Title of Invention

PIGMENT DISPERSIONS WITH POLYMERIC DISPERSANTS HAVING PENDING CHROMOPHORE GROUPS

Abstract

A pigment dispersion comprising a colour pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group wherein the at least one pending chromophore group is a derivative from a colour pigment selected from the group consisting of monoazo pigments, disazo pigments, ss-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments; the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; the polymeric dispersant has a polymeric backbone with a polymerization degree between 5 and 1000; and at most 30 % of the monomer units of the polymeric backbone have a pending chromophore group. The pigment dispersion can be advantageously used in Inkjet inks. Also disclosed is a method for preparing the pigment dispersion comprising the step of preparing the polymeric dispersant by copolymerizing a monomer already containing the pending chromophore group.

Full Text

Description PIGMENT DISPERSIONS WITH POLYMERIC DISPERSANTS HAVING PENDING CHROMOPHORE GROUPS Technical field [0001] The present invention relates to stable pigment dispersions and pigmented Inkjet inks comprising colour pigments that are stabilized by polymeric dispersants having pending chromophore groups which exhibit a structural similarity with the colour pigment. Background art [0002] Pigment dispersions are made using a dispersant. A dispersant is a substance for promoting the fonnation and stabilization of a dispersion of pigment particles in a dispersion medium. Dispersants are generally surface-active materials having an anionic, cationic or non-ionic structure. The presence of a dispersant substantially reduces the dispersing energy required. Dispersed pigment particles may have a tendency to re-agglomerate after the dispersing operation, due to mutual attraction forces. The use of dispersants also counteracts this re-agglomeration tendency of the pigment particles. [0003] The dispersant has to meet particulariy high requirements when used for inkjet inks. Inadequate dispersing manifests itself as increased viscosity in liquid systems, loss of brilliance and/or hue shifts. Moreover, particulariy good dispersion of the pigment particles is required to ensure unimpeded passage of the pigment particles through the nozzles of the print head, which are usually only a few micrometers in diameter. In addition, pigment particle agglomeration and the associated blockage of the printer nozzles has to be avoided in the standby periods of the printer. [0004] Polymeric dispersants contain in one part of the molecule so-called anchor groups, which adsorb onto the pigments to be dispersed. In a spatially separate part of the molecule, polymeric dispersants have polymer chains sticking out and whereby pigment particles are made compatible with the dispersion medium, i.e. stabilized. [0005] The properties of polymeric dispersants depend on both the nature of the monomers and their distribution in the polymer. Polymeric dispersants obtained by randomly polymerizing monomers (e.g. monomers A and B polymerized into ABBAABAB) or by polymerizing altemating monomers (e.g. monomers A and B polymerized into ABABABAB) generally result in a poor dispersion stability. Improvements in dispersion stability were obtained using graft copolymer and block copolymer dispersants. [0006] Graft copolymer dispersants consist of a polymeric backbone with side chains attached to the backbone. CA 2157361 (DU PONT) discloses pigment dispersions made by using a graft copolymer dispersant with a hydrophobic polymeric backbone and hydrophilic side chains. [0007] Block copolymer dispersants containing hydrophobic and hydrophilic blocks have been disclosed in numerous Inkjet ink patents. US 5859113 (DU PONT) discloses an AB block copolymer dispersant with a polymeric A segment of polymerized glycidyl (meth)acrylate monomers reacted with an aromatic or aliphatic carboxylic acid, and a polymeric B segment of polymerized alkyl (meth)acrylate monomers having 1-12 carbon atoms in the alkyl group, hydroxy alky! (meth)acrylate monomers. [0008] In the design of polymeric dispersants for aqueous Inkjet inks, the above mentioned anchor groups, which adsorb onto the pigments to be dispersed, are generally hydrophobic groups exhibiting an affinity for the pigment surface. [0009] EP 0763580 A (TOYO INK) discloses an aqueous type pigment dispersing agent having a portion which has a high affinity with a pigment and which has at least one type selected from the group consisting of an organic dye, anthraquinone and acridone only at a temiinal end or at both terminal ends of at least one aqueous polymer selected from the group consisting of an aqueous linear urethanic polymer and an aqueous linear acrylic polymer. EP 0763378 A (TOYO INK) discloses similar pigment dispersing agents for non-gqueous pigment dispersions. [0010] US 5420187 (TOYO INK) discloses a pigment-dispersing agent obtained by polymerizing an addition-polymerizable monomer having an acidic functional group and other addition-polymerizable monomer in the presence of a polymerization initiator, the polymerization initiator being a diazotization product prepared by diazotizing at least one compound selected from the group consisting of an anthraquinone derivative having an aromatic amino group, an acridone derivative having an aromatic amino group and an organic dyestuff having an aromatic amino group. In this pigment-dispersing agent, the colorant is located in the polymeric backbone itself. [0011] US 2003044707 (TOYO INK) discloses a dispersing agent for a pigment, comprising a specific compound having a structure wherein a phthalocyanine type molecular skeleton which is adsorptive on the pigment and an oligomer unit or polymer unit which prevents re-agglomeration of the pigment to bring out the effect of dispersion are covalently bonded, and having affinity for a medium or a solvent. [0012] Current practice is that the exact or almost the exact chemical structure of the colour pigment is incorporated as the anchor group in the polymeric dispersing agent to assure maximum affinity with the colour pigment. As a consequence, each pigment has its own tailor made polymeric dispersant. In practice, this requires the holding of an inventory of different polymeric dispersants for producing a complete range of colour Inkjet ink sets. The cyan ink with copper phthalocyanine as pigment is a rare exception in that all desired properties are combined in the same pigment But yellow pigments have to be selected based on the properties that are the most important in their application of Inkjet ink. For example, some yellow pigments are selected for their light stability, while others are selected to obtain images having high colour strength. The holding of such an inventory of different types of polymeric dispersants incurs financial penalties due to additional storage and logistical requirements as well as increasing the possibility of using the "wrong" polymeric dispersant for the production of a particular Inkjet ink. Another disadvantage is that the low solubility of the pigment generally complicates the synthesis of such polymeric dispersants. [0013] US 2004194665 (BASF) relates to pigment dispersions comprising for a pigment dispersant a substituted perylene derivatives in which the substituent has a sterically stabilizing and/or electrostatically stabilizing effect. The perylene derivatives are used to disperse pigments with a quite different chemical structure such as quinacridone pigments. No other pigment derivatives are disclosed. [0014] WO 2005056692 (SUN CHEMICAL) discloses highly concentrated colorant dispersions comprising: (a) at least about 45 wt. % of a pigment; and (b) a polymeric colored dispersant having the structure A- (B-X)n, wherein: A is an organic chromophore; B is a covalently bonded linking moiety; X is a branched or linear C50"C2oo polymeric covalently linked hydrocarbon; and n is an integer from 1 to 4. The chromophore group A is present in the polymeric dispersant either as an end group or in the polymeric backbone. The polymeric dispersants are used for dispersing pigments with quite different chemical structure compared to frie chromophore group A. [0015] US 4664709 (HOECHST) discloses pigment compositions comprising azoacylacetamide dispersing agents for azo pigments bearing some resemblance to the chromophore group of the dispersing agent. The chromophore group is present in the polymeric dispersant as an end group. [0016] GB 1343606 (ICI) discloses pigment dispersions containing a dyestuff of the formula D-(Z-O.OCR)n in which D is the radical of a dyestuff which is attached to Z through a carbon atom of an aromatic ring present in D, Z is a divalent bridging group, n is an integer of 1-8 and R is the residue of a carboxy ended polyester RCOOH derived from a hydroxycarboxylic acid of the fomnula HO-X-COOH in which X is a divalent saturated or unsaturated aliphatic radical containing at least 8 carbon atoms and in which there are at least 4 carbon atoms between the hydroxy and carboxy acid groups, or from a mixture of such a hydroxycarboxylic acid and a carboxylic acid free from hydroxy groups. In the examples the pigments are dispersed with dyestuffs having a radical D of approximately the same or higher molecular weight compared to the pigment. The radical of a dyestuff D is present in the polymeric dispersant either as an end group or in the polymeric backbone. [0017] GB 1424517 (ICI) discloses dispersions of an organic pigment in a solvent medium which contains dissolved therein a dispersing agent of the formula D"(Z-R)n wherein D is the radical of a dyestuff which is attached to Z through a carbon atom of an aromatic ring present in D; Z is a divalent bridging group; n is a positive integer having a value of from 1 to 8; and R is the residue of an optionally substituted addition polymer chain. In the examples the p-form copper phthalocyanine pigment is dispersed by dispersing agents having a radical D of a higher molecular weight compared to the pigment. The radical of a dyestuff D is present in the polymeric dispersant either as an end group or in the polymeric backbone. [0018] Polymeric nanoparticles with at least one chromophore group are disclosed as new colorants by EP 1245644 A (ROHM & HAAS), but they are not disclosed as polymeric dispersants for colour pigments, [0019] JP 2003-096191 A (RICOH) discloses quinacridone derivatives, indigo derivatives, diketopyrrolopyrrole derivatives and isoindolinone derivatives as a colorant in electrophoretic image displays. It is not disclosed if these dye derivatives can be used as a polymeric dispersant for a colour pigment. [0020] JP 2004-002529 A (KONICA MINOLTA) discloses aqueous dispersions of colored microparticles which are prepared by polymerizing monomers comprising a chromophore group. The suitability of these colored microparticles as polymeric dispersants is not addressed. [0021] For consistent image quality, the Inkjet ink requires a dispersion stability capable of dealing with high temperatures (above 60°C) during transport of the ink to a customer and changes in the dispersion medium of the Inkjet ink during use, for example, evaporation of solvent and increasing concentrations of humectants, penetrants and other additives. [0022] Therefore, it is highly desirable to be able to manufacture a range of stable pigmented Inkjet inks using a single polymeric dispersant obtained by simple synthesis. Objects of the invention [0023] it is an object of the present invention to provide inkjet inks using a polymeric dispersant obtainable by uncomplicated synthesis and suitable for different colour pigments. [0024] It is a further object of the present invention to provide inkjet inks with high dispersion stability. [0025] It is a further object of the present invention to provide inkjet inks producing images of high image quality with a high optical density. [0026] Further objects of the invention will become apparent from the description hereinafter. Summary of the invention [0027] It has been surprisingly found that inkjet inks with high optical density and high stability were obtained using a coloured polymeric dispersant wherein a certain number of pending chromophore groups exhibiting a structural similarity with the colour pigment were present. [0028] Objects of the present invention have been realized with a pigment dispersion comprising a colour pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group wherein the at least one pending chromophore group is a derivative from a colour pigment selected from the group consisting of monoazo pigments, disazo pigments, p-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments; the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; the polymeric dispersant has a polymeric backbone with a polymerization degree between 5 and 1000; and at most 30 % of the monomer units of the polymeric backbone have a pending chromophore group Disclosure of the Invention Definitions [0029] The term "colorant", as used in disclosing the present invention, means dyes and pigments. [0030] The term "dye", as used in disclosing the present invention, means a colorant having a solubility of 10 mg/L or more in the medium in which it is applied and under the ambient conditions pertaining. [0031] The term "pigment" is defined in DIN 55943, herein incorporated by reference, as a colouring agent that is practically insoluble in the application medium under the pertaining ambient conditions, hence having a solubility of less than 10 mg/L therein. [0032] The term "chromophore group", as used in disclosing the present invention, means a group with an absorption maximum between 300 nm and 2000 nm. [0033] The term "pending chromophore group", as used in disclosing the present invention, means a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occun"ing solely as an end group of the polymeric backbone. [0034] The term "C.I." is used in disclosing the present application as an abbreviation for Colour Index, [0035] The term "actinic radiation" as used in disclosing the present invention, means electromagnetic radiation capable of initiating photochemical reactions. [0036] The term "DP" is used in disclosing the present application as an abbreviation for degree of polymerization, i.e. the number of structural units (monomers) in the average polymer molecule. [0037] The temn "PD" is used in disclosing the present application as an abbreviation for polydispersity of a polymer. [0038] The term "dispersion", as used in disclosing the present invention, means an intimate mixture of at least two substances, one of which, called the dispersed phase or colloid, is uniformly distributed in a finely divided state through the second substance, called the dispersion medium. [0039] The term "polymeric dispersant", as used in disclosing the present invention, means a substance for promoting the formation and stabilization of a dispersion of one substance in a dispersion medium. [0040] The term "copolymer", as used in disclosing the present invention means a macromolecule in which two or more different species of monomer are incorporated into a polymer chain. [0041] The term "block copolymer", as used in disclosing the present invention, means a copolymer in which the monomers occur in relatively long alternate sequences in a chain. [0042] The term "spectral separation factor" as used in disclosing the present invention means the value obtained by calculating the ratio of the maximum absorbance Amax (measured at wavelength Amax) over the reference absorbance Aref determined at a higher wavelength Arsf. [0043] The abbreviation "SSF" is used in disclosing the present invention for spectral separation factor. [0044] The term "alkyl" means all variants possible for each number of carbon atoms in the alkyl group i.e. for three carbon atoms: n-propyl and isopropyl; for four carbon atoms: n-butyl, isobutyl and tertiary-butyl; for five carbon atoms: n-pentyl, 1,1-dimethyl-propyl, 2,2-dimethylpropyl and 2-methyl-butyl etc. [0045] The term "acyl group" means -(C"0)-aryI and -(C=0)-alkyl groups. [0046] The term "aliphatic group" means saturated straight chain, branched chain and alicyclic hydrocarbon groups. [0047] The term "unsaturated aliphatic group" means straight chain, branched chain and alicyclic hydrocarbon groups which contain at least one double or triple bond. [0048] The temn "aromatic group" as used in disclosing the present invention means an assemblage of cyclic conjugated carbon atoms, which are characterized by large resonance energies, e.g. benzene, naphthalene and anthracene. [0049] The term "alicyclic hydrocarbon group" means an assemblage of cyclic carbon atoms, which do not form an aromatic group, e.g. cyclohexane. [0050] The term "heteroaromatic group" means an aromatic group wherein at least one of the cyclic conjugated carbon atoms is replaced by a non-carbon atom such as a nitrogen atom, a sulphur atom, a phosphorous atom, selenium atom and a tellurium atom. [0051] The term "heterocyclic group" means an alicyclic hydrocarbon group wherein at least one of the cyclic carbon atoms is replaced by an oxygen atom, a nitrogen atom, a phosphorous atom, a silicon atom, a sulphur atom, a selenium atom or a tellurium atom. Pigmented inkjet ink [0052] The pigmented inkjet ink according to the present invention contains at least three components: (i) a colour pigment, (ii) a polymeric dispersant. and (iii) a dispersion medium. [0053] The pigmented inkjet ink according to the present invention may further contain at least one surfactant. [0054] The pigmented inkjet ink according to the present invention may further contain at least one biocide. [0055] The pigmented inkjet ink according to the present invention may further contain at least one humectant and/or penetrant. [0055] The pigmented inkjet ink according to the present invention may further contain at least one pH adjuster. [0057] The pigmented inkjet ink according to the present invention may contain at least one humectant to prevent the clogging of the nozzle, due to its ability to slow down the evaporation rate of ink. [0058] The viscosity of the pigmented inkjet ink according to the present invention is preferably lower than 100 mPa.s, more preferably lower than 30 mPa.s, and most preferably lower than 15 mPa.s at a shear rate of 100 s-1 and a temperature between 20 and 110 0C. [0059] The pigmented Inkjet ink according to the present invention is preferably an aqueous, a solvent based or an oil based pigmented Inkjet ink [0060] The pigmented Inkjet ink according to the present invention may be curable and may contain monomers, oligomers and/or prepolymers possessing different degrees of functionality. A mixture including combinations of mono-, di-. tri- and/or higher functionality monomers, oligomers or prepolymers may be used. The initiator typically initiates the polymerization reaction. A catalyst called an initiator for initiating the polymerization reaction may be included in the curable pigmented Inkjet ink. The initiator can be a thermal initiator, but is preferably a photo-initiator. The photo-initiator requires less energy to activate than the monomers, oligomers and/or prepolymers to form the polymer. The photo-initiator suitable for use in the curable fluid may be a Norrish type 1 initiator, a Norrish type II initiator or a photo-acid generator. Polymeric dispersants [0061] The polymeric dispersant used in the pigmented Inkjet ink according to the present invention contains one or more pending chromophore groups linked by a linking group to a polymeric backbone. [0062] The polymeric dispersant used in the pigmented Inkjet ink according to the present invention preferably has a polymeric backbone with a polymerization degree DP between 5 and 1000, more preferably between 10 and 500 and most preferably between 10 and 100. [0063] The polymeric dispersant used in the pigmented Inkjet ink according to the present invention preferably has a number average molecular weight Mn between 500 and 30000, more preferably between 1500 and 10000. [0064] The polymeric dispersant has preferably a polymeric dispersity PD smaller than 2, more preferably smaller than 1.75 and most preferably smaller than 1.5. [0065] The polymeric dispersant is used in the pigmented Inkjet ink in an amount of 5 to 600 wt%. preferably 10 to 100 wt% based on the weight of the pigment. Polymeric backbones [0066] The polymeric backbone of the polymeric dispersant used in the pigmented inkjet ink according to the present invention is required for the compatibility between polymeric dispersant and dispersion medium. [0067] It is not required that the polymeric backbone has an affinity for the pigment. For example, the polymeric backbone of a dispersant for aqueous inkjet inks can be a homopolymer of acrylic acid monomers. A homopolymer is generally incapable of dispersing pigments, but the presence of a pending chromophore group exhibiting a similarity with the pigment ensures an adequate affinity between polymeric dispersant and pigment surface. [0068] The polymeric backbone can also be a statistical copolymer, a block copolymer, a graft copolymer, a comb polymer or an alternating copolymer. Also suitable as polymeric backbone is a gradient copolymer as disclosed by MATYJASZEWSKI, K., et al. Atom Transfer Radical Polymerization. Chem. Reviews 2001. vol.101, p.2921-2990. Sometimes it can be useful to include a number of monomers with a high affinity for the pigment surface to enhance certain properties of the inks, e.g. dispersion stability. For example, the polymeric backbone of a dispersant for aqueous inkjet inks may contain hydrophobic monomers to increase the affinity of the polymeric dispersant for the pigment surface. However in enhancing this affinity for the pigment surface, care should be taken that enough of the polymeric backbone sticks out to make the pigment particles compatible with the dispersion medium. [0069] In graft copolymers the use of grafted chains of methoxypolyethyleneglycol (MPEG) has been found to be very advantageous in aqueous inkjet inks. For solvent-based inkjet inks the use of grafted chains of polyester were found to be very advantageous. A preferred MPEG macromonomer is BISOMER™ MPEG 350MA (methoxypolyethyleneglycol methacrylate) from LAPORTE INDUSTRIES LTD. [0070] For radiation curable inks with the dispersion medium comprising or consisting of monomers and/or oligomers, many (co)polymers having good solubility in the dispersion medium were found to be suitable for the polymer backbone of the polymeric dispersant; [0071] The copolymeric backbone consists preferably of no more than 2 or 3 monomer species. [0072] The monomers and/or oligomers used to prepare the polymeric dispersant used in the pigmented Inkjet ink according to the present invention can be any monomer and/or oligomer found in the Polymer Handbook, Vol. 1+2. 4th edition. Edited by J. BRANDRUP, et al. Wiley-lnterscience . 1999. [0073] Suitable examples of monomers include: acrylic acid, methacrylic acid, maleic acid, acryloyloxybenzoic acid and methacryloyloxybenzoic acid (or their salts), maleic anhydride; alkyl(meth)acrylates (linear, branched and cycloalkyl) such as methyl(meth)acrylate, n-butyl(meth)acrylate, tert-butyl(meth)acrylate, cyclohexyl(meth)acrytate and 2-ethylhexyl(meth)acrylate; aryl(meth)acrylates such as benzyl(meth)acrylate and phenyl(meth)acrylate; hydroxyalkyl(meth)acrylates such as hydroxyethyl(meth)acrylate and hydroxypropyl(meth)acrylate; (meth)acrylates with other types of functionalities (e.g. oxirane, amino, fluoro, polyethylene oxide, phosphate-substituted) such as glycidyl (meth)acrylate, dimethylaminoethyl(meth)acrylate, trifluoroethyl acrylate, methoxypolyethyleneglycol (meth)acrylate and tripropyleneglycol(meth)acrylate phosphate; allyl derivatives such as allyl glycidyl ether; styrenics such as styrene, 4-methylstyrene, 4-hydroxystyrene, and 4-acetoxystyrene; (meth)acrylonitrile; (meth)acrylamides (including N-mono and N,N-disubstituted) such as N-benzyl (meth)acrylamide; maleimides such as N-phenyl maleimide, N-benzyl maleimide and N-ethyl maleimide; vinyl derivatives such as vinylcaprolactam, vinylpyrrolidone, vinylimidazole, vinylnaphthalene and vinyl halldes; vinylethers such as vinylmethyl ether; and vinylesters of carboxylic acids such as vinylacetate and vinylbutyrate. Linking groups [0074] The pending chromophore group is linked by a linking group to the polymeric backbone. The linking group contains at least one carbon atom, one nitrogen atom, one oxygen atom, one phosphorous atom, one silicon atom, one sulphur atom, one selenium atom or one tellurium atom. [0075] The linking group consists of all atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone. [0076] In one embodiment, the linking group is the result of modification of a (co)polymer with a chromophore having a reactive group. Suitable reactive groups on the chromophore include thiol groups, primary or secondary amino groups, carboxylic acid groups or salts thereof, hydroxyl groups, isocyanate groups and epoxy groups. Typical covalent bonds formed by reaction of the chromophore with the polymeric backbone include an amide, an ester, a urethane, an ether and a thioether. [0077] In another embodiment, the polymeric dispersant is prepared by copolymerizing monomers of the polymeric backbone and monomers containing a chromophore group. In this case the linking group is already present in the monomer. This polymerization method offers the advantage of well-controlled design of polymeric dispersants for a wide variety of dispersion media. Due to its low solubility, a monomer containing the complete colour pigment as a chromophore group poses problems both in the synthesis of the polymeric dispersants, as well as the suitability of the polymeric dispersant for a wide variety of dispersion media and pigments. [0078] The linking group has preferably a molecular weight smaller than the molecular weight of the pending chromophore group, more preferably the linking group has a molecular weight smaller than 80% than the molecular weight of the pending chromophore group, and most preferably the linking group has a molecular weight smaller than 50% than the molecular weight of the pending chromophore group. Pending chromophore groups [0079] The pending chromophore group of the polymeric dispersant used in the pigmented Inkjet ink according to the present invention exhibits a similarity with the colour pigment of the pigmented Inkjet ink, and has a molecular weight which is smaller than 93%, preferably smaller than 85%, more preferably smaller than 75% and most preferably smaller than 65% of the molecular weight of the colour pigment. [0080] The pending chromophore group is a derivative from a colour pigment selected from the group consisting of monoazo pigments, disazo pigments, p-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindoiinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacrldone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments [0081] At most 30 % of the monomer units of the polymeric backbone of the polymeric dispersant used In the pigmented Inkjet ink according to the present invention have a pending chromophore group. [0082] At least 2 % of the monomer units of said polymeric backbone of the polymeric dispersant used in the pigmented Inkjet ink according to the present invention have a pending chromophore group. [0083] Preferably between 5 and 30 % of the monomer units of the polymeric backbone of the polymeric dispersant used in the pigmented Inkjet ink according to the present invention have a pending chromophore group. [0084] More preferably between 10 and 30 % of the monomer units of the polymeric backbone of the polymeric dispersant used in the pigmented Inkjet ink according to the present invention have a pending chromophore group. [0085] Polymeric dispersants having a homopolymer or statistical copolymer as polymeric backbone with more than 45 percent of the monomeric units of the polymeric backbone having pending chromophore groups exhibit problems of solubility of the polymeric dispersant in the dispersion medium and deterioration of the dispersing properties due to the fact that the dispersant would go flat on the pigment surface. However, in the case of a well-defined block-copolymer a good dispersion can be obtained with 50 percent of the monomeric units of the polymeric backbone having pending chromophore groups. This well-defined block-copoiymer preferably has at least one block containing no pending chron^iophore groups. [0086] In some cases, the dispersion stability of the pigment according to the present invention can be further improved by increasing the number of pending chromophore groups in the polymeric dispersant. In a preferred embodiment, two, three or more pending chromophore groups are located in close proximity of each other on the polymeric backbone. Close proximity means preferably less than 50 monomeric units, more preferably less than 20 monomeric units and most preferably less than 10 monomeric units between two pending chromophore groups. It is believed that the dispersion stability improvement by more pending chromophore groups is due to the dynamic character of the attaching and detaching of the pending chromophore group to the pigment surface. By increasing the number of pending chromophore groups, the probability that all pending chromophore groups will be in a "detached state" at the same time is. expected to decrease. [0087] In one embodiment the pending chromophore group of the polymeric dispersant used in the pigmented Inkjet ink according to the present invention is represented by Formula (I) wherein, L is a linking group forming a covalent bond with the polymeric backbone; and R1 to R8 are independently selected from the group consisting of hydrogen, an alkyl group and a halogen. Preferably the linking group contains at least one atom selected from the group consisting of an oxygen atom, a nitrogen atom and a sulphur atom. [00S8] In another embodiment the pending chromophore group of the polymeric dispersant used in the pigmented inl^jet ink according to the present invention is represented by formula (II): wherein, one of L1, L2 or L3 is said linking group and is selected from the group consisting of an aliphatic group, a substituted aliphatic group, an unsaturated aliphatic group and a substituted unsaturated aliphatic group; LI, L2 and/or L3, if not representing said linking group, are independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a carboxylic acid group, an ester group, an acyl group, a nitro group and a halogen; AR1 and AR2 represent an aromatic group; and n represents the integer 0 or 1. [0089] In a preferred embodiment the pending chromophore group of the polymeric dispersant may be represented by fonnula (111): wherein, one of R1 to R11 is said linking group forming a covalent bond with said polynneric backbone; R1 to R11, if not representing said linking group, are independently selected from the group consisting of hydrogen, an alky! group, an alkenyl group, an alkoxy group, an alcohol group, a carboxyiic acid group, an ester' group, an acyl group, a nitro group and a halogen; or R7 and R8 may together form a heterocyclic ring. Preferably the heterocyclic ring fomied by R7 and R8 is imidazolone or 2,3-dihydroxypyrazine, so that a benzimidazolone ring and a 2,3-dihydroxyquinoxaline ring respectively are formed in Formula (III). Synthesis [0090] The polymerization process may be a condensation polymerization, in which the chain growth is accompanied by elimination of small molecules such as water or methanol or an addition polymerization, in which the polymer is fomied without the loss of other materials. Polymerization of the monomers can be conducted according to any conventional method such as bulk polymerization and semi-continuous polymerization. [0091] The synthesis is preferably perfomed by a controlled radical polymerization (CRP) technique. Suitable polymerization techniques include ATRP (atom transfer radical polymerization), RAFT (reversible addition-fragmentation chain transfer polymerization), MADIX (reversible addition-fragmentation chain transfer process, using a transfer active xanthate), catalytic chain transfer (e.g. using cobalt complexes), GTP (group transfer polymerization), or nitroxide (e.g. TEMPO) mediated polymerizations. [0092] In one embodiment the polymeric dispersant used in the pigmented Inkjet ink according to the present invention is prepared by a post-polymerization modification with a chromophore. The chromophore is covalently linked to the polymer backbone of the polymeric dispersant. The post-polymerization modification can be any suitable reaction, e.g. an esterification reaction. [0093] An esterification reaction suitable for post-polymerization modification can be performed using N,N'-carbonyldiimidazole (GDI). In a first step, the carboxylic moieties of the polymer are activated with GDI to form an intermediate imidazole, which is then esterified with the chromophore having a reactive hydroxyl group. The completion of the first step can be observed when the GO2 degassing stops. Synthesis scheme with R representing the chromophore group: Side products of the reaction can be removed by acidifying the aqueous medium used for precipitation of the polymer (hydrolysis of remaining activated esters and protonation of imidazole that remains in water, in this way achieving the separation from the polymer). If the final modified polymer is water-soluble (e.g. modified homopolymer of acrylic acid), a dialysis can be performed to purify the polymer. [0094] In another embodiment the polymeric dispersant used in the pigmented Inkjet ink according to the present invention is prepared by a copolymerization with a monomer containing a ciiromophore group. It was observed that the pigment-based monomers containing a chromophore group were stable in the presence of radicals. Classical free radical polymerization (FRP) techniques for preparing statistical copolymers in a one reactor polymerization and ATRP for preparing block copoFymers were possible to prepare the polymeric dispersant used in the present invention. Monomers with a chromophore group [0095] A monomer with a chromophore group for the preparation of the polymeric dispersant used in the pigmented inkjet ink according to the present invention can be represented by the general formula: A-L-B wherein, A represents a polymerisable functional group, preferably an ethylenically unsatured polymerisable functional group; L represents a divalent linking group; and B represents a chromophore group. [0096] In a preferred embodiment, the ethylenically unsatured polymerisable group is selected from the group consisting of a styrene, an acrylate, a methacrylate, an acrylamide, a methacrylamide, a maleimide, a vinyl ester and a vinyl ether. [0097] The monomer with a chromophore group can be represented by Formula (GEN-I): wherein, ARi and AR2 represent a substituted or unsubstituted aromatic group and R represents a substituted or unsubstituted aliphatic group, with the proviso that one of R, ARi and AR2 has a substituent with a polymerizable functional group, preferably an ethylenically unsatured polymerizable functional group. [0098] In one embodiment AR2 of Formula (GEN-I) is replaced by an alky! group, preferably methyl or ethyl. [0099] In another embodiment AR2 of Formula (GEN-I) is replaced by an aliphatic substituent with a poiymerisable functional group, preferably an ethylenically unsatured poiymerisable functional group. Preferably this aliphatic ethylenically unsatured poiymerisable functional group is [0100] Suitable monomers according to Formula (GEN-I) include the monomers disclosed in Table 1 : styrene derivatives, in Table 2 : (meth)acrylate and (meth)acrylamide derivatives, and in Table 3 : other poiymerizable [0121] The pigment is used in the pigmented inkjet ink in an amount of 0.1 to 20 wt%, preferably 1 to 10 wt% based on the total weight of the pigmented inkjet ink. Dispersion media [0122] The dispersion medium used in the pigmented inkjet ink according to the present invention is a liquid. The dispersion medium may consist of water and/or organic solvent(s). [0123] If the pigmented inkjet ink is a curable pigmented inkjet ink, water and/or organic solvent(s) are replaced by one or more monomers and/or oligomers to obtain a liquid dispersion medium. Sometimes, it can be advantageous to add a small amount of an organic solvent to improve the dissolution of the dispersant. The content of organic solvent should be lower than 20 wt% based on the total weight of the pigmented inkjet ink. [0124] Suitable organic solvents include alcohols, aromatic hydrocarbons, ketones, esters, aliphatic hydrocarbons, higher fatty acids, carbitols. cellosolves, higher fatty acid esters. Suitable alcohols include, methanol, ethanol, propanol and 1-butanol, 1-pentanol, 2-butanol, t.-butanol. Suitable aromatic hydrocarbons include toluene, and xylene. Suitable ketones include methyl ethyl ketone, methyl isobutyl ketone, 2,4-pentanedione and hexafluoroacetone. Also glycol, glycoiethers, N-methylpyrroIidone, N,N-dimethylacetamid, N, N-dimethylformamid may be used, [0125] Suitable monomers and oligomers can be found in Polymer Handbook, Vol. 1 + 2. 4thth edition. Edited by J. BRANDRUP, et al. Wiley-Interscience , 1999. [0126] Suitable examples of monomers for curable pigmented inkjet inks include: acrylic acid, methacryiic acid, maleic acid (or their salts), maleic anhydride; alkyl(meth)acrylates (linear, branched and cycloalkyi) such as methyl(meth)acrylate, n-butyl(meth)acrylate, tert-butyl(meth)acrylate, cyclohexyl(meth)acrylate and 2-ethylhexyl(meth)acrylate; aryl(meth)acrylates such as benzyl(meth)acrylate and phenyl(meth)acrylate; hydroxyalkyl(meth)acrylates such as hydroxyethyl(meth)acrylate and hydroxypropyl(meth)acrylate; (meth)acrylates with other types of functionalities (e.g. oxirane, amino, fluoro, polyethylene oxide, phosphate-substituted) such as glycidyl (meth)acryiate, dimethylamlnoethyl(meth)acrylate, trifluoroethyl acrylate, methoxypolyethyleneglycol (meth)acrylate and tripropyleneglycol(meth)acrylate phosphate; allyl derivatives such as allyl glycidyl ether; styrenics such as styrene, 4-methylstyrene, 4-hydroxystyrene, and 4-acetoxystyrene; (meth)acrylonitrile; (meth)acrylamides (including N-mono and N,N-disubstituted) such as N-benzyl {meth)acrylamide; maleimides such as N-phenyl maleimide, N-benzyl maleimide and N-ethyl maleimide; vinyl derivatives such as vinylcaprolactam, vinylpyrrolidone, vinyiimidazole, vinylnaphthalene and vinyl halldes; vinylethers such as vinylmethyl ether; and vinylesters of carboxylic acids such as vinylacetate and vinylbutyrate. [0127] A combination of monomers, oligomers and/or prepolymers may also be used. The monomers, oligomers and/or prepolymers may possess different degrees of functionality, and a mixture including combinations of mono-, di-, tri-and higher functionality monomers, oligomers and/or prepolymers may be used. Surfactants [0128] The pigmented Inkjet ink according to the present Invention may contain at least one surfactant. The surfactant(s) can be anionic, cationic, non-ionic, or zwitter-ionic and are usually added in a total quantity less than 20 wt% based on the total weight of the pigmented Inkjet ink and particularly in a total less than 10 wt% based on the total weight of the pigmented Inkjet ink. [0129] Suitable surfactants for the pigmented Inkjet Ink according to the present invention include fatty acid salts, ester salts of a higher alcohol, alkylbenzene sulphonate salts, sulphosuccinate ester salts and phosphate ester salts of a higher alcohol (for example, sodium dodecyibenzenesulphonate and sodium dioctylsulphosuccinate), ethylene oxide adducts of a higher alcohol, ethylene oxide adducts of an alkylphenol, ethylene oxide adducts of a polyhydric alcohol fatty acid ester, and acetylene glycol and ethylene oxide adducts thereof (for example, polyoxyethylene nonyiphenyl ether, and SURFYNOL™ 104. 104H, 440, 465 and TG available from AIR PRODUCTS & CHEMICALS INC.). Biocides [0130] Suitable biocides for the pigmented Inkjet ink of the present invention include sodium dehydroacetate, 2-phenoxyethanoI, sodium benzoate, sodium pyridinethion-1-oxide, ethyl p-hydroxybenzoate and 1,2-benzisothiazolin-3-one and salts thereof. [0131] Preferred biocides are Bronidox™ available from HENKEL and Proxel™ GXL available from AVECIA. [0132] A biocide is preferably added in an amount of 0.001 to 3 wt%, more preferably 0.01 to 1.00 wt%, each based on the total weight of the pigmented Inkjet ink. pH adjusters [0133] The pigmented Inkjet ink according to the present invention may contain at least one pH adjuster. Suitable pH adjusters include NaOH, KOH, NEts, NH3, HCI, HNO3, H2S04and (poly)alkanolamines such as triethanolamine and 2-amino-2-methyl-1-propanoL Preferred pH adjusters are NaOH and H2SO4. Humectants/Penetrants [0134] Suitable humectants include triacetin, N-methyl-2-pyrrolidone, glycerol, urea, thiourea, ethylene urea, alkyl urea, alkyl thiourea, dialkyi urea and dialkyi thiourea, diols, including ethanediols, propanediols, propanetriols, butanediols, pentanediols, and hexanediols; glycols, including propylene glycol, polypropylene glycol, ethylene glycol, polyethylene glycol, diethylene glycol, tetraethylene glycol, and mixtures and derivatives thereof. Preferred humectants are triethylene glycol mono butylether, glycerol and 1,2-hexanediol. The humectant is preferably added to the Inkjet ink formulation in an amount of 0.1 to 40 wt% of the formulation, more preferably 0.1 to 10 wt% of the formulation, and most preferably approximately 4.0 to 6.0 wt%. Preparation of a pigmented Inkjet ink [0135] The pigmented Inkjet ink according to the present invention may be prepared by precipitating or milling the pigment in the dispersion medium in the presence of the polymeric dispersant. [0136] Mixing apparatuses may include a pressure kneader, an open kneader, a planetary mixer, a dissolver, and a Dalton Universal Mixer. Suitable milling and dispersion apparatuses are a ball mill, a pearl mill, a colloid mill, a high-speed disperser, double rollers, a bead mill, a paint conditioner, and triple rollers. The dispersions may also be prepared using ultrasonic energy. [0137] Many different types of materials may be used as milling media, such as glasses, ceramics, metals, and plastics. In a preferred embodiment, the grinding media can comprise particles, preferably substantially spherical in shape, e.g. beads consisting essentially of a polymeric resin or yttrium stabilized zirconium beads. [0138] In the process of mixing, milling and dispersion, each process is preferably performed with cooling to prevent build up of heat. [0139] In the process of mixing, milling and dispersion, each process is performed with cooling to prevent build up of heat, and for radiation curable Inkjet inks as much as possible under light conditions in which actinic radiation has been substantially excluded. [0140] The Inkjet ink according to the present invention may contain more than one pigment, the Inkjet ink may be prepared using separate dispersions for each pigment, or alternatively several pigments may be mixed and co-milled in preparing the dispersion. [0141] The dispersion process can be carried out in a continuous, batch or semi-batch mode. [0142] The preferred amounts and ratios of the ingredients of the mill grind will vary widely depending upon the specific materials and the intended applications. The contents of the milling mixture comprise the mill grind and the milling media. The mill grind comprises pigment, polymeric dispersant and a liquid carrier such as water. For Inkjet inks, the pigment is usually present in the mill grind at 1 to 50 wt%, excluding the milling media. The weight ratio of pigment over polymeric dispersant is 20:1 to 1:2. 0143] The milling time can vary widely and depends upon the pigment, mechanical means and residence conditions selected, the initial and desired final particle size, etc. In the present invention pigment dispersions with an average particle size of less than 100 nm may be prepared. 0144] After milling is completed, the milling media is separated from the milled particulate product (in either a dry or liquid dispersion form) using conventional separation techniques, such as by filtration, sieving through a mesh screen, and the like. Often the sieve is built into the mill, e.g. for a bead mill. The milled pigment concentrate is preferably separated from the milling media by filtration. 0145] In general it is desirable to make the Inkjet inks in the form of a concentrated mill grind, which is subsequently diluted to the appropriate concentration for use in the Inkjet printing system. This technique permits preparation of a greater quantity of pigmented ink from the equipment. By dilution, the Inkjet ink is adjusted to the desired viscosity, surface tension, colour, hue, saturation density, and print area coverage for the particular application. Spectral Separation Factor 0146] The spectral separation factor SSF was found to be an excellent measure to characterize a pigmented Inkjet ink, as it takes into account properties related to light-absorption (e.g. wavelength of maximum absorbance Amax, shape of the absorption spectrum and absorbance-value at Amax) as well as properties related to the dispersion quality and stability. 0147] A measurement of the absorbance at a higher wavelength gives an indication on the shape of the absorption spectrum. The dispersion quality can be evaluated based on the phenomenon of light scattering induced by solid particles in solutions. When measured in transmission, light scattering in pigment inks may be detected as an increased absorbance at higher wavelengths than the absorbance peak of the actual pigment. The dispersion stability can be evaluated by comparing the SSF before and after a heat treatment of e.g. a week at 800C. [0148] The spectral separation factor SSF of the ink is calculated by using the data of the recorded spectrum of an ink solution or a jetted image on a substrate and comparing the maximum absorbance to the absorbance at a higher reference wavelength Aref .The spectral separation factor is calculated as the ratio of the maximum absorbance Amax over the absorbance Aref at a reference wavelength. [0149] The SSF is an excellent tool to design inkjet ink sets with large colour gamut. Often inkjet ink sets are now commercialized, wherein the different inks are not sufficiently matched with each other. For example, the combined absorption of all inks does not give a complete absorption over the whole visible spectrum, e.g. "gaps" exist between the absorption spectra of the colorants. Another problem is that one Ink might be absorbing in the range of another ink. The resulting colour gamut of these inkjet ink sets is low or mediocre. EXAMPLES Materials [0150] All materials used in the following examples were readily available from standard sources such as Aldrich Chemical Co. (Belgium) and Acros (Belgium) unless otherwise specified. The water used was deionized water. [0151] SMA 1000P is a styrene maleic anhydride alternating copolymer available from ATOFINA. VERSICOL E5 was obtained from ALLIED COLLOIDS MANUFACTURING CO LTD as a 25% wt solution of pAA in water. This solution was freeze-dried to afford the dry powder of polyacrylic acid that was subsequently used for modification reactions, Raney Nickel™ is a catalysator from DEGUSSA. WAKO™ V-601 is dimethyl 2.2'-azobisisobutyrate from Wako Pure Chemical Industries, Ltd. MSTY or alpha methyistyrene dimer is 2,4-diphenyl-4-methy!-1-pentene from Goi Chemical Co., Ltd. AA is acrylic acid from from ACROS. MAA is methacrylic acid from ACROS. BA is butyl acrylate from ACROS. EHA is 2-ethyl hexyl acrylate from ACROS. STY is styrene from ACROS. Proxel™ Ultra 5 from AVECIA. Glycerol from ACROS. 1,2-propanediol from CALDIC CHEMIE NV. SurfynoFM 104H from AIR PRODUCTS & CHEMICALS INC. PY12 is the abbreviation for C.l. Pigment Yellow 12 for which Permanent™ Yellow DHG from CLARIANT was used. PY13 is the abbreviation for C.l. Pigment Yellow 13 for which Irgalite™ Yellow BAW from CIBA was used PY14 is the abbreviation for C.l. Pigment Yellow 14 for which Sunbrite Yellow 14/274-2168 from SUN CHEMICAL was used. PY17 is the abbreviation for C.l. Pigment Yellow 17 for which Graphtol™ Yellow GG from CLARIANT was used. PY74 is the abbreviation for C.l. Pigment Yellow 74 for which Hansa™ Brilliant Yellow 5GX03 from CLARIANT was used. PR122 is the abbreviation for C.l. Pigment Red 122 for which Ink jet magenta E02VP2621 from CLARIANT was used. PV19 is the abbreviation for C.l. Pigment Violet 19 for which Hostapenn™ Red E5B02 from CLARIANT was used. [0152] The chemical structure of the colour pigments used is listed in Table 5. Table 5 If the colour ink has a maximum absorbance Amax between 500 and 600 nm then the absorbance Aref must be determined at a reference wavelength of 650 nm, • If the colour ink has a maximum absorbance Amax between 600 and 700 nm then the absorbance Aret must be determined at a reference wavelength of 830 nm. [0154] The absorbance was determined in transmission with a Shimadzu UV-2101 PC double beam-spectrophotometer. The ink was diluted to have a pigment concentration of 0.002%. In the case of a magenta ink, the ink was diluted to have a pigment concentration of 0.005%. A spectrophotometric measurement of the UV-VIS-NIR absorption spectrum of the diluted ink was perfonned in transmission-mode with a double beam-spectrophotometer using the settings of Table 6. Quartz cells with a path length of 10 mm were used and water was chosen as a blank. [0155] Efficient pigmented Inkjet inks exhibiting a narrow absorption spectrum and a high maximum absorbance have a value for SSF of at least 30. 2. Dispersion stability [0156] The dispersion stability was evaluated by comparing the SSF before and after a heat treatment of one week at SO^'C. Pigmented inkjet inks exhibiting good dispersion stability have a SSF after heat treatment still larger than 30. 3. Polymer analysis [0157] Unless othen/vise specified all polymers have been characterized with gel permeation chromatography (GPC) and nuclear magnetic resonance spectroscopy (NMR) using the following methods. Random or block copolymers were analyzed with NMR by dissolving them in a deuterated solvent. For 'H-NMR ± 20 mg polymer was dissolved in 0.8 mL CDCI3 or DMS0-d6 or acetonltrile-d3 or D2O (with or without NaOD addition). Spectra were recorded on a Varian Inova 400 MHz instrument equipped with an ID-probe. For i^C-NMR ± 200 mg polymer was dissolved in 0.8 mL CDCis or DMS0-d6 or acetonitrile-d3 or D2O (with or without NaOD addition). Spectra were recorded on a Varian Gemini2000 300 MHz equipped with a SW-probe. [0158] Mn, Mwand polydispersity (PD) values were determined using gel permeation chromatography. For polymers dissolvable in organic solvents PL-mixed B columns (Polymer Laboratories Ltd) were used with THF+5% acetic acid as mobile phase using polystyrene with known molecular weights as calibration standards. These polymers were dissolved in the mobile phase at a concentration of 1mg/mL. For polymers dissolvable in water PL Aquagel OH-60, OH-50, OH-40 and/or OH-30 (Polymer Laboratories Ltd) column combinations were used depending on the molecular weight region of the polymers under investigation. As mobile phase water/methanol mixtures adjusted to pH 9.2 with e.g. disodiumhydrogen phosphate were used with or without the addition of neutral salts e.g. sodium nitrate. As calibration standards polyacrylic acids with known molecular weights were used. The polymers were dissolved in either water or water made basic with ammonium hydroxide at a concentration of 1 mg/mL. Refractive index detection was used. [0159] An example is now given to illustrate the calculation of the average composition of a random (= statistical) copolymer P(MAA-c-EHA). The Mn of the copolymer was determined with GPC to be 5000. The molar percentage of each monomer type by NMR was determined to be: 45 mole% MAA and 55 mole% EHA. Calculation: (0.45 X MMAA) + (0.55 x MEHA) = 140.09 5000 /140.09 = total number of monomeric units in average polymer chain = 36 Average number of MAA units = 0.45 x (5000/140.09) = 16 units Average number of EHA units = 0.55 x (5000/140.09) = 20 units Thus, the average composition is P(MAAi6-c-EHA2o). 4. Particle size [0160] The particle size of pigment particles in pigmented Inkjet ink was determined by photon correlation spectroscopy at a wavelength of 633 nm with a 4mW HeNe laser on a diluted sample of the pigmented Inkjet ink. The particle size analyzer used was a Malvern™ nano-S available from Goffin-Meyvis. [0161] The sample was prepared by addition of one drop of ink to a cuvet containing 1.5 mL water and mixed until a homogenous sample was obtained. The measured particle size is the average value of 3 consecutive measurements consisting of 6 runs of 20 seconds. For good Inkjet characteristics (jetting characteristics and print quality) the average particle size of the dispersed particles is preferably below 150 nm. 5. Calculation of %MW [0162] The %MW is calculated as the ratio of the molecular weight of the pending chromophore group over the molecular weight of the colour pigment multiplied by 100. EXAMPLE 1 [0163] This example illustrates that stable Inkjet inks of different pigments can be prepared using the same polymeric dispersant having at most 30 % of the monomer units of the polymeric backbone carrying a pending chromophore group. The polymeric backbone of the dispersant is a homopolymer, which is known to have poor dispersing capability. Polymeric dispersants DISP-1 to DISP-4 [0164] The polymeric dispersants DISP-1 to DISP-4 were prepared by copolymerizing a monomer MONC already containing a chromophore group. Chromophore MC-2 [0165] The formation of the chromophore MC-2 was accomplished by diazotation of compound MC-1D and subsequent coupling in the compound MC-2B. [0166] Preparation of compound MC-1C The vessel used to carry out this reaction was a 3 necked flask equipped with a stirrer, a cooler and a dropping-funnel. To a solution of 13.9 g (0.1 mol) 2-nitrophenol (compound MC-1 A) in 100 mL dimethylfomriamide was added 31.8 g (0,3 mol) of sodiumcarbonate. The mixture was heated to a temperature of about 150-160°C and 16.1 g (0.2 mol) of 2-chloroethanol (compound MC-1B) was added drop-wise. After addition of the 2-chloroethanol, the temperature was maintained at a temperature between 150 and 1600C for about 7 hours. The charge was cooled while stirring and the formed inorganic salts were filtered off. The filtrate was concentrated by evaporation at a temperature of 4000 until a red coloured mixture of oil and solid was formed. Then the oil was dissolved in methylenechloride and the inorganic salts were filtered off. The filtrate was evaporated for a second time and the fomied yellow oil was purified by preparative column chromatography. The yield of compound MC-1C was 79%. [0167] Preparation of compound MC-1D Compound MC-1D was made by catalytic reduction of compound MC-1C with hydrogen. A reactor was filled with 18.3 g (0.1 mol) of compound MC-1C in 100 mL ethanol and 1 mL of Raney Nickel™ slurry was added. The volume of the mixture was set to 150 mL with ethanol and the reduction was carried out at a starting temperature of 35°C under an initial H2-pressure of 60 bar. By shaking the reactor, the exothermic reaction started and the temperature increased to about 60°C. After reduction, the charge was mixed during 1 hour and the Raney Nicke'^ was filtered off. The filtrate was evaporated at a temperature of 50°C until the desired white crystalline product MC-1D appeared. The yield of compound MC-1D was 95%. Synthesis scheme of compound MC-1D : [0168] Preparation of chromophore MC-2 29.98 mL (0.36 mo!) of concentrated hydrochloric acid was added to a suspension of 15.3 g (0.1 mol) of compound MC-1D in 300 mL water. This mixture was cooled to a temperature of about 0-5°C and 8.97 g (0.13 mol) of sodiumnitrite was added. The diazonium-salt was kept at a temperature between 0 and 5'C. After 15 minutes the excess of nitrite was neutralized by adding 3.0 g (0.03 mol) of sulfamic acid and a pH of 7 was obtained by adding 25.2 g (0.3 mol) of sodiumcarbonate. While the diazionium-salt was made, 20.7 g (0.1 mol) of MC-2B from ACROS was dissolved in a mixture of 500 mL methanol and 10.0 mL (0.1 mol) 29 % sodiumhydroxide-solution. This solution was added drop-wise into the diazonium-salt solution and a yellow suspension was immediately formed. The temperature was maintained between 0 and 5°C for about 3 hours and the yellow product MC-2 was filtered and washed with methanol. The yield of the chromophore MC-2 was 92 %. Synthesis scheme of the chromophore MC-2 : Synthesis of the monomer MONC [0169] [0170] Ethylacetate (480 mL) was cooled to O°C. Acrylic acid (19.0 g, 0,264 mol) and 2,6-df-tert-butyl-4- methylphenol (0.2 g, 0.00088 mol) were added. Triethyiamine (26.7 g, 0.264 mol) was added drop-wise while the temperature was maintained between -5°C and 0°C. Finally benzene sulfonyl chloride (22.3 g, 0.126 mol) was added drop-wise. Triethyiamine hydrochloride precipitated. The reaction mixture was allowed to stir for 1 hour at 0°C resulting in the formation of the symmetric anhydride. To this mixture N-hydroxysuccinimide (0.7 g, 0.006 mol) and MC-2 (22.3 g, 0.06 mol) were added at 5°C. The reaction mixture was refluxed (78°C) for about 17 hours. The reaction mixture was diluted with EtOAc (100 mL) and extracted with distilled water (400 mL). The organic layer was separated and again extracted with a mixture of an aqueous solution of hydrochloric acid and distilled water (1/5). Finally the organic layer was washed with water and dried over MgS04. After evaporation of the solvent, the residue was suspended into distilled water and stirred for 45 minutes. Filtration provided a yellow solid. Synthesis of polymeric dispersant DISP-1 [0172] Tiie polymeric dispersant DISP-1 was prepared by copolymerizing the monomer MONC with AA monomers in 90/10 molar ratio of AA/MONC. [0173] The synthesis was performed in a 250 mL three-necked round-bottomed flask which was equipped with a cooling unit, a bubble counter on top and a stirring bar. 6.04 g of the monomer AA, 3.96 g of the monomer MONC, 0.43 g of the initiator WAKO™ V601, 0.44 g of the transfer agent MSTY were introduced in 89.13 g of dioxane. The total weight % concentration of the monomers was 10. The reaction mixture was degassed by bubbling nitrogen in the solution for approximately 30 min. The flask was immersed into an oil bath and heated to SO'^C and the mixture was further reacted for 20 hours. After polymerization, the reaction mixture was cooled down to room temperature. The polymer was precipitated in 1000 mL of water (acidified with HCI) and filtered off, followed by drying under vacuum at 40°C for 24 hours to afford 8.4 g of yellow powder of DlSP-1. (Yield=77.2%) [0174] Analytical results of DISP-1: GPC: Mn = 2745; Mw = 5478; PD= 2.00 (GPC in THF+5% acetic acid; calibrated vs. PS-standards) NMR: AA/MONC molar ratio was 90/10. On average DISP-1 contained 23.01 AA monomeric units and 2.55 MONC monomeric units. Synthesis of polymeric dispersant DISP-2 [0175] The polymeric dispersant DISP-2 was prepared by copolymerizing the monomer MONC with AA monomers in 81/19 molar ratio of AA/MONC. [0176] The synthesis was perfonned in a 250 mL three-necked round-bottomed flask which was equipped with a cooling unit, a bubble counter on top and a stin-ing bar. 4.04 g of the monomer AA, 5.96 g of the monomer MONC, 0.32 g of the initiator WAKO™ V601, 0.33 g of the transfer agent MSTY were introduced in 89.35 g of dioxane. The total weight % concentration of the monomers was 10. The reaction mixture was degassed by bubbling nitrogen in the solution for approximately 30 min. The flask was immersed into an oil bath and heated to 80°0 and the mixture was further reacted for 20 hours. After polymerization, the reaction mixture was cooled down to room temperature. The polymer was precipitated in 1000 mL of water (acidified with HCI) and filtered off, followed by drying under vacuum at 40°C for 24 hours to afford 7.5 g of yellow powder of DISP-2. (Yield=70.4%) [0177] Analytical results of DISP-2: GPC: Mn = 1845; Mw = 3187; PD= 1.73 (GPC in THF+5% acetic acid; calibrated vs. PS-standards) NMR: AA/MONC molar ratio was 81/19. On average DISP-2 contained 10.73 AA monomeric units and 2.51 MONC monomeric units. Synthesis of polymeric dispersant DISP-3 [0178] The polymeric dispersant DISP-3 was prepared by copolymerizing the monomer MONC with AA monomers in 71/29 molar ratio of AA/MONC. [0179] The synthesis was performed in a 100 mL three-necked round-bottomed flask which was equipped with a cooling unit, a bubble counter on top and a stin-ing bar. 1.42 g of the monomer AA. 3.58 g of the monomer MONC, 0.21 g of the initiator WAKO™ V601. 0.22 g of the transfer agent MSTY were introduced in 44.57 g of dioxane. The total weight % concentration of the monomers was 10. The reaction mixture was degassed by bubbling nitrogen in the solution for approximately 30 min. The flask was immersed into an oil bath and heated to 80°C and the mixture was further reacted for 20 hours. After polymerization, the reaction mixture was cooled down to room temperature. The polymer was precipitated in 500 mL of water (acidified with HCI) and filtered off, followed by drying under vacuum at 40°C for 24 hours to afford 4.6 g of yellow powder of DISP-3. (Yield=84.7%) [0180] Analytical results of DISP-3: GPC: Mn = 2633; Mw = 3982; PD= 1.51 (GPC in THF+5% acetic acid; calibrated vs. PS-standards) NMR: AA/MONC molar ratio was 71/29. On average DISP-3 contained 10.71 AA monomeric units and 4.37 MONC monomeric units. Synthesis of polymeric dispersant DISP-4 [0181] The polymeric dispersant DISP-4 was prepared by copolymerizlng the monomer MONC with AA monomers in 55/45 molar ratio of AA/MONC. [0182] The synthesis was performed in a 100 mL three-necked round-bottomed flask which was equipped with a cooling unit, a bubble counter on top and a stirring bar. 0.72 g of the monomer AA, 4,28 g of the monomer MONC, 0.21 g of the initiator WAKO™ V601, 0.22 g of the transfer agent MSTY were introduced in 44.57 g of dioxane. The total weight % concentration of the monomers was 10. The reaction mixture was degassed by bubbling nitrogen in the solution for approximately 30 min. The flask was immersed into an oil bath and heated to 80°C and the mixture was further reacted for 20 hours. After polymerization, the reaction mixture was cooled down to room temperature. The polymer was precipitated in 500 mL of water (acidified with HCI) and filtered off, followed by drying under vacuum at 40°C for 24 hours to afford 5 g of yellow powder of DISP-4. (Yield=92%) [0183] Analytical results of DISP-4: GPC: Mn = 2441; Mw = 3458; PD= 1.42 (GPC in THF+5% acetic acid; calibrated vs. PS-standards) NMR: AA/MONC molar ratio was 55/45. On average DISP-4 contained 5.81 AA monomeric units and 4.75 MONC monomeric units. Polymeric dispersants DISP-5 and DlSP-6 [0184] VERSICOL E5, a homopolymer of acrylic acid was used as polymeric dispersant DISP-5. The polymeric dispersant DISP-6 was prepared by modifying VERSICOL E5 through esterification with the chromophore MC-2.The resulting pending chromophore group PC-2 was linked by C* to the polymeric backbone through a linking group L containing an ester Synthesis of polymeric dispersant DISP-6 [0185] The reaction was performed in a three-necked round-bottomed flask that was equipped with a stirrer, a cooler and a bubble-counter on top. 4 g of the polyacrylic acid homopolymer (VERSICOL E5 as powder form) was introduced in the flask and dissolved in 40 mL of anhydrous dimethylacetamide (DMA). A slight flux of nitrogen was circulated through the flask. After (VERSICOL E5) was dissolved, 4.48 g of 1 .r-carbonyldiimidazole (CDI) was added and CO2 evolution was observed. The reaction was further stirred at room temperature for 1 hour after which 4.10 g of the chromophore MC-2 in combination with 169 mg of the catalyst dimethylaminopyridine (DMAP) were added. The heterogeneous mixture was stirred and heated to 80°C for 20 hours. The reaction mixture was cooled to room temperature and was treated by slowly adding 10 mL of a 2% v/v of acetic acid/water solution. The heterogeneous mixture obtained was basified to pH 10 with NaOH . and filtrated to remove remaining precipitates. The solution was dialyzed in water (Regenerated Cellulose Dialysis Membrane of MWCO of 1,000 Dalton - SPECTRA/POR™ 6) for two days and precipitates that appeared were filtered off again. The obtained solution was freeze-dried to give a fluffy yellow powder. Yield of DISP-6 was 4.8 g. [0186] Analytical results of DISP-6: GPC: Mn = 1208; Mw = 4960; PD= 4.11 (aqueous GPC; calibrated vs. PAA-standards) The degree of substitution was determined by "H-NMR-spectroscopy and expressed as the percentage of AA monomeric units. The degree of substitution of DISP-6 with the chromophore MC-2 was 13 molar %. Preparation of Inkjet ink [0187] All inkjet inks were prepared in the same manner to obtain a composition as described in Table 7, except that different pigments and polymeric [0188] An ink composition was made by mixing the pigment, the dispersant and about half of the water with a dissolverand subsequently treating this mixture with a roller mill procedure using yttrium-stabilised zirconium oxide-beads of 0.4 mm diameter ("high wear resistant zirconia grinding media" from TOSOH Co.). A polyethylene flask of 60mL was filled to half its volume with grinding beads and 20g of the mixture. The flask was closed with a lit and put on the roller mill for three days. The speed was set at 150 rpm. After milling the dispersion was separated from the beads using a filter cloth. Under stimng, the surfactant SurfynoI™ 104H and the biocide Proxel™ Ultra 5, glycerol, 1,2-propanediol and the remaining water were added. This mixture was stirred for 10 minutes and filtered. The filtration was peri'ormed in two steps. First, the ink mixture is filtered using a (plastipak) syringe with a microfiber disposable filtercapsule with 1pm pore diameter (GF/B microfiber from Whatman Inc.) Then the same [0191] From Table 9 it is clear that, although a homopolymer was used as the polymeric backbone for the dispersant, in the inventive pigmented Inkjet inks INV-1 to INV-5 the pigments PY17 and PY74 were dispersed exhibiting a high dispersion quality and stability. The SSF of the inventive yellow Inkjet inks INV-1 to INV-5 all were larger than 30 and therefore can be used to compose Inkjet ink sets with high colour gamut. EXAMPLE 2 [0192] This example illustrates that Inkjet inks of different pigments can be prepared with high dispersion quality using the same polymeric dispersant having at least 2 % of the monomer units of the polymeric backbone carrying a pending chromophore group. The polymeric backbone of the dispersant is a alternating polymer, which is known to have poor dispersing capability. Polymeric dispersants DISP-7 to DISP-1Q [0193] The alternating copolymer SMA 1000P was used as polymeric dispersant DlSP-7 to prepare a comparative Inkjet ink. DISP-7 was then used for preparing styrene maleic acid copolymers modified by chromophores MC-7andMC-12. Chromophore MC-7 [0194] The synthesis of the chromophore MC-7 will now be described. [0195] Preparation of chromophore MC-7 6.9 g (45.2 mmol) of compound MC-1D was mixed with 40 mL H2O and 10 mL methanol. Then, 4.5 g (54 mmol) of compound MC-1F was added and the mixture was stirred for 30 minutes. This is mixture A-MC-7. 5.8 g (45.2 mmol) of compound MC-7A was mixed in 150 mL H2O. 16.2 g (162 mmol) of concentrated HCI was added and the mixture was then cooled to a temperature of about 0 to 5°C. 4.05 g (58.8 mmol) of sodium nitrite was added and the mixture was kept at a temperature between 0 and 5°C. After 15 minutes the excess of nitrite was neutralized by adding 1.36 g (13.6 mmol) of sulfamic acid and a pH of 7 was obtained by adding 11.4 g (136 mmol) of sodium carbonate. The mixture A-MC-7 was added and the mixture was stirred for 1 hour at a temperature between 0 and 5°C. The yellow product was filtered and washed with methanol. The yield of the chromophore MC-7 was 80%. Synthesis scheme of chromophore MC-7 : [0196] The synthesis of the chromophore MC-12 will now be described. [0197] Preparation of compound MC-8B The vessel used to carry out this reaction was a 3 necked flask equipped with a stin-er, a cooler and a dropping-funnel. To a solution of 140 g (1 mol) 3-nitrophenol (compound MC-8A) and 1.4 L N-methylpyrolidone was added 190 mL sodium methylate 30% (1.025 mol). The mixture was destillated at a temperature of lOO°C and 80 mbar pressure. After the destination 87 mL (1.3 mol) of 2-chloroethanol (compound MC-1B) was added dropwise. After addition of the 2-chloroethanol, the mixture was heated to a temperature of about 120°C for 3 hours. The reaction mixture was poured into 6 L of water with 85 mL HCI cone. The product was filtrated. The yield of compound MC-8B was 27%. Synthesis scheme of compound MC-8B : [0198] Preparation of compound MC-8C Compound MC-8C was made by catalytic reduction of compound MC-8B with hydrogen. A reactor was filled with 101 g (0.55 mol) of compound MC-8B in 700 mL ethanol and 11 mL of Raney Nickel™ slurry was added. The reduction was earned out at a starting temperature of 75°C under an initial H2-pressure of 46 bar. After reduction, the charge was mixed during 1 hour and the Raney Nickel™ was filtered off. The filtrate was evaporated at a temperature of 50°C until the desired white crystalline product MC-8C appeared. The yield of compound MC-8C was 95%. Synthesis scheme of compound MC-8C : [0199] Preparation of chromophore MC-12 6.9 g (45.2 mmol) of compound MC-8C was mixed with 40 mL H2O and 10 mL methanol. Then, 4.5 g (54 mmol) of compound MC-1F was added and the mixture was stirred for 30 minutes. This is mixture A-MC-12. 5.8 g (45.2 mmol) of compound MC-7A was added to a mixture of 15 mL H2O and 50 mL methanol. 16.2 g (162 mmol) of concentrated HCI was added. The solution was cooled to a temperature of about 0 to 5°C. 4.05 g (58.8 mmol) of sodium nitrite was added and the mixture was kept at a temperature between 0 and 5°C. After 15 minutes the excess of nitrite was neutralized by adding 1.36 g (13.6 mmol) of sulfamic acid and a pH of 7 was obtained by adding 11.4 g (136 mmol) of sodium carbonate. The mixture A-MC-12 was added and the mixture was stirred for 1 hour at a temperature between 0 and 5°C. The stirring was continued for 1 hour at a temperature of 20°C. The yellow product was filtered and washed with methanol. The yield of the chromophore MC-12 was 91%. Synthesis scheme of the chromophore MC-12 : Synthesis of polymeric dispersants DISP-7 and DISP-8 [0200] The alternating copolymer SMA 1000P (also used below as DISP-7 to prepare comparative Inkjet inks) was used for preparing styrene maleic acid copolymers modified by the chromophore MC-7.The resulting pending chromophore group PC-7, consisting of 35 atoms, was linked by C* to the polymeric backbone through a linking group L containing an ester bond; [0201] The synthesis is based on a kinetic study on the mono-esterification of styrene maleic anhydride copolymers disclosed by [0202] The styrene maleic anhydride copolymer SMA 1000P was dissolved in a 1/1 solvent mixture of DMA (dimethylacetamide) and MEK. Then 5 mole% of MC-7. based on the anhydride units in the polymer, was added and the reaction was allowed to continue for 24 hours at room temperature. After 24 hours, the polymer was precipitated with methyl t-butyl ether, isolated by filtration and washed several times with methyl t-butyl ether. The isolated polymer was suspended in water and the pH was adjusted to 10, using 5 N NaOH. The mixture was stirred until the polymer dissolved. Upon complete dissolution, the pH was adjusted to 2. using 6N HCl. The polymeric dispersant was precipitated from the medium, isolated by filtration and dried. The degree of substitution was determined by ""H-NMR-spectroscopy and expressed as the percentage of esterified maleic acid units. The degree of substitution of DISP-8 with the chromophore MC-7 was 2%. [0204] The polymeric dispersant DISP-10 was prepared by modifying the alternating copolymer SMA 1000P (DISP-7) through esterification with the chromophore MC-12. [0205] The pending chromophore group PC-12 of DISP-10 is structurally the same as the pending chromophore group PC-7 of the polymeric dispersant DISP-8, except that it is connected through the same linking group L by a different C* to the polymeric backbone of DISP-10, i.e. linked in para instead of ortho position. [0206] The polymeric dispersant DISP-10 was prepared in the same manner as DlSP-8 except that the chromophore MC-7 was replaced by MC-12. The degree of substitution of DISP-10 with the chromophore MC-12 was found to be 2%. Preparation of Inkjet ink [0207] All Inkjet inks were prepared in the same manner to obtain a composition as described in Table 10, except that different pigments and dispersants were used. [0208] An ink composition was made by mixing the pigment, the dispersant and about half of the water with a dissolver and subsequently treating this mixture with a roller mill procedure using yttrium-stabilised zirconium oxide-beads of 0.4 mm diameter ("high wear resistant zirconia grinding media" from TOSOH Co.). A polyethylene flask of 60mL was filled to half its volume with grinding beads and 20g of the mixture. The flask was closed with a lit and put on the roller mill for three days. The speed was set at 150 rpm. After milling the dispersion was separated from the beads using a filter cloth. Under stirring, the surfactant Surfynol™ 104H and the biocide Proxel™ Ultra 5, glycerol, 1,2-propanediol and the remaining water were added. This mixture was stirred for 10 minutes and filtered. The filtration was performed in two steps. First, the ink mixture is filtered using a (plastipak) syringe with a microfiber disposable filtercapsule with 1|jm pore diameter (GF/B microfiber from Whatman Inc.) Then the same procedure is repeated on the filtrate. After the second filtration the ink is ready for evaluation. [0209] Using the above method, the comparative Inkjet ink COMP-5 and the inventive Inkjet inks INV-6 to INV-11 were prepared according to Table 11. Results ana evaiuaiion [0210] The spectral separation factor (SSF) was determined for each sample directly after preparation. The results are listed in Table 12 together with the calculated values for the %MW. [0211] From Table 12 it is clear that, although an alternating polymer was used as the polymeric backbone for the dispersant, in the inventive pigmented Inkjet inks lNV-6 to INV-11 the pigments were dispersed exhibiting a high dispersion quality. The SSF of the inventive yellow Inkjet inks INV-6 to INV-11 all were larger than 30 and therefore can be used to compose Inkjet ink sets with high colour gamut. Furthermore, one can see that the same polymeric dispersant with a pending chromofore group can be used for different pigments. EXAMPLE 3 [0212] This example illustrates that a stable magenta inkjet ink of the pigment PR122 can be prepared using a polymeric dispersant having less than 30 % of the monomer units of the polymeric backbone carrying a pending chromophore group. The polymeric backbone of the dispersant is a homopolymer, which is known to have poor dispersing capability. Polymeric dispersant DISP-11 [0213] The polymeric dispersant D!SP-11 was prepared by modifying VERSICOL E5 (DISP-5) through esterification with the chromophore MAG-1. [0214] The resulting pending chromophore group PM-1 was linked by N* to the polymeric backbone through a linking group L containing an ester bond. Chromophore MAG-1 [0215] 25 g (80 mmol) PV19 was suspended in 200 mL DMSO. 17.9 g (160 mmol) KOtBu was added and the suspension was heated to 70'C. 21.64 g (104 mmol) 2-(2-bromoethoxy)-tetrahydro-2H-pyran was added and the reaction was allowed to continue for 3 hours at 70"C. After cooling down to room temperature, 300 mL of water is added. The crude intermediate was isolated by filtration, washed with water and dried. The crude intermediate was suspended in 500 mL acetone. 8.0 mL HCI (cone.) was added and the reaction was allowed to continue for 1 hour at room temperature. N-hydroxyethyl-quinacridone was isolated by filtration, washed with aceton, resuspended in aceton, again isolated by filtration and dried. The crude product was used for polymer modification without further purification. The yield was 92 %. [0216] Synthesis scheme of MAG-1: Synthesis of polymeric dispersant DISP-11 [0217] The reaction was perfonned in a three-necked round-bottomed flask that was equipped with a stirrer, a cooler and a bubble-counter on top. 2 g of the polyacrylic acid homopolymer (VERSICOL E5 as powder fomi) was introduced in the flask and dissolved in 40 mL of anhydrous dimethylacetamide (DMA). A slight flux of nitrogen was circulated through the flask. After (VERSICOL E5) was dissolved, 2.24 g of 1.1'-carbonyldiimidazole (GDI) was added and CO2 evolution was observed. The reaction was further stirred at room temperature for 1 hour after which 1.97 g of the chromophore MAG-1 in combination with 84.5 mg of the catalyst dimethylaminopyridine (DMAP) were added. The heterogeneous mixture was stirred and heated to BC'C for 20 hours. The reaction mixture was cooled to room temperature and was treated by slowly adding 10 mL of a 2% v/v of acetic acid/water solution. The heterogeneous mixture obtained was basified to pH 10 with NaOH and filtrated to remove remaining precipitates. The solution was dialyzed in water (Regenerated Cellulose Dialysis Membrane of MWCO of 1,000 Dalton - SPECTRA/POR™ 6) for two days and precipitates that appeared were filtered off again. The obtained solution was freeze-dried to give a reddish and fluffy powder. Yield of DISP-11 was 4.8 g. [0218] Analytical results of DISP-11: GPC: Mn = 3213; Mw = 16601; PD= 5.17 (aqueous GPC; calibrated vs. PAA-standards) Although that the desired modification did take place, the degree of substitution of DISP-11 with the chromophore MAG-1 could not be estimated by NMR. Preparation of inkjet ink [0219] The magenta inkjet inks were prepared in the same manner to obtain a composition as described in Table 13, except that different dispersants were used. [0220] An ink composition was made by mixing the pigment, the dispersant and about half of the water with a dissolver and subsequently treating this mixture with a roller mill procedure using yttrium-stabilised zirconium oxide-beads of 0.4 mm diameter ("high wear resistant zirconia grinding media" from TOSOH Co.). A polyethylene flask of 60mL was filled to half its volume with grinding beads and 20g of the mixture. The flask was closed with a lit and put on the roller mill for three days. The speed was set at 150 rpm. After milling the dispersion was separated from the beads using a filter cloth. Under stirring, the surfactant Surfynoi™ 104H and the biocide ProxeF^ Ultra 5, glycerol, 1,2-propanediol and the remaining water were added. This mixture was stirred for 10 minutes and filtered. The filtration was perfomied in two steps. First, the ink mixture is filtered using a (plastipak) syringe with a microfiber disposable filtercapsule with 1pm pore diameter (GF/B microfiber from Whatman Inc.) Then the same procedure is repeated on the filtrate. After the second filtration the ink is ready for evaluation. [0221] Using the above method, the comparative inkjet ink COMP-6 and the inventive inkjet ink INV-12 were prepared according to Table 14. Results and evaluation [0222] The spectral separation factor (SSF) was determined for each sample directly after preparation. The degree of modification with the chromophore MAG-1 could not be determined due to poor solubility. The results are listed in Table 15 together with the calculated values for the %MW. [0223] From Table 15 it is clear that, although an homopolymer was used as the polymeric backbone for the dispersant, in the inventive pigmented inkjet ink INV-12 the pigment PR122 was dispersed exhibiting a high dispersion quality and stability. The SSF of the inventive magenta Inkjet ink INV-12 was larger than 30 and therefore can be used to compose inkjet ink sets with high colour gamut. Claims 1. A pigment dispersion comprising a colour pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group wherein said at least one pending chromophore group is a derivative from a colour pigment selected from the group consisting of monoazo pigments, disazo pigments, p-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrroio-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments; said at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; said linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; said polymeric dispersant has a polymeric backbone with a polymerization degree between 5 and 1000; and at most 30 % of the monomer units of said polymeric backbone have a pending chromophore group. 2. The pigment dispersion according to claim 1 wherein the linking group has a molecular weight smaller than the molecular weight of the pending chromophore group. 3. The pigment dispersion according to claim 1 or 2 wherein at least 2 % of the monomer units of said polymeric backbone have a pending chromophore group. 4. The pigment dispersion according to any of claims 1 to 3, wherein said at least one pending chromophore group has a molecular weight which is smaller than 93% of the molecular weight of said colour pigment. 5. The pigment dispersion according to any of claims 1 to 4, wherein said pending chromophore group is represented by Formula (I) wherein, L is a linking group forming a covalent bond with said polymeric backbone; and R1 to R8 are independently selected from the group consisting of hydrogen, an alkyl group and a halogen. 6. The pigment dispersion according to claim 5, wherein said colour pigment is selected from the group consisting of C. I. Pigment Red 122, C. I. Pigment Red 192, C. I. Pigment Red 202, C. I. Pigment Red 207, C. I. Pigment Red 29 and C. I. Pigment Violet 19. 7. The pigment dispersion according to any of claims 1 to 4, wherein said pending chromophore group is represented by said pending pending chromophore group is represented by formula (II): wherein, one of L1, L2 or L3 is said linking group and is selected from the group consisting of an aliphatic group, a substituted aliphatic group, an unsaturated aliphatic group and a substituted unsaturated aliphatic group; LI, L2 and/or L3, if not representing said linking group, are independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a carboxyfic acid group, an ester group, an acyl group, a nitro group and a halogen; and AR1 and AR2 represent an aromatic group. 8. The pigment dispersion according to claim 7, wherein said pending chromophore group is represented by Formula (III): (Ill) wherein, one of R1 to R11 is said linking group forming a covalent bond with said polymeric backbone; R1 to R11, if not representing said linking group, are independently selected from the group consisting of hydrogen, an alky! group, an alkenyl group, an alkoxy group, an alcohol group, a carboxylic acid group, an ester group, an acyl group, a nitro group and a halogen; or R7 and R8 may together form a heterocyclic ring. 9. The pigment dispersion according to claim 8, wherein said heterocyclic ring formed by R7 and R8 is imidazolone or 2,3-dihydroxypyrazine. 10. The pigment dispersion according to claim 7, wherein said pending chromophore group represented by formula (III) having an unreacted linking group is selected from the group consisting of: Yellow 1, 2,3. 5,6, 12, 13, 14, 17,49,55, 63.65,73, 74, 75,81, 83, 87, 97, 98, 111, 113, 116, 121, 124, 130, 152, 170. 171, 172, 174and 188. 12. A pigment dispersion according to any of claims 7 to 10, wherein said colour pigment is selected from the group consisting of C. I. Pigment Yellow 120, C. I. Pigment Yellow 151, C. I. Pigment Yellow 154, C. I. Pigment Yellow 175, C. I. Pigment Yellow 180. C. I. Pigment Yellow 181, C. I. Pigment Yellow 194, C. I. Pigment Orange 1, C. I. Pigment Orange 36, C. I. Pigment Orange 60, C. 1. Pigment Orange 62 and 0. I. Pigment Orange 72. 13. The pigment dispersion according to any of claims 1 to 12, wherein the polymeric backbone of the polymeric dispersant is a homopolymer. 14. The pigment dispersion according to any of claims 1 to 13, wherein said linking group contains at least one atom selected from the group consisting of an oxygen atom, a nitrogen atom and a sulfur atom. 15. The pigment dispersion according to claim 14, wherein said linking group in unreacted form is represented by -O-CH2-CH2-OH. 16. The pigment dispersion according to any of claims 1 to 15, wherein said pigment dispersion is an inkjet ink. 17. The pigment dispersion according to claim 16. wherein said inkjet ink is a curable inkjet ink. 18. A method for preparing the pigment dispersion according to any of claims 1 to 17 comprising the step of preparing said polymeric dispersant by copolymerizing a monomer already containing said pending chromophore group.

Documents:

185-CHENP-2008 AMENDED CLAIMS 23-09-2014.pdf

185-CHENP-2008 AMENDED PAGES OF SPECIFICATION 23-09-2014.pdf

185-CHENP-2008 CORRESPONDENCE OTHERS 09-01-2015.pdf

185-CHENP-2008 CORRESPONDENCE OTHERS . 31-12-2014.pdf

185-CHENP-2008 FORM-1 31-12-2014.pdf

185-CHENP-2008 FORM-3 23-09-2014.pdf

185-CHENP-2008 CORRESPONDENCE OTHERS 13-06-2014.pdf

185-CHENP-2008 EXAMINATION REPORT REPLY RECIEVED 23-09-2014.pdf

185-CHENP-2008 FORM-1 30-12-2014.pdf

185-CHENP-2008 FORM-1 31-12-2014.pdf

185-CHENP-2008 POWER OF ATTORNEY 23-09-2014.pdf

185-CHENP-2008 POWER OF ATTORNEY 30-12-2014.pdf

185-chenp-2008-abstract.pdf

185-chenp-2008-claims.pdf

185-chenp-2008-correspondnece-others.pdf

185-chenp-2008-description(complete).pdf

185-chenp-2008-form 1.pdf

185-chenp-2008-form 3.pdf

185-chenp-2008-form 5.pdf

185-chenp-2008-pct.pdf

Copy of General Power of authority.pdf

Form 13.pdf