Title of Invention

SHELL-AND-TUBE HEAT EXCHANGER WITH WEAR-RESISTANT TUBE PLATE LINING

Abstract

The invention relates to a shell-and-tube heat exchanger which contains a wear-resistant tube plate lining. In spite of short exposure periods, cracking gas flowing out of the cracking oven of thermal cracking equipment at high speeds contains coking particles that impact the tube plate on the gas inlet side of the shell-and-tube heat exchanger in a highly erosive manner. It would be highly desirable to be able to apply a metallic lining to the tube plate and the inlet region of the cooling tubes which is extremely resistant to high-temperature corrosion. It is proposed to develop a shell-and-tube heat exchanger which includes a wear-resistant tube plate lining for application in thermal cracking equipment which contains cooling tubes (1) through which the gas to be cooled is circulated, each tube being secured by a tube plate at both ends of the tube and enclosed in a casing through which a coolant material is also circulated. (2) The surface of the tube plate on the gas inlet side which is impacted by gas as it enters the shell-and-tube heat exchanger should be faced, at least partially, by a protective layer which is created by aligning individual sleeves of a heat-resistant metallic material side-to-side and end-to-end at the outer edges and inserting them into the tube ends

Full Text

FORM 2 THE PATENT ACT 1970 (39 of 1970) & The Patents Rules, 2003 COMPLETE SPECIFICATION (See Section 10, and rule 13) 1. TITLE OF INVENTION SHELL-AND-TUBE HEAT EXCHANGER WITH WEAR- RESISTANT TUBE PLATE LINING APPLICANT(S) a) Name : b) Nationality : c) Address : RUHR OEL GMBH GERMAN Company JOHANNASTRASSE 2-8 458 99 GELSENKIRCHEN GERMANY 3. PREAMBLE TO THE DESCRIPTION The following specification particularly describes the invention and the manner in which it is to be performed : - The invention pertains to a shell-and-tube heat exchanger (THE) which contains a wear-resistant tube plate lining for application in thermal cracking equipment. Shell-and-tube heat exchangers of this type are used, for example, in ethylene equipment to produce ethylene through thermal cracking downstream from the transfer line of a cracking furnace and are referred to as quench coolers (transfer line exchangers, or TLE's). Quench coolers must conform to unusually high standards of construction and material characteristics. The hot reaction mixture discharged from a cracking furnace after pyrolysis of hydrocarbon materials such as naphtha, LPG, ethane, or even hydrocracking residue (unconverted oil, waxy), which can reach temperatures of approximately 850° C, must be cooled quickly in the quench coolers in order to avoid undesirable side reactions. The quench cooler, or THE, functions as a waste heat boiler in which high steam pressure can be created through evaporation of feed water introduced to the casing side. Coking retardation occurs in cracking furnaces during this process, which must be removed at specific intervals (60-80 days) through oxidation with air. In order to remove the coking, the furnace is heated to minimal operating levels and a mixture of air and steam is introduced into the tubes of the cracking furnace. The carbon residues are burned off with this mixture. Particles of coking are loosened at the same time, and they are carried with the gasses along the cracked gas pathways through the quench cooler and into the coking removal conduits. The cracked gas or coking removal gas, which is discharged at high velocity from the cracking furnace, generally crosses a transfer line into an axial gas entry chamber and then, from below, into the quench cooler, where it collides against the lower tube plates before it is fed into the remainder of the process after its journey through the heat exchanging tubes of the quench cooler. In spite of short exposure periods, the cracking gas contains coking particles which become highly corrosive at the high velocities reached by the cracking gas. In order to cool the hot reaction mixture created in the cracking furnace quickly, the distance between cracking furnace and the cooling tubes must be traversed as quickly as possible. This necessitates that the gas entry chamber design be compressed, which would normally broaden out in diameter of the transfer line leading to the cooler, with the result that the stream of gas containing coking particulate is concentrated on the middle region of the tube plate and the cooling tubes, which are affected particularly severely. The weight-bearing wall elements are weakened, which creates the necessity of significant maintenance costs, and maintenance downtimes result in production downtimes. Various solutions have been proposed to this and similar problems. These are based on using of ceramic, fireproof materials as linings, structural members, or emulsions: EP-A-0 567 674 introduces heat exchangers for the cooling of synthetic gas created in coal gasification equipment. In this application, the tube plate on the gas inlet side is covered by cuboid-based nozzles which are positioned adjacent to and abutting one another on the outer edges. Each of these nozzles has a conical opening which narrows to a section of tubing which in turn is inserted into a heat exchanger tube. This solution offers no gastight closure between the individual cuboid-based elements. This would lead to buildup of coking residue in the empty spaces within the quench coolers of an olefin processor and destroy the materials. In addition, the ends of the nozzles which are used would form a tearing edge within the tube which, considering the high flow velocities within the quench coolers, would result in heavy turbulences. This would result in additional erosion. In DE-C-44 04068 a ceramic lining is revealed, which is comprised of fireproof molded elements. These can in some instances be hexagonal in shape and contain perforations through which pins or hooks can be inserted which are welded to the underside of the tube plate. The molded element can be attached to the tube plate in this fashion. This construction does not accomplish the goal of having a seamless emulsion or lamination. In addition, it is widely accepted that a cooling tube installed within a reactor must be equipped with a fireproof lining which is resistant to erosion (see US 4 124 068), in order to reduce the risk of tube failure and the resulting penetration of cooling water into the surrounding reaction mixture at elevated temperatures. The suggestion is made in DE 195 34 823 A 1 that tube plates on the gas inlet side be coated or lined with a chemically hardened, erosion-resistant, fireproof product. This coating should initially be formed from a castable substance, applied in a pliable format, and finally fired to achieve its final format as a fireproof mass. What these applications have in common is that they all combine ceramic —in other words, non-metallic — materials with the metallic apparatus material, principally steel. Practical experience has taught that combining ceramic and metallic components results in increased time, effort, and expense during manufacture, assembly, and repair and often creates problems because of the differences in material characteristics such as thermal expansion coefficients and varying levels of elasticity (brittle vs. ductile). In addition to these issues, inserted ceramic nozzles also have the problem of turbulence and the accompanying particular stresses to the materials at the rear end of the nozzle (from the perspective of flow direction) associated with the tearing edge located there. Contrary to the design laid out in DE 195 34 823, installing a lining consisting of a fireproof mass positioned solely in the focal area in the center of the tube plate has been shown to be impractical because the resulting inconsistent surface of the tube plate, in conjunction with the variations in material characteristics, results in the occurrence of particular problems in the transition range, i.e., at the outer edge of the fireproof form, possibly through chipping or spalling of the form or through particularly heavy erosion caused by turbulence at the edge. It should also be noted that installation of a lining made of a fireproof material only protects the tube plate as such. There is a distinct advantage to providing protection for at least the front part of each cooling tube (viewed from the perspective of flow direction). This can only be accomplished by applying a protective nozzle or sleeve. The problem of a significantly stronger flow rate and stress on the focal area as compared to the peripheral areas was also investigated. One proposed solution incorporated cone-shaped fittings (see US-PS 35 52 487). Another proposed installing diffuser-type diversion fixtures which could be free-standing within the entry chamber (see DE-PS 21 60 372). For the purposes of equalizing the flow through the entry chamber and also protecting the tube plate from erosion, an additional suggestion has been made that the THE be fitted out with inserted elements made of small rods bent into the shape of rings. The rings would be aligned along the surface of a cone, and the point of the cone would be directed toward the gas inlet (see EP 037 089 Al). The intention here is that the coking particles carried along in the focal range of the high-velocity gas flow would be decelerated and in part deflected outward in a radial pattern, so that they would then no longer contribute to erosion damage on the tube plate and the tubes. However, an undesirable differential pressure and the associated increased exposure time would result with fittings of this type, meaning that there would be a yield loss. This invention takes a different approach, in that it attempts to provide an effective wear protection by applying a metallic lining to the tube plate and to the entry space of the cooling tubes. Erosion at the inlet side tube plate and in the cooling tubes made it necessary to periodically shut down the quench cooler for purposes of inspection and maintenance. In the past, people attempted to correct the problem by welding material onto the tube plates in order to return them to the required wall thickness and periodically replacing the cooling tubes. This process is very complicated and costly and is also unsatisfactory in terms of the resistance capabilities of the replacement materials, since these might very well have the same characteristics as the materials that were originally used. It has been established that the material erosion in the gas inlet region is not caused solely by mechanical erosion, but by the combined effects of high-temperature corrosion (scaling) and mechanical erosion of the corrosion product that has been formed (iron oxide). Thus, one of the objectives of the invention is to apply a metallic lining which is highly resistant to high-temperature corrosion to the tube plates and the inlet region of the cooling tubes. All other characteristics of the lining must have similar material characteristics to the rest of the equipment material (ductility, heat expansion coefficient). It must be possible to add a partial lining without causing any negative side effects. In addition, the lining should be easy to install and easy to remove or replace. These objectives were met by developing a shell-and-tube heat exchanger (THE) equipped with a tube plate lining which is resistant to the wear occurring in these conditions for use in thermal cracking equipment which contains cooling tubes (1) through which the gas to be cooled is circulated, each tube being secured by a tube plate at both ends of the tube and enclosed in a casing through which a coolant material is circulated. (2) The surface of the tube plate on the gas inlet side which is impacted by gas as it enters the shell-and-tube heat exchanger should be faced, at least partially, by a protective layer which is created by aligning individual sleeves side-to-side and end-to-end at the outer edges and inserting the tube ends into them (Fig.l), typified by the fact that the insert sleeves are created from a heat-resistant metallic material. In principle (Fig. 2), the insert sleeves are simply constructed; the most basic application consists of a tube (4) and a plate (5). One end of the tube is attached to the plate such that the surface of the plate is positioned at a 90° angle to the length axis of the tube. In other words, one could say that the tube stands vertically on top of the plate. The plate (Fig. 3) is perforated to allow the inflowing gas to pass through the plate into the tube. In the most basic application of this principle, a hole would simply be drilled in the plate. Preferably, the diameter of the drilled opening should be similar or equal to the internal diameter of the tube. The insert tubes can be manufactured either by welded construction, by machining processes, by casting, or by precision cold forging. Ideally, the plate should be aligned with the center of the tube cross section. The tube's length axis is then threaded through the center of the plate surface. Logically, the drilled hole mentioned above is also located in the center of the plate surface. The plate itself is designed with a shape that allows the outer edges of the plate to abut the outer edges of the plates of adjoining sleeves in such a manner as to provide at least a partial continuous, gapless covering for the tube plate on the inlet side (Fig. The choice of which geometric shape is best suited for the plates depends upon the geometric relationship in which the individual cooling tubes are positioned relative to one another. Suitable individual geometric shapes which would create a solid, continuous larger surface when positioned next to each other would include, for example, triangular surfaces (especially isosceles, where all sides are the same length), rectangular surfaces (especially squares, but diamonds or rhombuses would be appropriate), and hexagons (especially those where all angles and sides are identical). If the tubes in the shell are positioned such that the top view looks like a grid network, where each tube marks a grid intersection and where the grid is square, then it would be preferable that the plates of all the sleeves would be square. Conveniently, the sleeve in the tube has an outer diameter which is equal to or only slightly smaller than the inner diameter measurement of the cooling tube. This is the only way that the insert sleeves, with their attached tubes, be fitted exactly into the cooing tubes. It has been established through practical application that the optimal length for tubes on the insert sleeves lies somewhere in the area of between 50 and 200 mm; tubes measuring between 70 and 150 mm in length are especially suitable. Tubes measuring between 100 and 120 mm are especially optimal, because this measurement is equal to the length of the tube section of the cooling tube which is subject to the greatest impact under operating conditions. The material thickness of the tubes and the plate of the insert sleeves are adapted to the rest of the dimensions of the THE and particular operating conditions. Generally, a tube wall thickness of about 1 mm is optimal. The preferred thickness of the plate is between 2 mm and 10 mm. As mentioned above, material erosion in the gas inlet region, especially in the highly impacted central region of the tube plate, by the combined effects of high-temperature corrosion (scaling) and mechanical erosion of the corrosion product that has been formed (iron oxide). As such, this is a new awareness that has not previously been considered in the industry, where it has always been accepted that material erosion has been caused solely, or at least primarily, by mechanical abrasion. This assumption has prevented the experts in the field from considering installing metallic linings instead of linings created from ceramic or other fireproof masses, especially since common methods of welding in earlier times were difficult and expensive and did not result in satisfactorily long operating times. This invention is also based upon the realization that metallic materials which have been adequately tempered against high temperature corrosion through specific conditions —in other words, on which corrosion products are not constantly being formed on the surface —are then also sufficiently resistant to the purely mechanical stresses of abrasion. Because of this, the preferred materials are high-temperature, corrosion-resistant alloys, especially steels containing chrome and nickel-based alloys. Because of their durability under the process conditions outlined here, austenitic steels are especially preferable for use in manufacture of the insert tubes. In order to achieve an optimal gas flow, this inlet in the sleeves is shaped conically or rounded off (6). In order to prevent a tearing edge from forming at the rear end of the sleeve as it has been inserted into the cooling tube, which might result in turbulence and material erosion within the cooing tube, the end of the tube which is placed against the plate is attached to the insert sleeve (7). An additional advantage of the insert sleeves as they are employed in this invention is in the formability of the metallic materials out of which they are constructed. This makes it possible to attach the sleeves to the cooling tube in a secure and continuous seam using a simple, common procedure such as rolling. In addition to rolling, the process of hydraulic fastening can be used. The material characteristics of the insert sleeves make it possible to produce the sleeves with a thin wall, which further minimizes the formation of tearing edge at the opposite end of the tube from the face. Also, a very thin wall which is firmly attached to the cooling tubes will have only a very minimal effect on heat transfer and the cooling operation of the THE will not be impacted at this point. In comparison with the current state-of-the-art technology, this invention exhibits the following advantages: Compared to ceramic, the elements or insert sleeves, are very robust and do not need any special protection against bumping or falling. The stability of the cooling tubes and of the sleeves is not placed under as much strain as when ceramic is used. Among other reasons, this is because permanent connection between cooling tube and sleeve tube is not completed until the rolling or hydraulic fastening takes place. This means that the process is applicable for repairs or modifications to previously-used coolers with cooling tubes which have been increased in internal diameter by removal. On machines such as these that have previously been damaged, it becomes necessary to make an additional expansion because of the material removal that has already taken place, but with the materials used it becomes easily do-able. The insert sleeves are then attached by rolling or hydraulic fastening and widened slightly more than they would be on comparable undamaged cooling tubes. Low manufacturing costs due to use of common materials and processes, automatable mass production. Installation of a cooler requires only minimal preliminary work, such as sandblasting, but no additional treatment of the outer surface and no closing of tubes as would be necessary, for example, when applying a pliable mass. Assembly costs are minimal, since tools required for this assembly are all commonly-used standard tools. Installation period is comparatively short, since no anchors, screws, or similar attachments must be installed. Likewise, there is no need for welding or firing, as there would be, for example, with a pliable mass. Another very important aspect is the quick and easy disassembly of the installed insert sleeves, with no danger of damage to the cooler. Preferably, a suitable tool (such as an internal pipe cutter, milling cutter, or drill) would be used to make a split cut between the plate and the tube. After removal of the plate, an arbor would be inserted between the cooling tube and the sleeve tube, onto which the sleeve tube would be manually pulled. The plates of the insert sleeves can be chamfered at the edges, meaning where the sleeve edges form the outer rim of the total formed surface and do not abut adjoining insert sleeves, so that they do not form a sharp ridge between the . insert sleeve plate and the tube plate. Application of the shell-and-tube heat transfer exchanger as outlined in this invention is not limited to thermal cracking equipment. In fact, it can be applied to other processes where similar stresses impact the materials because of the operating conditions such as, for example, downstream from fluidized bed combustion or combustion turbines. Shell-and-tube heat exchangers as outlined in this invention can be designed to accommodate all common construction formats, including fixed plate, floating head, and U-bend heat exchangers. Fixed-plate heat exchangers are commonly used in cracking facilities. Figure 1 shows a cross-section drawing through a tube plate (2) with, in this instance, 2 exemplary cooling tubes (1) which are connected to the base plate by means of a tube weld (3). A single sleeve consisting of a sleeve tube (4) and a sleeve plate (5) is inserted in each cooling tube. The plates attached to the sleeves of neighboring tubes (1) share a common edging rim (8), against which they all abut, fitting precisely. This makes it possible to completely cover the tube plate (2). The inflowing cracking gas is thus prevented from striking the plate, instead striking the face of the insert sleeve plate. Figure 2 depicts the longitudinal section of an insert sleeve, and Figure 3 depicts the top view of the same sleeve. The sleeve consists of the sleeve tube (4) and the sleeve plate (5). The rounded entry region (6) and the chamfered tube end (7) are also clearly recognizable. Reference Key List (1) Cooling tube (2) Tube plate (3) Tube weld (4) Sleeve tube (5). Sleeve plate (6) Rounded entry region (7) Chamfered tube end (8) Edging rim WE CLAIM: 1. Heat transfer tube bundle for cooling of gases emitted by thermal cracking equipment, equipped with a) a tube plate lining which is resistant to wear and tear from scaling b) cooling tubes (1) through which the gas to be cooled is conducted and which are held in place at both ends of each tube by a single tube plate, and c) a casing which contains a flowing coolant, in which the tube plate located on the gas inlet side is at least partially covered by a material barrier formed by the face sides of individual sleeves which are positioned next to each other, each abutting the next at the outer edge, and •inserted into the ends of the tubes, characterized in that the inserted sleeves are made of metal alloys which are resistant to scaling, and specifically from austenitic steel. 2. Heat transfer tube bundle according to Claim 1, characterized in that the inserted sleeves essentially consist of a single tube (4) to which a plate (5) is affixed at one end. The plate is positioned at a 90-degree angle to the vertical axis of the tube and has a hole drilled into the plate so that the incoming gas can flow through the plate (5) into the tube (4). 3. Heat transfer tube bundle according to Claim 2, characterized in that the center of the plate (5) is aligned with the central cross-section of the tube. 4. Heat transfer tube bundle according to the previous Claim, characterized in that the plate (5) is designed to be shaped in a way that allows the outer edges of each plate to abut the outer edges of the plates of neighboring sleeves (8) in such a way that the tube plate on the inlet side is at least partially covered by a continuous layer with no gaps. 5. Heat transfer tube bundle according to one of the previous Claims 2 to 4, characterized in that the plate (5) is rectangular, preferably square, in shape. 6. Heat transfer tube bundle according to one of the previous Claims 2 to 5, characterized in that the tube (4) of the sleeve has an outer diameter which is exactly equal to or slightly smaller than the inner diameter of the cooling tubes 7. Heat transfer tube bundle according to one of the previous Claims 2 to 6, characterized in that the tube (4) of the inserted sleeve measures 50 to 200 mm in length, preferably 70 to 150 mm, and optimally 100 to 120 mm. 8. Heat transfer tube bundle according to one of the previous Claims 2 to 7, characterized in that the wall thickness of the tube (4) of the inserted sleeve measures 1 mm. 9. Heat transfer tube bundle according to one of the previous Claims 2 to 8, characterized in that the plate (5) of the inserted sleeve is 2 to 110 mm thick. 10. Heat transfer tube bundle according to at least one of the previous Claims 2 to 9, characterized in that the tube end of the inserted sleeve opposite the plate (5) is chamfered. 11. Heat transfer, tube bundle according to one of the previous Claims 2 to 10, characterized in that the inserted sleeve is firmly connected to the respective cooling tube (1) by rolling or hydraulic expansion. 12. Process for equipping a heat transfer tube bundle according to Claim 1 with a material covering, characterized in that sleeves consisting of one tube (4) and one plate (5) each are inserted into the heat exchange tubes, and the inserted tube (4) .of the sleeve is firmly attached to the heat exchange tube (1) by rolling or hydraulic expansion. ABSTRACT The invention relates to a shell-and-tube heat exchanger which contains a wear-resistant tube plate lining. In spite of short exposure periods, cracking gas flowing out of the cracking oven of thermal cracking equipment at high speeds contains coking particles that impact the tube plate on the gas inlet side of the shell-and-tube heat exchanger in a highly erosive manner. It would be highly desirable to be able to apply a metallic lining to the tube plate and the inlet region of the cooling tubes which is extremely resistant to high-temperature corrosion. It is proposed to develop a shell-and-tube heat exchanger which includes a wear-resistant tube plate lining for application in thermal cracking equipment which contains cooling tubes (1) through which the gas to be cooled is circulated, each tube being secured by a tube plate at both ends of the tube and enclosed in a casing through which a coolant material is also circulated. (2) The surface of the tube plate on the gas inlet side which is impacted by gas as it enters the shell-and-tube heat exchanger should be faced, at least partially, by a protective layer which is created by aligning individual sleeves of a heat-resistant metallic material side-to-side and end-to-end at the outer edges and inserting them into the tube ends (Fig.l). To The Controller of Patent The Patent Office Mumbai

Documents:

82-MUMNP-2008-ABSTRACT(3-2-2012).pdf

82-MUMNP-2008-ABSTRACT(8-11-2012).pdf

82-mumnp-2008-abstract.doc

82-mumnp-2008-abstract.pdf

82-MUMNP-2008-CANCELLED PAGES(3-2-2012).pdf

82-MUMNP-2008-CLAIMS(AMENDED)-(3-2-2012).pdf

82-MUMNP-2008-CLAIMS(AMENDED)-(8-11-2012).pdf

82-MUMNP-2008-CLAIMS(MARKED COPY)-(8-11-2012).pdf

82-mumnp-2008-claims.doc

82-mumnp-2008-claims.pdf

82-mumnp-2008-correspondence(17-3-2008).pdf

82-MUMNP-2008-CORRESPONDENCE(3-2-2012).pdf

82-mumnp-2008-correspondence-others.pdf

82-mumnp-2008-correspondence-received.pdf

82-mumnp-2008-description (complete).pdf

82-mumnp-2008-drawings.pdf

82-MUMNP-2008-ENGLISH TRANSLATION(8-11-2012).pdf

82-MUMNP-2008-EP DOCUMENT(3-2-2012).pdf

82-mumnp-2008-form 1(4-3-2008).pdf

82-MUMNP-2008-FORM 26(8-11-2012).pdf

82-MUMNP-2008-FORM 3(3-2-2012).pdf

82-MUMNP-2008-FORM PCT-IB-304(8-11-2012).pdf

82-mumnp-2008-form-1.pdf

82-mumnp-2008-form-18.pdf

82-mumnp-2008-form-2.doc

82-mumnp-2008-form-2.pdf

82-mumnp-2008-form-3.pdf

82-mumnp-2008-form-5.pdf

82-mumnp-2008-form-pct-ib-306.pdf

82-mumnp-2008-geneal power of attorney(17-3-2008).pdf

82-mumnp-2008-pct-search report.pdf

82-MUMNP-2008-PETITION UNDER RULE 137(3-2-2012).pdf

82-MUMNP-2008-REPLY TO EXAMINATION REPORT(3-2-2012).pdf

82-MUMNP-2008-REPLY TO HEARING(8-11-2012).pdf

abstract1.jpg