Title of Invention

A DECORATIVE SHEET, A MOLDED ARTICLE FOR A PRODUCTION METHOD OF THE MOLDED ARTICLE .

Abstract The invention relates to a decorative sheet (10) comprising a base member (1), formed from a resin material having a first and a second principal surfaces (1a, 1b) opposite to each other; a decoration layer (2), provided on the first principal surface (1a) of the base member (1), having a pattern area (2a) representing a predetermined pattern; and a spread suppressing member (3), provided in a position corresponding to the pattern area (2a) on the side of the first principal surface (1a) or on the side of the second principal surface (1b) of the base member (l), for suppressing the spreading of the pattern area (2a) of the decoration layer (2). The spread suppressing member (3) has a higher coefficient of thermal conductivity than a coefficient of the thermal conductivity of the base member (1).
Full Text DESCRIPTION
TECHNICAL FIELD
The present invention relates to a molded article which is decorated, and
a production method thereof. The present invention also relates to a
decorative sheet used for decorating such a molded article, and a motor
vehicle provided with such a molded article.
BACKGROUND ART
Recently, as a technique for decorating various kinds of molded articles,
a technique for attaching a decorative sheet onto a surface of a molded
article is proposed. The decorative sheet used in this technique is
disclosed in Japanese Laid-Open Patent Publication No.10-249999, for
example.
The decorative sheet disclosed in the above-identified publication
includes a base member and an ink layer formed on a surface of the base
member by printing. The decorative sheet is attached to a molded article

with an adhesive. When such a decorative sheet is used, the molded
article can be easily recycled as compared with the case of paint
application using a coating material. In addition, such a decorative sheet
can create beautiful appearance which is different from the paint
application, so that a decorative quality can be improved.
A conventional decorative sheet is, however, suitable for the decoration
of a molded article having a flat surface, but is not suitable for the
decoration of a molded article having an uneven surface. When such a
decorative sheet is attached to a molded article having an uneven
surface, the decorative sheet is spread so as to follow the unevenness.
Therefore, if a pattern of a character, a graphic symbol, a picture, and
the like is represented in part of the decorative sheet, the pattern is
deformed, and the decorative appearance is uglified.
The present invention has been conducted in view of the above-described
problems, and the object of the present invention is to provide a
decorative sheet preferably used for the decoration of a molded article
having an uneven surface, a molded article to which the decorative sheet
is attached, a production method thereof, and a motor vehicle provided
with such a molded article.
DISCLOSURE OF INVENTION
The decorative sheet of the present invention includes: a base member,
formed from a resin material, having a first and a second principal
surfaces opposite to each other; a decoration layer, provided on the first
principal surface of the base member, having a pattern area representing
a predetermined pattern; and a spread suppressing member, provided in a
position corresponding to the pattern area on the side of the first
principal surface or on the side of the second principal surface of the
base member, for suppressing the spreading of the pattern area of the
decoration layer, thereby attaining the above-mentioned object.
In one preferred embodiment, the resin material is a thermoplastic resin
material.
In one preferred embodiment, the spread suppressing member has a
higher coefficient of thermal conductivity than a coefficient of thermal
conductivity of the base member.
In one preferred embodiment, the spread suppressing member is formed
from a material including metal or a metal compound.

In one preferred embodiment, the spread suppressing member is formed
of metal.
In one preferred embodiment, a coefficient of thermal conductivity of
the spread suppressing member is 10 W/m. K or more.
Preferably, a thickness of the spread suppressing member is 5 µ m or
more and 100 µ m or less.
Preferably, the spread suppressing member includes a first portion
which overlaps the pattern area.
More preferably, the spread suppressing member includes a second
portion positioned in an outer circumference of the first portion.
Preferably, a width of the second portion of the spread suppressing
member is 1 mm or more and 10 mm or less.
More preferably, a width of the second portion of the spread
suppressing member is 2 mm or more and 8 mm or less.
The molded article according to the present invention includes a molded
article body and the decorative sheet with the above-described structure
which is joined to a surface of the molded article body, thereby
attaining the above-mentioned object.
In another aspect, the molded article according to the present invention
includes: a molded article body; and a sheet joined to a surface of the
molded article body, wherein the sheet includes a base member and a
decoration layer provided on a face of the base member on the side of
the molded article body, the decoration layer has a pattern area
representing a predetermined pattern, and a portion of the sheet
corresponding to the pattern area has a thickness which is 1.1 times or
more and 1.8 times or less as large as a thickness of the other portion of
the sheet, thereby attaining the above-mentioned object.
Preferably, the portion of the sheet corresponding to the pattern area has
a thickness which is 1.2 times or more and 1.6 times or less as large as
the thickness of the other portion of the sheet.
The motor vehicle according to the present invention includes the
molded article having the above-described structure, thereby attaining
the above-mentioned object.
The production method of a molded article according to the present
invention includes the steps of: preparing a decorative sheet including:
a base member, formed from a resin material, having a first and a
second principal surfaces opposite to each other; a decoration layer,
provided on the first principal surface of the base member, having a
pattern area representing a predetermined pattern; and a spread
suppressing member, provided in a position corresponding to the pattern
area on the side of the first principal surface or on the side of the
second principal surface of the base member, for suppressing the
spreading of the pattern area of the decoration layer; preparing a molded
article body; and joining the decorative sheet to a surface of the molded
article body, thereby attaining the above-mentioned object.
In one preferred embodiment, the production method of a molded article
according to the present invention includes, before the step of joining
the decorative sheet to the surface of the molded article body, the step
of heating the decorative sheet.
In one preferred embodiment, the resin material is a thermoplastic resin
material.
In one preferred embodiment, the spread suppressing member has a
higher coefficient of thermal conductivity than a coefficient of thermal
conductivity of the base member.
In one preferred embodiment, the spread suppressing member is formed
form a material including metal or a metal compound.
In one preferred embodiment, the spread suppressing member is formed
of metal.
In one preferred embodiment, the coefficient of thermal conductivity of
the spread suppressing member is 10 W/m • K or more.
Preferably, a thickness of the spread suppressing member is 5 µ m or
more and 100 µ m or less.
Preferably, the spread suppressing member has a first portion which
overlaps the pattern area.
More preferably, the spread suppressing member includes a second
portion positioned in an outer circumference of the first portion.
Preferably, a width of the second portion of the spread suppressing
member is 1 mm or more and 10 mm or less.
More preferably, a width of the second portion of the spread
suppressing member is 2 mm or more and 8 mm or less.
In one preferred embodiment, the step of joining the decorative sheet to
the surface of the molded article body includes the step of moving the
heated decorative sheet closer to the molded article body, and the step
of reducing a pressure of a first space formed between the decorative
sheet coming closer to the molded article body and the molded article
body as compared with a pressure of a second space expanded
oppositely to the first space with respect to the decorative sheet.
In one preferred embodiment, the step of moving the decorative sheet
closer to the molded article body is performed in such a manner that the
spread suppressing member faces the second space.
In one preferred embodiment, in the production method of a molded
article according to the present invention includes, after the step of
moving the decorative sheet closer to the molded body, the step of
cooling the spread suppressing member by introducing a gas into the
second space.
In one preferred embodiment, the production method of a molded article
according to the present invention includes, after the step of joining the
decorative sheet to the surface of the molded body, the step of removing
the spread suppressing member.
In one preferred embodiment, the spread suppressing member is
provided on the side of the second principal surface of the base member.
In one preferred embodiment, after the step of joining the decorative
sheet to the surface of the molded article body, the decoration layer is
positioned between the base member and the molded article body.
In one preferred embodiment, the molded article body includes a first
member and a second member disposed on a surface of the first member,
and in the step of joining the decorative sheet to the surface of the
molded article body, the decorative sheet is joined to the surface of the
molded article body so as to cover both of the first member and the
second member, thereby joining the first member and the second
member.
In another aspect, the production method of a molded article according
to the present invention includes the steps of: preparing a decorative
sheet including a base member, formed from a resin material, having a
first and a second principal surfaces opposite to each other, and a
decoration layer, provided on the first principal surface of the base
member, having a pattern area representing a predetermined pattern;
preparing a molded article body; heating the decorative sheet; and
joining the decorative sheet which is heated to a surface of the molded
article body in a condition where a temperature of a portion of the
decorative sheet corresponding to the pattern area is lower than a
temperature of the other portion of the decorative sheet, thereby
attaining the above-mentioned object.
In one preferred embodiment, the step of joining the decorative sheet to
the surface of the molded article body includes the step of cooling the
decorative sheet in such a manner that the temperature of the portion
corresponding to the pattern area is rapidly lowered as compared with
the temperature of the other portion.
In one preferred embodiment, the decorative sheet further includes a
member, provided in a position corresponding to the pattern area on the
side of the first principal surface or on the side of the second principal
surface of the base member, having a higher coefficient of thermal
conductivity than a coefficient of thermal conductivity of the base
member.
In one preferred embodiment, the member is formed from a material
including metal.
In one preferred embodiment, the member is formed of metal.
In one preferred embodiment, a coefficient of thermal conductivity of
the member is 10 W/m • K or more.
The motor vehicle according to the present invention includes the
molded article produced by the above-described production method,
thereby attaining the above-mentioned object.
BRIEF DESCRIPTION OF DRAWINGS
FIG. 1(a) is a sectional view schematically showing a decorative sheet
according to the present invention, and FIG. 1(b) is a top view
schematically showing the decorative sheet according to the present
invention.
FIGS. 2(a) and (b) are views showing exemplary patterns represented by
a pattern area of a decoration layer.
FIG. 3 is a sectional view schematically showing another embodiment of
a decorative sheet according to the present invention.
FIGS. 4(a), (b), and (c) are views schematically showing one
embodiment of the use of the decorative sheet according to the present
invention.
FIG. 5 is a view schematically showing a preferred structure of a spread
suppressing member.
FIGS. 6(a) and (b) are views schematically showing an embodiment in
which the decorative sheet according to the present invention is joined to
a molded article body.
FIGS. 7(a) and (b) are views schematically showing another embodiment
in which the decorative sheet according to the present invention is joined
to a molded article.
FIG. 8 is a sectional view schematically showing a producing apparatus
used for producing a molded article with the decorative sheet according
to the present invention.
FIG. 9 is a process sectional view schematically showing a production
method of a molded article with the decorative sheet according to the
present invention.
FIG. 10 is a process sectional view schematically showing a production
method of a molded article with the decorative sheet according to the
present invention.
FIG. 11 is a process sectional view schematically showing a production
method of a molded article with the decorative sheet according to the
present invention.
FIG. 12 is a process sectional view schematically showing a production
method of a molded article with the decorative sheet according to the
present invention.
FIG. 13 is a process sectional view schematically showing a production
method of a molded article with the decorative sheet according to the
present invention.
FIG. 14 is a process sectional view schematically showing a production
method of a molded article with the decorative sheet according to the
present invention.
FIG. 15 is a time chart showing an exemplary time required for a
production process.
FIG. 16 is a sectional view schematically showing a molded article.
FIG. 17 is a sectional view schematically showing a molded article.
FIG. 18(a) and (b) are sectional views schematically showing a
condition where a decorative sheet is joined to a molded article body
having a plurality of members which are separately molded.
FIG. 19 is a view schematically showing a two-wheeled vehicle.
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter embodiments of the present invention will be described with
reference to the accompanying drawings. The present invention is not
limited to the embodiments described below.
A decorative sheet 10 in this embodiment is schematically shown in
FIGS. 1(a) and (b). The decorative sheet 10 includes, as shown in FIGS.

1(a) and (b), a base member 1 having a first principal surface la and a
second principal surface lb which are opposite to each other, and a
decoration layer 2 provided on the first principal surface la of the base
member 1.
The base member 1 is formed from a resin material, and typically formed
from a thermoplastic resin material. The decoration layer 2 is formed
from ink, or the like. The decoration layer 2 includes a pattern area 2a
representing a predetermined pattern. The pattern represented by the
pattern area 2a is concretely a design such as a diagram, a color-coding,
or gradation, and more concretely a character shown in FIG. 2(a), a
graphic symbol shown in FIG. 2(b), or a picture.
FIGS. 1(a) and (b) show a case where the decoration layer 2 having the
pattern area 2a in an entire face thereof is provided on part of the
principal surface la. Alternatively, as shown in FIG. 3, the decoration
layer 2 having the pattern area 2a only in part may be provided on the
entire face of the principal surface la. An area 2b other than the pattern
area 2a of the decoration layer 2 is a monotone area without any pattern,
for example.
FIGS. 4(a), (b), and (c) show examples of the use of the decorative sheet
10. The decorative sheet 10 is joined to the surface of a molded article
body 21, so as to decorate the molded article 20, as shown in FIGS. 4(a),
(b), and (c). The decoration layer 2 has a pattern area 2a, so that high
decorating effects can be attained, as compared with a decoration layer
having no pattern area 2a (a monotone decoration layer without any
pattern as a whole, for example). In other words, the pattern area 2a is
an area of which accuracy as decoration is more highly required than the
other area of the decoration layer 2 after the joining to the molded
article body 21.
The molded article body 21 shown in FIG. 4(a) has a protruding portion
21a of a hemispherical shape (a bowl-like shape), and the surface is
uneven. Therefore, when the decorative sheet 10 is to be joined, the
decorative sheet 10 is spread so as to follow the unevenness. In order to
preferably perform the spread of the decorative sheet 10, typically, the
joining is performed after the decorative sheet 10 is heated and softened.
The decorative sheet 10 according to the present invention is provided
with a spread suppressing member 3 for suppressing the spread of the
pattern area 2a, as shown in FIGS. 1(a) and (b), and FIG. 3. The spread
suppressing member 3 is provided in a position corresponding to the
pattern area 2a. The spread suppressing member 3 in this embodiment is
provided so as to overlap the pattern area 2a on the side of the second
principal surface lb of the base member 1 (on the side opposite to the
side on which the decoration layer 2 is provided).
The spread suppressing member 3 is a member with lower spreading
property than that of the base member 1, for example, so that the spread
of the pattern region 2a is suppressed.
Alternatively, the spread suppressing member 3 has a higher coefficient
of thermal conductivity than a coefficient of thermal conductivity of the
base member 1, so that the spread of the pattern area 2a is suppressed.
If the coefficient of thermal conductivity of the spread suppressing
member 3 is higher than the coefficient of thermal conductivity of the
base member 1, a temperature of a portion of the decorative sheet 10 on
which the spread suppressing member 3 is provided lowers more rapidly
than the other portion after the heating. Thus, the spreading property is
lowered as compared with the other portion. Therefore, the spreading of
the pattern area 2a is suppressed.
It is understood that the spread suppressing member 3 preferably has
both of the above-described two physical properties, in order to
effectively suppress the spread of the pattern region 2a.
If the joining as shown in FIGS. 4(a) to (c) is performed by using a
conventional decorative sheet, the pattern such as a character, a graphic
symbol, or a picture is deformed, so that the beautiful appearance of the
molded article is uglified.
On the contrary, the decorative sheet 10 according to the present
invention includes the spread suppressing member 3, so that the spread
of the pattern region 2a in joining to the molded article body 21 can be
suppressed. Therefore, when the decoration of the molded article is
performed by using the decorative sheet 10 according to the present
invention, the deformation of the pattern can be prevented, and beautiful
appearance can be attained. The spread suppressing member 3 is
provided so as to overlap only part of the principal surface lb of the
base member 1 in accordance with the pattern area 2a (that is, provided
partially with respect to the principal surface of the base member 1), so
that the following property of the decorative sheet 10 for the unevenness
of the surface of the molded article body 21 is hardly degraded.
Hereinafter, preferable materials, structures, and layouts of the spread
suppressing member 3, the decoration layer 2, and the base member 1
will be described.
As a material for the spread suppressing member 3, metal such as
aluminum, copper, stainless can be preferably used. As the spread
suppressing member 3, a foil, a film, a thin plate, or the like formed of
any one of the above-mentioned metals may be preferably used.
Generally, a coefficient of thermal conductivity of metal is higher than a
coefficient of thermal conductivity of a resin by two or three digits. For
this reason, if metal is used as the material for the spread suppressing
member 3, the coefficient of thermal conductivity of the spread
suppressing member 3 can be sufficiently higher than the coefficient of
thermal conductivity of the base member 1 formed from a resin material.
Therefore, it is easy to rapidly lower the temperature of the portion of
the decorative sheet 10 in which the spread suppressing member 3 is
provided. Thus, it is possible to effectively suppress the spread of the
pattern area 2a.
The spread suppressing member 3 is not limited to that formed of metal.
Since metal or a metal compound has a much higher coefficient of
thermal conductivity than that of a resin, the coefficient of thermal
conductivity of the spread suppressing member 3 can be higher than the
coefficient of thermal conductivity of the base member 1 by using a
material including metal or a metal compound. As a material including
metal or a metal compound, for example, a material in which filler
(inorganic filler) formed from metal or a metal compound is dispersedly
mixed in a resin matrix is listed. As a metal compound which
constitutes filler, for example, a metal oxide such as alumina can be
used.
In order to rapidly lower the temperature of the portion of the decorative
sheet 10 in which the spread suppressing member 3 is provided, and to
effectively suppress the spread of the pattern region 2a, the coefficient
of thermal conductivity of the spread suppressing member 3 is preferably
equal to or 50 times, and more preferably equal to or 100 times as
compared with the coefficient of thermal conductivity of the base
member 1. Specifically, the coefficient of thermal conductivity of the
spread suppressing member 3 is preferably 10 W/m • K or more, more
preferably 15 W/m• K or more, and much more preferably 20 W/m • K.
The coefficient of thermal conductivity of a resin material is about 0.2
(the coefficient of thermal conductivity of polycarbonate is 0.19 W/m •
K, and the coefficient of thermal conductivity of acryl resin is 0.2 W/m
• K, for example). On the contrary, the coefficient of thermal
conductivity of alumina is 21 W/m • K, and the coefficient of thermal
conductivity of aluminum is 236 W/m • K.
Alternatively, as the material for the spread suppressing member 3, a
resin material can be used. If a resin material having a higher deflection
temperature under load (a heat deflection temperature) than that of a
resin material which forms the base member 1, or a resin material having
higher rigidity than that of a resin material which forms the base member
1, is used, the spreading property of the spread suppressing member 3
can be lower than that of the base member 1, so that the spread of the
pattern region 2a can be suppressed.
A thickness of the spread suppressing member 3 is preferably 5 µm or
more and 100 µm or less. If the thickness is lower than 5 µm, the
strength is failed, and deformation or breakage may occur. If the
thickness exceeds 100 µ m, in the case where metal is used as the
material, the following property of the spread suppressing member 3
with respect to the unevenness (convex and concave) of the molded

article body 21 is sometimes insufficient. Thus, there is a fear that the
spread suppressing member 3 may be peeled off in joining.
As shown in FIG. 5, the spread suppressing member 3 preferably has a
portion which overlaps the pattern area 2a (an overlap portion) 3a.
When the spread suppressing member 3 has such an overlap portion 3a,
the effect for suppressing the spread can be directly attained for the
pattern area 2a. Thus, the spreading of the pattern area 2a can be
effectively suppressed.
As shown in the figure, when the spread suppressing member 3 also has
a portion 3b which is positioned in an outer circumference of the overlap
portion 3a (an outer circumference portion), the spreading of the pattern
area 2a can be more surely suppressed. From the point of view that the
spreading of the pattern area 2a is effectively suppressed, and the
spreading of the portion other than the pattern area 2a is not prevented,
the width of the outer circumference portion 3b of the spread
suppressing member 3 is preferably 1 mm or more and 10 mm or less,
and more preferably 2 mm or more and 8 mm or less.
Even if the spread suppressing member 3 does not include a portion
overlapping the pattern area 2a, but has a frame-like shape fringing the
pattern area 2a, the spreading of the pattern area 2a can be suppressed.
However, as shown in FIG. 5, the case where the spread suppressing
member 3 has the portion 3a overlapping the pattern area 2a can attain
higher effect for suppressing the spreading of the pattern area 2a.
As a material of the decoration layer 2, ink including a resin material as

a binder and pigment dispersed in the resin material can be used, for
example. The decoration layer 2 can be formed by printing with such
ink. The material of the decoration layer 2 is preferably superior in heat
resistance and flexibility. The ink disclosed in Japanese Laid-Open
Patent Publication No.2002-275405 has superior heat resistance and
flexibility, so that the ink can be preferably used as the material for the
decoration layer 2.
As a resin material which forms the base member 1, a thermoplastic
resin material can be suitably used, as described above. More
specifically, polycarbonate (PC), acrylic resin, polyethylene
terephthalate (PET), urethane resin, or the like can be preferably used.
However, since the base member 1 is required to have rigidity as a sheet
base member, it is preferred that a resin material be selected in
consideration of this point. Although a thermosetting resin material can
be used as the resin material which forms the base member 1, it is
preferred that a thermoplastic resin material be used in view of the
formability of the decorative sheet 10.
A thickness of the base member 1 is preferably 100 µm or more and
1000 µ m or less. If the thickness of the base member 1 is less than 100
µ m, it is difficult to handle the base member as a sheet, or there may
occur a disadvantageous case where the strength is not sufficient and
breakage occurs in joining. If the thickness of the base member 1
exceeds 1000 µ m, the following property with respect to the surface of
the molded article body 21 may be deteriorated.
The joining of the decorative sheet 10 may be performed, as shown in
FIG. 6(a), in such a manner that the first principal surface 1a on which
the decoration layer 2 is provided faces the molded article body 21, or
alternatively as shown in FIG. 6(b), in such a manner that the second
principal surface 1b on the opposite side to the first principal surface la
faces the molded article body 21.
The spread suppressing member 3 may be provided, as shown in FIGS.
6(a) and (b), on the side of the second principal surface lb of the base
member 1 (the side on which the decoration layer 2 is not provided), or
alternatively provided, as shown in FIGS. 7(a) and (b), on the side of the
first principal surface la of the base member 1 (the side on which the
decoration layer 2 is provided). In the case where the spread
suppressing member 3 is provided on the side of the first principal
surface la, after the decoration layer 2 is formed on the spread
suppressing member 3 by printing or other means, the accumulated body
may be provided on the first principal surface la of the base member 1.
Alternatively, the spread suppressing member 3 may be provided on both
sides of the first principal surface la and the second principal surface lb
of the base member 1.
As shown in FIG. 6(a) and FIG. 7(a), when the joining is performed in
such a manner that the first principal surface la on which the decoration
layer 2 is provided faces the molded article body 21, the decoration layer
2 is positioned between the base member 1 and the molded article body
21 in the completed molded article, so that the decoration layer 2 can be
advantageously protected by the base member 1.
On the other hand, as shown in FIG. 6(b) and FIG. 7(b), when the
joining is performed in such a manner that the second principal surface
1b faces the molded article body 21, the decoration layer 2 is positioned
on the outer side than the base member 1. Therefore, there is an
advantage that in addition to a transparent resin material or a translucent
resin material, an opaque resin material can be preferably used as the
resin material for forming the base member 1.
As shown in FIG. 6(a) and FIG. 7(b), when the joining is performed in
such a manner that the spread suppressing member 3 is positioned on the
side opposite to the molded article body 21 with respect to the base
member 1, it is possible to remove the spread suppressing member 3
after the joining. It is possible to prevent the beautiful appearance from
being deteriorated because the spread suppressing member 3 remains in
the completed molded article. In addition, it is possible to neglect the
contribution of the spread suppressing member 3 to decoration in the
completed molded article, so that the material for the spread suppressing
member 3 can be more freely selected (it is unnecessary to use a
transparent or translucent material, for example). Thus, it is possible to
preferably use various materials such as metal.
Especially when the spread suppressing member 3 is provided on the
side of the second principal surface 1b of the base member 1 (on the side
opposite to the side on which the decoration layer 2 is provided), and the
joining is performed in such a manner that the first principal surface la
on which the decoration layer 2 is provided faces the molded article
body 21, as shown in FIG. 6(a), both of the advantages that the
decoration layer 2 can be protected by the base member 1 and that it is
possible to remove the spread suppressing member 3. Thus, large merits
in practical use can be attained.
For the fixing of the spread suppressing member 3 and the decorative
sheet 10, an adhesive is used, for example. As an adhesive, a
thermoplastic resin (thermoplastic polyurethane resin or thermoplastic
acrylic resin) can be used, or a thermosetting resin (an epoxy resin, for
example) can be used. When the decorative sheet 10 is heated before the
joining, the adhesive preferably has high heat resistance. In the case
where the spread suppressing member 3 is removed after the joining, it is
preferred that the adhesive used for joining the spread suppressing
member 3 be easily peeled off. As an adhesive which has high heat
resistance and which can be easily peeled off, an adhesive of silicone
type is listed specifically.
Next, a production method of a molded article using the decorative sheet
10 and a production apparatus used in the production method will be
described.
First, a production apparatus 100 for the molded article is described with
reference to FIG. 8. The production apparatus 100 includes, as shown in
FIG. 8, a holding device (a holding frame) 30 for holding the decorative
sheet 10, a supporting device (a supporting table) 31 for supporting the
molded article body 21, a pressurizing box 32 positioned above the
holding device 30 and the supporting device 31, a sealing cylinder 33 for
moving up and down the pressurizing box 32, a pressurizing rubber hose
34 for introducing a gas into a space below the pressurizing box 32, a
heater (a far infrared heater, for example) 35 for heating the decorative
sheet 10, and a vacuum vessel 36 for accommodating them.
The vacuum vessel 36 includes a first vessel 36a for accommodating the
holding device 30, the supporting device 31, the box 32, the cylinder 33,
and the rubber hose 34, and a second vessel 36b for accommodating the
heater 35. The heater 35 may be introduced into the first vessel 36a via
a door 37, if required.
The supporting device 31 has a plurality of openings 31a. With a
vacuum pump which is externally provided, the atmospheric air is
sucked through the openings 31a, thereby realizing a reduced pressure
(evacuation) of the space spreading over the supporting device 31. The
rubber hose 34 is connected to the outside. By introducing a gas through
the rubber hose 34, the space spreading below the box 32 can be
pressurized.
Next, with reference to FIGS. 9 to 15, a production method of a molded
article utilizing the decorative sheet 10 will be described. FIGS. 9 to 14
are process sectional views schematically showing the production
method of the molded article. FIG. 15 is a time chart showing an
example of periods of time required for respective steps.
First, the decorative sheet 10 such as shown in FIG. 1 is prepared. The
decorative sheet 10 can be prepared from the above-described materials
by known techniques. For example, the decorative sheet 10 can be
prepared in such a manner that a decoration layer 2 is formed by printing
with ink on a first principal surface 1a of a base member 1, and a spread
suppressing member 3 is fixed with an adhesive on the side of a second
principal surface 1b of the base member 1.
In a separate step from the step of preparing the decorative sheet 10, a
molded article body 21 is prepared. The molded article body 21 may be
formed from a resin material, or may be formed from a metal material.
Alternatively, the molded article body 21 may be formed from the other
materials (formed of wood, for example). The molded article body 21
may be transparent, opaque, or translucent. The molded article body 21
can be prepared by a known technique. In the case where a resin
material is used, the molded article body 21 can be prepared by injection
molding, for example. As the resin material, both of a thermoplastic
resin and a thermosetting resin can be used. Specifically, an unsaturated
polyester resin, an epoxy resin, a vinyl ester resin, a polyurethane resin,
and the like can be used.
Next, as shown in FIG. 9, the molded article body 21 is placed on the
supporting device 31, and the decorative sheet 10 is fixed to the holding
device 30 so that the decorative sheet 10 is positioned above the molded
article body 21. At this time, an adhesive is applied to a surface of the
decorative sheet 10 on the side of the molded article body 21. In this
embodiment, thereafter, the air in the vacuum vessel 35 is sucked
through the openings 31a of the supporting device 31 by means of the
vacuum pump which is externally provided. Thus, the pressure in the
inside of the vacuum vessel 35 is preliminarily reduced. As the result of
the pressure reduction, the internal pressure of the vacuum vessel 35 is
2.7 kPa or less, for example.
Next, as shown in FIG. 10, the decorative sheet 10 is heated by means of
the heater 35, thereby softening the decorative sheet 10. At this time,
the decorative sheet 10 is typically heated up to temperatures equal to or
higher than a deflection temperature under load of the resin material
which forms the base member 1. If the heating temperature is too low, it
is difficult to deform the resin material. Therefore, the resin material
may be broken in shaping (in attaching), or the shaping itself cannot be
performed. If the heating temperature is too high, sags of sheet in
heating remarkably occur, so that it is difficult to perform the shaping,
or the appearance may be degraded because of air bubbles in the resin
material. Therefore, it is preferred that the heating temperature be
appropriately set in accordance with the kind of the resin material of the
base member 1. When polycarbonate is used as the resin material for
forming the base member 1, the decorative sheet 10 is heated up to about
195°C, for example. The movement of the heater 35 from the second
vessel 36b to the first vessel 36a is performed in about 3 to 5 seconds,
for example. The heating by the heater 35 is performed for about 15 to
30 seconds, for example.
Thereafter, as shown in FIG. 11, the pressurizing box 32 and the holding
device 30 are moved downwardly by the cylinder 33, so that the
decorative sheet 10 comes closer to the molded article body 21. The
downward movement is performed in about 1 to 2 seconds, for example.
In this embodiment, the decorative sheet 10 is moved downwardly.
Alternatively, the supporting device 31 for supporting the molded article
body 21 may be moved upwardly, so that the decorative sheet 10 comes
closer to the molded article body 21.
Next, as shown in FIG. 12, a pressure of a first space formed between
the decorative sheet 10 and the molded article body 21 is more reduced
than a pressure of a second space expanded on the opposite side to the
first space with respect to the decorative sheet 10 (that is, a space
formed between the decorative sheet 10 and the pressurizing box 32).
As a result, the decorative sheet 10 is joined to the molded article body
21, as shown in FIG. 13.
Specifically, together with the reduction of pressure in the first space by
means of the vacuum pump, a gas is introduced into the box 32 through
the rubber hose 34, so as to pressurize the second space. As a result, the
decorative sheet 10 is pressed against the molded article body 21 with a
substantially uniform pressure, thereby joining the decorative sheet 10 to
the molded article body 21. The pressure reduction in the first space is
performed, so that the internal pressure of the first space is 2.7 kPa or
less, for example. The pressurizing of the second space is performed, so
that the internal pressure of the second space is about 0.2 MPa to 0.5
MPa. The reduced pressure condition of the first space and the
pressurized condition of the second space are retained for a
predetermined period of time (for 15 seconds or more, for example). A
temperature of the gas (the air, for example) introduced into the second
space is about a room temperature (15°C to 30°C), for example.
Next, the vacuum vessel 35 is opened, so that the internal pressure of the
vacuum vessel 35 is returned to be the atmospheric pressure.
Unnecessary portions of the decorative sheet 10 are cut (trimmed) with
cutting means such as a rotary blade. Thereafter, the molded article
body 21 is released from the supporting device 30, thereby completing a
molded article 20, as shown in FIG. 14.
According to the above-described production method, it is possible to
perform the joining of the decorative sheet 10 to the molded article body
21 (that is, the figuration of the decorative sheet 10) in a very short
period of time (in 1 second or less, as exemplarily described). In
addition, in joining, the decorative sheet 10 is entirely spread, but the
spreading of the pattern portion 2a of the decoration layer 2 is
suppressed by means of the spread suppressing member 3. Therefore,
the distortion of pattern is prevented, and the beauty in appearance is not
deteriorated.
When the spreading property of the spread suppressing member 3 is
poorer than the spreading property of the base member 1, the spreading
of the pattern portion 2a is suppressed for this reason. When the
coefficient of thermal conductivity of the spread suppressing member 3
is higher than the coefficient of thermal conductivity of the base member
1, the temperature of the portion of the decorative sheet 10 in which the
spread suppressing member 3 is provided (that is, the portion
corresponding to the pattern area 2a) more rapidly lowers than the
temperature of the other portion of the decorative sheet 10. Therefore,
the joining of the decorative sheet 10 is performed in a condition where
the temperature of the portion of the decorative sheet 10 corresponding
to the pattern area 2a is lower than the temperature of the other portion
of the decorative sheet 10. Therefore, the spreading of the pattern
portion 2a is suppressed.
When the heating by the heater 35 is stopped, the decorative sheet 10 is
naturally cooled (allowed to cool). As a result, the above-described non-
uniform temperature distribution of the decorative sheet 10 can be
realized. Alternatively, more positive cooling may be performed. When
the gas is introduced into the second space in joining, as in this
embodiment, the introduced gas can not only pressurize the second
space, but also cool the surface of the decorative sheet 10 on the side of
the second space. Therefore, when the spread suppressing member 3
faces the second space, the spread suppressing member 3 is cooled by
the gas, so that the above-described non-uniform temperature
distribution can be rapidly realized. Therefore, even in the case where
the joining is performed in a very short time as described above, the
spreading of the pattern area 2a can be more surely suppressed.
In the case where the joining is performed so that the spread suppressing
member 3 faces the second space, the spread suppressing member 3 may
be removed from the molded article 20 if necessary. If the fixing of the
spread suppressing member 3 is performed by means of an adhesive
which can be easily peeled off, the removal can be preferably performed.
It is not necessarily that the spread suppressing member 3 is directly in
contact with the first principal surface la or the second principal
surface lb of the base member 1. The adhesive layer typically exists
between the base member 1 and the spread suppressing member 3, and
additionally, another layer may be interposed. FIG. 16 is a partially
enlarged view of an example of the sectional structure after the joining.
In the structure exemplarily shown in FIG. 16, on the second principal
surface lb of the base member 1 formed from polycarbonate, a
protecting layer 8 of an acrylic resin is formed. On the protecting layer
8, the spread suppressing member 3 formed of aluminum is provided
with the adhesive layer 9 interposed therebetween. The protecting layer
8 is positioned on the outer side than the base member 1 in the molded
article 20, so that the protecting layer 8 protects the base member 1 and
improves the weather resistance of the decorative sheet 10. The base
member 1 has a thickness of 200 µ m to 1000 µ m, for example. The
protecting layer 8 has a thickness of 5 µ m to 50 µm, for example. The
spread suppressing member 3 has a thickness of 5 µ m to 100 µ mm, for
example. The adhesive layer 9 has a thickness of 5 µ m to 50 µm, for
example.
As shown in FIG. 16, on the first principal surface 1a of the base
member 1, the decoration layer 2 formed of ink is provided. On the
decoration layer 2, a metal layer 6 formed from tin is provided with the
adhesive layer 7 interposed therebetween. Since the metal layer 6 has
metallic luster, the decorative sheet 10 can exhibit colors of metallic
tones (metallic color) having metallic appearance. Herein, the metal
layer 6 is formed in such a manner that tin is evaporated on a carrier
film 5, and the layered body is attached to the first principal surface la
with an adhesive. The decoration layer 2 has a thickness of 5 µm to 50
µm, for example. The metal layer 6 has a thickness of 0.25 µ m to 0.8
µm, for example, and is formed from soft metal such as tin.
The decorative sheet 10 shown in FIG. 16 is joined to the molded article
body 21 by means of the adhesive layer 4. The adhesive layer 4 has a
thickness of 5 µ m to 50 µm, for example. As described above, the
spread suppressing member 3 may be provided on the side of the first

principal surface la of the base member 1. More specifically, as shown
by a dot line in FIG. 16, on the first principal surface la of the base
member 1, the spread suppressing member 3 may be provided with the
decoration layer 2, the adhesive layer 7, the metal layer 6, and the
carrier film 5 interposed therebetween.
In order to maintain the decorating effect of the pattern area 2a of the
decoration layer 2 high, as shown in FIG. 17, the thickness T1 of the
portion of the sheet 10 corresponding to the pattern area 2a is preferably
1.1 times or more and 1.8 times or less as large as the thickness T2 of the
other portion of the sheet 10. More preferably, the thickness T1 is 1.2
times or more and 1.6 time or less as large as the thickness T2. When
the pattern area 2a is such thin that the thickness T1 is less than 1.1
times as large as the thickness T2, stepped cut may occur in the pattern
area 2a due to the unevenness of the surface of the molded article body
21, and desired decorating effects cannot be attained. When the
thickness T1 is more than 1.8 times as large as the thickness T2, the
appearance of the pattern area 2a may be distorted due to the lens effect,
or the portion corresponding to the pattern area 2a (the portion is raised
as compared with the other portion) may get scratched by friction.
In this embodiment, the molded article body 21 which is integrally
formed (in other words, which has a single member) is shown.
Alternatively, a molded article may have a plurality of members which
are separately molded, and the plurality of members may be mutually
coupled by the joining of the decorative sheet 10.
Specifically, as shown in FIG. 18(a), on a surface of a molded article
body 22 having a first member 22a and a second member 22b disposed
on a surface of the first member 22a, the decorative sheet 10 is joined so
as to cover both of the first member 22a and the second member 22b. As
a result, as shown in FIG. 18(b), a molded article 20' in which the first
member 22a and the second member 22b are coupled can be obtained.
A relative positional relationship between the first member 22a and the
second member 22b can be arbitrarily selected. For this reason, when
the plurality of members 22a and 22b of the molded article body 22 are
coupled by means of the joining of the decorative sheet 10, as described
above, a large variety of shapes of molded articles can be obtained by
using a relatively small number of molding dies. Therefore, the
production of the large variety of shapes of molded articles can be easily
performed at a low cost. For the first member 22a and the second
member 22b, a structure for temporarily tacking them, that is, a
positioning structure for determining the relative positional relationship
can be provided. The positioning structure may be a protruding portion
and a concave portion which are mutually engaged, for example.
The molded article produced by the production method using the
decorative sheet 10 is suitably used for interior or exterior of motor
vehicles, exterior of home electric appliances, and the like. For
example, the molded article is suitably used as a tank cover 51, a front
fender 52, and a tail cowl 53 of a motorbike 50 shown in FIG. 19. As we
all known, the "motor vehicles" widely indicate loco mobile
conveyances or machines for transporting passengers or merchandises, or
for moving things, and include a car, a motorbike, a bus, a truck, a
tractor, an airplane, a motorboat, a civil engineering vehicle, and the
like. The motor vehicles include not only those provided with an
internal combustion engine such as a gasoline engine, but also those
provided with an electric motor.
INDUSTRIAL APPLICABILITY
According to the decorative sheet of the present invention, since the
spread suppressing member for suppressing the spreading of the pattern
area is provided in a position corresponding to the pattern area of the
decoration layer, the spreading of the pattern area in the joining to the
molded article body can be suppressed. Accordingly, the decorative
sheet according to the present invention can be preferably used for the
decoration of a molded article of which the surface has unevenness.
When the production of the molded article is performed by using the
decorative sheet according to the present invention, distortion of pattern
can be prevented, and the obtained molded article has beautiful
appearance.
The molded article which is produced by using the decorative sheet
according to the present invention is preferably used for various goods,
and especially preferably used for interior and exterior of a motor
vehicle.
WE CLAIM:
----------
1. A decorative sheet (10) comprising!
a base member (1), formed from a resin material having
a first and a second principal surfaces (1a, 1b) opposite to each
other;
a decoration layer (2), provided on the first principal
surface (1a) of the base member (1), having a pattern area (2a)
representing a predetermined pattern; and
a spread suppressing member (3), provided in a position
corresponding to the pattern area (2a) on the side of the first
principal surface (la) or on the side of the second principal
surface (lb) of the base member (1), for suppressing the
spreading of the pattern area (2a) of the decoration layer (2),
characterized in that the spread suppressing member (3) has a
higher coefficient of thermal conductivity than a coefficient of
the thermal conductivity of the base member (1).
2. The decorative sheet as claimed in claim 1, wherein the
resin material is a thermoplastic resin material.
3. The decorative sheet as claimed in any one of claims 1
and 2, wherein the spread suppressing member (3) is formed from a
material comprising metal or a metal compound.
4. The decorative sheet as claimed in any one of claims 1
and 2, wherein the spread suppressing member (3) is formed of
metal.
5. The decorative sheet as claimed in any one of claims 1
to 4, wherein a coefficient of thermal conductivity of the spread
suppressing member (3) is 10 W/m K or more.
6. The decorative sheet as claimed in any one of claims
1 to 5, wherein a thickness of the spread suppressing member
is 5 m or more and 100 µ m or less.
7. The decorative sheet as claimed in any one of claims 1
to 6, wherein the spread suppressing member (3) comprises a first
portion (3a) which overlaps the pattern area (2a).
8. The decorative sheet as claimed in claim 7, wherein the
spread suppressing member (3) comprises a second portion (3b)
positioned in an outer circumference of the first portion (3a).
9. The decorative sheet as claimed in claim 8, wherein a
width of the second portion (3b) of the spread suppressing
member (3) is 1 mm or more and 10 mm or less.
10. The decorative sheet as claimed in claim 8, wherein a
width of the second portion (3b> of the spread suppressing member
(3) is 2 mm or more and 8 mm or less.
11. A molded article (20) comprising: a molded article
body (21); and a decorated sheet (10) as claimed in claims 1 to
10, the decorated sheet joined to a surface of the molded article
body (21), wherein
the sheet (10) comprises a base member (1) and a
decoration layer (2) provided on a face of the base member (1)
on the side of the molded article body (21),
the decoration layer (2) has a pattern area (2a)
representing a predetermined pattern, and
a first portion (3a) of the sheet (10) corresponding to
the pattern area (2a) has a thickness which is 1.1 times or more
and 1.8 times or less as large as a thickness of a second portion
(3b) of the sheet (10).
12. The molded article as claimed in claim 11, wherein the
first portion (3a) of the sheet (10) corresponding to the pattern
area (2a) has a thickness which is 1.2 times or more and 1.6
times or less as large as the thickness of the second portion (3b)
of the sheet (10).
13. A production method of a molded article as claimed in
claim 11 and 12 comprising the steps of :
preparing a decorative sheet having a base member,
formed from a resin material, having a first and a second
principal surfaces opposite to each other; providing a decoration
layer on the first principal surface of the base member
having a pattern area representing a predetermined pattern; and
providing a spread suppressing member in a position corresponding
to the pattern area on the side of the first principal surface or
on the side of the second principal surface of the base member,
for suppressing the spreading of the pattern area of the
decoration layer,
preparing a molded article body? and
joining the decorative sheet to a surface of the molded
article body.
14. The production method of a molded article as claimed in
claim 13, comprising, before the step of joining the decorative
sheet to the surface of the molded article body, a step of
heating the decorative sheet.
15. The production method of a molded article as claimed in
claim 14, wherein the resin material is a thermoplastic resin
material.
16. The production method of a molded article as claimed in
claim 14, or 15, wherein the spread suppressing member has a
higher coefficient of thermal conductivity than a coefficient of
thermal conductivity of the base member.
17. The production method of a molded article as claimed in
any one of claims 14 to 16, wherein the spread suppressing member
is formed form a material comprising metal or a metal compound.
10. The production method of a molded article as claimed in
any one of claims 14 to 16, wherein the spread suppressing member
is formed of metal.
19. The production method of a molded article as claimed in
any one of claims 14 to 18, wherein the coefficient of thermal
conductivity of the spread suppressing member is 10 W/m " K or
more.
20. The production method of a molded article as claimed in
any one of claims 14 to 19, wherein a thickness of the spread
suppressing member is 5 µ m or more and 100µ m or less.
21. The production method of a molded article as claimed in
any one of claims 14 to 20, wherein the spread suppressing member
has a first portion which overlaps the pattern area.
22. The production method of a molded article as claimed in
claim 21, wherein the spread suppressing member comprises a
second portion positioned in an outer circumference of the first
portion.
23. The production method of a molded article as claimed in
claim 22, wherein a width of the second portion of the spread
suppressing member is 1 mm or more and 10 mm or less.
24. The production method of a molded article as claimed in
claim 22, wherein a width of the second portion of the spread
suppressing member is 2 mm or more and 8 mm or less.
25. The production method of a molded article as claimed in
any one of claims 14 to 24, wherein the step of joining the
decorative sheet to the surface of the molded article body
comprises a step of moving the heated decorative sheet closer to
the molded article body, and a step of reducing a pressure of a
first space formed between the decorative sheet coming closer to
the molded article body and the molded article body as compared
with a pressure of a second space expanded oppositely to the
first space with respect to the decorative sheet.
26. The production method of molded article as claimed in
claim 25, wherein the step of moving the decorative sheet closer
to the molded article body is performed in such a manner that
the spread suppressing member faces the second space.
27. The production method of a molded article as claimed in
claim 26, comprising, after the step of moving the decorative
sheet closer to the molded body, the step of cooling the spread
suppressing member by introducing a gas into the second space.
28. The production method of a molded article as claimed in
claim 26 or 27, comprising, after the step of joining the
decorative sheet to the surface of the molded body, a step of
removing the spread suppressing member.
29. The production method of a molded article as claimed in
any one of claims 13 to 28, wherein the spread suppressing member
is provided on the side of the second principal surface of the
base member.
30. The production method of a molded article as claimed in
any one of claims 13 to 29, wherein after the step of joining the
decorative sheet to the surface of the molded article body, the
decoration layer is positioned between the base member and the
molded article body.
31. The production method of a molded article as claimed in
any one of claims 13 to 30, wherein the molded article body
comprises a first member and a second member disposed on a
surface of the first member, and
in the step of joining the decorative sheet to the
surface of the molded article body, the decorative sheet is
joined to the surface of the molded article body so as to cover
both of the first member and the second member, thereby joining
the first member and the second member.
32. A production method of a molded article as claimed in
claims 11 and 12 comprising the steps of:
preparing a decorative sheet having a base member,
formed from a resin material, having a first and a second
principal surfaces opposite to each other, and a decoration
layer, provided an the first principal surface of the base
member, having a pattern area representing a predetermined
pattern:
preparing a molded article body;
heating the decorative sheet; and
joining the decorative sheet which is heated to a
surface of the molded article body in a condition where a
temperature of a portion of the decorative sheet corresponding to
the pattern area is lower than a temperature of the other portion
of the decorative sheet.
33. The production method of a molded article as claimed in
claim 32, wherein the step of joining the decorative sheet to the
surface of the molded article body comprises the step of cooling
the decorative sheet in such a manner that the temperature of the
portion corresponding to the pattern area is rapidly lowered as
compared with the temperature of the other portion.
34. The production method of a molded article as claimed in
claim 33, wherein the decorative sheet additionaly comprises a
member, provided in a position corresponding to the pattern area
on the side of the first principal surface or on the side of the
second principal surface of the base member, having a higher
coefficient of thermal conductivity than a coefficient of thermal
conductivity of the base member.
35. The production method of a molded article as claimed in
claim 34, wherein the member is formed from a material comprising
metal.
36. The production method of a molded article as claimed in
claim 34, wherein the member is formed of metal.
37. The production method of molded article as claimed in
any one of claims 34 to 36, wherein a coefficient of thermal
conductivity of the member is 10 W/m • K or more.

The invention relates to a decorative sheet (10) comprising
a base member (1), formed from a resin material having a first
and a second principal surfaces (1a, 1b) opposite to each other;
a decoration layer (2), provided on the first principal surface
(1a) of the base member (1), having a pattern area (2a)
representing a predetermined pattern; and a spread suppressing
member (3), provided in a position corresponding to the pattern
area (2a) on the side of the first principal surface (1a) or on
the side of the second principal surface (1b) of the base member
(l), for suppressing the spreading of the pattern area (2a) of
the decoration layer (2). The spread suppressing member (3) has a
higher coefficient of thermal conductivity than a coefficient of
the thermal conductivity of the base member (1).

Documents:

1456-KOLNP-2004-(27-01-2012)-CORRESPONDENCE.pdf

1456-KOLNP-2004-(27-01-2012)-FORM 27.pdf

1456-KOLNP-2004-(27-01-2012)-PA.pdf

1456-kolnp-2004-abstract.pdf

1456-kolnp-2004-claims.pdf

1456-KOLNP-2004-CORRESPONDENCE-(12-12-2011).pdf

1456-kolnp-2004-correspondence.pdf

1456-kolnp-2004-description (complete).pdf

1456-kolnp-2004-drawings.pdf

1456-kolnp-2004-examination report.pdf

1456-kolnp-2004-form 1.pdf

1456-kolnp-2004-form 18.pdf

1456-kolnp-2004-form 2.pdf

1456-KOLNP-2004-FORM 27.pdf

1456-kolnp-2004-form 3.pdf

1456-kolnp-2004-form 5.pdf

1456-kolnp-2004-gpa.pdf

1456-KOLNP-2004-PA-CERTIFIED COPIES-(12-12-2011).pdf

1456-KOLNP-2004-PA.pdf

1456-kolnp-2004-reply to examination report.pdf

1456-kolnp-2004-specification.pdf

1456-kolnp-2004-translated copy of priority document.pdf


Patent Number 235073
Indian Patent Application Number 1456/KOLNP/2004
PG Journal Number 26/2009
Publication Date 26-Jun-2009
Grant Date 24-Jun-2009
Date of Filing 01-Oct-2004
Name of Patentee YAMAHA HATSUDOKI KABUSHIKI KAISHA
Applicant Address 2500 SHINGAI, IWATA-SHI, SHIZUOKA
Inventors:
# Inventor's Name Inventor's Address
1 SUZUKI YASUO YAMAHA HATSUDOKI KABUSHIKI KAISHA, 2500 SHINGAI, IWATA-SHI, SHIZUOKA 438 8501
2 MOROZUMI NAOHIRO YAMAHA HATSUDOKI KABUSHIKI KAISHA, 2500 SHINGAI, IWATA-SHI, SHIZUOKA 438 8501
PCT International Classification Number B23B 3/02
PCT International Application Number PCT/JP2003/016838
PCT International Filing date 2003-12-25
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 2003-002292 2003-01-08 Japan