Title of Invention

PLATE FOR A FUEL CELL ASSEMBLY

Abstract A unitized plate such as a bipolar plate for a fuel cell assembly is provided. The unitized plate includes a plurality of active regions electrically insulated from one another, and a plurality of inlet and outlet apertures formed in the plate. Each of the active regions is in fluid communication with a dedicated inlet aperture adapted to selectively deliver gaseous reactants thereto. A fuel cell assembly having a plurality of independently operable fuel cell stack units, and a method for operating the fuel cell assembly, is also provided.
Full Text PLATE FOR A FUEL CELL ASSEMBLY
FIELD OF THE INVENTION
[0001] The present disclosure relates to a fuel cell assembly, and more
particularly to a plate such as a bipolar plate for a fuel cell assembly having a
plurality of active regions electrically insulated from one another.
BACKGROUND OF THE INVENTION
[0002] A fuel cell has been proposed as a clean, efficient and environmentally
responsible power source for electric vehicles and various other applications. In
particular, the fuel cell has been identified as a potential alternative for the
traditional internal-combustion engine used in modern vehicles.
[0003] One type of fuel cell is known as a proton exchange membrane (PEM) fuel
cell. The PEM fuel cell typically includes three basic components: a cathode, an
anode, and an electrolyte membrane. The cathode and anode typically include a
finely divided catalyst, such as platinum, supported on carbon particles and
mixed with an ionomer. The electrolyte membrane is sandwiched between the
cathode and the anode to form a membrane-electrolyte-assembly (MEA). The
MEA is often disposed between porous diffusion media (DM) which facilitate a
delivery of gaseous reactants, typically hydrogen and oxygen from air, for an
electrochemical fuel cell reaction.
[0004] As described in U.S. Pat. No. 6,127,058, individual fuel cells may be
aligned in a planar array that is electrically connected via interconnect tabs. In
U.S. Pat. Nos. 6,080,503 and 6,495,278, electrochemical fuel cell stacks having
adhesively bonded layers formed for individual fuel cell modules are also
described. PEM-type fuel cell assemblies having multiple parallel fuel cell
substacks that employ shared fluid plate assemblies and shared membrane
electrode assemblies are also disclosed in U.S. Pat. No. 5,945,232.
[0005] In automotive applications, individual fuel cells are often stacked together
in series to form a fuel cell stack with a voltage sufficient to provide power to an
electric vehicle. Connecting individual fuel cells in series requires the fabrication


and handling of a multitude of individual fuel cells, however. A height of the
resultant fuel cell stack having the multitude of individual fuel cells may limit
placement of the fuel cell stack within an electric vehicle. Furthermore, DC-to-
DC voltage converters are typically employed in fuel cell systems to enable the
fuel cell stack to achieve the sufficient voltage. Voltage converters and related
componentry add undesirable complexity to the fuel cell system.
[0006] There is a continuing need for a simplified fuel cell assembly which
militates against the need for DC-to-DC converters, the need to fabricate a
multitude of individual fuel cells, and facilitates a placement of the fuel cell
assembly within a vehicle.
SUMMARY OF THE INVENTION
[0007] In concordance with the instant disclosure, a simplified fuel cell assembly
which militates against the necessity for DC-to-DC converters, militates against
the necessity to fabricate multiple individual fuel cells, and facilitates a placement
of the fuel cell assembly in a vehicle, is surprisingly discovered.
[0008] In one embodiment, a unitized fuel cell plate includes a plurality of active
regions formed thereon and electrically insulated from one another. The unitized
fuel cell plate further includes a plurality of inlet and outlet apertures formed
therein. Each one of the plurality of active regions is in fluid communication with
one of the inlet apertures. The one of the inlet apertures is adapted to selectively
deliver reactants to the one of the plurality of active regions.
[0009] In another embodiment, a fuel cell assembly is provided. The fuel cell
assembly includes a plurality of fuel cell stack units disposed adjacent one
another and electrically connected in series. The fuel cell stacks may be formed
with a plurality of the unitized plates. The plurality of fuel cell stacks yields a
voltage sufficient to power an electric vehicle.
[0010] In a further embodiment, a method for operating the fuel cell assembly
includes the steps of providing a plurality of fuel cell stacks including a plurality of
unitized bipolar plates and a plurality of unitized membrane-electrode
assemblies, connecting the fuel cell stacks in electrical series, and selectively

supplying gaseous reactants to each of the plurality of fuel cell stacks. A fuel cell
assembly having a voltage sufficient to power an electric vehicle is thereby
provided.
DRAWINGS
[0011] The above, as well as other advantages of the present disclosure, will
become readily apparent to those skilled in the art from the following detailed
description, particularly when considered in the light of the drawings described
hereafter.
[0012] FIG. 1 illustrates a schematic, exploded perspective view of a PEM fuel
cell stack of the prior art, showing only two cells;
[0013] FIG. 2 is a perspective view of a fuel cell assembly including a plurality of
fuel cell stacks connected in series according to an embodiment of the present
disclosure;
[0014] FIG. 3 is a perspective view of a fuel cell assembly including plurality of
fuel cell stacks connected in series according to an embodiment of the present
disclosure; and
[0015] FIG. 4 is an enlarged perspective view of a unitized fuel cell plate and a
unitized membrane assembly of the fuel cell assembly illustrated in FIG. 3.
DETAILED DESCRIPTION OF THE INVENTION
[0016] The following description is merely exemplary in nature and is not
intended to limit the present disclosure, application, or uses. It should also be
understood that throughout the drawings, corresponding reference numerals
indicate like or corresponding parts and features. In respect of the methods
disclosed, the steps presented are exemplary in nature, and thus, are not
necessary or critical.
[0017] FIG. 1 depicts an illustrative fuel cell stack 2 having a pair of MEAs 4, 6
separated from each other by an electrically conductive bipolar plate 8. For
simplicity, only a two-cell stack (i.e. one bipolar plate) is illustrated and described

in FIG. 1, it being understood that the typical fuel cell stack 2 will have many
more such cells and bipolar plates.
[0018] The MEAs 4, 6 and bipolar plate 8 are stacked together between a pair of
clamping plates 10, 12 and a pair of unipolar end plates 14, 16. The clamping
plates 10, 12 are electrically insulated from the end plates 14, 16 by a gasket or a
dielectric coating (not shown). The unipolar end plate 14, both working faces of
the bipolar plate 8, and the unipolar end plate 16 include respective active areas
18, 20, 22, 24. The active areas 18, 20, 22, 24 are typically flow fields for
distributing gaseous reactants such as hydrogen gas and air over an anode and
a cathode, respectively, of the MEAs 4, 6.
[0019] The bipolar plate 8 is typically formed by a conventional process for
shaping sheet metal such as stamping, machining, molding, or photo etching
through a photolithographic mask, for example. In one embodiment, the bipolar
plate 8 is formed from unipolar plates which are then joined. It should be further
understood that the bipolar plate 8 may also be formed from a composite
material. In one particular embodiment, the bipolar plate 8 is formed from a
graphite or graphite-filled polymer.
[0020] Nonconductive gaskets 26, 28, 30, 32 provide seals and an electrical
insulation between the several components of the fuel cell stack 2. Gas-
permeable diffusion media 34, 36, 38, 40 are adjacent the anodes and the
cathodes of the MEAs 4, 6. The end plates 14, 16 are disposed adjacent the
diffusion media 34, 40, respectively, while the bipolar plate 8 is disposed
adjacent the diffusion media 36 on the anode face of MEA 4. The bipolar plate 8
is further disposed adjacent the diffusion media 38 on the cathode face of MEA
6.
[0021] The bipolar plate 8, unipolar end plates 14, 16, and the gaskets 26, 28, 30,
32 each include a cathode supply aperture 72 and a cathode exhaust aperture
74, a coolant supply aperture 75 and a coolant exhaust aperture 77, and an
anode supply aperture 76 and an anode exhaust aperture 78. Supply manifolds
and exhaust manifolds of the fuel cell stack 2 are formed by an alignment of the
respective apertures 72, 74, 75, 77, 76, 78 in the bipolar plate 8, unipolar end

plates 14, 16, and the gaskets 26, 28, 30, 32. The hydrogen gas is supplied to
an anode supply manifold via an anode inlet conduit 80. The air is supplied to a
cathode supply manifold of the fuel cell stack 2 via a cathode inlet conduit 82. An
anode outlet conduit 84 and a cathode outlet conduit 86 are also provided for an
anode exhaust manifold and a cathode exhaust manifold, respectively. A coolant
inlet conduit 88 is provided for supplying liquid coolant to a coolant supply
manifold. A coolant outlet conduit 90 is provided for removing coolant from a
coolant exhaust manifold. It should be understood that the configurations of the
various inlets 80, 82, 88 and outlets 84, 86, 90 in FIG. 1 are for the purpose of
illustration, and other configurations may be chosen as desired.
[0022] FIG. 2 shows a plurality of individual fuel cell stack 2 units in a fuel cell
assembly 200. The plurality of individual fuel cell stacks 2 may be disposed
adjacent one another to form a "bank" of fuel cell stacks 2, thus enabling a
convenient placement of the fuel cell assembly 200 in a vehicle. Each of the fuel
cell stacks 2 is adapted to receive a dedicated supply of gaseous reactants. The
dedicated supplying of gaseous reactants enables an independent control of the
fuel cell stack 2 units of the fuel cell assembly 200.
[0023] The fuel cell stacks 2 are electrically connected in series to a first terminal
202 and second terminal 204. The first terminal 202 may be connected to one of
the end plates 14 of the fuel cell stacks 2, and the second terminal 204 may be
connected to one of the end plates 16 of the fuel cell stacks 2, for example. The
first terminal 202 and the second terminal 204 are in electrical communication
with an external load (not shown) such as a drive of an electric vehicle or a
battery bank, for example.
[0024] FIG. 3 shows a plurality of fuel cell stacks 2 joined together to form the
fuel cell assembly 200 according to an embodiment of the present disclosure. In
the embodiment shown, the fuel cell assembly 200 includes at least one
electrically insulating layer 300 disposed between adjacent fuel cell stacks 2.
The electrically insulating layer 300 is formed of any conventional electrically
insulating material known in the art such as a thermoplastic material and a
thermoset material, for example. It is understood that the thermoplastic material

and thermoset material may be rigid or elastic. A skilled artisan should
appreciate that other suitable insulating materials may be employed as desired.
[0025] FIG. 4 illustrates a unitized plate 400 of the fuel cell assembly 200. The
unitized plate 400 is adapted to be stacked with corresponding fuel cell
components, such as MEAs, gaskets, and endplates, in a configuration
substantially as shown in FIG. 1. As used herein, the term "unitized" means that
the unitized plates 400 provide independently operating fuel cell stack 2 units
when stacked to form the fuel cell assembly 200. It is understood that the
unitized plate 400 can be a bipolar plate or a unipolar plate, if desired. In the
embodiment shown, the unitized plate 400 is formed with a plurality of active
regions 402, 404. The active regions 402, 404 of the unitized plate 400 are
electrically conductive and serve as current collectors for the fuel cell stacks 2 in
the fuel cell assembly 200. The active regions 402, 404 are electrically insulated
from one another.
[0026] Headers 406 are disposed at a first end and a second end of the unitized
plate 400. In particular embodiments, the headers 406 are formed from an
electrically insulating or dielectric material having an electrical resistance
sufficient to militate against a flow of electrical current therethrough. The active
regions 402, 404 are further separated by electrically insulating dividers 408.
The electrically insulating dividers 408 may be formed from any conventional
electrically insulating material known in the art such as a thermoplastic material
and a thermoset material, for example. It is understood that the thermoplastic
material and thermoset material may be rigid or electrometric. A skilled artisan
should appreciate that other suitable insulating materials may be employed as
desired.
[0027] The fuel cell assembly 200 may include a border or frame (not shown). In
particular embodiments, the frame holds the unitized plate 400. The frame can
be constructed from a number of suitable materials including, but not limited to,
dielectric materials such as rigid thermoplastics, thermosets, elastomers, and
thermoplastic elastomers. In particular embodiments, the frame is integral with at
least one of the headers 406 and the electrically insulating dividers 408. It may

be further desirable to mold an integral seal to the unitized plates 400, for
example, via the frame. The integral seal may be formed by a molding process
known in the art.
[0028] The headers 406 may include a plurality of inlet apertures 410 and a
plurality of outlet apertures 412 that define a plurality of inlet manifolds and a
plurality of outlet manifolds, respectively, when the fuel cell assembly 200 is fully
assembled. In another embodiment, the inlet and outlet apertures 410,412 are
formed in the border or frame. In one embodiment, the headers 406 include a
seal integrally formed thereon.
[0029] The inlet and outlet apertures 410, 412 correspond substantially to the
inlet and outlet apertures 72, 74, 76, 78. It should be appreciated that each fuel
cell stack 2 unit receives a supply of reactants via dedicated supply manifolds
formed by the inlet apertures 410. The fuel cell stack 2 formed with the unitized
plates 400 are thereby independently operable.
[0030] In a particular embodiment, each of the active regions 402, 404 is in fluid
communication with a dedicated inlet aperture 410. The inlet apertures 410 are
thereby adapted to selectively deliver gaseous reactants, such as air and
hydrogen, as desired to the active regions 402, 404. Each of the plurality of
active regions 402, 404 may further be in fluid communication with a dedicated
outlet aperture 412. In an illustrative embodiment, the individual inlet aperture
410 delivers the gaseous reactants to one of the active regions 402. The
individual outlet aperture 412 may be adapted to independently receive an
exhaust stream from the individual active region 402.
[0031] A skilled artisan should appreciate that the fuel cell assembly 200 may be
adjusted to a desired voltage by limiting a supply of gaseous reactants to a
portion of the fuel cell stacks 2 formed with the unitized plates 400. For example,
gaseous reactants may be selectively provided to some fuel cell stacks 2 and not
provided to other fuel cell stacks 2 formed by the unitized plates 400. For
example, when one fuel cell stack 2 unit becomes inoperable or begins to exhibit
an undesirable performance, the gaseous reactants may be directed away from
the inoperable unit and the supply to the other units adjusted accordingly.

[0032] Similarly, one of ordinary skill should appreciated that the unitized plates
400, having the inlet apertures 410 adapted to selectively deliver gaseous
reactants to the active regions 402, 404, enables operational strategies such as
flow shifting and stack order switching, for example. Flow shifting involves an
alternating flow of gaseous reactants through a first stack and a second stack
connected in series, wherein a direction of the flow through the stacks alternates.
Stack order switching involves an alternating flow of gaseous reactants through
the first stack to the second stack connected in series, wherein the direction of
flow through the fuel cell stacks 2 remains constant. These methods of operating
the fuel cell stacks 2 may facilitate moisture control and optimize an operability of
the fuel cell stacks 2.
[0033] As further shown in FIG. 4, a single, unitized MEA 414 may have a
plurality of catalyst regions 416, 418 that form the anodes and cathodes of the
fuel cell stack 2 units. The plurality of catalyst regions 416, 418 may be
separated by an electrolyte membrane, with the catalyst regions 416, 418 applied
by a patch coating process, for example. In another embodiment, the MEA 414
has the catalyst disposed substantially evenly along a length of the MEA 414
surfaces, with the catalyst regions 416, 418 being formed by openings in a matrix
or screen layer bonded to the MEA 414 surfaces. The matrix or screen layer is
disposed over the catalyst and has openings that expose and define the
boundaries of the catalyst regions 416,418. The matrix or screen may be
formed from a dielectric material as described herein. Other suitable means for
applying the catalyst regions 416, 418 may be used as desired.
[0034] The unitized MEA 414 is configured for assembly with the unitized plates
400. The unitized plate 400 is generally disposed between a pair of the unitized
MEAs 414. As a nonlimiting example, the catalyst regions 416,418 are aligned
with and adapted to abut the active regions 402, 404 of the unitized plate 400
when the unitized plate 400 and the unitized MEA 414 are arranged in the fuel
cell assembly 200.
[0035] One of ordinary skill in the art should understand that the unitized plates
400 and the unitized MEAs 414 form a plurality of independently functioning fuel


cell stacks 2 when assembled. Thus, the fuel cell stacks 2 formed with the
unitized plates 400 may be operated substantially independently of one another
by controlling a flow of the gaseous reactants to the fuel cell stacks 2. The
independent fuel cell stacks 2 formed from the unitized plates 400 and the MEAs
414 may also be electrically linked in series to provide a desired voltage.
[0036] In a typical fuel cell assembly, a voltage converter (not shown) is
employed to boost the electrical voltage of the fuel cell stack. In the present
invention, the plurality of fuel cell stacks 2 units connected in series form a fuel
cell assembly 200 wherein a voltage generated is maximized. In a particular
embodiment, the fuel cell assembly 200 may be constructed with a plurality of the
unitized plates 400 and a plurality of the MEAs 414. For example, the active
regions 402, 404 are electrically connected in series to boost the electrical
voltage of the fuel cell assembly 200 in accordance with Ohm's Law. As a further
nonlimiting example, one 230-cell stack with about 800 cm2 of active area per
cell may be replaced by three 200-cell stacks with about 300 cm2 of active area
per cell. A skilled artisan should thereby understand that a single fuel cell stack
having a voltage converter to boost the electrical voltage can be replaced by the
fuel cell assembly 200 of the present disclosure. It should further be understood
that constructing the fuel cell assembly 200 from the unitized plates 400 and the
unitized MEAs 414 minimizes a complexity thereof.
[0037] The present disclosure further includes a method for operating the fuel cell
assembly 200. In one embodiment, the method includes the steps of providing
the fuel cell assembly 200 as described herein with the plurality of fuel cell stacks
2 formed with the unitized plates 400. Each of the fuel cell stacks 2 of the
assembly 200 is adapted to receive a supply of gaseous reactants. The fuel cell
stacks 2 are then connected in electrical series. The gaseous reactants may be
selectively supplied to each of the plurality of fuel cell stacks 2 as desired. For
example, the gaseous reactants may be selectively supplied to adjust the voltage
to a desired level. In other embodiments, the gaseous reactants may be
selectively supplied according to one or more operational strategies, such as
stack order switching, as previously described herein. It should be understood

that other suitable operational strategies may be employed with the fuel cell
assembly 200 of the disclosure by selectively supplying the gaseous reactants to
one or more of the plurality of fuel cell stacks 2.
[0038] While certain representative embodiments and details have been shown
for purposes of illustrating the invention, it will be apparent to those skilled in the
art that various changes may be made without departing from the scope of the
disclosure, which is further described in the following appended claims.


CLAIMS
What is claimed is:
1. A fuel cell plate, comprising:
a plate with a plurality of inlet and outlet apertures formed therein, and a
plurality of active regions formed thereon, each one of the plurality
of active regions in fluid communication with one of the inlet
apertures, the one of the inlet apertures adapted to selectively
deliver reactants to the one of the plurality of active regions.
2. The fuel cell plate of Claim 1, wherein each of the plurality of active
regions is in fluid communication with one of the plurality of outlet apertures.
3. The fuel cell plate of Claim 2, wherein the active regions include
flow fields adapted to receive the gaseous reactants.
4. The fuel cell plate of Claim 1, wherein the active regions are
separated by dielectric dividers.
5. The fuel cell plate of Claim 1, further comprising headers disposed
at a first end and a second end of the plate.
6. The fuel cell plate of Claim 5, wherein the headers are dielectric
and are formed integral with a dielectric frame adapted to be disposed on the
plate.
7. The fuel cell plate of Claim 1, wherein the plate is formed from an
electrically conductive composite material.
8. The fuel cell plate of Claim 7, wherein the electrically conductive
composite material is a graphite-filled polymer.


9. The fuel cell plate of Claim 1, wherein the plate is a bipolar plate.
10. The fuel cell plate of Claim 1, wherein the plate has a seal integrally
formed thereon.
11. A fuel cell assembly comprising:
a plurality of fuel cell stacks disposed adjacent one another and
electrically connected in series to provide a voltage sufficient to
power an electric vehicle,
wherein each of the fuel cell stacks is independently operable and
adapted to receive a dedicated supply of gaseous reactants.
12. The fuel cell assembly of Claim 11, wherein the fuel cell stacks are
coupled to one another to form a bank of fuel cell stacks configured for
placement in the electric vehicle.
13. The fuel cell assembly of Claim 11, wherein a pair of the plurality of
fuel cell stacks has an electrically insulating layer disposed therebetween.
14. The fuel cell assembly of Claim 11, wherein the fuel cell stacks are
formed from a plurality of unitized plates, each of the unitized plates disposed
between a pair of unitized MEAs.
15. The fuel cell assembly of Claim 14, wherein the unitized MEAs
have a plurality of catalyst regions.
16. The fuel cell assembly of Claim 15, wherein the catalyst regions are
aligned with the active regions of the unitized plates.


17. The fuel cell assembly of Claim 11, further comprising a plurality of
inlet manifolds adapted to independently deliver a supply of gaseous reactants to
each of the fuel cell stacks, and a plurality of outlet manifolds adapted to
independently receive an exhaust from each of the fuel cell stacks.
18. The fuel cell assembly of Claim 17, wherein a cross-sectional
perimeter of the inlet manifold and a cross-sectional perimeter of the outlet
manifolds is defined by apertures formed in the unitized plates and the unitized
MEAs.
19. The fuel cell assembly of Claim 17, wherein the inlet manifolds and
the outlet manifolds are formed in a frame coupled to the plurality of fuel cell
stacks.
20. A method for operating a fuel cell assembly, the method
comprising the steps of:
providing a plurality of fuel cell stacks including a plurality of unitized
bipolar plates and a plurality of unitized membrane-electrode
assemblies, each of the unitized bipolar plates being stacked
between a pair of the unitized membrane-electrode-assemblies,
each of the fuel cell stacks adapted to receive a dedicated supply of
gaseous reactants;
connecting the fuel cell stacks in electrical series; and
selectively supplying gaseous reactants to each of the plurality of fuel cell
stacks.

A unitized plate such as a bipolar plate for a fuel cell assembly is provided. The unitized plate includes a plurality of active regions electrically insulated from one another, and a plurality of inlet and outlet apertures formed in the plate. Each of the active regions is in fluid communication with a dedicated inlet
aperture adapted to selectively deliver gaseous reactants thereto. A fuel cell assembly having a plurality of independently operable fuel cell stack units, and a method for operating the fuel cell assembly, is also provided.

Documents:

1396-KOL-2008-(16-06-2014)-PETITION UNDER RULE 137.pdf

1396-kol-2008-abstract.pdf

1396-KOL-2008-ASSIGNMENT.pdf

1396-kol-2008-claims.pdf

1396-KOL-2008-CORRESPONDENCE 1.1.pdf

1396-KOL-2008-CORRESPONDENCE 1.2.pdf

1396-kol-2008-correspondence.pdf

1396-kol-2008-description (complete).pdf

1396-kol-2008-drawings.pdf

1396-kol-2008-form 1.pdf

1396-kol-2008-form 2.pdf

1396-kol-2008-form 3.pdf

1396-kol-2008-form 5.pdf

1396-kol-2008-gpa.pdf

1396-KOL-2008-OTHERS.pdf

1396-kol-2008-specification.pdf

1396-KOL-2008-TRANSLATED COPY OF PRIORITY DOCUMENT.pdf

abstract-1396-kol-2008.jpg


Patent Number 262673
Indian Patent Application Number 1396/KOL/2008
PG Journal Number 36/2014
Publication Date 05-Sep-2014
Grant Date 04-Sep-2014
Date of Filing 19-Aug-2008
Name of Patentee GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Applicant Address 300 GM RENAISSANCE CENTER DETROIT, MICHIGAN
Inventors:
# Inventor's Name Inventor's Address
1 MICHAEL K. BUDINSKI 2 LARCHWOOD DRIVE PITTSFORD, NY 14534
2 IVAN D. CHAPMAN 22 KETCHUM ST., VICTOR, NY 14564
3 WILLIAM PETTIT 16 ESSEX DRIVE ROCHESTER, NY 14623
PCT International Classification Number H01M8/00
PCT International Application Number N/A
PCT International Filing date
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 11/842,650 2007-08-21 U.S.A.