Title of Invention	"SILICON ETHER COMPOUNDS AND A METHOD FOR THE PREPARATION THEREOF"
Abstract	The present invention relates to silicon ether compounds having a general formula (I), a method for the preparation thereof and use thereof as a component of catalysts for polymerization of olefins. In particular, in propylene polymerization, catalyst systems comprising the silicon ether compounds as external electron donor component exhibit good hydrogen response, and can be used to prepare polymer having high isotacticity at high yield. (I) wherein R1-R10 groups are as defined in the description.

Title of Invention

"SILICON ETHER COMPOUNDS AND A METHOD FOR THE PREPARATION THEREOF"

Abstract

The present invention relates to silicon ether compounds having a general formula (I), a method for the preparation thereof and use thereof as a component of catalysts for polymerization of olefins. In particular, in propylene polymerization, catalyst systems comprising the silicon ether compounds as external electron donor component exhibit good hydrogen response, and can be used to prepare polymer having high isotacticity at high yield. (I) wherein R1-R10 groups are as defined in the description.

Full Text	SPECIFICATION Silicon Ether Compounds and a Method for the Preparation thereof Technical field The present invention relates to novel silicon ether compounds, a method for the preparation thereof and use thereof as a component of catalysts for olefins polymerization. In olefins polymerization or copolymerization, in particular, in propylene polymerization or copolymerization, catalyst systems comprising the silicon ether compounds as external electron donor component exhibit good hydrogen response, and can be used to prepare polymer having high isotacticity at high yield. Background Art Catalysts for olefins polymerization or copolymerization are well known in literatures. These catalysts typically comprise a transition metal-containing active component, generally comprising magnesium, titanium and halogen as main ingredients; a cocatalyst component, typically organo-aluminium compound; and external electron donor component, typically organo-silicon compound. For stereoelective polymerization of olefins, especially stereoelective polymerization of propylene, if no external electron donor component is used, most of these catalysts give a polymer having lower isotacticity, typically lower than 90%, so that they are not applicable to industrial scale production. Therefore, the addition of external electron donor component is often necessary. At present, the types of external electron donor compounds have developed from initial benzoates to current organosiloxane. For instance, WO 00/63261 discloses external electron donor compounds useful in olefins polymerization, i.e. silicon compounds having a general formula R11aR12bSi(OR13)c, wherein a and b are zero or integer of from 1 to 2, c is integer of from 1 to 3, and the sum of a+b+c is 4, R11, R12 and R13 are independently C1-C18 hydrocarbyl which optionally contains a heteroatom. The preferred are those silicon compounds in which a is 1, b is 1, c is 2, at least one of R11 and R12 is selected from the group consisting of branched alkyl, alkenyl, alkylene, cycloalkyl and aryl, having from 3 to 10 carbon atoms and containing optionally a heteroatom, and R13 is C1-C10 alkyl, especially methyl, for example, cyclohexylmethyldimethoxysilane. The also preferred are those silicon compounds in which a is 0, c is 3, R12 is branched alkyl or cycloalkyl, containing optionally a heteroatom, and R13 is methyl, for example, cyclohexyltrimethoxysilane and the like. It is noted that, among the silicon compounds having the general formula R11aR12bSi(OR13)c, those silicon compounds in which c is 1 are generally not deemed as good external electron donor. In the prior art, 2,2-dihydrocarbyl-1-hydrocarbyloxy-3-(trihydrocarbylsilyloxy)propane compounds have never been used as external electron donor compounds in olefins polymerization. However, the inventors have surprisingly found that, when used as external electron donor in olefins polymerization, especially in propylene polymerization, silicon ether compounds of general formula (I), which will be described in detail hereinbelow, exhibit good properties, for instance, the catalyst systems exhibit good hydrogen response, and can be used to prepare polymer having high isotacticity at high yield. Description the invention One object of the present invention is to provide silicon ether compounds having general formula (I) (Formula Removed) wherein, R1-R4 groups, which are identical to or different from each other, represent C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, R5-R10 groups, which are identical to or different from each other, represent hydrogen, halogen, or C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R1R10 groups optionally contain one or more hetero-atoms selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom for replacing carbon atom(s), hydrogen atom(s) or the both, with the priviso that when all R1-R3 are methyl, R4 is not 2-(3-methyl-2-buten-1-yl)-cyclopropan-1-yl; when R-1R2R3Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4 is not benzyl; when both R9 and R10 are hydrogen, R5-R8 groups are each methyl or hydrogen, and R4 is C1-C4 linear or branched alkyl, then R1-R3 are not simultaneously methyl or ethyl; and when both R9 and RIO are methyl, all R5-R8 are hydrogen, and R4 is C1-C3 linear or branched alkyl, then R1-R3 are not simultaneously ethyl. In an embodiment of the invention, in the silicon ether compounds having the general formula (I), R1-R4 groups, which are identical to or different from each other, represent C1-C10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R5-R10 groups, which are identical to or different from each other, represent hydrogen, halogen, or CrCio linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl. In another embodiment of the invention, in the silicon ether compounds having the general formula (I), R1-R4 groups, which are identical to or different from each other, represent methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, tert-butyl, phenyl or benzyl, R5-R8 groups are hydrogen atom, and R9 and RIO groups are independently CrCio linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl. In still another embodiment of the invention, the silicon ether compounds according to the invention have a general formula (II) (Formula Removed) wherein, R1'-R4' groups, which are identical to or different from each other, represent linear or branched C1-C5 alkyl, phenyl or benzyl, with the priviso that when R1R2'R3'Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4' is not benzyl; and when R4' is C1-C3 linear or branched alkyl, R1R21 and R3' are not simultaneously ethyl. Preferably, in the above general formula (II), R3' and R4' groups are independently methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl. More preferably, in the above general formula (II), R1and R2' groups are methyl, and R3' and R4' groups are independently methyl, ethyl, or tert-butyl. Most preferably, R4' group is methyl or ethyl. Examples of the silicon ether compounds of formula (I) include, but are not limited to, 2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(triethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(triethylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dimethyl-1-propoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(triphenylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(triphenylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(triethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(triphenylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-di-iso-butyl-1-ethoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(triethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(triphenylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-di-iso-butyl-1-propoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(triethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(triethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(triethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethyltolylsilyl)oxy]propane; Examples of a preferred group of the the silicon ether compounds of formula (I) include: 2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane; 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane. Many methods can be used to prepare the silicon ether compounds of the above formula (I), and this constitutes another aspect of the invention. For instance, a compound of the formula (III) (Formula Removed) wherein R4 group represents C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, R5-R10 groups, which are identical to or different from each other, represent hydrogen, halogen, or C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R4-R10 groups optionally contain one or more hetero-atoms selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom for replacing carbon atom(s), hydrogen atom(s) or the both, can react with a trihydrocarbylsilylating agent which can introduce -SiR1R2R3 group, wherein R1-R3 groups, which are identical to or different from each other, represent C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R1-R3 groups optionally contain one or more hetero-atoms selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom for replacing carbon atom(s), hydrogen atom(s) or the both, in an aprotic inert solvent and, if needed, in the presence of a base, to form corresponding silicon ether compound of the formula (I), wherein equivalent ratio of the compound of formula (III) to the trihydrocarbylsilylating agent is in a range of from 1:1 to 1:1.2. According to an embodiment of the invention, in the above preparation method, a trihydrocarbylsilyl halide is used as the trihydrocarbylsilylating agent, the reaction of the silylating agent and the compound of formula (III) is carried out in the presence of a base, and the raw materials are charged at such amounts that molar ratio of the compound of formula (III) : trihydrocarbylsilyl halide : base is in a range of 1 : 1-1.2 : 1-1.2. The base used can be selected from the group consisting of inorganic bases and organic bases, such as Na, K, NaOH, KOH, NaH, KH, CaH2, Na2CO3, K2CO3, NH3, Et3N, Me3N, Bu3N, pyridine, imidazole, 4-dimethylaminopyridine, and mixtures thereof. The preferred are organic bases, such as Et3N, imidazole, and 4-dimethylaminopyridine. According to another embodiment of the invention, in the above preparation method, a hexahydrocarbyl disilazane is used as the silylating agent, and the raw materials are charged at such amounts that molar ratio of the compound of formula (III) to hexahydrocarbyl disilazane is in a range of 1 : 0.5-0.6. The aprotic inert solvent can be selected from the group consisting of amides, halohydrocarbons, hydrocarbons, and ethers, such as dichloromethane, chloroform, benzene, toluene, n-hexane, cyclohexane, petroleum ether, diethyl ether, tetrahydrofuran, tert-butyl methyl ether, N,N-dimethyl formamide, and mixtures thereof, with dichloromethane being preferred. The trihydrocarbylsilylating agent can be selected from the group consisting of trihydrocarbylsilyl halides and hexahydrocarbyl disilazanes, such as trimethylsilyl chloride, ethyldimethylsilyl chloride, tert-butyldimethylsilyl chloride, triethylsilyl chloride, dimethylphenylsilyl chloride, n-butyldimethylsilyl chloride, benzyldimethylsilyl chloride, and hexamethyl disilazane. The preparation reaction is typically carried out at a temperature of from -20°C to 100°C, preferably at a lower temperature, more preferably at a temperature of from -5°C to room temperature. The compounds of the formula (III) are known in the art or can be synthesized through a method known per se in the art. For instance, said compounds can be obtained through mono-etherization of propandiols with haloalkanes. Specifically, a method can comprise the step of mono-etherizing a propandiol compound with a haloalkane in the presence of a solvent and in the presence of a base, to form a 3-hydrocarbyloxy-1 -propanol compound, wherein, the solvent used can be selected from the group consisting of tetrahydrofuran, dimethyl sulfoxide, diethyl ether, N,N-dimethyl formamide; aliphatic hydrocarbons, such as, pentane, hexane, and heptane; and aromatic hydrocarbons, such as, benzene, and toluene; wherein, the base used can be hydrides, hydroxides, or carbonates of alkali metals or alkali earth metals, such as, NaH, KH, CaH2, NaOH, KOH, Ca(OH)2, Na2CO3, K2CO3, or the like. Among these bases, NaH and NaOH are preferable. Furthermore, the base is preferably added gradually into the reaction mixture after the addition of the diol, haloalkane and solvent; and wherein, molar ratio of the base to the propandiols is in a range of from 0.5:1 to 1.5:1, preferably from 0.8:1 to 1.2:1, and molar ratio of the haloalkane to the propandiols is in a range of from 1:1 to 10:1, preferably from 1:1 to 2.5:1. The present invention further relates to a process for olefins polymerization, wherein , a silicon ether compound according to the invention is used as external electron donor compound. In a preferable embodiment, said process is homopolymerization or copolymerization of propylene. Processes for the polymerization of olefins and application mode and amount of external electron donor compounds therein are well known in the art. Examples The following examples further describe the invention, but do not make limitation to the invention in any way. Testing methods: 1. Isotacticity of polymer: measured by heptane extraction method (heptane boiling extraction for 6 hours) carried out according to the following procedure: 2g of dried polymer sample is extracted with boiling heptane in an extractor for 6 hours, then the residual substance is dried to constant weight, and ratio of the weight of the residual polymer (g) to 2 is taken as isotacticity. 2. Melt index of polymer: measured according to ASTM D1238-99. Some intermediates used in the Examples were prepared as follows. Preparation of 2,2-dimethyl-3-methoxy-1-propanol To a reactor were added 34.4 g of 2,2-dimethyl-1,3-propandiol and 150 ml of dried THF, then 11.3 g of NaH was slowly added with stirring. After the addition, the reaction mixture was refluxed for one hour. Next, a solution of 51.1 g of methyl iodide in 300 ml of THF was added dropwise, and upon completing the addition, the reaction was allowed to continue for further 6 hours. The THF was removed by distillation. The remainder was diluted with 50 ml of water, and extracted thrice with 3 X 50 ml of diethyl ether. The combined diethyl ether extract was dried over anhydrous magnesium sulfate. After filtering out the magnesium sulfate, diethyl ether was evaporated, and the remainder was distilled under vacuum. 27.7g of colorless and clear liquid 2,2-dimethyl-3-methoxy-1-propanol (yield 71%) was collected as 86-88 °C/71mmHg fraction. 1H-NMR(CDCI3/TMS, 300MHz) 5 (ppm): 0.91 (s, 6 H, 2CH3), 2.77 (t, 1H, OH), 3.25(s, 2H, -CH2O-), 3.34(s, 3 H, OCH3), 3.44(d, 2H, -CH2O-). Preparation of 2,2-dimethyl-3-ethoxy-1-propanol Colorless and clear 2,2-dimethyl-3-ethoxy-1-propanol as 83 °C/37 mmHg fraction was prepared from 2,2-dimethyl-1,3-propandiol and ethyl iodide through the same procedure as described in the preparation of 2,2-dimethyl-3-methoxy-1-propanol. 1H NMR (CDCI3/TMS, 300MHz) 8 (ppm): 0.92 (s, 6H, -CH3), 1.19 (t, 3H, -CH3), 2.98 (t, 1H, -OH), 3.29 (s, 2H, -CH2O-), 3.44-3.51 (m, 4H, -OCHjpCHs, -CH2O-). Preparation of 2,2-dibenzyl-3-methoxy-1-propanol 2,2-Dibenzyl-3-methoxy-1-propanol was prepared from 2,2-dibenzyl-1,3-propandiol and methyl iodide through the same procedure as described above. 1H-NMR(CDCI3/TMS) δ (ppm): 2.34(t, 1H, OH), 2.75(s, 4H, CH2Ph), 3.13(s, 2H, CH2O), 3.33(s, 3H, OCH3), 3.44(d, 2H, CH2O), 7.20(m, 6H, 6ArH), 7.28(m, 4H, 4ArH). Preparation of 2,2-di-iso-butyl-3-methoxy-1-propanol 2,2-Di-iso-butyl-3-methoxy-1-propanol was prepared from 2,2-di-iso-butyl-1,3-propandiol and methyl iodide through the same procedure as described above. 1H-NMR(CDCI3/TMS) δ (ppm): 0.92(t, 12H, 4CH3), 1.26(d, 4H, 2CH2), 1.69(m, 2H, 2CH), 2.84(t, 1H, OH), 3.31 (2s, 5H, CH3O, CH2O), 3.52(d, 2H, CH2O). Preparation of 2,2-di-n-butyl-3-methoxy-1-propanol 2,2-Di-n-butyl-3-methoxy-1-propanol was prepared from 2,2-di-n-butyl-1,3-propandiol and methyl iodide through the same procedure as described above. 1H-NMR(CDCI3/TMS) δ (ppm): 0.90(t, 6H, 2CH3), 1.20(t, 4H, 2CH2), 1.26(m, 8H, 4CH2), 2.75(t, 1H, OH), 3.29(s, 2H, CH2O), 3.32(s, 3H, OCH3), 3.48(d, 2H, CH2O). Preparation of 2,2-di-n-propyl-3-methoxy-1-propanol 2,2-Di-n-propyl-3-methoxy-1-propanol was prepared from 2,2-di-n-propyl-1,3-propandiol and methyl iodide through the same procedure as described above. 1H-NMR(CDCI3/TMS) δ (ppm): 0.89(t, 6H, 2CH3), 1.24(m, 8H, 4CH2), 2.70(s, 1H, OH), 3.28(s, 2H, CH2O), 3.32(s, 3H, OCH3), 3.48(s, 2H, CH2O). Example 1: Preparation of 2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane 1g of 2,2-dimethyl-3-methoxy-1-propanol was dissolved in 20 ml of dichloromethane. The resultant solution was cooled in ice-water bath to below 5°C, and 1.65 ml of triethyl amine was added thereto. After stirring the mixture for 5 minutes, 1 .29 ml of trimethylsilyl chloride was added drop-wise to the reaction mixture, and the mixture was stirred in ice-water bath for further 2 hours, and at room temperature for further 1 hour. The reaction mixture was washed with water, and the organic layer was separated and then dried over anhydrous sodium sulfate. After filtration, the filtrate was concentrated to give 1.33g of concentrate. The crude product was purified by column chromatography using petroleum ether as eluent, to give colorless pure compound. 1H-NMR(CDCI3/TMS) δ (ppm): 0.09(s, 9H, 3CH3), 0.85(s, 6H, 2CH3), 3.11 (s, 2H, -CH2O-), 3.30(s, 2H, -CH2O-), 3.32(s, 3H, CH3O-). Example 2: Preparation of 2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]-propane According to the procedure as described in Example 1, 2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-methoxy-1-propanol and reagent ethyldimethylsilyl chloride. 1H-NMR(CDCI3/TMS) δ (ppm): 0.06(s, 6H, 2CH3), 0.54(q, 2H, CH2), 0.85(s, 6H, 2CH3), 0.95(t, 3H, CH3), 3.11(s, 2H, CH2O), 3.31(2s, 5H, CH3O, CH2O). Example 3: Preparation of 2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy] -propane 1g of 2,2-dimethyl-3-methoxy-1-propanol was admixed with 10 ml of N,N-dimethyl formamide, and 0.29 g of imidazole was added thereto. The mixture was cooled in ice-water bath, and 1.65 ml of triethyl amine was added thereto. After stirring for 5 minutes, 1.65 g of tert-butyldimethylsilyl chloride in 10 ml of N,N-dimethyl formamide was slowly added to the reaction mixture, and the mixture was stirred in ice-water bath for further 4 hours. The reaction mixture was diluted with 10 ml of water, and extracted twice with 20 ml of dichloromethane for each time. The combined dichloromethane extract was dried over anhydrous sodium sulfate. After filtration, the filtrate was evaporated to dryness to give 1.78g of concentrate of 2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]-propane. The crude product was purified by column chromatography using petroleum ether as eluent, to give colorless pure compound. 1H-NMR(CDCI3/TMS) δ (ppm): 0.01 (s, 6H, 2CH3), 0.85(s, 6H, 2CH3), 0.88(s, 9H, 3CH3), 3.10(s, 2H, CH20), 3.30 (s, 5H, CH2O, OCH3). Example 4: Preparation of 2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy] -propane According to the procedure as described in Example 1, 2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-methoxy-1-propanol and reagent dimethylphenylsilyl chloride. 1H-NMR(CDCI3/TMS) 5 (ppm): 0.35(s, 6H, 2CH3), 0.87(s, 6H, 2CH3), 3.13(s, 2H, CH2O), 3.30(s, 3H, OCH3), 3.37 (s, 2H, CH2O), 7.38(m, 3H, 3ArH), 7.58(m, 2H, 2ArH). Example 5: Preparation of 2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane According to the procedure as described in Example 1, 2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-ethoxy-1-propanol and reagent trimethylsilyl chloride. 1H-NMR(CDCI3/TMS) 6 (ppm): 0.07(s, 9H, 3CH3), 0.83(s, 6H, 2CH3), 1.16(t, 3H, CH3), 3.12(8, 2H, CH2O), 3.30(s, 2H, CH2O), 3.43(q, 2H, CH2O). Example 6: Preparation of 2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy] -propane According to the procedure as described in Example 3, 2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-ethoxy-1-propanol and reagent tert-butyldimethylsilyl chloride. 1H-NMR(CDCI3/TMS) 5 (ppm): 0.01(s, 6H, 2CH3), 0.83(s, 6H, 2CH3), 0.88(s, 9H, 3CH3), 1.15(t, 3H, CH3), 3.13(s, 2H, CH2O), 3.31(s, 2H, CH2O), 3.43(q, 2H, CH2O). Example 7: Preparation of 2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane According to the procedure as described in Example 1, 2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-dibenzyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride. 1H-NMR(CDCl3/TMS) δ (ppm): 0.17(s, 9H, 3CH3), 2.72-2.82(dd, 4H, 2CH2), 2.81(s, 2H, CH2O), 3.10(8, 2H, CH2O), 3.46(s, 3H, OCH3), 7.22(m, 6H, 6ArH), 7.29(q, 4H, 4ArH). Example 8: Preparation of 2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy] -propane 4.16Mmol of 2,2-dibenzyl-3-methoxy-1-propanol was dissolved in 10 ml of N,N-dimethyl formamide, and 0.14 g (2.08mmol) of imidazole was added thereto. The solution was cooled in ice-water bath to below 5 °C, and 0.87 ml (6.24mmol) of triethyl amine was added thereto. After stirring for 5 minutes, 0.88 g (5.82mmol) of tert-butyldimethylsilyl chloride in 10 ml of N,N-dimethyl formamide was slowly added to the reaction mixture, and the mixture was stirred in ice-water bath for further 2 hours, and at room temperature for further 1 hour. The reaction mixture was diluted with 10 ml of water, and extracted using 30 ml of dichloromethane. The organic layer was separated, wished twice with 20 ml of water, and dried over anhydrous sodium sulfate. After filtration, the filtrate was concentrated to give 2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane. 1H-NMR(CDCI3/TMS) δ (ppm): 0.07(s, 6H, 2CH3), 1.01(s, 9H, 3CH3), 2.68-2.79(dd, 4H, 2CH2), 2.83(s, 2H, CH2O), 3.18(s, 2H, CH2O), 3.31(s, 3H, OCH3), 7.25(m, 10H, 10ArH). Example 9: Preparation of 2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy] -propane According to the procedure as described in Example 1, 2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-iso-butyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride. 1H-NMR(CDCI3/TMS) 5 (ppm): 0.06(s, 9H, 3CH3), 0.89(d, 6H, 2CH3), 0.90(d, 6H, 2CH3), 1.16(d, 2H, CH2), 1.18(d, 2H, CH2), 1.68(m, 2H, 2CH), 3.12(s, 2H, CH2O), 3.26(s, 3H, OCH3), 3.47(s, 2H, CH2O). Example 10: Preparation of 2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane According to the procedure as described in Example 1, 2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-butyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride. 1H-NMR(CDCI3/TMS) δ(ppm): 0.07(s, 9H, 3CH3), 0.89(t, 6H, 2CH3), 1.17(m, 8H, 4CH2), 1.26(m, 4H, 2CH2), 3.11 (s, 2H, CH2O), 3.28(s, 3H, OCH3), 3.31 (s, 2H, CH2O). Example 11: Preparation of 2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy] -propane According to the procedure as described in Example 8, 2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-butyl-3-methoxy-1-propanol and reagent tert-butyldimethylsilyl chloride. 1H-NMR(CDCI3/TMS) δ (ppm): 0.02(s, 6H, 2CH3), 0.88(s, 9H, 3CH3), 0.91 (t, 6H, 2CH3), 1.17(m, 8H, 4CH2), 1.27(m, 4H, 2CH2), 3.12(s, 2H, CH2O), 3.30(s, 3H, OCH3), 3.34(8, 2H, CH2O). Example 12: Preparation of 2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane According to the procedure as described in Example 1, 2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-butyl-3-methoxy-1-propanol and reagent triethylsilyl chloride. 1H-NMR(CDCI3/TMS) δ (ppm): 0.57(q, 6H, 3CH2), 0.91 (t, 6H, 2CH3), 0.96(t, 9H, 3CH3), 1.20(m, 8H, 4CH2), 1.27(m, 4H, 2CH2), 3.14(s, 2H, CH2O), 3.30(s, 3H, OCH3), 3.36(s, 2H, CH2O). Example 13: Preparation of 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy] -propane According to the procedure as described in Example 1, 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-propyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride. 1H-NMR(CDCI3/TMS) δ (ppm): 0.07(s, 9H, 3CH3), 0.88(t, 6H, 2CH3), 1.17(m, 8H, 4CH2), 3.11(s, 2H, CH2O), 3.28(s, 3H, OCH3), 3.32(s, 2H, CH2O). Examples 14-21 and Comparative Example 1 Preparation of the solid titanium-containing catalyst component To a reactor that had been completely purged with highly pure N2 were added successively 4.8g of magnesium dichloride, 95ml of toluene, 4ml of epichlorohydrin, and 12.5ml of tributyl phosphate. With stirring, the mixture was heated to 50°C and held at that temperature for 2.5 hours, thereby the solid was completely dissolved. Then 1.4g of phthalic anhydride was added thereto and the reaction mixture was held at that temperature with stirring for further one hour. The reaction mixture was cooled to below -25°C and 56ml of TiCI4 was added dropwise thereto over one hour, then the temperature was increased slowly to 80°C. Solid precipitated gradually during the heating. To the reaction mixture was added 6 mmol of di-n-butyl phthalate, and the reaction was held at that temperature with stirring for further one hour. After filtering, 70ml of toluene was used to wash the filter cake. The washing procedure was repeated twice. The resulting solid precipitates were treated with 60ml of toluene and 40ml of TiCI4 at 100°C for 2 hours, and after removing the mother liquid, the residue was treated with 60ml of toluene and 40ml of TiCI4 at 100°C for 2 hours again. After removing the mother liquid, the residue was washed with 60ml of toluene under boiling state for three times, washed with 60ml of hexane under boiling state for two times, washed with 60ml of hexane at room temperature for two times, to yield the solid titanium-containing catalyst component. Propylene polymerization experiments To a 5L stainless steel autoclave, in which atmosphere had been replaced with propylene gas completely, were added 2.5mmol of AIEt3, 0.1 mmol of silicon ether compounds prepared in the above Examples or known cyclohexylmethyldimethoxysilane, 10mg of the solid titanium-containing catalyst component prepared above, and 1L of hydrogen, followed by introduction of 2.3L of liquid propylene. The reactor was heated to 70°C, and held at that temperature for 1 hour. After the temperature was reduced and the pressure was relieved, PP resin powder was removed. Polymerization results were summarized in Table 1 . Table 1 (Table Removed) Example 22 and Comparative Example 2 Propylene polymerization experiments were carried out according to the same polymerization procedure as described above, except for that the amount of hydrogen gas was changed to 4L. Polymerization results were summarized in Table 2. For comparison, the results obtained in Example 15 as well as in Comparative Example 1 were also shown in Table 2. Table 2 (Table Removed) From the results shown in the Tables 1 and 2, it can be seen that, when the silicon ether compounds according to the present invention are used as external electron donor component of a catalyst for olefin polymerization, polymerization activity of the catalyst and isotacticity of the polymerization product obtained are satisfied. Furthermore, at the same hydrogen gas level, the polymerization using the silicon ether compounds according to the invention will give polymers having higher melt index than the polymerization using the silane compound commonly used in the art, and as the level of hydrogen gas increases, melt index increases more notably. These results sufficiently demonstrate that, when the silicon ether compounds according to the present invention are used as external electron donor component of a catalyst for olefin polymerization, the catalyst will exhibit relatively good hydrogen response, and this performance facilitates the development of various grades of polymers. The invention aims to develop novel external electron donor compounds useful in propylene polymerization. It is generally accepted that trihydrocarby-hydrocarbyloxy-silanes are not good external electron donors for olefin polymerization, and are not suitable for enhancing isotacticity of the polyolefin product. However, the inventors have found that, when using preferred silicon ether compounds of the invention substituting for cyclohexylmethyldimethoxysilane known in the art as external electron donor in olefin polymerization, a current catalyst remains its high catalytic activity, and exhibits good hydrogen response, and the prepared polypropylene has high isotacticity. These results prove that the silicon ether compounds of the invention are a class of highly effective external electron donor compounds. Although the present invention has been described in connection with embodiments and examples, further modifications and alternative embodiments of various aspects of the invention will be apparent to those skilled in the art in view of this description. Accordingly, this description is to be constructed as illustrative only and is for the purpose of teaching the general manner of carrying out the invention. We claim: 1. A silicon ether compound having a general formula (I): (Formula Removed) wherein, R1-R4 groups, which are identical to or different from each other, represent C1-C20 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, R5-R8 groups, which are identical to or different from each other, represent hydrogen, halogen, or C1-C20 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R9 and R10 groups, which are identical to or different from each other, represent halogen, or C1-C20 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, with the priviso that when all R1-R3 groups are methyl, R4 is not 2-(3-methyl-2-buten -1 -yl)-cyclopropan-1 -yl; when R1R2R3Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4 is not benzyl; and when both R9 and R10 are methyl, all R5-R8 groups are hydrogen, and R4 is C1-C3 linear or branched alkyl, then R1-R3 groups are not simultaneously ethyl. 2. The silicon ether compound of the formula (I) as claimed in claim 1, wherein R1-R4 groups, which are identical to or different from each other, represent C1-C-10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R5-R8 groups, which are identical to or different from each other, represent hydrogen, halogen, or C1-C10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R9-R10 groups, which are identical to or different from each other, represent halogen, or C1-C10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl. 3. The silicon ether compound of the formula (I) as claimed in claim 1, wherein R1-R4 groups, which are identical to or different from each other, represent methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, tert-butyl, phenyl or benzyl, R5-R8 groups are hydrogen atom, and R9 and R10 groups are independently C1-C10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl. 4. The silicon ether compound as claimed in claim 1, having a general formula (II): wherein, R1'-R4' groups, which are identical to or different from each other, represent linear or branched C1-C5 alkyl, phenyl or benzyl, with the priviso that when R1'R2'R3,Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4' is not benzyl; and when R4' is C1-C3 linear or branched alkyl, then R1', R2' and R3' are not simultaneously ethyl. 5. The silicon ether compound as claimed in claim 4, wherein R3' and R4' groups are independently methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl. 6. The silicon ether compound as claimed in claim 4, wherein R1' and R2' groups are methyl, and R3' and R4' groups are independently methyl, ethyl, or tert-butyl. 7. The silicon ether compound as claimed in claim 6, wherein R4' group is methyl or ethyl. 8. The silicon ether compound as claimed in claim 1, selected from the group consisting of 2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane; 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane. 9. A method for the preparation of the silicon ether compound as claimed in claim 1, comprising the step of: reacting a compound of the formula (III) (Formula Removed) wherein R4-R10 groups are as defined in claim 1, with a trihydrocarbylsilylating agent which can introduce -S1R1R2R3 group, wherein R1, R2 and R3 groups are as defined in claim 1, in an aprotic inert solvent and, if needed, in the presence of a base, to form corresponding silicon ether compound of the formula (I), wherein equivalent ratio of the compound of formula (III) to the trihydrocarbylsilylating agent is in a range of from 1:1 to 1:1.2. 10. The method as claimed in claim 9, wherein the aprotic inert solvent is selected from the group consisting of dichloromethane, chloroform, benzene, toluene, n-hexane, cyclohexane, petroleum ether, diethyl ether, tetrahydrofuran, tert-butyl methyl ether, N,N-dimethyl formamide, and mixtures thereof. 11. The method as claimed in claim 9, wherein a trihydrocarbylsilyl halide is used as the trihydrocarbylsilylating agent, the reaction of the silylating agent and the compound of the formula (III) is carried out in the presence of a base, and the raw materials are charged at such amounts that molar ratio of the compound of the formula (III) : trihydrocarbylsilyl halide : base is in a range of 1 : 1-1.2: 1-1.2. 12. The method as claimed in claim 11, wherein the base is selected from the group consisting of Na, K, NaOH, KOH, NaH, KH, CaH2 Na2CO3, K2CO3, NH3, Et3N, Me3N, Bu3N, pyridine, imidazole, 4-dimethylaminopyhdine, and mixtures thereof. 13. The method as claimed in claim 9, wherein a hexahydrocarbyl disilazane is used as the silylating agent, and the raw materials are charged at such amounts that molar ratio of the compound of the formula (III) to hexahydrocarbyl disilazane is in a range of 1 : 0.5-0.6. 14. A process comprising polymerizing olefins, with the silicon ether compound as claimed in claim 1 as an external electron donor compound. 15. The process as claimed in claim 14, wherein said process is homopolymerization or copolymerization of propylene.

Full Text

SPECIFICATION
Silicon Ether Compounds and a Method for the Preparation thereof
Technical field
The present invention relates to novel silicon ether compounds, a method for the preparation thereof and use thereof as a component of catalysts for olefins polymerization. In olefins polymerization or copolymerization, in particular, in propylene polymerization or copolymerization, catalyst systems comprising the silicon ether compounds as external electron donor component exhibit good hydrogen response, and can be used to prepare polymer having high isotacticity at high yield.
Background Art
Catalysts for olefins polymerization or copolymerization are well known in literatures. These catalysts typically comprise a transition metal-containing active component, generally comprising magnesium, titanium and halogen as main ingredients; a cocatalyst component, typically organo-aluminium compound; and external electron donor component, typically organo-silicon compound. For stereoelective polymerization of olefins, especially stereoelective polymerization of propylene, if no external electron donor component is used, most of these catalysts give a polymer having lower isotacticity, typically lower than 90%, so that they are not applicable to industrial scale production. Therefore, the addition of external electron donor component is often necessary.
At present, the types of external electron donor compounds have developed from initial benzoates to current organosiloxane. For instance, WO 00/63261 discloses external electron donor compounds useful in olefins polymerization, i.e. silicon compounds having a general formula R11aR12bSi(OR13)c, wherein a and b are zero or integer of from 1 to 2, c is integer of from 1 to 3, and the sum of a+b+c is 4, R11, R12 and R13 are independently C1-C18 hydrocarbyl which optionally contains a heteroatom. The preferred are those silicon compounds in which a is 1, b is 1, c is 2, at least one of R11 and R12 is selected from the group consisting of branched alkyl, alkenyl, alkylene, cycloalkyl and aryl, having from 3 to 10 carbon atoms and containing optionally a heteroatom, and R13 is C1-C10 alkyl, especially methyl, for example, cyclohexylmethyldimethoxysilane. The also preferred are those silicon compounds in which a is 0, c is 3, R12 is branched alkyl or cycloalkyl, containing optionally a heteroatom, and R13 is methyl, for example, cyclohexyltrimethoxysilane and the like.
It is noted that, among the silicon compounds having the general formula R11aR12bSi(OR13)c, those silicon compounds in which c is 1 are generally not deemed as

good external electron donor. In the prior art,
2,2-dihydrocarbyl-1-hydrocarbyloxy-3-(trihydrocarbylsilyloxy)propane compounds have never been used as external electron donor compounds in olefins polymerization. However, the inventors have surprisingly found that, when used as external electron donor in olefins polymerization, especially in propylene polymerization, silicon ether compounds of general formula (I), which will be described in detail hereinbelow, exhibit good properties, for instance, the catalyst systems exhibit good hydrogen response, and can be used to prepare polymer having high isotacticity at high yield.
Description the invention
One object of the present invention is to provide silicon ether compounds having general formula (I)
(Formula Removed)
wherein, R1-R4 groups, which are identical to or different from each other, represent
C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, R5-R10 groups,
which are identical to or different from each other, represent hydrogen, halogen, or
C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R1R10 groups
optionally contain one or more hetero-atoms selected from the group consisting of
nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom for replacing carbon
atom(s), hydrogen atom(s) or the both,
with the priviso that
when all R1-R3 are methyl, R4 is not 2-(3-methyl-2-buten-1-yl)-cyclopropan-1-yl;
when R-1R2R3Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4 is
not benzyl;
when both R9 and R10 are hydrogen, R5-R8 groups are each methyl or hydrogen, and R4
is C1-C4 linear or branched alkyl, then R1-R3 are not simultaneously methyl or ethyl; and
when both R9 and RIO are methyl, all R5-R8 are hydrogen, and R4 is C1-C3 linear or
branched alkyl, then R1-R3 are not simultaneously ethyl.
In an embodiment of the invention, in the silicon ether compounds having the general formula (I), R1-R4 groups, which are identical to or different from each other,

represent C1-C10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R5-R10 groups, which are identical to or different from each other, represent hydrogen, halogen, or CrCio linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl.
In another embodiment of the invention, in the silicon ether compounds having the general formula (I), R1-R4 groups, which are identical to or different from each other, represent methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, tert-butyl, phenyl or benzyl, R5-R8 groups are hydrogen atom, and R9 and RIO groups are independently CrCio linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl.
In still another embodiment of the invention, the silicon ether compounds according to the invention have a general formula (II)
(Formula Removed)

wherein, R1'-R4' groups, which are identical to or different from each other, represent
linear or branched C1-C5 alkyl, phenyl or benzyl,
with the priviso that
when R1R2'R3'Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4' is
not benzyl; and
when R4' is C1-C3 linear or branched alkyl, R1R21 and R3' are not simultaneously ethyl.
Preferably, in the above general formula (II), R3' and R4' groups are independently methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl.
More preferably, in the above general formula (II), R1and R2' groups are methyl, and R3' and R4' groups are independently methyl, ethyl, or tert-butyl. Most preferably, R4' group is methyl or ethyl.
Examples of the silicon ether compounds of formula (I) include, but are not limited to,
2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(triphenylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane;

2,2-dimethyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(triethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(triphenylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(n-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(dimethylbenzylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(dimethylphenethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(dimethyltolylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(triethylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(triphenylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(n-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(dimethylbenzylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(dimethylphenethylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-dimethyl-1-propoxy-3-[(dimethyltolylsilyl)oxy]propane;
2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(triphenylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;

2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(triphenylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(triethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(triphenylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(n-butyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(dimethylbenzylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(dimethylphenethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-di-iso-butyl-1-ethoxy-3-[(dimethyltolylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(triethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(triphenylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(n-butyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(dimethylbenzylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(dimethylphenethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-di-iso-butyl-1-propoxy-3-[(dimethyltolylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(triethylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(triphenylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(dimethylpropylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;

2,2-dibenzyl-1-methoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dibenzyl-1-methoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(triethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dibenzyl-1-ethoxy-3-[(dimethyltolylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(trimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(triethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(triphenylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(ethyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylpropylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(tert-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(n-butyldimethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylbenzylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylphenethylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethylphenylsilyl)oxy]propane; 2,2-dibenzyl-1-propoxy-3-[(dimethyltolylsilyl)oxy]propane;
Examples of a preferred group of the the silicon ether compounds of formula (I) include:
2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;

2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane; 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane.
Many methods can be used to prepare the silicon ether compounds of the above formula (I), and this constitutes another aspect of the invention. For instance, a compound of the formula (III)
(Formula Removed)

wherein R4 group represents C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, R5-R10 groups, which are identical to or different from each other, represent hydrogen, halogen, or C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R4-R10 groups optionally contain one or more hetero-atoms selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom for replacing carbon atom(s), hydrogen atom(s) or the both, can react with a trihydrocarbylsilylating agent which can introduce -SiR1R2R3 group, wherein R1-R3 groups, which are identical to or different from each other, represent C1-C2o linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R1-R3 groups optionally contain one or more hetero-atoms selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom for replacing carbon atom(s), hydrogen atom(s) or the both,
in an aprotic inert solvent and, if needed, in the presence of a base, to form corresponding silicon ether compound of the formula (I), wherein equivalent ratio of the compound of formula (III) to the trihydrocarbylsilylating agent is in a range of from 1:1 to 1:1.2.
According to an embodiment of the invention, in the above preparation method, a trihydrocarbylsilyl halide is used as the trihydrocarbylsilylating agent, the reaction of the silylating agent and the compound of formula (III) is carried out in the presence of a base, and the raw materials are charged at such amounts that molar ratio of the compound of formula (III) : trihydrocarbylsilyl halide : base is in a range of 1 : 1-1.2 : 1-1.2. The base used can be selected from the group consisting of inorganic bases and organic bases, such as Na, K, NaOH, KOH, NaH, KH, CaH2, Na2CO3, K2CO3, NH3, Et3N, Me3N, Bu3N,

pyridine, imidazole, 4-dimethylaminopyridine, and mixtures thereof. The preferred are organic bases, such as Et3N, imidazole, and 4-dimethylaminopyridine.
According to another embodiment of the invention, in the above preparation method, a hexahydrocarbyl disilazane is used as the silylating agent, and the raw materials are charged at such amounts that molar ratio of the compound of formula (III) to hexahydrocarbyl disilazane is in a range of 1 : 0.5-0.6.
The aprotic inert solvent can be selected from the group consisting of amides, halohydrocarbons, hydrocarbons, and ethers, such as dichloromethane, chloroform, benzene, toluene, n-hexane, cyclohexane, petroleum ether, diethyl ether, tetrahydrofuran, tert-butyl methyl ether, N,N-dimethyl formamide, and mixtures thereof, with dichloromethane being preferred.
The trihydrocarbylsilylating agent can be selected from the group consisting of trihydrocarbylsilyl halides and hexahydrocarbyl disilazanes, such as trimethylsilyl chloride, ethyldimethylsilyl chloride, tert-butyldimethylsilyl chloride, triethylsilyl chloride, dimethylphenylsilyl chloride, n-butyldimethylsilyl chloride, benzyldimethylsilyl chloride, and hexamethyl disilazane.
The preparation reaction is typically carried out at a temperature of from -20°C to 100°C, preferably at a lower temperature, more preferably at a temperature of from -5°C to room temperature.
The compounds of the formula (III) are known in the art or can be synthesized through a method known per se in the art. For instance, said compounds can be obtained through mono-etherization of propandiols with haloalkanes. Specifically, a method can comprise the step of mono-etherizing a propandiol compound with a haloalkane in the presence of a solvent and in the presence of a base, to form a 3-hydrocarbyloxy-1 -propanol compound,
wherein, the solvent used can be selected from the group consisting of tetrahydrofuran, dimethyl sulfoxide, diethyl ether, N,N-dimethyl formamide; aliphatic hydrocarbons, such as, pentane, hexane, and heptane; and aromatic hydrocarbons, such as, benzene, and toluene;
wherein, the base used can be hydrides, hydroxides, or carbonates of alkali metals or alkali earth metals, such as, NaH, KH, CaH2, NaOH, KOH, Ca(OH)2, Na2CO3, K2CO3, or the like. Among these bases, NaH and NaOH are preferable. Furthermore, the base is preferably added gradually into the reaction mixture after the addition of the diol, haloalkane and solvent;
and wherein, molar ratio of the base to the propandiols is in a range of from 0.5:1 to 1.5:1, preferably from 0.8:1 to 1.2:1, and molar ratio of the haloalkane to the propandiols is in a range of from 1:1 to 10:1, preferably from 1:1 to 2.5:1.
The present invention further relates to a process for olefins polymerization, wherein

, a silicon ether compound according to the invention is used as external electron donor compound. In a preferable embodiment, said process is homopolymerization or copolymerization of propylene. Processes for the polymerization of olefins and application mode and amount of external electron donor compounds therein are well known in the art.
Examples
The following examples further describe the invention, but do not make limitation to the invention in any way.
Testing methods:
1. Isotacticity of polymer: measured by heptane extraction method (heptane boiling
extraction for 6 hours) carried out according to the following procedure: 2g of dried
polymer sample is extracted with boiling heptane in an extractor for 6 hours, then the
residual substance is dried to constant weight, and ratio of the weight of the residual
polymer (g) to 2 is taken as isotacticity.
2. Melt index of polymer: measured according to ASTM D1238-99.
Some intermediates used in the Examples were prepared as follows. Preparation of 2,2-dimethyl-3-methoxy-1-propanol
To a reactor were added 34.4 g of 2,2-dimethyl-1,3-propandiol and 150 ml of dried THF, then 11.3 g of NaH was slowly added with stirring. After the addition, the reaction mixture was refluxed for one hour. Next, a solution of 51.1 g of methyl iodide in 300 ml of THF was added dropwise, and upon completing the addition, the reaction was allowed to continue for further 6 hours. The THF was removed by distillation. The remainder was diluted with 50 ml of water, and extracted thrice with 3 X 50 ml of diethyl ether. The combined diethyl ether extract was dried over anhydrous magnesium sulfate. After filtering out the magnesium sulfate, diethyl ether was evaporated, and the remainder was distilled under vacuum. 27.7g of colorless and clear liquid 2,2-dimethyl-3-methoxy-1-propanol (yield 71%) was collected as 86-88 °C/71mmHg fraction.
1H-NMR(CDCI3/TMS, 300MHz) 5 (ppm): 0.91 (s, 6 H, 2CH3), 2.77 (t, 1H, OH), 3.25(s, 2H, -CH2O-), 3.34(s, 3 H, OCH3), 3.44(d, 2H, -CH2O-).
Preparation of 2,2-dimethyl-3-ethoxy-1-propanol
Colorless and clear 2,2-dimethyl-3-ethoxy-1-propanol as 83 °C/37 mmHg fraction was prepared from 2,2-dimethyl-1,3-propandiol and ethyl iodide through the same procedure as described in the preparation of 2,2-dimethyl-3-methoxy-1-propanol.

1H NMR (CDCI3/TMS, 300MHz) 8 (ppm): 0.92 (s, 6H, -CH3), 1.19 (t, 3H, -CH3), 2.98 (t, 1H, -OH), 3.29 (s, 2H, -CH2O-), 3.44-3.51 (m, 4H, -OCHjpCHs, -CH2O-).
Preparation of 2,2-dibenzyl-3-methoxy-1-propanol
2,2-Dibenzyl-3-methoxy-1-propanol was prepared from 2,2-dibenzyl-1,3-propandiol and methyl iodide through the same procedure as described above.
1H-NMR(CDCI3/TMS) δ (ppm): 2.34(t, 1H, OH), 2.75(s, 4H, CH2Ph), 3.13(s, 2H, CH2O), 3.33(s, 3H, OCH3), 3.44(d, 2H, CH2O), 7.20(m, 6H, 6ArH), 7.28(m, 4H, 4ArH).
Preparation of 2,2-di-iso-butyl-3-methoxy-1-propanol
2,2-Di-iso-butyl-3-methoxy-1-propanol was prepared from
2,2-di-iso-butyl-1,3-propandiol and methyl iodide through the same procedure as described above.
1H-NMR(CDCI3/TMS) δ (ppm): 0.92(t, 12H, 4CH3), 1.26(d, 4H, 2CH2), 1.69(m, 2H, 2CH), 2.84(t, 1H, OH), 3.31 (2s, 5H, CH3O, CH2O), 3.52(d, 2H, CH2O).
Preparation of 2,2-di-n-butyl-3-methoxy-1-propanol
2,2-Di-n-butyl-3-methoxy-1-propanol was prepared from
2,2-di-n-butyl-1,3-propandiol and methyl iodide through the same procedure as described above.
1H-NMR(CDCI3/TMS) δ (ppm): 0.90(t, 6H, 2CH3), 1.20(t, 4H, 2CH2), 1.26(m, 8H, 4CH2), 2.75(t, 1H, OH), 3.29(s, 2H, CH2O), 3.32(s, 3H, OCH3), 3.48(d, 2H, CH2O).
Preparation of 2,2-di-n-propyl-3-methoxy-1-propanol
2,2-Di-n-propyl-3-methoxy-1-propanol was prepared from
2,2-di-n-propyl-1,3-propandiol and methyl iodide through the same procedure as described above.
1H-NMR(CDCI3/TMS) δ (ppm): 0.89(t, 6H, 2CH3), 1.24(m, 8H, 4CH2), 2.70(s, 1H, OH), 3.28(s, 2H, CH2O), 3.32(s, 3H, OCH3), 3.48(s, 2H, CH2O).
Example 1: Preparation of 2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane
1g of 2,2-dimethyl-3-methoxy-1-propanol was dissolved in 20 ml of dichloromethane. The resultant solution was cooled in ice-water bath to below 5°C, and 1.65 ml of triethyl amine was added thereto. After stirring the mixture for 5 minutes, 1 .29 ml of trimethylsilyl chloride was added drop-wise to the reaction mixture, and the mixture was stirred in ice-water bath for further 2 hours, and at room temperature for further 1 hour. The reaction mixture was washed with water, and the organic layer was separated and then dried over anhydrous sodium sulfate. After filtration, the filtrate was concentrated to give

1.33g of concentrate. The crude product was purified by column chromatography using petroleum ether as eluent, to give colorless pure compound.
1H-NMR(CDCI3/TMS) δ (ppm): 0.09(s, 9H, 3CH3), 0.85(s, 6H, 2CH3), 3.11 (s, 2H, -CH2O-), 3.30(s, 2H, -CH2O-), 3.32(s, 3H, CH3O-).
Example 2: Preparation of 2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]-propane
According to the procedure as described in Example 1, 2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-methoxy-1-propanol and reagent ethyldimethylsilyl chloride.
1H-NMR(CDCI3/TMS) δ (ppm): 0.06(s, 6H, 2CH3), 0.54(q, 2H, CH2), 0.85(s, 6H, 2CH3), 0.95(t, 3H, CH3), 3.11(s, 2H, CH2O), 3.31(2s, 5H, CH3O, CH2O).
Example 3: Preparation of 2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy] -propane
1g of 2,2-dimethyl-3-methoxy-1-propanol was admixed with 10 ml of N,N-dimethyl formamide, and 0.29 g of imidazole was added thereto. The mixture was cooled in ice-water bath, and 1.65 ml of triethyl amine was added thereto. After stirring for 5 minutes, 1.65 g of tert-butyldimethylsilyl chloride in 10 ml of N,N-dimethyl formamide was slowly added to the reaction mixture, and the mixture was stirred in ice-water bath for further 4 hours. The reaction mixture was diluted with 10 ml of water, and extracted twice with 20 ml of dichloromethane for each time. The combined dichloromethane extract was dried over anhydrous sodium sulfate. After filtration, the filtrate was evaporated to dryness to give 1.78g of concentrate of 2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]-propane. The crude product was purified by column chromatography using petroleum ether as eluent, to give colorless pure compound.
1H-NMR(CDCI3/TMS) δ (ppm): 0.01 (s, 6H, 2CH3), 0.85(s, 6H, 2CH3), 0.88(s, 9H, 3CH3), 3.10(s, 2H, CH20), 3.30 (s, 5H, CH2O, OCH3).
Example 4: Preparation of 2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy] -propane
According to the procedure as described in Example 1, 2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-methoxy-1-propanol and reagent dimethylphenylsilyl chloride.
1H-NMR(CDCI3/TMS) 5 (ppm): 0.35(s, 6H, 2CH3), 0.87(s, 6H, 2CH3), 3.13(s, 2H, CH2O), 3.30(s, 3H, OCH3), 3.37 (s, 2H, CH2O), 7.38(m, 3H, 3ArH), 7.58(m, 2H, 2ArH).

Example 5: Preparation of 2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane
According to the procedure as described in Example 1, 2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-ethoxy-1-propanol and reagent trimethylsilyl chloride.
1H-NMR(CDCI3/TMS) 6 (ppm): 0.07(s, 9H, 3CH3), 0.83(s, 6H, 2CH3), 1.16(t, 3H, CH3), 3.12(8, 2H, CH2O), 3.30(s, 2H, CH2O), 3.43(q, 2H, CH2O).
Example 6: Preparation of 2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy] -propane
According to the procedure as described in Example 3, 2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane was prepared from intermediate 2,2-dimethyl-3-ethoxy-1-propanol and reagent tert-butyldimethylsilyl chloride.
1H-NMR(CDCI3/TMS) 5 (ppm): 0.01(s, 6H, 2CH3), 0.83(s, 6H, 2CH3), 0.88(s, 9H, 3CH3), 1.15(t, 3H, CH3), 3.13(s, 2H, CH2O), 3.31(s, 2H, CH2O), 3.43(q, 2H, CH2O).
Example 7: Preparation of 2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane
According to the procedure as described in Example 1, 2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-dibenzyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride.
1H-NMR(CDCl3/TMS) δ (ppm): 0.17(s, 9H, 3CH3), 2.72-2.82(dd, 4H, 2CH2), 2.81(s, 2H, CH2O), 3.10(8, 2H, CH2O), 3.46(s, 3H, OCH3), 7.22(m, 6H, 6ArH), 7.29(q, 4H, 4ArH).
Example 8: Preparation of 2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy] -propane
4.16Mmol of 2,2-dibenzyl-3-methoxy-1-propanol was dissolved in 10 ml of N,N-dimethyl formamide, and 0.14 g (2.08mmol) of imidazole was added thereto. The solution was cooled in ice-water bath to below 5 °C, and 0.87 ml (6.24mmol) of triethyl amine was added thereto. After stirring for 5 minutes, 0.88 g (5.82mmol) of tert-butyldimethylsilyl chloride in 10 ml of N,N-dimethyl formamide was slowly added to the reaction mixture, and the mixture was stirred in ice-water bath for further 2 hours, and at room temperature for further 1 hour. The reaction mixture was diluted with 10 ml of water, and extracted using 30 ml of dichloromethane. The organic layer was separated, wished twice with 20 ml of water, and dried over anhydrous sodium sulfate. After filtration, the filtrate was concentrated to give 2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane.

1H-NMR(CDCI3/TMS) δ (ppm): 0.07(s, 6H, 2CH3), 1.01(s, 9H, 3CH3), 2.68-2.79(dd, 4H, 2CH2), 2.83(s, 2H, CH2O), 3.18(s, 2H, CH2O), 3.31(s, 3H, OCH3), 7.25(m, 10H, 10ArH).
Example 9: Preparation of 2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy] -propane
According to the procedure as described in Example 1, 2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-iso-butyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride.
1H-NMR(CDCI3/TMS) 5 (ppm): 0.06(s, 9H, 3CH3), 0.89(d, 6H, 2CH3), 0.90(d, 6H, 2CH3), 1.16(d, 2H, CH2), 1.18(d, 2H, CH2), 1.68(m, 2H, 2CH), 3.12(s, 2H, CH2O), 3.26(s, 3H, OCH3), 3.47(s, 2H, CH2O).
Example 10: Preparation of 2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane
According to the procedure as described in Example 1, 2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-butyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride.
1H-NMR(CDCI3/TMS) δ(ppm): 0.07(s, 9H, 3CH3), 0.89(t, 6H, 2CH3), 1.17(m, 8H, 4CH2), 1.26(m, 4H, 2CH2), 3.11 (s, 2H, CH2O), 3.28(s, 3H, OCH3), 3.31 (s, 2H, CH2O).
Example 11: Preparation of 2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy] -propane
According to the procedure as described in Example 8, 2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-butyl-3-methoxy-1-propanol and reagent tert-butyldimethylsilyl chloride.
1H-NMR(CDCI3/TMS) δ (ppm): 0.02(s, 6H, 2CH3), 0.88(s, 9H, 3CH3), 0.91 (t, 6H, 2CH3), 1.17(m, 8H, 4CH2), 1.27(m, 4H, 2CH2), 3.12(s, 2H, CH2O), 3.30(s, 3H, OCH3), 3.34(8, 2H, CH2O).
Example 12: Preparation of 2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane
According to the procedure as described in Example 1, 2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-butyl-3-methoxy-1-propanol and reagent triethylsilyl chloride.
1H-NMR(CDCI3/TMS) δ (ppm): 0.57(q, 6H, 3CH2), 0.91 (t, 6H, 2CH3), 0.96(t, 9H, 3CH3), 1.20(m, 8H, 4CH2), 1.27(m, 4H, 2CH2), 3.14(s, 2H, CH2O), 3.30(s, 3H, OCH3), 3.36(s, 2H, CH2O).

Example 13: Preparation of 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy] -propane
According to the procedure as described in Example 1, 2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane was prepared from intermediate 2,2-di-n-propyl-3-methoxy-1-propanol and reagent trimethylsilyl chloride.
1H-NMR(CDCI3/TMS) δ (ppm): 0.07(s, 9H, 3CH3), 0.88(t, 6H, 2CH3), 1.17(m, 8H, 4CH2), 3.11(s, 2H, CH2O), 3.28(s, 3H, OCH3), 3.32(s, 2H, CH2O).
Examples 14-21 and Comparative Example 1
Preparation of the solid titanium-containing catalyst component
To a reactor that had been completely purged with highly pure N2 were added successively 4.8g of magnesium dichloride, 95ml of toluene, 4ml of epichlorohydrin, and 12.5ml of tributyl phosphate. With stirring, the mixture was heated to 50°C and held at that temperature for 2.5 hours, thereby the solid was completely dissolved. Then 1.4g of phthalic anhydride was added thereto and the reaction mixture was held at that temperature with stirring for further one hour. The reaction mixture was cooled to below -25°C and 56ml of TiCI4 was added dropwise thereto over one hour, then the temperature was increased slowly to 80°C. Solid precipitated gradually during the heating. To the reaction mixture was added 6 mmol of di-n-butyl phthalate, and the reaction was held at that temperature with stirring for further one hour. After filtering, 70ml of toluene was used to wash the filter cake. The washing procedure was repeated twice. The resulting solid precipitates were treated with 60ml of toluene and 40ml of TiCI4 at 100°C for 2 hours, and after removing the mother liquid, the residue was treated with 60ml of toluene and 40ml of TiCI4 at 100°C for 2 hours again. After removing the mother liquid, the residue was washed with 60ml of toluene under boiling state for three times, washed with 60ml of hexane under boiling state for two times, washed with 60ml of hexane at room temperature for two times, to yield the solid titanium-containing catalyst component.
Propylene polymerization experiments
To a 5L stainless steel autoclave, in which atmosphere had been replaced with propylene gas completely, were added 2.5mmol of AIEt3, 0.1 mmol of silicon ether compounds prepared in the above Examples or known cyclohexylmethyldimethoxysilane, 10mg of the solid titanium-containing catalyst component prepared above, and 1L of hydrogen, followed by introduction of 2.3L of liquid propylene. The reactor was heated to 70°C, and held at that temperature for 1 hour. After the temperature was reduced and the pressure was relieved, PP resin powder was removed. Polymerization results were summarized in Table 1 .

Table 1
(Table Removed)

Example 22 and Comparative Example 2
Propylene polymerization experiments were carried out according to the same polymerization procedure as described above, except for that the amount of hydrogen gas was changed to 4L. Polymerization results were summarized in Table 2. For comparison, the results obtained in Example 15 as well as in Comparative Example 1 were also shown in Table 2.
Table 2
(Table Removed)

From the results shown in the Tables 1 and 2, it can be seen that, when the silicon ether compounds according to the present invention are used as external electron donor component of a catalyst for olefin polymerization, polymerization activity of the catalyst and isotacticity of the polymerization product obtained are satisfied. Furthermore, at the
same hydrogen gas level, the polymerization using the silicon ether compounds according to the invention will give polymers having higher melt index than the polymerization using the silane compound commonly used in the art, and as the level of hydrogen gas increases, melt index increases more notably. These results sufficiently demonstrate that, when the silicon ether compounds according to the present invention are used as external electron donor component of a catalyst for olefin polymerization, the catalyst will exhibit relatively good hydrogen response, and this performance facilitates the development of various grades of polymers.
The invention aims to develop novel external electron donor compounds useful in
propylene polymerization. It is generally accepted that
trihydrocarby-hydrocarbyloxy-silanes are not good external electron donors for olefin polymerization, and are not suitable for enhancing isotacticity of the polyolefin product. However, the inventors have found that, when using preferred silicon ether compounds of the invention substituting for cyclohexylmethyldimethoxysilane known in the art as external electron donor in olefin polymerization, a current catalyst remains its high catalytic activity, and exhibits good hydrogen response, and the prepared polypropylene has high isotacticity. These results prove that the silicon ether compounds of the invention are a class of highly effective external electron donor compounds.
Although the present invention has been described in connection with embodiments and examples, further modifications and alternative embodiments of various aspects of the invention will be apparent to those skilled in the art in view of this description. Accordingly, this description is to be constructed as illustrative only and is for the purpose of teaching the general manner of carrying out the invention.

We claim:
1. A silicon ether compound having a general formula (I):
(Formula Removed)
wherein, R1-R4 groups, which are identical to or different from each other, represent C1-C20 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, R5-R8 groups, which are identical to or different from each other, represent hydrogen, halogen, or C1-C20 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl, and R9 and R10 groups, which are identical to or different from each other, represent halogen, or C1-C20 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl,
with the priviso that
when all R1-R3 groups are methyl, R4 is not 2-(3-methyl-2-buten -1 -yl)-cyclopropan-1 -yl;
when R1R2R3Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4 is not benzyl; and
when both R9 and R10 are methyl, all R5-R8 groups are hydrogen, and R4 is C1-C3 linear or branched alkyl, then R1-R3 groups are not simultaneously ethyl.
2. The silicon ether compound of the formula (I) as claimed in claim 1,
wherein R1-R4 groups, which are identical to or different from each other,
represent C1-C-10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl,
and R5-R8 groups, which are identical to or different from each other, represent
hydrogen, halogen, or C1-C10 linear or branched, aliphatic, alicyclic or aromatic
hydrocarbyl, and R9-R10 groups, which are identical to or different from each
other, represent halogen, or C1-C10 linear or branched, aliphatic, alicyclic or
aromatic hydrocarbyl.

3. The silicon ether compound of the formula (I) as claimed in claim 1, wherein R1-R4 groups, which are identical to or different from each other, represent methyl, ethyl, n-propyl, iso-propyl, n-butyl, isobutyl, tert-butyl, phenyl or benzyl, R5-R8 groups are hydrogen atom, and R9 and R10 groups are independently C1-C10 linear or branched, aliphatic, alicyclic or aromatic hydrocarbyl.
4. The silicon ether compound as claimed in claim 1, having a general formula (II):
wherein, R1'-R4' groups, which are identical to or different from each other, represent linear or branched C1-C5 alkyl, phenyl or benzyl,
with the priviso that
when R1'R2'R3,Si group represents tert-butyldimethylsilyl or tert-butyldiphenylsilyl, R4' is not benzyl; and
when R4' is C1-C3 linear or branched alkyl, then R1', R2' and R3' are not simultaneously ethyl.
5. The silicon ether compound as claimed in claim 4, wherein R3' and R4' groups are independently methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl.
6. The silicon ether compound as claimed in claim 4, wherein R1' and R2' groups are methyl, and R3' and R4' groups are independently methyl, ethyl, or tert-butyl.
7. The silicon ether compound as claimed in claim 6, wherein R4' group is methyl or ethyl.

8. The silicon ether compound as claimed in claim 1, selected from the
group consisting of
2,2-dimethyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-methoxy-3-[(dimethylphenylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(ethyldimethylsilyl)oxy]propane;
2,2-dimethyl-1-ethoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-dibenzyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-di-iso-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(trimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(tert-butyldimethylsilyl)oxy]propane;
2,2-di-n-butyl-1-methoxy-3-[(triethylsilyl)oxy]propane;
2,2-di-n-propyl-1-methoxy-3-[(trimethylsilyl)oxy]propane.
9. A method for the preparation of the silicon ether compound as claimed
in claim 1, comprising the step of:
reacting a compound of the formula (III)
(Formula Removed)
wherein R4-R10 groups are as defined in claim 1,
with a trihydrocarbylsilylating agent which can introduce -S1R1R2R3 group,
wherein R1, R2 and R3 groups are as defined in claim 1,
in an aprotic inert solvent and, if needed, in the presence of a base, to form
corresponding silicon ether compound of the formula (I), wherein equivalent
ratio of the compound of formula (III) to the trihydrocarbylsilylating agent is in a
range of from 1:1 to 1:1.2.

10. The method as claimed in claim 9, wherein the aprotic inert solvent is selected from the group consisting of dichloromethane, chloroform, benzene, toluene, n-hexane, cyclohexane, petroleum ether, diethyl ether, tetrahydrofuran, tert-butyl methyl ether, N,N-dimethyl formamide, and mixtures thereof.
11. The method as claimed in claim 9, wherein a trihydrocarbylsilyl halide is used as the trihydrocarbylsilylating agent, the reaction of the silylating agent and the compound of the formula (III) is carried out in the presence of a base, and the raw materials are charged at such amounts that molar ratio of the compound of the formula (III) : trihydrocarbylsilyl halide : base is in a range of 1 : 1-1.2: 1-1.2.
12. The method as claimed in claim 11, wherein the base is selected from the group consisting of Na, K, NaOH, KOH, NaH, KH, CaH2 Na2CO3, K2CO3, NH3, Et3N, Me3N, Bu3N, pyridine, imidazole, 4-dimethylaminopyhdine, and mixtures thereof.

13. The method as claimed in claim 9, wherein a hexahydrocarbyl disilazane is used as the silylating agent, and the raw materials are charged at such amounts that molar ratio of the compound of the formula (III) to hexahydrocarbyl disilazane is in a range of 1 : 0.5-0.6.
14. A process comprising polymerizing olefins, with the silicon ether compound as claimed in claim 1 as an external electron donor compound.
15. The process as claimed in claim 14, wherein said process is homopolymerization or copolymerization of propylene.

Documents:

6375-delnp-2007-abstract.pdf

6375-DELNP-2007-Claims-(13-06-2012).pdf

6375-delnp-2007-claims.pdf

6375-DELNP-2007-Correspondence Others-(13-06-2012).pdf

6375-delnp-2007-correspondence-others.pdf

6375-delnp-2007-description (complete).pdf

6375-delnp-2007-form-1.pdf

6375-delnp-2007-form-2.pdf

6375-DELNP-2007-Form-3-(13-06-2012).pdf

6375-delnp-2007-form-3.pdf

6375-delnp-2007-form-5.pdf

6375-delnp-2007-pct-210.pdf

6375-delnp-2007-pct-306.pdf

6375-delnp-2007-pct-308.pdf

6375-DELNP-2007-Petition-137-(13-06-2012).pdf

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Patent Number

254081

Indian Patent Application Number

6375/DELNP/2007

PG Journal Number

38/2012

Publication Date

21-Sep-2012

Grant Date

18-Sep-2012

Date of Filing

16-Aug-2007

Name of Patentee

BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

Applicant Address

NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA

Inventors:

#	Inventor's Name	Inventor's Address
1	XIE, LUNJIA	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA.
2	ZHAO, SIYUAN	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA
3	SUN,ZHUFANG	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA
4	LI, TRIANYI	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA
5	ZHANG, MINGSEN	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA
6	GAO, MINGZHI	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA
7	MA,JING	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA
8	LIU, HAITAO	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA
9	WU,CHANGJIANG	NO.14, BEISANHUAN EAST ROAD, CHAOYANG DISTRICT, BEIJING 100013, CHINA

PCT International Classification Number

C07F 7/18

PCT International Application Number

PCT/CN2005/000196

PCT International Filing date

2005-02-17

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1			NA