Title of Invention	A TWO-COMPONENT POLYURETHANE COMPOSITION
Abstract	A two-component polyurethane composition composed of a polyol component K1 and a polylsocyanate component K1 K2; the polyol component K1 comprising at least one alkoxylated aromatic diol A1 and at least one aliphatic triol A2, and the polylsocyanate component K2 comprising at least one polylsocyanate B1, wherein the weight ratio A1/A2 is between 0.5 and 0.3.

Full Text

TWO-COMPONENT POLYURETHANE COMPOSITIONS THAT ARE ESPECIALLY SUITABLE FOR USE AS STRUCTURAL ADHESIVES Technical Field The invention relates to the field of two-component po1yurethane compositions, more particularly of structural two-component polyurethano adhesives. Prior Art Two-component polyurcthane adhesives based on polyols and poly isocyanates have already been known for a long time. Two-component polyurethane adhesives have the advantage that, after mixing, they cure rapidly and so are able to accommodate relatively high forces rapidly after just a short time. For use as structural adhesives, however, exacting requirements in respect of strengths and adhesive forces are imposed on such adhesives, since adhesives of this kind constitute elements of load-bearing structures. High strengths are typically achieved through high degrees of crosslinking . This is typically achieved through the use of relatively highly polyfunctional polyols or polyamlnes and relatively highly polyfunctional po1yisocyanates. Thus, for example, EP 1 253 159 Al discloses in the examples a structural adhesive whose po1yo1 component comprises a mixture of a tetra functional aliphatic polyol and a difunctional aliphatic polyol and whose isocyanate component is a prepolymer based on polypropylene glycol and 4,4'-diphenylmethane diisocyanate . A high level of use of the highly polyfunctional. reactants, however, has the effect of a massive decrease in the extension, with the result that stress peaks occur under load, and adhesives of this kind become brittle . There is therefore a desire for rapid adhesives which exhibit hiqh strengths and nevertheless a high elasticity. Description of the Invention It is an object of the present invention, therefore, to provide a two-component polyurethane composition, more particularly a structural two-component polyurethane adhesive, which features high strength with high extension. This is made possible through the two- component polyurethane composition of claim 1 . The addition of an alkoxylated aromatic diol to an aliphatic triol in the polyol component surprisingly increases the extension but without lowering the strength. The improved extension leads to improved Impact, toughness of the cured material. In addition it has been found that the composition of the invention, as a result in particular of the use of an alkoxylated aromatic diol, has improved adhesion to metallic surfaces. Finally it has been observed that the composi ti.ons of the invention are distinguished by outstanding aging stability, more particu1ar1y with respect to moisture find temperature fluctuation. Embodiments of the Invention The present invention relates to a two-component polyurethane composition composed of a polyol component K1 and a poly isocyanate component K2. This polyol component K1 comprises at least one alkoxylated aromatic diol A1 and at least one aliphatic triol A2. The po.l y.i socyana l.e component. K2 comprises at least, one polyisocyanatc B1. The prefix "poly" in designations- such as "polyol", "po 1 y i socyanatc", "polyether" or "polyamine" indicates in the present document that the substance in question contains, formally, more than one of the functional groups occurring in its name, per molecule. An "aromatic diol" here and below is a diol which contains at least one aromatic nucleus and two hydroxy groups. In the diol there may also be two or more aromatic nuclei present. Preferably the hydroxhyl , groups are not phenolic groups, i.e., they are advantageously not located directly on the aromatic nucleus. The aromatic nucleus may also be fused and/or heteroaromatic and/or a nucleus containing further s ubsfituents. In a heteroaromatic nuc1eus there are heteroatoms present which are part of the aromatic ring or r i rig system. Examples of aromatic nuclei of this kind are substituted benzene, naphthalene, anthracene, phenanthrene, imidazole, pyridine, pyrrole, pyrimidine, pyrazine, quinoline and phenazine. Examples of di.ois having two or more aromatic nuclei are diols having the parent structure of a bi phenyl,' terphenyl, 2,2.'- bipyridine, d i phony 1 methane, 1 , 1-dipheny 1 ethane or 2.,2.- dipheny1 propane. Aromatic diols which have shown themselves to be particularly suitable are those prepared from phenol and from formaldehyde, acefaldehyde or acetone or mixtures thereof, more particularly bisphenol A, bisphenol F or bisphenol A/F. Preferably the alkoxylated aromatic diol A1 is an ethoxylated and/or propoxylated aromatic diol.. Al koxylated diols of this kind preferably have the structure of the formula (I) In this formula the substituent R1 is a group CH2, (CH(CH3) or C(CH3)2- The indices n, n' , m and m' are values such that n+n'+m+m' 1 to 20, more particularly n+n'+m+m' 1 to 8. Furthermore, the substituents R2 and R3 are each such that R2 II and R3 - methyl or R2 methyl and R3 II. The segments a1 and a1' denote an oxypropylene unit (PO) and a2 and a2' an oxyethylene unit (EO) . The dashed lines in formula (1) represent the fact, schematically, that the sequence of the mutually attached alkylene glycol segments a , a1 , a2 and a2 is variable. tor instance, a blockwise or alternating or random sequence of these oxyalkylene units is possible. Alkoxylated aromatic diols of this kind are prepared in a manner which is known to the skilled worker. It is clear to the ski1led worker, furthermore, that in the a1koxylation of a diol it is also entirely possible for molecules to be formed which have different, degrees of alkoxylation in the two chains. It is also clear to the skilled worker, moreover, that in the case of alkoxylafions there are always distributions of different molecules. This is reflected in the fact, inter alia, that the total degree of alkoxylation (" TAG" - n+n' +m+m') may also be odd-numbered or adopt a non-integral va1ue. Purely propoxy la ted aromatic dlols of: the formula (I) are preferred over purely ethoxylated or mixed EO/PO- alkoxylated aromatic dlols of the formula (L), i.e., n is preferably - n' = 0. With particular preference the aromatic diol Al is a diol of the formula (1) with R1 = CH2 or C(CH3)2H, more particularty C(CH3)2 - Aromatic diols Al which have shown themselves to be most preferable are those of the formula (1) where R1 C(CH3)2, n-n'=0, and having a total degree of alkoxylation of between 2 and 16. It can be advantageous for the two-component polyurethane composition also to contain mixtures of different aromatic diols Al. The aromatic diol Al is used preferably in an amount of 2% to 10% by weight, based on the overall composition. The aliphatic trio! A2 is an aliphatic triol having a molecular weight of 360 to 6000 g/mol, corresponding to an OH equivalent weight of 120 to 2000, in particular a molecular weight of 120 to 2000 g/mol, preferably of 160 to 17 00 g/mol. There are different kinds of such aliphatic triols. Thus, for example, they may contain urethane and/or urea and/or ether groups. The morphology of the triols may be very different. Thus, for example, star-shaped or comb-shaped triols are possible. It is additionally possible for the triol to contain not only primary but also secondary hydroxyl groups. Preferably all three hydroxyl groups are primary hydroxyl groups. Aliphatic triols A2 can be attained, for example, from an aliphatic triisocyanatc, more particularly from an isocyanurate, which is formed from three isocyanate molecules, in an excess of aliphatic diols, more particularly of polyetherdiols, where appropriate by further subsequent extension by means of aliphatic diisocyanates and allpiiatic diols. Further exemplary aliphatic tri.ols A2 may be obtained from low molecular weight aliphatic triols, such as trimethylolpropane or glycerol, for example, and an aliphatic diisocyanate, with subsequent reaction with an aliphaticdiol . Further exemplary aliphatic triols A2 are products of an alkoxylation reaction of low molecular weight aliphatic triols, such as trimethylolpropane or glycerol, for example. In particular these are ethoxylated, or propoxyiated or bufoxylated, aliphatic triols, more particularly those of trimethylolpropane or glycerol. 1t may be advantageous for the two-component polyurethane composition also to contain mixtures of different aliphatic triols A2 . In particular it has been found advantageous to use mixtures of an aliphatic triol A2 having a relatively low molecular weight, more particularly between 360 and 2700 g/mol, with an aliphatic triol A2 having a higher molecular weight, more particularly between 4200 and 6000 g/mol. If only one aliphatic triol A2 is used, it is advantageous to choose one having a medium molecular weight, more particularly between 2000 and 1000 g/mol. The weight, ratio A1/A2 of aromatic diol Al to aliphatic triol A2 is preferably between 0.0b and 0.3. The pol.yol component K1 may further comprise other constituents. It is advantageous to use curing catalysts. Catalysts of this kind are known to the skilled worker tor the reaction of polyisocyanates with polyols, and where appropriate also for reaction with polyamines or water. Examples that may be mentioned of such catalysts include organometailic catalysts of tin, zinc and bismuth, such as dibutyl tin dilaurato, or tertiary amines, such as 1,4-diazobicyclo [2..2.2]octane (DABCO) , for examp1e. As additional constituents it is also possible for there to be diols, more particularly polyoxyalkylene- diols, and/or diamines. Suitable amines include, in particular, aliphatic, araliphatic, cycloaliphatic and toxicologically unobjectionable aromatic amines. Through the selection and concentration of suitable amines and also catalysts it is possible to exert an advantageous influence over the pot life, cure behavior and slip behavior. The polyisocyanate component K2 comprises at least one polyisocyanate B1. Particularly suitable as polyisocyanate B1 are, on the one hand, polyisocyanates B1' which in addition to two or more free isocyanate groups contain at least one urea or urethane or biuret or urethdione group . Particularly suitable are polyisocyanates based on aromatic polyisocyanates, more particularly on diphenylmethane diisocyanate (2,4'- and/or 4,4'-MDI). On the one hand, polyisocyanates of the type as available commercially in the form of DesniodurR VII 20 from Bayer have been found particularly suitable, further suitable polyisocyanates B1 arc isocyanurates or biurets of a diisocyanate, more particularly of HD1 and/or IPDI and/or TDI . If is entirely possible to use mixtures of polyisocyanates B1'. One preferred embodiment, employs a polyisocyanate B1' mixture of the Desmodur® VH 20 type with an HD1 i socyanurate . Particularly suitable as po1ylsocyanate B1 on the other hand are polyurethane prepolymers B1" which contain at least two isocyanate groups and which are formed from a reaction of at Least one polyisocyanate having a molecular weight of less than 300 g/mol, more particularly of between 150 g/mol and 270 g/mol, with at Least one polyol AB1. Particularly suitable as polyol AB1 are polyols which are selected from the group encompassing polyetherpolyols, polyestcrpolyols, polycarbonatepolyols, polyols formed from unsaturated monomers and mixtures thereof. The preparation of isocyanate-group-containing polyurethane prepolymers of this kind is accomplished in a known way and typically takes place in a stolchiometric excess of the polyisocyanate over the polyol. Polyisocyanates used for this purpose include, in particular, 2,1- and 2,6- tolylene diisocyanate (TDI), 2,4'- and 4,4'-diphenyl- methane diisocyanate (MDT), 1,6-hexamethy.l ene diiso- cyanate (HDI) and the isomer mixtures thereof, and mixtures with one another. MD1 is particularly preferred. Polyetherpolyols, also called polyoxyalkyl enepo'l yols, are polymerization products of ethylene oxide, 1,2- propy.l one oxide, 1,2- or 2,3-butylene oxide, tetrahydrofuran or mixtures thereof; where appropriate they are polymerized with the aid of a starter molecule having two or more active hydrogen atoms, such as water, ammonia, or compounds having two or more OH or NH groups, for example, such as 1, 2-ethanedi ol , 1,2- and 1 , 3-propanediol, neopentyl glycol, diethylene glycol, triethyl ene glycol, the isomeric dipropylene glycols and tripropylene glycols, the isomeric butanedio1s, pentanediols, hexanediols, heptanediols, octanediols, nonanediols, decanedlols, undecanediols, 1,3- and 1 , 4-cyclohexanedimetLianol , bisphenol A, hydrogenated blsphenol A, 1, 1, 1-trimethylolethane, 1,1,1-trimethylol propane, glycerol, aninino, and mixtures of the aforementioned compounds. It is possible to use not only polyoxyalkyienepolyols which have a low degree of unsaturation (measured in accordance with ASTM D-2819-69 and reported in millioquivatonls of unsaturation per gram of polyol (moq/g)), prepared for example by means of double metal cyanide complex catalysts (DMC catalysts), but also polyoxyalkylenepolyols having a higher degree of unsaturation, prepared for example by means of anionic catalysts such as NaOH, KOH or alkali metal alkoxides. Particu1ar1y suitable are polyoxya1kylenedio1s or polyoxyalkylcnetriols, more particularly polyoxy- propy] enediols or polyoxypropy]enetriols. Acclaim types of specific suitability are polyoxyalkylenediols or polyoxyalkylenetriols having a degree of unsaturation of less than 0.02. meq/g and having a molecular weight in the range from 1000 to 30 000 g/mol, and also polyoxypropylenedio1s and -triols having a molecular weight of 400 to 8000 g/mol. By "molecular weight" or "molar weight" is meant, in the present document, always the molecular weight average Mn . Likewise particularly suitable are what are called EO- endcapped" (othy 1 ene ox.i de-endcapped) polyoxypropy lene- diols or triols. The latter are special polyoxy- propylene-polyoxyethyl enepolyols, obtained for example by alkoxylating pure polyoxypropylenepo1yols with ethylene oxide after the end of the polypropoxy1ation, and which as a result have primary hydroxyl groups. Polyesterpolyols are, in particular, polyols which are formed for example from dihydric and/or trihydric alcohols such as, for example, 1, 2-ethanediol, diethylene glycol, 1 , 2-propanediol , dipropyl ene glycol, 1 , 4-butanediol., 1, 5-pentanediol, 1, 6-hexanodiol , neopentylglycol , glycerol , 1,1,1-trimethylolpropane or mixtures of the aforementioned alcohols with organic dicarboxyl ic acids or their anhydrides or esters, such as, for examp1e, succinic acid, g1utaric acid, adipic acid, suberic acid, sebacic acid, dodecanedicarboxylic acid, maleic acid, fumaric acid, phthalic acid, isophthalic acid, terephthalic acid and hexa- hydrophtha1ic acid or mixtures of the aforementioned acids, and also polyesterpolyols formed from lactones, such as E-capro1 actone, for example. Particularly preferred polycarbonatepolyo1s are those obtainable by reacting the abovementioned alcohols those used to synthesize the polyesterpolyols with dialkyl carbonates, diaryl carbonates or phosgene. By "polyols formed from unsaturated monomers" are meant, in particular, polyols of the kind formed from the polymerization of at least one of the monomers selected from the group encompassing ethylene, propylene, butyl one, butadiene, isoprene, styrene, vinyl alcohol, vinyl ethers, vinyl esters, acrylonitrile, acids, amides and esters of acrylic acid, methacrylic acid, maleic acid, fumaric acid, crotonic acid and itaconic acid and also mixtures thereof. Particularly suitable polyols formed from unsaturated monomers are hydroxy-functional polybutadienes such as pol ybu tadi enepol yo 1 s and hydrogenated polybutadiene- polyols, and also po1y(meth)acrylalepolyo1s. By " (meth)acrylate" is meant, here and in the remainder of Lhe present document;, esters of both acrylic acid and of methacrylic acid. Similarly, "(meth) acrylic acid" identifies not only acrylic acid but also methacrylic acid . "Poly(meth)acrylatepolyols" here are polymers which are copolymers of a hydroxy-functional (meth)acrylic ester and at least one further monomer selected from the qroup encompassing the monomers acrylic acid, methacrylic acid, C1-C18 alkyl esters of acrylic acid or methacrylic acid, styrcne, vinyl esters and vinyl alcoho1. Preferred hydroxy- functional (me th )acrylic csters are hydroxyethy 1 (meth) acrylate, hydroxypropy-L (meth)acrylate and hydroxybutyl (meth)acrylate. These stated polyols ABl preferably have an average molecular weight of 250 to 30 000 g/mol , more particularly of 1000 to 8000 g/mol, and are preferably diols or triols, more particularly having an average OH functionality in the range from 1.6 to 3. One preferred embodiment uses a mixture of polyols AB1 which is a mixture of diols and triols. In one embodiment of the invention the polylsocyanate component K2 comprises at least one polylsocyanate B1' and at least, one polylsocyanate polyurethane prepolymer Bl". Both components K1 and K2, may contain additional constituents in addition to those already mentioned, of the kind the skilled worker knows from two-component polyurethane chemistry. These constituents may be present in only one component or in both. Examples of additional constituents of this kind that are used include solvents, plasticizers and/or extenders, fillers, such as carbon blacks, chalks or taics, adhesion promoters, more particularly trialkoxysilanes, and thixotropic agents, such as amorphous silicas, and zeolites. As the skilled polyurethane adhesives worker knows, if is necessary to ensure, when preparing the components, particularly in the case of the polylsocyanate component K2, that the raw materials are very largely free from water and that, during and followinq their preparation, it is virtually impxxssibio for any molsture to come into contact with the component. This is achieved on the one hand by physical or chemical drylng of the starting substances, and also by opjerating under inert gas, typxically nitrogen. The components K1 and K2 are advantageously formulated such that the volume ratio of component. Kl to component K2 is between 1:3 and 3:1, more particularly between 1:2 and 2:1. With particular preference this ratio is approximately 1:1. The mixing ratio is preferably such that the NCO groups of conrponent K2 are stolchiometric in relation to the NCO-reactive group)s, typylcal ly Oil groups, of component Kl. If mixing is carried out not with substantial stolchiometry, i.e., with deviations of more than 5%, the reaction of components K1 and K2 is non-optimal, leading to a reduction in the me c h a n ic a 1 p) r o p e r Lies o f f h c c u r e d p) o 1 y u r e L h a n e compos i t i on. This is true in particular for an excess of the polyoJ. component. In the case of an excess of polylsocyanafe, the situation is likewise fundamentally disadvantageous, but the impaired mechanical properties can be at least partly remedied by the subsequent reaction of the un reacted isocyanafe group) s with molsture, o r 1 q 1 n a t. i n g f o r e x amp) 1 e f r om f h e a 1 m o s p) h o r i c molsture, which may if appropriate lead to further crosslinks. Prior to application, the components K1 and K2 are stored .separately from one another and are mixed with one another only during or immediately prior to application. The components are advantageously present in a pack which is composed of two separate chambers, with the polyol component Kl present in one chamber and the polylsocyanate component K2 present in the other chamber. The components K1 and K2 are introduced into the chambers of the pack and given an airtight and mo i s1u re-1 i gh t seal. Preferred packages of this kind are, on the one hand, side-by-si.de double cartridges or coaxial cartridges, in which two tubular chambers are arranged alongside one another or inside one another and are sealed with pistons in an airtight and molsture-tight way. The driving of these pistons allows the components to be extruded from the cartridge. The ends of the tubes opposite the pistons are modified in such a way, via an adapter where appropriate, that the chamber openings in the region of the opening are connected directly to one another via a dividing wall. Advantageously there is a thread made in the region of the exit opening of the chambers, so that a static mixer or dynamic mixer can be mounted closely. Packages of this kind are preferred in particular for small-scale applications, in particular for volumes of up to 1 liter. For larger applications, particularly for applications in industrial manufacture, the components K1 and K2 are advantageously dispensed and stored in drums or pails, in this case the components are extruded via hydraulic presses, in particular by way of follower plates, and are supplied via pipelines to a mixing apparatus of the kind typically used for two-component adhesives in i.ndu s t r i a1 manu f actu re. With any package it is important that the po1ylsocyanate component K2 at least. be given an airtight and molsture-tight seal, so that. both components can be stored for a long time, i.e., typically longer than 6 months. The method of adhesive bonding comprises the following steps: mixing the above-described components K1 and K2, applylng the mixed po'l yuref hane composition to at least one substrate surface to be bonded, carrylng out jolning within the open time, curing the polyurethane composition. Mixing is accomp.li.shod typically via static mixers or with the aid of dynamic mixers. At the mixing stage it is important to ensure that the two components are mixed as homogeneously as possible. If the two components are poorly mixed, there are local deviations from the optimum mixing ratio i.e., substantially stolchiometric - and this has the consequence of an impairment in the mechanical properties of the cured potyurethane composition. in order to assess the quality of mixing from a visual standpolnt as well it is advantageous if the two components K1 and K2 have two different colors, which can be distinguished well visually from one another and also from the mixture. An example of a color combination of this kind is present when one component is black and the other is white, in that case, effective mixing is present when there is a homogeneous gray color and there are no streaks or patterns in light or dark gray or in white or black. The mixed potyurethane composition 'is applied to at least one substrate surface to be bonded. The substrate to be bonded is preferably a metal, plastic, glass or ceramic. Typically there are two substrates present and intended for bonding. It is possible for the partner adherend, i.e., the second substrate, to be identical to or di f f erenf f rom the f i rs f subs 1, ra t.c . Adhos i ve ma y be applied to the first and/or second adherend. following application of adhesive, the adherends are jolned within the open time. Subsequent to jolning, the potyurethane composition is cured. This produces an assembly of the adherends, the adhesive positively connecting these adherends to one another. The polyurethano composition is preferably employed as a structural adhesive. Typi. cal examples of applications for such adhcsi.ves are found in built structures, automobiles, vehicles or boats. In these cases the c u r c d a d h e s i v e i s p art o f a 1 o a d - b e a r i n g st.ru c t u r e a n d t h e r e f o r e c o n s t i t u t e s a n i mp o r t a n t c o n n e c t i n g clem e n t, whose mechanical properties arc subject to exacting requirements. The present invention meets these exacting requirements very well, indeed. Moreover, as a result of the high extension, the adhesive composition of the invention exhibits high impact toughness and also an outstanding aging stabi l.ity, particularly with respect to molsture and temperature fluctuation. Additionally it has been found that the composition of the invention, particularly as a result o f; the use of an alkoxylated aromatic diol, has an improved adhesion to metallic surfaces. Examples Preparation The compositions Exl and Ex2 and also Ref.l as reference example, set out by way of example in table 1, aJ1 have the same component K2 . For the production of components Kl, ExAl and ExA2, and also of the reference component RefA.l, the po.lyol mixture was charged to a vacuum dissolver and, fo.l lowing the addition of catalyst and drylng agent, and in the absence of molsture, the mixture was stirred at. 25 °C for 2 0 minutes. These polyo.l components Kl were subsequent]y dispensed into one chamber of a sido-by- side double cartridge (vol/vol - 1:1) made of: polypropylene, and were given an airtight and molsture- fight seal with plastic pistons. For component K2, dried chalk was added to the polylsocyanate and incorporated homogeneously in a vacuum dissolver, with stirring and under reduced pressure, at 25°C for 20 minutes. Subsequently this polylsocyanate component K2 was dispensed into the second chamber of the abovementioned side-by-side double cartridge, and was likewise provided with an airtight and molsture-tight seal using a plastic piston. Components K1 and K2 were mixed 1:1 votumetrical1y by means of a static mixer, in the quantities indicated in tab1e 1 . Measurements The mixed components K1 and K2 were introduced into dumbbell molds in accordance with ISO 527, Part 2, 1B and were cured at 25°C for 2 4 h and then at 105°C for 3 h. following a conditioning time of 24 h at 25°C, elasticity modulus, tensi1e strength and elongation of the specimens thus produced were measured in accordance with ISO 527 on a ½wick 7,020 tensile testing machine, with a test temperature of 20°C and a test speed of 50 mm/min. From the results it. is evident that examples Ex1 and Ex2 have not only a higher tensile strength but also higher breaking elongation as compared with Ref.1. WE CLAIM: 1. A two-component polyurethane composition composed of a polyol component K1 and a polylsocyanate component K2; the polyol component K1 comprising at least one alkoxylated aromatic diol A1 and at least one aliphatic triol A2, and the polylsocyanate component K2 comprising at least one polylsocyanate B1, wherein the weight ratio A1/A2 is between 0.5 and 0.3. 2. The two-component polyurethane composition as claimed in claim 1, wherein the polylsocyanate Bl is a polylsocyanate Bl' which as well as two or more free isocyanate groups contains at least one urea or urethane or biuret or urethdione group. 3. The two-component polyurethane composition as claimed in claim 2, wherein the polylsocyanate B1' is an isocyanurate or biuret of a diisocyanate, more particularly of HDI and/or IPDI and/or TDI. 4. The two-component polyurethane composition as claimed in claim 1, wherein the polylsocyanate B1 is a polyurethane prepolymer B1" which contains at least two isocyanate groups and which is prepared from a reaction of at least one polylsocyanate having a molecular weight of less than 300 g/mol, more particularly of between 150 g/mol and 270 g/mol, with at least one polyol AB1. 5. The two-component polyurethane composition as claimed in claim 4, wherein the polylsocyanate having a molecular weight of less than 300 g/mol is MDI, HDI or TDI, more particularly MDI. 6. The two-component polyurethane composition as claimed in any one of the preceding claims, wherein the composition comprises at least one polylsocyanate B1' as described in claim 2 or 3 and at least one polyurethane prepolymer B1" as described in claim 4 or 5. 7. The two-component polyurethane composition as claimed in any one of the preceding claims, wherein the alkoxylated aromatic diol A1 is an ethoxylated and/or a propoxylated aromatic diol. & The two-component polyurethane composition as claimed in claim 7, wherein the diol has the formula (I) where R1 = CH2, CH(CH3) or C(CH3)2, R2=H and R3= methyl, or R2 = methyl and R3 = H, and also n+n'+m+m' = 1 to 20, more particularly n+n'+m+m' = 1 to 8, and the dashed lines indicate that the sequence of the mutually attached alkylene glycol segments a1, a1', a2 and a2' is variable. 9. The two-component polyurethane as claimed in claim 8, wherein n=n'=0. 10. The two-component polyurethane composition as claimed in any one of the preceding claims, wherein the aliphatic triol A2 possesses a molecular weight of 360 to 6000 g/mol, more particularly of 160 to 1700 g/mol. 11. The two-component polyurethane composition as claimed in any one of the preceding claims, wherein the aromatic diol A1 is present in an amount of 2% to 10% by weight, based on the overall composition. 12. The two-component polyurethane composition as claimed in any one of the preceding claims, wherein the volume ratio of components K1 and K2 is between 1:3 and 3:1, preferably approximately 1:1. 13. A method of adhesive bonding comprising the steps of -mixing the components K1 and K2 of a two-component polyurethane composition as claimed in any one of claims 1 to 13, -applylng the mixed polyurethane composition to at least one substrate surface to be bonded, -carrylng out jolning within the open time, -curing the polyurethane composition. 14. The method as claimed in claim 13, wherein the substrate to be bonded is a metal, plastic, glass or ceramic. ABSTRACT TITLE: A TWO-COMPONENT POLYURETHANE COMPOSITION A two-component polyurethane composition composed of a polyol component K1 and a polylsocyanate component K1 K2; the polyol component K1 comprising at least one alkoxylated aromatic diol A1 and at least one aliphatic triol A2, and the polylsocyanate component K2 comprising at least one polylsocyanate B1, wherein the weight ratio A1/A2 is between 0.5 and 0.3.

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03299-kolnp-2007-abstract.pdf

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3299-KOLNP-2007-(19-10-2011)-CORRESPONDENCE.pdf

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3299-KOLNP-2007-(27-03-2012)-ABSTRACT.pdf

3299-KOLNP-2007-(27-03-2012)-AMANDED CLAIMS.pdf

3299-KOLNP-2007-(27-03-2012)-CORRESPONDENCE.pdf

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3299-KOLNP-2007-(27-03-2012)-FORM-1.pdf

3299-KOLNP-2007-(27-03-2012)-FORM-2.pdf

3299-KOLNP-2007-(27-03-2012)-OTHERS.pdf

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3299-KOLNP-2007-(31-10-2011)-OTHERS.pdf

3299-KOLNP-2007-CORRESPONDENCE.pdf

3299-KOLNP-2007-EXAMINATION REPORT.pdf

3299-kolnp-2007-form 18.pdf

3299-KOLNP-2007-FORM 26.pdf

3299-KOLNP-2007-FORM 3.pdf

3299-KOLNP-2007-FORM 5.pdf

3299-KOLNP-2007-GRANTED-ABSTRACT.pdf

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3299-KOLNP-2007-GRANTED-DESCRIPTION (COMPLETE).pdf

3299-KOLNP-2007-GRANTED-FORM 1.pdf

3299-KOLNP-2007-GRANTED-FORM 2.pdf

3299-KOLNP-2007-GRANTED-SPECIFICATION.pdf

3299-KOLNP-2007-INTERNATIONAL PUBLICATION.pdf

3299-KOLNP-2007-INTERNATIONAL SEARCH REPORT.pdf

3299-KOLNP-2007-OTHERS PCT FORM.pdf

3299-KOLNP-2007-OTHERS.pdf

3299-KOLNP-2007-PCT PRIORITY DOCUMENT NOTIFICATION.pdf

3299-KOLNP-2007-REPLY TO EXAMINATION REPORT.pdf

3299-KOLNP-2007-TRANSLATED COPY OF PRIORITY DOCUMENT.pdf