Title of Invention

HYDROGEN-PROCESSING ASSEMBLIES AND HYDROGEN-PRODUCING SYSTEMS AND FUEL CELL SYSTEMS INCLUDING THE SAME

Abstract Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen- separation assembly positioned within the internal volume of an enclosure in a spaced relation to at least a portion of the internal perimeter of the body of the enclosure.
Full Text HYDROGEN-PROCESSING ASSEMBLIES AND HYDROGEN-PRODUCING
SYSTEMS AND FUEL CELL SYSTEMS INCLUDING THE SAME
Related Applications
The present application claims priority to U.S. Provisional Patent Application
Serial No. 60/802,716, which was filed on May 22, 2006, and which was entitled
HYDROGEN-PRODUCING FUEL PROCESSING ASSEMBLIES AND MEMBRANE-
BASED SEPARATION ASSEMBLIES FOR USE THEREWITH and similarly entitled
U.S. Patent Application Serial No. 11/750,806, which was filed on May 18, 2007.
The complete disclosures of the above-identified patent applications are hereby
incorporated by reference for all purposes.
Technical Field
The present disclosure relates generally to hydrogen-processing assemblies,
and more particularly to hydrogen-processing assemblies and components thereof
for purifying hydrogen gas.
Background of the Disclosure
Purified hydrogen gas is used in the manufacture of many products including
metals, edible fats and oils, and semiconductors and microelectronics. Purified
hydrogen gas also is an important fuel source for many energy conservation devices.
For example, fuel cells use purified hydrogen gas and an oxidant to produce
electrical potential. Various processes and devices may be used to produce
hydrogen gas. However, many hydrogen-producing processes produce an impure
hydrogen gas stream, which may also be referred to as a mixed gas stream that
contains hydrogen gas and other gases. Prior to delivering this stream to a fuel cell
stack or other hydrogen-consuming device, the mixed gas stream may be purified,
such as to remove at least a portion of the other gases.
A suitable mechanism for increasing the hydrogen purity of the mixed gas
stream is to utilize at least one hydrogen-selective membrane to separate the mixed
gas stream into a product stream and a byproduct stream. The product stream
contains a greater concentration of hydrogen gas and/or a reduced concentration of
one or more of the other gases than the mixed gas stream. The byproduct stream
contains at least a substantial portion of one or more of the other gases from the
mixed gas stream. Hydrogen purification using one or more hydrogen-selective
membranes is a pressure driven separation process, in which the one or more
hydrogen-selective membranes are contained in a pressure vessel. The mixed gas
stream contacts the mixed gas surface of the membrane(s), and the product stream
Is formed from at least a portion of the mixed gas stream that permeates through the

membrane(s). The byproduct stream is formed from at least a portion of the mixed
gas stream that does not permeate through the membrane(s). The pressure vessel is
typically sealed to prevent gases from entering or leaving the pressure vessel except
through defined inlet and outlet ports or conduits.
Brief Description of the Drawings
Fig. 1 is a schematic cross-sectional view of a hydrogen-processing assembly
according to the present disclosure.
Fig. 2 is a schematic cross-sectional view of a hydrogen-processing assembly
according to the present disclosure.
Fig. 3 is a schematic cross-sectional view of a membrane assembly according
to the present disclosure.
Fig. 4 is a schematic cross-sectional view of another membrane assembly
according to the present disclosure.
Fig. 5 is an exploded view of an illustrative, non-exclusive example of a
hydrogen-processing assembly according to the present disclosure.
Fig. 6 is a fragmentary plan view of portions of the enclosure and the
hydrogen-separation assembly of Rg. 5.
Fig. 7 is a fragmentary plan view of portions of the enclosure and the
hydrogen-separation assembly of Fig. 5.
Fig. 8 is an exploded view of an illustrative, non-exclusive example of another
hydrogen-processing assembly according to the present disclosure that includes a
hydrogen-producing region.
Fig. 9 is an exploded isometric view of an illustrative, non-exclusive example
of another hydrogen-separation assembly according to the present disclosure.
Fig. 10 is an exploded view of an illustrative, non-exclusive example of
another hydrogen-processing assembly according to the present disclosure that
includes a hydrogen-producing region.
Fig. 11 is an exploded isometric view of an Illustrative, non-exclusive example
of another hydrogen-separation assembly according to the present disclosure.
Fig. 12 is a schematic diagram of a fuel-processing system that includes a
hydrogen-processing assembly according to the present disclosure and a source of
hydrogen gas to be purified in the hydrogen-processing assembly.
Fig. 13 is a schematic diagram of a fuel-processing system that includes a
hydrogen-producing fuel processor integrated with a hydrogen-processing assembly
according to the present disclosure.

Fig. 14 is a schematic diagram of another fuel processor system that includes
a hydrogen-producing fuel processor and an integrated hydrogen-processing
assembly according to the present disclosure.
Fig. 15 is a schematic diagram of a fuel cell system that includes a hydrogen-
processing assembly according to the present disclosure.

Detailed Description and Best Mode of the Disclosure
An illustrative, non-exclusive example of a hydrogen-processing assembly
according to the present disclosure is schematically illustrated in cross-section in
Fig. 1 and generally indicated at 10. Assembly 10 includes a hydrogen-separation
region 12 and an enclosure 14. Enclosure 14 includes a body 16 that defines an
internal volume 18 having an internal perimeter 20.
Enclosure 14 may include at least a first portion 22 and a second portion 24
coupled together to form body 16 in the form of a sealed pressure vessel that
includes defined input and output ports that define fluid paths by which gases or
other fluids are delivered into and removed from the enclosure's internal volume.
First and second portions 22, 24 may be coupled together using any suitable
retention mechanism, or structure, 26. Examples of suitable structures 26 include
welds and/or bolts, although any suitable retention mechanism is within the scope of
the present disclosure. Examples of seals that may be used to provide a fluid-tight
interface between first and second portions 22, 24 include, but are not limited to,
gaskets and/or welds. Additionally or alternatively, first and second portions 22, 24
may be secured together so that at least a predetermined amount of compression is
applied to various components that define the hydrogen-separation region within the
enclosure and/or other components that may be incorporated into a hydrogen-
processing assembly according to the present disclosure. In other words, first and
second portions 22, 24, when secured together by a suitable retention mechanism or
structure, may apply compression to various components that define the hydrogen-
separation region and/or other components housed within an enclosure of a
hydrogen-processing assembly, thereby maintaining an appropriate position of the
various components within the enclosure. Additionally or alternatively, the
compression applied to the various components that define the hydrogen-separation
region and/or other components may provide fluid-tight interfaces between the
various components that define the hydrogen-separation region, various other
components, and/or between the components that define the hydrogen-separation
region and other components.
Enclosure 14 includes a mixed gas region 32 and a permeate region 34. The
mixed gas and permeate regions are separated by hydrogen-separation region 12. At
least one input port 36 is provided, through which a fluid stream 38 is delivered to the
enclosure. In the schematically illustrated example shown in Fig. 1, fluid stream 38 is
indicated to be a mixed gas stream 40 that contains hydrogen gas 42 and other
gases 44 that are delivered to mixed gas region 32. Hydrogen gas may be a majority

component of the mixed gas stream. As somewhat schematically illustrated in Fig. 1,
hydrogen-separation region 12 extends between mixed gas region 32 and permeate
region 34 so that gas in the mixed gas region must pass through the hydrogen-
separation region in order to enter the permeate region. As discussed in more detail
herein, this may require the gas to pass through at least one hydrogen-selective
membrane. The permeate and mixed gas regions may be of any suitable relative
size within the enclosure.
Enclosure 14 also includes at least one product output port 46, through which
a permeate stream 48 is removed from permeate region 34. The permeate stream
contains at least one of a greater concentration of hydrogen gas and a lower
concentration of the other gases than the mixed gas stream. It is within the scope of
the present disclosure that permeate stream 48 may (but is not required to) also at
least initially include a carrier, or sweep, gas component, such as may be delivered
as a sweep gas stream 37 through a sweep gas port 39 that is in fluid communication
with the permeate region. The enclosure also includes at least one byproduct output
port 50, through which a byproduct stream 52 containing at least one of a substantial
portion of the other gases 44 and a reduced concentration of hydrogen gas (relative
to the mixed gas stream) is removed from the mixed gas region 32.
Hydrogen-separation region 12 includes at least one hydrogen-selective
membrane 54 having a first, or mixed gas, surface 56, which is oriented for contact
by mixed gas stream 40, and a second, or permeate, surface 58, which is generally
opposed to surface 56. Accordingly, in the schematically illustrated example of Fig. 1,
mixed gas stream 40 is delivered to the mixed gas region of the enclosure so that it
comes into contact with the mixed gas surface of the one or more hydrogen-selective
membranes. Permeate stream 48 is formed from at least a portion of the mixed gas
stream that passes through the hydrogen-separation region to permeate region 34.
Byproduct stream 52 is formed from at least a portion of the mixed gas stream that
does not pass through the separation region. In some embodiments, byproduct
stream 52 may contain a portion of the hydrogen gas present in the mixed gas
stream. The separation region may (but is not required to) also be adapted to trap or
otherwise retain at least a portion of the other gases, which may then be removed as
a byproduct stream as the separation region is replaced, regenerated, or otherwise
recharged.
In Fig 1, streams 37, 40, 48, and 52 schematically represent that each of
these streams may include more than one actual stream flowing into or out of
assembly 10. For example, assembly 10 may receive a plurality of mixed gas

streams 40, a single mixed gas stream 40 that is divided into two or more streams
prior to contacting separation region 12, a single stream that is delivered into internal
volume 18, etc. Accordingly, enclosure 14 may include more than one input port 36.
Similarly, an enclosure 14 according to the present disclosure may include more than
one sweep gas port 39, more than one product outlet port 46, and/or more than one
byproduct outlet port 50.
The hydrogen-selective membranes may be formed of any hydrogen-
permeable material suitable for use in the operating environment and parameters in
which hydrogen-processing assembly 10 is operated. Illustrative, non-exclusive
examples of suitable materials for membranes 54 are disclosed in U.S. Patent
Nos. 6,537,352 and 5,997,594, and in U.S. Provisional Patent Application Serial
No. 60/854,058, the entire disclosures of which are incorporated herein by reference
for ail purposes. In some embodiments, the hydrogen-selective membranes may be
formed from at least one of palladium and a palladium alloy. Illustrative, non-
exclusive examples of palladium alloys include alloys of palladium with copper, silver,
and/or gold. However, the membranes may be formed from other hydrogen-
permeable and/or hydrogen-selective materials, including metals and metal alloys
other than palladium and palladium alloys. Illustrative examples of various
membranes, membrane configurations, and methods for preparing the same are
disclosed in U.S. Patent Nos. 6,152,995, 6,221,117, 6,319,306, and 6,537,352, the
complete disclosures of which are incorporated herein by reference for all purposes.
In some embodiments, a plurality of spaced-apart hydrogen-selective
membranes 54 may be used in a hydrogen-separation region to form at least a
portion of a hydrogen-separation assembly 28. When present, the plurality of
membranes may collectively define one or more membrane assemblies, or
membrane assemblies, 30. In such embodiments, the hydrogen-separation
assembly 28 may generally extend from first portion 22 to second portion 24.
Accordingly, the first and second portions of the enclosure may effectively compress
the hydrogen-separation assembly. Other configurations of enclosure 14 are equally
within the scope of the present disclosure. For example, in some embodiments,
enclosure 14 may additionally or alternatively include end plates coupled to opposite
sides of a body portion. In such embodiments, the end plates may effectively
compress the hydrogen-separation assembly 28 (and other components that may be
housed within the enclosure) between the pair of opposing end plates.
Hydrogen purification using one or more hydrogen-selective membranes is
typically a pressure-driven separation process in which the mixed gas stream is

delivered into contact with the mixed gas surfaces of the membranes at a higher
pressure than the gases in the permeate region of the hydrogen-separation region.
Although not required to all embodiments, the hydrogen-separation region may be
heated via any suitable mechanism to an elevated temperature when the hydrogen-
separation region is utilized to separate the mixed gas stream into the permeate and
byproduct streams. Illustrative, non-exclusive examples of suitable operating
temperatures for hydrogen purification using palladium and palladium alloy
membranes include temperatures of at least 275° C, temperatures of at least 325° C,
temperatures of at least 350° C, temperatures in the range of 275-500° C,
temperatures in the range of 275-375° C, temperatures in the range of 300-450° C,
temperatures in the range of 350-450° C, and the like.
In some embodiments, and as schematically illustrated in Fig. 1, hydrogen-
processing assemblies 10 may, though are not required to, further include a
hydrogen-producing region 70. Illustrative, non-exclusive examples of hydrogen-
producing regions suitable for incorporation in hydrogen-processing assemblies 10 of
the present disclosure are disclosed in U.S. Patent Application Serial No. 11/263,726
and U.S. Provisional Patent Application Serial No. 60/802,716, the complete
disclosures of which are hereby incorporated by reference for all purposes. In such
embodiments, the first and second portions 22, 24 of body 16 may effectively
compress both the hydrogen-separation assembly and one or more components of
the hydrogen-producing region.
In embodiments incorporating a hydrogen-producing region 70, the fluid
stream (38) that is delivered to the internal volume of enclosure 14 may be in the
form of one or more hydrogen-producing fluids, or feed streams, 72. The feed
stream, or streams, are delivered to the hydrogen-producing region 70, which may
include a suitable catalyst 73 for catalyzing the formation of hydrogen gas from the
feed stream(s) delivered thereto. Illustrative, non-exclusive examples of feed
stream(s) 72 include water 74 and/or a carbon-containing feedstock 76, which (when
present) may be delivered In the same or separate fluid streams.
In the hydrogen-producing region, the feed stream(s) chemically react to
produce hydrogen gas therefrom in the form of mixed gas stream 40. In other words,
rather than receiving mixed gas stream 40 from an external source (as schematically
illustrated In a solid arrow in Fig. 1), hydrogen-processing assemblies 10 according to
the present disclosure may optionally include a hydrogen-producing region 70 that is
housed within enclosure 14 itself. This hydrogen-producing region produces mixed
gas stream 40 (schematically illustrated as a dashed arrow in Fig. 1) containing

hydrogen gas 42 and other gases 44 within the enclosure, and this mixed gas stream
is then delivered to mixed gas region 32 and separated into permeate and byproduct
streams by hydrogen-separation region 12, as discussed above and schematically
illustrated in Fig. 1.
Illustrative, non-exclusive examples of suitable mechanisms for producing
mixed gas stream 40 from one or more feed stream(s) include steam reforming and
autbthermal reforming, in which reforming catalysts are used to produce hydrogen
gas from at least one feed stream 72 containing water 74 and a carbon-containing
feedstock 76. In a steam reforming process, hydrogen-producing region 70 may be
referred to as a reforming region, and output, or mixed gas, stream 40 may be
referred to as a reformate stream. The other gases that are typically present In the
reformate stream include carbon monoxide, carbon dioxide, methane, steam, and/or
unreacted carbon-containing feedstock. In an autothermal reforming reaction, a
suitable autothermal reforming catalyst is used to produce hydrogen gas from water
and a carbon-containing feedstock in the presence of air. When autothermal
reforming is used, the fuel processor further includes an air delivery assembly that is
adapted to deliver an air stream to the hydrogen-producing region. Autothermal
hydrogen-producing reactions utilize a primary endothermic reaction that is utilized in
conjunction with an exothermic partial oxidation reaction, which generates heat within
the hydrogen-producing region upon initiation of the initial oxidation reaction.
Illustrative, non-exclusive examples of other suitable mechanisms for
producing hydrogen gas include pyrolysis and catalytic partial oxidation of a carbon-
containing feedstock, in which case the feed stream includes a carbon-containing
feedstock and does not (or does not need to) contain water. A further illustrative,
non-exclusive example of a mechanism for producing hydrogen gas is electrolysis, in
which case the feed stream Includes water but not a carbon-containing feedstock.
Illustrative, non-exclusive examples of suitable carbon-containing feedstocks include
at least one hydrocarbon or alcohol. Illustrative, non-exclusive examples of suitable
hydrocarbons include methane, propane, butane, natural gas, diesel, kerosene,
gasoline and the like. Illustrative, non-exclusive examples of suitable alcohols include
methanol, ethanol, and polyols, such as ethylene glycol and propylene glycol. It is
within the scope of the present disclosure that a hydrogen-processing assembly 10
that includes a hydrogen-producing region 70 may utilize more than a single
hydrogen-producing mechanism in the hydrogen-producing region.
Fig. 2 schematically Illustrates an illustrative, non-exclusive example of a
hydrogen-processing assembly 10 from a slightly different perspective than

schematically illustrated in Fig. 1. That is, Fig. 2 may be described as a schematic
plan view of a cross-section of an illustrative, non-exclusive example of a hydrogen-
processing assembly 10. In Fig. 2, hydrogen-separation assembly 28 is positioned
within internal volume 18 of enclosure 14 in a spaced relation to at least a portion of
internal perimeter 20 of body 16. Hydrogen-separation assembly 28 may be
described as having an outer perimeter 60. For hydrogen-separation assemblies
containing one or more planar, or generally planar, membranes, this outer perimeter
may be described as being measured in, or parallel to, the plane of the membrane(s).
That is, outer perimeter 60 may refer to at least a portion of the generally external
surface of a hydrogen-separation region, hydrogen-separation assembly, or
membrane assembly. Accordingly, in the example schematically illustrated In Fig. 2,
the permeate region 34 may be described as being defined between at least a
portion of the outer perimeter 60 and at least a portion of the internal perimeter 20 of
body 16. In such embodiments, the permeate region Is in direct fluid communication
with the internal perimeter of the body. Stated differently, the permeate stream 48
exits hydrogen-separation region 28 directly into the internal volume 18 of the
enclosure 14.
Various configurations of the relation between hydrogen-separation
assembly 28 and internal perimeter 20 are within the scope of the present disclosure.
For example, and as schematically illustrated in Fig. 2, permeate region 34 may be
defined between an entire outer perimeter (that is, an entire perimeter as viewed
from a specific cross-section but not necessarily the entire outer surface) of
hydrogen-separation assembly 28 and at least a portion of internal perimeter 20 of
enclosure body 16. Additionally or alternatively, the permeate region may be defined
between at least a majority of an outer perimeter of the hydrogen-separation
assembly and at least a portion of the Internal perimeter of the enclosure body. For
example, and as discussed above, in some embodiments, the hydrogen-separation
assembly Is directly or indirectly compressed between portions of the enclosure, and
therefore the portions of the outer perimeter or outer surface of the hydrogen-
separation assembly that are in direct or indirect contact with the enclosure body may
not define a portion of the permeate region. Additionally or alternatively, and as
schematically illustrated in dashed lines in Fig. 2, additional structure 62 may prevent
a portion of the outer perimeter of the hydrogen-separation assembly and a portion of
the internal perimeter of the body from defining the permeate region. In some such
embodiments, the outer perimeter of the hydrogen-separation assembly may be
described as having two generally opposed portions 64, 66, and the permeate region

therefore defined between at least two generally opposed portions 68, 69 of internal
perimeter 20 of body 16 and the two generally opposed portions 64, 66 of outer
perimeter 60 of the hydrogen-separation assembly.
Additionally or alternatively, in embodiments where enclosure 14 includes at
least a first portion and a second portion coupled together to form body 18, the
spaced relation of the hydrogen-separation assembly and at least a portion of
internal perimeter 20 of the enclosure body 16 may be maintained by the
compression between the first and second portions of the body. In other words, to
maintain the spaced relation between the hydrogen-separation assembly and the
enclosure body, hydrogen-processing assembly 10 may be assembled so that the
compression between the body portions generally prevents the hydrogen-separation
assembly from moving within the enclosure relative to the body.
Figs. 3 and 4 schematically illustrate non-exclusive examples of membrane
assemblies 30 that may be used in hydrogen-processing assemblies according to the
present disclosure. In some embodiments, membrane assemblies 30 may form at
least a portion of a hydrogen-separation assembly 28. As schematically illustrated in
Figs. 3 and 4, membrane assemblies 30 may (but are not required to) be generally
planar. That is, the membrane assemblies may have generally parallel opposing
sides. Similarly, hydrogen-separation assemblies, which may include one or more
membrane assemblies, may likewise (but are not required to) be generally planar.
Membrane assemblies, and thus hydrogen-separation assemblies, according to the
present disclosure include at least one hydrogen-selective membrane 54 and at least
one harvesting region 78 that is adjacent to the permeate surface 58 of the at least
one hydrogen-selective membrane. The harvesting region of a membrane assembly
is a conduit, channel, or other region through which the permeate stream 48 travels,
or flows, from the permeate surface 58 of the membrane to the permeate region of
the internal volume.
In some embodiments, the harvesting region may be in direct fluid
communication with the permeate region of the enclosure's internal volume, and thus
also in direct fluid communication with the internal perimeter of the enclosure. In such
an embodiment, the permeate gas stream flows directly from the harvesting region,
which is at least substantially (if not completely) coextensive with the one or more
hydrogen-selective membranes of the hydrogen-separation assembly, into the
permeate region (which is exterior of the hydrogen-separation assembly) without
flowing through a series of gasket-defined and/or manifold-defined flow passages.

The permeate stream may, in such an embodiment, exit the membrane
assembly and/or the hydrogen-separation assembly in a direction that is generally
parallel to the membrane, membrane assembly, and/or hydrogen-separation
assembly. Stated differently, in some embodiments, the hydrogen-separation
assembly may be configured so the permeate stream exits the membrane assembly
and/or hydrogen-separation assembly in a direction generally parallel to the
hydrogen-selective assembly. In some embodiments, the hydrogen-selective
assembly may be configured to minimize the flow path, or length, through which the
permeate gas must travel through the harvesting conduit membrane assembly
Additionally or alternatively, in some embodiments, the hydrogen-separation
assembly may be configured so the permeate stream exits the hydrogen-separation
assembly in a direction generally parallel to the plane of the hydrogen-selective
membrane. Additionally or alternatively, the hydrogen-separation assembly may be
adapted to receive the mixed gas stream 40 from a first direction and configured so
the permeate stream exits the hydrogen-separation assembly in a second direction
generally perpendicular to the first direction. Additionally or alternatively, the
hydrogen-separation assembly may be configured so the permeate stream flows
from the permeate surface to the permeate region in a direction generally parallel to
the permeate surface of the membrane(s). Additionally or alternatively, the hydrogen-
separation assembly may be configured so the permeate stream flows through the
harvesting region in a direction that is generally parallel to the plane of the at least
one hydrogen-selective membrane.
Some membrane assemblies according to the present disclosure may not
include permeate gaskets that assist in forming gas seals about the periphery of the
permeate surface of the hydrogen-selective membranes and adjacent structure. That
is, such membrane assemblies according to the present disclosure may not include
gaskets that provide seals around the entire perimeter of the permeate surface of
hydrogen-selective membranes. The absence of a permeate gasket or other
continuous seal associated with the permeate surface of a hydrogen-selective
membrane may provide greater hydrogen separation and longer membrane life than
some other configurations for membrane-based separation assemblies. The absence
of the permeate gasket may reduce the likelihood of wrinkles, creases, or other
forces on the hydrogen-selective membranes, such as responsive to thermal cycling
of the membranes. This thermal cycling, and the resultant forces upon the
membranes, may have a greater likelihood of causing holes, cracks, and/or leak
paths to form in the membranes when permeate gaskets are used.

Harvesting region 78 may be defined by various structure(s) incorporated into
a membrane assembly 30 or hydrogen-separation assembly 28 to support the
membrane(s) such that the permeate surface(s) of the membrane(s) are supported in
a manner that permits gas that passes through the membrane to be collected and
extracted to form the permeate gas stream. For example, the harvesting region may
be defined by a support, such as a screen structure 80 that includes at least one
screen. Screen structure 80 may (but is not required to) include a plurality of screen
members including screen members of varying coarseness. For example, screen
structure 80 may include a coarse mesh screen sandwiched between fine mesh
screens, where the terms "fine" and "coarse" are relative terms. In some
embodiments, the outer screen members are selected to support membranes 54
without piercing the membranes and without having sufficient apertures, edges or
other projections that may pierce, weaken or otherwise damage the membrane under
the operating conditions with which assembly 10 is operated. Some embodiments of
screen structure 80 may use a relatively coarser inner screen member to provide for
enhanced, or larger, parallel flow conduits, although this is not required to all
embodiments. In other words, the finer mesh screens may provide better protection
for the membranes, while the coarser mesh screen(s) may provide better flow
generally parallel to the membranes, and in some embodiments may be selected to
be stiffer, or less flexible, than the finer mesh screens.
Additionally or alternatively, membrane assemblies may incorporate screen
structure 80 directly adjacent the permeate surface of a hydrogen-selective
membrane. In other words, membrane assemblies 30, and thus hydrogen-separation
assemblies 28, may be constructed without a gasket directly adjacent the permeate
surface of the membrane. Stated differently, in some embodiments, hydrogen-
separation assemblies do not include a gasket between the permeate surface and
the adjacent screen or other support structure.
The membrane assemblies that are schematically illustrated in Figs. 3 and 4
may be described as having harvesting regions 78 that are generally parallel to the at
least one hydrogen-selective membrane 54. Additionally or alternatively, the
harvesting region may be described as being generally coextensive with the at least
one hydrogen-selective membrane.
The non-exclusive example of a membrane assembly 30 illustrated in Fig. 3
includes only a single hydrogen-selective membrane, and may be referred to as a
single-membrane assembly 88. Single-membrane assembly 88 includes a harvesting
region 78 defined between the permeate surface 58 of the membrane and a barrier

structure 82. Barrier structure 82 may be any suitable structure that includes a
surface 84 generally opposed to the permeate surface 58 of membrane 54 and
through which gas that permeates into the harvesting conduit does not pass. Instead,
the barrier structure, which is generally opposed to the permeate surface of
membrane 54 and spaced apart therefrom, defines a boundary that redirects the flow
of permeate gas along the harvesting conduit.' As illustrative, non-exclusive
examples, barrier structure 82 may be a plate or other structure incorporated into a
hydrogen-separation assembly. Additionally or alternatively, barrier structure 82 may
be a wall of an enclosure, or other component, of a hydrogen-processing assembly
according to the present disclosure. Any suitable structure that defines harvesting
conduit 78 between itself and a hydrogen-selective membrane is within the scope of
the present disclosure.
As schematically illustrated in Fig. 4, membrane assemblies (and thus
hydrogen-separation assemblies) according to the present disclosure may include a
plurality of hydrogen-selective membranes. The non-exclusive example of a
membrane assembly 30 illustrated in Fig. 4 includes a pair of hydrogen-selective
membranes 54, and may be referred to as a double-membrane assembly 90. In
double-membrane assembly 90, the respective permeate surfaces 58 generally face
each other and are spaced apart to define a harvesting region 78 through which the
permeate stream flows to the permeate region of the internal volume of the
enclosure. As discussed above, membrane assemblies 30, and thus double-
membrane assemblies 90, may (but are not required to) include a screen
structure 80 that defines the harvesting conduit. Stated differently, screen
structure 80 may be generally coextensive with the spaced apart opposing permeate
surfaces of a pair of hydrogen-selective membranes.
Additionally or alternatively, and as schematically illustrated in Figs. 3 and 4,
membrane assemblies 30 (and thus hydrogen-separation assemblies 28) according
to the present disclosure may include suitable alternative support structure 86 that is
configured to define a harvesting conduit. For example, support structure 86 may
include a gasket or other spacer that generally creates a channel, conduit, or other
suitable region adjacent the permeate surface(s) of one or more hydrogen-selective
membranes. Stated differently, suitable support structure 86 may be configured to
space a hydrogen-selective membrane away from either a corresponding hydrogen-
selective membrane, as in a double-membrane assembly 90, or away from a suitable
barrier structure 82, as in a single-membrane assembly 88, to define a channel,
conduit, or other region therebetween that defines a harvesting region for the flow of

a permeate stream from the one or more membranes to the permeate region of a
hydrogen-processing assembly.
Additionally or alternatively, hydrogen-separation assemblies according to the
present disclosure may include more than one membrane assembly. Such assembly
of multiple membrane assemblies may be described as membrane assemblies
themselves or as hydrogen-separation assemblies. In some embodiments, a
hydrogen-separation assembly may include membrane assemblies having various
configurations. For example, a non-exclusive example of a hydrogen-separation
assembly according to the present disclosure may include a single-membrane
assembly 88 adjacent a double-membrane assembly 90. In such a configuration, the
hydrogen-separation assembly may be described as including a plurality of spaced
apart hydrogen-selective membranes including a pair of membranes with their
respective permeate surfaces generally facing each other and spaced apart to define
a harvesting region. The plurality of membranes may further include at least a third
membrane with its mixed gas surface generally facing and spaced apart from the
mixed gas surface of one of the membranes of the pair of membranes. In such a
configuration, the space defined between the two mixed gas surfaces may define at
least a portion of the mixed gas region of the enclosure of a hydrogen-processing
assembly according to the present disclosure. Illustrative, non-exclusive examples of
hydrogen-separation assemblies including these characteristics are illustrated in
Figs. 8 and 11 and are described in greater detail below.
Figs. 5-11 illustrate various illustrative non-exclusive examples of
embodiments of hydrogen-processing assemblies 10, and components thereof,
according to the present disclosure. Assemblies 10 according to the present
disclosure, while illustrated in Figs. 5-11 with like numerals corresponding to the
various components and portions thereof, etc. introduced above, are not limited to
such illustrated configurations. For example, the shape, number, and location of
various components, including, but not limited to, the input and output ports, the
hydrogen-separation assembly, membrane assemblies within the hydrogen-
separation assembly, the hydrogen-producing region (if any), etc. are not limited to
the configurations illustrated. Illustrative, non-exclusive examples of enclosures
having various shapes and configurations differing from those illustrated herein, and
which may be used and/or modified to be used for hydrogen-processing assemblies
according to the present disclosure are disclosed in U.S. Patent Nos. 6,494,937,
6.569.227. 6.723.156. and 6719.832. and U.S. Patent Application Serial

Nos. 11/263,726, and 11/638,076, the entire disclosures of which are hereby
incorporated by reference for all purposes.
In Fig. 5, an example of a suitable construction for a hydrogen-processing
assembly 10 that does not include a hydrogen-producing region is shown in an
unassembled, exploded condition, and is generally indicated at 100. As shown in
Fig. 5, the enclosure of assembly 100 includes a first body portion 22 and a second
body portion 24. During assembly of assembly 100, hydrogen-separation
assembly 28 is positioned in internal volume 16 so that the permeate region is
defined between at least a portion of the perimeter 60 of the hydrogen-separation
assembly and at least a portion of the inside perimeter 20 of the first body portion 22.
In other words, the hydrogen-separation assembly is placed within the internal
volume of the first body portion 16 so that it is in a spaced relation to the internal
perimeter of the first body portion to define a permeate region therebetween. Then,
the second body portion 24 is positioned at least partially within the opening to the
first body portion 22 to compress the hydrogen-separation assembly within the
internal volume. A seal weld or other suitable sealing mechanism or structure may
then be applied at the interface of the body portions to create a fluid-tight interface.
As discussed, it is within the scope of the present disclosure that any suitable
retention mechanism may be used to provide a fluid-tight interface between the body
portions of the enclosure and to further provide a suitable amount of compression to
the hydrogen-separation assembly within the enclosure, such as to provide and/or
maintain internal seals and/or flow paths between and/or within the various
components of the hydrogen-separation assembly.
The non-exclusive illustrative example of enclosure 14 shown in Fig. 5 further
includes an input port 36 for receiving a mixed gas stream for delivery to the mixed
gas region of the internal volume, a product output port 46 for removal of the
hydrogen-rich permeate stream, and a byproduct output port 50 for removal of
byproduct gases.
The non-exclusive illustrative example of a hydrogen-separation assembly 28
illustrated in Fig. 5 may be described as generally planar, and as schematically
illustrated by the multiple arrows extending from the top and bottom (as viewed in
Fig. 5) of the hydrogen-separation assembly, the hydrogen-rich, or permeate, stream
exits the hydrogen-separation assembly in a direction generally parallel to the plane
of the hydrogen-separation assembly. Stated differently, the permeate stream exits
the hydrogen-separation assembly and enters the permeate region of the internal
volume from a direction generally parallel to the plane of the hydrogen-separation

assembly and the hydrogen-selective membranes located therein. The hydrogen-
separation assembly illustrated in Fig. 5 includes gas distribution conduits 140
and 170, which define at least portions of the mixed gas region and which provide
flow paths for the mixed gas and byproduct streams, respectively, through the
hydrogen-separation assembly. In other words, the mixed gas stream enters the
enclosure via inlet 36. The portion of the mixed gas stream that does not pass
through the hydrogen-selective membranes (that is, the byproduct stream 52) is
forced into distribution conduit 170 and then out byproduct outlet port 50. The portion
of the mixed gas stream that does pass through the hydrogen-selective membranes
forms permeate stream 48, which is forced into the permeate region of the internal
volume and subsequently expelled from the enclosure via product output port 46.
Enclosure 14 is also illustrated as including optional mounts 150, which may
be used to position the enclosure 14 with respect to other components of a hydrogen
generation system and/or fuel cell system, etc.
As shown in Figs. 5-7, first body portion 22 may include at least one
projection, or guide, 146 that extends into internal volume 16 to align or otherwise
position the hydrogen-separation region within the internal volume of the enclosure.
In Fig. 5, two pairs of guides 146 are illustrated, but it is within the scope of the
present disclosure that no guides, one guide, or any number of guides may be
utilized. When more than one guide is utilized, the guides may have the same or
different sizes, shapes, and/or relative orientations within the enclosure.
As also shown in Figs. 5-7, hydrogen-separation assembly 28 may include
recesses 152 that are sized to receive the guides 146 of the body portion when the
membrane assembly is inserted into internal volume 16. Stated differently, the
recesses on the hydrogen-separation assembly are designed to align with the guides
that extend into the enclosure's internal volume to position the hydrogen-separation
assembly in a selected orientation within the compartment. Accordingly, the first body
portion may be described as providing alignment guides for the hydrogen-separation
assembly. In Fig. 5, it can be seen that second body portion 24 may also include
recesses 152. Recesses 152 may guide, or align, the first and second portions when
the portions are assembled to form the enclosure. The illustrated guides and
recesses are not required to all enclosures and/or hydrogen-separation assemblies
and/or components thereof according to the present disclosure.
As discussed and as somewhat schematically illustrated in Figs. 6-7, at least
a portion of the perimeter 60 of the hydrogen-separation assembly 28 does not seal
against at least a portion of the internal perimeter 20 of the internal volume. Instead,

a gas passage, or channel 176 exists between hydrogen-separation assembly 28
and the internal perimeter 20 to form at least a portion of the permeate region 34 of
the internal volume. The size of passage 176 may vary within the scope of the
present disclosure, and may be smaller than is depicted for the purpose of
illustration. The hydrogen-rich gas, or permeate stream, may flow through this
passage and be withdrawn from the enclosure through the product output port.
As illustrated in Fig. 6, hydrogen-separation assemblies 28 according to the
present disclosure may (but are not required to) include spacers, or protrusions, 124
that extend from at least a portion of the outside perimeter 60 and aid in positioning
the hydrogen-separation assembly within the enclosure in its spaced relation as
described herein. For example, in the illustrated example, spacers 124 may be
generally trapezoidal in shape and may extend from one or more of the various
components that make up a hydrogen-separation assembly, although any suitable
shape is within the scope of the present disclosure. In some embodiments,
spacers 124 may extend from one or more of the feed plates and/or sealing plates
that may be incorporated into a hydrogen-separation assembly. In some such
embodiments, the spacers may be (but are not require to be) less than the full
thickness of the associated plate. When used, spacers 124 do not extend across the
entire thickness of the hydrogen-separation assembly so that they do not block the
flow of permeate gas within the permeate region 34. The spacers extend from the
hydrogen-separation assembly to, or toward, the inside perimeter of the internal
enclosure, and in some embodiments may extend into contact with the internal
enclosure.
Additionally or alternatively, spacers that extend from the Inside perimeter 20
of the internal enclosure are equally within the scope of the present disclosure, and
like spacers 124 may aid in the positioning of the hydrogen-separation assembly
within the enclosure and thereby maintain the spaced relation between the two. Any
suitable mechanism, component, and/or structure for maintaining the spaced relation
between at least a portion of the outer perimeter of the hydrogen-separation
assembly and the inside perimeter of the body of the enclosure is within the scope of
the present disclosure.
An optional groove 126 may extend into the first body portion 22 of the
enclosure, as illustrated in Fig. 6. Groove 126 may effectively enlarge the permeate
region 34 and thereby aid in the flow of the permeate gas through gas passage 176
> and thus permeate region 34 to the product output port 46 by increasing the space
between at least a portion of the outer perimeter of the hydrogen-separation

assembly and at least a portion of the inside perimeter of the body. The groove,
when present, may be described as defining at least a portion of a permeate gas
passage through which permeate gas flows from the hydrogen-separation assembly
to the product output port. As mentioned above, the relative size of the channel 176,
and further the groove 126, may vary within the scope of the present disclosure from
that depicted in Fig. 6 for the purpose of illustration.
As illustrated in Figs. 5-11, and as perhaps best seen in Fig. 7, the various
plates and gaskets that form a hydrogen-separation assembly according to the
present disclosure, may be sized with asymmetrical shapes so that these
components may only be located in the enclosure in a predetermined configuration.
This is not required, but it may assist in assembly of the components because they
cannot be inadvertently positioned in the housing in a backwards or upside-down
configuration. In the Illustrative, non-exclusive example of a suitable asymmetrical
shape, a corner region 128 of the hydrogen-separation assembly has a different
shape than the other comer regions, with this difference being sufficient to permit that
corner to be only inserted into one of the corresponding corner regions of the
enclosure's internal volume. The non-exclusive example illustrated in Fig. 7
incorporates a more squared-off corner than the other three corners of the hydrogen-
separation assemblies illustrated herein, although any suitable shape of one or more
corner regions that facilitate proper positioning of the hydrogen-separation, assembly
within an enclosure are within the scope of the present disclosure. Additionally or
alternatively, regions other than the corner regions may facilitate the same
functionality. Accordingly, some enclosures according to the present disclosure may
be described as being keyed, or indexed, to define the orientation of the gaskets,
frames, supports and similar components that are stacked therein.
As also best illustrated in Fig. 7, some hydrogen-separation assemblies and
enclosures according to the present disclosure may be configured so that the spaced
relation between the two does not extend around the entire perimeters thereof. For
example, and as illustrated in Fig. 7, the components that define a hydrogen-
separation assembly and/or other components that may be housed within an
enclosure according to the present disclosure may include an end region 130 that is
shaped so as to not provide (or to at least minimally provide) a channel or space
between the end region 130 and the inside perimeter 20 of the enclosure body. Such
a configuration, together with the optional spacers 124 discussed above and
illustrated in Fig. 6, may thereby aid in the positioning and maintaining of the
hydrogen-separation assembly (and/or other components) In a spaced relation to the

inside perimeter of the body of the enclosure. Additionally or alternatively, such a
configuration may aid in the directing of the permeate gas that enters the
channel 176 from the harvesting regions of the membrane assemblies to the product
output port of the enclosure. That is, because the hydrogen purification process
according of the present disclosure is a pressure driven process, reducing the
distance required that the permeate gas has to travel to exit the enclosure reduces
the pressure drop associated therewith and thereby may provide for greater
hydrogen flux, as discussed above.
In Fig. 8, an illustrative, non-exclusive example of a suitable construction for a
hydrogen-processing assembly 10 that includes a hydrogen-producing region 70 is
shown in an unassembled, exploded condition, and is generally indicated at 120.
Accordingly, in addition to the various components (and variants thereof) discussed
above in regards to hydrogen-processing assembly 100 in Fig. 5, the hydrogen-
processing assembly 120 illustrated in Fig. 7 further includes an input port 36 for
receiving a feed stream 38 for delivery to hydrogen-producing region 70, and an
access port 122 for loading and removing catalyst from the hydrogen-producing
region. Assemblies. 120 according to the present disclosure are not required to
include a catalyst access port. During use of illustrated assembly 120 to produce
and/or purify hydrogen gas, access port 122 may be capped off or otherwise sealed.
In Fig. 8, the second body portion 24 of assembly 120 is shown including an
optional protrusion 123 that aligns generally with gas distribution conduit 140, and
thereby may aid in the positioning of the hydrogen-separation assembly within the
enclosure, in applying compression to the gas distribution conduits, and/or in
maintaining the spaced relation between the hydrogen-separation assembly and the
inside perimeter of the enclosure body. Second portion 24 may include more than
one protrusion, or projecting rib, such as is illustrated in dashed lines at 123 to align
generally with gas distribution conduit 170. In embodiments incorporating a
protrusion 123, the protrusion may be configured to extend only far enough into the
internal volume to properly align with the hydrogen-separation assembly and not
prevent the flow of mixed-gas through conduit 140 to and/or from the membrane
assemblies and/or other components.
An illustrative, non-exclusive example of a suitable construction for a
hydrogen-separation assembly 28 that may be used in either hydrogen-processing
assembly 100 or 120 is shown in Fig. 9 and indicated at 154. As illustrated,
assembly 154 includes a plurality of membrane assemblies 30 that include hydrogen-
selective membranes 54. The illustrated assembly 28 includes a single-membrane

assembly 88 and a double-membrane assembly 90. Also shown are various porous
membrane supports, or screens, 162, that define the harvesting regions of the
membrane assemblies. Membrane assemblies 30 include sealing gaskets 168 that
extend proximate the membranes and screens, but not around the perimeters of the
membranes and screens, to provide seals for the gas distribution conduits 140,170.
Various sealing gaskets 202, 204, 206, 208, 210, and 212, feed plates 214,
216, and sealing plate 218 are also provided. Plate 218 may also be referred to as a
transition plate. In the illustrated example, the mixed gas region of the internal
volume is at least partially defined by the internal spaces of the various sealing
gaskets and feed plates and by the gas distribution conduits 140 and 170.
Accordingly, in application, a mixed gas stream enters the mixed gas region via the
internal space of sealing gasket 212. A portion of the mixed gas stream then travels
into the conduit 140 via feed plate 216 to be distributed to the single-membrane
assembly 88 and the near side (as viewed in Fig. 9) of the double-membrane
assembly 90 to come into contact with the mixed gas surfaces of the hydrogen-
selective membranes 54 via the feed plate 214 and sealing gaskets 204, 208, 210.
The portion of the mixed gas stream that is not distributed via the gas conduit 170
travels through feed passage 215 in feed plate 216 to come into contact with the
mixed gas surface of the far (as viewed in Fig. ,9) hydrogen-selective membrane of
double-membrane assembly 90. The portion of the mixed gas stream that does not
pass through the hydrogen-selective membranes is pressure driven into gas
conduit 170 via feed plate 214 to be expelled from the enclosure via the byproduct
output port.
The portion of the mixed gas stream that does pass through the hydrogen-
selective membranes to form the hydrogen-rich, or permeate, stream flows into the
permeate region of the internal volume via screens 162 of membrane assemblies 30.
Thereafter the permeate stream may be removed from the enclosure through the
product output port.
Also illustrated in Fig. 9 are an optional catalyst retention plate 160 and
sealing gasket 166 that may be used in hydrogen-processing assemblies according
to the present disclosure that include a hydrogen-producing region 70, such as
hydrogen-processing assembly 120 shown in Fig. 8 and discussed above. In
application, the catalyst retention plate 160 retains the catalyst material within the
hydrogen-producing region. Feed stream 38 enters hydrogen-producing region 70 via
input port 36, and percolates through the catalyst material to form the mixed gas
stream, which in the illustrated example of Fig. 9, enters the mixed gas region via

slits or other apertures 167 in the retention plate. The mixed gas then travels through
the hydrogen-separation assembly, as discussed above, to form both the permeate
stream and the byproduct stream.
In Fig. 10, another illustrative, non-exclusive example of a suitable
construction for a hydrogen-processing assembly 10 that does not include a
hydrogen-producing region is shown in an unassembled, exploded condition, and is
generally indicated at 180. Assembly 180 includes an optional hydrogen-polishing
region 182 that further purifies the permeate stream subsequent to being formed by
the hydrogen-separation assembly 28. In the illustrated example, the hydrogen-
polishing region incorporates a methanation catalyst, or methanation catalyst
bed, 185 within the enclosure and held in place between a catalyst support plate 184,
which may take the form of a compressible pad or support, and the inside surface of
the enclosure adjacent the product output port 46. As illustrated, an additional
support plate 186, which may take the form of a screen, may also be provided to
generally prevent the catalyst material from being expunged through the product
output port along with the purified hydrogen. Accordingly, plate 186 may include one
or more apertures, or holes, that permit the purified hydrogen to pass, while retaining
the catalyst bed within the polishing region 182. In the illustrated example of Fig. 10,
the permeate stream, upon exiting the hydrogen-separation assembly, enters the
permeate region defined by the outer perimeter 60 of the hydrogen-separation
assembly and the inside perimeter 20 of the enclosure body, and is pressure driven
into the hydrogen-polishing region, where, as described in more detail herein,
compositions that may be harmful to downstream components of a fuel cell system,
such as carbon monoxide for example, may be removed by the catalyst bed.
An illustrative, non-exclusive example of a suitable construction for a
hydrogen-separation assembly 28 that may be used in hydrogen-processing
assembly 180 is shown in Fig. 11, and indicated at 188. Like hydrogen-separation
assembly 154 illustrated in Fig. 9, assembly 188 includes a plurality of membrane
assemblies 30 that include hydrogen-selective membranes 54. Assembly 188
includes a single-membrane assembly 88 and a double-membrane assembly 90,
both including porous membrane supports, or screens, 162, that define the
harvesting regions of the membrane assemblies. As discussed, the number and type
of membrane assemblies in separation assemblies according to the present
disclosure may vary, including more or less membrane assemblies than are shown in
the illustrated graphical examples. The membrane assemblies shown in Fig. 11
further include sealing gaskets 168 that extend proximate the membranes and

screens, but not around the perimeters of the membranes and screens, to provide
seals for the gas distribution conduits 190,192,194 that define a portion of the mixed
gas region of the assembly.
Various sealing gaskets 402, 404, 406, 408, 410, and 412, feed plates 414,
416, and sealing plate, or transition feed plate, 418 are also provided. In the
illustrated example, the mixed gas region of the internal volume is at least partially
defined by the internal spaces of the various sealing gaskets and feed plates and by
the gas distribution conduits 190, 192, and 194. As indicated, sealing plate 418 does
not include a conduit passage on one end, thereby effectively separating gas
conduits 190 and 194. Accordingly, in application, a mixed gas stream first enters the
mixed gas region through gas conduit 190. The mixed gas stream then travels into
the internal space of gasket 404 via feed passages 215 in feed plate 414, where it
comes into contact with the mixed gas surface of the near (as viewed in Fig. 11)
hydrogen-selective membrane 54 of the double-membrane assembly 90. The portion
of the mixed gas stream that does not pass through the near membrane, travels into
gas conduit 192 via feed plate 414 where it is then distributed to the internal space of
gaskets 406, 408, 410, and sealing plate 418 to come into contact with the mixed gas
surface of the far (as viewed in Fig. 11) membrane 54 of double-membrane
assembly 90 and the membrane 54 of the single-membrane assembly 88. The
portion of the mixed gas stream that does not pass through any of the membranes 54
is pressure driven into gas conduit 194 via feed plate 416 to be expelled from the
enclosure as a byproduct stream via the byproduct output port of the enclosure.
The portion of the mixed gas stream that does pass through the hydrogen-
selective membranes to form the hydrogen-rich or permeate stream, flows into the
permeate region of the internal volume via screens 162 of membrane assemblies 30.
Thereafter the permeate stream may be removed from the enclosure through the
product output port. As discussed above, when hydrogen-separation assembly 188 is
incorporated into hydrogen-processing assembly 180 illustrated in Fig. 10, the
permeate stream is further purified in the hydrogen-polishing region, prior to exiting
the enclosure via product output port 46.
During fabrication of the membrane assemblies and hydrogen-separation
assemblies 28 of the present disclosure, adhesive may (but is not required to) be
used to secure the membranes 54 to the screen structures 162 and/or to secure the
components of the screen structures, as discussed in more detail in U.S. Patent
No. 6,319,306, the entire disclosure of which is hereby incorporated for all purposes.
An example of a suitable adhesive is sold by 3M under the trade name SUPER 77.

The adhesive may be at least substantially, if not completely, removed after
fabrication of the membrane assembly so as not to interfere with the permeability,
selectivity and flow paths of the gases. An example of a suitable method for removing
adhesive from the membranes and/or screen structures or other supports is by
exposure to oxidizing conditions prior to initial operation of assembly 10. The
objective of the oxidative conditioning is to burn out the adhesive without excessively
oxidizing the membrane. A suitable procedure for such oxidizing is disclosed in U.S.
Patent No. 6,319,306.
It is also within the scope of the present disclosure that the screen members,
when utilized, may be otherwise secured together, such as by sintering, welding,
brazing, diffusion bonding and/or with a mechanical fastener. It is also within the
scope of the present disclosure that the screen members, when utilized, may not be
coupled together other than by being compressed together in the hydrogen-
separation assembly of a hydrogen-processing assembly. Screens 162 may (but are
not required to) include a coating on the surfaces that engage the permeate surfaces
of membranes 54. Examples of suitable coatings are disclosed in U.S. Patent
No. 6,569,227, incorporated above.
Other examples of attachment mechanisms that achieve gas-tight seals
between the various components forming membrane assemblies 30 and hydrogen-
separation assemblies 28 include one or more of brazing, gasketing, and welding.
It is within the scope of the present disclosure that the various gaskets,
plates, and/or other components of membrane assemblies and/or hydrogen-
separation assemblies discussed herein do not all need to be formed from the same
materials and/or do not necessarily have the same dimensions, such as the same
thicknesses. For example, illustrative, non-exclusive examples of suitable gaskets
that may be used are flexible graphite gaskets, including those sold under the trade
name GRAFOIL™ by Union Carbide, although other materials may be used, such as
depending upon the operating conditions under which an assembly 10 is used.
Various structural components may be formed from stainless steel or one or more
other suitable structural materials discussed in the above-incorporated patents and
applications.
An illustrative, non-exclusive example of a hydrogen-processing assembly 10
that is adapted to receive mixed gas stream 40 from a source of hydrogen gas to be
purified is schematically illustrated in Fig. 12. As shown, illustrative, non-exclusive
examples of hydrogen sources are indicated generally at 302 and include a
hydrogen-producing fuel processor 300 and a hydrogen storage device 306. In

Fig. 12, a fuel processor is generally indicated at 300, and the combination of a fuel
processor and a hydrogen-purification device, or hydrogen-processing assembly 10,
may be referred to as a hydrogen-producing fuel-processing system 303. Also shown
in dashed lines at 304 is a heating assembly, which may be provided to provide heat
to assembly 10 and may take a variety of forms. Fuel processor 300 may take any
suitable form including, but not limited to, the various forms of hydrogen-producing
region 70 discussed above. The schematic representation of fuel processor 300 in
Fig. 12 is meant to include any associated heating assemblies, feedstock delivery
systems, air delivery systems, feed stream sources or supplies, etc. Illustrative, non-
exclusive examples of suitable hydrogen storage devices 306 include hydride beds
and pressurized tanks.
Fuel processors are often operated at elevated temperatures and/or
pressures. As a result, it may be desirable to at least partially integrate hydrogen-
processing assembly 10 with fuel processor 300, as opposed to having assembly 10
and fuel processor 300 connected by external fluid transportation conduits. An
example of such a configuration is shown in Fig. 13, in which the fuel processor
includes a shell or housing 312, which device 10 forms a portion of and/or extends at
least partially within. In such a configuration, fuel processor 300 may be described as
including device 10. Integrating the fuel processor or other source of mixed gas
stream 40 with hydrogen-processing assembly 10 enables the devices to be more
easily moved as a unit. It also enables the fuel processing system's components,
including assembly 10, to be heated by a common heating assembly and/or for at
least some, if not all, of the heating requirements of assembly 10 to be satisfied by
heat generated by processor 300.
As discussed, fuel processor 300 is any suitable device that produces a
mixed gas stream containing hydrogen gas, and preferably a mixed gas stream that
contains a majority of hydrogen gas. For purposes of illustration, the following
discussion will describe fuel processor 300 as being adapted to receive a feed
stream 316 containing a carbon-containing feedstock 318 and water 320, as shown
in Fig. 14. However, it is within the scope of the present disclosure that the fuel
processor 300 may take other forms, and that feed stream 316 may have other
compositions, such as containing only a carbon-containing feedstock or only water.
Feed stream 316 may be delivered to fuel processor 300 via any suitable
mechanism. A single feed stream 316 is shown in Fig. 14, but it should be
understood that more than one stream 316 may be used and that these streams may
contain the same or different components. When the carbon-containing

feedstock 318 is miscible with water, the feedstock may be delivered with the water
component of feed stream 316, such as shown in Fig. 14. When the carbon-
containing feedstock is immiscible or only slightly miscible with water, these
components may be delivered to fuel processor 300 in separate streams, such as
shown in dashed lines in Fig. 14. In Fig. 14, feed stream 316 is shown being
delivered to fuel processor 300 by a feed stream delivery system 317. Delivery
system 317 includes any suitable mechanism, device, or combination thereof that
delivers the feed stream to fuel processor 300. For example, the delivery system may
include one or more pumps that deliver the components of stream 316 from a supply.
Additionally or alternatively, delivery system 317 may include a valve assembly
adapted to regulate the flow of the components from a pressurized supply. The
supplies may be located external the fuel cell system, or may be contained within or
adjacent the system.
As generally indicated at 332 in Fig. 14, fuel processor 300 includes a
hydrogen-producing region in which mixed gas stream 40 is produced from feed
stream 316. As discussed, a variety of different processes may be utilized in the
hydrogen-producing region. An example of such a process is steam reforming, in
which region 332 includes a steam reforming catalyst 334. As discussed, other
hydrogen-producing mechanisms may be utilized without departing from the scope of
the present disclosure. As discussed, in the context of a steam or autothermal
reformer, mixed gas stream 40 may also be referred to as a reformate stream. The
fuel processor may be adapted to produce substantially pure hydrogen gas, or even
pure hydrogen gas. For the purposes of the present disclosure, substantially pure
hydrogen gas may be greater than 90% pure, greater than 95% pure, greater
than 99% pure, greater than 99.5% pure, or greater than 99.9% pure. Illustrative,
non-exclusive examples of suitable fuel processors are disclosed in U.S. Patent
Nos. 6,221,117 and 6,319,306, incorporated above, and U.S. Patent Application
Publication No. 2001/0045061, the complete disclosure of which is hereby
incorporated by reference In its entirety for all purposes.
Fuel processor 300 may, but does not necessarily, further include a polishing
region 348, such as shown in Fig. 14. Polishing region 348 receives hydrogen-rich
stream 48 from assembly 10 and further purifies the stream by reducing the
concentration of, or removing, selected compositions therein. In Fig. 14, the resulting
stream is indicated at 314 and may be referred to as a product hydrogen stream or
purified hydrogen stream. When fuel processor 300 does not include polishing
region 348, hydrogen-rich stream 48 forms product hydrogen stream 314. For

example, when stream 48 is intended for use in a fuel cell stack, compositions that
may damage the fuel cell stack, such as carbon monoxide and carbon dioxide, may
be removed from the hydrogen-rich stream, if necessary. The concentration of
carbon monoxide may be less than 10 ppm (parts per million) to prevent the control
system from isolating the fuel cell stack. For example, the system may limit the
concentration of carbon monoxide to less than 5 ppm, or even less than 1 ppm. The
concentration of carbon dioxide may be greater than that of carbon monoxide. For
example, concentrations of less than 25% carbon dioxide may be acceptable. For
example, the concentration of carbon dioxide may be less than 10%, or even less
than 1%. Concentrations of carbon dioxide may be less than 50 ppm. It should be
understood that the concentrations presented herein are illustrative examples, and
that concentrations other than those presented herein may be used and are within
the scope of the present disclosure. For example, particular users or manufacturers
may require minimum or maximum concentration levels or ranges that are different
than those identified herein.
Region 348 includes any suitable structure for removing or reducing the
concentration of the selected compositions in stream 48. For example, when the
product stream is intended for use in a proton exchange membrane (PEM) fuel cell
stack or other device that will be damaged if the stream contains more than
determined concentrations of carbon monoxide or carbon dioxide, it may be desirable
to include at least one methanation catalyst bed 350. Bed 350 converts carbon
monoxide and carbon dioxide into methane and water, both of which will not damage
a PEM fuel cell stack. Polishing region 348 may also include another hydrogen-
producing region 352, such as another reforming catalyst bed, to convert any
unreacted feedstock into hydrogen gas. In such an embodiment, the second
reforming catalyst bed may be upstream from the methanation catalyst bed so as not
to reintroduce carbon dioxide or carbon monoxide downstream of the methanation
catalyst bed.
Steam reformers typically operate at temperatures in the range of 200° C and
900° C, and at pressures in the range of 50 psi and 1000 psi, although temperatures
outside of this range are within the scope of the present disclosure, such as
depending upon the particular type and configuration of fuel processor being used.
Any suitable heating mechanism or device may be used to provide this heat, such as
a heater, burner, combustion catalyst, or the like. The heating assembly may be
external the fuel processor or may form a combustion chamber that forms part of the

fuel processor. The fuel for the heating assembly may be provided by the fuel-
processing or fuel cell system, by an external source, or both.
In Fig. 14, fuel processor 300 is shown including a shell 312 in which the
above-described components are contained. Shell 312, which also may be referred
to as a housing, enables the components of the fuel processor to be moved as a unit.
It also protects the components of the fuel processor from damage by providing a
protective enclosure and reduces the heating demand of the fuel processor because
the components of the fuel processor may be heated as a unit. Shell 312 may, but
does not necessarily, include insulating material 333, such as a solid insulating
material, blanket insulating material, or an air-filled cavity. It is within the scope of the
present disclosure, however, that the fuel processor may be formed without a
housing or shell. When fuel processor 300 includes insulating material 333, the
insulating material may be internal the shell, external the shell, or both. When the
insulating material is external a shell containing the above-described reforming,
separation and/or polishing regions, the fuel processor may further include an outer
cover or jacket external the insulation.
It is further within the scope of the present disclosure that one or more of the
components of fuel processor 300 may either extend beyond the shell or be located
external at least shell 312. For example, assembly 10 may extend at least partially
beyond shell 312, as indicated in Fig. 13. As another example, and as schematically
illustrated in Fig. 14, polishing region 348 may be external of shell 312 and/or a
portion of hydrogen-producing region 332 (such as portions of one or more reforming
catalyst beds) may extend beyond the shell.
As indicated above, fuel processor 300 may be adapted to deliver hydrogen-
rich stream 48 or product hydrogen stream 314 to at least one fuel cell stack, which
produces an electric current therefrom. In such a configuration, the fuel processor
and fuel cell stack may be referred to as a fuel cell system. An example of such a
system is schematically illustrated in Fig. 15, in which a fuel cell stack is generally
indicated at 322. The fuel cell stack is adapted to produce an electric current from the
portion of product hydrogen stream 314 delivered thereto. In the illustrated
embodiment, a single fuel processor 300 and a single fuel cell stack 322 are shown
and described, however, more than one of either or both of these components may
be used. It should be understood that these components have been schematically
illustrated and that the fuel cell system may include additional components that are
not specifically illustrated in the figures, such as feed pumps, air delivery systems,
heat exchangers, heating assemblies and the like.

Fuel cell stack 322 contains at least one, and typically multiple, fuel cells 324
that are adapted to produce an electric current from the portion of the product
hydrogen stream 314 delivered thereto. This electric current may be used to satisfy
the energy demands, or applied load, of an associated energy-consuming
device 325. Illustrative examples of devices 325 include, but should not be limited to,
a motor vehicle, recreational vehicle, boat, tools, lights or lighting assemblies,
appliances (such as a household or other appliance), household, signaling or
communication equipment, etc. It should be understood that device 325 is
schematically illustrated in Fig. 15 and is meant to represent one or more devices or
collection of devices that are adapted to draw electric current from the fuel cell
system. A fuel cell stack typically includes multiple fuel cells joined together between
common end plates 323, which contain fluid delivery/removal conduits (not shown).
Examples of suitable fuel cells include PEM fuel cells and alkaline fuel cells. Fuel cell
stack 322 may receive all of product hydrogen stream 314. Some or all of stream 314
may additionally, or alternatively, be delivered, via a suitable conduit, for use in
another hydrogen-consuming process, burned for fuel or heat, or stored for later use.
Industrial Applicability
The present disclosure, including fuel-processing systems, hydrogen-
processing assemblies, fuel cell systems, and components thereof, is applicable to
the fuel-processing and other industries in which hydrogen gas is purified, produced
and/or utilized.
In the event that any of the references that are incorporated by reference
herein define a term in a manner or are otherwise inconsistent with either the non-
incorporated disclosure of the present application or with any of the other
incorporated references, the non-incorporated disclosure of the present application
shall control and the term or terms as used therein only control with respect to the
patent document in which the term or terms are defined.
The disclosure set forth above encompasses multiple distinct inventions with
independent utility. While each of these inventions has been disclosed in a preferred
form or method, the specific alternatives, embodiments, and/or methods thereof as
disclosed and illustrated herein are not to be considered in a limiting sense, as
numerous variations are possible. The present disclosure includes all novel and non-
obvious combinations and subcombinations of the various elements, features,
functions, properties, methods and/or steps disclosed herein. Similarly, where any
disclosure above or claim below recites "a" or "a first" element, step of a method, or
the equivalent thereof, such disclosure or claim should be understood to include one

. or more such elements or steps, neither requiring nor excluding two or more such
elements or steps.
Inventions embodied in various combinations and subcombinations of
features, functions, elements, properties, steps and/or methods may be claimed
through presentation of new claims in a related application. Such new claims,
whether they are directed to a different invention or directed to the same invention,
whether different, broader, narrower, or equal in scope to the original claims, are also
regarded as included within the subject matter of the present disclosure.

CLAIMS;
1. A hydrogen-processing assembly, comprising:
an enclosure, comprising:
a body defining an internal volume and having an internal perimeter,
the internal volume including a mixed gas region and a permeate region;
at least one input port extending through the body and through which
a fluid stream is delivered to the enclosure;
at least one product output port extending through the body and
through which a permeate stream is removed from the permeate region; and
at least one byproduct output port extending through the body and
through which a byproduct stream is removed from the mixed gas region; and
a hydrogen-separation assembly positioned within the internal volume in a
spaced relation to at least a portion of the internal perimeter of the body of the
enclosure, the hydrogen-separation assembly including at least one hydrogen-
selective membrane and having an outer perimeter measured in the plane of the at
least one hydrogen-selective membrane, wherein the hydrogen-separation assembly
is adapted to receive a mixed gas stream containing hydrogen gas and other gases
and to separate the mixed gas stream into the permeate stream and the byproduct
stream, wherein the permeate stream has at least one of a greater concentration of
hydrogen gas and a lower concentration of the other gases than the mixed gas
stream, and further wherein the byproduct stream contains at least a substantial
portion of the other gases;
wherein the permeate region of the internal volume is defined between at
least a portion of the outer perimeter of the hydrogen-separation assembly and at
least a portion of the internal perimeter of the body of the enclosure.

2. The hydrogen-processing assembly of claim 1, wherein the permeate
region is defined between at least a majority of the outer perimeter of the hydrogen-
separation assembly and at least a portion of the internal perimeter of the body of the
enclosure.
3. The hydrogen-processing assembly of claim 1, wherein the permeate
region is in direct fluid communication with the at least a portion of the internal
perimeter of the body of the enclosure.
4. The hydrogen-processing assembly of claim 1,
wherein the outer perimeter of the hydrogen-separation assembly includes
two generally opposed portions; and
wherein the permeate region is defined between at least two portions of the
internal perimeter of the body and the two generally opposed portions of the outer
perimeter of the hydrogen-separation assembly.
5. The hydrogen-processing assembly of claim 1, wherein the hydrogen-
separation assembly includes a plurality of protrusions that extend from the outer
perimeter of the hydrogen-separation assembly toward the internal perimeter of the
enclosure to position the hydrogen-separation assembly within the enclosure.
6. The hydrogen-processing assembly of claim 1, wherein the body of
the enclosure includes at least one internal recess that defines a gas flow passage
for the permeate gas stream.
7. The hydrogen-processing assembly of claim 1, wherein the hydrogen-
separation assembly and the body of the enclosure are keyed to define only one
orientation for the hydrogen-separation assembly within the enclosure.

8. The hydrogen-processing assembly of claim 1,
wherein the body of the enclosure includes a first portion and a second
portion;
wherein the hydrogen-separation assembly is compressed between the first
and second portions; and
wherein the spaced relation of the hydrogen-separation assembly and the at
least a portion of the internal perimeter of the body of the enclosure is maintained by
the compression between the first and second portions of the body.
9. The hydrogen-processing assembly of claim 1,
wherein the fluid stream is the mixed gas stream and is delivered to the mixed
gas region;
wherein the at least one hydrogen-selective membrane includes a first
surface adapted to be contacted by the mixed gas stream and a permeate surface
generally opposed to the first surface; and
wherein the permeate stream is formed from a portion of the mixed gas
stream that passes through the membrane to the permeate region of the internal
volume.

10. The hydrogen-processing assembly of claim 1, further comprising a
hydrogen-producing region positioned within-the enclosure;
wherein the fluid stream is a feed stream and is delivered to the hydrogen-
producing region;
wherein in the hydrogen-producing region, the feed stream is chemically
reacted to produce hydrogen gas therefrom in the form of the mixed gas stream, and
wherein the mixed gas stream is delivered to the mixed gas region of the internal
volume;
wherein the at least one hydrogen-selective membrane includes a first
surface adapted to be contacted by the mixed gas stream and a permeate surface
generally opposed to the first surface; and
wherein the permeate stream is formed from a portion of the mixed gas
stream that passes through the membrane to the permeate region of the internal
volume.
11. The hydrogen-processing assembly of claim 1, wherein the hydrogen-
separation assembly is generally planar and is configured so the permeate stream
exits the hydrogen-separation assembly in a direction generally parallel to the
hydrogen-separation assembly.
12. The hydrogen-processing assembly of claim 1, wherein hydrogen-
separation assembly is configured so the permeate stream exits the hydrogen-
separation assembly in a direction generally parallel to the hydrogen-selective
membrane.

13. The hydrogen-processing assembly of claim 1, wherein the hydrogen-
separation assembly is adapted to receive the mixed gas stream from a first direction
and configured so the permeate stream exits the hydrogen-separation assembly in a
second direction generally perpendicular to the first direction.
14. The hydrogen-processing assembly of claim 1,
wherein the at least one hydrogen-selective membrane includes a first
surface adapted to be contacted by the mixed gas stream and a permeate surface
generally opposed to the first surface;
wherein the permeate stream is formed from a portion of the mixed gas
stream that passes through the membrane to the permeate region of the internal
volume; and
wherein the hydrogen-separation assembly is configured so the permeate
stream flows from the permeate surface to the permeate region in a direction
generally parallel to the permeate surface.

15. The hydrogen-processing assembly of claim 1,
wherein the at least one hydrogen-selective membrane includes a first
surface adapted to be contacted by the mixed gas stream and a permeate surface
generally opposed to the first surface;
wherein the permeate stream is formed from a portion of the mixed gas
stream that passes through the membrane from the first surface to the permeate
surface;
wherein the hydrogen-separation assembly includes at least one harvesting
region that is adjacent to the permeate surface; and
wherein the hydrogen-separation assembly is configured so the permeate
stream flows through the harvesting region in a direction that is generally parallel to
the at least one hydrogen-selective membrane.
16. The hydrogen-processing assembly of claim 15. wherein the
hydrogen-separation assembly includes at least one screen that defines the
harvesting region, and further wherein the hydrogen-separation assembly does not
include a gasket between the permeate surface and the screen.
17. The hydrogen-processing assembly of claim 15, wherein the at least
one harvesting region is generally parallel to the at least one hydrogen-selective
membrane and is generally coextensive with the at least one hydrogen-selective
membrane.
18. The hydrogen-processing assembly of claim 15, wherein the
hydrogen-separation assembly does not include a gasket adjacent to the permeate
surface.

19. The hydrogen-processing assembly of claim 1, wherein the hydrogen-
separation assembly includes a plurality of spaced-apart hydrogen-selective
membranes, each membrane having a first surface adapted to be contacted by at
least a portion of the mixed gas stream and a permeate surface generally opposed to
the first surface.
20. The hydrogen-processing assembly of claim 19, wherein the plurality
of membranes includes at least one pair of membranes with their respective
permeate surfaces generally facing each other and spaced apart to define a
harvesting region through which the permeate stream flows to the permeate region of
the internal volume.

21. The hydrogen-processing assembly of claim 19, wherein the
hydrogen-separation assembly includes at least one screen that defines the
harvesting region, and further wherein the hydrogen-separation assembly does not
include a gasket extending between the permeate surfaces of the at least one pair of
membranes.
22. The hydrogen-processing assembly of claim 20, wherein the plurality
of membranes includes at least a third membrane with its first surface generally
facing and spaced apart from the first surface of one of the membranes of the pair of
membranes.
23. The hydrogen-processing assembly of claim 1, further comprising a
methanation catalyst bed within the enclosure.

24. The hydrogen-processing assembly of claim 1, in combination with a
fuel cell stack adapted to receive at least a portion of the permeate stream.
25. The hydrogen-processing assembly of claim 1, in combination with a
hydrogen-producing region adapted to produce the mixed gas stream.
26. The hydrogen-processing assembly of claim 25, wherein the
hydrogen-producing region includes at least one reforming catalyst bed.

27. The hydrogen-processing assembly of claim 26, wherein the
hydrogen-producing region is external to the enclosure.
28. The hydrogen-processing assembly of claim 26, wherein the
hydrogen-producing region is internal to the enclosure.
29. The hydrogen-processing assembly of claim of claim 26. in further
combination with a fuel cell stack adapted to receive at least a portion of the
permeate stream and to produce an electric current therefrom.

30. A hydrogen-processing assembly, comprising:
an enclosure, comprising:
a body defining an internal volume and having an Internal perimeter,
the internal volume including a mixed gas region and a permeate region;
at least one input port extending through the body and through which
a fluid stream is delivered to the enclosure;
at least one product output port extending through the body and
through which a permeate stream is removed from the permeate region; and
at least one byproduct output port extending through the body and
through which a byproduct stream is removed from the mixed gas region; and
a hydrogen-separation assembly positioned within the internal volume In a
spaced relation to at least a portion of the internal perimeter of the body of the
enclosure, the hydrogen-separation assembly including at least one generally planar
membrane module having an outer perimeter and including at least one hydrogen-
selective membrane and at least one harvesting region adjacent to the at least one
hydrogen-selective membrane, wherein the hydrogen-separation assembly is
adapted to receive a mixed gas stream containing hydrogen gas and other gases
and to separate the mixed gas stream into the permeate stream and the byproduct
stream, wherein the permeate stream has at least one of a greater concentration of
hydrogen gas and a lower concentration of the other gases than the mixed gas
stream, wherein the byproduct stream contains at least a substantial portion of the
other gases, wherein the at least one hydrogen-selective membrane includes a first
surface adapted to be contacted by the mixed gas stream and a permeate surface
generally opposed to the first surface, and further wherein the permeate stream is
formed from a portion of the mixed gas stream that passes through the membrane to
the harvesting region of the internal volume, wherein the harvesting region includes a
support adapted to support the permeate surface of the membrane, wherein the

hydrogen-separation assembly does not include a seal between the membrane and
the support, and further wherein the permeate region is in direct fluid communication
with the at least a portion of the internal perimeter of the body of the enclosure;
wherein the permeate region of the internal volume is defined between at
least a portion of the outer perimeter of the at least one generally planar membrane
module and at least a portion of the internal perimeter of the body of the enclosure.
31. The hydrogen-processing assembly of claim 30, wherein the at least
one harvesting region is generally parallel to the at least one hydrogen-selective
membrane.
32. The hydrogen-processing assembly of claim 30, wherein the at least
one harvesting region is generally coextensive to the at least one hydrogen-selective
membrane.

33. A hydrogen-processing assembly, comprising:
an enclosure, comprising:
a body defining an internal volume and having an internal perimeter,
the internal volume including a mixed gas region and a permeate region;
at least one input port extending through the body and through which
a fluid stream is delivered to the enclosure;
at least one product output port extending through the body and
through which a permeate stream is removed from the permeate region; and
at least one byproduct output port extending through the body and
through which a byproduct stream is removed from the mixed gas region; and
a hydrogen-separation assembly positioned within the internal volume
in a spaced relation to at least a portion of the internal perimeter of the body of the
enclosure, the hydrogen-separation assembly having an outer perimeter and
including at least a pair of generally opposed hydrogen-selective membranes,
wherein the hydrogen-separation assembly is adapted to receive a mixed gas stream
containing hydrogen gas and other gases and to separate the mixed gas stream Into
the permeate stream and the byproduct stream, wherein the permeate stream has at
least one of a greater concentration of hydrogen gas and a lower concentration of the
other gases than the mixed gas stream, wherein the byproduct stream contains at
least a substantial portion of the other gases, wherein each of the hydrogen-selective
membranes includes a first surface adapted to be contacted by the mixed gas stream
and a permeate surface generally opposed to the first surface, and further wherein
the permeate stream is formed from a portion of the mixed gas stream that passes
through the membranes to the permeate region of the internal volume;
wherein the hydrogen-separation assembly does not Include a seal extending
between the permeate surfaces of the pair of generally opposed membranes.

34. The hydrogen-processing assembly of claim 30, wherein the permeate
region of the internal volume is defined between at least a portion of the outer
perimeter of the hydrogen-separation assembly and at least a portion of the internal
perimeter of the body of the enclosure.

Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen-
separation assembly positioned within the internal volume of an enclosure in a
spaced relation to at least a portion of the internal perimeter of the body of the
enclosure.

Documents:

4290-KOLNP-2008-(05-09-2014)-AMANDED PAGES OF SPECIFICATION.pdf

4290-KOLNP-2008-(05-09-2014)-CORRESPONDENCE.pdf

4290-KOLNP-2008-(05-09-2014)-FORM-1.pdf

4290-KOLNP-2008-(05-09-2014)-FORM-13.pdf

4290-KOLNP-2008-(05-09-2014)-FORM-5.pdf

4290-KOLNP-2008-(05-09-2014)-OTHERS.pdf

4290-KOLNP-2008-(12-08-2013)-CORRESPONDENCE.pdf

4290-KOLNP-2008-(12-08-2013)-OTHERS.pdf

4290-KOLNP-2008-(12-08-2013)-PA.pdf

4290-KOLNP-2008-(14-08-2013)-ABSTRACT.pdf

4290-KOLNP-2008-(14-08-2013)-ANNEXURE TO FORM 3.pdf

4290-KOLNP-2008-(14-08-2013)-CLAIMS.pdf

4290-KOLNP-2008-(14-08-2013)-CORRESPONDENCE.pdf

4290-KOLNP-2008-(14-08-2013)-DESCRIPTION (COMPLETE).pdf

4290-KOLNP-2008-(14-08-2013)-DRAWINGS.pdf

4290-KOLNP-2008-(14-08-2013)-FORM-2.pdf

4290-KOLNP-2008-(14-08-2013)-OTHERS.pdf

4290-KOLNP-2008-(14-08-2013)-PETITION UNDER RULE 137.pdf

4290-kolnp-2008-abstract.pdf

4290-kolnp-2008-assignment.pdf

4290-kolnp-2008-claims.pdf

4290-KOLNP-2008-CORRESPONDENCE-1.1.pdf

4290-kolnp-2008-correspondence.pdf

4290-kolnp-2008-description (complete).pdf

4290-kolnp-2008-drawings.pdf

4290-kolnp-2008-form 1.pdf

4290-KOLNP-2008-FORM 18.pdf

4290-KOLNP-2008-FORM 3-1.1.pdf

4290-kolnp-2008-form 3.pdf

4290-kolnp-2008-form 5.pdf

4290-kolnp-2008-gpa.pdf

4290-kolnp-2008-international preliminary examination report.pdf

4290-kolnp-2008-international publication.pdf

4290-kolnp-2008-international search report.pdf

4290-kolnp-2008-pct priority document notification.pdf

4290-kolnp-2008-pct request form.pdf

4290-kolnp-2008-specification.pdf

abstract-4290-kolnp-2008.jpg


Patent Number 264791
Indian Patent Application Number 4290/KOLNP/2008
PG Journal Number 04/2015
Publication Date 23-Jan-2015
Grant Date 21-Jan-2015
Date of Filing 22-Oct-2008
Name of Patentee IDATECH, LLC
Applicant Address 63065 NE 18TH STREET, BEND, OR 97701
Inventors:
# Inventor's Name Inventor's Address
1 POPHAM VERON WADE 3170 N.E. WELLS ACRES ROAD, BEND, OR 97701
2 PLEDGER WILLIAM A 66925 THN PEAKS COURT, BEND, OR 97701
3 TAYLOR KYLE 62245 CODY ROAD, BEND, OR 97701
4 STUDEBAKER R. TODD 5142 WHITAKER ROAD, CHUBBUCK, ID 83202
PCT International Classification Number H01M 8/06
PCT International Application Number PCT/US2007/012289
PCT International Filing date 2007-05-22
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 60/802,716 2006-05-22 U.S.A.