Title of Invention

AGENT FOR PROCESSING SYNTHETIC FIBERS AND METHOD FOR PROCESSING SYSNTHETIC FIBERS

Abstract

To provide an agent for processing synthetic fibers and a method for processing the synthetic fibers, wherein the agent contains a lubricant and a functional agent, and also contains 0.05 to 20 % by weight of a specific phosphoric ester as at least a part of said functional agent, and said phosphoric ester has one to three residual groups obtained by removing all hydroxyl groups from (poly) alkyleneglycol having a (poly) oxyalkylene group composed of 1-50 oxyalkylene units with 2-4 carbon atoms, in the ester molecular.

Full Text

FIBERS BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to an agent for processing synthetic fibers and a method for processing synthetic fibers. In recent years, high speed of the process is further advanced remarkably in a spinning process or a textured process of the synthetic fibers, so that it tends to generate a fluff or a yarn break increasingly in accordance with the high speed. In order to prevent the generation of the fluff or the yarn break, it has been carried out that the agent, where the content ratio of a functional agent is increased for preventing the generation of the fluff or the yarn break, is used as an agent for processing synthetic fibers to be adhered to the synthetic fibers, or the adhesion amount of the agents for processing synthetic fibers to the synthetic fibers is increased. However, it still cannot deal sufficiently with the problems accompanied with the high speed in recent years. The present invention relates to the agent for processing synthetic fibers and the method for processing synthetic fibers, which are capable of dealing with the problems accompanied with the high speed in recent years in the spinning process or the textured process of the synthetic fibers, so as to prevent the generation of the fluff or the yarn break sufficiently. Description of the Conventional Art Conventionally, as the agent for processing synthetic fibers, the agent containing a lubricant and the functional agent has been used in general. As said agent for processing synthetic fibers, various agents containing the functional agent for preventing the generation of the fluff or the yarn break have been known, (for example, referring to Japanese Patent Laid -Open No. 310241-1995, Japanese Patent Laid-Open No. 325949-1996, Japanese Patent Laid-Open No. 61646- 1999). However, in these conventional agents for processing synthetic fibers, there are problems that the generation of the fluff or the yarn break cannot be prevented sufficiently in the spinning process or the textured process with the high speed in recent years . The present invention has the object to provide the agent for processing synthetic fibers and the method for processing synthetic fibers, which are capable of dealing with the problems accompanied with the high speed in recent years in the spinning process or the textured process of the synthetic fibers, and preventing the generation of the fluff or the yarn break sufficiently. Summary of the Invention Present inventors have examined in order to solve the above - described problems and, as a result, it has been found out that the agent for processing synthetic fibers, where the predetermined amount of a specified phosphoric ester is contained as at least a part of the functional agent, is surely preferable, and adhering the predetermined amount of said agent for processing synthetic fibers to the synthetic fibers is surely preferable. That is, the present invention relates to the agent for processing synthetic fibers, where 0.05 to 20 % by weight of the phosphoric ester shown by formula 1 is contained as at least a part of the functional agent. Moreover, the present invention also relates to the method for adhering said agents of the present invention to the synthetic fibers to have 0.1 to 3 % by weight. where R1, R2 and R3 are simultaneously the same or different alkyl group with 1-24 carbon atoms, alkenyl group with 2-24 carbon atoms or organic group shown by Formula 2, and at least one of said R1, R2 and R3 is the organic group shown by Formula 2. [Formula 2] -A- 0- R4 where R4 is hydrogen atom, alkyl group with 1-24 carbon atoms or alkenyl group with 2-24 carbon atoms, and A is a residual group obtained by removing all hydroxyl groups from (poly) alkyleneglycol having a (poly) oxyalkylene group composed of 1-50 oxyalkylene units with 2-4 carbon atoms. First, the agent for processing synthetic fibers of the present invention will be explained. The agent for processing synthetic fibers of the present invention contains the lubricant and the functional agent, and also contains the phosphoric ester shown by Formula 1 as at least a part of said functional agent. The phosphoric ester shown by Formula 1 is the phosphoric ester where R1, R2 and R3 therein are simultaneously the same or different alkyl group with 1-24 carbon atoms, alkenyl group with 2-24 carbon atoms or organic group shown by Formula 2, and at least one of said R1, R2 and R3 is the organic group shown by Formula 2. As for said phosphoric ester shown by Formula 1, the following three cases are contained, that is, (1) the phosphoric ester in the case that all of the R1, R2 and R3 in Formula 1 are the same organic group, (2) the phosphoric ester in the case that any two of R1, R2 and R3 in Formula 1 are the same organic group and another one is the different organic group, and (3) the phosphoric ester in the case that all of R1, R2 and R3 in Formula 1 are the different organic groups. When one or two of R1, R2 and R3 in Formula 1 are the alkyl group with 1-24 carbon atoms, the following groups can be used as said alkyl group, that is, a methyl group, an ethyl group, a butyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, undecyl group, a dodecyl group, a tetradecyl group, a pentadecyl group, a hexadecyl group, a heptadecyl group, an octadecyl group, a nonadecyl group, an eicosanyl group, a heneicosanyl group, a docosanyl group, a tricosanyl group, a tetracosanyl group, a pentacosanyl group, a hexacosanyl group. a heptacosanyl group, an octacosanyl group, a 2 -methyl-pentyl group, an 2-ethyl -hexyl group, a 2-propyl-heptyl group, a 2-butyl-octyl group, a 2-pentyl-nonyl group, a 2-hexyl-decyl group, a 2-heptyl-undecyl group, an 2-octyl-dodecyl group, a 2-nonyl-tridecyl group, a 2-decyl-tetradecyl group, an 2 -undecyl-pentadecyl group, a 2 - dodecyl-hexadecyl group or the like. When one or two of R1, R2 and R3 in Formula 1 are the alkenyl group with 2-24 carbon atoms, the following groups can be used as the alkenyl group, that is, an 10-undecenyl group, a 9C-octadecenyl group, a 9t-octadecenyl group, a 9C, 12C-octadeca- 9, 12- dienonyl group, a 9C, 12C, 15C-octadeca- 9, 12, 15- trienonyl group, a 9C-eicocenyl group, a 5, 8, 11, 14 - eicosa tetraenoyl group, 13C - docosenyl group, 13t-docosenyl group or the like. When one or more than two of R1, R2 and R3 in Formula 1 are the organic group shown by Formula 2, the following organic groups are contained as said organic group, that is, (1) the organic group in the case that R4 in Formula 2 is a hydrogen atom, and A is the residual group obtained by removing all hydroxyl groups from alkyleneglycol having one oxyalkylene unit with 2-4 carbon atoms, (2) the organic group in the case that R4 in Formula 2 is the alkyl group with 1-24 carbon atoms, and A is the residual group obtained by removing all hydroxyl groups from alkyleneglycol having one oxyalkylene unit with 2-4 carbon atoms, (3) the organic group in the case that R4 in Formula 2 is the alkenyl group with 2-24 carbon atoms, and A is the residual group obtained by removing all hydroxyl groups from alkyleneglycol having one oxyalkylene unit with 2-4 carbon atoms, (4) the organic group in the case that R4 in Formula 2 is a hydrogen atom, and A is the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having the polyoxyalkylene group composed of 2-50 oxyalkylene units with 2-4 carbon atoms, (5) the organic group in the case that R4 in Formula 2 is the alkyl group with 1-24 carbon atoms, and A is the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having the polyoxyalkylene group composed of 2-50 oxyalkylene units with 2-4 carbon atoms, (6) the organic group in the case that R4 in Formula 2 is the alkenyl group with 2-24 carbon atoms, and A is the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having the polyoxyalkylene group composed of 2-50 oxyalkylene units with 2-4 carbon atoms. R4 in Formula 2 is a hydrogen atom, the alkyl group with 1-24 carbon atoms or the alkenyl group with 2-24 carbon atoms. As for the alkyl group with 1-24 carbon atoms and the alkenyl group with 2-24 carbon atoms, the above description with respect to R1, R2 and R3 is similarly applied. It is preferable that the phosphoric ester shown by Formula 1 is the ester where R4 in Formula 2 is the hydrogen atom. As A in Formula 2, (1) the residual group obtained by removing all hydroxyl groups from alkyleneglycol having one oxyalkylene unit with 2-4 carbon atoms, and (2) the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having the polyoxyalkylene group composed of 2-50 oxyalkylene units with 2-4 carbon atoms, are contained as described above. However, as A in Formula 2, the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having the polyoxyalkylene group composed of 2-50 oxyalkylene units with 2-4 carbon atoms, is preferable. As the oxyalkylene unit with 2-4 carbon atoms composing said polyoxyalkylene group, although oxyethylene unit, oxypropylene unit and oxybutylene unit can be used, the oxyethylene unit and the oxypropylene unit are preferable, and the oxyethylene unit is more preferable. Moreover, it is preferable that the total number of repeating said oxyalkylene units is two to fifteen. When the polyoxyalkylene group is composed with more than two oxyalkylene units, which are different each other, a random link or a block link can be used as a linking means. Therefore, as the phosphoric ester shown by Formula 1, the phosphoric ester where A in Formula 2 is the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having the polyoxyalkylene group composed of 2-50 oxyalkylene units with 2-4 carbon atoms, is preferable, and the phosphoric ester where A in Formula 2 is the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having the polyoxyalkylene group composed of 2-15 oxyalkylene units with 2 or 3 carbon atoms is more preferable, and it is especially preferable that said polyalkyleneglycol is polyethyleneglycol . The above - described phosphoric ester shown by Formula 1 can be produced by the publicly known method. For example, one of the methods which can be used is adding the predetermined amount of a phosphorous pentoxide to a fatty monovalent alcohol to react them to obtain a phosphoric ester and thereafter carrying out an addition reaction of alkyleneoxide to said phosphoric ester. The agent for processing synthetic fibers of the present invention contains the lubricant and the functional agent, and also contains 0.05 to 20 % by weight of the above-described phosphoric ester shown by Formula 1 as at least a part of said functional agent. However, it is preferable that said agents contains 0.8 to 15 % by weight of said phosphoric ester, and is more preferable 3 to 12 % by weight. As the functional agent other than the phosphoric ester shown by Formula 1, the publicly known agent can be used. For example, the following agents can be used, that is, (1) an antistatic agent, such as an anionic surfactant, i.e. an alkyl sulfonate, an alkyl carboxylate or the like, a cationic surfactant, i.e. dodecyltrimethylammonium ethosulfate or the like, and an amphoteric surfactant, i.e. octyldimethylammonioacetate or the like, (2) an oiliness agent, such as an organophosphate, a fatty acid or the like, (3) a wetting agent, such as a polyether modified silicone having a polydimethylsiloxane chain having an average molecular weight of 1500 to 3000 as a main chain and polyoxyalkylene chain having an average molecular weight of 700 to 5000 as a side chain, a surfactant having perfluoroalkyl group, or the like, (4) a cohennsive agent, such as a polyetherpolyester or the like, (5) a boundary lubricant, such as an organic titanium compound, an organic phosphorus compound or the like, (6) an antioxidant, which has a phenol-type, a phosphite-type, a thioether-type, an amine-type, or the like, or (7) a rust preventive or the like. When the above-described other functional agent is used, it is preferable that the using amount of said other functional agent is 0.2 to 15 % by weight in the agents for processing synthetic fibers, and more preferably 1 to 12 % by weight. In the agents for processing synthetic fibers of the present invention, as the lubricant, the publicly known agents can be used. For example, (1) a fatty ester, (2) an aromatic ester, (3) a polyether compound, (4) a (poly) etherester compound, (5) a mineral oil, (6) a silicone oil or the like, can be used. As the above-described fatty ester, the following compounds can be used, that is, (1) the ester compound, where the fatty monovalent alcohol is esterified with a fatty monocarboxylic acid, such as butyl stearate, octyl stearate, oleyllaurate, oleyloleate, isopentacosanyl isostearate or the like, (2) the ester compound, where a fatty polyvalent alcohol is esterified with the fatty monocarboxylic acid, such as 1, 6 - hexanedioldidecanoate, trimethylolpropane monoolate monolaurate or the like, (3) the ester compound, where the fatty monovalent alcohol is esterified with a fatty polyvalent carboxylic acid, such as dilauryladipate, dioleylazelate or the like. In these compounds, the fatty ester with 17-60 carbon atoms is preferable, and the fatty ester with 17-60 carbon atoms, where the fatty monovalent alcohol is esterified with the fatty monocarboxylic acid or the fatty polyvalent alcohol is esterified with the fatty mono carboxylic acid, is more preferable. As the above - described aromatic ester, the following ester compounds can be used, that is, (1) the ester compound, where a aromatic alcohol is esterified with the fatty monocarboxylic acid, such as benzyl stearate, benzyl laurate or the like, (2) the ester compound, where the fatty monovalent alcohol is esterified with the aromatic carboxylic acid, such as diisostearyl isophthalate, trioctyl trimellitate or the like. In these esters, the ester where the fatty monovalent alcohol is esterified with the aromatic carboxylic acid is preferable. As the above - described polyether compound, a polyether monool, a polyether diol, a polyether triol or the like, all of which have the polyoxyalkylene group in the molecular, can be used. However, the polyether compound having the average molecular weight of 700 to 10000 is preferable. Further, the polyether compound having the average molecular weight of 700 to 10000, where alkylene oxide with 2-4 carbon atoms is added in the block state or randomly to a monovalent to trivalent hydroxy compound with 1-18 carbon atoms, is more preferable As the above - described (poly) etherester compound, the following (poly) ehterester compounds can be used, that is, (1) the (poly) etherester compound, where the (poly) ether compound, in which the alkylene oxide with 2-4 carbon atoms is added to the monovalent to trivalent fatty alcohol with 4-26 carbon atoms, is esterified with the fatty carboxylic acid with 4-26 carbon atoms, (2) the (poly) etherester compound, where the (poly) ether compound, in which the alkylene oxide with 2-4 carbon atoms is added to the monovalent to trivalent aromatic alcohol, is esterified with the fatty carboxylic acid with 4-26 carbon atoms, or (3) the (poly) etherester compound, where the (poly) ether compound, in which the alkylene oxide with 2-4 carbon atoms is added to the fatty alcohol with 4-26 carbon atoms, is esterified with the aromatic carboxylic acid. As the above - described mineral oil, various mineral oils having various viscosities can be used. In these oils, it is preferable that the mineral oil has the viscosity of 1X10-6 to 1.3X10-1 m2 / s at 30 °C, and more preferable 1X10-6 to 5X10-5 m2 / s at 30 °C. As such preferable mineral oil, a liquid paraffin can be used. As the above - described silicone oil, various silicone oils having various viscosities can be used. In these silicone oils, a linear polyorganosiloxane having the viscosity of 1X10-3 to 1 m2 / s at 30 °C can be preferably used. As said linear polyorganosi loxane, a linear polydimethylsiloxane, a linear polydimethylsiloxane having a modifying group, or the like, where the viscosity at 30 °C is 1X10-3 to 1 m2 / s, can be used. In this case, as the modifying group, a ethyl group, a phenyl group, a fluoropropyl group, aminopropyl group, a carboxyoctyl group, a polyoxye thyleneoxypropyl group, a w - methoxypolyethoxypolypropoxy group or the like can be used. Among those, the linear polydimethylsiloxane is more preferable. As the agent for processing synthetic fibers of the present invention, it is preferable that the agent contains 50 to 90 % by weight of the above-described lubricant and 1 to 30 % by weight of the above-described functional agent, and also contains 0.05 to 20 % by weight of the above-described phosphoric ester shown by Formula 1 as at least a part of said functional agent, and it is more preferable that the agent contains 0.8 to 15 % by weight of said phosphoric agent shown by Formula 1. The agent for processing synthetic fibers of the present invention can contain the emulsifier further. As said emulsifier, the publicly known emulsifier can be used. For example, the following compounds can be used as the emulsifier, that is, (1) a nonionic surfactant having the polyoxyalkylene group in the molecular, such as polyoxyalkylene alkylether, polyoxyalkylene alkylphenylether, polyoxyalkylene alkylester, polyoxy castor oil, polyoxyalkylene alkylamionoether or the like, (2) a polyvalent alcohol partial ester type nonionic surfactant, such as sorbitan monolaurate, sorbitan trioleate, glycerin monolaurate, diglycerin dilaurate or the like, (3) a polyoxyalkylene polyvalent alcohol fatty acid ester type nonionic surfactant, such as a compound where alkyleneoxide is added to a partial ester of a fatty acid with a trivalent to hexavalent alcohol, a partial or complete ester of the fatty acid with the trivalent to hexavalent alcohol being added with alkyleneoxide, or a compound where alkyleneoxide is added to ester of a hydroxyl - fatty acid with the trivalent to hexavalent alcohol. In these surfactants, the polyoxyalkylene alkylether having the polyoxyalkylene group, where the number of repeating the oxyethylene group is 3 to 10, and the alkyl group with 8-18 carbon atoms in the molecular is preferable. When the above-described emulsifier is used, it is preferable that the amount of the emulsifier is 2 to 30 % by weight in the agent for processing synthetic fibers. In the case that the agent for processing synthetic fibers of the present invention contains the emulsifier, as said agent for processing synthetic fibers, it is preferable that the agent comprises the above - described lubricant, functional agent and emulsifier, contains 50 to 90 % by weight of said lubricant, 1 to 30 % by weight of said functional agent and 2 to 30 % by weight of said emulsifier, and also contains 0.05 to 20 % by weight of the phosphoric ester shown by Formula 1 as at least a part of said functional agent. Further, the agents containing 0.8 to 15 % by weight of the said phosphoric ester is more preferable. Next, the method for processing synthetic fibers of the present invention will be explained. The method comprises a step of adhering the agent for processing synthetic fibers of the present invention to the synthetic fibers to have 0.1 to 3 % by weight, preferably 0.3 to 1.2 % by weight. As the process for adhering said agent for processing synthetic fibers to the synthetic fibers, a spinning process, a process carrying out a spinning and drawing simultaneously, or the like, can be used. As the method of adhering the agent for processing synthetic fiber to the synthetic fibers, the following methods can be used, that is, an oiling roller application, an oiling jet with metering pump, a dip oiling, a spray oiling or the like. Furthermore, as a condition at the time of adhering the agent for processing synthetic fibers to the synthetic fibers, although a neat, an organic solvent solution, an aqueous solution or the like can be used, the aqueous solution is preferable. When said agent for processing synthetic fibers is adhered in the condition of the aqueous solution, it is also preferable that the amount of the agent is 0.1 to 3 % by weight, more preferably 0.3 to 1.2 % by weight. As the synthetic fibers being applied objects of the method for processing synthetic fibers of the present invention, the following fibers can be used, that is, (1) a polyester fiber, such as polyethylene terephthalate, polypropylene terephthalate, a poly (lactic acid) polymers or the like, (2) a polyamide fiber, such as nylon 6, nylon 66 or the like, (3) a polyacrylic fiber, such as polyacryl, modaacryl or the like, (4) a polyolefin fiber, such as polyethylene, polypropylene or the like or a polyurethane fiber. In these fibers, when the polyester fiber or polyamide fiber is used, the present invention has the excellent effectiveness. DETAILED DESCRIPTION OF PREFERRED EMBODIMENT As the preferred embodiment of the agent for processing synthetic fibers of the present invention, the following embodiments from (1) to (17) can be used. (1) The agent for processing synthetic fibers comprising 85 % by weight of the following lubricant (A-1) , 5 % by weight of the following phosphoric ester (B-1) as the functional agent, 5 % by weight of the following emulsifier (C-1), 2 % by weight of the following functional agent (D-1) and 3 % by weight of the following functional agent (E-1) as the other functional agents, where the total amount is 100 % by weight. The lubricant (A-1) : a mixture of polyether monool comprising, (1) a polyether monool having a number average molecular weight of 3000 where an ethylene oxide (hereinafter referred to as EO) and a propylene oxide (hereinafter referred to as PO) are added randomly to butyl alcohol to have a weight ratio EO/PO-50/50, (2) a polyether monool having the number average molecular weight of 1000, where EO and PO are added randamly to butyl alcohol to have the weight ratio EO/PO-50/50, and (3) a polyether monool having the number average molecular weight of 1000, where EO and PO are added in the block state to octyl alcohol to have the weight ratio EO/PO-35/65. In said mixture, the weight ratio of these polyether monools (1)/(2)/(3) is 30/50/20. The phosphoric ester (B - 1) : didodecyl ( w - hydroxy-polyoxyethylene) phosphate having the number of repeating the oxyethylene group of 4 (hereinafter referred to as n=4), which is the phosphoric ester shown by Formula 1, where R1 and -R2 are the dodecyl group, and R3 is the organic group shown by Formula 2 and is w -hydroxy-polyoxyethylene (n = 4) group. The emulsifier (C-1) : a -dodecyl-co - hydroxy - polyoxyethylene (n=7). The functional agent (D-1) : a mixture comprising (1) a potassium decylsulfonate and (2) a potassium w -dodecyl-trioxyethylene phosphate, wherein the weight ratio (l)/(2) is 42/58. The functional agent (E-1) : a mixture comprising (1) a polyether modified silicone and (2) an ethyleneglycol, wherein the weight ratio (l)/(2) is 33/67. (2) The agent for processing synthetic fibers comprising 84 % by weight of the lubricant (A-1), 5 % by weight of the following phosphoric ester (B-2) as the functional agent, 10 % by weight of the emulsifier (C-1), and 1 % by weight of the following functional agent (D-2) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B-2) : (w -hydroxy-polyoxyethylene(n-8)) dioctadecyl phosphate, which is the phosphoric ester shown by Formula 1, where R1 and R2 are the octadecyl group and R3 is the organic group shown by Formula 2 and is w -hydroxy-polyoxyethylene (n-8) group. The functional agent (D-2) : tributylmethylammonium = diethyl phosphate. (3) The agent for processing synthetic fibers comprising 73 % by weight of the lubricant (A-1) , 5 % by weight of the following phosphoric ester (B-3) as the functional agent, 20 % by weight of the emulsifier (C-1) , 2 % by weight of the functional agent (D-1) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 3) rdodecyl bis( w -hydroxy-polyoxyethylene(n = 4) ) phosphate, which is the phosphoric ester shown by Formula 1, where R1 is the dodecyl group, and R2 and R3 are the organic group shown by Formula 2 and are CO -hydroxy-polyoxyethylene (n-4) group. (4) The agent for processing synthetic fibers comprising 73 % by weight of the lubricant (A-1), 5 % by weight of the following phosphoric ester (B-4) as the functional agent, 20 % by weight of the emulsifier (C-1), and 2 % by weight of the functional agent (D -1) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B-4) : bis (w -hydroxy- polyoxyethylene (n=8)) octadecyl phosphate, which is the phosphoric ester shown by Formula 1, where R1 is the dodecyl group, and R2 and R3 are the organic group shown by Formula 2 and are w -hydroxy-polyoxyethylene (n-8) group. (5) The agent for processing synthetic fibers comprising 85 % by weight of the following lubricant (A-2), 3 % by weight of the phosphoric ester (B-1), 2 % by weight of the phosphoric ester (B-3) as the functional agents, 5 % by weight of the emulsifier (C -1), 2 % by weight of the functional agent (D-1) and 3 % by weight of the functional agent (E-1) as the other functional agents, where the total amount is 100 % by weight. The lubricant (A-2) : a mixture comprising, (1) a ester where a -butyl-w -hydroxy-polyoxyethylene (n=8) is esterified with dodecanoic acid, (2) the polyether monool having the number average molecular weight of 3000, where EO and PO are added randomly to butyl alcohol to have the weight ratio EO/PO=50/50, and (3) the polyether monool having the number average molecular weight of 1000, where EO and PO are added in the block state to octyl alcohol to have the weight ratio EO/PO=35/65. In said mixture, the weight ratio of these compounds (l)/(2)/(3) is 18/29/53. (6) The agent for processing synthetic fibers comprising 84 % by weight of the lubricant (A-2) , 2.5 % by weight of the phosphoric ester (B-2) , 2.5 % by weight of the phosphoric ester (B-4) as the functional agents, 10 % by weight of the emulsifier (C-1) , and 1 % by weight of the functional agent (D-2) as the other functional agent, where the total amount is 100 % by weight. (7) The agent for processing synthetic fibers comprising 58 % by weight of the following lubricant (A-3) , 12 % by weight of the following phosphoric ester (B-5) as the functional agent, 23 % by weight of the following emulsifier (C-2), 4 % by weight of the functional agent (D-1) and 3 % by weight of the following functional agent (E - 2) as the other functional agents, wherein the total amount is 100 % by weight. The lubricant (A-3) : a mixture comprising (1) lauryloctanate and (2) the mineral oil having the viscosity of 1.3X10-5 m2 / s at 30°C , wherein the weight ratio (1) / (2) is 69/31 . The phosphoric ester (B-5) : tris ( CO -hydroxy- polyoxyethylene (n=4)) phosphate, which is the phosphoric ester shown by Formula 1, where the R1 R2 and R3 are the organic group shown by Formula 2 and are w -hydroxy-polyoxyethylene (n-4) group. The emulsifier (C-2) : a mixture comprising (1) an agent, where 20 mol EO is added to a hydrogenated caster oil, and (2) diester, where 1 mol polyethyleneglycol having the average molecular weight of 600 is esterified with 2 mol lauric acid. In said mixture, the weight ratio of the agent and diester (l)/(2) is 80/20. The functional agent (E-2) : a mixture comprising (1) an oleic acid and (2) propyleneglycol , wherein the weight ratio (l)/(2) is 80/20. (8) The agent for processing synthetic fibers comprising 68 % by weight of the lubricant (A-2) , 15 % by weight of the following phosphoric ester (B-6) as the functional agent, 15 % by weight of the emulsifier (C-1) , 2 % by weight of the following functional agent (D-3) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 6) : dodecenyl ( w -hydroxy-polyoxyethylene(n=4)) octyl phosphate, which is the phosphoric ester shown by Formula 1, where R1 is the octyl group, R2 is the dodecenyl group and R3 is the organic group shown by Formula 2 and is w -hydroxy-polyoxyethylene (n = 4) group. D-3 : oleic acid tetraethylammonium salt. (9) The agent for processing synthetic fibers comprising 75 % by weight of the lubricant (A-2) , 10 % by weight of the following phosphoric ester (B-7) as the functional agent, 10 % by weight of the emulsifier (C-1) , 2 % by weight of the functional agent (D-1) and 3 % by weight of the functional agent (E-1) as the other functional agents, where the total amount is 100 % by weight. The phosphoric ester (B - 7) : (w -hydroxy-polyoxypropylene) dioctyl phosphate having the number of repeating the oxypropylene group of 5 (hereinafter referred to as m=5), which is the phosphoric ester shown by Formula 1, where R1 and R2 are the octyl group, and R3 is the organic group shown by Formula 2 and is CO -hydroxy-polyoxypropylene (m=5) group. (10) The agent for processing synthetic fibers comprising 73 % by weight of the lubricant (A-2) , 10 % by weight of the following phosphoric ester (B-8) as the functional agent, 15 % by weight of the emulsifier (C-1), and 2 % by weight of the functional agent (D -1) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 8) rdidodecyl ( CO -hydroxy-polyoxyethylene (n-2) polyoxypropylene (m-5)) phosphate, which is the phosphoric ester shown by Formula 1, where R1 and R2 are the dodecyl group, and R3 is the organic group shown by Formula 2 and is CO -hydroxy-polyoxyethylene (n=2) polyoxypropylene (m= 5 ) group. (11) The agent for processing synthetic fibers comprising 59 % by weight of the lubricant (A-3) , 10 % by weight of the following phosphoric ester (B-9) as the functional agent, 20 % by weight of the emulsifier (C-2) , 6 % by weight of the functional agent (D-1) and 5 % by weight of the functional agent (E-2) as the other functional agents, where the total amount is 100 % by weight. The phosphoric ester (B - 9) :dibutyl ( w -hydroxy-polyoxyethylene (n=20)) phosphate, which is the phosphoric ester shown by Formula 1, where R1 and R2 are the butyl group, and R3 is the organic group shown by Formula 2 and is CO -hydroxy-polyoxyethylene (n = 20) group. (12) The agent for processing synthetic fibers comprising 78 % by weight of the lubricant (A-1) , 10 % by weight of the following phosphoric ester (B-10) as the functional agent, 10 % by weight of the emulsifier (C-1), and 2 % by weight of the functional agent (D -2) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 10) :butyl ( w -hydroxy-polyoxyethylene(n=46)) octyl phosphate, which is the phosphoric ester shown by Formula 1, where R1 is the butyl group, R2 is the octyl group, and R3 is the organic group shown by Formula 2 and is w - hydroxy-polyoxyethylene (n=46) group. (13) The agent for processing synthetic fibers comprising 78 % by weight of the lubricant (A-1) , 10 % by weight of the following phosphoric ester (B-11) as the functional agent, 10 % by weight of the emulsifier (C-1), and 2 % by weight of the functional agent (D -2) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 11) : dihexyl ( w -hydroxy-polyoxybutylene) phosphate having the number of repeating the oxybutylene group of 3, (hereinafter referred to as p=3), which is the phosphoric ester shown by Formula 1 where R1 and R2 are the hexyl group, and R3 is the organic group shown by Formula 2 and is w -hydroxy-polyoxybutylene (p=3) group. (14) The agent for processing synthetic fibers comprising 68 % by weight of the lubricant (A-2) , 20 % by weight of the following phosphoric ester (B-12) as the functional agent, 10 % by weight of the emulsifier (C-l), and 2 % by weight of the functional agent (D -4) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 12) : ( to -methyloxy-polyoxyethylene (n=4)) dioctyl phosphate, which is the phosphoric ester shown by Formula 1, where R1 and R2 are the octyl group, and R3 is the organic group shown by Formula 2 and is w - methyloxy - polyoxyethylene (n = 4) group. D-4 : lauryldimethyl betaine. (15) The agent for processing synthetic fibers comprising 78 % by weight of the lubricant (A-1), 5 % by weight of the following phosphoric ester (B-13) as the functional agent, 15 % by weight of the emulsifier (C-1), and 2 % by weight of the functional agent (D -1) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 13) rdioctyl ( w -vinyloxy-polyoxyethylene (n=4)) phosphate, which is the phosphoric ester shown by Formula 1 where R1 and R2 are the octyl group, and R3 is the organic group shown by Formula 2 and is 0) -vinyloxy-polyoxyethylene (n=4) group. (16) The agent for processing synthetic fibers comprising 70 % by weight of the lubricant (A-l) , 20 % by weight of the following phosphoric ester (B-14) as the functional agent, 5 % by weight of the emulsifier (C-1) , 2 % by weight of the functional agent (D-1) and 3 % by weight of the functional agent (E-1) as the other functional agents, where the total amount is 100 % by weight. The phosphoric ester (B - 14) :2 -hydroxyethyl dioctyl phosphate, which is the phosphoric ester shown by Formula 1, where R1 and R2 are the octyl group, and R3 is the organic group shown by Formula 2 and is 2 -hydroxyethylethyl group. (17) The agent for processing synthetic fibers comprising 78 % by weight of the lubricant (A-1) , 5 % by weight of the following phosphoric ester (B-15) as the functional agent, 15 % by weight of the emulsifier (C-1), and 2 % by weight of the functional agent (D -1) as the other functional agent, where the total amount is 100 % by weight. The phosphoric ester (B - 15) :bis (2-hydroxyethyl) octyl phosphate, which is the phosphoric ester shown by Formula 1, where R1 is the octyl group, and R2 and R3 are the organic group shown by Formula 2 and are 2-hydroxyethyl group. Furthermore, as the preferred embodiment of the method for processing synthetic fibers of the present invention, the following embodiment (18) can be used. (18) The method for processing synthetic fibers comprising steps of making any one of the agents for processing synthetic fibers (1) to (17) into the aqueous solution, and adhering the aqueous solution to the spun polyethylene terephthalate fiber as the agents for processing synthetic fibers to have 0.5 % by weight or 0.9 % by weight. Hereinafter, although examples will be described in order to explain the constitution and effect of the present invention more concretely, the present invention is not limited to these examples. In addition, in the following examples, a part means a weight part, and % means % by weight. Examples Examination Classification 1 (Synthesis of the phosphoric ester shown by Formula 1) Synthesis of the phosphoric ester (B-1) 434 g (1 mol) of a didodecyl hydrogen phosphate was charged into an autoclave, and the inside of the autoclaves was replaced by a nitrogen gas and heated at 80 °C. Then, 176 g (4 mol) of ethylene oxide was entered with pressure to be reacted. After one hour reaction, the reactant was obtained. When the obtained reactant was analyzed, the reactant was the phosphoric ester (B-l) shown by Formula 1, where R1 and R2 were the dodecyl group, and R3 was the w - hydroxy - polyoxyethylene (n=4) group. Synthesis of phosphoric esters (B-2) to (B-15) and (b-1) Phosphoric esters (B-2) to (B-15) and (b-1) were synthesized like the phosphoric ester (B-l) . These contents were shown in Table 1 collectively Examination Classification 2 (Preparation of the agents for processing synthetic fibers) Example 1 The agent for processing synthetic fibers (example 1) was prepared by uniformly mixing 85 parts of the lubricant (A-1) described in Table 2, 5 parts of the phosphoric ester (B - 1) prepared in the examination classification 1 as the functional agent, 5 parts of the emulsifier (C-1) described in Table 2, and 2 parts of the functional agent (D-1) and 3 part of the functional agent (E-1), which were described in Table 2, as the other functional agents, the total amount being 100 weight parts. • Examples 2 to 17 and Comparison examples 1 to 3 The agent for processing synthetic fibers of examples 2 to 17 and comparison examples 1 to 3 were prepared like Example 1. The content of the agent for processing synthetic fibers prepared in each example including Example 1 were shown in Table 2 collectively. In Table 2, A-1 : the mixture comprising, (1) the polyether monool having the number average molecular weight of 3000, where EO and PO were added randomly to butyl alcohol to have a weight ratio EO/PO=50/50, (2) the polyether monool having the number average molecular weight of 1000, where EO and PO were added randomly to butyl alcohol to have the weight ratio EO/PO=50/50, and (3) the polyether monool having the number average molecular weight of 1000, where EO and PO were added in the block state to octyl alcohol to have the weight ratio EO/PO=35/65; In said mixture, the weight ratio of these polyether monools (l)/(2)/{3) was 30/50/20. A-2 : the mixture comprising, (1) the ester, where a - butyl - w - hydroxy - polyoxyethylene (n = 8) was esterified with dodecanoic acid, (2) the polyether monool having the number average molecular weight of 3000, where EO and PO were added randomly to butyl alcohol to have the weight ratio EO/PO-50/50, and (3) the polyether monool having the number average molecular weight of 1000, where EO and PO were added in the block state to octyl alcohol to have the weight ratio EO/PO=35/65. In said mixture, the weight ratio of these compounds (l)/(2)/(3) was 18/29/53. A-3 : the mixture comprising (1) lauryloctanate and (2) the mineral oil having the viscosity of 1.3 X10-5 m2 / s at 30 °C, wherein the weight ratio (l)/(2) was 69/31. B-1 toB-15 andb-1 : phosphoric esters, whichwere synthesized in the examination classification 1 and described in Table 1. C - 1 : a - dodecyl - w - hydroxy - polyoxye thylene (n-7) . C-2 : the mixture comprising (1) the agent, where 20 mol EO was added to the hydrogenated caster oil, and (2) a diester, where 1 mol polyethyleneglycol having the average molecular weight of 600 was esterified with 2 mol lauric acid. In said mixture, the weight ratio (l)/(2) was 80/20. D-1 : the mixture comprising, (1) potassium decylsulfonate and (2) potassium w - dodecyl-trioxyethylene phosphate, wherein the weight ratio(l)/(2) was 42/58. D-2 : tributylmethylammonium diethyl phosphate. D-3 : tetraethylammonium oleate. D-4 : dodecyldimethylammonioacetate. E-1 : the mixture comprising, (1) the polyether modified silicone having the polydimethylsiloxane chain having the average molecular weight of 2300 as a main chain and the polyoxyalkylene chain having the average molecular weight of 3000 as the side chain, and (2) ethy1eneglycol. In said mixture, the weight ratio (l)/(2) was 33/67. E-2 : the mixture comprising, (1) oleic acid and (2) propyleneglycol, wherein the weight ratio (l}/(2) was 67/33. Examination Classification 3 (Adhesion of the agent for processing synthetic fibers to the synthetic fibers, False-twisting process and Evaluation) • Adhesion of the agent for processing synthetic fibers to the synthetic fibers. The agent for processing synthetic fibers prepared in the examination classification 2 and dilution water were uniformly mixed to make 10 % aqueous solution. After drying polyethylene terephthalate chip having an intrinsic viscosity of 0.64 and 0.2 % content of titanium oxide by the general method, said polyethylene terephthalate chip was spun by using an extruder at 295 degree C, and extruded from a spinneret to be solidified to make a traveling yarn by cooling. After adhering the prepared 10 % aqueous solution to the traveling yarn to have the adhesion amount described in Table 3 as the agents for processing synthetic fibers by the oiling jet with metering pump, the yarn was bundled by the guide, and wound at the speed of 3000 m / minute without causing elongation mechanically . Then, a par tial or i en ted yarn of a 128 decitex 36 filament was obtained as a 10kg cake . • False-twisting process The false-twisting process was carried out under the following conditions by a contact type False- twisting Apparatus, by using said cake. • • Conditions of the False-twisting process by the contact type False-twisting Apparatus : By using the contact type False - twisting Apparatus (SDS 1200 of Teijin Seiki Co., Ltd.), the false - twisting process was carried out with a continuous operation for 25 days under the following conditions, that is, a yarn speed was 800 m / minute, a draw ratio was 1.652, a twisting method was a friction disc method, which had one inlet side guide disc, one outlet side guide disc and seven rigid polyurethane discs, a length of a primary heater was 2.5 m, an surface temperature of said primary heater was 210 °C, there was no secondary heater, and a target twist number was 3300 T / m. • Evaluation of fluff In said false-twisting process, the number of fluff per hour was measured by a Fray counter (DT- 105 of Toray Engineering Co., Ltd.), before winding the false-twisting processed yarn, and said number was evaluated with the following basis. These results were shown in Table 3. AAA : The number of measured fluff was 0. AA : The number of measured fluff was 1. A : The number of measured fluff was 2 to 5. B : The number of measured fluff was 6 to 9. C : The number of measured fluff was more than 10 . • Evaluation of the yarn break In said false -twisting process, the number of times of the yarn break generated during the continuous operation for 25 days was converted to the number of times per hour, and evaluated with the following basis. These results were shown in Table 3. AAA : The number of times of the generated yarn break was 0 . AA : The number of times of the generated yarn break was less than 1, (but excluding 0). A : The number of times of the generated yarn break was not less than 1 but less than 2. B : The number of times of the generated yarn break was not less than 2 but less than 3. C : The number of times of the generated yarn break was not less than 3. In Table 3 , the adhesion amount was the adhesion % of the agent for processing synthetic fibers to the synthetic fibers. The above - explained present invention has, as clearly shown above, effects capable of dealing with the problem accompanied with the high speed in the spinning process or the textured process of the synthetic fibers in recent years, and preventing the generation of the fluff or the yarn break sufficiently. We claim: 1. An agent for processing synthetic fibers characterized in that, the agent comprises a lubricant, a functional agent as defined herein under and also an emulsifier, such as herein described wherein (a) the contents of the lubricant, the functional agent and the emulsifier are 50 to 90 % by weight, 1 to 30 % by weight and 2 to 30 % by weight respectively, (b) the said lubricant is one or more than two lands selected from a fatty ester compound having 17-60 carbon atoms, a polyether compound having an average molecular weight of 700 to 10000, and a mineral oil having viscosity of 1 X 10-6 to 5 X10-5m2/sat30°C,and (c) 0.05 to 20 % by weight of a phosphoric compound shown by following Formula 1 is contained as at least a part of the functional agent, [Formula 1] where R1, R2 and R3 are simultaneously the same or different alkyl group having 1 to 24 carbon atoms, alkenyl group having 2 to 24 carbon atoms or organic group shown by following Formula 2, and at least one of said R1, R2 and R3 is the organic group shown by following Formula 2, [Formula 2] -A-O-H where A is a residual group obtained by removing all hydroxyl groups from (poly) alkyleneglycol having a (poly) oxyalkylene group composed of total 1 to 50 oxyalkylene units having 2 to 4 carbon atoms. 2. The agent for processing synthetic fibers as claimed in claim 1, wherein the phosphoric compound shown by Formula 1 is such mat A in Formula 2 is the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having a polyoxyalkylene group composed of 2 to 15 oxyalkylene units having 2 or 3 carbon atoms. 3. The agent for processing synthetic fibers as claimed in claim 2, wherein the polyalkyleneglycol is polyethyleneglycol. 4. The agent for processing synthetic fibers as claimed in claim 1, wherein the agent contains 0.8 to 15 % by weight of the phosphoric compound shown by Formula 1. 5. A method for processing synthetic fibers characterized in: that the method comprises a step of adhering an agent for processing synthetic fibers defined hereunder to running spun synthetic fiber yarns at a synthetic fiber spinning process to have 0.1 to 3 % by weight of the agent with respect to the running synthetic fiber yams, that the agent for processing synthetic fibers contains a lubricant, a functional agent and an emulsifier defined hereunder, that contents of the lubricant, the functional agent and the emulsifier are 50 to 90 % by weight, 1 to 30 % by weight and 2 to 30 % by weight respectively, that the lubricant is one or more than two kinds selected from a fatty ester compound having 17-60 carbon atoms, a polyether compound having an average molecular weight of 700 to 10000, and a mineral oil having viscosity of 1 X 10-6 to 5 X 10-5 m2/s at 30 oC, and that 0.05 to 20 % by weight of a phosphoric compound shown by following Formula 1 is contained as at least a part of the functional agent, where R1, R2 and R3 are simultaneously the same or different alkyl group having 1to 24 carbon atoms, alkenyl group having 2 to 24 carbon atoms or organic group shown by following Formula 2, and at least one of said R1, R2 and R3 is the organic group shown by following Formula 2,. [Formula 2] -A-O-H where A is a residual group obtained by removing all hydroxyl groups from (poly) alkyleneglycol having a (poly) oxyalkylene group composed of total I to 50 oxyalkylene units having 2 to 4 carbon atoms. 6. The method for processing synthetic fibers as claimed in claim 5, wherein the agent for processing synthetic fibers contains such a phosphoric compound that A in Formula 2 is the residual group obtained by removing all hydroxyl groups from polyalkyleneglycol having a polyoxyalkylene group composed of 2 to 15 oxyalkylene units having 2 or 3 carbon atoms. 7. The method for processing synthetic fibers as claimed in claim 5, wherein the agent for processing synthetic fibers contains 0.8 to 15 % by weight of the phosphoric compound shown by Formula 1. 8. The method for processing synthetic fibers as claimed in claim 7, wherein the method comprising steps of making an aqueous solution of the agent for processing synthetic fibers and adhering said aqueous solution to the running synthetic fiber yarns to have 0.1 to 3 % by weight of the agents for processing synthetic fibers. 9. The method for processing synthetic fibers as claimed in claim 8, wherein the synthetic fibers are polyester fibers or polyamide fibers. To provide an agent for processing synthetic fibers and a method for processing the synthetic fibers, wherein the agent contains a lubricant and a functional agent, and also contains 0.05 to 20 % by weight of a specific phosphoric ester as at least a part of said functional agent, and said phosphoric ester has one to three residual groups obtained by removing all hydroxyl groups from (poly) alkyleneglycol having a (poly) oxyalkylene group composed of 1-50 oxyalkylene units with 2-4 carbon atoms, in the ester molecular.

Documents:

138-KOL-2004-CORRESPONDENCE.pdf

138-kol-2004-granted-abstract.pdf

138-kol-2004-granted-assignment.pdf

138-kol-2004-granted-claims.pdf

138-kol-2004-granted-correspondence.pdf

138-kol-2004-granted-description (complete).pdf

138-kol-2004-granted-examination report.pdf

138-kol-2004-granted-form 1.pdf

138-kol-2004-granted-form 13.pdf

138-kol-2004-granted-form 18.pdf

138-kol-2004-granted-form 2.pdf

138-kol-2004-granted-form 3.pdf

138-kol-2004-granted-form 5.pdf

138-kol-2004-granted-gpa.pdf

138-kol-2004-granted-priority document.pdf

138-kol-2004-granted-reply to examination report.pdf

138-kol-2004-granted-specification.pdf

138-kol-2004-granted-translated copy of priority document.pdf

138-KOL-2004-OTHERS.pdf