Title of Invention

COMPOSITIONS COMPRISING SUBSTITUTED CYCLE KETOENOLS AND AT LEAST ONE COMPOUND WHICH IMPROVES CROP PLANT COMPATIBILITY.

Abstract

The present invention relates to selective herbicidal compositions comprising an effective amount of an active compound combination comprising (a) at least one substituted cyclic ketoenol of the formula (I) V (i) in which X, Z, W and Y and the group CKE are as defined in the description, and (b) at least one compound which improves crop plant compatibility selected from the group of compounds listed in the description, in particular cloquintocet- mexyl and mefenpyr-diethyl. The invention furthermore relates to the use of these compositions as herbicides and to a method for controlling undesirable vegetation using these compositions.

Full Text

FORM 2 THE PATENTS ACT 1970 [39 OF 1970] COMPLETE SPECIFICATION [See Section 10] "SELECTIVE HERBICIDES BASED ON SUBSTITUTED CYCLIC KETOENOLS AND SAFENERS" BAYER AKTIENGESELLSCHAFT, a body corporate organised under the laws of Germany, of D-51368 Leverkusen, Germany, The following specification particularly describes the nature of the invention and the manner in which it is to be performed:- Le A 35 591-Foreign Countries Lu/ngb/NT -1 - Selective herbicides based on substituted cyclic ketoenols and safeners The invention relates to novel selective herbicidal active compound combinations which comprise substituted cyclic ketoenols, on the one hand, and at least one compound which improves crop plant compatibility, on the other, and which can be 5 used with particularly good results for the selective control of weeds in various crops of useful plants. Unsubstituted bicyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-355 599, EP-A-415 211 and JP 12-053 670) and substituted monocyclic 3-arylpyrrolidine-2,4- 10 dione derivatives (EP-A-377 893 and EP-A-442 077) having herbicidal action are already known. Also known are polycyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-442 073) and lH-arylpyrrolidinedione derivatives (EP-A-456 063, EP-A-521 334, 15 EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/16748, WO 99/24437, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972 and WO 01/23354). 20 Also known are 3-aryl-D3-dihydrofuranone derivatives having herbicidal properties, from EP-A-528 156, EP-A-0 647 637, WO 95/26 345, WO 96/20 196, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 98/05638, WO 98/25928, WO 99/16748, WO 99/43649, WO 99/48869, 25 WO 99/55673, JP 12-239 276 and WO 01/17972. 3-Aryl-A3-dihydrothiophenone derivatives, too, are known (WO 95/26 345, WO 96/25 395, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 98/05638, WO 98/25928, WO 99/16748, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/23354). Le A 35 591-Foreign Countries -2- Phenylpyrone derivatives which are substituted in the phenyl ring and have herbicidal properties are described in EP-A-588 137, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/16 436, WO 97/19 941, WO 97/36 868, WO 98/05638, WO 99/43649, WO 99/48869, WO 99/55673 and WO 01/17972. 5 It is known that certain substituted 2-arylcyclopentanediones have herbicidal properties (cf. for example, US-4 283 348; 4 338 122; 4 436 666; 4 526 723; 4 551547; 4 632 698; WO 96/01798; WO 96/03 366, WO 97/14 667 and also WO 98/39281, WO 99/43649, WO 99/48869, WO 99/55673 and WO 01/17972). 10 Moreover, it is known that certain substituted 2-arylcyclohexanediones have herbicidal and acaricidal properties (US-4 175 135, 4 209 432, 4 256 657, 4 256 658, 4 256 659, 4 257 858, 4 283 348, 4 303 669, 4 351666, 4 409 153, 4 436 666, 4 526 723, 4 613 617, 4 659 372, DE-A 2 813 341, and also Wheeler, T.N., J. Org. 15 Chem. 44, 4906 (1979), WO 99/43649, WO 99/48869, WO 99/55673 and WO 01/17972). However, the activity of these compounds and/or their compatibility with crop plants are not under all conditions entirely satisfactory. 20 Surprisingly, it has now been found that certain substituted cyclic ketoenols, when used together with the compounds (safeners/antidotes) described below which improve crop plant compatibilty, prevent damage to the crop plants extremely well and can be used particularly advantageously as broad-spectrum combination preparations for the 25 selective control of undesirable plants in crops of useful plants, such as, for example, in cereals, but also in maize, soya beans and rice. The invention provides selective herbicidal combinations comprising an effective amount of an active compound combination comprising 30 (a) at least one substituted cyclic ketoenol of the formula (I) Le A 35 591-Foreign Countries -3- (I) in which X represents halogen, alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkylthio, 5 alkylsulphinyl, alkylsulphonyl, haloalkyl, haloalkoxy, haloalkenyloxy, nitro or cyano, Z represents hydrogen, in each case optionally substituted alkenyl, alkinyl, aryl or represents hetaryl, 10 W and Y independently of one another represent hydrogen, halogen, alkyl, alkoxy, alkenyloxy, haloalkyl, haloalkoxy, haloalkenyloxy, nitro or cyano, with the proviso that, if Y represents 4-methyl, W and X do not simultaneously 15 represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl, CKE represents one of the groups 20 0-G A. B O ^ (2), Le A 35 591-Foreign Countries (3), A D 0: •^ L^ 0 0 (4), A B Q3 (5) or O! (6), 10 represents hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, saturated or unsaturated, optionally substituted cycloalkyl, in which optionally at least one ring atom is replaced by a heteroatom, or in each case optionally halogen-, alkyl-, haloalkyl-, alkoxy-, haloalkoxy-. cyano- or nitro-substituted aryl, arylalkyl or hetaryl, B represents hydrogen, alkyl or alkoxyalkyl, or 15 A and B together with the carbon atom to which they are attached represent a saturated or unsaturated, unsubstituted or substituted cycle which optionally contains at least one heteroatom, 20 D represents hydrogen or an optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkoxyalkyl, saturated or unsaturated cycloalkyl, in which optioinally one or more ring members are replaced by heteroatoms, arylalkyl, aryl, hetarylalkyl or hetaryl, or Le A 35 591-Foreign Countries -5 A and D together with the atoms to which they are attached represent a saturated or unsaturated cycle which is unsubstituted or substituted in the A,D moiety and optionally contains at least one heteroatom, or A and Q1 together represent alkanediyl or alkenediyl which are in each case 5 optionally substituted by hydroxyl or by in each case optionally substituted alkyl, alkoxy, alkylthio, cycloalkyl, benzyloxy or aryl, or Q1 represents hydrogen or alkyl, 10 Q2, Q4, Q5 and Q6 independently of one another represent hydrogen or alkyl, Q3 represents hydrogen, alkyl, alkoxyalkyl, alkylthioalkyl, optionally substituted cycloalkyl (in which optionally one methylene group is replaced by oxygen or sulphur) or optionally substituted phenyl, or 15 Q3 and Q4 together with the carbon atom to which they are attached, represent a saturated or unsaturated, unsubstituted or substituted cycle which optionally contains a heteroatom, 20 G represents hydrogen (a) or represents one of the groups O L ^ -^R1 (b), ^M'R2(c), /S°^R3(d), 7/V (e), \ / E(f) or )r-^ 7 (9), L R in which 25 E represents a metal ion equivalent or an ammonium ion, Le A 35 591-Foreign Countries 6- L represents oxygen or sulphur, M represents oxygen or sulphur, 5 Rl represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen-, alkyl- or alkoxy-substituted cycloalkyl, which may be interrupted by at least one heteroatom, represents in each case optionally substituted 10 phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, R2 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or represents in each case optionally substituted cycloalkyl, phenyl or benzyl, 15 R^, R4 and R^ independently of one another represent in each case optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio and represent in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio, 20 R6 and R^ independently of one another represent hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, represent optionally substituted phenyl, represent optionally substituted benzyl, or together with the N atom to which 25 they are attached represent a cycle which is optionally interrupted by oxygen or sulphur, including all possible tautomeric forms of the compounds of the general formula (I) and the possible salts or acid or base adducts of the compounds of 30 the general formula (I) - and Le A 35 591-Foreign Countries -7- (b) at least one compound which improves crop plant compatibility, from the group of compounds below: 5 4-dichloroacetyl-l-oxa-4-aza-spiro[4.5]-decane (AD-67, MON-4660), 1-dichloro- acetyl-hexahydro-3,3,8a-trimethylpyrrolo[ 1,2-a]-pyrimidin-6(2H)-one (dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-l,4-benzoxazine (benoxa-cor), 1-methyl-hexyl 5-chloro-quinolin-8-oxy-acetate (cloquintocet-mexyl - cf. also related compounds in EP-A-86750, EP-A-94349, EP-A-191736, EP-A-492366), 3- 10 (2-chloro-benzyl)-l-(l-methyl-l-phenyl-ethyl)-urea (cumyluron), a-(cyano- methoximino)-phenylacetonitrile (cyometrinil), 2,4-dichloro-phenoxyacetic acid (2,4-D), 4-(2,4-dichloro-phenoxy)-butyric acid (2,4-DB), l-(l-methyl-l-phenyl-ethyl)-3-(4-methyl-phenyl)-urea (daimuron, dymron), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), S-l -methyl-1-phenyl-ethyl piperidine-1-thiocarboxylate (dimepiperate), 15 2,2-dichloro-N-(2-oxo-2-(2-propenylamino)-ethyl)-N-(2-propenyl)-acetamide (DKA- 24), 2,2-dichloro-N,N-di-2-propenyl-acetamide (dichlormid), 4,6-dichloro-2-phenyl-pyrimidine (fenclorim), ethyl l-(2,4-dichloro-phenyl)-5-trichloromethyl-lH-l,2,4-triazole-3-carboxylate (fenchlorazole-ethyl - cf. also related compounds in EP-A-174562 and EP-A-346620), phenylmethyl 2-chloro-4-trifluoromethyl-thiazole- 20 5-carboxylate (flurazole), 4-chloro-N-(l,3-dioxolan-2-yl-methoxy)-a-trifluoro- acetophenone oxime (fluxofenim), 3-dichloroacetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidine (furilazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl - cf. also related compounds in WO-A-95/07897), l-(ethoxycarbonyl)-ethyl 3,6-dichloro-2-methoxybenzoate 25 (lactidichlor), (4-chloro-o-tolyloxy)-acetic acid (MCPA), 2-(4-chloro-o-tolyloxy)- propionic acid (mecoprop), diethyl l-(2,4-dichloro-phenyl)-4,5-dihydro-5-methyl-lH-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl - cf. also related compounds in WO-A-91/07874), 2-dichloromethyl-2-methyl-l,3-dioxolane (MG-191), 2-propenyl-l-oxa-4-azaspiro[4.5]decane 4-carbodithioate (MG-838), 1,8-naphthalic anhydride, 30 a-(l,3-dioxolan-2-yl-methoximino)-phenylacetonitrile (oxabetrinil), 2,2-dichloro-N- (1,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamide (PPG-1292), 3-dichloroacetyl- Le A 35 591-Foreign Countries -8- 2,2-dimethyl-oxazolidine (R-28725), 3-dichloroacetyl-2,2,5-trimethyl-oxazolidine (R-29148), 4-(4-chloro-o-tolyl)-butyric acid, 4-(4--chloro-phenoxy)-butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, ethyl diphenyl-methoxyacetate, methyl l-(2-chloro-phenyl)-5-phenyl-lH-pyrazole-3-carboxylate, 5 ethyl l-(2,4-dichloro-phenyl)-5-methyl-lH-pyrazole--3-carboxylate, ethyl l-(2,4- dichloro-phenyl)-5-isopropyl-lH-pyrazole-3-carboxylate, ethyl l-(2,4-dichloro-phenyl)-5-(l, 1 -dimethyl-ethyl)- lH-pyrazole-3-carboxylate, ethyl 1 -(2,4-dichloro-phenyl)-5-phenyl-lH-pyrazole-3-carboxylate (cf. also related compounds in EP-A-269806 and EP-A-333131), ethyl 5-(2,4-dichloro-benzyl)-2-isoxazoline-3- 10 carboxylate, ethyl 5-phenyl-2-isoxazoline-3-carboxylate, ethyl 5-(4-fluoro-phenyl)-5- phenyl-2-isoxazoline-3-carboxylate (cf. also related compounds in WO-A-91/08202), 1,3-dimethyl-but-l-yl 5-chloro-quinolin-8-oxy-acetate, 4-allyloxy-butyl 5-chloro-quinolin-8-oxy-acetate, l-allyloxy-prop-2-yl 5-chloro-quinolin-8-oxy-acetate, methyl 5-chloro-quinoxalin-8-oxy-acetate, ethyl 5-chloro-quinolin-8-oxy-acetate, allyl 5- 15 chloro-quinoxalin-8-oxy-acetate, 2-oxo-prop-l-yl 5-chloro-quinolin-8-oxy-acetate, diethyl 5-chloro-quinolin-8-oxy-malonate, diallyl 5-chloro-quinoxalin-8-oxy-malonate, diethyl 5-chloro-quinolin-8-oxy-malonate (cf. also related compounds in EP-A-582198), 4-carboxy-chroman-4-yl-acetic acid (AC-304415, cf. EP-A-613618), 4-chloro-phenoxy-acetic acid, 3,3' -dimethyl-4-methoxy-benzophenone, l-bromo-4- 20 chloromethylsulphonyl-benzene, 1 -[4-(N-2-methoxybenzoylsulphamoyl)-phenyl]-3- methyl-urea (alias N-(2-methoxy-benzoyl)-4-[(methylamino-carbonyl)-amino]- benzenesulphonamide), l-[4-(N-2-methoxybenzoylsulphamoyl)-phenyl]-3,3- dimethyl-urea, 1 -[4-(N-4,5-dimethylbenzoylsulphamoyl)-phenyl]-3-methyl-urea, 1 -[4-(N-naphthylsulphamoyl)-phenyl]-3,3-dimethyl-urea, N-(2-methoxy-5-methyl- 25 benzoyl)-4-(cyclopropylaminocarbonyl)-benzenesulphonamide, and/or one of the following compounds defined by general formulae of the general formula (IIa) 30 Le A 35 591-Foreign Countries -9 (X)n- r^, 0 A 8 (na) *A1 ^R8 or of the general formula (lib) (Hb) or the formula (lie) O 12 R10^ ^ R R 11 (He) where 10 n represents a number between 0 and 5, A represents one of the divalent heterocyclic groupings shown below OR14 R 15 03. o 13 R 13' :N 15. / (CH2)n R // O—N A2 represents optionally Ci-C4-alkyl- and/or Ci-C4-alkoxy-carbonyl-substituted alkanediyl with 1 or 2 carbon atoms, Le A 35 591-Foreign Countries -10 R8 represents hydroxyl, mercapto, amino, Ci-C6-alkoxy, Ci-C6-alkylthio, Cj-C6-alkylamino or di-(Ci-C4-alkyl)-amino, R9 represents hydroxyl, mercapto, amino, Ci-C6-alkoxy, Ci-C6-alkylthio, C]-C6- 5 alkylamino or di-(Ci-C4-alkyl)-amino, R10 represents in each case optionally fluorine-, chlorine- and/or bromine-substituted Ci-C4-alkyl, 10 R11 represents hydrogen, in each case optionally fluorine-, chlorine- and/or bromine-substituted Ci-C6-alkyl, C2-C6-alkenyl or C2-C6-alkinyl, d-C4-alkoxy-C]-C4-alkyl, dioxolanyl-C]-C4-alkyl, furyl, furyl-Ci-C4-alkyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine- and/or bromine- or Ci-C4-alkyl-substituted phenyl, 15 R represents hydrogen, in each case optionally fluorine-, chlorine- and/or bromine-substituted Ci-C6-alkyl, C2-C6-alkenyl or C2-C6-alkinyl, Ci-C4-alkoxy-Ci-C4-alkyl, dioxolanyl-C]-C4-alkyl, furyl, furyl-Ci-C4-alkyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine- and/or bromine- or Ci-C4-alkyl- 20 substituted phenyl, or together with R1' represents C3-C6-alkanediyl or C2-C5- oxaalkanediyl, each of which is optionally substituted by C]-C4-alkyl, phenyl, furyl, a fused-on benzene ring or by two substituents which together with the C atom to which they are attached form a 5- or 6-membered carbocycle, 25 R represents hydrogen, cyano, halogen, or represents in each case optionally fluorine-, chlorine- and/or bromine-substituted Ci-C4-alkyl, C3-C6-cycloalkyl or phenyl, R14 represents hydrogen, optionally hydroxyl-, cyano-, halogen- or Ci-C4-alkoxy- 30 substituted CrC6-alkyl, C3-C6-cycloalkyl or tri-(Ci-C4-alkyl)-silyl, Le A 35 591-Foreign Countries -11 R15 represents hydrogen, cyano, halogen, or represents in each case optionally fluorine-, chlorine- and/or bromine-substituted Ci-C4-alkyl, C3-C6-cycloalkyl or phenyl, 5 X1 represents nitro, cyano, halogen, C]-C4-alkyl, Ci-C4-haloalkyl, d-C4-alkoxy or Ci-C4-haloalkoxy, X represents hydrogen, cyano, nitro, halogen, Ci-C4-alkyl, Ci-C4-haloalkyl, 10 15 Ci-C4-alkoxy or Ci-C4-haloalkoxy, X3 represents hydrogen, cyano, nitro, halogen, Ci-C4-alkyl, Ci-C4-haloalkyl, C]-C4-alkoxy or d-C4-haloalkoxy, and/or the following compounds defined by general formulae of the general formula (Ed) R rll8 ^MX )n Rie ^ -(x4)n SO, O (lid) 20 or of the general formula (He) O (x5)n R' R' 20 [I A I SO, r^N -(x4)n (He) where Le A 35 591-Foreign Countries -12 n represents a number between 0 and 5, R16 represents hydrogen or C1-C4-alkyl, 1 7 R represents hydrogen or C1-C4-alkyl, 1 O R represents hydrogen, in each case optionally cyano-, halogen- or C1-C4-alkoxy- substituted C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylamino or di- 10 (C1-C4-alkyl)-amino, or in each case optionally cyano-, halogen- or Ci-C4-alkyl- substituted C3-C6-cycloalkyl, C3-C6-cycloalkyloxy, C3-C6-cycloalkylthio or C3-C6-cycloalkylamino, R19 represents hydrogen, optionally cyano-, hydroxyl-, halogen- or d-C4-alkoxy- 15 substituted Ci-C6-alkyl, in each case optionally cyano- or halogen-substituted C3-C6-alkenyl or C3-C6-alkinyl, or optionally cyano-, halogen- or C1-C4-alkyl-substituted C3-C6-cycloalkyl, 20 R represents hydrogen, optionally cyano-, hydroxyl-, halogen- or C1-C4-alkoxy- 20 substituted C1-C6-alkyl, in each case optionally cyano- or halogen-substituted C3-C6-alkenyl or C3-C6-alkinyl, optionally cyano-, halogen- or C1-C4-alkyl- substituted C3-C6-cycloalkyl, or optionally nitro-, cyano-, halogen-, C1-C4 alkyl-, C1-C4-haloalkyl-, C1-C4-alkoxy- or C1-C4-haloalkoxy-substituted phenyl, or together with R19 represents in each case optionally C1-C4-alkyl-substituted 25 C2-C6-alkanediyl or C2-Cs-oxaalkanediyl, X represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy, and Le A 35 591-Foreign Countries 13 X5 represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy. In the definitions, the hydrocarbon chains, such as an alkyl or alkanediyl, are in each case straight-chain or branched - including in combination with heteroatoms, such as in alkoxy. 10 15 Depending inter alia on the nature of the substituents, the compounds of the formula (I) can be present as geometrical and/or optical isomers or isomer mixtures of varying composition which, if appropriate, can be separated in a customary manner. The present invention provides both the pure isomers and the isomer mixtures, and their use and the compositions comprising them. However, for the sake of simplicity, hereinbelow only compounds of the formula (I) are referred to, although what is meant are both the pure compounds and, if appropriate, also mixtures having various proportions of isomeric compounds. Including the meanings (1) to (6) of the groupe CKE, the following principal structures (1-1) to (1-6) result: 20 ,G 0 X A, J y B' N~ > / o w (1-1), (I-2), o w (I-3), Le A 35 591-Foreign Countries 14- Q '6 W (1-5), Q° Q in which A, B, D, G, Q1, Q2, Q3, Q4, Q5, Q6, W, X, Y and Z are as defined above. Including the different meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-l-a) to (I-l-g) result if CKE represents the group (1), (I-l-b): A D (I-l-c): (I-l-d): R2-M R -SCL-0 /= '=0 X E-0 /={^Y (M-e): (I-l-f): A D N B- Le A 35 591-Foreign Countries -15 (I-l-g): A yDB—I-N' / ° 7 V°R7-N V in which A, B, D, E, L, M, W, X, Y, Z, Rl, R2, R3, R4 R5; R6 and R7 are as defined above. Including the different meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-2-a) to (I-2-g) result if CKE represents the group (2) 0 W (I-2-b): O W (I-2-c): (I-2-d): II O — C-M-FT A / X O W B- 0-S02-RJ A / X o w Le A 35 591-Foreign Countries -16- (I-2-e): 0 W (I-2-g): RD O-C-N O W in which A, B, E, L, M, W, X, Y, Z, R1, R2, R3, R4, R5, R6 and R7 are as defined above. Including the different meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-3-a) to (I-3-g) result if CKE represents the group (3) O W (I-3-b): 0 W Le A 35 591-Foreign Countries 17 (I-3-c): (I-3-d): L II O-C-M-R A / X O W O-SCL-R A / X 0 W (I-3-e): L \\ R4 n-p X 5 / x R o w 0 W (I-3-g): R° O W 10 in which A, B, E, L, M, W, X, Y, Z, R1, R2, R3, R4, R5, R6 and R? are as defined above. Depending on the position of the substituent G, the compounds of the formula (1-4) can be present in the two isomeric forms of the formulae (1-4-A) and (I-4-B) Le A 35 591-Foreign Countries -18 0 W O W (I-4-A) (I-4-B) which is meant to be indicated by the broken line in formula (1-4). The compounds of the formulae (1-4-A) and (I-4-B) can be present both as mixtures 5 and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-4-A) and (I-4-B) can, if appropriate, be separated in a manner known per se by physical methods, for example by chromatographic methods. For reasons of clarity, hereinbelow only one of the possible isomers is shown in each 10 case. This does not exclude that the compounds may, if appropriate, be present in the form of the isomer mixtures or in the respective other isomeric form. Including the different meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-4-a) to (I-4-g) result if CKE represents the group (4) 15 (I-4-b): D A-f Vo o w z Le A 35 591-Foreign Countries 19 (I-4-c): (I-4-d): R-S02-0 Y R5" I' (I-4-e): (I-4-f): D E-0 N' W (I-4-g): in which A, D, E, L, M, W, X, Y, Z, R1, R2, R3, R4, R5, R6 and R? are as defined above. Depending on the position of the substituent G, the compounds of the formula (1-5) can be present in the two isomeric forms of the formulae (I-5-A) and (I-5-B) Le A 35 591-Foreign Countries 20 A O X (I-5-B) which is meant to be indicated by the broken line in the formula (1-5). The compounds of the formulae (I-5-A) and (I-5-B) can be present both as mixtures 5 and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-5-A) and (I-5-B) can, if appropriate, be separated by physical methods, for example by chromatographic methods. For reasons of clarity, hereinbelow only one of the possible isomers is shown in each 10 case. This does not exclude that the compounds may, if appropriate, be present in the form of the isomer mixtures or in the respective other isomeric form. Including the different meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-5-a) to (I-5-g) result: 15 (I-5-a): (I-5-b): Q1 Q2 O W Le A 35 591-Foreign Countries 21 - (I-5-c): (I-5-d): Y Z w L n A O-C-M-R x / w .Y A C)-S02-RJ X B- O Q1' Qz (I-5-f): A P'P\R5 X W B- Q1 Q O-E I 2 O w (I-5-g): ,2 O W in which A, B, Q1, Q2, E, L, M, W, X, Y, Z, R1, R2, R3, R4, R5, R6 and R7 are as defined 5 above. Depending on the position of the substituent G, the compounds of the formula (1-6) can be present in the two isomeric forms of the formulae (1-6-A) and (I-6-B) which is meant to be indicated by the broken line in the formula (1-6): 10 Le A 35 591-Foreign Countries 22- O X G D t 0 X B^ / \ °Z o^y-tyi z Q Q6 0 W (I-6-A) 10 The compounds of the formulae (I-6-A) and (I-6-B) can be present both as mixtures and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-6-A) and (I-6-B) may, if appropriate, be separated by physical methods, for example by chromatographic methods. For reasons of clarity, hereinbelow only one of the possible isomers is shown in each case. This includes that the compound in question may, if appropriate, be present as an isomer mixture or in the respective other isomeric form. Including the different meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-6-a) to (I-6-g) result: (I-6-a): (I-6-b): ,4 QJA ^ Q3A Le A 35 591-Foreign Countries -23- (I-6-c): (I-6-d): R-MQ ^ Q3A QV?YB (I-6-e): (I-6-f): (I-6-g): in which A, B, E, L, M, Q3, Q4, Q5, Q6, W, X, Y, Z, R1, R2, R3, R4, R5, R6 and R7 are as defined above. The formula (I) provides a general definition of the substituted cyclic ketoenols according to the invention of the herbicidal compositions. Preferred substituents and Le A 35 591-Foreign Countries -24- ranges of the radicals given in the formulae mentioned above and below are illustrated below: X preferably represents halogen, Ci-C6-alkyl, C2-C6-alkenyl, Cj-Q-haloalkyl, 5 Ci-C6-alkoxy, C3-C6-alkenyloxy, Ci-C6-haloalkoxy, C3-C6-haloalkenyloxy, nitro or cyano, Z preferably represents hydrogen, C2-C6-alkenyl, C2-C6-alkinyl or represents one of the radicals 10 V3 S 3 in which 15 V1 represents hydrogen, halogen, C1-C12-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulphinyl, C1-C6-alkylsulphonyl, C1-C4-haloalkyl, C1-C4- haloalkoxy, nitro or cyano, 20 V2 and V3 independently of one another represent hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy, W and Y independently of one another preferably represent hydrogen, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, nitro or 25 cyano, Le A 35 591-Foreign Countries 25- with the proviso that, if Y represents 4-methyl, W and X do not simultaneously represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl. CKE preferably represents one of the groups D A B A B / O" (4), 10 15 preferably represents hydrogen or in each case optionally halogen-substituted C1-C12-alkyl, C3-C8-alkenyl, C1-C10-alkoxy-C1-C8-alkyl, C1-C10-alkylthio- C1-C6-alkyl, optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-Cg-cycloalkyl, in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-haloalkyl-, C1-C6-alkoxy-, C1-C6-haloalkoxy-, cyano- or nitro-substituted phenyl or phenyl- C1-C6-alkyl. 20 B preferably represents hydrogen, C1-C12-alkyl or C1-C8-alkoxy- C1-C6-alkyl, or Le A 35 591-Foreign Countries -26- A, B and the carbon atom to which they are attached preferably represent saturated C3-C10-cycloalkyl or unsaturated C5-C10-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which are optionally mono- or disubstituted by C1-C8-alkyl, C3-C10-cycloalkyl, C1-C8-haloalkyl, 5 C1-C8-alkoxy, C1-C8-alkylthio, halogen or phenyl, or A, B and the carbon atom to which they are attached preferably represent C3-C6- cycloalkyl which is substituted by an alkylenediyl or by an alkylenedioxyl or by an alkylenedithioyl group which, with the carbon atom to which it is 10 attached, forms a further five- to eight-membered ring and which is optionally substituted by C1-C4alkyl which optionally contain one or two not directly adjacent oxygen and/or sulphur atoms, or A,B 15 and the carbon atom to which they are attached preferably represent C3-C8- cycloalkyl or C5-C8-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent in each case optionally C1-C6-alkyl-, C1-C6-alkoxy- or halogen-substituted C2-C6-alkanediyl, C2-Cg-alkenediyl or C4-C6-alkanedienediyl in which optionally one methylene group is replaced by oxygen or sulphur. 20 D preferably represents hydrogen, in each case optionally halogen-substituted C1-C12-alkyl, C3-C8-alkenyl, C3-C8-alkinyl, C1-C10-alkoxy-C2-C8-alkyl, optionally halogen-, C1-C4-alkyl-, C1-C4-alkoxy- or C1-C4-haloalkyl-substituted C3-Cg-cycloalkyl, in which optionally one ring member is replaced by oxygen or sulphur or in each case optionally halogen-, C1-C6-alkyl-, C1-C6-haloalkyl-, C1-C6-alkoxy-, C1-C6-haloalkoxy-, cyano- or nitro-substituted phenyl or phenyl- C1-C6-alkyl. A and D together preferably represent in each case optionally substituted C3-C6- 30 alkanediyl or C3-C6-alkenediyl in which optionally one methylene group is replaced by a carbonyl group, by oxygen or by sulphur, Le A 35 591-Foreign Countries -27- possible substituents being in each case: halogen, hydroxyl, mercapto or in each case optionally halogen-substituted C1-C10-alkyl or C1-C6-alkoxy, or a further C3-C6-alkanediyl grouping, C3- C6-alkenediyl grouping or a butadienyl grouping which is optionally 5 substituted by C1-C6-alkyl or in which optionally two adjacent substituents together with the carbon atoms to which they are attached form a further saturated or unsaturated cycle having 5 or 6 ring atoms (in the case of the compound of the formula (1-1), A and D together with the atoms to which they are attached then represent, for example, the groups AD-1 to AD 10 10 mentioned further below), which may contain oxygen or sulphur. 15 20 A and Q1 together preferably represent C3-C6-alkanediyl or C4-C6-alkenediyl, each of which is optionally mono- or disubstituted by identical or different halogens, by C1-C10-alkyl, C1-C6-alkoxy, C1-C6-alkylthio or C3-C7-cycloalkyl, each of which is optionally mono- to trisubstituted by identical or different halogens, or by benzyloxy or phenyl, each of which is optionally mono- to trisubstituted by identical or different substituents from the group consisting of halogen, C1-C6-alkyl and C1-C6-alkoxy in which C3-C6-alkanediyl or C1-C6-alkenediyl is furthermore bridged by a Ci-C2-alkanediyl group or by an oxygen atom, or Q1 preferably represents hydrogen or C1-C4-alkyl. Q2, Q4, Q5 and Q6 independently of one another preferably represent hydrogen or 25 C1-C4-alkyl. Q3 preferably represents hydrogen, C1-C6-alkyl, C1-C6-alkoxy-C1-C2-alkyl, C1-C6-alkylthio-C1-C2-alkyl, optionally halogen-, C1-C4-alkyl- or C1-C4- alkoxy-substituted C3-C8-cycloalkyl in which optionally one methylene group 30 is replaced by oxygen or sulphur or represents optionally halogen-, C1-C4- Le A 35 591-Foreign Countries -28 alkyl-, C1-C4-alkoxy-, C1-C2-haloalkyl-, C1-C2-haloalkoxy-, cyano- or nitro-substituted phenyl, or Q3 and Q4 together with the carbon atom to which they are attached preferably 5 represent an optionally C1-C4-alkyl-, C1-C4-alkoxy- or C1-C2-haloalkyl- substituted C3-C7-ring in which optionally one ring atom is replaced by oxygen or sulphur. preferably represents hydrogen (a) or represents one of the groups R4 .SOz-R3 "P. 5 10 in particular (a), (b), (c) or (g), in which 15 E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur, and M represents oxygen or sulphur. 20 R1 preferably represents in each case optionally halogen-substituted C1-C20-alkyl, C2-C20-alkenyl, C1-C8-alkoxy-C1-C8-alkyl, C1-C8-alkylthio-C1-C8-alkyl, poly- C1-C8-alkoxy- C1-C8-alkyl or optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl, in which optionally one or more 25 (preferably not more than two) not directly adjacent ring members are replaced by oxygen and/or sulphur, Le A 35 591-Foreign Countries 29- represents optionally halogen-, cyano-, nitro-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-haloalkyl-, C1-C6-haloalkoxy-, C1-C6-alkylthio- or C1-C6-alkylsulphonyl-substituted phenyl, 5 represents optionally halogen-, nitro-, cyano-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-haloalkyl- or C1-C6-haloalkoxy-substituted phenyl- C1-C6-alkyl, represents optionally halogen- or C1-C6-alkyl-substituted 5- or 6-membered hetaryl (for example pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl or 10 thienyl), represents optionally halogen- or C1-C6-alkyl-substituted phenoxy- C1-C6-alkyl or 15 represents optionally halogen-, amino- or Ci-Cg-alkyl-substituted 5- or 6- membered hetaryloxy- C1-C6-alkyl (for example pyridyloxy-Ci-Cg-alkyl, pyrimidyloxy- C1-C6-alkyl or thiazolyloxy- C1-C6-alkyl). R2 preferably represents in each case optionally halogen-substituted Ci-C2o- 20 alkyl, C2-C20-alkenyl, C1-C8-alkoxy-C2-C8-alkyl, poly-C1-C8-alkoxy-C2-C8- alkyl, represents optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl or 25 represents in each case optionally halogen-, cyano-, nitro-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-haloalkyl- or C1-C6-haloalkoxy-substituted phenyl or benzyl. Le A 35 591-Foreign Countries -30- R3 preferably represents optionally halogen-substituted C1-C8-alkyl or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4-haloalkyl-, C1-C4-haloalkoxy-, cyano- or nitro-substituted phenyl or benzyl. 5 R4 and R5 independently of one another preferably represent in each case optionally halogen-substituted C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylamino, di- (C1-C8-alkyl)amino, C1-C8-alkylthio, C2-C8-alkenylthio, C3-C7-cyclo- alkylthio or represent in each case optionally halogen-, nitro-, cyano-, Ci-C4- alkoxy-, C1-C4-haloalkoxy-, C1-C4-alkylthio-, C1-C4-haloalkylthio-, C1-C4- 10 alkyl- or C1-C4-haloalkyl-substituted phenyl, phenoxy or phenylthio. R6 and R7 independently of one another preferably represent hydrogen, represent in each case optionally halogen-substituted C1-C8-alkyl, C3-C8-cycloalkyl, C1-C8-alkoxy, C3-C8-alkenyl, C1-C8-alkoxy- C1-C8-alkyl, represent 15 optionally halogen-, C1-C8-haloalkyl-, C1-C8-alkyl- or C1-C8-alkoxy- substituted phenyl, optionally halogen-, C1-C8-alkyl-, C1-C8-haloalkyl- or C1-C8-alkoxy-substituted benzyl or together represent an optionally C1-C4-alkyl-substituted C3-Cg-alkylene radical in which optionally one carbon atom is replaced by oxygen or sulphur. 20 In the radical definitions mentioned as being preferred, halogen represents fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and bromine. X particularly preferably represents fluorine, chlorine, bromine, C1-C4-alkyl, 25 C2-C4-alkenyl, C1-C4alkoxy, trifluoromethyl., trifluoromethoxy, trifluoro- ethoxy or cyano. Z particularly preferably represents hydrogen, C;)-C4-alkenyl, C2-C4-alkinyl or represents the radical 30 Le A 35 591-Foreign Countries 31- V1 particularly preferably represents hydrogen, fluorine, chlorine, bromine, C1-C6-alkyl, C1-C4alkoxy, C1-C2-haloalkyl, C1-C2-haloalkoxy, nitro or 5 cyano. V2 particularly preferably represents hydrogen, fluorine, chlorine, bromine, C1-C4-alkyl, C1-C4-alkoxy, C1-C2-haloalkyl or C1-C2-haloalkoxy. 10 W and Y independently of one another particularly preferably represent hydrogen, fluorine, chlorine, bromine, C1-C4alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy, with the proviso that, if Y represents 4-methyl, W and X do not simultaneously 15 represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl and with the proviso that X does not represent alkenyl if Z does not represent hydrogen, 20 CKE particularly preferably represents one of the groups 0'G n-G (2), (3), °! G Aix • Le A 35 591-Foreign Countries 32 (5), Q" Q 5 Q5 O- QU 0 (6). particularly preferably represents hydrogen, in each case optionally fluorine-or chlorine-substituted C1-C6-alkyl, C1-C4-alkoxy- C1-C4-alkyl or optionally fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy-substituted C3-C7-cycloalkyl. 10 15 B particularly preferably represents hydrogen or C1 -C6-alkyl, or A, B and the carbon atom to which they are attached particularly preferably represent saturated C3-C7-cycloalkyl or unsaturated C5-C7-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally monosubstituted by C1-C6-alkyl, C1-C3-haloalkyl or C1-C6-alkoxy, or 20 A, B and the carbon atom to which they are attached particularly preferably represent Cs-Cg-cycloalkyl which is substituted by an alkylenediyl or by an alkylenedioxy or by an alkylenedithiol group which, together with the carbon atom to which it is attached, forms a further five- or six-membered ring and which is optionally substituted by methyl or ethyl and optionally contains one or two not directly adjacent oxygen or sulphur atoms, or A, B and the carbon atom to which they are attached particularly preferably 25 represent C3-C6-cycloalkyl or C5-C6-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent in each case optionally C1-C5-alkyl-, C1-C5-alkoxy-, fluorine-, chlorine- or bromine- Le A 35 591-Foreign Countries -33- substituted C2-C4-alkanediyl, C2-C4-alkenediyl in which optionally one methylene group is replaced by oxygen or sulphur or represent butadienediyl. D particularly preferably represents hydrogen, represents in each case optionally 5 fluorine- or chlorine-substituted Ci-C6-alkyl, C3-Cg-alkenyl, Ci-C4-alkoxy- C2-C3-alkyl, represents optionally Ci-C4-alkyl-, Ci-C4-alkoxy- or C4-C2- haloalkyl-substituted C3-C7-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur or (but not in the case of compounds of the formula (I-l)) represents in each case optionally fluorine-, chlorine-, 10 bromine-, Ci-C4-alkyl-, Ci-C4-haloalkyl-, C \ -C4-alkoxy- or C4-C4- haloalkoxy-substituted phenyl, pyridyl or benzyl, or A and D together particularly preferably represent optionally substituted C3-C5- alkanediyl in which one methylene group may be replaced by oxygen or 15 sulphur, possible substituents being Ci-C4-alkyl, or I X AD-1 AD-2 AD-3 A and D (in the case of the compounds of the formula (I-l)) together with the atoms to which they are attached represent one of the groups AD-1 to AD-10: Le A 35 591-Foreign Countries 34- AD-4 AD-5 AD-6 AD-8 AD-9 AD-10 A and Q1 together particularly preferably represent C3-C4-alkanediyl or C3-C4-alkenediyl, each of which is optionally mono- or disubstituted by identical or different substituents from the group consisting of Cj^-alkyl and (VC4-alkoxy, or Q1 particularly preferably represents hydrogen. 10 Q2 particularly preferably represents hydrogen. Q4, Q5 and Q6 independently of one another particularly preferably represent hydrogen or C1-C2-alkyl. Q3 particularly preferably represents hydrogen, C1-C4-alkyl, C1-C4-alkoxy- 15 C1-C2-alkyl, C1-C4-alkylthio-C1-C2-alkyl or optionally methyl- or methoxy- substituted C3-C6-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur, or 20 Q3 and Q4 together with the carbon to which they are attached particularly preferably represent an optionally C1-C4-alkyl- or C1-C4-alkoxy-substituted saturated Le A 35 591-Foreign Countries -35 C5-C6-ring in which optionally one ring member is replaced by oxygen or sulphur. G particularly preferably represents hydrogen (a) or represents one of the groups 5 0 L^R1 (b), ^M'R2(C), ^SOT-R3 ^ Z (d), R* // R (e), \ R6E (f) °f WV (g), L R in particular (a), (b) or (c), in which 10 E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur, 15 M represents oxygen or sulphur, R.1 particularly preferably represents in each case optionally fluorine- or chlorine- substituted C1-C16-alkyl, C2-C16-alkenyl, C1-C6-alkoxy- C1-C4-alkyl, C1-C4-alkylthio- C1-C4-alkyl or optionally fluorine-, chlorine-, C1-C4-alkyl- 20 or C1-C4-alkoxy-substituted C3-C7-cycloalkyl in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur, represents optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4- 25 alkyl-, C1-C4-alkoxy-, C1-C3-haloalkyl- or C1-C3-haloalkoxy-substituted phenyl, Le A 35 591-Foreign Countries 36- 10 R^ particularly preferably represents in each case optionally fluorine-substituted C1-C16-alkyl, C2-C16-alkenyl or C1-C6-alkoxy-C2-C6-alkyl, represents optionally fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy-substituted C3-C7-cycloalkyl, represents in each case optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4-alkyl-, Cl-C3-alkoxy-, Cl-C3-haloalkyl- or Cl-C3-haloalkoxy-substituted phenyl or benzyl. R3 particularly preferably represents optionally fluorine-substituted Ci-Cg-alkyl or represents optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C4-alkoxy-, C1-C3-haloalkyl-, C1-C3-haloalkoxy-, cyano- or nitro-substituted phenyl. 15 R4 particularly preferably represents C1-C6-alkyl, C1-C6-alkoxy, C1-C6- alkylamino, di-(C1-C6-alkyl)amino, C1-C6-alkylthio, C3-C4-alkenylthio, C3-C6-cycloalkylthio or represents in each case optionally fluorine-, chlorine-, bromine-, nitro-, cyano-, C1-C3-alkoxy-, Ci-C3-haloalkoxy-, 20 C1-C3-alkylthio-, C1-C3-haloalkylthio-, C1-C3-alkyl- or C1-C3-haloalkyl- substituted phenyl, phenoxy or phenylthio. R5 particularly preferably represents Ci-C6-alkoxy or Ci-C6-alkylthio. 25 R6 particularly preferably represents hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C1-C6-alkoxy, C3-C6-alkenyl, C1-C6-alkoxy- C1-C4-alkyl, represents optionally fluorine-, chlorine-, bromine-, C1-C3-haloalkyl-, C1-C4-alkyl- or C1-C4-alkoxy-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C3-haloalkyl- or C1-C4-alkoxy-substituted 30 benzyl. Le A 35 591-Foreign Countries -37- R.7 particularly preferably represents Ci-C6-alkyl, C3-C6-alkenyl or d-C6-alkoxy-Ci-C4-alkyl. R6 and R7 together particularly preferably represent an optionally methyl- or ethyl- 5 substituted C4-C5-alkylene radical in which optionally one methylene group is replaced by oxygen or sulphur. In the radical definitions mentioned as being particularly preferred, halogen represents fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and 10 bromine. X very particularly preferably represents chlorine, bromine, methyl, ethyl, propyl, vinyl, methoxy, ethoxy, trifluoromethyl, difluoromethoxy, trifluoro-methoxy or cyano. 15 Z very particularly preferably represents hydrogen, vinyl, ethinyl or represents the radical 20 V1 very particularly preferably represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, methoxy, ethoxy, n-propoxy, isopropoxy, trifluoromethyl, trifiuoromethoxy, or cyano. 25 V2 very particularly preferably represents hydrogen, fluorine, chlorine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy, trifluoromethyl or trifiuoromethoxy. Le A 35 591-Foreign Countries 38 W and Y independently of one another very particularly preferably represent hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, methoxy or ethoxy, with the proviso that, if Y represents 4-methyl, W and X do not simultaneously represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl and with the proviso that X does not represent vinyl if Z does not represent hydrogen. CKE very particularly preferably represents one of the groups 10 (D, (2), (3), G O- D O O (4), (5), (6). 15 very particularly preferably represents hydrogen, represents Ci-C4-alkyl or Ci-C2-alkoxy-Ci-C2-alkyl, each of which is optionally mono- to tri-substituted by fluorine, or represents C3-Cg-cycloalkyl which is optionally monosubstituted by fluorine, methyl, ethyl or methoxy. B very particularly preferably represents hydrogen, methyl or ethyl, or Le A 35 591-Foreign Countries -39- A, B and the carbon atom to which they are attached very particularly preferably represent saturated Cs-Cg-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally monosubstituted by methyl, ethyl, propyl, isopropyl, trifluoromethyl, methoxy, ethoxy, propoxy, butoxy or isobutoxy, or A, B and the carbon atom to which they are attached very particularly preferably represent C5-C6-cycloalkyl which is substituted by an alkylenedioxyl group which contains two not directly adjacent oxygen atoms, 10 D very particularly preferably represents hydrogen, represents in each case optionally fluorine- or chlorine-substituted C1-C4-alkyl, C3-C4-alkenyl, C1-C2- alkoxy-C2-C3-alkyl or C3-C6-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur, or (but not in the case of the compounds of the 15 formula (1-1)) represents phenyl or pyridyl, each of which is optionally monosubstituted by fluorine, chlorine, bromine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy, or 20 A and D together very particularly preferably represent optionally substituted C3-C4-alkanediyl in which optionally one carbon atom is replaced by oxygen or sulphur and which is optionally substituted by methyl, or 25 A and D (in the case of compounds of the formula (1-1)) together with the atom to which they are attached represent the group ^N' AD-1 Le A 35 591-Foreign Countries -40- A and Q1 together very particularly preferably represent C3-C4-alkanediyl which is optionally mono- or disubstituted by methyl or methoxy, or 5 Q1 very particularly preferably represents hydrogen. Q2 very particularly preferably represents hydrogen. Q4, Q5 and Q6 independently of one another very particularly preferably represent 10 hydrogen or methyl. Q3 very particularly preferably represents hydrogen, methyl, ethyl or C3-C6-cycloalkyl, or 15 Q3 and Q4 together with the carbon to which they are attached very particularly preferably represent an optionally methyl- or methoxy-substituted saturated C5-C6-ring in which optionally one ring member is replaced by oxygen or sulphur. 20 G very particularly preferably represents hydrogen (a) or represents one of the groups O L ,R4 ^ R (b), ^M (c), ^ ' (d), // R5(e), L' R6 E (f> °r VN^ 7 L ^ 25 in particular (a), (b) or (c), in which Le A 35 591-Foreign Countries -41- E represents a metal ion equivalent or an ammonium ion, L represents oxygen, 5 M represents oxygen or sulphur. Rl very particularly preferably represents C1-C10-alkyl, C2-C10-alkenyl, C1-C4 alkoxy-C1-C2-alkyl, C1-C4-alkylthio-C1-C2-alkyl each of which is optionally mono- to trisubstituted by fluorine or chlorine, or represents 10 C3-C6-cycloalkyl which is optionally mono- or disubstituted by fluorine, chlorine, methyl, ethyl or methoxy, represents phenyl which is optionally mono- or disubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, methoxy, trifluoromethyl or 15 trifluoromethoxy, R2 very particularly preferably represents Ci-Ci()-alkyl, C2-Cio-alkenyl or Ci-C4-alkoxy-C2-C4-alkyl, each of which is optionally mono- to trisubstituted by fluorine, or 20 represents C3-C6-cycloalkyl which is optionally monosubstituted by fluorine, methyl or methoxy, or represents phenyl or benzyl, each of which is optionally mono- or 25 disubstituted by fluorine, chlorine, cyano, nitro, methyl, methoxy, tri- fluoromethyl or trifluoromethoxy. R3 very particularly preferably represents methyl, ethyl, n-propyl, isopropyl, each of which is optionally mono- to trisubstituted by fluorine, or represents phenyl 30 which is optionally monosubstituted by fluorine, chlorine, bromine, methyl, tert-butyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro. Le A 35 591-Foreign Countries 42 R4 very particularly preferably represents C1-C4-alkyl, C1-C4-alkoxy, C1-C4- alkylamino, di-( C1-C4-alkyl)amino, C1-C4-alkylthio or represents phenyl, phenoxy or phenylthio, each of which is optionally monosubstituted by 5 fluorine, chlorine, bromine, nitro, cyano, C1-C2-alkoxy, C1-C2-fluoroalkoxy, C1-C2-alkylthio, C1-C2-fluoroalkylthio or Ci-C3-alkyl. R5 very particularly preferably represents Ci-C3-alkoxy or Ci-C3-alkylthio. 10 R6 very particularly preferably represents hydrogen, represents C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-alkoxy, C3-C4-alkenyl, C1-C4-alkoxy- C1-C4-alkyl, represents phenyl which is optionally mono- or disubstituted by fluorine, chlorine, bromine, trifluoromethyl, methyl or methoxy, represents benzyl which is optionally monosubstituted by fluorine, chlorine, bromine, 15 methyl, trifluoromethyl or methoxy. R7 very particularly preferably represents C1-C4-alkyl, C3-C4-alkenyl or C1-C4-alkoxy-C1-C2-alkyl. 20 R6 and R^ together very particularly preferably represent a C5-Cg-alkylene radical in which optionally one methylene group is replaced by oxygen or sulphur. Most preferred are compounds in which Z represents hydrogen and Y is located in the position para to the group CKE or in which Z represents the group O 25 \ / in the position para or meta to the group CKE. Emphasis is given to compounds in which Y represents 4-alkyl (in particular 4-methyl). Le A 35 591-Foreign Countries -43- The general or preferred radical definitions or illustrations given above can be combined with one another as desired, i.e. including combinations between the respective ranges and preferred ranges. 5 Preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings given above as being preferred (preferable). Particular preference according to the invention is given to the compounds of the 10 formula (I) which contain a combination of the meanings given above as being particularly preferred. Very particular preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings given above as being 15 very particularly preferred. Saturated or unsaturated hydrocarbon radicals such as alkyl or alkenyl can, as far as this is possible, in each case be straight-chain or branched, including in combination with heteroatoms, such as, for example, in alkoxy. 20 Unless indicated otherwise, optionally substituted radicals can be mono- or polysubstituted, where in the case of polysubstitution the substituents can be identical or different. 25 In the following, additional preferred radical definitions in the aryl moiety of the compounds of the formula (I) are mentioned. Compounds of the formula (I) containing these radical definitions form preferred subgroups of the compounds of the formula (I). 30 The following applies for such subgroups: Le A 35 591-Foreign Countries 5 10 15 -44- W preferably represents C1-C6-alkyl or C1-C6-alkoxy, X preferably represents halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogeno-alkyl, C1-C4-halogenoalkoxy or cyano, Y is preferably in the 4-position where it preferably represents hydrogen, halogen, cyano or C1-C4-halogenoalkyl and Z preferably represents hydrogen. W also preferably represents hydrogen, halogen or C1-C6-alkyl, X also preferably represents halogen, C1-C6-alkyl, C1-C6-alkoxy, C4-C4-halogenoalkyl, Ci-C4-halogenoalkoxy or cyano, Y is also preferably in the 4-position where it preferably represents the radical 20 Z preferably also represents hydrogen, V1 preferably also represents halogen, C1-C12-alkyl, C1-C6-alkoxy, C1-C4-halo- genoalkyl or Ci-C4-halogenoalkoxy, 25 V also preferably represents hydrogen, halogen, d-C6-alkyl, Ci-C6-alkoxy or C1 -C4-halogenoalkyl, Le A 35 591-Foreign Countries -45- V1 and V2 also together preferably represent C3-C4-alkanediyl, which can optionally be substituted by halogen and/or C1-C2-alkyl and which can optionally be interrupted by one or two oxygen atoms. 5 W also preferably represents hydrogen or C1-C6-alkyl, X also preferably represents halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy or cyano or 10 Y is also preferably in the 5-position where it preferably represents the radical _>-v2' Z is also preferably in the 4-position where it preferably represents hydrogen, 15 C1-C6-alkyl or halogen, V1 also preferably represents halogen, C1-C12-alkyl, C1-C6-alkoxy, C1-C4-halo-genoalkyl or C1-C4-halogenoalkoxy, 20 V2 also preferably represents hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy or C1-C4-halogenoalkyl, V1 and V2 together also preferably represent C3-C4-alkanediyl, which can optionally be substituted by halogen and C1-C2-alkyl and which can optionally be 25 interrupted by one or two oxygen atoms. W also preferably represents hydrogen, methyl, propyl, isopropyl or halogen, Le A 35 591-Foreign Countries -46- X also preferably represents halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy or cyano, Y is also preferably in the 3- or 5-position where it preferably represents 5 hydrogen, halogen or C1 -C6-alkyl, Z is also preferably in the 4-position where it preferably represents hydrogen, halogen, C1-alkyl, C1-C4-halogenoalkyl, cyano or C1-C4-halogenoalkoxy. 10 The following also applies for the subgroups: W particularly preferably represents C1-C4-alkyl or C1-C4-alkoxy, X particularly preferably represents chlorine, bromine, C1-C4-alkyl, C1-C4- 15 alkoxy, C1-C2-halogenoalkyl, C1-C2-halogenoalkoxy or cyano, Y is particularly preferably in the 4-position where it particularly preferably represents hydrogen, chlorine, bromine, cyano or trifiuoromethyl. 20 Z particularly preferably represents hydrogen. W also particularly preferably represents hydrogen, chlorine, bromine or C1-C4-alkyl, 25 X also particularly preferably represents chlorine, bromine, C1-C4-alkyl, C1-C4- alkoxy, C1-C2-halogenoalkyl, C1-C2-halogenoalkoxy or cyano, Y is also particularly preferably in the 4-position v/here it particularly preferably represents the radical 30 Le A 35 591-Foreign Countries -47- Z also particularly preferably represents hydrogen, 5 V1 also particularly preferably represents fluorine, chlorine, C1-C4-alkyl, C1-C4- alkoxy, C1-C2-halogenoalkyl or C1-C2-halogenoalkoxy, V also particularly preferably represents hydrogen, fluorine, chlorine, C1-C4- alkyl, d-C4-alkoxy or Ci-C2-halogenoalkyl, 10 V1 and V2 together also particularly preferably represent -O-CH2-O- and -O-CF2-O-. W also particularly preferably represents hydrogen or C1 –C4alkyl, 15 X also particularly preferably represents chlorine, C1-C4-alkyl or C1-C2- halogenoalkyl, V is also particularly preferably in the 5-position where it particularly preferably represents the radical 20 Z is also particularly preferably in the 4-position where it particularly preferably represents hydrogen, C1-C4-alkyl or chlorine. 25 V also particularly preferably represents fluorine, chlorine, C1-C4-alkyl, C1-C4- alkoxy, C1-C2-halogenoalkyl or C1-C2-halogenoalkoxy, Le A 35 591-Foreign Countries 48- V2 also particularly preferably represents hydrogen, fluorine, chlorine, C1-C4-alkyl, C1-C4-alkoxy or C)-C2-halogenoalkyl, 5 V1 and V2 together also particularly preferably represent -O-CH2-O- and -O-CF2-O-. W also particularly preferably represents hydrogen, methyl, chlorine or bromine, X also particularly preferably represents chlorine, bromine, C1-C4-alkyl, C1-C4- 10 alkoxy, C1-C2-halogenoalkyl, C1-C2-halogenoalkoxy or cyano, Y is also particularly preferably in the 3- or 5-position where it particularly preferably represents hydrogen, chlorine, bromine or C1-C4-alkyl, 15 Z is also preferably in the 4-position where it preferably represents hydrogen, chlorine, bromine, C1-C4-alkyl, C1-C2-halogenoalkyl, cyano or C1-C2-halogenoalkoxy. 20 The following also applies for the subgroups: W very particularly preferably represents ethyl or methoxy, X very particularly preferably represents chlorine, bromine, methyl, ethyl, propyl, methoxy, trifluoromethyl, difluoromethoxy, trifluoroethoxy or cyano, 25 Y is very particularly preferably in the 4-position where it very particularly preferably represents hydrogen, chlorine or bromine, Z very particularly preferably represents hydrogen. 30 W also particularly preferably represents hydrogen, chlorine, bromine or methyl, Le A 35 591-Foreign Countries -49- X also very particularly preferably represents chlorine, bromine, methyl, ethyl, propyl, methoxy, trifluoromethyl, difiuoromethoxy or cyano, 5 Y is also very particularly preferably in the 4-position where it very particularly preferably represents the radical 10 Z also very particularly preferably represents hydrogen, V1 also very particularly preferably represents fluorine, chlorine, methyl, methoxy, trifluoromethyl or trifiuoromethoxy, 15 V also very particularly preferably represents hydrogen, fluorine, chlorine, methyl, methoxy or trifluoromethyl. W also very particularly preferably represents hydrogen or methyl, 20 X also very particularly preferably represents chlorine, methyl or trifluoro- methyl, Y is also very particularly preferably in the 5-position where it very particularly preferably represents the radical 25 Le A 35 591-Foreign Countries 50- Z is also very particularly preferably in the 4-position where it very particularly preferably represents hydrogen or methyl, V1 also very particularly preferably represents fluorine, chlorine, methyl, 5 methoxy, trifluoromethyl or trifluoromethoxy, V2 also very particularly preferably represents hydrogen, fluorine, chlorine, methyl, methoxy or trifluoromethyl. 10 W also very particularly preferably represents hydrogen, methyl, chlorine or bromine, X also very particularly preferably represents chlorine, bromine, methyl, methoxy, trifluoromethyl, difluoromethoxy, trifluoroethoxy or cyano, 15 Y is also very particularly preferably in the 3- or 5-position where it very particularly preferably represents hydrogen, chlorine, bromine or methyl, Z is also very particularly preferably in the 4-position where it very particularly 20 preferably represents hydrogen, chlorine, bromine, methyl, trifluoromethyl or trifluoromethoxy. The following also applies for the subgroups: 25 W particularly preferably represents ethyl or methoxy, X particularly preferably represents chlorine, bromine, methyl, ethyl, propyl, methoxy, trifluoromethyl, difluoromethoxy or cyano, 30 Y is particularly preferably in the 4-position where it particularly preferably represents hydrogen, chlorine or bromine, Le A 35 591-Foreign Countries 51 Z is particularly preferably in the 5-position where it particularly preferably represents hydrogen. 5 The following also applies for the subgroups: W also particularly preferably represents hydrogen, chlorine, bromine or methyl, X also particularly preferably represents chlorine, bromine, methyl, ethyl, 10 propyl, methoxy, trifluoromethyl, difluoromethoxy or cyano, Y is also particularly preferably in the 4-position where it particularly preferably represents the radical 15 Z also particularly preferably represents hydrogen, V1 also particularly preferably represents fluorine, chlorine, methyl, methoxy, tri- 20 fluoromethyl or trifluoromethoxy, V also particularly preferably represents hydrogen, fluorine, chlorine, methyl, methoxy or trifluoromethyl. 25 W also particularly represents hydrogen or methyl, X also particularly preferably represents chlorine or methyl, Le A 35 591-Foreign Countries -52 Y is also particularly preferably in the 5-position where it particularly preferably represents the radical 5 Z is also particularly preferably in the 4-position where it particularly preferably represents hydrogen or methyl, V1 also particularly preferably represents fluorine, chlorine, methyl, methoxy, tri- 10 fluoromethyl or trifiuoromethoxy, V2 also particularly preferably represents hydrogen, fluorine, chlorine, methyl, methoxy or trifluoromethyl. 15 The following also applies for the subgroups: W also particularly preferably represents hydrogen, methyl, chlorine or bromine, X also particularly preferably represents chlorine, bromine, methyl, methoxy, 20 trifluoromethyl, difluoromethoxy or cyano. Y is also particularly preferably in the 3- or 5-position where it particularly preferably represents hydrogen, chlorine, bromine or methyl, 25 Z is also particularly preferably in the 4-position where it particularly preferably represents hydrogen, chlorine, bromine, methyl, trifluoromethyl or trifiuoromethoxy. Le A 35 591-Foreign Countries -53- In addition to the compounds mentioned in the examples, the following compounds of the formula (I-l-a) may be specifically mentioned: OH X u o w 5 Table 1: W = CH3, X = CH3, Y = 4-CH3, Z = H. A B D CH3 CH3 H C2H5 CH3 H C3H7 CH3 H i-C3H7 CH3 H A CH3 H -(CH2)4 H -(CH2)5- H -(CH2)2-0-(CH2)2- H -CH2-0-(CH2)3- H -CH2-CHCH3-(CH2)3- H -(CH2)2-CHCH3-(CH2)2- H -(CH2)2-CHOCH3-(CH2)2- H -(CH2)2-CHOC2H5-(CH2)2- H -(CH2)2-C(CH3)2-(CH2)2- H Le A 35 591-Foreign Countries -54- A D B -(CH2)3- H -(CH2)4- H -(CH2)2-0-(CH2)- H -(CH2)2-S-CH2- H — CH2-( ""i i fi H — H A1 Ul — (CH2)3-I H CH3 H H C2H5 H H C3H7 H H i-C3H7 H H A H H Ck H CH3 CH3 H CH3 C2H5 H CH3 i-C3H7 H CH3 A H Table 2: A, B and D are as indicated in Table 1 W - CH3; X = CH3; Y = 4-C1; Z = H. 5 Table 3: A, B and D are as indicated in Table 1 W = CH3; X = CH3; Y = 4-Br; Z = H. Table 4: A, B and D are as indicated in Table 1 10 W = C2H5; X = CH3; Y = 4-C1; Z = H. Le A 35 591-Foreign Countries 55- Table 5; A, B and D are as indicated in Table 1 W = C2H5; X = CH3; Y = 4-Br; Z = H. Table 6: A, B and D are as indicated in Table 1 5 W = C2H5; X = C2H5; Y = 4-C1; Z = H. Table 7: A, B and D are as indicated in Table 1 W = C2H5; X = C2H5; Y = 4-Br; Z - H. 10 Table 8: A, B and D are as indicated in Table 1 W = CH3; X = CI; Y = 4-Cl; Z = H. Table 9: A, B and D are as indicated in Table 1 W = CH3; X = Br; Y = 4-Br; Z = H. 15 Table 10: A, B and D are as indicated in Table 1 W = CH3; X - CI; Y - 4-Br; Z = H. Table 11: A, B and D are as indicated in Table 1 20 W = CH3; X = Br; Y = 4-Cl; Z = H. Table 12: A, B and D are as indicated in Table 1 W = C2H5; X - CI; Y = 4-Cl; Z - H. 25 Table 13: A, B and D are as indicated in Table 1 W = C2H5; X = Br; Y = 4-Br; Z = H. Table 14: A, B and D are as indicated in Table 1 W = C2H5; X = CI; Y = 4-Br; Z = H. 30 Le A 35 591-Foreign Countries 56 Table 15: A, B and D are as indicated in Table 1 W - C2H5; X = Br; Y = 4-C1; Z = H. Table 16: A, B and D are as indicated in Table 1 5 W = CH3; X = CH3; Y = H; Z = 4-(4-Cl-C6H4). Table 17: A, B and D are as indicated in Table 1 W = CH3; X = CI; Y = H; Z = 4-(4-Cl-C6H4). 10 Table 18: A, B and D are as indicated in Table 1 W = C2H5; X = CH3; Y = H; Z = 4-(4-Cl-C6H4). Table 19: A, B and D are as indicated in Table 1 W = C2H5; X = CI; Y = H; Z = 4-(4-Cl-C6H4). 15 Table 20: A, B and D are as indicated in Table 1 W = C2H5; X = C2H5; Y = H; Z = 4-(4-Cl-C6H4). Table 21: A, B and D are as indicated in Table 1 20 W = H; X = CH3; Y = H; Z = 5-(4-Cl-C6H4). Table 22: A, B and D are as indicated in Table 1 W = H; X = CH3; Y = 4-CH3; Z = 5-(4-Cl-C6H4). 25 In addition to the compounds mentioned in the Preparation Examples, the following compounds of the formula (I-2-a) may be specifically mentioned: OH X O W Le A 35 591-Foreign Countries -57- Table 23: W = CH3, X = CH3, Y = 4-CH3, Z = H A B CH3 CH3 C2H5 CH3 C3H7 CH3 i-C3H7 CH3 -(CH2)5- -(CH2)2-0-(CH2)2- -CH2-0-(CH2)3- -CH2-CHCH3-(CH2)3- -(CH2)2-CHCH3-(CH2)2- -(CH2)2-CHOCH3-(CH2)2- -(CH2)2-CHOC2H5-(CH2)2- 5 Table 24: A and B are as indicated in Table 23 W = CH3; X = CH3; Y = 4-C1; Z = H. Table 25: A and B are as indicated in Table 23 W = CH3; X = CH3; Y =4-Br; Z = H. 10 Table 26: A and B are as indicated in Table 23 W = C2H5; X = CH3; Y = 4-C1; Z = H. Table 27: A and B are as indicated in Table 23 15 W = C2H5; X = CH3; Y = 4-Br; Z - H. Table 28: A and B are as indicated in Table 23 W = C2H5; X = C2H5; Y = 4-C1; Z = H. Le A 35 591-Foreign Countries 58- Table 29: A and B are as indicated in Table 23 W = C2H5; X = C2H5; Y = 4-Br; Z = H. 5 Table 30: A and B are as indicated in Table 23 W = CH3; X = CH3; Y = H; Z = 4-(4-CI-C6H4). Table 31: A and B are as indicated in Table 23 W = CH3; X - C2H5; Y = H; Z = 4-(4-Cl-C6H4). 10 Table 32: A and B are as indicated in Table 23 W = C2H5; X = C2H5; Y = H; Z = 4-(4-Cl-C6H4). 15 Table 33: A and B are as indicated in Table 23 W = CI; X = CH3; Y = H; Z = 4-(4-Cl-C6H4). Table 34: A and B are as indicated in Table 23 W = CI; X = C2H5; Y = H; Z = 4-(4-Cl-C6H4). 20 Table 35: A and B are as indicated in Table 23 W - H; X = CH3; Y = H; Z = 5-(4-Cl-C6H4). Table 36: A and B are as indicated in Table 23 W = H; X - CH3; Y = 4-CH3; Z = 5-(4-Cl-C6H4). 25 The combinations for W, X, Y and Z described in Tables 1-36 are likewise preferred combinations of radicals in the compounds of the formula (I). Preferred meanings of the groups listed above in connection with the compounds 30 improving crop plant compatibility ("herbicide safeners") of the formulae (Ha), (lib), (He), (Ed) and (He) are defined below. Le A 35 591-Foreign Countries -59 n preferably represents the number 0,1,2, 3 or 4. A1 preferably represents one of the divalent heterocyclic groupings shown below R13^T^ )=i /=N " b-N OR14 R13 R13 A preferably represents in each case optionally methyl-, ethyl-, methoxycarbonyl-or ethoxy-carbonyl-substituted methylene or ethylene. 10 15 Q R preferably represents hydroxyl, mercapto, amino, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i-propylthio, n-, i-, s-or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino or diethylamino. R preferably represents hydroxyl, mercapto, amino, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i-propylthio, n-, i-, s-or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino or diethylamino. 20 R10 preferably represents in each case optionally fluorine-, chlorine- and/or bromine-substituted methyl, ethyl, n- or i-propyl. R11 preferably represents hydrogen, in each case optionally fluorine- and/or 25 chlorine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, propinyl or butinyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, Le A 35 591-Foreign Countries -60 or optionally fluorine-, chlorine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-substituted phenyl. R12 preferably represents hydrogen, in each case optionally fluorine- and/or 5 chlorine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, propinyl or butinyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-substituted phenyl, or together with R11 represents one of the radicals 10 -CH2-0-CH2-CH2- and -CH2-CH2-0-CH2-CH2-, which are optionally substituted by methyl, ethyl, furyl, phenyl, a fused-on benzene ring or by two substituents which together with the C atom to which they are attached form a 5- or 6-membered carbocycle. 15 R preferably represents hydrogen, cyano, fluorine, chlorine, bromine, or represents in each case optionally fluorine-, chlorine- and/or bromine-substituted methyl, ethyl, n- or i-propyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl or phenyl. R14 preferably represents hydrogen, optionally hydroxyl-, cyano-, fluorine-, 20 chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i- propyl, n-, i-, s- or t-butyl. R15 preferably represents hydrogen, cyano, fluorine, chlorine, bromine, or represents in each case optionally fluorine-, chlorine- and/or bromine-substituted methyl, 25 ethyl, n- or i-propyl, n-, i-, s- or t-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl or phenyl. X1 preferably represents nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, trifiuoromethyl, 30 trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifiuoromethoxy. Le A 35 591-Foreign Countries -61- X2 preferably represents hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, trifluoromethyl, trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, 5 methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy. X preferably represents hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, trifluoromethyl, trichloromethyl, chlorodifluoromethyl, fluorodichloromethyl, 10 methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy. R16 preferably represents hydrogen, methyl, ethyl, n- or i-propyl. R preferably represents hydrogen, methyl, ethyl, n- or i-propyl. 15 1 R R preferably represents hydrogen, in each case optionally cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, 20 methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino or diethylamino, or in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclo-pentyloxy, cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, 25 cyclohexylthio, cyclopropylamino, cyclobutylamino, cyclopentylamino or cyclohexylamino. R19 preferably represents hydrogen, in each case optionally cyano-, hydroxyl-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, 30 ethyl, n- or i-propyl, n-, i- or s-butyl, in each case optionally cyano-, fluorine-, chlorine- or bromine-substituted propenyl, butenyl, propinyl or butinyl, or in Le A 35 591-Foreign Countries -62- each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl. R20 preferably represents hydrogen, represents in each case optionally cyano-, 5 hydroxyl-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl, in each case optionally cyano-, fluorine-, chlorine- or bromine-substituted propenyl, butenyl, propinyl or butinyl, in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl or 10 cyclohexyl, or optionally nitro-, cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy- or trifluoromethoxy-substituted phenyl, or together with R19 represents in each case optionally methyl- or ethyl-substituted butane-1,4-diyl (trimethylene), pentane-l,5-diyl, l-oxa-butane-l,4-diyl or 3- 15 oxa-pentane-1,5-diyl. X4 preferably represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoro 20 methoxy or trifluoromethoxy. X5 preferably represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, 25 difluoromethoxy or trifluoromethoxy. Examples of compounds of the formula (Ha) which are very particularly preferred as herbicide safeners according to the invention are listed in Table 2 below. Le A 35 591-Foreign Countries -63- Table 2: Examples of the compounds of the formula (Ha) 3 1 4rf^i2 o (* )n"+ J 1 (Ha) Le A 35 591-Foreign Countries -65- Le A J5 Wl-foreign countries -66- Examples of compounds of the formula (lib) which are very particularly preferred as herbicide safeners according to the invention are listed in Table 3 below. K^f' o A2 FT 5 Table 3: Examples of the compounds of the formula (lib) Le A 35 591-Foreign Countries -67- Examples of the compounds (He) which are very particularly preferred as herbicide safeners according to the invention are listed in Table 4 below. 5 Le A 35 591-Foreign Countries -68- Table 4: Examples of the compounds of the formula (He) Examples of the compounds of the formula (lid) which are very particularly preferred 5 as herbicide safeners according to the invention are listed in Table 5 below. Le A 35 591-Foreign Countries -69- R17 ' is \\ I i -}—(x4)n S02 Y (Dd) 0 Table 5: Examples of the compounds of the formula (Ed) Example No. R16 R17 R18 (positions)(X4)n (positions)(X5)n IId-1 H H CH3 (2) OCH3 - IId-2 H H C2H5 (2) OCH3 - Hd-3 H H C3H7-n (2) OCH3 - nd-4 H H C3H7-i (2) OCH3 - Hd-5 H H L \ (2) OCH3 - Hd-6 H H CH3 (2) OCH3 (5) CH3 Hd-7 H H C2H5 (2) OCH3 (5) CH3 Hd-8 H H C3H7-n (2) OCH3 (5) CH3 IId-9 H H C3H7-i (2) OCH3 (5) CH3 IId-10 H H L \ (2) OCH3 (5) CH3 nd-ii H H oc :HJ (2) OCH3 (5) CH3 Le A 35 591-Foreign Countries -70- ExampleNo. R16 R17 R18 (positions) (X\ (positions)(X5)n Hd-12 H H OC2H5 (2) OCH3 (5) CH3 - nd-13 H H OC3H7-i (2) OCH3 (5) CH3 - Hd-14 H H SCH3 (2) OCH3 (5) CH3 - Hd-15 H H SC2H5 (2) OCH3 (5) CH3 - Hd-16 H H SC3H7-i (2) OCH3 (5) CH3 - Hd-17 H H NHCH3 (2) OCH3 (5) CH3 - Hd-18 H H NHC2H5 (2) OCH3 (5) CH3 - Hd-19 H H NHC3H7-i (2) OCH3 (5) CH3 - Hd-20 H H A (2) OCH3 (5) CH3 - Hd-21 H H NHCH3 (2) OCH3 - Hd-22 H H NHC3H7-i (2) OCH3 - Hd-23 H H N(CH3)2 (2) OCH3 - Hd-24 H H N(CH3)2 (3) CH3(4) CH3 - Examples of the compounds of the formula (He) which are very particularly preferred as herbicide safeners according to the invention are listed in Table 6 below. Le A 35 591-Foreign Countries -71- Table 6: Examples of the compounds of the formula (He) ExampleNo. R16 R19 R 20 (positions) (X4)„ (positions)(X5)„ He-l H H CH3 (2) OCH3 - Ee-2 H H C2H5 (2) OCH3 - He-3 H H C3H7-n (2) OCH3 - He-4 H H C3H7-i (2) OCH3 - He-5 H H L \ (2) OCH3 - Ee-6 H CH3 CH3 (2) OCH3 - He-7 H H CH3 (2) OCH3 (5) CH3 - He-8 H H C2H5 (2) OCH3 (5)CH3 - He-9 H H C3H7-n (2) OCH3 (5) CH3 - He-10 H H C3H7-i (2) OCH3 (5)CH3 - He-11 H H / \ (2) OCH3 (5) CH3 - Ee-12 H CH3 CH3 (2) OCH3 (5) CH3 - Le A 35 591-Foreign Countries -72- Most preferred compounds which improve crop plant compatibility [component (b)] are cloquintocet-mexyl, fenchlorazole-ethyl, isoxadifen-ethyl, mefenpyr-diethyl, furilazole, fenclorim, cumyluron, dymron, dimepiperate and the compound IIe-11, and particular emphasis is given to cloquintocet-mexyl and mefenpyr-diethyl. 5 Examples of the selectively herbicidal combinations according to the invention of in each case one active compound of the formula (I) and in each case one of the safeners defined above are listed in Table 7 below. 10 Table 7; Examples of combinations according to the invention Active compound of the formula (I) Safener 1-1 cloquintocet-mexyl 1-1 fenchlorazole-ethyl 1-1 isoxadifen-ethyl 1-1 mefenpyr-diethyl 1-1 furilazole 1-1 fenclorim 1-1 cumyluron 1-1 daimuron /dymron 1-1 dimepiperate 1-1 He-11 1-2 cloquintocet-mexyl 1-2 fenchlorazole-ethyl 1-2 isoxadifen-ethyl 1-2 mefenpyr-diethyl 1-2 furilazole 1-2 fenclorim 1-2 cumyluron Le A 35 591-Foreign Countries -73- Active compound of the formula (I) Safener 1-2 daimuron /dymron 1-2 dimepiperate 1-2 He-11 1-3 cloquintocet-mexyl 1-3 fenchlorazole-ethyl 1-3 isoxadifen-ethyl 1-3 mefenpyr-diethyl 1-3 furilazole 1-3 fenclorim 1-3 cumyluron 1-3 daimuron /dymron 1-3 dimepiperate 1-3 He-11 1-4 cloquintocet-mexyl 1-4 fenchlorazole-ethyl 1-4 isoxadifen-ethyl 1-4 mefenpyr-diethyl 1-4 furilazole 1-4 fenclorim 1-4 cumyluron 1-4 daimuron /dymron 1-4 dimepiperate 1-4 He-11 1-5 cloquintocet-mexyl 1-5 fenchlorazole-ethyl 1-5 isoxadifen-ethyl 1-5 mefenpyr-diethyl 1-5 furilazole -74- Active compound of the formula (I) Safener 1-5 fenclorim 1-5 cumyluron 1-5 daimuron /dymron 1-5 dimepiperate 1-5 He-11 1-6 cloquintocet-mexyl 1-6 fenchlorazole-ethyl 1-6 isoxadifen-ethyl 1-6 mefenpyr-diethyl 1-6 furilazole 1-6 fenclorim 1-6 cumyluron 1-6 daimuron /dymron 1-6 dimepiperate 1-6 He-11 Surprisingly, it has now been found that the above-defined active compound combinations of substituted cyclic ketoenols of the general formula (I) and safeners (antidotes) of group (b) listed above, whilst being tolerated very well by crop plants, 5 have particularly high herbicidal activity and can be used in various crops, in particular in cereal (especially wheat), but also in soya beans, potatoes, maize and rice, for the selective control of weeds. Here, it has to be considered to be surprising that, from a large number of known 10 safeners or antidotes which are capable of antagonizing the damaging effect of a herbicide on the crop plants, it is in particular the abovementioned compounds of group (h) which neutralize the damaging effect of substituted cvclic ketoenols on the Le A 35 591-Foreign Countries -75- crop plants virtually completely without negatively affecting the herbicidal activity with respect to the weeds. Emphasis is given here to the particularly advantageous effect of the particularly and 5 most preferred combination partners from group (b), in particular in respect of sparing cereal plants, such as, for example, wheat, barley and rye, but also maize and rice, as crop plants. The active compound combinations according to the invention can be used, for 10 example, in connection with the following plants: Dicotyledonous weeds of the genera: Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, 15 Cirsium, Carduus, Sonchus, Solanum, Rorippa, Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum. Dicotyledonous crops of the genera: Gossypium, Glycine, Beta, Daucus, Phaseolus, 20 Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, Cucumis, Cuburbita, Helianthus. Monocotyledonous weeds of the genera: Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, 25 Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera. Monocotyledonous crops of the genera: Oryza, Zea, Triticum, Hordeum, Avena, 30 Secale, Sorghum, Panicum, Saccharum, Ananas, Asparagus, Allium. Le A 35 591-Foreign Countries -76- However, the use of the active compound combinations according to the invention is in no way restricted to these genera, but also extends in the same manner to other plants. 5 According to the invention, it is possible to treat all plants and parts of plants. Here, plants are to be understood as meaning all plant and plant populations such as desirable and undesirable wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which are obtained by conventional breeding and optimization methods or by biotechnological and recombinant methods or 10 combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by breeders' rights. Plant parts are to be understood as meaning all above-ground and below-grounds parts and organs of the plants, such as shoots, leaves, flowers and roots, where leaves, needles, stems, trunks, flowers, fruit bodies, fruits and seeds and also roots, tubers and rhizomes may 15 be mentioned by way of example. Plant parts also include harvested produce and vegetative and generative propagation material, for example seedlings, tubers, rhizomes, cuttings and seeds. The treatment according to the invention of the plants and plant parts with the active 20 compounds is carried out directly or by action on their environment, habitat or storage space by customary treatment methods, for example by dipping, spraying, evaporating, atomizing, broadcasting, spreading-on and, in the case of propagation material, in particular in the case of the seeds, furthermore by applying one or more coats. 25 The advantageous effect of the crop plant compatibility of the active compound combinations according to the invention is particularly highly pronounced at certain concentration ratios. However, the weight ratios of the active compounds in the active compound combinations can be varied within relatively wide ranges. In 30 general, 0.001 to 1000 parts by weight, preferably 0.01 to 100 parts by weight, particularly preferably 0.05 to 10 parts by weight and most preferably 0.07 to 1.5 Le A 35 591-Foreign Countries -77- parts by weight of one of the compounds which improve crop plant compatibility mentioned under (b) above (antidotes/safeners) are present per part by weight of active compound of the formula (I) or its salts. 5 The active compounds or active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusting agents, pastes, soluble powders, granules, suspoemulsion concentrates, natural and synthetic materials impregnated with active compound, and very fine capsules in polymeric substances. 10 These formulations are produced in a known manner, for example by mixing the active compounds with extenders, that is liquid solvents and/or solid carriers, optionally with the use of surfactants, that is emulsifiers and/or dispersants and/or foam-formers. 15 If the extender used is water, it is also possible to use, for example, organic solvents as auxiliary solvents. Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, 20 aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol, and also their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulphoxide, and also water. 25 Suitable solid carriers are: for example ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, ground synthetic minerals, such as finely divided silica, alumina and silicates, suitable solid 30 carriers for granules are: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, and also synthetic granules of Le A 35 591-Foreign Countries -78- inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; suitable emulsifiers and/or foam- formers are: for example non-ionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl 5 polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: for example lignosulfite waste liquors and methylcellulose. Tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the 10 form of powders, granules or latices, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids, can be used in the formulations. Other possible additives are mineral and vegetable oils. 15 It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc. 20 The formulations generally comprise from 0.1 to 95 per cent by weight of active compounds including the safeners, preferably between 0.5 and 90%. The active compound combinations according to the invention are generally used in the form of finished formulations. However, the active compounds contained in the 25 active compound combinations can also be mixed in individual formulations when used, i.e. in the form of tank mixes. The novel active compound combinations, as such or in their formulations, can furthermore be used as a mixture with other known herbicides, finished formulations 30 or tank mixes again being possible. A mixture with other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellents, growth Le A 35 591-Foreign Countries -79- factors, plant nutrients and agents which improve soil structure, is also possible. For certain intended uses, in particular in the post-emergence method, it may furthermore be advantageous to include, as further additives in the formulations, mineral or vegetable oils which are tolerated by plants (for example the commercial preparation 5 "Rako Binol"), or ammonium salts such as, for example, ammonium sulfate or ammonium thiocyanate. The novel active compound combinations can be used as such, in the form of their formulations or the use forms prepared therefrom by further dilution, such as ready- 10 to-use solutions, suspensions, emulsions, powders, pastes and granules. They are used in the customary manner, for example by washing, spraying, atomizing, dusting or scattering. The amounts of the active compound combinations according to the invention 15 applied can be varied within a certain range; they depend, inter alia, on the weather and on soil factors. In general, the application rates are between 0.005 and 5 kg per ha, preferably between 0.01 and 2 kg per ha, particularly preferably between 0.05 and 1.0 kg per ha. The active compound combinations according to the invention can be applied before 20 and after emergence of the plants, that is to say by the pre-emergence and post- emergence method. Use Examples 25 The active compound or safener components are in each case dissolved in a few ml (generally 2-3 ml) of solvent (generally acetone or N,N-dimethyl-formamide), and the solutions are combined and then - if appropriate after addition of an emulsifier -diluted with water to the desired concentration. In general, an aqueous spray liquor was prepared using 0.1% of the additive Renex-36. 30 Le A 35 591-Foreign Countries -80- Example A Post-emergence test 5 The test plants are grown under controlled conditions (temperature, light, atmos- pheric humidity) in a greenhouse. The test plants are sprayed when they have reached a height of 5-15 cm. The concentration of the spray liquor is chosen such that the particular amounts of active compound desired are applied in 500 1 of water/ha. 10 After spraying, the pots with the test plants are kept in a greenhouse chamber under controlled conditions (temperature, light, atmospheric humidity) until the test has ended. About three weeks after the application, the degree of damage to the crop plants is rated in % damage in comparison to the development of the untreated control. 15 The figures denote: 0 % = no damage (like untreated control) 100 % = total destruction/damage 20 Active compounds, application rates, test plants and results are shown in the tables below, the terms being used in the tables being as defined below: Le A 35 591-Foreign Countries -81- Active compounds Example I-1-a-1 PH,q H3C OH H3C 94% pure (known from EP-A 456 063) Example I-l-a-2 H,C O n3 100% pure (known from WO 97/02243) 10 Example I-l-a-3 H3Q HN H3° H3C OH 99% pure (known from WO 97/02243) -82- Example-l-a-4 88% pure (known from WO 99/43649) 5 Mefenpyr-diethyl (used as 100 EC) Cloquintocet-mexyl, 99% pure Table A-l Application rate g of ai/ha Winter barleyobserved Example I-1-a-1 440 70 220 25 110 10 Example I-l-a-1 + mefenpyr- 440 + 50 15 diethyl 220 + 50 10 110 + 50 0 Table A-2 Application rate g of ai/ha Winter wheatobserved Example I-l-a-2 125 10 Example I-l-a-2 + mefenpyr-diethyl 125 + 50 5 -83- Table A-3 Application rate g of ai/ha Winter barleyobserved Example I-l-a-2 250 125 65 20 Example I-l-a-2 + mefenpyr-diethyl 250 + 50 125 + 50 50 10 Table A-4 Application rate g of ai/ha Winter wheatobserved Example I-1-a-3 250 125 15 10 Example I-l-a-3 + mefenpyr-diethyl 250 + 50 125 + 50 0 0 Table A-5 Application rate g of ai/ha Winter barleyobserved Example I-l-a-4 250 35 125 35 60 5 Example I-l-a-4 + mefenpyr- 250 + 50 5 diethyl 125 + 50 0 60 + 50 0 -84- Table A-6 Application rate Winter Winter g of ai/ha barley wheat observed observed Mefenpyr-diethyl 50 0 0 Table A-7 Application rate g of ai/ha Winter barleyobserved Example I-1-a-1 440 70 220 25 110 10 Example I-l-a-1 + 440 + 50 10 cloquintocet-mexyl 220 + 50 5 110 + 50 5 Table A-8 Application rate g of ai/ha Winter wheatobserved Example I-l-a-2 250 40 Example I-l-a-2 + cloquintocet-mexyl 250 + 50 15 -85- Table A-9 Application rate g of ai/ha Winter barleyobserved Example I-l-a-2 250 65 125 20 60 5 Example I-l-a-2 + 250 + 50 15 cloquintocet-mexyl 125 + 50 5 60 + 50 0 Table A-10 Application rate g of ai/ha Winter barleyobserved Example I-l-a-3 250 40 Example I-l-a-3 + cloquintocet-mexyl 250 + 50 30 Table A-ll Application rate Winter barley g of ai/ha observed Example I-l-a-4 250 35 125 35 Example I-l-a-4 + 250 + 50 10 cloquintocet-mexyl 125 + 50 10 Le A 35 591-Foreign Countries -86-Table A-12 Application rate g of ai/ha Winter wheatobserved Winter barleyobserved cloquintocet-mexyl 50 0 0 Le A 35 591-Foreign Countries 87 5 Patent Claims 1. Compositions, comprising an effective amount of an active compound combination comprising (a) at least one substituted cyclic ketoenol of the formula (I) (I) in which 10 X represents halogen, alkyl, alkenyl, alkoxy, alkenyloxy, alkylthio, alkyl-sulphinyl, alkylsulphonyl, haloalkyl, haloalkoxy, haloalkenyloxy, nitro or cyano, 15 Z represents hydrogen or represents in each case optionally substituted alkenyl, alkinyl, aryl or hetaryl, W and Y independently of one another represent hydrogen, halogen, alkyl, alkoxy, alkenyloxy, haloalkyl, haloalkoxy, haloalkenyloxy, nitro or 20 cyano, with the proviso that, if Y represents 4-methyl, W and X do not simultaneously represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl, 25 CKE represents one of the groups Le A 35 591-Foreign Countries -88- A B A B O-G o O-G 0 (D, (3), (5) or (2), (4), in which 10 represents hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, saturated or unsaturated, optionally substituted cycloalkyl, in which optionally at least one ring atom is replaced by a heteroatom, or in each case optionally halogen-, alkyl-, haloalkyl-, alkoxy-, haloalkoxy-, cyano- or nitro-substituted aryl, arylalkyl or hetaryl, 15 B represents hydrogen, alkyl or alkoxyalkyl, or A and B together with the carbon atom to which they are attached represent a saturated or unsaturated, unsubstituted or substituted cycle which optionally contains at least one heteroatom, 20 D represents hydrogen or an optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkoxyalkyl, saturated or Le A 35 591-Foreign Countries -89- unsaturated cycloalkyl, in which optioinally one or more ring members are replaced by heteroatoms, arylalkyl, aryl, hetarylalkyl or hetaryl, or A and D together with the atoms to which they are attached represent a 5 saturated or unsaturated cycle which is unsubstituted or substituted in the A,D moiety and optionally contains at least one heteroatom, or A and Q1 together represent alkanediyl or alkenediyl which are in each case optionally substituted by hydroxyl or by in each case optionally 10 substituted alkyl, alkoxy, alkylthio, cycloalkyl, benzyloxy or aryl, or Q1 represents hydrogen or alkyl, Q2, Q4, Q5 and Q6 independently of one another represent hydrogen or alkyl, 15 Q3 represents hydrogen, alkyl, alkoxyalkyl, alkylthioalkyl, optionally substituted cycloalkyl (in which optionally one methylene group is replaced by oxygen or sulphur) or optionally substituted phenyl, or 20 Q3 and Q4 together with the carbon atom to which they are attached, represent a saturated or unsaturated, unsubstituted or substituted cycle which optionally contains a heteroatom, G represents hydrogen (a) or represents one of the groups 25 0^R1 (b), LAr^ic -so^R\d,, R4 E (f) or y~Nx 7 (g), L R Le A 35 591-Foreign Countries -90- in which E represents a metal ion equivalent or an ammonium ion, 5 L represents oxygen or sulphur, M represents oxygen or sulphur, Rl represents in each case optionally halogen-substituted alkyl, 10 alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen-, alkyl- or alkoxy-substituted cycloalkyl, which may be interrupted by at least one heteroatom, represents in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, 15 R2 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or represents in each case optionally substituted cycloalkyl, phenyl or benzyl, 20 R-3, R4 and R5 independently of one another represent in each case optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio and represent in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio, 25 R6 and R7 independently of one another represent hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, represent optionally substituted phenyl, represent optionally substituted benzyl, or together with the N 30 atom to which they are attached represent a cycle which is optionally interrupted by oxygen or sulphur, Le A 35 591-Foreign Countries -91- - including all possible tautomeric forms of the compounds of the general formula (I) and the possible salts or acid or base adducts of the compounds of the general formula (I) - 5 and (b) at least one compound which improves crop plant compatibility, from the group of compounds below: 10 4-dichloroacetyl-l-oxa-4-aza-spiro[4.5]-decane (AD-67, MON-4660), 1- dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[l,2-a]-pyrimidin-6(2H)-one (dicyclonon, BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-l,4-benzoxazine (benoxacor), 1-methyl-hexyl 5-chloro-quinolin-8-oxy-acetate (cloquintocet-mexyl - cf. also related compounds in EP-A-86750, 15 EP-A-94349, EP-A-191736, EP-A-492366), 3-(2-chloro-benzyl)-l-(l-methyl- 1 -phenyl -ethyl)-urea (cumyluron), a-(cyanomethoximino)-phenylacetonitrile (cyometrinil), 2,4-dichloro-phenoxyacetic acid (2,4-D), 4-(2,4-dichloro-phenoxy)-butyric acid (2,4-DB), 1-(1-methyl-l-phenyl-ethyl)-3-(4-methyl-phenyl)-urea (daimuron, dymron), 3,6-dichloro-2-methoxy-benzoic acid 20 (dicamba), S-l-methyl-1-phenyl-ethyl piperidine-1-thiocarboxylate (dime- piperate), 2,2-dichloro-N-(2-oxo-2-(2-propenylamino)-ethyl)-N-(2-propenyl)-acetamide (DKA-24), 2,2-dichloro-N,N-di-2-propenyl-acetamide (dichlor-mid), 4,6-dichloro-2-phenyl-pyrimidine (fenclorim), ethyl l-(2,4-dichloro-phenyl)-5-trichloromethyl-lH-l,2,4-triazole-3-carboxylate (fenchlorazole- 25 ethyl - cf. also related compounds in EP-A-174562 and EP-A-346620), phenyl-methyl 2-chloro-4-trifluoromethyl-thiazole-5-carboxylate (flurazole), 4-chloro-N-(l,3-dioxolan-2-yl-methoxy)-a-trifluoro-acetophenone oxime (fluxofenim), 3-dichloroacetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidine (furilazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazole- 30 carboxylate (isoxadifen-ethyl - cf. also related compounds in WO-A-95/07897), 1 -(ethoxycarbonyl)-ethyl 3,6-dichloro-2-methoxybenzoate Le A 35 591-Foreign Countries -92- (lactidichlor), (4-chloro-o-tolyloxy)-acetic acid (MCPA), 2-(4-chloro-o- tolyloxy)-propionic acid (mecoprop), diethyl l-(2,4-dichloro-phenyl)-4,5- dihydro-5-methyl-lH-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl - cf. also related compounds in WO-A-91/07874), 2-dichloromethyl-2-methyl-l,3- 5 dioxolane (MG-191), 2-propenyl-l-oxa-4-azaspiro[4.5]decane 4-carbo- dithioate (MG-838), 1,8-naphthalic anhydride, oc-(l,3-dioxolan-2-yl-methoximino)-phenylacetonitrile (oxabetrinil), 2,2-dichloro-N-(l ,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamide (PPG-1292), 3-dichloroacetyl-2,2-dimethyl-oxazolidine (R-28725), 3-dichloroaceryl-2,2,5-trimethyl-oxazolidine 10 (R-29148), 4-(4-chloro-o-tolyl)-butyric acid, 4-(4-chloro-phenoxy)-butyric acid, diphenylmethoxyacetic acid, methyl diphenylmethoxyacetate, ethyl diphenylmethoxyacetate, methyl l-(2-chloro-phenyl)-5-phenyl-lH-pyrazole-3-carboxylate, ethyl l-(2,4-dichloro-phenyl)-5-methyl-lH-pyrazole-3-carboxylate, ethyl 1 -(2,4-dichloro-phenyl)-5-isopropyl- lH-pyrazole-3- 15 carboxylate, ethyl l-(2,4-dichloro-phenyl)-5-(l,l-dimethyl-ethyl)-lH- pyrazole-3-carboxylate, ethyl l-(2,4-dichloro-phenyl)-5-phenyl-lH-pyrazole-3-carboxylate (cf. also related compounds in EP-A-269806 and EP-A-333131), ethyl 5-(2,4-dichloro-benzyl)-2-isoxazoline-3-carboxylate, ethyl 5-phenyl-2-isoxazoline-3-carboxylate, ethyl 5-(4-fluoro-phenyl)-5- 20 phenyl-2-isoxazoline-3-carboxylate (cf. also related compounds in WO- A-91/08202), 1,3-dimethyl-but-l-yl 5-chloro-quinolin-8-oxy-acetate, 4-allyloxy-butyl 5-chloro-quinolin-8-oxy-acetate, 1 -allyloxy-prop-2-yl 5-chloro-quinolin-8-oxy-acetate, methyl 5-chloro-quinoxalin-8-oxy-acetate, ethyl 5-chloro-quinolin-8-oxy-acetate, allyl 5-chloro-quinoxalin-8-oxy- 25 acetate, 2-oxo-prop-l-yl 5-chloro-quinolin-8-oxy-acetate, diethyl 5-chloro- quinolin-8-oxy-malonate, diallyl 5-chloro-quinoxalin-8-oxy-malonate, diethyl 5-chloro-quinolin-8-oxy-malonate (cf. also related compounds in EP-A-582198), 4-carboxy-chroman-4-yl-acetic acid (AC-304415, cf. EP-A-613618), 4-chloro-phenoxy-acetic acid, 3,3'-dimethyl-4-methoxy- 30 benzophenone, l-bromo-4-chloromethylsulphonyl-benzene, l-[4-(N-2- methoxybenzoylsulphamoyl)-phenyl] -3 -methyl-urea (alias N-(2-methoxy- Le A 35 591-Foreign Countries 93 benzoyl)-4-[(methylamino-carbonyl)-amino]-benzenesulphonamide), l-[4-(N- 2-methoxybenzoylsulphamoyl)-phenyl]-3,3-dimethyl-urea, l-[4-(N-4,5-di- methylbenzoylsulphamoyl)-phenyl]-3-methyl-urea, 1 -[4-(N-naphthyl- sulphamoyl)-phenyl]-3,3-dimethyl-urea, N-(2-methoxy-5-methyl-benzoyl)-4-(cyclopropylaminocarbonyl)-benzenesulphonamide, and/or one of the following compounds defined by general formulae of the general formula (Ha) 10 (x1)n- .^ 0 X. (Ha) or of the general formula (lib) LA. 15 O I A' ^FT (Hb) or the formula (lie) ./ O R10^N' i- R 11 (He) 20 where n represents a number between 0 and 5, Le A 35 591-Foreign Countries -94- represents one of the divalent heterocyclic groupings shown below ,N.N /W ■OR14 R13 R ■N R O-N A2 represents optionally Ci-C4-alkyl- and/or Ci-C4-alkoxy-carbonyl- 5 substituted alkanediyl with 1 or 2 carbon atoms, R8 represents hydroxyl, mercapto, amino, Ci-C6-alkoxy, Ci-C6-alkylthio, Ci-C6-alkylamino or di-(Ci-C4-alkyl)-amino, 10 R9 represents hydroxyl, mercapto, amino, C[-C6-alkoxy, Ci-C6-alkylthio, C]-C6-alkylamino or di-(Ci-C4-alkyl)-amino, R10 represents in each case optionally fluorine-, chlorine- and/or bromine- substituted Ci-C4-alkyl, 15 R11 represents hydrogen, in each case optionally fluorine-, chlorine- and/or bromine-substituted C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkinyl, C1-C4-alkoxy- C1-C4-alkyl, dioxolanyl- C1-C4-alkyl, furyl, furyl- C1-C4- allcyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine- 20 and/or bromine- or C1-C4-alkyl-substituted phenyl, R represents hydrogen, in each case optionally fluorine-, chlorine- and/or bromine-substituted C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkinyl, C1-C4-alkoxy- C1-C4-alkyl, dioxolanyl- C1-C4-alkyl, furyl, furyl- C1-C4- 25 alkyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine- and/or bromine- or C1-C4-alkyl-substituted phenyl, or together with R11 represents C3-C6-alkanediyl or C2-C5-oxaalkanediyl, each of which is optionally substituted by C1-C4-alkyl, phenyl, furyl, a fused- Le A 35 591-Foreign Countries 95 on benzene ring or by two substituents which together with the C atom to which they are attached form a 5- or 6-membered carbocycle, R13 represents hydrogen, cyano, halogen, or represents in each case 5 optionally fluorine-, chlorine- and/or bromine-substituted Ci-C4-alkyl, C3-C6-cycloalkyl or phenyl, R14 represents hydrogen, optionally hydroxyl-, cyano-, halogen- or C1-C4- alkoxy-substituted C1-C6-alkyl, C3-C6-cycloalkyl or tri-( C1-C4-alkyl)- 10 silyl, R15 represents hydrogen, cyano, halogen, or represents in each case optionally fluorine-, chlorine- and/or bromine-substituted Ci-C4-alkyl, C3-C6-cycloalkyl or phenyl, 15 X1 represents nitro, cyano, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy, X2 represents hydrogen, cyano, nitro, halogen, C1-C4-alkyl, C1-C4- 20 haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy, X3 represents hydrogen, cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy, 25 and/or one of the following compounds defined by general formulae of the general formula (IId) Le A 35 591-Foreign Countries 96- 17 R I V" V*f ^ R1 R18 k^\ M> SO, O r^N ■(x4). (Ed) or of the general formula (He) (x5)n .19 *N ,20 O SO ,16 R- ^^ o I "(X4)n (He) where n represents a number between 0 and 5, 10 R16 represents hydrogen or C1-C4-alkyl, R17 represents hydrogen or C1-C4-alkyl, 15 20 R 18 represents hydrogen, in each case optionally cyano-, halogen- or C1-C4-alkoxy-substituted C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C4-alkylamino or di-(C1-C4-alkyl)-amino, or in each case optionally cyano-, halogen- or C1-C4-alkyl-substituted C3-C6-cycloalkyl, C3-C6-cycloalkyloxy, C3-C6-cycloalkylthio or C3-C6-cycloalkylamino, 19 R represents hydrogen, optionally cyano-, hydroxyl-, halogen- or C1-C4-alkoxy-substituted Ci-C6-alkyl, in each case optionally cyano- or Le A 35 591-Foreign Countries 97- halogen-substituted C3-C6-alkenyl or C3-C6-alkinyl, or optionally cyano-, halogen- or C1-C4-alkyl-substituted C3-C6-cycloalkyl, R20 represents hydrogen, optionally cyano-, hydroxyl-, halogen- or C1-C4- 5 alkoxy-substituted C1-C6-alkyl, in each case optionally cyano- or halogen-substituted C3-C6-alkenyl or C3-C6-alkinyl, optionally cyano-, halogen- or C1-C4-alkyl-substituted C3-C6-cycloalkyl, or optionally nitro-, cyano-, halogen-, C1-C4-alkyl-, C1-C4-haloalkyl-, C1-C4-alkoxy- or C1-C4-haloalkoxy-substituted phenyl, or together with R19 10 represents in each case optionally C1-C4-alkyl-substituted C2-C6- alkanediyl or C2-C5-oxaalkanediyl, X4 represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy 15 or C1-C4-haloalkoxy, and X5 represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy. 20 2. Compositions according to Claim 1 where, in formula (I) X represents halogen, C1-C6-alkyl, C2-C6-alkenyl, C1-C6-haloalkyl, C1-C6-alkoxy, C3-C6-alkenyloxy, C1-C6-haloalkoxy, C3-C6-halo- 25 alkenyloxy, nitro or cyano, Z represents hydrogen, C2-C6-alkenyl, C2-C6-alkinyl or represents one of the radicals Le A 35 591-Foreign Countries -98- vJ V* V v^ V in which V1 represents hydrogen, halogen, C1-C12-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulphinyl, C1-C6-alkylsulphonyl, C1-C4-haloalkyl, C1-C4-haloalkoxy, nitro or cyano, 10 V2 and V3 independently of one another represent hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-haloalkyl or C1-C4-haloalkoxy, 15 W and Y independently of one another represent hydrogen, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, nitro or cyano, 20 with the proviso that, if Y represents 4-methyl, W and X do not simultaneously represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl, CKE represents one of the groups O" Le A 35 591-Foreign Countries 99 Oi A B 0 -G ^ 0 (3), A D : G o o (4), 10 represents hydrogen or in each case optionally halogen-substituted C1-C12-alkyl, C3-C8-alkenyl, C1-C10-alkoxy- C1-C8-alkyl, C1-C10-alkylthio- C1-C6-alkyl, optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-Cg-cycloalkyl, in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-haloalkyl-, C1-C6-alkoxy-, C1-C6-haloalkoxyl, cyano- or nitro-substituted phenyl or phenyl- C1-C6-alkyl, and B represents hydrogen, C1-C12-alkyl or C1-C8-alkoxy- C1-C6-alkyl, or 15 20 A, B and the carbon atom to which they are attached represent saturated C3-C10-cycloalkyl or unsaturated C5-C10-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which are optionally mono- or disubstituted by C1-C8-alkyl, C3-C10-cycloalkyl, C1-C8-haloalkyl, C1-C8-alkoxy, C1-C8-alkylthio, halogen or phenyl, or A, B and the carbon atom to which they are attached represent C3-C6-cycloalkyl which is substituted by an alkylenediyl or by an alkylenedioxyl or by an alkylenedithioyl group which, with the carbon Le A 35 591-Foreign Countries -100- atom to which it is attached, forms a further five- to eight-membered ring and which is optionally substituted by C1-C4alkyl which optionally contain one or two not directly adjacent oxygen and/or sulphur atoms, or 5 A, B and the carbon atom to which they are attached represent C3-C8- cycloalkyl or C5-Cg-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent in each case optionally C1-C6-alkyl-, C1-C6-alkoxy- or halogen-substituted 10 C2-C6-alkanediyl, C2-C6-alkenediyl or C4-C6-alkanedienediyl in which optionally one methylene group is replaced by oxygen or sulphur, and D represents hydrogen, in each case optionally halogen-substituted 15 C1-C12-alkyl, C3-C8-alkenyl, C3-C8-alkinyl, C1-C10-alkoxy-C2-C8- alkyl, optionally halogen-, C1-C4-alkyl-, C1-C4alkoxy- or C1-C4- haloalkyl-substituted C3-Cg-cycloalkyl, in which optionally one ring member is replaced by oxygen or sulphur or in each case optionally halogen-, C1-C6-alkyl-, C1-C6-haloalkyl-, CrC6-alkoxy-, C1-C6- 20 haloalkoxy-, cyano- or nitro-substituted phenyl or phenyl- C1-C6-alkyl, or A and D together represent in each case optionally substituted C3-C6- alkanediyl or C3-Cg-alkenediyl in which optionally one methylene 25 group is replaced by a carbonyl group, by oxygen or by sulphur, possible substituents being in each case: halogen, hydroxyl, mercapto or in each case optionally halogen- substituted C1-C10-alkyl or C1-C6-alkoxy, or a further C3-C6- 30 alkanediyl grouping, C3-C6-alkenediyl grouping or a butadienyl grouping which is optionally substituted by C1-C6-alkyl or in which Le A 35 591-Foreign Countries -101 optionally two adjacent substituents together with the carbon atoms to which they are attached form a further saturated or unsaturated cycle having 5 or 6 ring atoms, which may contain oxygen or sulphur, or 5 A and Q1 together represent C3-C6-alkanediyl or C4-C6-alkenediyl, each of which is optionally mono- or disubstituted by identical or different halogens, by C1-C10-alkyl, C1-C6-alkoxy, C1-C6-alkylthio or C3-C7- cycloalkyl, each of which is optionally mono- to trisubstituted by identical or different halogens, or by benzyloxy or phenyl, each of 10 which is optionally mono- to trisubstituted by identical or different substituents from the group consisting of halogen, C1-C6-alkyl and C1-C6-alkoxy in which C3-C6-alkanediyl or C4-C6-alkenediyl is furthermore bridged by a C1-C2-alkanediyl group or by an oxygen atom, or 15 Q1 represents hydrogen or C1-C4-alkyl, and Q2, Q4, Q5 and Q6 independently of one another represent hydrogen or C1-C4-alkyl, 20 Q3 represents hydrogen, C1-C6-alkyl, C1-C6-alkoxy-C1-C2-alkyl, C1-C6- alkylthio-C1-C2-alkyl, optionally halogen-, C1-C6-alkyl- or C1-C4- alkoxy-substituted C3-Cg-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur or represents 25 optionally halogen-, C1-C4-alkyl-, C1-C4-alkoxy-, C1-C2-haloalkyl-, C1-C2-haloalkoxy-, cyano- or nitro-substituted phenyl, or Q3 and Q4 together with the carbon atom to which they are attached represent an optionally C1-C4-alkyl-, C1-C4-alkoxy- or C1-C2-haloalkyl- 30 substituted C3-C7-ring in which optionally one ring atom is replaced by oxygen or sulphur, Le A 35 591-Foreign Countries -102 G represents hydrogen (a) or represents one of the groups 0 L R4 ^R1 (b), ^M'R2 (C). ^'^^(d), "/V (e)> R6 E (f) or L R (9) 10 in which E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur, M represents oxygen or sulphur, R1 represents in each case optionally halogen-substituted Ci-C2o-alkyl, C2-C20-alkenyl, C1-C8-alkoxy- C1-C8-alkyl, C1-C8-alkylthio- C1-C8- 15 alkyl, poly- C1-C8-alkoxy- C1-C8-alkyl or optionally halogen-, C1-C6 alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl, in which optionally one or more (preferably not more than two) not directly adjacent ring members are replaced by oxygen and/or sulphur, 20 represents optionally halogen-, cyano-, nitro-, C1-C6-alkyl-, C1-C6 alkoxy-, C1-C6-haloalkyl-, C1-C6-haloalkoxy-, C1-C6-alkylthio- or C1-C6-alkylsulphonyl-substituted phenyl, represents optionally halogen-, nitro-, cyano-, C1-C6-alkyl-, C1-C6 alkoxy-, C1-C6-haloalkyl- or C1-C6-haloalkoxy-substituted phenyl- 25 C1-C6-alkyl, Le A 35 591-Foreign Countries -103- represents optionally halogen- or C1-C6-alkyl-substituted 5- or 6-membered hetaryl (for example pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl or thienyl), 5 represents optionally halogen- or C1-C6-alkyl-substituted phenoxy- CrC6-alkyl or represents optionally halogen-, amino- or C1-C6-alkyl-substituted 5- or 6-membered hetaryloxy- C1-C6-alkyl (for example pyridyloxy- 10 C1-C6-alkyl, pyrimidyloxy- C1-C6-alkyl or thiazolyloxy- C1-C6-alkyl), R2 represents in each case optionally halogen-substituted C1-C20-alkyl, C2-C20-alkenyl, C1-C8-alkoxy-C2-Cg-alkyl, poly- C1-C8-alkoxy-C2-C8-alkyl, 15 represents optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl or represents in each case optionally halogen-, cyano-, nitro-, C1-C6- 20 alkyl-, C1-C6-alkoxy-, C1-C6-haloalkyl- or C1-C6-haloalkoxy- substituted phenyl or benzyl, and R3 represents optionally halogen-substituted C1-C8-alkyl or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4- 25 haloalkyl-, C1-C4-haloalkoxy-, cyano- or nitro-substituted phenyl or benzyl, and R4 and R5 independently of one another represent in each case optionally halogen-substituted C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylamino, 30 di-(C1-C8-alkyl)amino, C1-C8-alkylthio, C2-C8-alkenylthio, C3-C7- cycloalkylthio or represent in each case optionally halogen-, nitro-, Le A 35 591-Foreign Countries 104- cyano-, C1-C4-alkoxy-, C1-C4-haloalkoxy-, C1-C4-alkylthio-, C1-C4-haloalkylthio-, C1-C4-alkyl- or C1-C4-haloalkyl-substituted phenyl, phenoxy or phenylthio, and 5 R6 and R7 independently of one another represent hydrogen, represent in each case optionally halogen-substituted C1-C8-alkyl, C3-C8-cycloalkyl, C1-C8-alkoxy, C3-C8-alkenyl, C1-C8-alkoxy- C1-C8-alkyl, represent optionally halogen-, C1-C8-haloalkyl-, C1-C8-alkyl- or C1-C8- alkoxy-substituted phenyl, optionally halogen-, C1-C8-alkyl-, C1-C8- 10 haloalkyl- or C1-C8-alkoxy-substituted benzyl or together represent an optionally C1-C4-alkyl-substituted C3-C6-alkylene radical in which optionally one carbon atom is replaced by oxygen or sulphur. 3. Compositions according to Claim 1, in which, in formula (I) 15 X represents fluorine, chlorine, bromine, C1-C4-alkyl, C2-C4-alkenyl, C1-C4-alkoxy, trifiuoromethyl, trifluoromethoxy, trifluoroethoxy or cyano, 20 Z represents hydrogen, C2-C4-alkenyl, C2-C4-alkinyl or represents the radical 25 V1 represents hydrogen, fluorine, chlorine, bromine, C1-C6-alkyl, C1-C4- alkoxy, C1-C2-haloalkyl, C1-C2-haloalkoxy, nitro or cyano, V2 represents hydrogen, fluorine, chlorine, bromine, C1-C4-alkyl, C1-C4-alkoxy, C1-C2-haloalkyl or C1-C2-haloalkoxy, Le A 35 591-Foreign Countries -105 W and Y independently of one another represent hydrogen, fluorine, chlorine, bromine, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy, with the proviso that, if Y represents 4-methyl, W and X do not simultaneously represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl and 10 with the proviso that X does not represent alkenyl if Z does not represent hydrogen, CKE represents one of the groups 15 (3), O 0 (4), (5), (6). 20 Le A 35 591-Foreign Countries 106 A represents hydrogen, in each case optionally fluorine- or chlorine-substituted C1-C6-alkyl, C1-C4-alkoxy- C1-C4-alkyl or optionally fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy-substituted C3-C7-cycloalkyl, and 5 B represents hydrogen or C1-C6-alkyl, or A, B and the carbon atom to which they are attached represent saturated C3-C7-cycloalkyl or unsaturated C5-C7-cycloalkyl in which optionally 10 one ring member is replaced by oxygen or sulphur and which is optionally monosubstituted by C1-C4-alkyl, C1-C3-haloalkyl or C1-C6-alkoxy, or A, B and the carbon atom to which they are attached represent C5-C6- 15 cycloalkyl which is substituted by an alkylenediyl or by an alkylene- dioxy or by an alkylenedithiol group which, together with the carbon atom to which it is attached, forms a further five- or six-membered ring and which is optionally substituted by methyl or ethyl and optionally contains one or two not directly adjacent oxygen or sulphur 20 atoms, or A, B and the carbon atom to which they are attached represent C3-C6- cycloalkyl or C5-C6-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent in each 25 case optionally C1-C5-alkyl-, C1-C5-alkoxy-, fluorine-, chlorine- or bromine-substituted C2-C4-alkanediyl, C2-C4-alkenediyl in which optionally one methylene group is replaced by oxygen or sulphur or represent butadienediyl, and 30 D represents hydrogen, represents in each case optionally fluorine- or chlorine-substituted C1-C6-alkyl, C3-C6-alkenyl, C1-C4-alkoxy- Le A 35 591-Foreign Countries -107- C2-C3-alkyl, represents optionally C1-C4-alkyl-, C1-C4-alkoxy- or C1-C2-haloalkyl-substituted C3-C7-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur or (but not in the case of compounds of the formula ,G0 X u o w K (1-1)) represents in each case optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C4-haloalkyl-, C1-C4-alkoxy- or C1-C4- 10 haloalkoxy-substituted phenyl, pyridyl or benzyl, or A and D together represent optionally substituted C3-C5-alkanediyl in which one methylene group may be replaced by oxygen or sulphur, possible substituents being Ci-C4-alkyl, or 15 A and D (in the case of the compounds of the formula 0 x u 0 w £ (1-1)) 20 together with the atoms to which they are attached represent one of the groups AD-1 to AD-10: Le A 35 591-Foreign Countries 108- N r^V N' AD-1 AD-2 AD-3 ^V^ N' N' AD-4 AD-5 AD-6 N' AD-7 AD-8 AD-9 10 AD-10 or A and Q1 together represent C3-C4-alkanediyl or C3-C4-alkenediyl, each of which is optionally mono- or disubstituted by identical or different substituents from the group consisting of C1-C4-alkyl and C1-C4-alkoxy, or Q1 represents hydrogen, and Q2 represents hydrogen, and Le A 35 591-Foreign Countries 109 Q4, Q5 and Q6 independently of one another represent hydrogen or C1-C2-alkyl, and Q3 represents hydrogen, C1-C4-alkyl, C1-C4-alkoxy-C1-C2-alkyl, C1-C4- 5 alkylthio-C1-C2-alkyl or optionally methyl- or methoxy-substituted C3-C6-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur, or Q3 and Q4 together with the carbon to which they are attached represent an 10 optionally C1-C4-alkyl- or C1-C4-alkoxy-substituted saturated C5-C6- ring in which optionally one ring member is replaced by oxygen or sulphur, and G represents hydrogen (a) or represents one of the groups O L R4 ^R1 (b), /^M'R2(c), /S°^R3(d), 7/^5(e), 15 RD E (f) °r y^ (g), in which E represents a metal ion equivalent or an ammonium ion, 20 L represents oxygen or sulphur, M represents oxygen or sulphur, 25 R.1 represents in each case optionally fluorine- or chlorine-substituted C1-C16-alkyl, C2-C16-alkenyl, C1-C6-alkoxy- C1-C4-alkyl, C1-C6-alkylthio- C1-C6-alkyl or optionally fluorine-, chlorine-, C1-C4-alkyl- Le A 35 591-Foreign Countries 110 or C1-C4-alkoxy-substituted C3-C7-cycloalkyl in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur, 5 represents optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4-aIkyl-, C1-C4-alkoxy-, C1-C3-haloalkyl- or C1-C3-haloalkoxy-substituted phenyl, R2 represents in each case optionally fluorine-substituted C1-C16-alkyl 10 C2-C16-alkenyl or C1-C6-alkoxy-C2-C6-alkyl, represents optionally fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy-substituted C3-C7-cycloalkyl, or 15 represents in each case optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4-alkyl-, C1-C3-alkoxy-, C1-C3-haloalkyl- or C1-C3-haloalkoxy-substituted phenyl or benzyl, R3 represents optionally fluorine-substituted C1-C6-alkyl or represents 20 optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C4alkoxy-, C1-C3-haloalkyl-, C1-C3-haloalkoxy-, cyano- or nitro-substituted phenyl, R4 represents C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylamino, di- 25 (C1-C6-alkyl)amino, C1-C6-alkylthio, C3-C4-alkenylthio, C3-C6- cycloalkylthio or represents in each case optionally fluorine-, chlorine-, bromine-, nitro-, cyano-, C1-C3-alkoxy-, C1-C3-halo-alkoxy-, C1-C3-alkylthio-, C1-C3-haloalkylthio-, C1-C3-alkyl- or C1-C3-haloalkyl-substituted phenyl, phenoxy or phenylthio, 30 R5 represents C1-C6-alkoxy or C1-C6-alkylthio, Le A 35 591-Foreign Countries -111 10 R6 represents hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C1-C6-alkoxy, C3-C6-alkenyl, C1-C6-alkoxy- C1-C4-alkyl, represents optionally fluorine-, chlorine-, bromine-, C1-C3-haloalkyl-, C1-C4-alkyl- or C1-C4-alkoxy-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C3-haloalkyl- or C1-C4-alkoxy-substituted benzyl, and R7 represents Ci-C6-alkyl, C3-C6-alkenyl or Ci-C6-alkoxy-Ci-C4-alkyl, or R6 and R7 together represent an optionally methyl- or ethyl-substituted C4-C5-alkylene radical in which optionally one methylene group is replaced by oxygen or sulphur. 15 4. Compositions according to Claim 1, in which, in formula (I) X represents chlorine, bromine, methyl, ethyl, propyl, vinyl, ethinyl, methoxy, ethoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy or cyano, 20 Z represents hydrogen, vinyl, ethinyl or represents the radical v - 25 V1 represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, methoxy, ethoxy, n-propoxy, isopropoxy, trifluoromethyl, trifluoromethoxy, trifluoro-ethoxy or cyano, Le A 35 591-Foreign Countries -112- V2 represents hydrogen, fluorine, chlorine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy, 10 W and Y independently of one another represent hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, methoxy or ethoxy, with the proviso that, if Y represents 4-methyl, W and X do not simultaneously represent ethyl or W does not represent methoxy or difluoromethoxy if X represents ethyl and with the proviso that X does not represent vinyl or ethinyl if Z does not represent hydrogen, CKE represents one of the groups O B -G O (1), (2), Oi o- I G o (3), (5), D "0' o. Q Q 5 Q5 O Q (4), (6), 15 20 represents hydrogen, represents C1-C4-alkyl or Ci-C2-alkoxy-Ci-C2-alkyl, each of which is optionally mono- to trisubstituted by fluorine, or represents C3-Cg-cycloalkyl which is optionally monosubstituted by fluorine, methyl, ethyl or methoxy, Le A 35 591-Foreign Countries 113 B represents hydrogen, methyl or ethyl, or A, B and the carbon atom to which they are attached represent saturated C5-C6-cycloalkyl in which optionally one ring member is replaced by 5 oxygen or sulphur and which is optionally mono substituted by methyl, ethyl, propyl, isopropyl, trifluoromethyl, methoxy, ethoxy, propoxy, butoxy or isobutoxy, or A, B and the carbon atom to which they are attached represent C5-C6- 10 cycloalkyl which is substituted by an alkylenedioxyl group which contains two not directly adjacent oxygen atoms, D represents hydrogen, represents in each case optionally fluorine- or chlorine-substituted C1-C4-alkyl, C3-C4-alkenyl, C1-C2-alkoxy-C2- 15 C3-alkyl or C3-C6-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur, or (but not in the case of the compounds of the formula (1-1) (1-1)) 20 25 or represents phenyl or pyridyl, each of which is optionally mono-substituted by fluorine, chlorine, bromine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy, Le A 35 591-Foreign Countries 114- A and D together represent optionally substituted C3-C4-alkanediyl in which optionally one carbon atom is replaced by oxygen or sulphur and which is optionally substituted by methyl, or 5 A and D (in the case of compounds of the formula O W together with the atom to which they are attached represent the group 10 ^N' A and Q1 together represent C3-C4-alkanediyl which is optionally mono- or disubstituted by methyl or methoxy, or 15 Q1 represents hydrogen, Q2 represents hydrogen, 20 Q4, Q5 and Q6 independently of one another represent hydrogen or methyl, Q3 represents hydrogen, methyl, ethyl or C3-C6-cycloalkyl, or Le A 35 591-Foreign Countries -115 Q3 and Q4 together with the carbon to which they are attached represent an optionally methyl- or methoxy-substituted saturated C5-C6-ring in which optionally one ring member is replaced by oxygen or sulphur, G represents hydrogen (a) or represents one of the groups O L R4 ' R (b), /"M (C), / ? (d), // R5(e), E (f) or L %r (g), in which 10 E represents a metal ion equivalent or an ammonium ion, L represents oxygen, 15 M represents oxygen or sulphur, Rl represents C1-C10-alkyl, C2-C10-alkenyl, C1-C4-alkoxy-C1-C2- alkyl, C1-C4-alkylthio-C1-C2-alkyl each of which is optionally mono- to trisubstituted by fluorine or chlorine, or represents C3-C5-- 20 cycloalkyl which is optionally mono- to trisubstituted by fluorine, chlorine, methyl, ethyl or methoxy, represents phenyl which is optionally mono- or disubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, methoxy, trifluoro- 25 methyl or trifluoromethoxy, Le A 35 591-Foreign Countries 116 R2 represents C1-C10-alkyl, C2-C10-alkenyl or C1-C4-alkoxy-C2-C4-alkyl, each of which is optionally mono- to trisubstituted by fluorine, or 5 represents C3-Cg-cycloalkyl which is optionally monosubstituted by fluorine, methyl or methoxy, or represents phenyl or benzyl, each of which is optionally mono- or disubstituted by fluorine, chlorine, cyano, nitro, methyl, methoxy, 10 trifluoromethyl or trifiuoromethoxy, R3 represents methyl, ethyl, n-propyl, isopropyl, each of which is optionally mono- to trisubstituted by fluorine, or represents phenyl which is optionally monosubstituted by fluorine, chlorine, bromine, 15 methyl, tert-butyl, methoxy, trifluoromethyl, trifiuoromethoxy, cyano or nitro, R4 represents C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylamino, di- (C1-C4-alkyl)amino, C1-C4-alkylthio or represents phenyl, phenoxy 20 or phenylthio, each of which is optionally monosubstituted by fluorine, chlorine, bromine, nitro, cyano, C1-C2-alkoxy, C1-C2-fluoroalkoxy, C1-C2-alkylthio, C1-C2-fluoroalkylthio or C1-C3-alkyl, R5 represents C1-C3-alkoxy or C1-C3-alkylthio, 25 R^ represents hydrogen, represents C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-alkoxy, C3-C4-alkenyl, C1-C4-alkoxy- C1-C4-alkyl, represents phenyl which is optionally mono- or disubstituted by fluorine, chlorine, bromine, trifluoromethyl, methyl or methoxy, represents 30 benzyl which is optionally monosubstituted by fluorine, chlorine, bromine, methyl, trifluoromethyl or methoxy, Le A 35 591-Foreign Countries -117 - R^ represents C1-C4-alkyl, C3-C4-alkenyl or C1-C4-alkoxy-C1-C2-alkyl, or R6 and R7 together represent a C5-Cg-alkylene radical in which optionally 5 one methylene group is replaced by oxygen or sulphur. 5. Compositions according to Claim 4 in which, in formula (I), Z represents hydrogen and Y is located in the position para to the group CKE, or in which Z represents the group CI ^ {j j— in the position para or 10 meta to the group CKE. 6. Compositions according to any of Claims 1 to 5 in which, in formulae (Ha), (lib), (lie), (Ed), and (He) 15 n represents the number 0,1, 2, 3 or 4, A1 represents one of the divalent heterocyclic groupings shown below 20 A2 represents in each case optionally methyl-, ethyl-, methoxycarbonyl-or ethoxycarbonyl-substituted methylene or ethylene, o R represents hydroxyl, mercapto, amino, methoxy, ethoxy, n- or i- 25 propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i-propylthio, Le A 35 591-Foreign Countries 118 n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino or diethylamino, R9 represents hydroxyl, mercapto, amino, methoxy, ethoxy, n- or 5 i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i- propylthio, n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino or diethylamino, 10 R10 represents in each case optionally fluorine-, chlorine- and/or bromine- substituted methyl, ethyl, n- or i-propyl, R11 represents hydrogen, in each case optionally fluorine- and/or chlorine- substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, 15 butenyl, propinyl or butinyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine-, methyl-, ethyl-, n- or i-propyl, n-, i-, s- or t-butyl-substituted phenyl, 20 R12 represents hydrogen, in each case optionally fluorine- and/or chlorine- substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, propinyl or butinyl, methoxymethyl, ethoxymethyl, methoxyethyl, ethoxyethyl, dioxolanylmethyl, furyl, furylmethyl, thienyl, thiazolyl, piperidinyl, or optionally fluorine-, chlorine-, 25 methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-substituted phenyl, or together with R11 represents one of the radicals -CH2-0-CH2-CH2-and -CH2-CH2-O-CH2-CH2-, which are optionally substituted by methyl, ethyl, furyl, phenyl, a fused-on benzene ring or by two substituents which together with the C atom to which they are attached 30 form a 5- or 6-membered carbocycle, Le A 35 591-Foreign Countries -119- R represents hydrogen, cyano, fluorine, chlorine, bromine, or represents in each case optionally fluorine-, chlorine- and/or bromine-substituted methyl, ethyl, n- or i-propyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl or phenyl, 5 R14 represents hydrogen, optionally hydroxyl-, cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, 10 R15 represents hydrogen, cyano, fluorine, chlorine, bromine, or represents in each case optionally fluorine-, chlorine- and/or bromine-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl or phenyl, 15 X1 represents nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloromethyl, trifluoromethyl, trichloromethyl, chlorodifluoromethyl, fluoro-dichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifiuoromethoxy, 20 X2 represents hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloro methyl, trifluoromethyl, trichloromethyl, chlorodifluoromethyl, fluoro- dichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or 25 trifiuoromethoxy, X3 represents hydrogen, nitro, cyano, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, dichloro methyl, trifluoromethyl, trichloromethyl, chlorodifluoromethyl, 30 fluorodichloromethyl, methoxy, ethoxy, n- or i-propoxy, difluoro- methoxy or trifiuoromethoxy, Le A 35 591-Foreign Countries 120- R16 represents hydrogen, methyl, ethyl, n- or i-propyl, R17 represents hydrogen, methyl, ethyl, n- or i-propyl, 5 R18 represents hydrogen, in each case optionally cyano-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy, ethoxy, n- or i- propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i-propylthio, 10 n-, i-, s- or t-butylthio, methylamino, ethylamino, n- or i-propylarnino, n-, i-, s- or t-butylamino, dimethylamino or diethylamino, or in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, 15 cyclohexyloxy, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio, cyclopropylamino, cyclobutylamino, cyclo-pentylamino or cyclohexylamino, R19 represents hydrogen, in each case optionally cyano-, hydroxyl-, 20 fluorine-, chlorine, methoxy-, ethoxy-, n- or i-propoxy-substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl, in each case optionally cyano-, fluorine-, chlorine- or bromine-substituted propenyl, butenyl, propinyl or butinyl, or in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-substituted 25 cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, R20 represents hydrogen, represents in each case optionally cyano-, hydroxyl-, fluorine-, chlorine-, methoxy-, ethoxy-, n- or i-propoxy- substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl, in each case 30 optionally cyano-, fluorine-, chlorine- or bromine-substituted propenyl, butenyl, propinyl or butinyl, in each case optionally cyano-, Le A 35 591-Foreign Countries -121 fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl- substituted cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, or optionally nitro-, cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-, methoxy-, 5 ethoxy-, n- or i-propoxy-, difluoromethoxy- or trifluoromethoxy- substituted phenyl, or together with R19 represents in each case optionally methyl- or ethyl-substituted butane-1,4-diyl (trimethylene), pentane-l,5-diyl, 1-oxa-butane-1,4-diyl or 3-oxa-pentane-l,5-diyl, 10 X4 represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy, and 15 X5 represents nitro, cyano, carboxyl, carbamoyl, formyl, sulphamoyl, hydroxyl, amino, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy or trifluoromethoxy. 20 7. Compositions according to any of Claims 1 to 5 in which the compound which improves crop plant compatibility is cloquintocet-mexyl, fenchlorazole-ethyl, isoxadifen-ethyl, mefenpyr-diethyl, furilazole, fenclorim, cumyluron, dymron, dimepiperate or the compound O O ^H, *N 25 S02 y ^ -CH3 O Le A 35 591-Foreign Countries 122 8. Compositions according to any one of Claims 1 to 5 in which the compound which improves crop plant compatibility is cloquintocet-mexyl or mefenpyr-di ethyl. 5 9. Compositions according to Claim 1, characterized in that from 0.05 to 10 parts by weight of the compound which improves crop plant compatibility are present per part by weight of the active compound of the formula (I). 10. Method for controlling undesirable vegetation, characterized in that a 10 composition according to Claim 1 is allowed to act on the plants and/or their habitat. 11. Use of a composition according to Claim 1 for controlling undesirable vegetation. - 123 - 12 Compositions substantially as hereinbefore described with reference to the foregoing examples. Dated this 24/7/2002 Le A 35 591-Foreign Countries -123 - Selective herbicides based on substituted cyclic ketoenols and safeners A b s t r a c t The present invention relates to selective herbicidal compositions comprising an effective amount of an active compound combination comprising (a) at least one substituted cyclic ketoenol of the formula (I) (i) in which X, Z, W and Y and the group CKE are as defined in the description, and (b) at least one compound which improves crop plant compatibility selected from the group of compounds listed in the description, in particular cloquintocet- mexyl and mefenpyr-diethyl. The invention furthermore relates to the use of these compositions as herbicides and to a method for controlling undesirable vegetation using these compositions.

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