Indian Patents. 251669:"AN AUXILIARY COMPOSITION FOR USE IN LAUNDERING OR TREATMENT OF FABRICS AND PROCESS THEREOF"

Title of Invention	"AN AUXILIARY COMPOSITION FOR USE IN LAUNDERING OR TREATMENT OF FABRICS AND PROCESS THEREOF"
Abstract	The present invention relates to an auxiliary composition, for use in the laundering or treatment of fabrics, the auxiliary composition comprising: an admix of (i) a clay and (ii) a silicone in an emulsified form comprising a water-in-oil emulsion, the water- in-oil emulsion comprising: a continuous phase comprising a silicone; and a discontinuous phase comprising water and a bleach.

Full Text	A COMPOSITION FOR USE IN THE LAUNDERING OR TREATMENT OF FABRICS, AND A PROCESS FOR MAKING THE COMPOSITION Technical Field The present invention relates to a composition for use in the laundering or treatment of fabrics. More specifically, the present invention relates to a laundry detergent composition capable of both cleaning and softening fabric during a laundering process. The present invention also relates to a process for making the above composition. Background Laundry detergent compositions that both clean and soften fabric during a laundering process are known and have been developed and sold by laundry detergent manufacturers for many years. Typically, these laundry detergent compositions comprise components that are capable of providing a fabric-softening benefit to the laundered fabric; such fabric-softening components include clays and silicones. The incorporation of clay into laundry detergent compositions to impart a fabric-softening benefit to the laundered fabric is described in the following references. A granular, built laundry detergent composition comprising a smectite clay that is capable of both cleaning and softening a fabric during a laundering process is described in US 4,062,647 (Storm, T. D., and Nirschl, J. P.; The Procter & Gamble Company). A heavy duty fabric-softening detergent comprising bentonite clay agglomerates is described in GB 2 138 037 (Allen, E., Coutureau, M., and Dillarstone, A.; Colgate-Palmolive Company). Laundry detergents compositions containing fabric-softening clays of between 150 and 2,000 microns in size are described in US 4,885,101 (Tai, H. T.; Lever Brothers Company). The fabric-softening performance of clay-containing laundry detergent compositions is improved by the incorporation of a flocculating aid to the clay-containing laundry detergent composition. For example, a detergent composition comprising a smectite type clay and a polymeric clay-flocculating agent is described in EP 0 299 575 (Raemdonck, H., and Busch, A.; The Procter & Gamble Company). The use of silicones to provide a fabric-softening benefit to laundered fabric during a laundering process is also known. US 4,585,563 (Busch, A., and Kosmas, S.; The Procter & Gamble Company) describes that specific organo-functional polydialkylsiloxanes can advantageously be incorporated in granular detergents to provide remarkable benefits inclusive of through-the-wash softening and further textile handling improvements. US 5,277,968 (Canivenc, E.; Rhone-Poulenc Chemie) describes a process for the conditioning of textile substrates to allegedly impart a pleasant feel and good hydrophobicity thereto, comprising treating such textile substances with an effective conditioning amount of a specific polydiorganosiloxane. Detergent Manufacturers have attempted to incorporate both clay and silicone in the same laundry detergent composition. For example, siliconates were incorporated in clay-containing compositions to allegedly improve their dispensing performance. US 4,419, 250 (Allen, E., Dillarstone, R., and Reul, J. A.; Colgate-Palmolive Company) describes agglomerated bentonite particles that comprise a salt of a lower alkyl siliconic acid and/or a polymerization product(s) thereof. US 4,421, 657 (Allen, E., Dillarstone, R., and Reul, J. A.; Colgate-Palmolive Company) describes a particulate heavy-duty laundering and textile-softening composition comprising bentonite clay and a siliconate. US 4, 482,477 (Allen, E., Dillarstone, R., and Reul, J. A.; Colgate-Palmolive Company) describes a particulate built synthetic organic detergent composition which includes a dispensing assisting proportion of a siliconate and preferably bentonite as a fabric-softening agent. In another example, EP 0 163 352 (York, D. W.; The Procter & Gamble Company) describes the incorporation of silicone into a clay-containing laundry detergent composition in an attempt to control the excessive suds that are generated by the clay-containing laundry detergent composition during the laundering process. EP 0 381 487 (Biggin, I. S., and Cartwright, P. S.; BP Chemicals Limited) describes an aqueous based liquid detergent formulation comprising clay that is pretreated with a barrier material such as a polysiloxane. Detergent manufacturers have also attempted to incorporate a silicone, clay and a flocculant in a laundry detergent composition. For example, a fabric treatment composition comprising substituted polysiloxanes, softening clay and a clay flocculant is described in WO92/07927 (Marteleur, C. A. A. V. J., and Convents, A. C.; The Procter & Gamble Company). More recently, fabric care compositions comprising an organophilic clay and functionalised oil are described in US 6,656,901 B2 (Moorfield, D., and Whilton, N.; Unilever Home & Personal Care USA division of Conopco, Inc.). WO02/092748 (Instone, T. et al; Unilever PLC) describes a granular composition comprising an intimate blend of a non-ionic surfactant and a water-insoluble liquid, which may a silicone, and a granular carrier material, which may be a clay. W003/055966 (Cocardo, D. M., et al; Hindustain Lever Limited) describes a fabric care composition comprising a solid carrier, which may be a clay, and an anti-wrinkle agent, which may be a silicone. However, despite all of the above attempts, whatever improved fabric-softening performance benefit detergent manufacturers have been able to achieve for a laundry detergent has come at the expense of its fabric-cleaning performance and also its processabiliry. Therefore, there is still a need to improve the fabric-softening performance of a laundry detergent composition without unduly negatively affecting its fabric-cleaning performance and processability. Summary The present invention overcomes the above mentioned problem by providing an auxiliary composition, for use in the laundering or treatment of fabrics, comprising an admix of (i) clay and (ii) silicone in an emulsified form. Description Clay Typically, the clay is a fabric-softening clay such as a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontonite clays, saponite clays and mixtures thereof. Preferably, the smectite clay is a dioctahedral smectite clay, more preferably a montmorillonite clay. Dioctrahedral smectite clays typically have one of the following two general formulae: Formula (I) NaxAl2-xMgxSi4Oio (OH)2 or Formula (II) CaxAl2.xMgxSi4Oio (OH)2 wherein x is a number from 0.1 to 0.5, preferably from 0.2 to 0.4. Preferred clays are low charge montmorillonite clays (also known as a sodium montmorillonite clay or Wyoming type montmorillonite clay) which have a general formula corresponding to formula (I) above. Preferred clays are also high charge montmorillonite clays (also known as a calcium montmorillonite clay or Cheto type montmorillonite clay) which have a general formula corresponding to formula (II) above. Preferred clays are supplied under the tradenames: Fulasoft 1 by Arcillas Activadas Andinas; White Bentonite STP by Fordamin; and Detercal P7 by Laviosa Chemica Mineraria SPA. The clay may be a hectorite clay. Typical hectorite clay has the general formula: Formula (III) [(Mg3-xLix)Si4.yMemyO10(OH2.zFz)]-(x+y)((x+y)/n)Mn+ wherein y = 0 to 0.4, if y = >0 then Mem is Al, Fe or B, preferably y = 0; Mn+ is a monovalent (n = 1) or a divalent (n = 2) metal ion, preferably selected from Na, K, Mg, Ca and Sr. x is a number from 0.1 to 0.5, preferably from 0.2 to 0.4, more preferably from 0.25 to 0.35. z is a number from 0 to 2. The value of (x + y) is the layer charge of the clay, preferably the value of (x + y) is in the range of from 0.1 to 0.5, preferably from 0.2 to 0.4, more preferably from 0.25 to 0.35. A preferred hectorite clay is that supplied by Rheox under the tradename Bentone HC. Other preferred hectorite clays for use herein are those hectorite clays supplied by CSM Materials under the tradename Hectorite U and Hectorite R, respectively. The clay may also be selected from the group consisting of: allophane clays; chlorite clays, preferred chlorite clays are amesite clays, baileychlore clays, chamosite clays, clinochlore clays, cookeite clays, corundophite clays, daphnite clays, delessite clays, gonyerite clays, nimite clays, odinite clays, orthochamosite clays, pannantite clays, penninite clays, rhipidolite clays, sudoite clays and thuringite clays; illite clays; inter-stratified clays; iron oxyhydroxide clays, preferred iron oxyhydoxide clays are hematite clays, goethite clays, lepidocrite clays and ferrihydrite clays; kaolin clays, preferred kaolin clays are kaolinite clays, halloysite clays, dickite clays, nacrite clays and hisingerite clays; smectite clays; vermiculite clays; and mixtures thereof. The clay may also be a light coloured crystalline clay mineral, preferably having a reflectance of at least 60, more preferably at least 70, or at least 80 at a wavelength of 460nm. Preferred light coloured crystalline clay minerals are china clays, halloysite clays, dioctahedral clays such as kaolinite, trioctahedral clays such as antigorite and amesite, smectite and hormite clays such as bentonite (montmorillonite), beidilite, nontronite, hectorite, attapulgite, pimelite, mica, muscovite and vermiculite clays, as well as pyrophyllite/talc, willemseite and minnesotaite clays. Preferred light coloured crystalline clay minerals are described in GB2357523A and WO01/44425. Preferred clays have a cationic exchange capacity of at least 70meq/100g. The cationic exchange capacity of clays can be measured using the method described in Grimshaw, The Chemistry and Physics of Clays, Interscience Publishers, Inc., pp. 264-265 (1971). Preferably, the clay has a weight average primary particle size, typically of greater than 20 micrometers, preferably more than 23 micrometers, preferably more than 25 micrometers, or preferably from 21 micrometers to 60 micrometers, more preferably from 22 micrometers to 50 micrometers, more preferably from 23 micrometers to 40 micrometers, more preferably from 24 micrometers to 30 micrometers, more preferably from 25 micrometers to 28 micrometers. Clays having these preferred weight average primary particle sizes provide a further improved fabric-softening benefit. The method for determining the weight average particle size of the clay is described in more detail hereinafter. Method For Determining The Weight Average Primary Particle Size Of The Clay: The weight average primary particle size of the clay is typically determined using the following method: 12g clay is placed in a glass beaker containing 250ml distilled water and vigorously stirred for 5 minutes to form a clay solution. The clay is not sonicated, or microfluidised in a high pressure microfluidizer processor, but is added to said beaker of water in an unprocessed form (i.e. in its raw form). 1ml clay solution is added to the reservoir volume of an Accusizer 780 single-particle optical sizer (SPOS) using a micropipette. The clay solution that is added to the reservoir volume of said Accusizer 780 SPOS is diluted in more distilled water to form a diluted clay solution; this dilution occurs in the reservoir volume of said Accusizer 780 SPOS and is an automated process that is controlled by said Accusizer 780 SPOS, which determines the optimum concentration of said diluted clay solution for determining the weight average particle size of the clay particles in the diluted clay solution. The diluted clay solution is left in the reservoir volume of said Accusizer 780 SPOS for 3 minutes. The clay solution is vigorously stirred for the whole period of time that it is in the reservoir volume of said Accusizer 780 SPOS. The diluted clay solution is then sucked through the sensors of said Accusizer 780 SPOS; this is an automated process that is controlled by said Accusizer 780 SPOS, which determines the optimum flow rate of the diluted clay solution through the sensors for determining the weight average particle size of the clay particles in the diluted clay solution. All of the steps of this method are carried out at a temperature of 20°C. This method is carried out in triplicate and the mean of these results determined. Silicone The silicone is preferably a fabric-softening silicone. The silicone typically has the general formula (Figure Removed) Formula (IV) wherein, each RI and R2 in each repeating unit, -(Si(Ri)(R2)0)-, are independently selected from branched or unbranched, substituted or unsubstituted Ci-Cio alkyl or alkenyl, substituted or unsubstituted phenyl, or units of -[-RiR2Si-O-]-; x is a number from 50 to 300,000, preferably from 100 to 100,000, more preferably from 200 to 50,000; wherein, the substituted alkyl, alkenyl or phenyl are typically substituted with halogen, amino, hydroxyl groups, quaternary ammonium groups, polyalkoxy groups, carboxyl groups, or nitro groups; and wherein the polymer is terminated by a hydroxyl group, hydrogen or -SiRs, wherein, Ra is hydroxyl, hydrogen, methyl or a functional group. Suitable silicones include: amino-silicones, such as those described in EP150872, WO92/01773 and US4800026; quaternary-silicones, such as those described in US4448810 and EP459821; high-viscosity silicones, such as those described in WOOO/71806 and WOOO/71807; modified polydimethylsiloxane; functionalized polydimethyl siloxane such as those described in US5668102, Preferably, the silicone is a polydimethylsiloxane. The silicone may preferably be a silicone mixture of two or more different types of silicone. Preferred silicone mixtures are those comprising: a high-viscosity silicone and a low viscosity silicone; a functionalised silicone and a non-functionalised silicone; or a non-charged silicone polymer and a cationic silicone polymer. The silicone typically has a viscosity, of from 5,000cp to 5,000,000cp, or from greater than lO.OOOcp to l,000,000cp, or from 10,000cp to 600,000cp, more preferably from 50,000cp to 400,000cp, and more preferably from 80,000cp to 200,000cp when measured at a shear rate of 20s"1 and at ambient conditions (20°C and 1 atmosphere). The silicone is typically in a liquid or liquefiable form, especially when admixed with the clay. Typically, the silicone is a polymeric silicone comprising more than 3, preferably more than 5 or even more than 10 siloxane monomer units. The silicone is in the form of an emulsion, especially when admixed with the clay. The emulsion can be a water-in oil emulsion or an oil-in water emulsion. The emulsion is preferably in the form of a water-in-oil emulsion with the silicone forming at least part, and preferably all, of the continuous phase, and the water forming at least part, and preferably all, of the discontinuous phase. The emulsion typically has a volume average primary droplet size of from 0.1 micrometers to 5,000 micrometers, preferably from 0.1 micrometers to 50 micrometers, and most preferably from 0.1 micrometers to 5 micrometers. The volume average primary particle size is typically measured using a Coulter Multisizer™ or by the method described in more detail below. The silicone in emulsified form typically has a viscosity of from SOOcp to 70,000cp, or from 3,000cp to 20,000cp. Commercially available silicone oils that are suitable for use are DC200™ (12,500cp to 600,000cp), supplied by Dow Corning, or silicones of the Baysilone Fluid M series supplied by GE Silicone. Alternatively, preformed silicone emulsions are also suitable for use. These emulsions may comprise water and/or other solvents in an effective amount to aid the emulsification of the silicone. Method For Determining The Volume Average Droplet Size Of The Silicone: The volume average droplet size of the emulsion is typically determined by the following method: An emulsion is applied to a microscope slide with the cover slip being gently applied. The emulsion is observed at 400X and 1,OOOX magnification under the microscope and the average droplet size of the emulsion is calculated by comparison with a standard stage micrometer. Emulsifier The emulsifier can be any surfactant, preferably a detersive surfactant. Suitabke detersive surfactants include anionic detersive surfactants, non-ionic detersive surfactants, cationic detersive surfactants, zwitterionic detersive surfactants amphoteric detersive surfactants and mixtures thereof. Preferred detersive surfactants are selected from the group consisting of C8-18alkyl sulphates, C8-18alkyl ethoxylated sulphates having an average degree of ethoxylation of from 1 to 7, C8-18 linear alkylbenzene sulphonates, d carboxylic acids, C8-18alkyl ethoxylated alcohols having an average degree of ethoxylation of from 1 to 7, Cn-24 alkyl N-methyl glucose amides, C8-18alkyl polyglucosides, amine oxides, Cn-24 alkyl betaines, C8-18 mono-alkyl mono-ethoxy dimethyl quaternary ammonium chlorides, and mixtures thereof. Most preferably, the emulsifier is an anionic detersive surfactant such as a linear alkyl benzene sulphonate. Charged polymeric fabric-softening boosting component The charged polymeric fabric-softening boosting component is preferably cationic. Preferably, the charged polymeric fabric-softening boosting component is a cationic guar gum. The charged polymeric fabric-softening boosting component may be a cationic polymer that comprises (i) acrylamide monomer units, (ii) other cationic monomer units and (iii) optionally, other monomer units. The charged polymeric fabric-softening boosting component may be a cationically-modified polyacrylamide or co-polymer thereof; any cationic modification can be used for these polyacrylamides. Highly preferred charged polymeric fabric-softening boosting components are co-polymers of acrylamide and a methyl chloride quaternary salt of dimethylaminoethyl acrylate (DMA3-MeCl), for example such as those supplied by BASF, Ludwigshafen, Germany, under the tradename Sedipur CL343. Formula (V) (Figure Removed) The general structure of acrylamide is: The general structure for DMASMeCl is: (Figure Removed) Formula (VI) Preferred cationic polymers have the following general structure: (Figure Removed) Formula (VII) wherein n and m independently are numbers in the range of from 100 to 100,000, preferably from 800 to 3400. The molar ratio of n:m is preferably in the range of from 4:1 to 3:7, preferably from 3:2 to 2:3. Suitable charged polymeric fabric-softening boosting components are described in more detail in, and can be synthesized according to the methods described in, DE10027634, DE10027636, DE10027638, US61 1 1056, US6147183, WO98/17762, W098/21301, W001/05872 and, W001/05874. The charged polymeric fabric-softening boosting component preferably has an average degree of cationic substitution of from 1% to 70%, preferably from above 10% to 70%, more preferably from 10% to 60%. If the charged polymeric fabric-softening boosting component is a cationic guar gum, then preferably its degree of cationic substitution is from 10% to 15%. However, if the charged polymeric fabric-softening boosting component is a polymer having a general structure according to formula VII above, then preferably its degree of cationic substitution is from 40% to 60%. The average degree of cationic substitution typically means the molar percentage of monomers in the cationic polymer that are cationically substituted. The average degree of cationic substitution can be determined by any known methods, such as colloid titration. One such colloid titration method is described in more detail by Horn, D., in Prog. Colloid &Polymer ScL, 1978, 8, p243-265. The charged polymeric fabric-softening boosting component preferably has a charge density of from 0.2meq/g to 1.5meq/g. The charge density is typically defined in terms of the number of charges carried by the polymer, expressed in rnilliequivalents/gram. One equivalent is the weight of the material required to give one mole of charge; one milliequivalent is a thousandth of this. Preferably, the charged polymeric fabric-softening boosting component has a weight average molecular weight of from above 100,000 Da to below 10,000,000 Da, preferably from 500,000 Da to 2,000,000 Da, and preferably from 1,000,000 Da to 2,000,000. Any known gel permeation chromatography (GPC) measurement methods for determining the weight average molecular weight of a polymer can be used to measure the weight average molecular weight of the charged polymeric fabric-softening boosting component. GPC measurements are described in more detail in Polymer Analysis by Stuart, B. H., pl08-l 12, published by John Wiley & Sons Ltd, UK, © 2002. A typical GPC method for determining the weight average molecular weight of the charged polymeric fabric-softening boosting component is described below: Method For Determining The Weight Average Molecular Weight of the Charged Polymeric Fabric-Softening Boosting Component: 1. Dissolve 1.5g of polymer in 1 litre of deionised water. 2. Filter the mixture obtained in step 1, using a Sartorius Minisart RC25 filter. 3. According the manufacturer's instructions, inject 100 litres of the mixture obtained in step 2., on a GPC machine that is fitted with a Suprema MAX (8mm by 30cm) column operating at 35°C and a ERC7510 detector, with 0.2M aqueous solution of acetic acid and potassium chloride solution being used as an elution solvent at a flux of 0.8 ml/min. 4. The weight average molecular weight is obtained by analysing the data from the GPC according to the manufacturer's instructions. Flocculating aid The flocculating aid is capable of flocculating clay. Typically, the flocculating aid is polymeric. Preferably the flocculating aid is a polymer comprising monomer units selected from the group consisting of ethylene oxide, acrylamide, acrylic acid and mixtures thereof. Preferably the flocculating aid is a polyethyleneoxide. Typically the flocculating aid has a molecular weight of at least 100,000 Da, preferably from 150,000 Da to 5,000,000 Da and most preferably from 200,000 Da to 700,000 Da. Adjunct components The auxiliary composition and/or the laundry detergent composition may optionally comprise one or more adjunct components. These adjunct components are typically selected from the group consisting of detersive surfactants, builders, polymeric co-builders, bleach, chelants, enzymes, anti-redeposition polymers, soil-release polymers, polymeric soil-dispersing and/or soil-suspending agents, dye-transfer inhibitors, fabric-integrity agents, brighteners, suds suppressors, fabric-softeners, flocculants, and combinations thereof. Auxiliary composition The auxiliary composition is for use in the laundering or treatment of fabrics and typically either forms part of a fully formulated laundry detergent composition or is an additive composition, suitable for addition to a fully formulated laundry detergent composition. Preferably, the auxiliary composition forms part of a fully formulated laundry detergent composition. The auxiliary composition comprises an admix of clay and a silicone in an emulsified form. Typically, the auxiliary composition additionally comprises a charged polymeric fabric-softening boosting component and optionally one or more adjunct components. Preferably, the charged polymeric fabric-softening boosting component is present in the auxiliary composition in the form of an admix with the clay and the silicone; this means that typically, the charged polymeric fabric-softening boosting component is present in the same particle as the clay and silicone. Preferably, the weight ratio of the silicone to emulsifier, if present, in the auxiliary composition is from 3:1 to 20:1. Preferably, the weight ratio of silicone to clay is from 0.05 to 0.3. Laundry detergent composition The laundry detergent composition comprises the auxiliary composition, a detersive surfactant, optionally a flocculating aid, optionally a builder and optionally a bleach. The laundry detergent composition optionally comprises one or more other adjunct components. The laundry detergent composition is preferably in particulate form, preferably in free-flowing particulate form, although the composition may be hi any liquid or solid form. The composition in solid form can be in the form of an agglomerate, granule, flake, extrudate, bar, tablet or any combination thereof. The solid composition can be made by methods such as dry-mixing, agglomerating, compaction, spray drying, pan-granulation, spheronization or any combination thereof. The solid composition preferably has a bulk density of from 300g/l to l,500g/l, preferably from 500g/l to l,000g/l. The composition may also be in the form of a liquid, gel, paste, dispersion, preferably a colloidal dispersion or any combination thereof. Liquid compositions typically have a viscosity of from SOOcps to 3,000cps, when measured at a shear rate of 20s"1 at ambient conditions (20°C and 1 atmosphere), and typically have a density of from 800g/l to 1300g/l. If tthe composition is in the form of a dispersion, then it will typically have a volume average particle size of from 1 micrometer to 5,000 micrometers, preferably from 1 micrometer to 50 micrometers. The particles that form the dispersion are usually the clay and, if present, the silicone. Typically, a Coulter Multisizer is used to measure the volume average particle size of a dispersion. The composition may in unit dose form, including not only tablets, but also unit dose pouches wherein the composition is at least partially enclosed, preferably completely enclosed, by a film such as a polyvinyl alcohol film. The composition is capable of both cleaning and softening fabric during a laundering process. Typically, the composition is formulated for use in an automatic washing machine, although it can also be formulated for hand-washing use. The following adjunct components and levels thereof, when incorporated into a laundry detergent composition of the present invention, further improve the fabric-softening performance and fabric-cleaning performance of the laundry detergrnt composition: at least 10% by weight of the composition of alkyl benzene sulphonate detersive surfactant; at least 0.5%, or at least 1%, or even at least 2% by weight of the composition of cationic quaternary ammonium detersive surfactant; at least 1% by weight of the composition alkoxylated alkyl sulphate detersive surfactant, preferably ethoxylated alkyl sulphate detersive surfactant; less than 12% or even less than 6%, or even 0%, by weight of the composition zeolite builder; and any combination thereof. Preferably the laundry detergent composition comprises at least 6%, or even at least 8%, or even at least 12%, or even at least 18%, by weight of the laundry detergent composition of the auxiliary composition. Preferably the composition comprises at least 0.3% by weight of the composition of a flocculating aid. The weight ratio of clay to flocculating aid in the laundry detergent composition is preferably in the range of from 10:1 to 200:1, preferably from 14:1 to 160:1 more preferably from 20:1 to 100:1 and more preferably from 50:1 to 80:1. Process The process for making the auxiliary composition comprises the steps of (i) contacting a silicone with water, and optionally an emulsifier, to form a silicone in an emulsified form; and (ii) thereafter contacting the silicone in an emulsified form with clay to form an admix of clay and a silicone. Preferably the silicone is in a liquid or liquefiable form when it is contacted to the clay in step (ii). Preferably the emulsion formed in step (i) is a water-in-oil emulsion with the silicone forming at least part of, and preferably all of, the continuous phase of the emulsion, and the water forms at least part of, and preferably all of, the discontinous phase of the emulsion. Preferably, a charged polymeric fabric-softening boosting component is contacted to the clay and silicone in step (ii). The intimate mixing of the charged polymeric fabric-softening boosting component with the clay and silicone further improves the fabric-softening performance of the resultant auxiliary composition. Step (i) may be carried out at ambient temperature (e.g. 20°C), but it may be preferred that step (i) is carried out at elevated temperature such as a temperature in the range of from 30°C to 60°C. If an emulsifier is used in the process, then preferably the emulsifier is contacted to water to form an emulsifier-water mixture, thereafter the emulsifier-water mixture is contacted to the silicone. For continuous processes, step (i) is typically carried out in an in-line static mixer or an in-line dynamic (shear) mixer. For non-continuous processes, step (i) is typically carried out in a batch mixer such as a Z-blade mixer, anchor mixer or a paddle mixer. The admix of clay and silicone is preferably subsequently agglomerated in a high-sheer mixer. Suitable high-sheer mixers include CB Loedige mixers, Schugi mixers, Littleford mixers, Drais mixers and lab scale mixers such as Braun mixers. Preferably the high-sheer mixer is a pin mixer such as a CB Loedige mixer or Littleford mixer or Drais mixer. The high-sheer mixers are typically operated at high speed, preferably having a tip speed of from 30ms"1 to 35ms"1. Preferably water is added to the high-sheer mixer. The admix of clay and silicone are typically subsequently subjected to a conditioning step in a low-shear mixer. Suitable low-shear mixers include Ploughshear mixers such as a Loedige KM. Preferably the low-shear mixer has a tip speed of from 5ms"1 to 10ms"1. Optionally, fine particles such as zeolite and/or clay particles, typically having an average particle size of from 1 micrometer to 40 micrometers or even from 1 micrometer to 10 micrometers are introduced into the low-shear mixer. This dusting step improves the flowability of the resultant particles by reducing their stickiness and controlling their growth. The admix of clay and silicone is typically subjected to a sizing step, wherein particles having a particle size of greater than 500mm are removed from the admix. Typically, these large particles are removed from the admix by sieving. The admix of clay and silicone is preferably subjected to hot air having a temperature of greater than 50°C or even greater than 100°C. Typically, the admix of clay and silicone is dried at an elevated temperature (e.g. a temperature of greater than 50°C or even greater than 100°C); preferably, the admix is dried in a low-shear apparatus such as fluid bed drier. Following this preferred drying step, the admix of clay and silicone is preferably thereafter subjected to cold air having a temperature of less than 15°C, preferably from 1°C to 10°C. This cooling step is preferably carried out in a fluid bed cooler. The admix of clay and silicone is preferably subjected to a second sizing step, wherein particles having a particle size of less than 250 micrometers are removed from the admix. These small particles are removed from the admix by sieving and/or elutriation. If elutriation is used, then preferably the second sizing step is carried out in a fluid bed such as the fluid bed dryer and/or cooler, if used in the process. The admix of clay and silicone is preferably subjected to a third sizing step, wherein particles having a particle size of greater than 1,400 micrometers are removed from the admix. These large particles are removed from the admix by sieving. The large particles that are optionally removed from the admix during the first and/or third sizing steps are typically recycled back to the high sheer mixer and/or to the fluid bed dryer or cooler, if used in the process. Optionally, these large particles are subjected to a grinding step prior to their introduction to the high sheer mixer and/or fluid bed dryer or cooler. The small particles that are optionally removed from the admix during the second sizing step are typically recycled back to the high sheer mixer and/or low shear mixer, if used in the process. Examples Example 1: A process for preparing a silicone emulsion 81.9g of silicone (polydimethylsiloxane) having a viscosity of 100,000cp is added to a beaker. 8.2g of 30w/w% aqueous Cn-Cia alkyl benzenesulphonate (LAS) solution is then added the beaker and the silicone, LAS and water are mixed thoroughly by hand using a flat knife for 2 minutes to form an emulsion. Example 2: A process for making a clay/silicone agglomerate 601.2g of bentonite clay and 7.7g of cationic guar gum are added to a Braun mixer. 90. Ig of the emulsion of example 1 is added to the Braun mixer, and all of the ingredients in the mixer are mixed for 10 seconds at l,100rpm (speed setting 8). The speed of the Braun mixer is then increased to 2,000rpm (speed setting 14) and 50g water is added slowly to the Braun mixer. The mixer is kept at 2,000rpm for 30 seconds so that wet agglomerates are formed. The wet agglomerates are transferred to a fluid bed dried and dried for 4 minutes at 137°C to form dry agglomerates. The dry agglomerates are sieved to removed agglomerates having a particle size greater than 1,400 micrometers and agglomerates having a particle size of less than 250 micrometers. Example 3: A clay/silicone agglomerate A clay/silicone agglomerate suitable for use in the present invention comprises: 80.3wt% bentonite clay, 1.0wt% cationic guar gum, 10.9wt% silicone (polydimethylsiloxane), 0.3wt% Cn-Cu alkyl benzenesulphonate (LAS) and 7.5wt% water. Example 4: A clay/silicone agglomerate A clay/silicone agglomerate suitable for use in the present invention comprises: 72.8wt% bentonite clay, 0.7wt% cationic guar gum, 15.9wt% silicone (polydimethylsiloxane), 0.5wt% Cn-Cu alkyl benzenesulphonate (LAS) and 10.1wt% water. Example 5: A laundry detergent composition A laundry detergent composition suitable for use in the present invention comprises: 15wt% clay/silicone agglomerates of either example 3 or example 4 above; 0.2wt% polyethylene oxide having a weight average molecular weight of 300,OOODa; 1 lwt% Cl 1-13 linear alkylbenzenesulphonate detersive surfactant; 0.3wt% C12-14 alkyl sulphate detersive surfactant; lwt% C^-Cn alkyl, di-methyl, ethoxy quaternary ammonium detersive surfactant; 4wt% crystalline layered sodium silicate; 12wt% zeolite A; 2.5wt% citric acid; 20wt% sodium carbonate; 0.1 wt% sodium silicate; 0.8wt% hydrophobically modified cellulose; 0.2wt% protease; 0.1 wt% amylase; 1.5wt% tetraacetlyethylenediamine; 6.5wt% percarbonate; 0.1 wt% ethylenediamine-N'N-disuccinic acid, (S,S) isomer in the form of a sodium salt; 1.2wt% 1,1-hydroxyethane diphosphonic acid; 0.1 wt% magnesium sulphate; 0.7wt% perfume; 18wt% sulphate; 4.7wt% miscellaneous/water. Example 6: A laundry detergent composition A laundry detergent composition suitable for use in the present invention comprises: 12.5wt% clay/silicone agglomerates of either example 3 or example 4 above; 0.3wt% polyethylene oxide having a weight average molecular weight of 300,OOODa; llwt% Cn-13 linear alkylbenzenesulphonate detersive surfactant; 2.5wt% Cn-Cn alkyl, di-methyl, ethoxy quaternary ammonium detersive surfactant; 4wt% crystalline layered sodium silicate; 12wt% zeolite A; 20wt% sodium carbonate; 1.5wt% tetraacetlyethylenediamine; 6.5wt% percarbonate; 1.0wt% perfume; 18wt% sulphate; 10.7wt% miscellaneous/water. Example 7: A laundry detergent composition A laundry detergent composition suitable for use in the present invention comprises: 12.5wt% clay/silicone agglomerates of either example 3 or example 4 above; 6.0wt% clay; 0.3wt% polyethylene oxide having a weight average molecular weight of 300,OOODa; 10wt% C\\.H linear alkylbenzenesulphonate detersive surfactant; lwt% alkyl sulphate detersive surfactant condensed with an average of 7 moles of ethylene oxide; 4wt% crystalline layered sodium silicate; 18wt% zeolite A; 20wt% sodium carbonate; 1.5wt% tetraacetlyethylenediamine; 6.5wt% percarbonate; 1.0wt% perfume; 15wt% sulphate; 4.2wt% miscellaneous/water. We Claim: 1. An auxiliary composition, for use in the laundering or treatment of fabrics, the auxiliary composition comprising: an admix of (i) a clay and (ii) a silicone in an emulsified form comprising a water-in-oil emulsion, the water-in-oil emulsion comprising: a continuous phase comprising a silicone; and a discontinuous phase comprising water and a bleach wherein the weight ratio to silicone to clay is between 0.05 to 0.3 and the weight ratio of silicone to emulsifier is from 3:1 to 20:1. 2. The auxiliary composition as claimed in claim 1, wherein the auxiliary composition further comprises at least one charged polymeric fabric-softening boosting component. 3. The auxiliary composition as claimed in claim 2, wherein the charged polymeric fabric-softening boosting component has a charge density of from 0.2 meg/g to 1.5 meg/g. 4. The auxiliary composition as claimed in claim 2. wherein the charged polymeric fabric-softening boosting component has a weight average molecular weight of from 1,000,000 to 2,000,000 Da. 5. The auxiliary composition as claimed in claim 2, wherein the charged polymeric fabric-softening boosting component is cationic guar gum. 6. The auxiliary composition as claimed in claim 1, wherein the silicone in an emulsified form has a viscosity of from 3000 cp to 20,000 cp at a shear rate of 20 s-1, preferably from 500 cp to 7,000 cp at a shear rate of 20 s-1. 7. The auxiliary composition as claimed in claim 1, wherein the silicone has a viscosity of from 10,000 cp to 600,000 cp at a shear rate of 20 s-1, preferably from 50,000 cp to 400,000 cp at a shear rate of 20 s-1. 8. The auxiliary composition as claimed in claim 1, wherein the silicone is a polydimethylsiloxane. 9. The auxiliary composition as claimed in claim 1. wherein the discontinuous phase of the emulsion has an average droplet size of from 0.1 micrometers to 5 micrometers. 10. The auxiliary composition as claimed in claim 1. wherein the clay is a fabric-softening clay, preferably a montmorillonite clay. 11. The auxiliary composition as claimed in claim 1, wherein the emulsifier is an anionic detersive surfactant, preferably a linear alkylbenzene sulphonate detersive surfactant. 12. The auxiliary composition as claimed in claim 1, wherein the clay has a primary particle size of from 14 micrometers to 160 micrometers. 13. An auxiliary composition as claimed in claim 1. whenever used in a laundry detergent composition comprising: i) said auxiliary composition; ii) a detersive surfactant; iii) optionally, a flocculating aid: iv) optionally, a builder; and v) optionally one or more adjunct component. 14. The laundry detergent as claimed in claim 13, wherein the flocculating aid is a polyethylene oxide having a weight average molecular weight of from 200.000 to Da to 700,000 Da. 15. The laundry detergent as claimed in claim 13, wherein the composition is in free-flowing particulate form. 16. A process for preparing an auxiliary composition as claimed in claim 1, the process comprises the steps of: i) contacting a silicone with water, and optionally an emulsifier, to form a silicone in an emulsified form; and ii) thereafter contacting the silicone in an emulsified form with clay to form an admix of clay and a silicone in an emulsified form; and wherein the weight ratio to silicone to clay is between 0.05 to 0.3 and the weight ratio of silicone to emulsifier is from 3:1 to 20:1. 17. The process as claimed in claim 16. wherein at least one charged polymeric fabric- softening boosting component is contacted to the clay and silicone in step (ii). 18. The process as claimed in claim 16. wherein the admix of clay and a silicon in an art emulsified from is subsequently agglomerated in a high-shear mixer to form an agglomerate. 19. The process as claimed in claim 18. wherein the water is added to the high-shear mixer. 20. The process as claimed in claim 16. wherein the admix of clay and silicone in an emulsified form is subjected to a temperature of greater than 100°C.

Full Text

A COMPOSITION FOR USE IN THE LAUNDERING OR TREATMENT OF FABRICS, AND A PROCESS FOR MAKING THE COMPOSITION
Technical Field
The present invention relates to a composition for use in the laundering or treatment of fabrics. More specifically, the present invention relates to a laundry detergent composition capable of both cleaning and softening fabric during a laundering process. The present invention also relates to a process for making the above composition.
Background
Laundry detergent compositions that both clean and soften fabric during a laundering process are known and have been developed and sold by laundry detergent manufacturers for many years. Typically, these laundry detergent compositions comprise components that are capable of providing a fabric-softening benefit to the laundered fabric; such fabric-softening components include clays and silicones.
The incorporation of clay into laundry detergent compositions to impart a fabric-softening benefit to the laundered fabric is described in the following references. A granular, built laundry detergent composition comprising a smectite clay that is capable of both cleaning and softening a fabric during a laundering process is described in US 4,062,647 (Storm, T. D., and Nirschl, J. P.; The Procter & Gamble Company). A heavy duty fabric-softening detergent comprising bentonite clay agglomerates is described in GB 2 138 037 (Allen, E., Coutureau, M., and Dillarstone, A.; Colgate-Palmolive Company). Laundry detergents compositions containing fabric-softening clays of between 150 and 2,000 microns in size are described in US 4,885,101 (Tai, H. T.; Lever Brothers Company). The fabric-softening performance of clay-containing laundry detergent compositions is improved by the incorporation of a flocculating aid to the clay-containing laundry detergent composition. For example, a detergent composition comprising a smectite type clay and a polymeric clay-flocculating agent is described in EP 0 299 575 (Raemdonck, H., and Busch, A.; The Procter & Gamble Company).
The use of silicones to provide a fabric-softening benefit to laundered fabric during a laundering process is also known. US 4,585,563 (Busch, A., and Kosmas, S.; The Procter & Gamble Company) describes that specific organo-functional polydialkylsiloxanes can advantageously be incorporated in granular detergents to provide remarkable benefits inclusive of through-the-wash softening and further textile handling improvements. US 5,277,968 (Canivenc, E.; Rhone-Poulenc Chemie) describes a process for the conditioning of textile substrates to allegedly impart a pleasant feel and good hydrophobicity thereto, comprising treating such textile substances with an effective conditioning amount of a specific polydiorganosiloxane.
Detergent Manufacturers have attempted to incorporate both clay and silicone in the same laundry detergent composition. For example, siliconates were incorporated in clay-containing compositions to allegedly improve their dispensing performance. US 4,419, 250 (Allen, E., Dillarstone, R., and Reul, J. A.; Colgate-Palmolive Company) describes agglomerated bentonite particles that comprise a salt of a lower alkyl siliconic acid and/or a polymerization product(s) thereof. US 4,421, 657 (Allen, E., Dillarstone, R., and Reul, J. A.; Colgate-Palmolive Company) describes a particulate heavy-duty laundering and textile-softening composition comprising bentonite clay and a siliconate. US 4, 482,477 (Allen, E., Dillarstone, R., and Reul, J. A.; Colgate-Palmolive Company) describes a particulate built synthetic organic detergent composition which includes a dispensing assisting proportion of a siliconate and preferably bentonite as a fabric-softening agent. In another example, EP 0 163 352 (York, D. W.; The Procter & Gamble Company) describes the incorporation of silicone into a clay-containing laundry detergent composition in an attempt to control the excessive suds that are generated by the clay-containing laundry detergent composition during the laundering process. EP 0 381 487 (Biggin, I. S., and Cartwright, P. S.; BP Chemicals Limited) describes an aqueous based liquid detergent formulation comprising clay that is pretreated with a barrier material such as a polysiloxane.
Detergent manufacturers have also attempted to incorporate a silicone, clay and a flocculant in a laundry detergent composition. For example, a fabric treatment composition comprising substituted polysiloxanes, softening clay and a clay flocculant is
described in WO92/07927 (Marteleur, C. A. A. V. J., and Convents, A. C.; The Procter & Gamble Company).
More recently, fabric care compositions comprising an organophilic clay and functionalised oil are described in US 6,656,901 B2 (Moorfield, D., and Whilton, N.; Unilever Home & Personal Care USA division of Conopco, Inc.). WO02/092748 (Instone, T. et al; Unilever PLC) describes a granular composition comprising an intimate blend of a non-ionic surfactant and a water-insoluble liquid, which may a silicone, and a granular carrier material, which may be a clay. W003/055966 (Cocardo, D. M., et al; Hindustain Lever Limited) describes a fabric care composition comprising a solid carrier, which may be a clay, and an anti-wrinkle agent, which may be a silicone.
However, despite all of the above attempts, whatever improved fabric-softening performance benefit detergent manufacturers have been able to achieve for a laundry detergent has come at the expense of its fabric-cleaning performance and also its processabiliry. Therefore, there is still a need to improve the fabric-softening performance of a laundry detergent composition without unduly negatively affecting its fabric-cleaning performance and processability.
Summary
The present invention overcomes the above mentioned problem by providing an auxiliary composition, for use in the laundering or treatment of fabrics, comprising an admix of (i) clay and (ii) silicone in an emulsified form.
Description
Clay
Typically, the clay is a fabric-softening clay such as a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontonite clays, saponite clays and mixtures thereof. Preferably, the smectite clay is a dioctahedral smectite clay, more preferably a montmorillonite clay. Dioctrahedral smectite clays typically have one of the following two general formulae:
Formula (I) NaxAl2-xMgxSi4Oio (OH)2
or
Formula (II) CaxAl2.xMgxSi4Oio (OH)2
wherein x is a number from 0.1 to 0.5, preferably from 0.2 to 0.4.
Preferred clays are low charge montmorillonite clays (also known as a sodium montmorillonite clay or Wyoming type montmorillonite clay) which have a general formula corresponding to formula (I) above. Preferred clays are also high charge montmorillonite clays (also known as a calcium montmorillonite clay or Cheto type montmorillonite clay) which have a general formula corresponding to formula (II) above. Preferred clays are supplied under the tradenames: Fulasoft 1 by Arcillas Activadas Andinas; White Bentonite STP by Fordamin; and Detercal P7 by Laviosa Chemica Mineraria SPA.
The clay may be a hectorite clay. Typical hectorite clay has the general formula:
Formula (III) [(Mg3-xLix)Si4.yMemyO10(OH2.zFz)]-(x+y)((x+y)/n)Mn+
wherein y = 0 to 0.4, if y = >0 then Mem is Al, Fe or B, preferably y = 0; Mn+ is a monovalent (n = 1) or a divalent (n = 2) metal ion, preferably selected from Na, K, Mg, Ca and Sr. x is a number from 0.1 to 0.5, preferably from 0.2 to 0.4, more preferably from

0.25 to 0.35. z is a number from 0 to 2. The value of (x + y) is the layer charge of the clay, preferably the value of (x + y) is in the range of from 0.1 to 0.5, preferably from 0.2 to 0.4, more preferably from 0.25 to 0.35. A preferred hectorite clay is that supplied by Rheox under the tradename Bentone HC. Other preferred hectorite clays for use herein are those hectorite clays supplied by CSM Materials under the tradename Hectorite U and Hectorite R, respectively.
The clay may also be selected from the group consisting of: allophane clays; chlorite clays, preferred chlorite clays are amesite clays, baileychlore clays, chamosite clays, clinochlore clays, cookeite clays, corundophite clays, daphnite clays, delessite clays, gonyerite clays, nimite clays, odinite clays, orthochamosite clays, pannantite clays, penninite clays, rhipidolite clays, sudoite clays and thuringite clays; illite clays; inter-stratified clays; iron oxyhydroxide clays, preferred iron oxyhydoxide clays are hematite clays, goethite clays, lepidocrite clays and ferrihydrite clays; kaolin clays, preferred kaolin clays are kaolinite clays, halloysite clays, dickite clays, nacrite clays and hisingerite clays; smectite clays; vermiculite clays; and mixtures thereof.
The clay may also be a light coloured crystalline clay mineral, preferably having a reflectance of at least 60, more preferably at least 70, or at least 80 at a wavelength of 460nm. Preferred light coloured crystalline clay minerals are china clays, halloysite clays, dioctahedral clays such as kaolinite, trioctahedral clays such as antigorite and amesite, smectite and hormite clays such as bentonite (montmorillonite), beidilite, nontronite, hectorite, attapulgite, pimelite, mica, muscovite and vermiculite clays, as well as pyrophyllite/talc, willemseite and minnesotaite clays. Preferred light coloured crystalline clay minerals are described in GB2357523A and WO01/44425.
Preferred clays have a cationic exchange capacity of at least 70meq/100g. The cationic exchange capacity of clays can be measured using the method described in Grimshaw, The Chemistry and Physics of Clays, Interscience Publishers, Inc., pp. 264-265 (1971).
Preferably, the clay has a weight average primary particle size, typically of greater than 20 micrometers, preferably more than 23 micrometers, preferably more than 25 micrometers, or preferably from 21 micrometers to 60 micrometers, more preferably from 22 micrometers to 50 micrometers, more preferably from 23 micrometers to 40
micrometers, more preferably from 24 micrometers to 30 micrometers, more preferably from 25 micrometers to 28 micrometers. Clays having these preferred weight average primary particle sizes provide a further improved fabric-softening benefit. The method for determining the weight average particle size of the clay is described in more detail hereinafter.
Method For Determining The Weight Average Primary Particle Size Of The Clay:
The weight average primary particle size of the clay is typically determined using the following method: 12g clay is placed in a glass beaker containing 250ml distilled water and vigorously stirred for 5 minutes to form a clay solution. The clay is not sonicated, or microfluidised in a high pressure microfluidizer processor, but is added to said beaker of water in an unprocessed form (i.e. in its raw form). 1ml clay solution is added to the reservoir volume of an Accusizer 780 single-particle optical sizer (SPOS) using a micropipette. The clay solution that is added to the reservoir volume of said Accusizer 780 SPOS is diluted in more distilled water to form a diluted clay solution; this dilution occurs in the reservoir volume of said Accusizer 780 SPOS and is an automated process that is controlled by said Accusizer 780 SPOS, which determines the optimum concentration of said diluted clay solution for determining the weight average particle size of the clay particles in the diluted clay solution. The diluted clay solution is left in the reservoir volume of said Accusizer 780 SPOS for 3 minutes. The clay solution is vigorously stirred for the whole period of time that it is in the reservoir volume of said Accusizer 780 SPOS. The diluted clay solution is then sucked through the sensors of said Accusizer 780 SPOS; this is an automated process that is controlled by said Accusizer 780 SPOS, which determines the optimum flow rate of the diluted clay solution through the sensors for determining the weight average particle size of the clay particles in the diluted clay solution. All of the steps of this method are carried out at a temperature of 20°C. This method is carried out in triplicate and the mean of these results determined.
Silicone
The silicone is preferably a fabric-softening silicone. The silicone typically has the general formula

(Figure Removed)

Formula (IV)

wherein, each RI and R2 in each repeating unit, -(Si(Ri)(R2)0)-, are independently selected from branched or unbranched, substituted or unsubstituted Ci-Cio alkyl or alkenyl, substituted or unsubstituted phenyl, or units of -[-RiR2Si-O-]-; x is a number from 50 to 300,000, preferably from 100 to 100,000, more preferably from 200 to 50,000; wherein, the substituted alkyl, alkenyl or phenyl are typically substituted with halogen, amino, hydroxyl groups, quaternary ammonium groups, polyalkoxy groups, carboxyl groups, or nitro groups; and wherein the polymer is terminated by a hydroxyl group, hydrogen or -SiRs, wherein, Ra is hydroxyl, hydrogen, methyl or a functional group.
Suitable silicones include: amino-silicones, such as those described in EP150872, WO92/01773 and US4800026; quaternary-silicones, such as those described in US4448810 and EP459821; high-viscosity silicones, such as those described in WOOO/71806 and WOOO/71807; modified polydimethylsiloxane; functionalized polydimethyl siloxane such as those described in US5668102, Preferably, the silicone is a polydimethylsiloxane.
The silicone may preferably be a silicone mixture of two or more different types of silicone. Preferred silicone mixtures are those comprising: a high-viscosity silicone and a low viscosity silicone; a functionalised silicone and a non-functionalised silicone; or a non-charged silicone polymer and a cationic silicone polymer.
The silicone typically has a viscosity, of from 5,000cp to 5,000,000cp, or from greater than lO.OOOcp to l,000,000cp, or from 10,000cp to 600,000cp, more preferably from 50,000cp to 400,000cp, and more preferably from 80,000cp to 200,000cp when measured at a shear rate of 20s"1 and at ambient conditions (20°C and 1 atmosphere). The silicone is typically in a liquid or liquefiable form, especially when admixed with the clay. Typically, the silicone is a polymeric silicone comprising more than 3, preferably more than 5 or even more than 10 siloxane monomer units.
The silicone is in the form of an emulsion, especially when admixed with the clay. The emulsion can be a water-in oil emulsion or an oil-in water emulsion. The emulsion is
preferably in the form of a water-in-oil emulsion with the silicone forming at least part, and preferably all, of the continuous phase, and the water forming at least part, and preferably all, of the discontinuous phase. The emulsion typically has a volume average primary droplet size of from 0.1 micrometers to 5,000 micrometers, preferably from 0.1 micrometers to 50 micrometers, and most preferably from 0.1 micrometers to 5 micrometers. The volume average primary particle size is typically measured using a Coulter Multisizer™ or by the method described in more detail below.
The silicone in emulsified form typically has a viscosity of from SOOcp to 70,000cp, or from 3,000cp to 20,000cp.
Commercially available silicone oils that are suitable for use are DC200™ (12,500cp to 600,000cp), supplied by Dow Corning, or silicones of the Baysilone Fluid M series supplied by GE Silicone. Alternatively, preformed silicone emulsions are also suitable for use. These emulsions may comprise water and/or other solvents in an effective amount to aid the emulsification of the silicone.
Method For Determining The Volume Average Droplet Size Of The Silicone:
The volume average droplet size of the emulsion is typically determined by the following method: An emulsion is applied to a microscope slide with the cover slip being gently applied. The emulsion is observed at 400X and 1,OOOX magnification under the microscope and the average droplet size of the emulsion is calculated by comparison with a standard stage micrometer.
Emulsifier
The emulsifier can be any surfactant, preferably a detersive surfactant. Suitabke detersive surfactants include anionic detersive surfactants, non-ionic detersive surfactants, cationic detersive surfactants, zwitterionic detersive surfactants amphoteric detersive surfactants and mixtures thereof. Preferred detersive surfactants are selected from the group consisting of C8-18alkyl sulphates, C8-18alkyl ethoxylated sulphates having an average degree of ethoxylation of from 1 to 7, C8-18 linear alkylbenzene sulphonates, d carboxylic acids, C8-18alkyl ethoxylated alcohols having an average degree of ethoxylation of from 1 to 7, Cn-24 alkyl N-methyl glucose amides, C8-18alkyl
polyglucosides, amine oxides, Cn-24 alkyl betaines, C8-18 mono-alkyl mono-ethoxy dimethyl quaternary ammonium chlorides, and mixtures thereof. Most preferably, the emulsifier is an anionic detersive surfactant such as a linear alkyl benzene sulphonate.
Charged polymeric fabric-softening boosting component
The charged polymeric fabric-softening boosting component is preferably cationic. Preferably, the charged polymeric fabric-softening boosting component is a cationic guar gum.
The charged polymeric fabric-softening boosting component may be a cationic polymer that comprises (i) acrylamide monomer units, (ii) other cationic monomer units and (iii) optionally, other monomer units. The charged polymeric fabric-softening boosting component may be a cationically-modified polyacrylamide or co-polymer thereof; any cationic modification can be used for these polyacrylamides. Highly preferred charged polymeric fabric-softening boosting components are co-polymers of acrylamide and a methyl chloride quaternary salt of dimethylaminoethyl acrylate (DMA3-MeCl), for example such as those supplied by BASF, Ludwigshafen, Germany, under the tradename Sedipur CL343.
Formula (V)
(Figure Removed)
The general structure of acrylamide is:
The general structure for DMASMeCl is:
(Figure Removed)
Formula (VI)
Preferred cationic polymers have the following general structure:
(Figure Removed)

Formula (VII)
wherein n and m independently are numbers in the range of from 100 to 100,000, preferably from 800 to 3400. The molar ratio of n:m is preferably in the range of from 4:1 to 3:7, preferably from 3:2 to 2:3.
Suitable charged polymeric fabric-softening boosting components are described in more detail in, and can be synthesized according to the methods described in, DE10027634, DE10027636, DE10027638, US61 1 1056, US6147183, WO98/17762, W098/21301, W001/05872 and, W001/05874.
The charged polymeric fabric-softening boosting component preferably has an average degree of cationic substitution of from 1% to 70%, preferably from above 10% to 70%, more preferably from 10% to 60%. If the charged polymeric fabric-softening boosting component is a cationic guar gum, then preferably its degree of cationic substitution is from 10% to 15%. However, if the charged polymeric fabric-softening boosting component is a polymer having a general structure according to formula VII above, then preferably its degree of cationic substitution is from 40% to 60%. The average degree of cationic substitution typically means the molar percentage of monomers in the cationic polymer that are cationically substituted. The average degree of cationic substitution can be determined by any known methods, such as colloid titration. One such colloid titration method is described in more detail by Horn, D., in Prog. Colloid &Polymer ScL, 1978, 8, p243-265.
The charged polymeric fabric-softening boosting component preferably has a charge density of from 0.2meq/g to 1.5meq/g. The charge density is typically defined in terms of the number of charges carried by the polymer, expressed in rnilliequivalents/gram. One equivalent is the weight of the material required to give one mole of charge; one milliequivalent is a thousandth of this.
Preferably, the charged polymeric fabric-softening boosting component has a weight average molecular weight of from above 100,000 Da to below 10,000,000 Da,
preferably from 500,000 Da to 2,000,000 Da, and preferably from 1,000,000 Da to 2,000,000. Any known gel permeation chromatography (GPC) measurement methods for determining the weight average molecular weight of a polymer can be used to measure the weight average molecular weight of the charged polymeric fabric-softening boosting component. GPC measurements are described in more detail in Polymer Analysis by Stuart, B. H., pl08-l 12, published by John Wiley & Sons Ltd, UK, © 2002. A typical GPC method for determining the weight average molecular weight of the charged polymeric fabric-softening boosting component is described below:
Method For Determining The Weight Average Molecular Weight of the Charged Polymeric Fabric-Softening Boosting Component:
1. Dissolve 1.5g of polymer in 1 litre of deionised water.
2. Filter the mixture obtained in step 1, using a Sartorius Minisart RC25 filter.
3. According the manufacturer's instructions, inject 100 litres of the mixture obtained
in step 2., on a GPC machine that is fitted with a Suprema MAX (8mm by 30cm)
column operating at 35°C and a ERC7510 detector, with 0.2M aqueous solution of
acetic acid and potassium chloride solution being used as an elution solvent at a
flux of 0.8 ml/min.
4. The weight average molecular weight is obtained by analysing the data from the
GPC according to the manufacturer's instructions.
Flocculating aid
The flocculating aid is capable of flocculating clay. Typically, the flocculating aid is polymeric. Preferably the flocculating aid is a polymer comprising monomer units selected from the group consisting of ethylene oxide, acrylamide, acrylic acid and mixtures thereof. Preferably the flocculating aid is a polyethyleneoxide. Typically the flocculating aid has a molecular weight of at least 100,000 Da, preferably from 150,000 Da to 5,000,000 Da and most preferably from 200,000 Da to 700,000 Da.
Adjunct components
The auxiliary composition and/or the laundry detergent composition may optionally comprise one or more adjunct components. These adjunct components are typically

selected from the group consisting of detersive surfactants, builders, polymeric co-builders, bleach, chelants, enzymes, anti-redeposition polymers, soil-release polymers, polymeric soil-dispersing and/or soil-suspending agents, dye-transfer inhibitors, fabric-integrity agents, brighteners, suds suppressors, fabric-softeners, flocculants, and combinations thereof.
Auxiliary composition
The auxiliary composition is for use in the laundering or treatment of fabrics and typically either forms part of a fully formulated laundry detergent composition or is an additive composition, suitable for addition to a fully formulated laundry detergent composition. Preferably, the auxiliary composition forms part of a fully formulated laundry detergent composition.
The auxiliary composition comprises an admix of clay and a silicone in an emulsified form. Typically, the auxiliary composition additionally comprises a charged polymeric fabric-softening boosting component and optionally one or more adjunct components. Preferably, the charged polymeric fabric-softening boosting component is present in the auxiliary composition in the form of an admix with the clay and the silicone; this means that typically, the charged polymeric fabric-softening boosting component is present in the same particle as the clay and silicone.
Preferably, the weight ratio of the silicone to emulsifier, if present, in the auxiliary composition is from 3:1 to 20:1. Preferably, the weight ratio of silicone to clay is from 0.05 to 0.3.
Laundry detergent composition
The laundry detergent composition comprises the auxiliary composition, a detersive surfactant, optionally a flocculating aid, optionally a builder and optionally a bleach. The laundry detergent composition optionally comprises one or more other adjunct components.
The laundry detergent composition is preferably in particulate form, preferably in free-flowing particulate form, although the composition may be hi any liquid or solid form. The composition in solid form can be in the form of an agglomerate, granule, flake,
extrudate, bar, tablet or any combination thereof. The solid composition can be made by methods such as dry-mixing, agglomerating, compaction, spray drying, pan-granulation, spheronization or any combination thereof. The solid composition preferably has a bulk density of from 300g/l to l,500g/l, preferably from 500g/l to l,000g/l.
The composition may also be in the form of a liquid, gel, paste, dispersion, preferably a colloidal dispersion or any combination thereof. Liquid compositions typically have a viscosity of from SOOcps to 3,000cps, when measured at a shear rate of 20s"1 at ambient conditions (20°C and 1 atmosphere), and typically have a density of from 800g/l to 1300g/l. If tthe composition is in the form of a dispersion, then it will typically have a volume average particle size of from 1 micrometer to 5,000 micrometers, preferably from 1 micrometer to 50 micrometers. The particles that form the dispersion are usually the clay and, if present, the silicone. Typically, a Coulter Multisizer is used to measure the volume average particle size of a dispersion.
The composition may in unit dose form, including not only tablets, but also unit dose pouches wherein the composition is at least partially enclosed, preferably completely enclosed, by a film such as a polyvinyl alcohol film.
The composition is capable of both cleaning and softening fabric during a laundering process. Typically, the composition is formulated for use in an automatic washing machine, although it can also be formulated for hand-washing use.
The following adjunct components and levels thereof, when incorporated into a laundry detergent composition of the present invention, further improve the fabric-softening performance and fabric-cleaning performance of the laundry detergrnt composition: at least 10% by weight of the composition of alkyl benzene sulphonate detersive surfactant; at least 0.5%, or at least 1%, or even at least 2% by weight of the composition of cationic quaternary ammonium detersive surfactant; at least 1% by weight of the composition alkoxylated alkyl sulphate detersive surfactant, preferably ethoxylated alkyl sulphate detersive surfactant; less than 12% or even less than 6%, or even 0%, by weight of the composition zeolite builder; and any combination thereof. Preferably the laundry detergent composition comprises at least 6%, or even at least 8%, or even at least 12%, or even at least 18%, by weight of the laundry detergent composition of the auxiliary composition. Preferably the composition comprises at least 0.3% by weight of
the composition of a flocculating aid. The weight ratio of clay to flocculating aid in the laundry detergent composition is preferably in the range of from 10:1 to 200:1, preferably from 14:1 to 160:1 more preferably from 20:1 to 100:1 and more preferably from 50:1 to 80:1.
Process
The process for making the auxiliary composition comprises the steps of (i) contacting a silicone with water, and optionally an emulsifier, to form a silicone in an emulsified form; and (ii) thereafter contacting the silicone in an emulsified form with clay to form an admix of clay and a silicone.
Preferably the silicone is in a liquid or liquefiable form when it is contacted to the clay in step (ii). Preferably the emulsion formed in step (i) is a water-in-oil emulsion with the silicone forming at least part of, and preferably all of, the continuous phase of the emulsion, and the water forms at least part of, and preferably all of, the discontinous phase of the emulsion.
Preferably, a charged polymeric fabric-softening boosting component is contacted to the clay and silicone in step (ii). The intimate mixing of the charged polymeric fabric-softening boosting component with the clay and silicone further improves the fabric-softening performance of the resultant auxiliary composition.
Step (i) may be carried out at ambient temperature (e.g. 20°C), but it may be preferred that step (i) is carried out at elevated temperature such as a temperature in the range of from 30°C to 60°C. If an emulsifier is used in the process, then preferably the emulsifier is contacted to water to form an emulsifier-water mixture, thereafter the emulsifier-water mixture is contacted to the silicone. For continuous processes, step (i) is typically carried out in an in-line static mixer or an in-line dynamic (shear) mixer. For non-continuous processes, step (i) is typically carried out in a batch mixer such as a Z-blade mixer, anchor mixer or a paddle mixer.
The admix of clay and silicone is preferably subsequently agglomerated in a high-sheer mixer. Suitable high-sheer mixers include CB Loedige mixers, Schugi mixers, Littleford mixers, Drais mixers and lab scale mixers such as Braun mixers. Preferably the high-sheer mixer is a pin mixer such as a CB Loedige mixer or Littleford mixer or Drais
mixer. The high-sheer mixers are typically operated at high speed, preferably having a tip speed of from 30ms"1 to 35ms"1. Preferably water is added to the high-sheer mixer.
The admix of clay and silicone are typically subsequently subjected to a conditioning step in a low-shear mixer. Suitable low-shear mixers include Ploughshear mixers such as a Loedige KM. Preferably the low-shear mixer has a tip speed of from 5ms"1 to 10ms"1. Optionally, fine particles such as zeolite and/or clay particles, typically having an average particle size of from 1 micrometer to 40 micrometers or even from 1 micrometer to 10 micrometers are introduced into the low-shear mixer. This dusting step improves the flowability of the resultant particles by reducing their stickiness and controlling their growth.
The admix of clay and silicone is typically subjected to a sizing step, wherein particles having a particle size of greater than 500mm are removed from the admix. Typically, these large particles are removed from the admix by sieving.
The admix of clay and silicone is preferably subjected to hot air having a temperature of greater than 50°C or even greater than 100°C. Typically, the admix of clay and silicone is dried at an elevated temperature (e.g. a temperature of greater than 50°C or even greater than 100°C); preferably, the admix is dried in a low-shear apparatus such as fluid bed drier. Following this preferred drying step, the admix of clay and silicone is preferably thereafter subjected to cold air having a temperature of less than 15°C, preferably from 1°C to 10°C. This cooling step is preferably carried out in a fluid bed cooler.
The admix of clay and silicone is preferably subjected to a second sizing step, wherein particles having a particle size of less than 250 micrometers are removed from the admix. These small particles are removed from the admix by sieving and/or elutriation. If elutriation is used, then preferably the second sizing step is carried out in a fluid bed such as the fluid bed dryer and/or cooler, if used in the process.
The admix of clay and silicone is preferably subjected to a third sizing step, wherein particles having a particle size of greater than 1,400 micrometers are removed from the admix. These large particles are removed from the admix by sieving.
The large particles that are optionally removed from the admix during the first and/or third sizing steps are typically recycled back to the high sheer mixer and/or to the
fluid bed dryer or cooler, if used in the process. Optionally, these large particles are subjected to a grinding step prior to their introduction to the high sheer mixer and/or fluid bed dryer or cooler. The small particles that are optionally removed from the admix during the second sizing step are typically recycled back to the high sheer mixer and/or low shear mixer, if used in the process.
Examples
Example 1: A process for preparing a silicone emulsion
81.9g of silicone (polydimethylsiloxane) having a viscosity of 100,000cp is added to a beaker. 8.2g of 30w/w% aqueous Cn-Cia alkyl benzenesulphonate (LAS) solution is then added the beaker and the silicone, LAS and water are mixed thoroughly by hand using a flat knife for 2 minutes to form an emulsion.
Example 2: A process for making a clay/silicone agglomerate
601.2g of bentonite clay and 7.7g of cationic guar gum are added to a Braun mixer. 90. Ig of the emulsion of example 1 is added to the Braun mixer, and all of the ingredients in the mixer are mixed for 10 seconds at l,100rpm (speed setting 8). The speed of the Braun mixer is then increased to 2,000rpm (speed setting 14) and 50g water is added slowly to the Braun mixer. The mixer is kept at 2,000rpm for 30 seconds so that wet agglomerates are formed. The wet agglomerates are transferred to a fluid bed dried and dried for 4 minutes at 137°C to form dry agglomerates. The dry agglomerates are sieved to removed agglomerates having a particle size greater than 1,400 micrometers and agglomerates having a particle size of less than 250 micrometers.
Example 3: A clay/silicone agglomerate
A clay/silicone agglomerate suitable for use in the present invention comprises: 80.3wt% bentonite clay, 1.0wt% cationic guar gum, 10.9wt% silicone (polydimethylsiloxane), 0.3wt% Cn-Cu alkyl benzenesulphonate (LAS) and 7.5wt% water.
Example 4: A clay/silicone agglomerate
A clay/silicone agglomerate suitable for use in the present invention comprises: 72.8wt% bentonite clay, 0.7wt% cationic guar gum, 15.9wt% silicone (polydimethylsiloxane), 0.5wt% Cn-Cu alkyl benzenesulphonate (LAS) and 10.1wt% water.
Example 5: A laundry detergent composition
A laundry detergent composition suitable for use in the present invention comprises: 15wt% clay/silicone agglomerates of either example 3 or example 4 above; 0.2wt% polyethylene oxide having a weight average molecular weight of 300,OOODa; 1 lwt% Cl 1-13 linear alkylbenzenesulphonate detersive surfactant; 0.3wt% C12-14 alkyl sulphate detersive surfactant; lwt% C^-Cn alkyl, di-methyl, ethoxy quaternary ammonium detersive surfactant; 4wt% crystalline layered sodium silicate; 12wt% zeolite A; 2.5wt% citric acid; 20wt% sodium carbonate; 0.1 wt% sodium silicate; 0.8wt% hydrophobically modified cellulose; 0.2wt% protease; 0.1 wt% amylase; 1.5wt% tetraacetlyethylenediamine; 6.5wt% percarbonate;
0.1 wt% ethylenediamine-N'N-disuccinic acid, (S,S) isomer in the form of a sodium salt; 1.2wt% 1,1-hydroxyethane diphosphonic acid; 0.1 wt% magnesium sulphate; 0.7wt% perfume; 18wt% sulphate; 4.7wt% miscellaneous/water.
Example 6: A laundry detergent composition
A laundry detergent composition suitable for use in the present invention comprises: 12.5wt% clay/silicone agglomerates of either example 3 or example 4 above; 0.3wt% polyethylene oxide having a weight average molecular weight of 300,OOODa; llwt% Cn-13 linear alkylbenzenesulphonate detersive surfactant; 2.5wt% Cn-Cn alkyl, di-methyl, ethoxy quaternary ammonium detersive surfactant; 4wt% crystalline layered sodium silicate; 12wt% zeolite A; 20wt% sodium carbonate; 1.5wt% tetraacetlyethylenediamine; 6.5wt% percarbonate; 1.0wt% perfume; 18wt% sulphate; 10.7wt% miscellaneous/water.
Example 7: A laundry detergent composition
A laundry detergent composition suitable for use in the present invention comprises: 12.5wt% clay/silicone agglomerates of either example 3 or example 4 above; 6.0wt% clay; 0.3wt% polyethylene oxide having a weight average molecular weight of 300,OOODa; 10wt% C\\.H linear alkylbenzenesulphonate detersive surfactant; lwt% alkyl sulphate detersive surfactant condensed with an average of 7 moles of ethylene oxide; 4wt% crystalline layered sodium silicate; 18wt% zeolite A; 20wt% sodium carbonate; 1.5wt% tetraacetlyethylenediamine; 6.5wt% percarbonate; 1.0wt% perfume; 15wt% sulphate; 4.2wt% miscellaneous/water.

We Claim:
1. An auxiliary composition, for use in the laundering or treatment of fabrics, the auxiliary
composition comprising:
an admix of (i) a clay and
(ii) a silicone in an emulsified form comprising a water-in-oil emulsion, the water-in-oil emulsion comprising: a continuous phase comprising a silicone; and a discontinuous phase comprising water and a bleach wherein the weight ratio to silicone to clay is between 0.05 to 0.3 and the weight ratio of silicone to emulsifier is from 3:1 to 20:1.
2. The auxiliary composition as claimed in claim 1, wherein the auxiliary composition further comprises at least one charged polymeric fabric-softening boosting component.
3. The auxiliary composition as claimed in claim 2, wherein the charged polymeric fabric-softening boosting component has a charge density of from 0.2 meg/g to 1.5 meg/g.
4. The auxiliary composition as claimed in claim 2. wherein the charged polymeric fabric-softening boosting component has a weight average molecular weight of from 1,000,000 to 2,000,000 Da.
5. The auxiliary composition as claimed in claim 2, wherein the charged polymeric fabric-softening boosting component is cationic guar gum.
6. The auxiliary composition as claimed in claim 1, wherein the silicone in an emulsified form has a viscosity of from 3000 cp to 20,000 cp at a shear rate of 20 s-1, preferably from 500 cp to 7,000 cp at a shear rate of 20 s-1.
7. The auxiliary composition as claimed in claim 1, wherein the silicone has a viscosity of from 10,000 cp to 600,000 cp at a shear rate of 20 s-1, preferably from 50,000 cp to
400,000 cp at a shear rate of 20 s-1.
8. The auxiliary composition as claimed in claim 1, wherein the silicone is a
polydimethylsiloxane.
9. The auxiliary composition as claimed in claim 1. wherein the discontinuous phase of the emulsion has an average droplet size of from 0.1 micrometers to 5 micrometers.
10. The auxiliary composition as claimed in claim 1. wherein the clay is a fabric-softening clay, preferably a montmorillonite clay.
11. The auxiliary composition as claimed in claim 1, wherein the emulsifier is an anionic detersive surfactant, preferably a linear alkylbenzene sulphonate detersive surfactant.
12. The auxiliary composition as claimed in claim 1, wherein the clay has a primary particle size of from 14 micrometers to 160 micrometers.
13. An auxiliary composition as claimed in claim 1. whenever used in a laundry detergent composition comprising:
i) said auxiliary composition;
ii) a detersive surfactant;
iii) optionally, a flocculating aid:
iv) optionally, a builder; and
v) optionally one or more adjunct component.
14. The laundry detergent as claimed in claim 13, wherein the flocculating aid is a polyethylene oxide having a weight average molecular weight of from 200.000 to Da to 700,000 Da.
15. The laundry detergent as claimed in claim 13, wherein the composition is in free-flowing particulate form.
16. A process for preparing an auxiliary composition as claimed in claim 1, the process comprises the steps of:
i) contacting a silicone with water, and optionally an emulsifier, to form a silicone in
an emulsified form; and ii) thereafter contacting the silicone in an emulsified form with clay to form an admix
of clay and a silicone in an emulsified form; and wherein the weight ratio to silicone to clay is between 0.05 to 0.3 and the weight ratio of silicone to emulsifier is from 3:1 to 20:1.
17. The process as claimed in claim 16. wherein at least one charged polymeric fabric-
softening boosting component is contacted to the clay and silicone in step (ii).
18. The process as claimed in claim 16. wherein the admix of clay and a silicon in an art emulsified from is subsequently agglomerated in a high-shear mixer to form an agglomerate.
19. The process as claimed in claim 18. wherein the water is added to the high-shear mixer.
20. The process as claimed in claim 16. wherein the admix of clay and silicone in an
emulsified form is subjected to a temperature of greater than 100°C.

Documents:

4340-DELNP-2006-Abstract (03-11-2009).pdf

4340-DELNP-2006-Abstract-(07-02-2012).pdf

4340-delnp-2006-abstract.pdf

4340-delnp-2006-assignment.pdf

4340-DELNP-2006-Claims (03-11-2009).pdf

4340-delnp-2006-Claims-(26-03-2010).pdf

4340-delnp-2006-claims.pdf

4340-delnp-2006-Correspondence Others-(02-06-2011).pdf

4340-DELNP-2006-Correspondence Others-(07-02-2012).pdf

4340-DELNP-2006-Correspondence-Others (03-11-2009).pdf

4340-delnp-2006-Correspondence-Others (19-11-2009).pdf

4340-DELNP-2006-Correspondence-Others (22-01-2010).pdf

4340-DELNP-2006-Correspondence-Others (29-10-2009).pdf

4340-DELNP-2006-Correspondence-Others-(05-05-2010).pdf

4340-DELNP-2006-Correspondence-Others-(09-12-2010).pdf

4340-delnp-2006-Correspondence-Others-(12-03-2010).pdf

4340-DELNP-2006-Correspondence-Others-(14-06-2010).pdf

4340-delnp-2006-Correspondence-Others-(22-03-2010).pdf

4340-DELNP-2006-Correspondence-Others-(22-06-2010).pdf

4340-delnp-2006-Correspondence-Others-(26-03-2010).pdf

4340-delnp-2006-Correspondence-Others-(28-04-2011).pdf

4340-delnp-2006-correspondence-others-1.pdf

4340-delnp-2006-correspondence-others.pdf

4340-delnp-2006-Description (Complete)-(26-03-2010).pdf

4340-delnp-2006-description (complete).pdf

4340-DELNP-2006-Form-1 (03-11-2009).pdf

4340-DELNP-2006-Form-1-(07-02-2012).pdf

4340-delnp-2006-form-1.pdf

4340-delnp-2006-form-18.pdf

4340-DELNP-2006-Form-2 (03-11-2009).pdf

4340-DELNP-2006-Form-2-(07-02-2012).pdf

4340-delnp-2006-form-2.pdf

4340-delnp-2006-Form-3 (19-11-2009).pdf

4340-DELNP-2006-Form-3 (29-10-2009).pdf

4340-DELNP-2006-Form-3-(09-12-2010).pdf

4340-DELNP-2006-Form-3-(14-06-2010).pdf

4340-delnp-2006-Form-3-(28-04-2011).pdf

4340-delnp-2006-form-3.pdf

4340-delnp-2006-form-5.pdf

4340-delnp-2006-gpa.pdf

4340-delnp-2006-pct-210.pdf

4340-delnp-2006-pct-304.pdf

4340-delnp-2006-Petition 137-(12-03-2010).pdf

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Patent Number

251669

Indian Patent Application Number

4340/DELNP/2006

PG Journal Number

13/2012

Publication Date

30-Mar-2012

Grant Date

27-Mar-2012

Date of Filing

27-Jul-2006

Name of Patentee

THE PROCTER & GAMBLE COMPANY

Applicant Address

ONE PROCTER & CAMBLE PLAZA, CINCINNATI, OHIO 45202, U.S.A.

Inventors:

#	Inventor's Name	Inventor's Address
1	BLYTH, KEVIN, GRAHAM	16 GARSDALE ROAD, WHITLEY BAY TYNE AND WEAR NE26 4 NU, GREAT BRITAIN,
2	GRAYDON, ANDREW, RUSSELL	27 DENEWELL AVENUE, LOW FELL, GATESHEAD TYNE AND WEAR NE9 5HD, GREAT BRITAIN
3	STEPHENSON, COLIN	76 SINONSIDE TERRACE, HEATON, NEWCASTLE UPON TYNE TYNE AND WEAR NE65 5JY, GREAT BRITAIN

PCT International Classification Number

C11D 3/37

PCT International Application Number

PCT/US2005/003066

PCT International Filing date

2005-02-01

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	04250560.2	2004-02-03	EUROPEAN UNION
2	PCT/US2005/003066	2005-02-01	EUROPEAN UNION