Title of Invention	"METHOD AND APPARATUS OF BLOWING METAL-OXIDE-CONTAINING FINE PARTICLES INTO A REDUCTION GAS STREAM"
Abstract	The present invention relates to a novel method for synthesizing imidazole derivatives having 4-aryl, 5-pyrimidine heterocyclic rings using a novel cycloaddition reaction.

Full Text

The present invention relates to a method and apparatus of blowing metal-oxide-containing fine particles into a reduction gas stream carried in a reduction gas line. The process of introducing fine ore particles into a reducing gas duct and of reducing the ore particles during transport in the reducing gas duct is known (JP-A-6324125). According to JP-A-62-164569, the fine ore is sucked into the reducing gas cannot come into optimum contact with the individual metal-oxide-containing fine particles. The fine particles entering the reducing gas stream form a compact material stream even if they are injected into the reducing gas stream by means of a carrier gas. Only after a certain distance has been covered is the material stream fanned so that only a smaller distance, and, thus, only less time is available for reduction. Another disadvantage is that the material stream, due to its compactness resulting from its entering the space accommodating the reducing gas, may cause wearing of the wall delimiting said space by abrasion. The object of the invention is to avoid these disadvantages and difficulties and to solve the technical problem of creating a process of the type described above as well as an arrangement for carrying out the process allowing to ensure an optimum contact of the individual fine particles with the reducing gas immediately after the metal-oxide-containing fine particles have entered a space accommodating the reducing gas so that each fine particle is enclosed by reducing gas, immediately after exiting the duct feeding the fine particles. This is to enable the chemical, physical and thermal reactions, which all take place starting from the surfaces of the fine particles, to proceed immediately after introduction of the fine particles into the space accommodating the reducing gas so that the time during which the fine particles are staying in this space can be optimally used. This is also to allow a minimization of the arrangement for direct reduction and an optimum utilization of the reducing gas. According to the invention, the problem is solved by feeding a central material stream formed by the fine particles and a carrier gas into the reducing gas and by directing at least one gas stream formed by a secondary gas against the material stream, the gas stream atomizing the material stream and the fine particles being evenly distributed within the reducing gas. Thereby, optimum contact between the reducing gas and fine ore particles being provided, reduction processes can start immediately after entering the reducing gas stream and can take place longer and more thoroughly. Furthermore, due to the reduced compactness of the material stream, abrasion of the wall is limited. Accordingly, there is provided a method of blowing metal-oxide-containing fine particles into a reduction gas stream carried in a reduction gas line characterized in that it comprises the steps of introducing, a central material jet, formed by the fine particles and a carrier gas into the reaction gas stream directing at least one gas jet, formed by a secondary gas, in the reaction gas stream being directed against the material jet; said gas jet atomizing the material jet and uniform distribution of the fine particles in the reaction gas stream, thereby the gas jet imparting a torsional moment to the material jet about the axis of the material jet and the fine particles leaving the material jet due to centrifugal forces resulting in breaking of the said material jet. Accordingly, there is also provided an apparatus for carrying out the method characterized in that it comprises the combination of the following features: • a space (3) for receiving reduction gas, bounded 5 by a wall (2, 23), the space (3) for the reduction gas being formed by a tube (23) ducting the reaction gas, • an injection (1), opening laterally into the space (3) through the wall (2, 23), • which has a central tube (4) conducting fine particles and a carrier gas and • is provided at the mouth (5) of the central pipe (4) with at least one nozzle (6) , which is connected to a gas duct (7) for the feeding in of a secondary gas, • the longitudinal axis (6') of the nozzle (6) forming in normal projection an angle (a) with the longitudinal centre line (9) of the central pipe (4), • and the longitudinal axis (6') of the nozzle (6) being directed at a skewed angle with respect to the longitudinal centre line (9) of the central pipe (4) , the material jet of the central pipe (4) being capable of being subjected by the nozzle (6) at least partly to a torsional moment about the axis of the material jet. The gas stream preferably imparts to the material stream a moment of rotation about the axis of the material stream, the fine particles exit from the material stream by the centrifugal forces and the latter is dispersed. The effect of utilizing the centrifugal forces can be even intensified by the gas stream imparting to the material stream periodically fluctuating moments of rotation, preferably of different dimensions, which also allows to find the optimum moment rotation. The gas stream is expediently directed against the material stream askew and in such a manner as to intersect he material stream and only penetrates the outer zones of the material stream, angle a between the gas stream and the material stream being periodically variable. The gas stream is advantageously formed by inert gas, but also a reducing gas can be used therefore. According to a preferred embodiment, the reducing gas flows past the material stream, i.e. the material stream is injected into a reducing gas stream, the material stream being expediently oriented in a direction opposite to the direction of flow of the reducing gas, preferably at an angle ranging between 100° and 160°. Preferably, at least one gas stream is directed against the center of the material stream and penetrates the latter. • and the longitudinal axis of the nozzle being directed at a skewed angle with respect to the longitudinal centre axis of the central tube, the material jet of the central tube being capable of being subjected by the nozzle at least partly to a torsional moment about the axis of the material jet. The gas stream preferably imparts to the material stream a moment of rotation about the axis of the material stream, the fine particles exit from the material stream by the centrifugal forces and the latter is dispersed. The effect of utilizing the centrifugal forces can be even intensified by the gas stream imparting to the material stream periodically fluctuating moments of rotation, preferably of different dimensions, which also allows to find the optimum moment rotation. The gas stream is expediently directed against the material stream askew and in such a manner as to intersect he material stream and only penetrates the outer zones of the material stream, angle a between the gas stream and the material stream being periodically variable. The gas stream is advantageously formed by inert gas, but also a reducing gas can be used therefore. According to a preferred embodiment, the reducing gas flows past the material stream, i.e. the material stream is injected into a reducing gas stream, the material stream being expediently oriented in a direction opposite to the direction of flow of the reducing gas, preferably at an angle ranging between 100° and 160°. Preferably, at least one gas stream is directed against the center of the material stream and penetrates the latter. The process according to the invention can be particularly advantageously used for a reduction process characterized in that the material stream is fed into a reducing gas stream that departs from a meltdown gasifying zone in which a reducing gas containing CO and H2 is formed by coal gasification and in which partially and/or completely reduced metal-containing particles are completely reduced or melted, respectively, and said reducing gas stream, after the material stream has entered, is subjected to solids separation and subsequently reacted in a reduction zone under reduction of a metal-oxide-containing ore, the fine particles separated during solids separation being supplied to the meltdown gasifying zone via a dust burner effecting an agglomeration of the fine particles. An arrangement for carrying out the process according to the invention is characterized by the combination of the following characteristic features: • a space delimited by a wall for receiving a reducing gas, • an injection nozzle entering the space through the wall, • which is provided with a central pipe conducting fine particles and a carrier gas and • at the mouth of the central pipe, is provided with at least one nozzle connected to a gas duct for feeding a secondary gas, wherein • the longitudinal axis of the nozzle encloses an angle a with the longitudinal center line of the central pipe, which ranges preferably between 20° and 60°. According to a preferred embodiment, the longitudinal axis of the nozzle is oriented askew relative to the longitudinal center line of the central pipe, wherein, if the longitudinal axis of the nozzle is projected perpendicularly onto a plane laid through the longitudinal center line of the central pipe and the nozzle mouth, an angle a ranging between 20° and 60° is formed between the projected longitudinal axis of the nozzle and the longitudinal center line of the central pipe. In this arrangement, the nozzle is expediently movably arranged at the mouth of the central pipe and, with its longitudinal axis, is capable of assuming different positions, preferably different askew positions, relative to the longitudinal center line of the central pipe. For atomizing the material stream, it may be advantageous under certain local circumstances if several nozzles are arranged only at one half of the circumference of the mouth of the central pipe. For material streams of larger volumes, several nozzles are expediently arranged over the entire circumference of the mouth of the central pipe in such as way as to be distributed approximately evenly. A preferred variant is characterized in that the space for the reducing gas is formed by a pipe conducting the reducing gas, into which the injection nozzle opens from the side, the longitudinal center line of the injection nozzle and the center line of the pipe conducting the reducing gas expediently including an angle ranging between 100° and 160°. The longitudinal axis of at least one nozzle preferably intersects the longitudinal center line of the central pipe. A preferred application of the arrangement according to the invention is characterized in that the arrangement opens into a gas discharge pipe departing from a melter gasifier for melting and optionally completely reducing metal ores as well as for producing a reducing gas containing CO and H2 by coal gasification and the gas discharge pipe opens into a solids separator, such as a cyclone, from which the solids separated in the solids separator can be recircled into the melter gasifier via a solids recircling duct and a dust burner. In the following, the invention is explained in greater detail by several embodiments schematically represented in the drawing, Fig. 1 showing a longitudinal section through an arrangement according to the invention and Fig. 2 a relevant cross section along line ll-ll of Fig. 1. In Figs. 3 to 5, different embodiments of the arrangement according to the invention are schematically represented. Fig. 6 shows the layout of an arrangement according to the invention in a plant for the direct reduction of fine ore. According to the embodiment represented in Figs. 1 and 2, the arrangement for injecting metal-oxide-containing fine particles into a reducing gas is provided with injection nozzle 1 opening into space 3, which is penetrated by reducing gas, through wall 2. This space may be formed, for example, by a pipeline. Injection nozzle 1 is provided with central pipe 4 through which the fine particles are blown to its mouth 5 by means of a carrier gas so that a material stream formed by the fine particles is formed at the mouth. At mouth 5 of central pipe 4, several nozzles 6 enclosing central pipe 4 peripherally are provided which are connected to gas duct 7 for feeding a secondary gas, via gas conducting pipes 8 each. These gas conducting pipes 8 are designed as pipes arranged in parallel with longitudinal center line 9 of central pipe 4, which are provided in annular space 10 enclosing central pipe 4 peripherally, into which space gas duct 7 runs. This annular space 10 is delimited by jacket 11 at the outside, which is closed at the end face at mouth 5 and at the opposite end face by means of end flanges 12, 13. Gas conducting pipes 8 can be turned in relation to end flanges 12, 13 by means of gastight bearings 14, 15. The ends of gas conducting pipes 8 that are opposite to each other are closed with flanges 16, 17. At outer flanges 17, pivots 18 are mounted, which project outwards. At pivots 18, drives for turning the gas conducting pipes around their longitudinal axes 19 are provided, which are not represented in detail. At inside flanges 16 of gas conducting pipes 8, nozzles 6 are located whose axes 6' enclose an angle a with longitudinal center line 9 of the central pipe. Gas conducting pipes 8 and, finally, nozzles 6 are supplied with gas via annular space 10 and openings 20 of gas conducting pipes 8. By turning gas conducting pipes 8 around their longitudinal axes 19, the gas streams flowing from nozzles 6 can be varied as to their position in relation to the material stream in a way that the gas streams can be brought from a position intersecting longitudinal center line 9 of central pipe 4 into a position that is askew in relation to this longitudinal center line. A means for turning gas conducting pipes 8 around their longitudinal axes 19 allows to periodically change the position of the gas streams in relation to the material stream. Angle a enclosed by the gas streams with longitudinal center line 9 of central pipe 4 ranges preferably between 20° and 60° and need not be equally large for all gas streams. According to the embodiment represented in Figs. 1 and 2, several nozzles 6 are arranged over the entire circumference of mouth 5 of central pipe 4 in such as way as to be distributed evenly. It may possibly suffice if several nozzles 6 are arranged only at one half of the circumference of mouth 5 of the central pipe 4, as shown e.g. in Figs. 4 and 5. This is especially the case if the reducing gas in space 3 shows an intense directional flow. It can be seen from Figs. 3, 4 and 5 that the gas streams symbolized by arrows 21 are either oriented in a direction directly opposite to longitudinal center line 9 of the central pipe (Fig. 5) or askew to it (Figs. 3, 4), the material stream proper, with a minimum diameter corresponding to mouth 5, still being hit by the gas streams. The gas streams thus impart to the material stream a rotation about its longitudinal center line 9, the fine particles exit from the material stream by the centrifugal forces and the latter is dispersed. This function occurs in addition to the atomizing effect caused by the gas streams. The gas streams are preferably formed by an inert gas. Inert gas may also be used as carrier gas. Instead of nozzles 6 also an annular gap could be provided in end flange 12, through which a fan-shaped gas stream is directed against the material stream. If the position of the gas streams in relation to the material stream need not be changed, gas conducting pipes 8 are not required; in this case, nozzles 6 can be rigidly inserted in end flange 12. As shown in Fig. 6 below, the layout of the arrangement according to the invention is described by a reducing gas discharge duct 23 conveying a reducing gas from melter gasifier 22, in which a reducing gas containing CO and H2 is formed in a meltdown gasifying zone by coal gasification and reduced iron ore is melted, to a reduction vessel not represented. Both the reduction vessel in which ore is reduced and the melter gasifier can be designed, for example, as described in EP-A - 0 576 414 The reducing gas leaving melter gasifier 22 at opening 24 in dome region 25 of melter gasifier 22 is supplied to cyclone 26 via reducing gas discharge duct 23, in which cyclone the particles entrained by the reducing gas are separated. In the starting region of reducing gas discharge duct 23, cooling gas is fed into the reducing gas via gas feeding means 27 in order to cool the reducing gas to the temperature required for reduction in the reduction vessel. Injection nozzle 1 according to the invention is located shortly thereafter, longitudinal center line 9 of central pipe 4 being oriented in a direction opposite to the direction of flow of the reducing gas and forming an angle between 100° and 160° with it. The iron ore injected into the reducing gas and finely distributed in the latter immediately after entering into the reducing gas discharge duct is reduced, at least partially reduced, within reducing gas discharge duct 23 and separated in cyclone 26. The at least partially reduced iron ore is supplied via dust bins 27 and injector 28 operated preferably with nitrogen gas to dust burner 29 located at a side wall of melter gasifier 22. Dust burner 29 effects an agglomeration of the fine particles and optionally also complete reduction. Additionally to iron ore also fine-grained metallurgical wastes or recyclings in oxidized and/or metallic form as well as possibly additionally carbon-containing materials can be charged via the arrangement according to the invention. The arrangement according to invention allows to replace 15 to 30% of the ore by fine ore and/or metallurgical dusts, etc., which may also be mixed with contaminants. WE CLAIM: 1. Method of blowing metal-oxide-containing fine particles into a reduction gas stream carried in a reduction gas line characterized in that it comprises the steps of introducing, a central material jet, formed by the fine particles and a carrier gas into the reaction gas stream directing at least one gas jet, formed by a secondary gas, in the reaction gas stream being directed against the material jet; said gas jet atomizing the material jet and uniform distribution of the fine particles in the reaction gas stream, thereby the gas jet imparting a torsional moment to the material jet about the axis of the material jet and the fine particles leaving the material jet due to centrifugal forces resulting in breaking of the said material jet. 2. Method as claimed in Claim 1, wherein the gas jet imparts periodically fluctuating torsional moments, preferably of differing magnitudes, to the material jet. 3. Method as claimed in Claim 1 or 2, wherein the gas jet is directed against the material jet at a skewed angle in a manner that it intersects the material jet, and penetrates only into the outer regions of the material jet. 4. Method as claimed in Claim 3, wherein the angle (a) between the gas jet and the material jet is periodically variable. 5. Method as claimed in one or more of Claims 1 to 4, wherein the gas jet is formed by inert gas. 6. Method as claimed in one or more of Claims 1 to 5, wherein the reduction gas flows to the material jet. 7. Method as claimed in Claim 6, wherein the material jet is directed against the direction of flow of the reduction gas, preferably at an angle of between 100 and 160°. Method as claimed in one or more of Claims 1 to 7, wherein at least one gas jet is directed towards the centre of the material jet and penetrates into the latter. Method as claimed in one or more of Claims 1 to 8, wherein the material jet is directed into a reduction gas stream, which emerges from a fusion-gasifying zone, in which a CO- and H2-containing reduction gas is formed by coal gasification and partly and/or fully reduced metal-containing particles are fully reduced or fused, respectively, and which reaction gas stream is subjected to a solids separation after the material jet has been introduced and is then converted in a reduction zone, involving reduction of a metaloxide-containing ore, the fine particles separated during the solids separation being fed to the fusion-gasifying zone via a pulverized-fuel burner (29) , which has the effect of agglomerating the fine particles. Apparatus for carrying out the method as claimed in one or more of Claims 1 to 9, characterized in that it comprises the combination of the following features: a space (3) for receiving reduction gas, bounded 5 by a wall (2, 23), the space (3) for the reduction gas being formed by a tube (23) ducting the reaction gas, an injection (1), opening laterally into the space (3) through the wall (2, 23), which has a central tube (4) conducting fine particles and a carrier gas and is provided at the mouth (5) of the central pipe (4) with at least one nozzle (6) , which is connected to a gas duct (7) for the feeding in of a secondary gas, the longitudinal axis (6') of the nozzle (6) forming in normal projection an angle (a) with the longitudinal centre line (9) of the central pipe (4), and the longitudinal axis (6') of the nozzle (6) being directed at a skewed angle with respect to the longitudinal centre line (9) of the central pipe (4) , the material jet of the central pipe (4) being capable of being subjected by the nozzle (6) at least partly to a torsional moment about the axis of the material jet. 11. Apparatus as claimed in Claim 10, wherein the angle (a) lies in the range between 20 and 60°. 12. Apparatus according to Claim 10 or 11, wherein the longitudinal axis (6') of the nozzle (6) is aligned at a skewed angle with respect to the longitudinal centre line (9) of the central pipe (4) , an angle (a) in the range between 20 and 60° being formed when the longitudinal axis (6') of the nozzle (6) is projected perpendicularly on a plane, taken through the centre longitudinal line (9) of the central tube and the nozzle mouth, between the projected longitudinal centre axis (6') of the nozzle (6) and the longitudinal centre line (9) of the central pipe (4) 13. Apparatus as claimed in one of Claims 10 to 12, wherein the nozzle (6) is arranged movably at the mouth (5) of the central pipe (4) and can assume different positions with its longitudinal axis (6'), preferably different swewed positions, with respect to the longitudinal centre line (9) of the central pipe (4) 14. Apparatus as claimed in one or more of Claims 10 to 13, wherein a plurality of nozzles are arranged around only one circumferential half of the mouth (5) of the central pipe (4). 15. Apparatus as claimed in one or more of Claims 10 to 13, wherein a plurality of nozzles (6) are arranged such that they are distributed approximately uniformly around the entire circumference of the mouth (5) of the central pipe (4) . 16. Apparatus as claimed in one or more of Claims 10 to 15, wherein the longitudinal centre axis (9) of the injection nozzle (1) forms an angle of between 100 and 160° with the axis of the pipe (23) ducting the reduction gas. 17. Apparatus as claimed in one or more of Claims 10 to 16,wherein the longitudinal axis (6') of at least one nozzle (6) intersects the longitudinal centre line (9) of the central pipe (4). 18. Apparatus as claimed in one or more of Claims 11 to 16, wherein the apparatus opens into a gas discharge pipe (23), which emerges from a meter gasifier (22) for the fusing and possibly final reduction of metal ores and for the generation of a CO- and H2-containing reduction gas by coal gasification, and the gas discharge pipe (23) opens out into a solids separator (26) such as a cyclone, from which the solids separated in the solids separator (26) can be returned via a solids return line and a dust burner (29) into the fusion gasifier (22). 19. Method of blowing metal-oxide-containing fine particles substantially as hereinbefore described with reference to and as illustrated in the accompanying drawings.

Documents:

2853-del-1997-abstract.pdf

2853-del-1997-claims.pdf

2853-del-1997-correspondence-others.pdf

2853-del-1997-correspondence-po.pdf

2853-del-1997-description (complete).pdf

2853-del-1997-drawings.pdf

2853-del-1997-form-1.pdf

2853-del-1997-form-13.pdf

2853-del-1997-form-19.pdf

2853-del-1997-form-2.pdf

2853-del-1997-form-3.pdf

2853-del-1997-form-4.pdf

2853-del-1997-form-5.pdf

2853-del-1997-gpa.pdf

2853-del-1997-petition-137.pdf

2853-del-1997-petition-138.pdf