Title of Invention	A PROCESS FOR CARRYING OUT REACTIONS BETWEEN AT LEAST TWO FLUID REACTANTS (R1, R2) USING A REACTOR
Abstract	A process for carrying out reactions between at least two fluid reactants (R1,R2) using a reactor in which there are located wall elements (1), slot-shaped reaction spaces (3) and cavities (9) for conducting a fluid heat—carrier through, characterized in that a) the slot-shaped reaction spaces (3) are formed between lateral surfaces (2) of, in each instance, two substantially equally large and substantially right- parallelepipedal wall elements (1) made of solid plates and in that the wall elements (1) are arranged interchangeably in a block (24) within a virtual right parallelepiped, b) the reactants (R1,R2) are introduced into the slot-shaped reaction spaces (3) from edge regions situated on the same side of the block (24) and are conducted through the reaction spaces (3) as reaction mixture in like directions in parallel flows and in that c) the fluid heat-carrier is conducted through the tubular cavities (9) extending in the interior of the wall elements (1).

Title of Invention

A PROCESS FOR CARRYING OUT REACTIONS BETWEEN AT LEAST TWO FLUID REACTANTS (R1, R2) USING A REACTOR

Abstract

A process for carrying out reactions between at least two fluid reactants (R1,R2) using a reactor in which there are located wall elements (1), slot-shaped reaction spaces (3) and cavities (9) for conducting a fluid heat—carrier through, characterized in that a) the slot-shaped reaction spaces (3) are formed between lateral surfaces (2) of, in each instance, two substantially equally large and substantially right- parallelepipedal wall elements (1) made of solid plates and in that the wall elements (1) are arranged interchangeably in a block (24) within a virtual right parallelepiped, b) the reactants (R1,R2) are introduced into the slot-shaped reaction spaces (3) from edge regions situated on the same side of the block (24) and are conducted through the reaction spaces (3) as reaction mixture in like directions in parallel flows and in that c) the fluid heat-carrier is conducted through the tubular cavities (9) extending in the interior of the wall elements (1).

Full Text	Process and device for carrying out reactions in a reactor with slot-shaped reaction spaces COMPLETE DESCRIPTION The invention relates to a process for carrying out reactions between at least two fluid reactants using a reactor in which there are located wall elements, slot- shaped reaction spaces and cavities for conducting a fluid heat-carrier through. BACKGROUND OF THE INVENTION By virtue of DE 33 42 74 9 A1 a plate-type reactor for chemical syntheses under high pressure is known wherein the plates take the form of flat right parallelepipeds which are bounded by sheet-metal walls and which each form a chamber filled with a catalyst, the two largest walls of which are gas-impermeable. Flow of the reaction gases through the granular catalyst takes place either horizontally or vertically through two open or pierced narrow sides of the right parallelepiped which are located opposite each other. With a view to heating or cooling (depending on the reaction, either exothermic or endothermic), cooling channels are provided in the chambers for the circulation of a liquid heat-carrier. These cooling channels may be formed by sheet-metal structures which take the form of crosspieces, corrugated sheet metal or such like and which are firmly connected to the smooth walls, for example by welding. The totality of the chambers is adapted in outline to the shape of a cylindrical reactor, so that the chambers have, in part, varying sizes and are perfused in succession by the reaction gases, e.g. also in groups. The structural design is enormously elaborate, and the production output, which as such is already low, can at best be increased by axial lengthening and/or by a parallel connection of several reactors. By virtue of EP 0 691 701 A1 a stacked reforming generator is known wherein, with a view to carrying out endothermic reactions, a reforming chambers with heat-recovery medium connected downstream is embedded in each instance between two combustion chambers. In this case the directions of flow of the gases in the reforming chambers and in the combustion chambers are opposite, semipermeable walls being arranged ahead of the heat-recovery chambers which are connected downstream in each instance. The heat-recovery medium consists, in exemplary manner, of spheres of aluminium oxide. With a view to improving the exchange of heat, between the individual chambers there are arranged horizontal heat-conducting sheets which are provided with openings for the passage of fuel in the heating region. Between each such group of three there is located, in turn, a fuel-distributing chamber. The device is extraordinarily complicated in structure and is neither provided non suitable for exothermic processes since the device possesses no cooling channels, as this would run counter to the sense and purpose of the known solution. The structural design, which is not suitable for operation at high pressure, serves the purpose of shortening the overall length by virtue of the omission of special heating zones. By virtue of DE 44 44 364 C2 a vertical fixed-bed reactor with rectangular casing cross-section is known for exothermic reactions between gases, wherein the fixed bed consisting of catalysts is subdivided by vertical partitions for the purpose of forming separate flow channels and a plate-type heat-exchanger. Below and above the flow channels, catalyst-free interspaces are located in each instance in alternating arrangement. The gases emerge at the upper end of the fixed bed from some of the flow channels and are conducted again through lateral overflow channels beneath the fixed bed, from where they are supplied through the respective other flow channels to a gas outlet nozzle. The device is neither provided nor suitable for endothermic processes, since the device possesses no means for a supply of heat. In addition, on account of the rectangular cross-section of the casing the structural design is not suitable for operation at high pressure. By virtue of EP 0 754 4 92 A2 a plate-type reactor for reactions of fluid media is known which is constructed in the form of a static mixer with exchange of heat. For this purpose, numerous plates are stacked on top of one another, the lowest of which is closed in the outward direction and the uppermost of which merely possesses bores in the outward direction for the intake and discharge of the media to be caused to react or that have been caused to react, and of a heat-carrier medium. The respective second plates from below and from above possess, in addition, recesses which are open on one side for the redirection of the reactants through the stack in a meandering shape. In the plates situated in between there are located X-shaped or cloverleaf-shaped mixing chambers and reaction chambers which are connected to one another in the direction of the stack. The heat-exchanger channel is also guided through the stack of plates in a meandering shape. The plates consist of material with good thermal conductivity, preferably metals and alloys, have a thickness between 0.25 and 25 mm and can be produced by micromachining, etching, stamping, lithographic processes etc. They are firmly and tightly connected to one another on their surfaces outside the apertures, i.e. on the periphery, for example by clamping, bolts, rivets, soldering, adhesive bonding etc, and thereby form a laminate. The complicated flow paths give rise to high resistances to fluid flow and are not capable of being filled with catalysts. On account of the requisite machining, the production process is extremely elaborate, because all the contact surfaces have to be finely ground. By virtue of DE 197 54 185 C1 a reactor for the catalytic conversion of fluid reaction media is known wherein a fixed bed consisting of catalyst material which is supported on a sieve plate is subdivided by vertical thermal sheets which each consist of two metal sheets which have been deformed repeatedly in the shape of a cushion and which are welded to one another, including a space for conducting a cooling or heating medium through at points which are distributed in the form of a grid. The reaction media and a heat- carrier medium are conducted in counterflow through the columns of the fixed bed between the thermal sheets, on the one hand, and the cavities in the thermal sheets, on the other hand. The container of the reactor is constructed in the form of a vertical cylinder, and the thermal sheets are adapted to the cylinder, that is to say they have varying sizes. Also in this case the production output, can at best be increased by axial lengthening and/or by a parallel connection of several reactors. By virtue of DE 198 16 2 96 A1 from the same applicant it is known to generate an aqueous solution of hydrogen peroxide from water, hydrogen and oxygen in a reactor which may contain both a fixed-bed packing consisting of particulate catalysts and planar monolithic carriers which are provided with channels, take the form of heat-exchangers and are provided with coatings of catalyst material. By way of catalysts, elements from the 8th and/or 1st subgroups of the Periodic Table are specified, such as Ru, Rh, Pd, Tr, Pt and Au, whereby Pd and Pt are particularly preferred. Activated carbon, water-insoluble oxides, mixed oxides, sulfates, phosphates and silicates of alkaline-earth metals, Al, Si, Sn and of metals pertaining to the 3rd to 6th subgroups are specified by way of carrier materials. Oxides of silicon, of aluminium, of tin, of titanium, of zirconium, of niobium and of tantalum as well as barium sulfate are specified as being preferred. Metallic or ceramic walls having the function of heat-exchangers analogous to plate-type heat-exchangers are named as materials for monolithic carriers. The specified experimental reactor had an inside diameter of 18 mm with a length of 4 00 mm. The temperatures were within the range from 0 to 90 °C, preferably 20 to 70 °C, the pressures were between atmospheric pressure and about 10 MPa, preferably between about 0.5 and 5 MPa. Also with respect to this state of the art, the production output can at best be increased by axial lengthening and/or by a parallel connection of several reactors. A reactor as to DE 195 44 985 C1 as well as DE 197 53 720 A1 comprises a plate-like heat exchanges wherein the fluid head-carrier is conducted through the slot formed between two plates. There is no hint on the function of width slot- shaped reaction spaces. A device as to DE 197 41 645 Al comprises a microreactor with reactions and cooling channels wherein the depth a of the reaction channels is thickness b between reaction and cooling channels is µm. This document gives no indication to use reaction spaces other than said channels. A microreactor comprising many parallel grooves as reaction spaces is thought by DE 197 48 481. The manufacture of a reactor for large scale throughput is expensive. Furthermore, so-called microreactors are known in which the dimensions of the flow channels are in the region of a few hundred micrometres (as a rule, high transport values (heat-transfer and mass-transfer parameters). The fine channels act as flame barriers, so that no explosions are able to spread. In the case of toxic reactants, a small storage volume (hold-up volume) leads, in addition, to inherently safe reactors. But a filling of the channels with catalysts is impossible by reason of the small dimensions. A further crucial disadvantage is the elaborate production process. In order to avoid clogging of the fine channels, over and above this an appropriate protection of the filter has to be provided for upstream of the reactor. High production outputs can only be obtained by means of parallel connections of many such reactors. Furthermore, the reactors can only be operated at higher pressures when the cooling medium is at the same pressure level. GENERAL DESCRIPTION OF THE INVENTION The object underlying the invention is to specify a process and a device with which it is possible to carry out, optionally, exothermic and endothermic processes whereby several fluid reactants react with react other in the presence or absence of catalysts and whereby the reaction region of the reactor is constructed in a modular design, so that it is possible to adapt the production output to the requirements. In accordance with the invention, the object as formulated is achieved, in the case of the process specified at the outset, in that a) the slot-shaped reaction spaces are formed between lateral surfaces of, in each instance, two substantially equally large and substantially right-parallelepiped wall elements made from solid plates and in that the wall elements are arranged interchangeably in a block within a virtual right parallelepiped, b) the reactants are introduced into the slot-shaped reaction spaces from edge regions situated on the same side of the block and are conducted through the reaction spaces as reaction mixture in like directions in parallel flows, and in that c) the fluid heat-carrier is conducted through the cavities extending in the interior of the wail elements. BRIEF DESCRIPTION OF DRAWINGS Shown are: Figure 1 a perspective exploded representation of a group consisting of two wall elements, Figure 2 a perspective schematic representation of a series arrangement of numerous wall elements according to Figure 1, Figure 3 a vertical section through a series arrangement; according to Figure 2 above the bottom of a pressure-resistant reactor, Figure 4 the detail from circle A in Figure 3 on an enlarged scale, supplemented in perspective view, Figure 5 a partial vertically sectioned side view through the subject of Figure 3 after rotation about an angle of 90 degrees, Figure 6 the subject of Figure 2, schematically supplemented by a distributing space and a collecting space for educt(s) and product, Figure 7 a vertical section through a plate and a distributing body with flow channels for reactants and/or heat-carrier, Figure 8 a partial vertical section through a first exemplary embodiment of a reactor with a pressure vessel, Figure 9 a bottom view of the lid of the pressure vessel according to Figure 8. Figure 10 a partial vertical section through a second exemplary embodiment of a reactor with a pressure vessel. DETAILD DESCRIPTION By virtue of the invention the object as formulated is achieved in full measure; in particular, it is possible to carry out, optionally, exothermic and endothermic processes whereby several fluid reactants (gases and/or liquids) react with each other in the presence or absence catalysts and whereby the reaction region of the reactor is constructed in a modular design, so that it is possible to adapt the production output to the requirements. By reducing width of the reaction spaces from e.g. 5 mm to 0,05 mm the ratio of the surface to the volume of the reaction spaces is increasing. As a result, problems araising from the limited heat transfer within gases are decreased, so that highly exothermic or endothermic reactions can safely be performed. However, still further advantages arise: combination of microreaction technology with the advantages of simple manufacture according to classical workshop techniques, easy interchange of indivi dual wall elements (the term "substantially equally large and substantially right- parallelepiped" means that minor deviations, caused by continetive reasons, are tolerable) , virtually arbitrary thickness of the wali. elements without impairment of function, enlargement of the specific surface area by profiling/roughening, direct total or partial coating of the lateral surfaces with varying catalyst material by impregnating, spraying, printing or such like with varying thickness, filling of the reaction spaces with catalyst particles of varying size, possibilities of gas/gas reactions, gas/liquid reactions, liquid/liquid reactions, impression of flow patterns and flow channels, e.g. for drainage and for allowing liquid reaction products to flow off, simple separation, possibility of altering the slot widths, mixing of the reactants only in the reaction spaces, good reaction control, avoidance of backflows out of the reaction spaces, good controllability by reason of high heat-transfer coefficients and large surfaces, i.e. rapid response to changes in loading and/or in the desired temperature values and uniform temperature profile and thereby longer service lives of the catalyst by avoidance of "hot spots", inherent safety in the course of causing otherwise explosive reaction mixtures to react, small dead volume ("hold-up volume"), possibility of working under high pressure, slight losses of pressure in the reaction spaces, immersibility in liquid solvents and operability with a sump which can be temperature-controlled (heated/cooled) from outside and which enables a gentle termination of the reaction by "quenching" and/or washing, possible addition of inhibitors in order to prevent secondary reactions, reducibility of the volume of the gas/liquid by means of filling materials and/or displacers in the pressure vessel on the other side of the product outlet in the sump, reduction in the number of connections and easier sealability as regards leakages (important in the case of toxic components), low resistances to diffusion, high space-time yields, in particular higher throughputs than in the case of the known microreactors, simpler "scale-up" from the laboratory scale to the production scale by multiplication ("number-up"), simple and compact structural design, reduction of investment costs and operating costs (maintenance, consumption of energy), possibility of the construction of small plants. In this connection it is particularly advantageous, within the scope of further configurations of the process according to the invention, if - either individually or in combination: at least one reactant is supplied through the wall elements and is introduced into the reaction space in question through at least one of the lateral surfaces of the wall elements, a distributing medium, from which the reaction spaces are provided with the reactants, is arranged on at least one side of the block, by way of distributing medium, use is made of a solid body with groups of channels, the cross-sections of which are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants that form an explosive mixture, by way of distributing medium, use is made of a packing material with a grain size and with interspaces that are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants that form an explosive mixture, the slot width of the reaction spaces is preferably chosen between 0.05 and 5 mm and more preferred 0,05 to 0,2 mm, in case of explosive reactions mixtures the slot width os chosen so small that no spreading of flames is possible, the reaction spaces are filled with granular catalyst, the lateral surfaces of the wall elements facing towards the reaction spaces are covered at least in places with catalyst material, the lateral surfaces of the wall elements facing towards the reaction spaces are provided with a profiled structure for the purpose of enlarging the surface area, the wall elements are immersed at least partially in an aqueous or organic solvent or solvent mixture, by way of solvent, use is made of water, optionally with at least an addition of inhibitors that prevent a decomposition and/or degradation of the reaction product, and/or, if the process is used for the purpose of producing hydrogen peroxide from water (vapour), hydrogen and air, optionally enriched with oxygen, or oxygen. The invention also relates to a device for carrying out reactions between at least two fluid reactants using a reactor in which there are located wall elements, slot- shaped reaction spaces and cavities for the purpose of conducting a fluid heat-carrier through. With a view to achieving the same object, such a device Ls characterised, according to the invention, in that a) the slot-shaped reaction spaces are arranged between lateral surfaces of, in each instance, two substantially equally large and substantially right-parallelepipedal wall elements made from solid plates and in that the wall elements are arranged interchangeably in a block within a virtual right parallelepiped, b) the supply of the reactants into the slot-shaped reaction spaces is capable of being carried out from the same side of the block, the reaction mixture being capable of being guided through the reaction spaces in like directions and in parallel flows and in that c) the wall elements each tubular cavities for conducting the fluid heat-carrier through the wall element. The process and the device are suitable, in exemplary manner, for the following processes: selective hydrogenations and oxidations, production of propenal by catalytic oxidation of propene with an O2-containing gas having elevated oxygen concentration in comparison with air, accompanied by an increase in selectivity, for example in the presence of a Mo-containing catalyst at a temperature within the range from 350 to 500 °C and at a pressure wi thin the range from 0.1 to 5 MPa, production of acrylic acid by catalytic oxidation of propene, for example in the presence of a Mo-containing catalyst and a promoter at 250 to 350 °C and at 0.1 to 0.5 MPa , production of ethylene oxide or propylene oxide from ethylene or propylene, respectively, and gaseous hydrogen peroxide in the presence of an oxidic or siliceous catalyst, such as titanium silicalite, at a temperature within the range from 60 to 200 °C and at. a pressure within the range from 0.1 to 0.5 MPa, direct synthesis of hydrogen peroxide from H2 and O2 or an O2-containing gas in the presence of a noble-metal catalyst and water or water vapour - for example according to the process disclosed in DE-A 198 16 296 and according to those processes disclosed in further documents cited therein. By way of catalysts in this connection, use may be made of elements from the 8th and/or 1st subgroups of the Periodic Table, such as Ru, Rh, Pd, Ir, Pt and Au, whereby Pd and PL are particularly preferred. The catalysts may be employed per se, e.g. as suspension catalysts, or in the form of supported catalysts by way of packing in the slot-shaped reaction spaces, or they are fixed to the wall elements, directly or through the agency of layer-forming supporting materials. By way of supporting materials, use may be made of activated carbon, water-insoluble oxides, mixed oxides, sulfates, phosphates and silicates of alkaline-earth metals, Al, Si, Sn and of metals pertaining to the 3rd to 6th subgroups. Oxides of silicon, of aluminium, of tin, of titanium, of zirconium, of niobium and of tantalum as well as barium sulfate are preferred. In the case of the direct synthesis of hydrogen peroxide, the reaction temperatures lie, in exemplary manner, within the range from 0 to 90 °C, preferably 20 to 70 °C, the pressures lie between atmospheric pressure and about 10 MPa, preferably between about 0.5 and 5 MPa. In this connection it is particularly advantageous, within the scope of further configurations of the device according to the invention, if - either individually or in combination: in the wall elements there is arranged, in each instance, at least one feed channel which leads into the reaction space in question through at least one of the lateral surfaces of the wall elements, on at least one side of the block there is arranged a distributing medium through which the reaction spaces are capable of being provided with the reactants, the distributing medium is a solid body with groups of channels, the cross-sections of which are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants that form an explosive mixture, the distributing medium is a packing material with a grain size and with interspaces that are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants that form an explosive mixture, the slot width of the reaction spaces preferably amounts to between 0.05 and 5 mm and especially preferred to 0,05 to 0,2 mm, the reaction spaces are filled with granular catalyst, the lateral surfaces of the wall elements facing towards the reaction spaces are covered at least in places with catalyst material, the lateral surfaces of the wall elements facing towards the reaction spaces are provided with a profiled structure for the purpose of enlarging the surface area, the wall elements are partially or completely arranged in a vessel, the reaction spaces on the narrow sides of the wall elements extending parallel to the direction of flow of the reactants are closed by plates in which there are located openings for the feeding and drainage of a heat- carrier into the wall elements and out of the wall elements, in the plates there are located further openings for the feeding of at least one of the reactants into the wall elements and the wall elements are each provided with at least one feed channel which via discharge openings leads, in each instance, into one of the reaction spaces, the wall elements are each provided with a group of tubular cavities which extend parallel to the lateral surfaces of the wall elements and are closed at their ends by the plates which are mounted onto the narrow sides of the wall elements and in which openings for the heat-carrier that are in alignment with the cavities are located, the plates are provided on their outsides and ahead of the openings with flow channels extending at right angles to the wall elements for at least one of the reactants and/or a heat-carrier , the plates are covered on their outsides facing away from the wall elements by a distributing body in which there are located flow channels into which the openings in the plates lead, the wall elements are formed by two subelements having semicylindrical or otherwise shaped recesses whereby tubular cavities are formed by two respective subelements pressing together , the wall elements are accommodated as a block in a pressure vessel, the pressure vessel is capable of being filled at least partially with a solvent, the pressure vessel possesses a lid with a partition and two connecting sockets for the feeding of two reactants and the partition is capable of being mounted onto the distributing medium, the slot width of the reaction spaces is capable of being changed by varying the thickness of spacers. Exemplary embodiments of the subject-matter of the invention will be elucidated Ln greater detail below on the basis of Figures 1 to 10. In Figure 1 there are shown - in exploded representation - two wall elements 1 with lateral surfaces 2 which include between themselves a reaction space 3 through which the reactants flow in the direction of the arrow 4. In each of the wall elements there are arranged cavities 5 in the form of through bores which extend parallel to the lateral surfaces 2 and terminate in the narrow sides 6 of the wall elements 1. Alternative solutions are specified further below. The wall elements 1 take the form of flat right parallelepipeds, the largest surfaces of which are the lateral surfaces 2. These lateral surfaces 2 may - as shown - be provided with a profiled structure, that is to say they may be roughened, for example, in order to enlarge the effective surface area. The lateral surfaces 2 may furthermore be wholly or partially provided with surface deposits consisting of a catalyst material, but this is not represented separately here. Further particulars are evident from Figure 4. It is also possible, alternatively or in addition, to arrange particulate catalysts in the reaction space 3, the size of which is adapted to the slot width "s" (Figure 4). Figure 2 shows the combination of thirteen such equally large wall elements 1 so as to form a right- parallelepipedal block 24; however, this number is variable, wherein one of the essential purposes of the invention lies, namely the possibility of adaptation to varying production outputs and processes. The mass transport in unidirectional parallel flows - here from above in a downward direction - is only hinted at by means of arrows. Figure 3 shows a vertical section through a series arrangement according to Figure 2 above the bottom 7 of a pressure-resistant reactor, the lower flanged joint 8 of which is shown here. The supply of liquid solvents is effected via the pipe 9, the removal of residual gases is effected via the pipe 10, the removal of the end product is effected via the pipe 11, and the removal of sump material is effected via the pipe 12, optionally with a view to cleaning. Figure 4 shows the detail from circle A in Figure 3 on an enlarged scale and supplemented in perspective view, i.e. the circumstances on both sides of a reaction space 3. The slot width "s" of the reaction space 3 is maintained at a predetermined measurement by spacers 13 and is chosen, in exemplary manner, between 0.05 and 5 mm. However, this range may also be fallen below or exceeded. In case of highly exothermic and endothermic reactions, esspecially comprising an explosive gas mixture, the slot width is reduced until any flame spreading is avoided. The optimal lot width depends on the medium and reaction type and i s determined by experiments. As can be seen from Figures 4 and 6 the slot width "s" of the inventive device is significantly smaller than the thickness of the wall elements. In the tubular wall elements there are located the cavities 5, which have already been described, for conducting a fluid heat-carrier through. Depending on the temperature control thereof, heat can be dissipated in the case of an exothermic process or heat can be supplied in the case of an endothermic process. By way of heat- carrier, use may be made of water, oils, gases and optionally also the product itself. In the wall elements 1 there are located furthermore semicylindrical recesses 14 which complement one another so as to form a substantially cylindrical feed channel 15 for a first reactant. Located furthermore in the wall elements are further feed channels 16 for at least one further reactant. The feed channels 16 are connected to the respective reaction space 3 by means of discharge openings 17, whereby the discharge openings 17 lead into the Lateral surfaces 2 of the wall elements so that the reactants are able to mix in the reaction spaces 3. The cavities 5, the feed channels 15 and 16 and also the row(s) of discharge openings 17 are parallel to one another and to the lateral surfaces 2 of the wall elements 1 and extend over the entire length thereof - viewed in the horizontal direction. The cooling channels (= tubular cavities (5)) may, Ln a manner analogous to the formation of the feed channels (15) according to Figure 4, also be configured, in such a way that each wall element (1) is split parallel to the lateral surfaces (2) into two subelements and semicylindrical or otherwise shaped recesses are arranged in the slot surfaces. As a result of pressing the respective two corresponding subelements together, cavities (5) are formed, through which a fluid heat-carrier is able to flow. The term "tubular" comprises round or square-formed channels or pipes. The slot width "s" is so chosen that no flames are able to spread in the reaction spaces 3 in the case of explosive reaction mixtures. In special cases, the local formation of explosions in the reaction spaces may also be permitted, in which case care has only to be taken structurally to ensure that these explosions do not flash over to adjacent reaction spaces. Important in this connection is the fact that the feed channels 15 and 16 extend in the (upper) edge region of the wall elements 1 or of the reaction spaces 3, so that virtually the entire (vertical) length of the reaction spaces 3 is available for the reaction. Further particulars of and alternatives to the supply and removal of reactants and heat-carrier will be elucidated in still more detail on the basis of the following Figures. Figure 5 shows a partially sectioned side view through the subject of Figure 3 after rotation about a vertical axis by an angle of 90 degrees. Two reactants are supplied to the system through the feed pipes 18 and 19: in the case of the production of hydrogen peroxide, air via feed pipe 18 and hydrogen via feed pipe 19. The transport of the fluid heat-carrier through the cavities 5 will also be elucidated in greater detail on the basis of Figure 5: the narrow sides 6 of the wall elements 1 are closed by mounted plates 20 in which there are arranged U-shaped channels 21 for the connection of, in each instance, two cavities 5. However, this is only represented on the left-hand, side of the block. The heat-carrier is supplied through a feed pipe 22 and is removed through a drain 23. For the wall elements, use may be made of sufficiently heat conductive, preferable metallic, substantially right- parallelepipedal plates. The wall elements 1, which are preferably made out of metal (e.g. stainless steel), may consist of solid plates with appropriate bores (cavities 5 and feed channels 16) and recesses 14. Alternatively, the cavities 5 may be combined, optionally also in groups, in which case conducting devices, e.g. ribs, for guidance of the heat-carriers are arranged within the cavities which are then larger. The wall elements 1 may also be composed of two plate-like subelements which are connected to one another in sealed manner, for example screwed together. The only important point is that they withstand the, in some cases, considerable pressure differences (up to 10 MPa or 100 bar) between the heat-carrier and the reactants. Figure 6 shows the subject of Figure 2, schematically and complemented in thick lines by an (upper) distributing space 48 with a central feed pipe 49 for educt(s) and a (lower) collecting space 50 with a drain 51 for the product. One of the reactants or a mixture of the reactants R1 and R2 can be supplied via the distributing space 48. In the case of a mixture, the feed pipes 15 and 16 (in Figure 4) can be dispensed with if the spacers 13 are interrupted. In the case of explosive reaction mixtures, in addition to the procedure according to the arrangement in Figure 2 a procedure according to the arrangements in Figures 8 to 10 can also be adopted. The open narrow sides 6 of the wall elements 1 can be covered by a plate combination, consisting of a plate 41 and a distributing body 47, which is designed to be uninterrupted over the width and height of all the wail elements 1 and which is represented - on a greatly enLarged scale - in Figure 7. Figure 7 shows a vertical section through the upper edge region of such a plate combination 41/47 with a flow channel 45 for one of the reactants and with flow channels 4 6 for the heat-carrier. For the intake and/or discharge thereof, openings 42 and 43 which are connected to the flow channels 45 and 4 6 in the distributing body 47 are arranged in the plate 41. The flow channels 45 and 46, which extend perpendicular to the plane of the drawing, are formed, for example, by grooves in the distributing body 47. The grooves may be produced by metal-cutting, by casting or forging. This results in great stability of form which withstands the pressure differences that are demanded. This plate combination 41/47 - with its openings 42 and 43 in alignment with the associated channels in the wall elements 1 - is now screwed in sealing manner by means of a gasket 54 onto all the narrow sides 6 of the wall elements 1 of the block 24. Only a few of the numerous screw joints 52 are represented. By this means, a provision of the wall elements 1 is effected corresponding to the arrows 53 in Figure 6. By means of dashed lines 55 it is indicated that several flow channels 4 6 may also be combined to form a common flow channel or distributing space. The plate combination 41/47 may also be redesigned to the effect that it is suitable for a provision of wall elements 1 according to Figure 4. Now Figure 8 shows, on the basis of a partial vertical section, a schematic representation of a complete reactor, e.g. for the production of hydrogen peroxide. A right- parallelepipedal block 24 consisting of several wail elements 1 according to Figures 1 and 2 is suspended from above in a pressure vessel 2 5 which is filled with a solvent 27, for example water, to a level 26. The slot- shaped reaction spaces 3 extend parallel to the plane of the drawing. At the top the pressure vessel. 25 possesses a Lid 2.8 which is subdivided by a partition 29 into two chambers 30 and 31, the partition 29 being mounted in sealing manner onto a distributing medium 37 which consists of a solid body (preferably made of metal) with two separate groups of narrow channels 39 and 40. The channels 39 extend in the solid body from the chamber 30 to the upper ends of the reaction spaces 3, the channels 40 extend from the chamber 31 to the upper ends of the reaction spaces 3. In those channels 39 and 40 the reactants are accordingly unable to mix, but, even if this were to happen, no flames are able to spread in the channels 39 and 40. Mixing of the reactants takes place only in the reaction spaces 3, in which likewise no flames are able to spread if it is a guestion of a reaction mixture that is explosive as such. The explosive properties of the reaction mixture are material-dependent and reaction-dependent and have to be determined in the given case. Through a connecting socket 34 a first reactant "R1" is supplied to chamber 30, and through a further connecting socket 35 a second reactant "R2" is supplied to chamber 31. The waste gases that are not needed are conducted away according to arrow 32, the product is withdrawn according to arrow 33, and the sump can be emptied through the pipe 12. Figure 8 shows, in addition, another connecting socket 36 for a third reactant "R3" and/or a solvent such as water. The plates 41 which are applied at both ends are only indicated very schematically. Figure 9 shows a bottom view of the lid 2 8 of the pressure vessel 25 according to Figure 8. Bores 28a serve for screw coupling. Figure 10 differs from Figure 8 in that, by way of distributing medium 38, there is arranged above the block 24 of wall elements 1 a packing material which consists of heat-conducting particles, for example sand, grit, metal shavings, metallic fibres or such like, which rest on a sieve plate which is not shown. In this distributing medium 38 the reactants R1 and R2 already mix in accordance with random distribution before they enter the reaction spaces 3. However, the distributing medium forms such narrow interspaces that, likewise, no spreading of flames with explosive consequences is able to occur in them. The spatial location of the wall elements 1 is practically arbitrary: in accordance with the Figures, they may be arranged in a horizontal series arrangement, but they may also be arranged in a vertical, stack. The direction of the parallel flows can also be adapted to practical needs: as shown, the parallel flows can be guided vertically from the top downwards, but they may also be guided the other way round, from the bottom upwards. The parallel flows may also run horizontally. As a result, the block 2 4 with the plates 41 and the connections can be "rotated" into various spatial locations. List of Reference Symbols: 1 wall elements 2 lateral surfaces 3 reaction spaces 4 arrow 5 cavities 6 narrow sides 7 bottom 8 flanged joint 9 pipe 10 pipe 11 pipe 12 pipe 13 spacer 14 recesses 15 feed channel 16 feed channels 17 discharge openings 18 feed pipe 19 feed pipe 20 plates 21 channels 22 feed pipe 23 drain 24 block 25 pressure vessel 26 level 27 solvent 28 lid 28a bores 29 partition 30 chamber 31 chamber 32 arrow 33 arrow 34 connecting socket 35 connecting socket 36 connecting socket 37 distributing medium 38 distributing medium 39 channels 40 channels 41 plates 42 openings 43 openings 44 outside 45 flow channels 46 flow channels 47 distributing body 48 distributing space 49 feed pipe 50 collecting space 51 drain 52 screwed joint 53 arrows 54 gasket 55 lines R1 reactant R2 reactant R3 reactant s slot width A detail (from Figure 3) WE CLAIM: 1. A process for carrying out reactions between at least two fluid reactants (R1, R2) using a reactor in which there are located wall elements (1), slot-shaped reaction spaces (3) and cavities (5) for conducting a fluid heat-carrier through, characterized in that (a) the reaction spaces (3) are slot-shaped and formed between lateral surfaces (2) of, in each instance, two substantially equally large and substantially right parallelepipedal wall elements (1) made of solid plates and in that the wall elements (1) are arranged interchangeably in a block (24) within a virtual right parallelepiped, b) the reactants (R1,R2) are introduced into the slot-shaped reaction spaces (3) from edge regions situated on the same side of the block (24) and are conducted through the reaction spaces (3) as reaction mixture in like directions in parallel flows and in that c) the fluid heat-carrier-is conducted though the tubular cavities (5) extending in the interior of the wall elements (1). and wherein the slot width ("s") of the reaction spaces (3) amounts to between 0.05 and 5 mm, whereby in case of explosive reaction mixtures the slot width "s" of the reaction spaces is chosen so small in order to avoid spreading of flames. 2. Process as claimed in Claim 1, wherein at least one reactant is supplied through the wall elements (1) and is introduced into the reaction space (3) in question through at least one of the lateral surfaces (2) of the wall elements (1). 3. Process as claimed in Claim 1, wherein on at least one side of the block (24) there is arranged a distributing medium (37,38) from which the reaction spaces (3) are provided with the reactants (R1, R2). 4. Process as claimed in Claim 3, wherein by way of distributing medium (37) use is made of a solid body with groups of channels (39,40), the cross-sections of which are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants (R1,R2) that form an explosive mixture. 5. Process as claimed in Claim 3, wherein by way of distributing medium (38) use is made of a packing material with a grain size and with interspaces that are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants (R1,R2) that form an explosive mixture. 6. Process as claimed in Claim 1, wherein the slot width of the reaction spaces (3) is chosen between 0.05 and 5 mm, whereby in case of explosive reaction mixtures the slot width "s" of the reaction spaces is chosen so small in order to avoid spreading of flames. 7. Process as claimed in Claim 1, wherein the reaction spaces (3) are filled with granular catalyst. 8. Process as claimed in Claim 1, wherein the lateral surfaces (2) of the wall elements (1) facing towards the reaction spaces (3) are covered at least in places with catalyst material. 9. Process as claimed in Claim 1, wherein the lateral surfaces (2) of the wall elements (1) facing towards the reaction spaces (3) are provided with a profiled structure for the purpose of enlarging the surface area. 10. Process as claimed in Claim 1, wherein the wall elements (1) are immersed at least partially in a solvent (27). 11. Process as claimed in Claim 10, wherein use is made of water by way of solvent (27). 12. Process as claimed in Claim 10, wherein at least one stabilizing additive for countering decomposition or degradation of the reaction product is added to the solvent (27). 13. Process as claimed in at least one of Claims 1 to 12, characterized by use for the direct synthesis of hydrogen peroxide from hydrogen and oxygen or an 02-containing gas in the presence of a catalyst containing at least one element from the 8th and/or 1st subgroups of the Periodic Table and water or water vapour. 14. Process as claimed in at least one of Claims 1 to 12, characterised by use for the production of propenal from propene and an 02-containing gas in the presence of a catalyst. 15. Process as claimed in at least one of Claims 1 to 12, characterized by use for the production of acrylic acid from propene and an 02- containing gas in the presence of a catalyst and a promoter. 16. Process as claimed in at least one of Claims 1 to 12, characterized by use for the production of ethylene oxide or propylene oxide from ethylene or propylene, respectively, and gaseous hydrogen peroxide in the presence of an oxidic or siliceous catalyst. 17. A device for carrying out reactions between at least two fluid reactants (R1,R2) using a reactor in which there are located wall elements (1), reaction spaces (3), and cavities (5) for conducting a fluid heat-carrier through, wherein (a) the reaction spaces (3) are slot-shaped and arranged between lateral surfaces (2) of, in each instance, two substantially equally large and substantially right-parallelepipedal wall elements (1) made of solid platesand in that the wall elements (1) are arranged interchangeably in a block (24) within a virtual right parallelepiped, (b) the supply of the reactants into the slot-shaped reaction spaces (3) is capable of being carried out from the same side of the block (24), the reaction mixture being capable of being guided through the reaction spaces (3) in like directions and in parallel flows, and in that (c) the wall elements (1) possess tubular cavities (5) for conducting the fluid heat-carrier through the wall element(1). and wherein the slot width ("s") of the reaction spaces (3) amounts to between 0.05 and 5 mm, whereby in case of explosive reaction mixtures the slot width "s" of the reaction spaces is chosen so small in order to avoid spreading of flames. 18. Device as claimed in Claim 17, wherein in the wall elements (1) there is arranged, in each instance, at least one feed channel (16) for at least one reactant, which leads into the reaction space (3) in question through at least one of the lateral surfaces (2 ) of the wall elements(1) 19. Device as claimed in Claim 17, wherein on at least one side of the block (24) there is arranged a distributing medium (37, 38) through which the reaction spaces ( 3 ) are capable of being provided with the reactants (R1, R2). 20. Device as claimed in Claim 19, wherein the distributing medium (37) is a solid body with groups of channels (39,40), the cross-sections of which are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants (R1, R2) that form an explosive mixture. 21. Device as claimed in Claim 19, wherein the distributing medium (38) is a packing material with a grain size and with interspaces that are chosen to be so small that no spreading of flames is possible in them in the course of the supply of reactants (R1,R2) reactants (R1, R2) that form an explosive mixture. 22. Device as claimed in Claim 17, wherein the slot width ("s") of the reaction spaces (3) amounts to between 0.05 and 5 mm, whereby in case of explosive reaction mixtures the slot width "s" of the reaction spaces is chosen so small in order to avoid spreading of flames. 23. Device as claimed in Claim 17, wherein the reaction spaces (3) are filled with granular catalyst. 24. Device as claimed in Claim 17, wherein the lateral surfaces (2) of the wall elements (1) facing towards the reaction spaces (3) are covered at least in places with catalyst material. 25. Device as claimed in Claim 17, wherein the lateral surfaces (2) of the wall elements (1) facing towards the reaction spaces (3) are provided with a profiled structure for the purpose of enlarging the surface area. 26. Device as claimed in Claim 17, wherein the reaction spaces (3) are covered on the narrow sides (6) of the wall elements (1) extending parallel to the direction of flow of the reactants (R1, R2) by plates (41) in which there are located openings (43) for the feeding and drainage of a heat-carrier into the wall elements (1) and out of the wall elements (1). 27. Device as claimed in Claim 26, wherein in the pates (41) there are located further openings (42) for feeding at least one of the reactants (R1,R2) into the wall elements (1) and in that the wall elements(1) are each provided with at least one feed channel (16) which leads via discharge openings (17) into, in each instance, one of the reaction spaces (3). 28. Device as claimed in Claim 26, wherein the wall elements (1) are each provided with a group of cavities (5) which extend parallel to the lateral surfaces (2) of the wall elements (1) and are closed at their ends by the plates (41) which are mounted onto the narrow sides (6) of the wall elements (1) and in which the openings (43) for the heat-carrier which are in alignment with the cavities (5) are located. 29. Device as claimed in Claims 26 and 27, wherein the plates (41) are provided on their outsides (44) and ahead of the openings (42,43) with flow channels (45, 46) extending at right angles to the wall elements (1) for at least one of the reactants (R1, R2) and/or the heat-carrier. 30. Device as claimed in Claim 29, wherein the plates (41) are covered on their outsides (44) facing away from the wall elements (1) by a distributing body (47) in which the flow channels (45, 46) are located into which the openings (42,43) in the plates (41) lead. 31. Device as claimed in Claim 17, wherein the wall elements (1) are accommodated as a block (24) in a pressure vessel (25). 32. Device as claimed in Claims 19 and 31, wherein the pressure vessel (25) possesses a lid (28) with a partition (29) and two connecting sockets (34,35) for the feeding of two reactants (R1, R2), said partition (29) being capable of being mounted onto the distributing medium (37,38). 33. Device as claimed in Claim 17, wherein the slot width ("s") of the reaction spaces (3) is capable of being changed by varying the thickness of spacers (13). A process for carrying out reactions between at least two fluid reactants (R1,R2) using a reactor in which there are located wall elements (1), slot-shaped reaction spaces (3) and cavities (9) for conducting a fluid heat—carrier through, characterized in that a) the slot-shaped reaction spaces (3) are formed between lateral surfaces (2) of, in each instance, two substantially equally large and substantially right- parallelepipedal wall elements (1) made of solid plates and in that the wall elements (1) are arranged interchangeably in a block (24) within a virtual right parallelepiped, b) the reactants (R1,R2) are introduced into the slot-shaped reaction spaces (3) from edge regions situated on the same side of the block (24) and are conducted through the reaction spaces (3) as reaction mixture in like directions in parallel flows and in that c) the fluid heat-carrier is conducted through the tubular cavities (9) extending in the interior of the wall elements (1).

Full Text

Process and device for carrying out reactions in a reactor
with slot-shaped reaction spaces
COMPLETE DESCRIPTION
The invention relates to a process for carrying out
reactions between at least two fluid reactants using a
reactor in which there are located wall elements, slot-
shaped reaction spaces and cavities for conducting a fluid
heat-carrier through.
BACKGROUND OF THE INVENTION
By virtue of DE 33 42 74 9 A1 a plate-type reactor for
chemical syntheses under high pressure is known wherein the
plates take the form of flat right parallelepipeds which
are bounded by sheet-metal walls and which each form a
chamber filled with a catalyst, the two largest walls of
which are gas-impermeable. Flow of the reaction gases
through the granular catalyst takes place either
horizontally or vertically through two open or pierced
narrow sides of the right parallelepiped which are located
opposite each other. With a view to heating or cooling
(depending on the reaction, either exothermic or
endothermic), cooling channels are provided in the chambers
for the circulation of a liquid heat-carrier. These
cooling channels may be formed by sheet-metal structures
which take the form of crosspieces, corrugated sheet metal
or such like and which are firmly connected to the smooth
walls, for example by welding. The totality of the
chambers is adapted in outline to the shape of a
cylindrical reactor, so that the chambers have, in part,
varying sizes and are perfused in succession by the
reaction gases, e.g. also in groups. The structural design
is enormously elaborate, and the production output, which
as such is already low, can at best be increased by axial
lengthening and/or by a parallel connection of several
reactors.

By virtue of EP 0 691 701 A1 a stacked reforming generator
is known wherein, with a view to carrying out endothermic
reactions, a reforming chambers with heat-recovery medium
connected downstream is embedded in each instance between
two combustion chambers. In this case the directions of
flow of the gases in the reforming chambers and in the
combustion chambers are opposite, semipermeable walls being
arranged ahead of the heat-recovery chambers which are
connected downstream in each instance. The heat-recovery
medium consists, in exemplary manner, of spheres of
aluminium oxide. With a view to improving the exchange of
heat, between the individual chambers there are arranged
horizontal heat-conducting sheets which are provided with
openings for the passage of fuel in the heating region.
Between each such group of three there is located, in turn,
a fuel-distributing chamber. The device is extraordinarily
complicated in structure and is neither provided non
suitable for exothermic processes since the device
possesses no cooling channels, as this would run counter to
the sense and purpose of the known solution. The
structural design, which is not suitable for operation at
high pressure, serves the purpose of shortening the overall
length by virtue of the omission of special heating zones.
By virtue of DE 44 44 364 C2 a vertical fixed-bed reactor
with rectangular casing cross-section is known for
exothermic reactions between gases, wherein the fixed bed
consisting of catalysts is subdivided by vertical
partitions for the purpose of forming separate flow
channels and a plate-type heat-exchanger. Below and above
the flow channels, catalyst-free interspaces are located in
each instance in alternating arrangement. The gases emerge
at the upper end of the fixed bed from some of the flow
channels and are conducted again through lateral overflow
channels beneath the fixed bed, from where they are
supplied through the respective other flow channels to a
gas outlet nozzle. The device is neither provided nor

suitable for endothermic processes, since the device
possesses no means for a supply of heat. In addition, on
account of the rectangular cross-section of the casing the
structural design is not suitable for operation at high
pressure.
By virtue of EP 0 754 4 92 A2 a plate-type reactor for
reactions of fluid media is known which is constructed in
the form of a static mixer with exchange of heat. For this
purpose, numerous plates are stacked on top of one another,
the lowest of which is closed in the outward direction and
the uppermost of which merely possesses bores in the
outward direction for the intake and discharge of the media
to be caused to react or that have been caused to react, and
of a heat-carrier medium. The respective second plates
from below and from above possess, in addition, recesses
which are open on one side for the redirection of the
reactants through the stack in a meandering shape. In the
plates situated in between there are located X-shaped or
cloverleaf-shaped mixing chambers and reaction chambers
which are connected to one another in the direction of the
stack. The heat-exchanger channel is also guided through
the stack of plates in a meandering shape. The plates
consist of material with good thermal conductivity,
preferably metals and alloys, have a thickness between 0.25
and 25 mm and can be produced by micromachining, etching,
stamping, lithographic processes etc. They are firmly and
tightly connected to one another on their surfaces outside
the apertures, i.e. on the periphery, for example by
clamping, bolts, rivets, soldering, adhesive bonding etc,
and thereby form a laminate. The complicated flow paths
give rise to high resistances to fluid flow and are not
capable of being filled with catalysts. On account of the
requisite machining, the production process is extremely
elaborate, because all the contact surfaces have to be
finely ground.

By virtue of DE 197 54 185 C1 a reactor for the catalytic
conversion of fluid reaction media is known wherein a fixed
bed consisting of catalyst material which is supported on a
sieve plate is subdivided by vertical thermal sheets which
each consist of two metal sheets which have been deformed
repeatedly in the shape of a cushion and which are welded
to one another, including a space for conducting a cooling
or heating medium through at points which are distributed
in the form of a grid. The reaction media and a heat-
carrier medium are conducted in counterflow through the
columns of the fixed bed between the thermal sheets, on the
one hand, and the cavities in the thermal sheets, on the
other hand. The container of the reactor is constructed in
the form of a vertical cylinder, and the thermal sheets are
adapted to the cylinder, that is to say they have varying
sizes. Also in this case the production output, can at best
be increased by axial lengthening and/or by a parallel
connection of several reactors.
By virtue of DE 198 16 2 96 A1 from the same applicant it is
known to generate an aqueous solution of hydrogen peroxide
from water, hydrogen and oxygen in a reactor which may
contain both a fixed-bed packing consisting of particulate
catalysts and planar monolithic carriers which are provided
with channels, take the form of heat-exchangers and are
provided with coatings of catalyst material. By way of
catalysts, elements from the 8th and/or 1st subgroups of
the Periodic Table are specified, such as Ru, Rh, Pd, Tr,
Pt and Au, whereby Pd and Pt are particularly preferred.
Activated carbon, water-insoluble oxides, mixed oxides,
sulfates, phosphates and silicates of alkaline-earth
metals, Al, Si, Sn and of metals pertaining to the 3rd to
6th subgroups are specified by way of carrier materials.
Oxides of silicon, of aluminium, of tin, of titanium, of
zirconium, of niobium and of tantalum as well as barium
sulfate are specified as being preferred. Metallic or
ceramic walls having the function of heat-exchangers

analogous to plate-type heat-exchangers are named as
materials for monolithic carriers. The specified
experimental reactor had an inside diameter of 18 mm with a
length of 4 00 mm. The temperatures were within the range
from 0 to 90 °C, preferably 20 to 70 °C, the pressures were
between atmospheric pressure and about 10 MPa, preferably
between about 0.5 and 5 MPa. Also with respect to this
state of the art, the production output can at best be
increased by axial lengthening and/or by a parallel
connection of several reactors.
A reactor as to DE 195 44 985 C1 as well as DE 197 53 720
A1 comprises a plate-like heat exchanges wherein the fluid
head-carrier is conducted through the slot formed between
two plates. There is no hint on the function of width slot-
shaped reaction spaces.
A device as to DE 197 41 645 Al comprises a microreactor
with reactions and cooling channels wherein the depth a of
the reaction channels is thickness b between reaction and cooling channels is µm. This document gives no indication to use reaction
spaces other than said channels. A microreactor comprising
many parallel grooves as reaction spaces is thought by DE
197 48 481. The manufacture of a reactor for large scale
throughput is expensive.
Furthermore, so-called microreactors are known in which the
dimensions of the flow channels are in the region of a few
hundred micrometres (as a rule, high transport values (heat-transfer and mass-transfer
parameters). The fine channels act as flame barriers, so
that no explosions are able to spread. In the case of
toxic reactants, a small storage volume (hold-up volume)
leads, in addition, to inherently safe reactors. But a
filling of the channels with catalysts is impossible by
reason of the small dimensions. A further crucial
disadvantage is the elaborate production process. In order

to avoid clogging of the fine channels, over and above this
an appropriate protection of the filter has to be provided
for upstream of the reactor. High production outputs can
only be obtained by means of parallel connections of many
such reactors. Furthermore, the reactors can only be
operated at higher pressures when the cooling medium is at
the same pressure level.
GENERAL DESCRIPTION OF THE INVENTION
The object underlying the invention is to specify a process
and a device with which it is possible to carry out,
optionally, exothermic and endothermic processes whereby
several fluid reactants react with react other in the
presence or absence of catalysts and whereby the reaction
region of the reactor is constructed in a modular design,
so that it is possible to adapt the production output to
the requirements.
In accordance with the invention, the object as formulated
is achieved, in the case of the process specified at the
outset, in that
a) the slot-shaped reaction spaces are formed between
lateral surfaces of, in each instance, two substantially
equally large and substantially right-parallelepiped
wall elements made from solid plates and in that the
wall elements are arranged interchangeably in a block
within a virtual right parallelepiped,
b) the reactants are introduced into the slot-shaped
reaction spaces from edge regions situated on the same
side of the block and are conducted through the reaction
spaces as reaction mixture in like directions in
parallel flows, and in that
c) the fluid heat-carrier is conducted through the
cavities extending in the interior of the wail elements.
BRIEF DESCRIPTION OF DRAWINGS

Shown are:
Figure 1 a perspective exploded representation of a group
consisting of two wall elements,
Figure 2 a perspective schematic representation of a
series arrangement of numerous wall elements
according to Figure 1,
Figure 3 a vertical section through a series arrangement;
according to Figure 2 above the bottom of a
pressure-resistant reactor,
Figure 4 the detail from circle A in Figure 3 on an
enlarged scale, supplemented in perspective view,
Figure 5 a partial vertically sectioned side view through
the subject of Figure 3 after rotation about an
angle of 90 degrees,
Figure 6 the subject of Figure 2, schematically
supplemented by a distributing space and a
collecting space for educt(s) and product,
Figure 7 a vertical section through a plate and a
distributing body with flow channels for
reactants and/or heat-carrier,
Figure 8 a partial vertical section through a first
exemplary embodiment of a reactor with a pressure
vessel,
Figure 9 a bottom view of the lid of the pressure vessel
according to Figure 8.
Figure 10 a partial vertical section through a second
exemplary embodiment of a reactor with a pressure
vessel.
DETAILD DESCRIPTION

By virtue of the invention the object as formulated is
achieved in full measure; in particular, it is possible to
carry out, optionally, exothermic and endothermic processes
whereby several fluid reactants (gases and/or liquids)
react with each other in the presence or absence catalysts
and whereby the reaction region of the reactor is
constructed in a modular design, so that it is possible to
adapt the production output to the requirements. By
reducing width of the reaction spaces from e.g. 5 mm to
0,05 mm the ratio of the surface to the volume of the
reaction spaces is increasing. As a result, problems
araising from the limited heat transfer within gases are
decreased, so that highly exothermic or endothermic
reactions can safely be performed.
However, still further advantages arise:
combination of microreaction technology with the
advantages of simple manufacture according to classical
workshop techniques,
easy interchange of indivi dual wall elements (the term
"substantially equally large and substantially right-
parallelepiped" means that minor deviations, caused by
continetive reasons, are tolerable) ,
virtually arbitrary thickness of the wali. elements
without impairment of function,
enlargement of the specific surface area by
profiling/roughening,
direct total or partial coating of the lateral surfaces
with varying catalyst material by impregnating,
spraying, printing or such like with varying thickness,
filling of the reaction spaces with catalyst particles
of varying size,

possibilities of gas/gas reactions, gas/liquid
reactions, liquid/liquid reactions,
impression of flow patterns and flow channels, e.g. for
drainage and for allowing liquid reaction products to
flow off, simple separation,
possibility of altering the slot widths,
mixing of the reactants only in the reaction spaces,
good reaction control,
avoidance of backflows out of the reaction spaces,
good controllability by reason of high heat-transfer
coefficients and large surfaces, i.e. rapid response to
changes in loading and/or in the desired temperature
values and uniform temperature profile and thereby
longer service lives of the catalyst by avoidance of
"hot spots",
inherent safety in the course of causing otherwise
explosive reaction mixtures to react,
small dead volume ("hold-up volume"),
possibility of working under high pressure, slight
losses of pressure in the reaction spaces,
immersibility in liquid solvents and operability with a
sump which can be temperature-controlled (heated/cooled)
from outside and which enables a gentle termination of
the reaction by "quenching" and/or washing,
possible addition of inhibitors in order to prevent
secondary reactions, reducibility of the volume of the
gas/liquid by means of filling materials and/or
displacers in the pressure vessel on the other side of
the product outlet in the sump,

reduction in the number of connections and easier
sealability as regards leakages (important in the case
of toxic components),
low resistances to diffusion, high space-time yields, in
particular higher throughputs than in the case of the
known microreactors, simpler "scale-up" from the
laboratory scale to the production scale by
multiplication ("number-up"),
simple and compact structural design, reduction of
investment costs and operating costs (maintenance,
consumption of energy),
possibility of the construction of small plants.
In this connection it is particularly advantageous, within
the scope of further configurations of the process
according to the invention, if - either individually or in
combination:
at least one reactant is supplied through the wall
elements and is introduced into the reaction space in
question through at least one of the lateral surfaces of
the wall elements,
a distributing medium, from which the reaction spaces
are provided with the reactants, is arranged on at least
one side of the block,
by way of distributing medium, use is made of a solid
body with groups of channels, the cross-sections of
which are chosen to be so small that no spreading of
flames is possible in them in the course of the supply
of reactants that form an explosive mixture,
by way of distributing medium, use is made of a packing
material with a grain size and with interspaces that are

chosen to be so small that no spreading of flames is
possible in them in the course of the supply of
reactants that form an explosive mixture,
the slot width of the reaction spaces is preferably
chosen between 0.05 and 5 mm and more preferred 0,05 to
0,2 mm,
in case of explosive reactions mixtures the slot width
os chosen so small that no spreading of flames is
possible,
the reaction spaces are filled with granular catalyst,
the lateral surfaces of the wall elements facing towards
the reaction spaces are covered at least in places with
catalyst material,
the lateral surfaces of the wall elements facing towards
the reaction spaces are provided with a profiled
structure for the purpose of enlarging the surface area,
the wall elements are immersed at least partially in an
aqueous or organic solvent or solvent mixture,
by way of solvent, use is made of water, optionally with
at least an addition of inhibitors that prevent a
decomposition and/or degradation of the reaction
product, and/or, if
the process is used for the purpose of producing
hydrogen peroxide from water (vapour), hydrogen and air,
optionally enriched with oxygen, or oxygen.
The invention also relates to a device for carrying out
reactions between at least two fluid reactants using a
reactor in which there are located wall elements, slot-
shaped reaction spaces and cavities for the purpose of
conducting a fluid heat-carrier through.

With a view to achieving the same object, such a device Ls
characterised, according to the invention, in that
a) the slot-shaped reaction spaces are arranged between
lateral surfaces of, in each instance, two substantially
equally large and substantially right-parallelepipedal wall
elements made from solid plates and in that the wall
elements are arranged interchangeably in a block within a
virtual right parallelepiped,
b) the supply of the reactants into the slot-shaped
reaction spaces is capable of being carried out from the
same side of the block, the reaction mixture being capable
of being guided through the reaction spaces in like
directions and in parallel flows and in that
c) the wall elements each tubular cavities for conducting
the fluid heat-carrier through the wall element.
The process and the device are suitable, in exemplary
manner, for the following processes:
selective hydrogenations and oxidations,
production of propenal by catalytic oxidation of propene
with an O2-containing gas having elevated oxygen
concentration in comparison with air, accompanied by an
increase in selectivity, for example in the presence of
a Mo-containing catalyst at a temperature within the
range from 350 to 500 °C and at a pressure wi thin the
range from 0.1 to 5 MPa,
production of acrylic acid by catalytic oxidation of
propene, for example in the presence of a Mo-containing
catalyst and a promoter at 250 to 350 °C and at 0.1 to
0.5 MPa ,
production of ethylene oxide or propylene oxide from
ethylene or propylene, respectively, and gaseous
hydrogen peroxide in the presence of an oxidic or
siliceous catalyst, such as titanium silicalite, at a

temperature within the range from 60 to 200 °C and at. a
pressure within the range from 0.1 to 0.5 MPa,
direct synthesis of hydrogen peroxide from H2 and O2 or
an O2-containing gas in the presence of a noble-metal
catalyst and water or water vapour - for example
according to the process disclosed in DE-A 198 16 296
and according to those processes disclosed in further
documents cited therein. By way of catalysts in this
connection, use may be made of elements from the 8th
and/or 1st subgroups of the Periodic Table, such as Ru,
Rh, Pd, Ir, Pt and Au, whereby Pd and PL are
particularly preferred. The catalysts may be employed
per se, e.g. as suspension catalysts, or in the form of
supported catalysts by way of packing in the slot-shaped
reaction spaces, or they are fixed to the wall elements,
directly or through the agency of layer-forming
supporting materials. By way of supporting materials,
use may be made of activated carbon, water-insoluble
oxides, mixed oxides, sulfates, phosphates and silicates
of alkaline-earth metals, Al, Si, Sn and of metals
pertaining to the 3rd to 6th subgroups. Oxides of
silicon, of aluminium, of tin, of titanium, of
zirconium, of niobium and of tantalum as well as barium
sulfate are preferred. In the case of the direct
synthesis of hydrogen peroxide, the reaction
temperatures lie, in exemplary manner, within the range
from 0 to 90 °C, preferably 20 to 70 °C, the pressures
lie between atmospheric pressure and about 10 MPa,
preferably between about 0.5 and 5 MPa.
In this connection it is particularly advantageous, within
the scope of further configurations of the device according
to the invention, if - either individually or in
combination:
in the wall elements there is arranged, in each
instance, at least one feed channel which leads into the

reaction space in question through at least one of the
lateral surfaces of the wall elements,
on at least one side of the block there is arranged a
distributing medium through which the reaction spaces
are capable of being provided with the reactants,
the distributing medium is a solid body with groups of
channels, the cross-sections of which are chosen to be
so small that no spreading of flames is possible in them
in the course of the supply of reactants that form an
explosive mixture,
the distributing medium is a packing material with a
grain size and with interspaces that are chosen to be so
small that no spreading of flames is possible in them in
the course of the supply of reactants that form an
explosive mixture,
the slot width of the reaction spaces preferably amounts
to between 0.05 and 5 mm and especially preferred to
0,05 to 0,2 mm,
the reaction spaces are filled with granular catalyst,
the lateral surfaces of the wall elements facing towards
the reaction spaces are covered at least in places with
catalyst material,
the lateral surfaces of the wall elements facing towards
the reaction spaces are provided with a profiled
structure for the purpose of enlarging the surface area,
the wall elements are partially or completely arranged
in a vessel,
the reaction spaces on the narrow sides of the wall
elements extending parallel to the direction of flow of
the reactants are closed by plates in which there are
located openings for the feeding and drainage of a heat-

carrier into the wall elements and out of the wall
elements,
in the plates there are located further openings for the
feeding of at least one of the reactants into the wall
elements and the wall elements are each provided with at
least one feed channel which via discharge openings
leads, in each instance, into one of the reaction
spaces,
the wall elements are each provided with a group of
tubular cavities which extend parallel to the lateral
surfaces of the wall elements and are closed at their
ends by the plates which are mounted onto the narrow
sides of the wall elements and in which openings for the
heat-carrier that are in alignment with the cavities are
located,
the plates are provided on their outsides and ahead of
the openings with flow channels extending at right
angles to the wall elements for at least one of the
reactants and/or a heat-carrier ,
the plates are covered on their outsides facing away
from the wall elements by a distributing body in which
there are located flow channels into which the openings
in the plates lead,
the wall elements are formed by two subelements having
semicylindrical or otherwise shaped recesses whereby
tubular cavities are formed by two respective
subelements pressing together ,
the wall elements are accommodated as a block in a
pressure vessel,
the pressure vessel is capable of being filled at least
partially with a solvent,

the pressure vessel possesses a lid with a partition and
two connecting sockets for the feeding of two reactants
and the partition is capable of being mounted onto the
distributing medium,
the slot width of the reaction spaces is capable of
being changed by varying the thickness of spacers.
Exemplary embodiments of the subject-matter of the
invention will be elucidated Ln greater detail below on the
basis of Figures 1 to 10.
In Figure 1 there are shown - in exploded representation -
two wall elements 1 with lateral surfaces 2 which include
between themselves a reaction space 3 through which the
reactants flow in the direction of the arrow 4. In each of
the wall elements there are arranged cavities 5 in the form
of through bores which extend parallel to the lateral
surfaces 2 and terminate in the narrow sides 6 of the wall
elements 1. Alternative solutions are specified further
below.
The wall elements 1 take the form of flat right
parallelepipeds, the largest surfaces of which are the
lateral surfaces 2. These lateral surfaces 2 may - as
shown - be provided with a profiled structure, that is to
say they may be roughened, for example, in order to enlarge
the effective surface area. The lateral surfaces 2 may
furthermore be wholly or partially provided with surface
deposits consisting of a catalyst material, but this is not
represented separately here. Further particulars are
evident from Figure 4. It is also possible, alternatively
or in addition, to arrange particulate catalysts in the
reaction space 3, the size of which is adapted to the slot
width "s" (Figure 4).
Figure 2 shows the combination of thirteen such equally
large wall elements 1 so as to form a right-

parallelepipedal block 24; however, this number is
variable, wherein one of the essential purposes of the
invention lies, namely the possibility of adaptation to
varying production outputs and processes. The mass
transport in unidirectional parallel flows - here from
above in a downward direction - is only hinted at by means
of arrows.
Figure 3 shows a vertical section through a series
arrangement according to Figure 2 above the bottom 7 of a
pressure-resistant reactor, the lower flanged joint 8 of
which is shown here. The supply of liquid solvents is
effected via the pipe 9, the removal of residual gases is
effected via the pipe 10, the removal of the end product is
effected via the pipe 11, and the removal of sump material
is effected via the pipe 12, optionally with a view to
cleaning.
Figure 4 shows the detail from circle A in Figure 3 on an
enlarged scale and supplemented in perspective view, i.e.
the circumstances on both sides of a reaction space 3. The
slot width "s" of the reaction space 3 is maintained at a
predetermined measurement by spacers 13 and is chosen, in
exemplary manner, between 0.05 and 5 mm. However, this
range may also be fallen below or exceeded. In case of
highly exothermic and endothermic reactions, esspecially
comprising an explosive gas mixture, the slot width is
reduced until any flame spreading is avoided. The optimal
lot width depends on the medium and reaction type and i s
determined by experiments. As can be seen from Figures 4
and 6 the slot width "s" of the inventive device is
significantly smaller than the thickness of the wall
elements. In the tubular wall elements there are located
the cavities 5, which have already been described, for
conducting a fluid heat-carrier through. Depending on the
temperature control thereof, heat can be dissipated in the
case of an exothermic process or heat can be supplied in

the case of an endothermic process. By way of heat-
carrier, use may be made of water, oils, gases and
optionally also the product itself.
In the wall elements 1 there are located furthermore
semicylindrical recesses 14 which complement one another so
as to form a substantially cylindrical feed channel 15 for
a first reactant. Located furthermore in the wall elements
are further feed channels 16 for at least one further
reactant. The feed channels 16 are connected to the
respective reaction space 3 by means of discharge openings
17, whereby the discharge openings 17 lead into the Lateral
surfaces 2 of the wall elements so that the reactants are
able to mix in the reaction spaces 3. The cavities 5, the
feed channels 15 and 16 and also the row(s) of discharge
openings 17 are parallel to one another and to the lateral
surfaces 2 of the wall elements 1 and extend over the
entire length thereof - viewed in the horizontal direction.
The cooling channels (= tubular cavities (5)) may, Ln a
manner analogous to the formation of the feed channels (15)
according to Figure 4, also be configured, in such a way
that each wall element (1) is split parallel to the lateral
surfaces (2) into two subelements and semicylindrical or
otherwise shaped recesses are arranged in the slot
surfaces. As a result of pressing the respective two
corresponding subelements together, cavities (5) are
formed, through which a fluid heat-carrier is able to flow.
The term "tubular" comprises round or square-formed
channels or pipes.
The slot width "s" is so chosen that no flames are able to
spread in the reaction spaces 3 in the case of explosive
reaction mixtures. In special cases, the local formation
of explosions in the reaction spaces may also be permitted,
in which case care has only to be taken structurally to
ensure that these explosions do not flash over to adjacent
reaction spaces.

Important in this connection is the fact that the feed
channels 15 and 16 extend in the (upper) edge region of the
wall elements 1 or of the reaction spaces 3, so that
virtually the entire (vertical) length of the reaction
spaces 3 is available for the reaction. Further
particulars of and alternatives to the supply and removal
of reactants and heat-carrier will be elucidated in still
more detail on the basis of the following Figures.
Figure 5 shows a partially sectioned side view through the
subject of Figure 3 after rotation about a vertical axis by
an angle of 90 degrees. Two reactants are supplied to the
system through the feed pipes 18 and 19: in the case of the
production of hydrogen peroxide, air via feed pipe 18 and
hydrogen via feed pipe 19. The transport of the fluid
heat-carrier through the cavities 5 will also be elucidated
in greater detail on the basis of Figure 5: the narrow
sides 6 of the wall elements 1 are closed by mounted plates
20 in which there are arranged U-shaped channels 21 for the
connection of, in each instance, two cavities 5. However,
this is only represented on the left-hand, side of the
block. The heat-carrier is supplied through a feed pipe 22
and is removed through a drain 23.
For the wall elements, use may be made of sufficiently heat
conductive, preferable metallic, substantially right-
parallelepipedal plates. The wall elements 1, which are
preferably made out of metal (e.g. stainless steel), may
consist of solid plates with appropriate bores (cavities 5
and feed channels 16) and recesses 14. Alternatively, the
cavities 5 may be combined, optionally also in groups, in
which case conducting devices, e.g. ribs, for guidance of
the heat-carriers are arranged within the cavities which
are then larger. The wall elements 1 may also be composed
of two plate-like subelements which are connected to one
another in sealed manner, for example screwed together.
The only important point is that they withstand the, in

some cases, considerable pressure differences (up to 10 MPa
or 100 bar) between the heat-carrier and the reactants.
Figure 6 shows the subject of Figure 2, schematically and
complemented in thick lines by an (upper) distributing
space 48 with a central feed pipe 49 for educt(s) and a
(lower) collecting space 50 with a drain 51 for the
product. One of the reactants or a mixture of the
reactants R1 and R2 can be supplied via the distributing
space 48. In the case of a mixture, the feed pipes 15 and
16 (in Figure 4) can be dispensed with if the spacers 13
are interrupted. In the case of explosive reaction
mixtures, in addition to the procedure according to the
arrangement in Figure 2 a procedure according to the
arrangements in Figures 8 to 10 can also be adopted.
The open narrow sides 6 of the wall elements 1 can be
covered by a plate combination, consisting of a plate 41
and a distributing body 47, which is designed to be
uninterrupted over the width and height of all the wail
elements 1 and which is represented - on a greatly enLarged
scale - in Figure 7. Figure 7 shows a vertical section
through the upper edge region of such a plate combination
41/47 with a flow channel 45 for one of the reactants and
with flow channels 4 6 for the heat-carrier. For the intake
and/or discharge thereof, openings 42 and 43 which are
connected to the flow channels 45 and 4 6 in the
distributing body 47 are arranged in the plate 41.
The flow channels 45 and 46, which extend perpendicular to
the plane of the drawing, are formed, for example, by
grooves in the distributing body 47. The grooves may be
produced by metal-cutting, by casting or forging. This
results in great stability of form which withstands the
pressure differences that are demanded. This plate
combination 41/47 - with its openings 42 and 43 in
alignment with the associated channels in the wall elements
1 - is now screwed in sealing manner by means of a gasket

54 onto all the narrow sides 6 of the wall elements 1 of
the block 24. Only a few of the numerous screw joints 52
are represented. By this means, a provision of the wall
elements 1 is effected corresponding to the arrows 53 in
Figure 6. By means of dashed lines 55 it is indicated that
several flow channels 4 6 may also be combined to form a
common flow channel or distributing space.
The plate combination 41/47 may also be redesigned to the
effect that it is suitable for a provision of wall elements
1 according to Figure 4.
Now Figure 8 shows, on the basis of a partial vertical
section, a schematic representation of a complete reactor,
e.g. for the production of hydrogen peroxide. A right-
parallelepipedal block 24 consisting of several wail
elements 1 according to Figures 1 and 2 is suspended from
above in a pressure vessel 2 5 which is filled with a
solvent 27, for example water, to a level 26. The slot-
shaped reaction spaces 3 extend parallel to the plane of
the drawing.
At the top the pressure vessel. 25 possesses a Lid 2.8 which
is subdivided by a partition 29 into two chambers 30 and
31, the partition 29 being mounted in sealing manner onto a
distributing medium 37 which consists of a solid body
(preferably made of metal) with two separate groups of
narrow channels 39 and 40. The channels 39 extend in the
solid body from the chamber 30 to the upper ends of the
reaction spaces 3, the channels 40 extend from the chamber
31 to the upper ends of the reaction spaces 3. In those
channels 39 and 40 the reactants are accordingly unable to
mix, but, even if this were to happen, no flames are able
to spread in the channels 39 and 40. Mixing of the
reactants takes place only in the reaction spaces 3, in
which likewise no flames are able to spread if it is a
guestion of a reaction mixture that is explosive as such.
The explosive properties of the reaction mixture are

material-dependent and reaction-dependent and have to be
determined in the given case.
Through a connecting socket 34 a first reactant "R1" is
supplied to chamber 30, and through a further connecting
socket 35 a second reactant "R2" is supplied to chamber 31.
The waste gases that are not needed are conducted away
according to arrow 32, the product is withdrawn according
to arrow 33, and the sump can be emptied through the pipe
12. Figure 8 shows, in addition, another connecting socket
36 for a third reactant "R3" and/or a solvent such as
water. The plates 41 which are applied at both ends are
only indicated very schematically.
Figure 9 shows a bottom view of the lid 2 8 of the pressure
vessel 25 according to Figure 8. Bores 28a serve for screw
coupling.
Figure 10 differs from Figure 8 in that, by way of
distributing medium 38, there is arranged above the block
24 of wall elements 1 a packing material which consists of
heat-conducting particles, for example sand, grit, metal
shavings, metallic fibres or such like, which rest on a
sieve plate which is not shown. In this distributing
medium 38 the reactants R1 and R2 already mix in accordance
with random distribution before they enter the reaction
spaces 3. However, the distributing medium forms such
narrow interspaces that, likewise, no spreading of flames
with explosive consequences is able to occur in them.
The spatial location of the wall elements 1 is practically
arbitrary: in accordance with the Figures, they may be
arranged in a horizontal series arrangement, but they may
also be arranged in a vertical, stack. The direction of the
parallel flows can also be adapted to practical needs: as
shown, the parallel flows can be guided vertically from the
top downwards, but they may also be guided the other way
round, from the bottom upwards. The parallel flows may

also run horizontally. As a result, the block 2 4 with the
plates 41 and the connections can be "rotated" into various
spatial locations.

List of Reference Symbols:
1 wall elements
2 lateral surfaces
3 reaction spaces
4 arrow
5 cavities
6 narrow sides
7 bottom
8 flanged joint
9 pipe
10 pipe
11 pipe
12 pipe
13 spacer
14 recesses
15 feed channel
16 feed channels
17 discharge openings
18 feed pipe
19 feed pipe
20 plates
21 channels
22 feed pipe
23 drain
24 block
25 pressure vessel
26 level
27 solvent
28 lid
28a bores
29 partition
30 chamber
31 chamber
32 arrow
33 arrow
34 connecting socket
35 connecting socket
36 connecting socket
37 distributing medium
38 distributing medium
39 channels
40 channels
41 plates
42 openings
43 openings
44 outside
45 flow channels
46 flow channels

47 distributing body
48 distributing space
49 feed pipe
50 collecting space
51 drain
52 screwed joint
53 arrows
54 gasket
55 lines
R1 reactant
R2 reactant
R3 reactant
s slot width
A detail (from Figure 3)

WE CLAIM:
1. A process for carrying out reactions between at least two fluid
reactants (R1, R2) using a reactor in which there are located wall
elements (1), slot-shaped reaction spaces (3) and cavities (5) for
conducting a fluid heat-carrier through,
characterized in that
(a) the reaction spaces (3) are slot-shaped and formed between
lateral surfaces (2) of, in each instance, two substantially equally
large and substantially right parallelepipedal wall elements (1)
made of solid plates and in that the wall elements (1) are arranged
interchangeably in a block (24) within a virtual right parallelepiped,
b) the reactants (R1,R2) are introduced into the slot-shaped reaction
spaces (3) from edge regions situated on the same side of the block
(24) and are conducted through the reaction spaces (3) as reaction
mixture in like directions in parallel flows and in that
c) the fluid heat-carrier-is conducted though the tubular cavities (5)
extending in the interior of the wall elements (1).
and wherein the slot width ("s") of the reaction spaces (3) amounts to
between 0.05 and 5 mm, whereby in case of explosive reaction
mixtures the slot width "s" of the reaction spaces is chosen so small in
order to avoid spreading of flames.

2. Process as claimed in Claim 1,
wherein
at least one reactant is supplied through the wall elements (1) and is
introduced into the reaction space (3) in question through at least one
of the lateral surfaces (2) of the wall elements (1).
3. Process as claimed in Claim 1,
wherein
on at least one side of the block (24) there is arranged a distributing
medium (37,38) from which the reaction spaces (3) are provided with
the reactants (R1, R2).
4. Process as claimed in Claim 3,
wherein
by way of distributing medium (37) use is made of a solid body with
groups of channels (39,40), the cross-sections of which are chosen to
be so small that no spreading of flames is possible in them in the
course of the supply of reactants (R1,R2) that form an explosive
mixture.

5. Process as claimed in Claim 3,
wherein
by way of distributing medium (38) use is made of a packing material
with a grain size and with interspaces that are chosen to be so small
that no spreading of flames is possible in them in the course of the
supply of reactants (R1,R2) that form an explosive mixture.
6. Process as claimed in Claim 1,
wherein
the slot width of the reaction spaces (3) is chosen between 0.05 and 5
mm, whereby in case of explosive reaction mixtures the slot width "s"
of the reaction spaces is chosen so small in order to avoid spreading of
flames.
7. Process as claimed in Claim 1,
wherein
the reaction spaces (3) are filled with granular catalyst.
8. Process as claimed in Claim 1,
wherein

the lateral surfaces (2) of the wall elements (1) facing towards the
reaction spaces (3) are covered at least in places with catalyst
material.
9. Process as claimed in Claim 1,
wherein
the lateral surfaces (2) of the wall elements (1) facing towards the
reaction spaces (3) are provided with a profiled structure for the
purpose of enlarging the surface area.
10. Process as claimed in Claim 1, wherein the wall elements (1) are
immersed at least partially in a solvent (27).
11. Process as claimed in Claim 10,
wherein
use is made of water by way of solvent (27).
12. Process as claimed in Claim 10,
wherein
at least one stabilizing additive for countering decomposition or
degradation of the reaction product is added to the solvent (27).

13. Process as claimed in at least one of Claims 1 to 12,
characterized by use for the direct synthesis of hydrogen peroxide from
hydrogen and oxygen or an 02-containing gas in the presence of a
catalyst containing at least one element from the 8th and/or 1st
subgroups of the Periodic Table and water or water vapour.
14. Process as claimed in at least one of Claims 1 to 12, characterised by
use for the production of propenal from propene and an 02-containing
gas in the presence of a catalyst.
15. Process as claimed in at least one of Claims 1 to 12, characterized by
use for the production of acrylic acid from propene and an 02-
containing gas in the presence of a catalyst and a promoter.
16. Process as claimed in at least one of Claims 1 to 12, characterized by
use for the production of ethylene oxide or propylene oxide from
ethylene or propylene, respectively, and gaseous hydrogen peroxide in
the presence of an oxidic or siliceous catalyst.

17. A device for carrying out reactions between at least two fluid reactants
(R1,R2) using a reactor in which there are located wall elements (1),
reaction spaces (3), and cavities (5) for conducting a fluid heat-carrier
through,
wherein
(a) the reaction spaces (3) are slot-shaped and arranged between
lateral surfaces (2) of, in each instance, two substantially equally large
and substantially right-parallelepipedal wall elements (1) made of solid
platesand in that the wall elements (1) are arranged interchangeably in
a block (24) within a virtual right parallelepiped,
(b) the supply of the reactants into the slot-shaped reaction spaces (3)
is capable of being carried out from the same side of the block (24),
the reaction mixture being capable of being guided through the
reaction spaces (3) in like directions and in parallel flows, and in that
(c) the wall elements (1) possess tubular cavities (5) for conducting
the fluid heat-carrier through the wall element(1).
and wherein the slot width ("s") of the reaction spaces (3) amounts to
between 0.05 and 5 mm, whereby in case of explosive reaction
mixtures the slot width "s" of the reaction spaces is chosen so small in
order to avoid spreading of flames.

18. Device as claimed in Claim 17,
wherein
in the wall elements (1) there is arranged, in each instance, at least
one feed channel (16) for at least one reactant, which leads into the
reaction space (3) in question through at least one of the lateral
surfaces (2 ) of the wall elements(1)
19. Device as claimed in Claim 17,
wherein
on at least one side of the block (24) there is arranged a distributing
medium (37, 38) through which the reaction spaces ( 3 ) are capable of
being provided with the reactants (R1, R2).
20. Device as claimed in Claim 19,
wherein
the distributing medium (37) is a solid body with groups of channels
(39,40), the cross-sections of which are chosen to be so small that no
spreading of flames is possible in them in the course of the supply of
reactants (R1, R2) that form an explosive mixture.
21. Device as claimed in Claim 19,
wherein

the distributing medium (38) is a packing material with a grain size and
with interspaces that are chosen to be so small that no spreading of
flames is possible in them in the course of the supply of reactants
(R1,R2) reactants (R1, R2) that form an explosive mixture.
22. Device as claimed in Claim 17, wherein
the slot width ("s") of the reaction spaces (3) amounts to between 0.05
and 5 mm, whereby in case of explosive reaction mixtures the slot
width "s" of the reaction spaces is chosen so small in order to avoid
spreading of flames.
23. Device as claimed in Claim 17,
wherein
the reaction spaces (3) are filled with granular catalyst.
24. Device as claimed in Claim 17,
wherein
the lateral surfaces (2) of the wall elements (1) facing towards the
reaction spaces (3) are covered at least in places with catalyst
material.

25. Device as claimed in Claim 17,
wherein
the lateral surfaces (2) of the wall elements (1) facing towards the
reaction spaces (3) are provided with a profiled structure for the
purpose of enlarging the surface area.
26. Device as claimed in Claim 17,
wherein
the reaction spaces (3) are covered on the narrow sides (6) of the wall
elements (1) extending parallel to the direction of flow of the reactants
(R1, R2) by plates (41) in which there are located openings (43) for the
feeding and drainage of a heat-carrier into the wall elements (1) and
out of the wall elements (1).
27. Device as claimed in Claim 26,
wherein
in the pates (41) there are located further openings (42) for feeding at
least one of the reactants (R1,R2) into the wall elements (1) and in that
the wall elements(1) are each provided with at least one feed channel
(16) which leads via discharge openings (17) into, in each instance,
one of the reaction spaces (3).

28. Device as claimed in Claim 26,
wherein
the wall elements (1) are each provided with a group of cavities (5)
which extend parallel to the lateral surfaces (2) of the wall elements (1)
and are closed at their ends by the plates (41) which are mounted onto
the narrow sides (6) of the wall elements (1) and in which the openings
(43) for the heat-carrier which are in alignment with the cavities (5)
are located.
29. Device as claimed in Claims 26 and 27,
wherein
the plates (41) are provided on their outsides (44) and ahead of the
openings (42,43) with flow channels (45, 46) extending at right angles
to the wall elements (1) for at least one of the reactants (R1, R2) and/or
the heat-carrier.
30. Device as claimed in Claim 29,
wherein
the plates (41) are covered on their outsides (44) facing away from the
wall elements (1) by a distributing body (47) in which the flow channels
(45, 46) are located into which the openings (42,43) in the plates (41)
lead.

31. Device as claimed in Claim 17,
wherein
the wall elements (1) are accommodated as a block (24) in a pressure
vessel (25).
32. Device as claimed in Claims 19 and 31,
wherein
the pressure vessel (25) possesses a lid (28) with a partition (29) and
two connecting sockets (34,35) for the feeding of two reactants
(R1, R2), said partition (29) being capable of being mounted onto the
distributing medium (37,38).
33. Device as claimed in Claim 17,
wherein
the slot width ("s") of the reaction spaces (3) is capable of being
changed by varying the thickness of spacers (13).

A process for carrying out reactions between at least two
fluid reactants (R1,R2) using a reactor in which there are
located wall elements (1), slot-shaped reaction spaces (3) and
cavities (9) for conducting a fluid heat—carrier through,
characterized in that a) the slot-shaped reaction spaces (3) are
formed between lateral surfaces (2) of, in each instance, two
substantially equally large and substantially right-
parallelepipedal wall elements (1) made of solid plates and in
that the wall elements (1) are arranged interchangeably in a
block (24) within a virtual right parallelepiped, b) the
reactants (R1,R2) are introduced into the slot-shaped reaction
spaces (3) from edge regions situated on the same side of the
block (24) and are conducted through the reaction spaces (3) as
reaction mixture in like directions in parallel flows and in that
c) the fluid heat-carrier is conducted through the tubular
cavities (9) extending in the interior of the wall elements (1).

Documents:

157-KOLNP-2003-CORRESPONDENCE 1.1.pdf

157-KOLNP-2003-CORRESPONDENCE.pdf

157-KOLNP-2003-FORM 15.pdf

157-KOLNP-2003-FORM 27.pdf

157-kolnp-2003-granted-abstract.pdf

157-kolnp-2003-granted-claims.pdf

157-kolnp-2003-granted-correspondence.pdf

157-kolnp-2003-granted-description (complete).pdf

157-kolnp-2003-granted-drawings.pdf

157-kolnp-2003-granted-examination report.pdf

157-kolnp-2003-granted-form 1.pdf

157-kolnp-2003-granted-form 18.pdf

157-kolnp-2003-granted-form 2.pdf

157-kolnp-2003-granted-form 3.pdf

157-kolnp-2003-granted-form 5.pdf

157-kolnp-2003-granted-gpa.pdf

157-kolnp-2003-granted-priority document.pdf

157-kolnp-2003-granted-reply to examination report.pdf

157-kolnp-2003-granted-specification.pdf

157-kolnp-2003-granted-translated copy of priority document.pdf

157-KOLNP-2003-PA.pdf

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Patent Number

227812

Indian Patent Application Number

157/KOLNP/2003

PG Journal Number

04/2009

Publication Date

23-Jan-2009

Grant Date

20-Jan-2009

Date of Filing

10-Feb-2003

Name of Patentee

DEGUSSA AG

Applicant Address

BENNLGSERPLATZ 1, 40474 DUSSELDORF, GERMANY & UHDE GMBH, FRIEDRICH-UHDE-STRASSE 15, D-44141 DORTMUND

Inventors:

#	Inventor's Name	Inventor's Address
1	DR. RUDIGER SCHUTTE	IM GOLDEMEN RING 11, D-63755 ALZENAU
2	DR. TORTEN BALDUF	OPPAUER STRASSE 10, D-45772 MARL
3	DR. CATRIN BECKER	EMMERICH-JOSEF-STRASSE 18, D-65929 FRANKFURT
4	DR. INA HEMME	FRIEDRICHSTRASSE 50, D-63450 HANAU
5	DR. BIRGIT BERTSCH-FRANK	ZUR WALDESRUH 156, D-42329 WUPPERTAL
6	DR. WERNER WILDNER	STELNHELMER STRASSE 91, D-63500 SELIGENSTADT
7	JURGEN ROLLMANN	DORFMAUERWEG 14, D-63762 PFAUMHEIM
8	DR. GEORG MARKOWZ	ALTE STRASSE 11, D-63791 KARLSTEIN

PCT International Classification Number

B01J 19/24

PCT International Application Number

PCT/EP2001/08937

PCT International Filing date

2001-08-02

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	10042746.4	2000-08-31	Germany