Title of Invention

A BLADE FOR A WIND TURBINE

Abstract

A blade far a wind turbine, wherein at least a third of the total length, measured from tip to hub, of said blade comprises a layer (1, 2) along an outer periphery of the cross-section of said blade, characterised in that the layer (1,2) is at least party constituted by a number of pre-fabricated strips (1,2) arranged in a sequence along the outer periphery, said pre-fabdicated strips (1,2) being arranged side by side so that connections between the adjacent strips (1,2) are oriented substantially orthogonal to the surface of the layer in a plane orthogonal to the length of the blade.

Full Text

2 The present invention relates to a blade for wind turbines, in which biade, on the periphery layer of the cross section of the blade, a number of pre-fabricated strips are arranged. The present application has been divided out of Indian Patent Application No. 63/KOLNP/2004. (hereinafter referred to as "parent application") BACKGROUND OF THE INVENTION Wind turbine blades are today manufactured comprising a bearing central inner beam, commonly of a hollow, square cross-section and made from a glass fibre and resin composite, surrounded with two shells forming the upper and the lower outer surface of the blade and determining the aerodynamic properties thereof. The shells may be of a single layer or at least along a part of the circumference be a sadwich constructs comprising two parallel layers of glass fibres and resin having 3 space in between filed with e.g. a polyurethane foam. The use of a wooden material to reinforce the inner side of a single layer shell or to fill the space of a sandwich construction is well known, it is realised that the forces and torque increase steeply with the increasing length of blades and that the strength and stiffness of the inner beam must be steeply increased as well for the known blades, as the shells only contribute minor to the overall toad bearing properties of the blade. In order for the shell to bear a substantial part of the forces of the inner bearn, the above discussed structures that are reinforced with wooden material require for larger dimensions of blades a thickness of the wooden layer 3 that would increase the weight of the blade significantly, thus causing increased stresses to the blade. It is the object of the invention to provide a blade for a wind turbine which has properties of laminated products, i.e. high strength in comparison with the amount of material and lower production costs compared to solid products, but where the strength compared to the costs of manufacturing the blade is highly increased compared to prior art blades. DESCRIPTION OF THE INVENTION The invention of the "parent" application discloses a blade for a wind turbine, wherein at feast a third of the total length, measured from tip to hub, of said blade comprises a layer along an outer periphery of the cross-section of said blade, characterised in that the layer is at least partly constituted by a number of prefabricated strips arranged in a sequence along the outer periphery, and at least some of the pre-fabricated strips are fibrous composite material puftrusions. The present invention provides a bfa.de for a wind turbine, wherein at least a third of the total length, measured from tip to hub, of said bfade comprises a layer along an outer periphery of the cross-section of said blade, characterised in that the layer is at least partly constituted by a number of pre-fabricated strips arranged in a sequence along the outer periphery, said pre-fabrfcated strips 4 being arranged side by side so that connections between the adjacent strips are oriented substantially orthogonal to the surface of the layer in a plane orthogonal to the length of the blade. The present invention also provides a blade for a wind turbine wherein at least a third of the total length, measured from tip to hub, of said blade comprises a layer along an outer periphery of the cross-section of said blade, characterised in that the layer is at least partly constituted by a number of prefabricated strips arranged in a sequence along the outer periphery, wherein at least some of the strips have elongated strip cross-sections in a plane orthogonal to the length of the blade ; at least some of said strips are arranged with a short side of the strip cross-section along the outer periphery of the cross-section of the blade ; and/or at least some of said strips are arranged with a long side of the strip cross-section substantially orthogonal to the outer periphery of the cross-section of the blade. The present invention further provides a method for manufacturing a prefabricated strip for a blade of a wind turbine, satd blade comprising a layer material arranged along an outer periphery of the cross-section of the blade, said method comprising the steps of: assembling at least two individual materials to constitute the pre- fabricated strip ; 5 selecting at least one of said at least two individual materials among fibrous composite materials ; inserting the assembled at least two individual materials into a container such as a bag ; evacuating the container, infusing a curing resin, and allowing the resin to cure; and taking out from the container the assembled and cured strip thus fabricated. The present invention in addition provides a method for manufacturing a shell for a blade of 3 wind turbine, said shell comprising a layer material arranged along an outer periphery of the cross-section of the shell, said layer comprising prefabricated strips, said method comprising the following steps : applying a surface material, preferably gel coat, to a mould for the blade ; optionally applying a metal mesh, a glass fibre mesh and any transfer media ; providing at least two individual materials to constitute the pre-fabricated strips ; selecting at least one of said at least two individual materials among fibrous composite materials : positioning said at least two individual materials onto the other applied materials ; 6 inserting the thus applied individual materials and other materials into a container: evacuating the container, infusing a curing resin, and allowing the resin to cure; and de-moulding from the mould the shell thus fabricated. Thus, the object is obtained by a blade, which blade over a substantial longitudinal part comprises a layer along an outer periphery of the cross-section of the blade, said layer being constituted by a plurality of pre-fabricated strips arranged in a sequence along the outer periphery of the blade. By the term "a substantial longitudinal part" is understood a part extending over at least a third of the total length of the blade from tip to bub, preferably over at least half of the total length of the blade. According to a preferred embodiment, 60-85% of the total length, such as about 70%, comprises such layer. Thereby, the optimal material properties may be obtained by combining different types of strips, such as pultruded fibrous composite strips comprising different fibres, such as carbon fibres, glass fibres and/or natural fibres, wooden strips, composite strips formed as ho flow tubes etc. Each of the types of strips are much simpler, and thus cheaper, to manufacture than to form a whole blade, and the strips may be jointed by suitable methods, such as by injection of resin or by vacuum infusion of resin. 7 According to the instant invention, a wind turbine blade may be obtained, which reduces the forces and torque on the inner beam. Furthermore, the resistance against tension and compression forces in a layer near the outer periphery of the shell provides the blade with an improved structural efficiency with respect to an edge-wise bending mode. Accordingly, in a preferred embodiment, at least some of the pre-fabricated strips are made from pultruded fibrous composite material, such as carbon-resin. Thereby, a construction is obtained with an excellent stiffness, but which is not prone to buckling. Thus, the inner structure of the blade may be made of a lighter construction, e.g. by replacing the commonly used inner beam of a square cross section with two lighter webs at the leading edge and the travelling edge, respectively. The periphery layer may. in a preferred embodiment, be assembled by injection of resin or by vacuum infusion of resin. Use of resin infusion leads to a speedy, healthy and safe manufacturing process, leaving no or only very few voids in the resin. A limitation of the number of voids reduces subsequent finishing, A very little amount of the fibres in the blade is actually infused. The resin is mainly a glue rather thari a matrix. This results in a structure being more tolerant to any possible voids. 8 According to one. preferred embodiment, the blade over a substantial longitudinal part comprises a layer along the outer periphery of its cross-section, wherein the layer at least partly is constituted by strips of a wooden material and strips of a fibrous composite material In an alternating sequence along the outer periphery. Thereby, the excellent stiffness of fibrous composite materials and the high resistance against buckling of wooden materials is combined to achieve a shell with suitable properties in a cost-effective manner. An especially advantageous embodiment comprises at least some strips made from a wooden material, preferably plywood used as the wooden material, and natural fibre pultrusions, preferably carbon fibre pultrusions, as the fibrous composite material The advantages obtained by this embodiment are that the materials are compatible and both are having low thermal expansion coefficients. Both types of material work at similar low range of strains resulting in the possibility of stiffer blades as compared to the weight of the blades. Also, natural fibres may be prone to buckling, and although wood is bulky, wood is not prone to buckling, thus also for this reason, the two types of material are very complementary. 9 The strips may in general be made from wood, laminated wood, pultrusions from any fibre man-made or natural with any resin, thermoset, thermoplastic, man- made or naturally derived, foam plastics, lightweight core materials in any proportion, At least some of the pre-fabricated strips are advantageously formed from a fibrous composite material. The fibres of the fibrous material may be any known fibre having suitable properties to reinforce the wood composite, such as carbon fibres, glass fibres, Kevlar fibres, natural fibres, e.g. from hemp of flax, coir fibres, etc. or any combination thereof, As exampfe, carbon has a higher strain to failure than wood. Carbon acts as stiffening additive but wood fails first This has been taken advantage of in coupon testing to prove strength of carbon and wood separately. Adding carbon and thus the possibility of using thinner skins may reduce skin buckling margins Carbon fibres are relatively expensive : however, wood is cheap and can cover the area of the blade incurring very low costs. Wood itself, however, produces thick inefficient skins in highly stressed blades. Carbon fibres combined with wood may produce thinner skins, which are structurally efficient and satisfying. Also, wood is highly defect tolerant The percentage of the total cross-sectional area of the shell comprised of fibrous composite material is preferably within the range of 3% io 30% in the p^rt of the blade having highest content of the fibrous material, more preferred within the range of 6% to 20%. 10 Likewise, the of the total cross-sectional area of the shell comprised of fibres is preferably within the range of 2% to 20%, more preferred within the range of 4% to 15%. in a particularly preferred embodiment of the present invention, at least some of the strips are constituted by hollow tubes formed from a fibrous composite material. Thereby, material and weight is saved while advantageous structural properties are preserved. At least some of the strips of the fibrous composite material are preferably pultrusions, i.e. strips made by putrouding mixture of fibres and a matrix material that is cured after pultrusion, such as a processable resin, e.g. vinyl ester. Thereby, a strip having straight fibres and a low void content is obtained. Also, a low content of resin may be obtained leading to little shrinkage and rapid curing. It is thus advantageous that the pultrusions have a pultrusion direction substantially aligned with a longitudinal direction of the blade in which direction the properties of the fibres are required. However, pultrusion terminating joints are stress raisers, so particular attention is being given to these in structural element testing. 11 The fibrous composite material comprises advantageously a fibre volume fraction of 50% to 90%, preferably from 60% to 80%. In particular, the fibrous composite material may comprise a carbon fibre volume fraction of 50% to 90%, preferably from 60% to 80%. According to a preferred embodiment at least some of the pre-fabricated strips are made from a wooden material as wooden material are low in costs, have light weight, and the material properties of the wooden material may be completed to form the required blade material properties by combining with strips of other material types, such as fibrous composite materials. The wooden material may be stripe of wood, which if necessary are glued together in the longitudinal direction of the blade. A preferred embodiment employs plywood, in particular unidirectional plywood as the wooden material because of the homogeneous material properties. Another type of wooden material that may be employee! is comprised by wooden fibres held in a cured resin. Wood is seeing same direct stresses, so it is possible to use new joint patterns and glues using established design allowables, and stiil being confident of the structure of the wooden material. The layer is, according to one embodiment at least partly constituted by strips of a wooden material and stripe of a fibrous composite material in a sequence along the outer periphery. The sequence may preferably be an alternating 12 sequence of strips of a wooden material and strips of a fibrous composite material The alternating sequence preferably ranges over only a part of the complete periphery of the blade. It is advantageous that the layer discussed is part of a sandwich construction as discussed previously, i.e. is enclosed in an outer shell and an inner shell made from a fibrous composite material such as glass fibre web held by a cured synthetic resin. Types of specimens; Minibeams - 1 - beam, 2.5m long by 150mm by 150rnm (25mm thick flanges) with half scale skins. Includes pultrusion terminations, defects, wood joints. 6m x 1.2m Aerofoil - Type A designed to fall in direct overstress, testing skins, leading and trailing edge joints. Type P specimen with relatively thin skins for buckling investigations, 31 m Blade - A blade built tn the A131 mould with the same root fixings as the AL4Q (72xM30 fixings), with skins built with a similar distribution of wood and carbon as AL40, double webs and similar leading edge joint. 13 14 15 The invention may incorporate a lightning protection system comprising two possibly replacesble lightning attractors, preferably close to the tip. One of the lightning attractors are placed on the windward side, and the other lightning attraclor is placed on the leeward side. Both are connected to a width of aluminium mesh or similar material extending over the fibre reinforced area under the surface layer of gel coat of the blade, and are passed down to the root of the blade, where it is earthed. A radio frequency, e.g. a radar signal, absorption medium may optionally be infused with the rest of the structure. It is also possible to embed optical fibres in the blade, either additional to the reinforcing fibres or as a substitute to the reinforcing fibres. Optical fibres may be used to measure loads on and within the surface of the blade during operation of the wind turbine. Alternatively, resistance measurement of carbon fibres may be used to measure loads on or within the surface of the blade. Also, the carbon fibres used for measuring such loads may be one or more of the reinforcing fibres or may be carbon fibres additional to the reinforcing fibres and dedicated to measuring these loads. 16 BRIEF DESCRIPTION OF THE ACCOMPANYING DRAWINGS A preferred embodiment of the blade according to the instant invention is shown in the accompanying drawings, of which Fig. 1 is a cross-section of a blade having a layer comprised of strips of plywood in alternating sequence with strips of a fibre pultrusion ; Fig. 2a is a cross-section of a blade similar to the blade of Fig. 1 having a different distribution along the periphery of the parts with pultrusion strips ; Fig, 2b shows a plane view of a blade similar to the blade shown in cross-section in Fig. 2a, thus having a similar distribution along the periphery of the parts with pultrusion strips ; Fig. 2c is a photograph of the surface of the blade of Fig. 2a with the outer shell of composite material removed ; and Fig. 3 illustrates the vacuum resin infusion process. DETAILED DESCRIPTION OF THE INVENTION The blade shown in cross-section in Fig. 1 has a layer comprised of 40 x 40 millimetre strips of birch plywood 1 in alternating sequence wrth 6 x 40 millimetre strips of a carbon fibre puitrusion 2. The layer 1, 2 stretches along the central part of the blade between two C-beams 3,4 of a, fass fibre web and synthetic resin composite denoted the LE (leading edge) Web 3 and the TE (travelling edge) Web 4 and replacing the central inner beam discussed previously. The layer 1, 2 17 is sandwiched between an inner layer 5 and an outer layer 6 of glass epoxy skins that carry shear stress and promote the transverse stiffness of the blade. The space defined between the upper and lower shell thus constituted by the birch plywood 1 and the carbon fibre pultrusion 2, and the LE Web 3 and the TE Web 4 is lilted with a balsa wood core 7. The blade shown in Figs, 2a, 2b and 2c are similar to the one shown in Fig. 1; with the exception that the reinforcement of carbon fibre pultrusions 2 are situated near the areas of contact between the upper and the lower shell and the LE Web 3 and the TE Web 4, where the stress concentration is highest. In the embodiment shown, double web is used instead of a single web. This is to give sufficient buckling margin on the skins during compression. Also, the leading web reduces the leading edge joint shear load, alfowing a smaller leading edge joint area. This is advantageous during manufacturing of the blade. The technology is advantageous In that the addition of fibre pultrusions to a wood construction promotes the stiffness of the construction. The carbon fibre pultrusions are not used ail along the blade length but only in the middle 70% where required by the stresses. The btade skin cross section may be up to 10% by area of carbon fibre puitrusion in the more highly stressed regions, dispersed throughout the wood composite in the shown embodiment The skins are typically 60% of the thickness of the biade skins comprised purely by wood, 18 which reduces weight and improves the structural efficiency in the critical edgewise bending mode. The outer and inner glass epoxy skins are manufactured with glass fibres oriented plus and minus 45 degrees to the longitudinal direction of the blade. Pultrusions have the advantage of guaranteeing straight fibres and low void content in the carbon fibre composite itself. Furthermore, puitrusions have the advantage of speeding the blade infusion process as the fine carbon fibres would otherwise need significantly more time to infuse. The pultrusion has a high fibre volume fraction, about 70%, with a medium strength but highly processabfe resin, as example vinyl ester. Preferably, when manufacturing the blade, the resin is supplied with "peelply" on the two long sides, which is removed to produce a dean textured surface ensuring a good bond. The manufacturing process of a shell of a blade shown in Fig, 3 comprises the steps of applying a gei coat (not shown) to a mould 8 followed by a transfer media 9 such as a transfer mesh, 45 degrees glass fibre web 10 and epoxy (not shown) to the mould to create the outer glass epoxy skin. Hereafter the wood and pultrusion strips 1, 2 are positioned and a metal mesh 11 such as an aluminium mesh for the lightning protection is then applied. The shell is then wrapped in a container, in the process shown a vacuum bag 12, which is evacuated by exterior means 13. Then, resin is injected from a resin reservoir 14 through resin channels 15 formed between adjacent strips, from which the resin 19 spreads throughout the construction driven by the vacuum. A general resin used for infusion is Prime 20 from SP Systems. After curing of the resin, an inner glass epoxy skin 16 is manufactured on top of the wood and pultruston strips 1, 2. 20 WE CLAIM : 1. A blade for a wind turbine, wherein at least a third of the total length, measured from tip to hub, of said blade comprises a layer (1,2) along an outer periphery of ths cross-section of said blade, characterised in that the layer 0-2) is at least partly constituted by a number of prefabricated strips (1, 2) arranged in a sequence afong the outer periphery, said prefabricated strips (1, 2) being arranged side by side so that connections between the adjacent strips (1, 2) are oriented substantially orthogonal to the surface of the layer in a plane orthogonal to the length of the blade. 2. A blade for a wind turbine wherein, at least a third of the total length, measured from tip to hub, of said blade comprises a layer (1,2) along an outer periphery of the cross-section of said blade, characterised in that the layer (1,2) is at least partly constituted by a number of pre-fabricated strips (1, 2) arranged in a sequence along the outer periphery, wherein at least some of the strips (2) have elongated strip cross-sections in a plane orthogonal to the length of the blade ; at least some of said strips (2) are arranged with a short side of the strip cross-section along the outer periphery of the cross-section of the blade ; and/or at least some of said strips are arranged with a Jong side of the strip cross section substantially orthogonal to the outer periphery of the cross-section of the blade. 3. A blade as claimed in claim 1 or 2. wherein the strips of the outer layer (1,2) are jointed by means of resin infusion. 21 4. A blade as claimed in claim 3, wherein the strips of the outer layer (1. 2) are jointed by means of vacuum infusion of a resin. 5. A blade as ciaimed in any of claims 1 to A. wherein at least some of the pre-fabricated strips are formed from a fibrous composite material. 6. A blade as claimed in any of claims 1 to 5. wherein at least some of the prefabricated strips (2) are constituted by hollow tubes formed from a fibrous composite material. 7. A blade as claimed in claim 5 or 6, wherein at least some of the pre- fabricated strips of the fibrous composite material are pultrusions. 8. A blade as claimed in claim 1 or 2, wherein said strips comprise a plurality of pre-fabricated pultruded strips {2} of a fibrous composite material. 9. A blade as ciaimed in claim 7 or 8, wherein the pultruded strips (2) have a pultrusion direction substantial aligned with a longitudinal direction of the blade. 10. A blade as claimed in any of claims 5 to 9, wherein the fibrous composite material com prises a fere Volume fraction from 50% to 90%. 11. A blade as claimed in claim 10, wherein the fibrous composite material comprises a fibre volume fraction of from 60% to 80%. 22 12. A blade as claimed in any of claims 5 to 10, wherein the fibrous composite material comprises a carbon fibre volume fraction from 50% to 90%. 13. A blade as ciaimed in claim 12, wherein the fibrous composite material comprises a fibre volume of from 60% to 80%, 14. A blade as claimed in any preceding claim, wherein the layer (1. 2) at least partly is constituted by a number of strips made from a wooden material arranged in a sequence along the outer periphery. 15. A blade as claimed in claim 14, wherein the wooden material is plywood. 16. A blade as claimed in ciaim 14, wherein the wooden material is comprised by wooden fibres held in a cured resin. 17. A blade as claimed in any of claims 14 to 16, wherein the layer (1. 2} at least partly is constituted by strips of a wooden material and strips of a fibrous composite material arranged in a sequence along the outer periphery. 18. A blade as claimed in claim 17, wherein said sequence is an alternating sequenpe of strips of a wooden material and strips of a fibrous composite material. 23 19. A blade as claimed in any preceding claim, wherein said layer is enclosed in an outer shell and an inner shell made from a fibrous composite material. 20. A blade as claimed in any preceding claim, wherein load measuring fibres are enclosed in either one or both of the outer shell and the inner shell. 21. A blade as claimed in claim 20, wherein the load measuring fibres are optical fibres being additional to, or alternatively is substitute to, the reinforcing fibres. 22. A blade as claimed in claim 20, wherein the load measuring fibres are carbon fibres in additional to, or alternatively is substitute to, the reinforcing fibres. 23. A blade as claimed in any preceding claim, wherein lightning protection means comprising lightning attractors are incorporated into either one or both of the shells. 24. A blade as claimed in claim 23, wherein the lightning attractors are connected to a width of metal mesh (11) or similar material extending ever the fibre reinforced area of the shells. 25. A blade as claimed in any preceding claim, wherein a radio frequency absorption medium is incorporated into either one or both of the shells. 24 26. A method for manufacturing a prefabricated strip for a blade as claimed in any of claims 1 to 25, sald blade comprising a layer material arranged along an outer periphery of the cross-section of the blade, said method comprising the steps, of: assembling at least two individual materials (1,2) to constitute the pre- fabricated strip ; selecting at least one of said at least two individual materials (1, 2) among fibrous composite materials ; inserting the assembled at feast two individual materials (1, 2) into a container (12) such as a bag ; evacuating the container (12), infusing a curing resin, and allowing the resin to cure ; and taking out "from the container (12) the assembled and cured strip thus fabricated, 27. Method for manufacturing a shell for a blade as claimed in any of the claims 1 to 25, said shelf comprising a layer material arranged along an outer periphery of the cross-section of the shell, said teyer comprising prefabricated strips, said method comprising the foflowing steps : applying a surface material, preferably gel coat, to a mould (8) for the blade ; optionally applying a metal mesh (11), a glass fibre mesh and any transfer media , 25 providing at feast two individual materials (1, 2) to constitute the pre- fabricated strips ; selecting at least one of said at least two individual materials (1,2) among fibrous composite materials : positioning said at least two individual materials (1, 2) onto the other applied materials (10); inserting the thus applied individual materials and other materials into a container (12) ; evacuating the container (12), infusing a curing resin, and allowing the resin to cure ; and de-moulding from the mould the shelf thus fabricated. A blade far a wind turbine, wherein at least a third of the total length, measured from tip to hub, of said blade comprises a layer (1, 2) along an outer periphery of the cross-section of said blade, characterised in that the layer (1,2) is at least party constituted by a number of pre-fabricated strips (1,2) arranged in a sequence along the outer periphery, said pre-fabdicated strips (1,2) being arranged side by side so that connections between the adjacent strips (1,2) are oriented substantially orthogonal to the surface of the layer in a plane orthogonal to the length of the blade.

Documents:

00229-kol-2006-abstract.pdf

00229-kol-2006-claims.pdf

00229-kol-2006-description complete.pdf

00229-kol-2006-drawings.pdf

00229-kol-2006-form 1.pdf

00229-kol-2006-form 2.pdf

00229-kol-2006-form 3.pdf

00229-kol-2006-form 5.pdf

00229-kol-2006-gpa.pdf

229-KOL-2006-(10-10-2011)-CERTIFIED COPIES(OTHER COUNTRIES).pdf

229-KOL-2006-(10-10-2011)-CORRESPONDENCE.pdf

229-KOL-2006-(10-10-2011)-FORM 13.pdf

229-KOL-2006-(23-09-2011)-CORRESPONDENCE.pdf

229-KOL-2006-(23-09-2011)-OTHERS.pdf

229-KOL-2006-(28-09-2012)-PETITION UNDER RULE 137.pdf

229-KOL-2006-(29-03-2012)-CORRESPONDENCE.pdf

229-KOL-2006-(29-03-2012)-FORM-13.pdf

229-KOL-2006-(29-03-2012)-PA.pdf

229-KOL-2006-ASSIGNMENT.pdf

229-KOL-2006-CORRESPONDENCE.pdf

229-KOL-2006-EXAMINATION REPORT.pdf

229-KOL-2006-FORM 13 1.1.pdf

229-KOL-2006-FORM 13.pdf

229-KOL-2006-FORM 18.pdf

229-KOL-2006-FORM 3.pdf

229-KOL-2006-FORM 5.pdf

229-KOL-2006-FORM 6.pdf

229-KOL-2006-GPA.pdf

229-KOL-2006-GRANTED-ABSTRACT.pdf

229-KOL-2006-GRANTED-CLAIMS.pdf

229-KOL-2006-GRANTED-DESCRIPTION (COMPLETE).pdf

229-KOL-2006-GRANTED-DRAWINGS.pdf

229-KOL-2006-GRANTED-FORM 1.pdf

229-KOL-2006-GRANTED-FORM 2.pdf

229-KOL-2006-GRANTED-LETTER PATENT.pdf

229-KOL-2006-GRANTED-SPECIFICATION.pdf

229-KOL-2006-OTHERS.pdf

229-KOL-2006-PA 1.2.pdf

229-KOL-2006-PA-1.1.pdf

229-KOL-2006-PA.pdf

229-KOL-2006-REPLY TO EXAMINATION REPORT.pdf

abstract-00229-kol-2006.jpg