container means any vessel intended to contain liquids, gases, solid, pasty, viscous or powdery materials or mixtures of these, which can be equipped with a baffle such as: vessel, tank or container, cistern, column, drier, exchanger or other. Only glass-lined containers will be dealt with in relation with the present invention. The most frequent use of baffles being related with reaction containers, this latter term will be used to indicate the container, even if it can be applied to all other types of container. To solve the technical manufacturing problem, the object of this invention consists in conceiving a baffle secured at a distance to the inner adjacent wall of the container and secured to this wall by means of a local connection. The baffle then remains almost insensitive to any expansion of the remainder of the container because differing expansions of the baffle and the wall are allowed. Thus, in the present invention, instead of securing the baffle over its entire length to the inner wall of the container, a partial securing by means of one or several connections is preferred. Preferentially, the baffle is secured locally by means of a single connection. By local connection, it must be understood a connection whose extent is limited, i.e. a connection not extending over the overall height of the baffle and whose width is thus less than the length of the baffle. In this way, the major part of the baffle remains free and can be deformed, and expand freely without influencing nor being influenced by the remainder of the container in particular during the thermal cycles encountered during enameling. Moreover, in the preferred case where the fabrication is achieved by welding, the weld bead has a reduced length, which avoids the above-mentioned disadvantages of the prior art. Lastly, according to the present invention the baffle may either be full or hollow. When the baffle is hollow, its interior space can then be designed to include a connecting fluid path through its local connection, with a circulation system for a fluid, to provide a heating or cooling function, for the container, this system for example consisting of a double walled construction, a serpentine, a halfshell or other such forms. A means can be provided for the circulation of the fluid in the baffle. For these many reasons, the device of this invention satisfies all the above-mentioned objectives without presenting any of the disadvantages. It thus represents a completely new ideal device that allows provision of one or more baffles in an glass-lined container while ensuring provision of an glass-lined coating for the unit in a simple, effective, reliable and durable way. From its design, except at its local connection, there is a space located between the body of the baffle and the interior wall of the container to which it is welded. This space allows a free movement of the material present in the container between the baffle and the interior wall of the container, except at the local connection of the baffle. The space also considerably facilitates the ease of subsequent cleaning of the container. This space also eliminates the disadvantage usually encountered with containers equipped with a baffle such as that of US patent n° 4,172,877 in which material accumulates in the angle formed between the side of the baffle and the interior surface of the container to which it is welded. This accumulation, which usually forms on the side opposite the directional flow of the agitation, is avoided in the present invention, by the permanent flow permitted between the container inner wall and the baffle. Lastly, from its particularly advantageous form, the baffle according to this invention increases the hydraulic performance of the baffle and reduces mixing time and homogenization, which enables time saving and reduces industrial costs considerably. Other characteristics and advantages of the invention will be apparent from the following description, which refers to the accompanying drawings,, in which: figure 1 is a vertical cross-sectional view of a tank or container with a double envelope provided with an impeller and two solid baffles opposite each other, according to the invention; figure 2 is a vertical cross-sectional view of a tank or container with a double envelope provided with an impeller and two hollow baffles opposite each other and provided with a connecting fluid path to the double envelope of the tank or container, according to the invention; figure 3 is a vertical cross-sectional view of a tank or container fitted with an external serpentine and provided with an impeller and two baffles opposite each other, according to an embodiment of the invention; figure 4 is a vertical cross-sectional view of a tank or container provided with a double walled construction provided with an impeller and two pairs of baffles opposite each other, according to another embodiment of the invention,- figure 5 is a vertical cross-sectional view of a tank or container with a double walled construction provided with an impeller and two pairs of baffles opposite each other with low local fixation, according to another embodiment of the invention; figure 6 is a vertical cross-sectional view of a tank or container with a double walled construction provided with an impeller and two pairs of baffles opposite each other with approximately central fixation, according to another embodiment of the invention; figures 7 to 15 are partial horizontal crosssectional views of part of a tank or container provided with a baffle, showing the various forms that the baffle section may take, according to the invention; figure 16 is a horizontal cross-sectional view of an tank or container provided with six baffles, according to an embodiment of the invention; figure 17 is a vertical cross-sectional view of a horizontal tank or container provided with two baffles, according to an embodiment of the invention; figure 18 is a diagrammatic horizontal crosssectional view of the fluid flow past and around a baffle, according to the prior art of US patent n° 4,172,877; and figure 19 is a diagrammatic horizontal crosssectional view of the fluid flow past and around a baffle, according to the invention. Figure 1 represents a chemical reactor tank or container 1 fitted with three integral top openings 2, 3 and 4 through which the various reagents, solvents and catalysts can be introduced or various instruments or accessories (impeller, probes, emptying tubes and or devices, etc.) can be passed through and into the tank or container 1. Tank or container 1 is provided with a mechanical impeller 5 whose stem 6 crosses the central opening 3 and extends towards the lower part of the tank or container. Stem 6 ends for example in a hub fitted with three tilted blades 7, to agitate the contents 8 of tank or container 1 when the stem 6 is rotated by a driving mechanism 10 positioned outside the tank or container. In order to resist the aggressions of a highly potent reacting medium forming the content 8 of tank or container 1, the internal surface of the tank or container may be completely coated with a glasslined protective coating 9 also called vitrified coating. In the same way, all surfaces that may be brought in contact with the contents 8 must also be glass-lined. It is obviously the same for stem 6 and blades 7 of impeller 5. A second wall 11 surrounds the internal wall 12 of tank or container 1, these walls 12 and 13 being at a specific and constant distance from each other to create between them an enclosed space 13. This space 13 is anticipated for the provision of a hot or cold fluid medium to facilitate the control of the internal temperature of the tank or container according to the well-known principle of the double walled tank or container. In this figure, tank or container 1 comprises several baffles 14 independent of the internal wall 12 of the tank or container 1 being secured at a distance from the internal wall 12 and welded onto this wall 12 with a local connection 15 whose width is less than the length of the baffle, according to the invention. Lastly, at its lowest part, the tank or container 1 shows an opening 17 which may be used as an opening for draining the contents 8. In this first embodiment, the baffles 14 are solid. Their local connections 15 are vertically positioned at the approximate midpoint of each baffle 14. The baffles are shaped into a simple general form, similar to a board substantially vertical and perpendicular to the internal wall 12 of the tank or container I, whose edges and angles are rounded. In a second embodiment shown in figure 2, a tank or container 1 similar to that of figure 1 is equipped with several baffles 14 being secured at a distance from the internal wall 12 of the tank or container I and welded against this wall 12 by the transitional local connection 15. According to this embodiment, the baffles 14 of the invention are hollow and define an interior hollow space 16 which can possibly and additionally be arranged to be provided with a connecting fluid path to the enclosed space 13 between the external wall 11 and the internal wall 12 of the double walled construction of the tank or container 1. In this way, a fluid, to provide a heating or cooling function, can be circulated in the double walled construction of tank or container 1 and can additionally circulate in the baffles 14, which considerably improves the heat exchange characteristics of the unit. An equivalent connection to the interior hollow space 16 for the heating or cooling fluid can be provided in a similar way when the tank or container is equipped with a hemi-coil, half-shells or with any other similar system. In the two preceding embodiments represented in figures 1 and 2, the baffles have a simple and traditional general form. The baffle according to the invention, by its advantageous design, can beneficially adopt more complex and varied general forms. It can thus adapt to the stresses and the particular design features of each practical situation considered and confer additional advantages. Thus, the baffle according to the invention can for example be curved towards its lowest end. It 10 can thus adopt a "hockey stick" shape, as represented in figure 3 where it is shown fitted to a tank or container with a hemi-coil or half-shell. Such a general shape for the baffle makes it possible for example to establish a counter-agitation in the contents of the tank or container. Obviously, the baffle according to the invention can be curved, convex or arched at another vertical position and for example slightly higher as represented in figure 4. Moreover,local connection 15 is not necessarily located in the vertical middle of the baffle, but can be positioned at an unspecified height. Thus, for example in the embodiment of figure 4, it can be located near the lower edge of the baffle 14. In the case of the alternate embodiment represented in this figure 4, one can also note that the baffles according to the invention can also be secured tilted, i.,e. positioned relative to the wall of the tank or container forming an unspecified angle with respect to the vertical. As represented in figures 5 and 6, it is also possible to combine baffles into pairs to obtain the equivalent of one baffle having a significantly greater length. One can observe in these figures that the baffles forming each pair are not necessarily identical. One can obviously plan to combine baffles in any number greater than two. The use of several combined baffle shapes in pairs or more, makes it possible for example to reduce manufacturing costs by utilizing common shapes in a flexible way to adapt to various tanks or containers. Moreover, if the baffles can adopt various general forms, they can also be different in height, width and thickness to facilitate adaptation and conformation to the requirements of any tank or container. They can also exhibit various sectional forms to create the required mechanical effects for the fluids involved. Figures 7 to 15 show some examples of these sectional forms which can be used for the baffles 14 . These sectional forms can be used for solid baffles as well as hollow baffles. Figure 7 represents a baffle 14 with a traditional sectional shape, a substantially rectangular type with rounded edges. Figure 8 represents a baffle 14 having a section with convex sides, while on figure 9 these same convex sides are concave. Figure 10 represents a baffle 14, the section of which exhibits undulations on one of the sides. In the same way, one can consider that the section of baffle 14 can exhibit an unspecified number of undulations on one or more of its sides. Figure 11 represents a section of baffle 14 with a curved side end. Figure 12 represents a baffle 14 having a "T" shaped section. Figure 13 represents a baffle 14 whose section is in the form of a quarter of a circle or quadrant. Figure 14 represents a baffle 14 having a "V" shaped section. Lastly, the baffles 14 can also be secured in a non-perpendicular way to the wall of the tank or container as represented in figure 15. Figures 7 to 15 are given only by way of examples of sectional forms and those skilled in the art will easily be able to consider other forms for the baffle section, by varying its dimensions, its concavity or its convexity, its orientation, its slope, its position and angle of fixation, etc. As already mentioned above, a container can be provided with one or several baffles 14. According to a preferential embodiment of the invention, a container can be equipped with several baffles 14 distributed regularly and/or laid out appreciably along a theoretical curve, for example in the shape of a helix, located on the internal wall 12 of a tank or container 1. Figure 16 represents a horizontal crosssectional view of a horizontal cut through a tank or container 1 provided with six baffles 14 having a traditional sectional form of appreciably rectangular shape with rounded edges, baffles 14 being distributed evenly on the internal wall 12 of the tank or container, i.e. with a relative angular spacing appreciably constant, for example approximately 60° in the case shown in this figure. Figure 17 represents a transverse crosssectional view of a horizontal tank or container 19 provided with two baffles of different forms. The first one is in the form of a quadrant or quarter of a circle while the second is in the shape of half a circle. Figure 18 represents a diagrammatic crosssectional view or horizontal cut to show the flow of fluid 20 at the level of a baffle 21 according to the prior art which is positioned against the internal wall 12 of tank or container 1 and is secured to this wall along all its height. With such a baffle 21, an accumulation of material in the form of a deposit is possible because of a stagnated fluid flow at a dead zone 22 that is not sufficiently agitated by the fluid flow. By way of comparison, figure 19 represents a diagrammatic cross-sectional view or horizontal cut to show the flow of fluid 20 at the level of a baffle 14 according to the invention, where the baffle 14 is not secured to the wall of the tank or container. Advantageously, any accumulation of material in the form of deposit is avoided because the circulation of fluid 20 on both sides of the baffle is sufficiently agitated. According to another embodiment not represented, a tank or container 1 may be equipped with several baffles 14 laid out along a theoretical curve forming a helix on the internal wall 12 of the tank or container or presenting themselves appreciably in the shape of a helix. In this case, the baffles can follow the general orientation of a helix or can be positioned differently whilst their relative positioning continues and follows the basic shape of a helix. One can also consider that the baffles 14 are laid out substantially along a theoretical curve of a different type or along several different curves. Lastly, it can additionally be planned to use several local connections to secure the baffle to the internal wall of the container when necessary for strength or other reasons. The baffle device according to the invention is particularly well adapted to be used on the inner wall of a tank or container as represented in the figures. However, it must be well understood that its use is not limited to this application. This baffle device can thus be secured against the wall of an unspecified container, glasslined or not, with a single or double wall construction, with a serpentine surrounding the internal wall or not, and comprising an unspecified number of openings for whatever purposes or means of agitation. In the same way, the baffle according to the invention is not inevitably installed within chemical tanks or containers, but can be used on any type of container for which it is useful to accomplish effective agitation without dead zones. Obviously, the number, the general form, the sectional form, the slope, the orientation and the provision of the various baffles according to the invention represented in the figures are given here only as exemplary representations and are to be considered in no circumstances as restrictive. Many variations can be imagined for the baffle according to the present invention without exceeding its scope. These variations will be obvious for those skilled in the art, who will be able in particular to consider other numbers, general forms, sectional forms, slopes, orientations and/or provisions for the baffles without exceeding the scope of the claims. We Claim: 1. Glass-lined reaction container with one or more baffles secured to the internal glass-lined wall of the reaction container is equipped with a coolant circulation system, characterized in that each baffle is connected to the reactor internal wall (12), at a distance from said wall, by means of a local connection (15) whose greatest dimension is lower than the length of each baffle and in that the external surface of the baffle body and its connection are glass-lined, this local connection enables each baffle to be almost insensitive to the expansion of the rest of the container and forms a group of glass-lined surfaces with the internal lateral surface of the container. 2. Glass-lined reaction container as claimed in claim 1, wherein the local connection (15) is formed by welding to the internal wall (12). 3. Glass-lined reaction container as claimed in claim 1 or 2, wherein at least one baffle is a hollow body. 4. Glass-lined reaction container as claimed in claim 3, wherein the inner hollow space (16) of the baffle (14) is in fluid communication, via its local connection (15), with the container's heating or cooling system fluid by fluid circulation. 5. Glass-lined reaction container as claimed in any of claims 1 or 2, wherein at least one baffle is a solid body. 6. Glass-lined reaction container as claimed in any of the preceding claims, wherein at least one local connection (15) is located at mid-height of the baffle (14). 7. Glass-lined reaction container as claimed in any of claims 1 to 6, wherein at least one local connection (15) is located close to one of the edges of the ends of the baffle (14). 8. Glass-lined reaction container as claimed in any of the preceding claims, wherein the body of the baffle exhibits a flat form similar to a board mainly vertical and perpendicular to the internal wall (12) of the container (1) with rounded angles. 9. Glass-lined reaction container as claimed in any of claims 1 to 7, wherein the body of at least one baffle takes the shape of a "hockey stick". 10. Glass-lined reaction container as claimed in any of claims 1 to 7, wherein the body of at least one baffle is curved, at its vertically higher or lower part and/or on its side edge. 11. Glass-lined reaction container as claimed in any of the preceding claims, wherein the form of the cross section of the body of at least one baffle is mainly rectangular and has rounded edges. 12. Glass-lined reaction container as claimed in any of claims 1 to 10, wherein the body of at least one baffle exhibits convex rounded sides. 13. Glass-lined reaction container as claimed in any of claims 1 to 10, wherein the body of at least one baffle exhibits concave rounded sides. 14. Glass-lined reaction container as claimed in any of claims 1 to 10, wherein the form of the body section of at least one baffle presents at least an undulation on one of its sides. 15. Glass-lined reaction container as claimed in any of the preceding claims, wherein the body of at least one baffle is secured to the adjacent wall in an tilted presentation compared to the longitudinal, axis of the container. 16. Glass-lined reaction container as claimed in any of the preceding claims, wherein the body of at least one baffle is secured in skew relative to the internal wall (12) of the container (1). 17. Glass-lined reaction container as claimed in the preceding claim, wherein one end of the body of each baffle is close to the adjacent side wall and in that its opposite end is further away from the adjacent sidewall. 18. Glass-lined container intended to be glass-lined, wherein it has at least one glass- lined baffle connected to the internal wall according to any of the preceding claims. 19. Glass-lined container as claimed in the preceding claim, wherein it has several baffles (14) distributed regularly. 20. Glass-lined container as claimed in the claims 18 or 19, wherein it has several baffles (14) laid out along a theoretical curve relative to the internal wall (12) of the container (1). 21. Glass-lined container as claimed in the preceding claim, wherein the theoretical curve is a helix.

Documents:

2403-DELNP-2005-Abstract-(21-08-2008).pdf

2403-DELNP-2005-Abstract-24-03-2008.pdf

2403-delnp-2005-abstract.pdf

2403-DELNP-2005-Claims-(21-08-2008).pdf

2403-DELNP-2005-Claims-(30-05-2008).pdf

2403-DELNP-2005-Claims-24-03-2008.pdf

2403-delnp-2005-claims.pdf

2403-delnp-2005-complete specification (granted).pdf

2403-DELNP-2005-Correspondence-Others-(19-04-2011).pdf

2403-DELNP-2005-Correspondence-Others-(30-05-2008).pdf

2403-DELNP-2005-Correspondence-Others-05-05-2008.pdf

2403-DELNP-2005-Correspondence-Others-23-05-2008.pdf

2403-DELNP-2005-Correspondence-Others-24-03-2008.pdf

2403-delnp-2005-correspondence-others.pdf

2403-delnp-2005-description (complete)-21-08-2008.pdf

2403-DELNP-2005-Description (Complete)-24-03-2008.pdf

2403-delnp-2005-description (complete).pdf

2403-DELNP-2005-Drawings-24-03-2008.pdf

2403-delnp-2005-drawings.pdf

2403-DELNP-2005-Form-1-(21-08-2008).pdf

2403-DELNP-2005-Form-1-24-03-2008.pdf

2403-delnp-2005-form-1.pdf

2403-DELNP-2005-Form-13-(30-05-2008).pdf

2403-delnp-2005-form-18.pdf

2403-DELNP-2005-Form-2-(21-08-2008).pdf

2403-DELNP-2005-Form-2-24-03-2008.pdf

2403-delnp-2005-form-2.pdf

2403-DELNP-2005-Form-27-(19-04-2011).pdf

2403-DELNP-2005-Form-3-24-03-2008.pdf

2403-delnp-2005-form-3.pdf

2403-DELNP-2005-Form-5-24-03-2008.pdf

2403-delnp-2005-form-5.pdf

2403-delnp-2005-form-6.pdf

2403-DELNP-2005-GPA-24-03-2008.pdf

2403-delnp-2005-gpa.pdf

2403-DELNP-2005-Others Docoment-05-05-2008.pdf

2403-DELNP-2005-Others Document-23-05-2008.pdf

2403-DELNP-2005-Petition-137-24-03-2008.pdf

2403-DELNP-2005-Petition-138-24-03-2008.pdf

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