Title of Invention

ELASTIC BOUNDARY-WAVE DEVICE

Abstract Provided is an elastic boundary-wave device, which utilizes elastic boundary-waves to propagate through a boundary between LiNbO3 or LiTaO3 and a dielectric layer so that the loss is reduced by making use of SH-type elastic boundary-waves although the electrode film is made thin. In the elastic boundary-wave device, a plurality of grooves (1b) are formed in the upper face of a LiNbO3 substrate (1) and are filled with a metallic material to form an electrode film (3) including IDT electrodes. A dielectric layer (4) such as a SiO2 film is formed to cover the upper face (1a) of the piezoelectric substrate (1) and the electrode film (3), and is flattened on its surface. The thickness of the electrode film (3), the Euler's angle (θ) (0 degrees, θ, -45 degrees - +45 degrees) of the LiNbO3 substrate and the thickness of the dielectric layer (4) are defined within any of the ranges tabulated in the following Table 1.
Full Text DESCRIPTION
ELASTIC BOUNDARY-WAVE DEVICE
Technical Field
[0001]
The present invention relates to boundary acoustic
wave devices used as, for example, resonators or band-pass
filters. The present invention particularly relates to a
boundary acoustic wave device including a piezoelectric
body, an electrode formed by embedding a metal in the upper
surface of the piezoelectric body, and a dielectric body
extending over the piezoelectric body and the electrode.
Background Art
[0002]
Duplexers (DPXs) and RF filters used in mobile
communication systems need to have both broad band-pass
properties and good temperature properties. Conventional
boundary acoustic wave devices used for such DPXs or RF
filters each include a piezoelectric substrate made of 36-
50 degrees rotated Y-plate X-propagation LiTaO3. The
piezoelectric substrate has a temperature coefficient of
frequency of -45 to -35 ppm/°C. A known technique for
improving temperature properties is to form a SiO2 layer
having a positive temperature coefficient of frequency over
IDT electrodes arranged on the piezoelectric substrate.


[0003]
In such a structure that the SiO2 layer extends over the
IDT electrodes, unevenness occurs between fingers of the IDT
electrodes and spaces between the electrode fingers. That
is, a surface of the SiO2 layer cannot avoid having
differences in height between the IDT electrodes and spaces
therebetween. Therefore, there is a problem in that surface
irregularities of the SiO2 layer cause the deterioration of
insertion loss.
[0004]
An increase in the thickness of the IDT electrodes
necessarily increases the height of the irregularities.
Therefore, the IDT electrodes cannot be increased in
thickness.
[0005]
In recent years, boundary acoustic wave devices have
been replacing surface acoustic wave devices and have been
attracting much attention because the boundary acoustic wave
devices are useful in manufacturing small-size packages.
Non-patent Document 1 below discloses a boundary acoustic
wave device including a LiNbO3 substrate, IDT electrodes,
and a SiO2 layer defining a dielectric body laminated in
that order. The IDT electrodes have a large thickness such
that the acoustic velocity of an SH-type boundary acoustic
wave propagating between the LiNbO3 substrate and the SiO2


layer is less than that of a slow transverse wave
propagating in the SiO2 layer; hence, the SH-type boundary
acoustic wave is nonleaky. Fig. 3 of Non-patent Document 1
shows that the thickness of an IDT electrode that is
sufficient for an SH-type boundary acoustic wave to be
nonleaky is 0.15λ or more when the IDT electrode is made of
Al, or 0.04λ or more when the IDT electrode is made of one
of Cu, Ag, and Au, wherein λ represents the wavelength of
the SH-type boundary acoustic wave.
Non-patent Document 1: "RF Filter using Boundary Acoustic
Wave" (Proc. Symp. Ultrason. Electron., Vol. 26, pp. 25-26
(2005/11))
Disclosure of Invention
[0006]
When boundary acoustic wave devices, as well as the
boundary acoustic wave device disclosed in Non-patent
Document 1, include IDT electrodes which are made of Au and
which have a thickness of 0.04λ or more, frequency
properties of the boundary acoustic wave devices vary
significantly due to differences in thickness between the
electrodes. Therefore, it has been difficult to manufacture
boundary acoustic wave devices having good frequency
properties with high reproducibility.
[0007]
In view of the foregoing circumstances, it is an object


of the present invention to provide a boundary acoustic wave
device which includes electrodes having reduced thickness,
which can confine an SH-type boundary acoustic wave between
a piezoelectric body and a dielectric body, and which has
low loss.
[0008]
A first aspect of the present invention provides a
boundary acoustic wave device that includes a LiNbO3
substrate which has a plurality of grooves formed in the
upper surface thereof and which has Euler angles (0°, θ, -
45° to +45°), electrodes formed by filling the grooves with
a metal material, and a dielectric layer formed over the
LiNbO3 substrate and the electrodes. The upper surface of
the dielectric layer is flat. The metal material used to
form the electrodes is at least one selected from the group
consisting of Al, Ti, Ni, Cr, Cu, W, Ta, Pt, Ag, and Au. Al
and Ti are grouped into a first group. Ni and Cr are
grouped into a second group. Cu, W, Ta, Pt, Ag, and Au are
grouped into a third group. The thickness of the electrodes
made of the metal materials assigned to each group, θ of the
Euler angles of the LiNbO3 substrate, and the thickness of
the dielectric layer are within any of ranges shown in Table
1 below.
[0009]
[Table 1]


[0010]
In the boundary acoustic wave device of the first
aspect, the thickness of the electrodes, θ of the Euler
angles of the LiNbO3 substrate, and the thickness of the
dielectric layer are within any of ranges shown in Table 2
below.
[0011]

[0012]
A second aspect of the present invention provides a

boundary acoustic wave device that includes a LiTaO3
substrate which has a plurality of grooves formed in the
upper surface thereof and which has Euler angles (0°, θ, -
45° to +45°); electrodes formed by filling the grooves with
a metal material; and a dielectric layer formed over the
LiTaO3 substrate and the electrodes. The upper surface of
the dielectric layer is flat. The metal material used to
form the electrodes is at least one selected from the group
consisting of Al, Cu, Au, Ta, and Pt. The thickness of the
electrodes, θ of the Euler angles of the LiTaO3 substrate,
and the thickness of the dielectric layer are within any of
ranges shown in Table 3 below.
[0013]

[0014]

In the boundary acoustic wave device according to the
second aspect, the thickness of the electrodes, θ of the
Euler angles of the LiTaO3 substrate, and the thickness of
the dielectric layer are within any of ranges shown in Table
4 below.
[0015]

[0016]
In the boundary acoustic wave device according to each
aspect, the dielectric layer is made of silicon dioxide.
Since silicon dioxide has a positive temperature coefficient
of frequency TCF and LiNbO3 and LiTaO3 have a negative
temperature coefficient of frequency TCF, a boundary
acoustic wave device having a temperature coefficient of
frequency with a small absolute value and good temperature

properties can be provided.
(Advantages)
[0017]
In the boundary acoustic wave device according to the
first aspect, the electrodes are formed by filling the
grooves, which are formed in the upper surface of the LiNbO3
substrate, with the metal material and the dielectric layer
is formed over the LiNbO3 substrate and the electrodes, the
thickness of the electrodes can be adjusted by varying the
depth of the grooves. Therefore, there are substantially no
unevenness between electrode-bearing portions and electrode-
free portions; hence, the upper surface of the dielectric
layer can be readily planarized and the insertion loss can
be reduced.
[0018]
In addition, the metal material used to form the
electrodes is at least one of the metal materials of the
first group, those of the second group, and those of the
third group and θ of the Euler angles of the LiNbO3 substrate,
the thickness of the dielectric layer, and the thickness of
the electrodes are within any of ranges shown in Table 1.
Therefore, as is clear from experiments below, an SH-type
boundary acoustic wave can be nonleaky even if the
electrodes have a reduced thickness. Hence, a boundary
acoustic wave device which uses such a SH-type boundary

acoustic wave and which has low loss can be provided.
[0019]
When the thickness of the electrodes, 0 of the Euler
angles, and the thickness of the dielectric layer are any of
those shown in Table 2, the loss of the boundary acoustic
wave device can be further reduced.
[0020]
According to the second aspect, the electrodes are
formed by filling the grooves, which are formed in the upper
surface of the LiTaO3 substrate, with the metal material and
the dielectric layer is formed over the LiNbO3 substrate and
the electrodes, there are substantially no unevenness
between electrode-bearing portions and electrode-free
portions; hence, the upper surface of the dielectric layer
is flat and therefore the insertion loss can be reduced. In
addition, the material used to form the electrodes is at
least one of metal materials such as Al, Cu, Au, Ta, and Pt
and the thickness of the electrodes, θ of the Euler angles
of the LiTaO3 substrate, and the thickness of the dielectric
layer are within any of ranges shown in Table 2. Therefore,
an SH-type boundary acoustic wave can be nonleaky even if
the electrodes have a reduced thickness. Hence, a boundary
acoustic wave device which uses such a SH-type boundary
acoustic wave and which has low loss can be provided.
[0021]

In particular, when the thickness of the electrodes, θ
of the Euler angles, and the thickness of the dielectric
layer are within any of the ranges shown in Table 4, the
loss of the boundary acoustic wave device can be further
reduced.
Brief Description of Drawings
[0022]
[Fig. 1] Figs. 1(a) to 1(f) are front sectional views
illustrating a method for manufacturing a boundary acoustic
wave device according to an embodiment the present invention
and the structure of the boundary acoustic wave device.
[Fig. 2] Fig. 2 is a schematic plan view of an
electrode structure of the boundary acoustic wave device
shown in Fig. 1.
[Fig. 3] Fig. 3 is a graph showing the relationship
between the normalized thickness H/λ of electrode layers
formed by filling grooves, disposed in LiNbO3 substrates
which are included in boundary acoustic wave devices
according to this embodiment and which have Euler angles (0°,
103°, 0°), with Al or Ti and the attenuation constant a of
the boundary acoustic wave devices.
[Fig. 4] Fig. 4 is a graph showing the relationship
between the normalized thickness H/λ, of electrode layers
formed by filling grooves, disposed in LiNbO3 substrates
which are included in boundary acoustic wave devices


according to this embodiment and which have Euler angles (0°,
103°, 0°), with Ni or Cr and the attenuation constant a of
the boundary acoustic wave devices.
[Fig. 5] Fig. 5 is a graph showing the relationship
between the normalized thickness H/λ, of electrode layers
formed by filling grooves, disposed in LiNbO3 substrates
which are included in boundary acoustic wave devices
according to this embodiment and which have Euler angles (0°,
103°, 0°), with each metal material of a third group and the
attenuation constant α of the boundary acoustic wave devices.
[Fig. 6] Fig. 6 is a graph showing the relationship
between θ of the Euler angles of LiNbO3 substrates and the
attenuation constant a of electrodes which are made of Al
and which are varied in normalized thickness.
[Fig. 7] Fig. 7 is a graph showing the relationship
between 9 of the Euler angles of LiNbO3 substrates and the
attenuation constant a of electrodes which are made of Ni
and which are varied in normalized thickness.
[Fig. 8] Fig. 8 is a graph showing the relationship
between 0 of the Euler angles of LiNbO3 substrates and the
attenuation constant a of electrodes which are made of Cu
and which are varied in normalized thickness.
[Fig. 9] Fig. 9 is a graph showing the variation in
electromechanical coefficient k2 with the thickness of
electrodes made of Al and the thickness of SiO2 layers, the


electrodes being IDT electrodes formed in grooves disposed
in LiNbO3 substrates with Euler angles (0°, 103°, 0°) using
Al, the SiO2 layers being deposited on the electrodes.
[Fig. 10] Fig. 10 is a graph showing the variation in
electromechanical coefficient k2 with the thickness of
electrodes made of Ni and the thickness of SiO2 layers, the
electrodes being IDT electrodes formed in grooves disposed
in LiNbO3 substrates with Euler angles (0°, 103°, 0°) using
Ni, the SiO2 layers being deposited on the electrodes.
[Fig. 11] Fig. 11 is a graph showing the variation in
electromechanical coefficient k2 with the thickness of
electrodes made of Cu and the thickness of SiO2 layers, the
electrodes being IDT electrodes formed in grooves disposed
in LiNbO3 substrates with Euler angles (0°, 103°, 0°) using
Cu, the SiO2 layers being deposited on the electrodes.
[Fig. 12] Fig. 12 is a schematic view illustrating the
energy distribution of an acoustic wave propagating in a
SiO2/embedded IDT electrode/LiNbO3 multilayer structure
including a SiO2 layer with a normalized thickness H/λ, of
less than 0.8.
[Fig. 13] Fig. 13 is a schematic view illustrating the
energy distribution of an acoustic wave propagating in a
SiO2/embedded IDT electrode/LiNbO3 multilayer structure
including a SiO2 layer with a normalized thickness H/λ of 0.8
or more.


[Fig. 14] Fig. 14 is a graph showing the temperature
coefficient of frequency TCF of a boundary acoustic wave
device according to a first embodiment and the temperature
coefficient of frequency TCF of a boundary acoustic wave
device of a comparative example that includes IDT electrodes
which are not of an embedded type, the boundary acoustic
wave device according to the first embodiment and the
boundary acoustic wave device of the comparative example
including SiO2 layers with a thickness of 1λ, or 2λ.
[Fig. 15] Fig. 15 is a graph illustrating the
relationship between 0 of the Euler angles (0°, 0, 0°) of
LiTaO3 substrates, the thickness of IDT electrodes made of
Al, and the attenuation constant a of boundary acoustic wave
devices.
[Fig. 16] Fig. 16 is a graph illustrating the
relationship between θ of the Euler angles (0°, θ, 0°) of
LiTaO3 substrates, the thickness of IDT electrodes made of
Cu, and the attenuation constant a of boundary acoustic wave
devices.
[Fig. 17] Fig. 17 is a graph illustrating the
relationship between 0 of the Euler angles (0°, θ, 0°) of
LiTaO3 substrates, the thickness of IDT electrodes made of
Au, and the attenuation constant α of boundary acoustic wave
devices.
[Fig. 18] Fig. 18 is a graph illustrating the


relationship between θ of the Euler angles (0°, θ, 0°) of
LiTaO3 substrates, the thickness of IDT electrodes made of
Ta, and the attenuation constant a of boundary acoustic wave
devices.
[Fig. 19] Fig. 19 is a graph illustrating the
relationship between θ of the Euler angles (0°, θ, 0°) of
LiTaO3 substrates, the thickness of IDT electrodes made of
Pt, and the attenuation constant a of boundary acoustic wave
devices.
[Fig. 20] Fig. 20 is a graph showing the relationship
between the normalized thickness H/λ, of SiO2 layers, the
normalized thickness of Al layers, and the electromechanical
coefficient k2 of structures in which embedded electrodes
made of Al are formed in LiTa03 with Euler angles (0°, 126°,
0°) and SiO2 is deposited on the electrodes.
[Fig. 21] Fig. 21 is a graph showing the relationship
between the normalized thickness H/λ of SiO2 layers, the
normalized thickness of Au layers, and the electromechanical
coefficient k2 of structures in which embedded electrodes
made of Au are formed in LiTaO3 with Euler angles (0°, 126°,
0°) and SiO2 is deposited on the electrodes.
[Fig. 22] Fig. 22 is a graph showing the relationship
between the normalized thickness H/λ of SiO2 layers, the
normalized thickness of Cu layers, and the electromechanical
coefficient k2 of structures in which embedded electrodes


made of Cu are formed in LiTaO3 with Euler angles (0°, 126°,
0°) and SiO2 is deposited on the electrodes.
[Fig. 23] Fig. 23 is a graph showing the relationship
between the normalized thickness H/λ of SiO2 layers, the
normalized thickness of Ta layers, and the electromechanical
coefficient k2 of structures in which embedded electrodes
made of Ta are formed in LiTaO3 with Euler angles (0°, 126°,
0°) and SiO2 is deposited on the electrodes.
[Fig. 24] Fig. 24 is a graph showing the relationship
between the normalized thickness H/λ of SiO2 layers, the
normalized thickness of Pt layers, and the electromechanical
coefficient k2 of structures in which embedded electrodes
made of Pt are formed in LiTaO3 with Euler angles (0°, 126°,
0°) and SiO2 is deposited on the electrodes.
Reference Numerals
[0023]

12 and 13 reflectors


Best Modes for Carrying Out the Invention
[0024]
Embodiments of the present invention will now be
described with reference to the accompanying drawings in
detail. The present invention will become apparent from the
description.
[0025]
(First experiment)
A method for manufacturing a boundary acoustic wave
device according to an embodiment of the present invention
is described below with reference to Figs. 1(a) to 1(f) such
that the structure of the boundary acoustic wave device
becomes apparent.
[0026]
As shown in Figs. 1(a) and 1(b), a LiNbO3 substrate
defining a piezoelectric substrate is prepared.
[0027]
A photoresist layer 2 is formed over the upper surface
la of the LiNbO3 substrate 1. The photoresist layer 2 can be
formed from any photoresist material resistant to reactive
ion etching (RIE) performed later. In this example, a
positive resist, AZ-1500™, available from Clariant (Japan)
K.K. is used. In this example, the thickness of the
photoresist layer 2 is 2 µm.
[0028]


The photoresist layer 2 is patterned in such a manner
that the photoresist layer is exposed to light and then
developed, whereby a photoresist pattern 2A is formed as
shown in Fig. 1(b). In the photoresist pattern 2A, portions
for forming IDT electrodes are removed from the photoresist
layer.
[0029]
As shown in Fig. 1(c), a plurality of grooves 1b with a
desired depth are formed in the upper surface 1a of the
LiNbO3 substrate 1 by reactive ion etching. The desired
depth thereof is equal to the thickness of the IDT
electrodes formed later. However, the etching depth may be
slightly greater or less than the thickness of the IDT
electrodes.
[0030]
A1 layers are formed by vapor deposition or sputtering.
This allows the A1 layers, that is, electrode layers 3 to be
placed in the grooves 1b as shown in Fig. 1(d) . An A1 layer
is placed on the photoresist pattern 2A.
[0031]
The LiNbO3 substrate is immersed in a stripping solution
containing acetone or the like, whereby the photoresist
pattern 2A and the A1 layer placed on the photoresist
pattern 2A are removed. This allows the grooves 1b to be
filled with the electrode layers 3 and allows the LiNbO3


substrate 1 to have a substantially flat upper surface as
shown in Fig. 1(e).
[0032]
As shown in Fig. 1(f), a SiO2 layer 4 defining a
dielectric layer is formed on the upper surface, whereby the
boundary acoustic wave device 5 is obtained. The SiO2 layer
4 has a flat surface. This is because the upper surface 1a
of the LiNbO3 substrate 1 and the upper surface of each
electrode layer 3 are substantially flush with each other
and are substantially flat. Therefore, the surface of the
SiO2 layer 4 can be securely planarized when the SiO2 layer 4
is formed by a common process.
[0033]
A process for forming the SiO2 layer 4 is not
particularly limited. The SiO2 layer 4 may be formed by an
appropriate process such as a printing process, a vapor
deposition process, or a sputtering process.
[0034]
The method for manufacturing the boundary acoustic wave
device 5 of this embodiment is as described above with
reference to Figs. 1(a) to 1(f), which principally
illustrate electrode portions. In particular, the electrode
layers 3 form an electrode structure including IDT
electrodes. The electrode structure is not particularly
limited and may be a one port-type boundary acoustic wave


resonator 11 shown in Fig. 2 in plan view. In this case,
the electrode layers form reflectors 12 and 13 arranged on
both sides of the electrode layers 3 which form the IDT
electrodes in the direction of a boundary acoustic wave
propagation.
[0035]
In this example, there are substantially no unevenness
between electrode-bearing portions and electrode-free
portions; hence, the upper surface of the SiO2 layer 4,
which defines a dielectric layer, can be readily planarized
and the insertion loss can be reduced.
[0036]
The boundary acoustic wave device, which has low loss,
can be provided without increasing the thickness of the
electrode layers 3. The electrode layers 3 are made of a
metal material that is at least one selected from the group
consisting of Al, Ti, Ni, Cr, Cu, W, Ta, Pt, Ag, and Au. Al
and Ti are grouped into a first group; Ni and Cr are grouped
into a second group; Cu, W, Ta, Pt, Ag, and Au are grouped
into a third group; the thickness of the electrode layers
made of the metal materials assigned to each group, 9 of the
Euler angles of the LiNbO3 substrate 1, and the thickness of
a dielectric layer are within any of ranges shown in Table 5
below. Therefore, although the electrode layers have a
small thickness, the boundary acoustic wave device, which


has low loss, can be provided. This is described below in
detail using examples.
[0037]

[0038]
Non-patent Document 1 cited above describes that the
SH-type boundary acoustic wave is nonleaky in a
SiO2/electrodes/y-cut X-propagation LiNbO3 multilayer
structure when the electrodes are made of Al and have a
thickness of 0.16A, or more or when the electrodes are made
of Au, Cu, or Ag and have a thickness of 0.04λ or more.
[0039]
However, experiments conducted by the inventors have
shown that an SH-type boundary acoustic wave can be nonleaky
in the boundary acoustic wave device 5 of this embodiment
although the electrode layers 3, which are formed by filling
the grooves lb with the metal material, have a small


thickness. This is described below with reference to Figs.
3 to 5.
[0040]
Fig. 3 is a graph showing the relationship between the
thickness of electrode layers 3 made of the metal materials
of the first group and the attenuation constant a of
boundary acoustic wave devices 5 including LiNbO3 substrates
with Euler angles (0°, 103°, 0°). Fig. 4 is a graph showing
the relationship between the thickness of electrode layers 3
made of the metal materials of the second group and the
attenuation constant a of boundary acoustic wave devices 5.
Fig. 5 is a graph showing the relationship between the
thickness of electrode layers 3 made of the metal materials
of the third group and the attenuation constant a of
boundary acoustic wave devices 5. The electrode layers 3
have an electrode structure for forming the one port-type
boundary acoustic wave resonator shown in Fig. 3.
[0041]
Figs. 3 to 5 illustrate that the following combination
is within ranges specified in Tables 6 to 11: a combination
of the thickness of the electrode layers that are made of
the corresponding metal materials of the first to third
groups such that the propagation loss a is 0.1 dB/λ or less
or substantially zero, θ of Euler angles, and a SiO2 layer.
[0042]


[0045]
[Table 9]
α≈0


[0048]
As is clear from Figs. 3 to 5, since the electrode
layers 3 are formed by filling the grooves lb with the metal

materials, the attenuation constant a of an SH-type boundary
acoustic wave is 0.1 dB/λ or less and therefore the SH-type
boundary acoustic wave is nonleaky when the electrode layers
3 are made of Al or Ti and have a thickness of 0.03λ, or
more; when the IDT electrodes are made of one of the metal
materials of the second group, that is, Ni or Cr and have a
thickness of 0.01λ or more; or when the IDT electrodes are
made of one of the metal materials of the third group, that
is, Cu, W, Ta, Pt, Ag, or Au and have a thickness of 0.005λ,
or more.
[0049]
In the boundary acoustic wave devices 5, θ of the Euler
angles (0°, θ, 0°) of each LiNbO3 substrate is varied and IDT
electrodes are made of the corresponding metal materials of
the first to third groups. Figs. 6 to 8 each show the
relationship between θ of the Euler angles and the
attenuation constant α.
[0050]
As is clear from Figs. 6 to 8, the attenuation constant
a is very small and therefore a boundary acoustic wave is
nonleaky in a specific range when the IDT electrodes are
made of the corresponding metal materials of the first to
third groups and 6 of the Euler angles and the thickness of
the electrodes are varied.
[0051]

In the boundary acoustic wave devices 5, dielectric
layers were formed from SiO2 layers 4. The following
relationship was determined using LiNbO3 substrates with
Euler angles (0°, 103°, 0°): the relationship between the
normalized thickness H/λ, of the dielectric layers formed
from the SiO2 layers 4 and the electromechanical coefficient
k2 of SH-type normalization. The results are shown in Figs.
9 to 11. As is clear from Figs. 9 to 11, an increase in the
thickness of the SiO2 layer 4 tends to reduces the
electromechanical coefficient k2 of an SH-type boundary
acoustic wave. Since the magnitude of the electromechanical
coefficient k2 may be selected depending on applications,
the thickness of the dielectric layers formed from the SiO2
layers 4 may be selected within ranges shown in Figs. 9 to
11 depending on a range required for the electromechanical
coefficient k2 of the SH-type boundary acoustic wave.
[0052]
The results of electrode layers 3 made of Al, Ni, and
Cu are shown in Figs. 9 to 11. It has been confirmed that
Ti shows substantially the same value as that of Al; Cr
shows substantially the same value as that of Ni; and Cu, W,
Ta, Pt, or Ag shows a value close to that of Au.
[0053]
Figs. 12 and 13 are schematic views each illustrating
the energy distribution of an acoustic wave propagating in a

structure including an IDT electrode placed in a groove lb
formed in a LiNbO3 substrate 1 and a SiO2 layer 4 deposited
over the IDT electrode, the SiO2 layer 4 defining a
dielectric layer of which normalized thicknesses H/λ are
less than 0.8 and 0.8 or more, respectively.
[0054]
As is clear from Fig. 12, the energy of the acoustic
wave is distributed over the upper surface of the dielectric
layer made from the SiO2 layer 4, which has a normalized
thickness H/λ of less than 0.8; hence, the structure cannot
be used as any boundary acoustic wave device. In contrast,
the SiO2 layer 4 shown in Fig. 13 has a normalized thickness
H/λ of 0.8 or more and therefore the energy of the acoustic
wave is confined in this structure; hence, this structure
can be used as a boundary acoustic wave device.
[0055]
The results shown in Figs. 3 to 5, 6 to 8, 9 to 11, 12,
and 13 show that the following relationship may be within
any of ranges shown in Table 5: the relationship between
the type of a material most suitable for electrodes used for
boundary acoustic waves, the normalized thickness H/λ of
each electrode, the normalized thickness of a dielectric
layer made of SiO2, and θ of the Euler angles. In Table 5,
Euler angles are expressed in the form of (0°, θ, -45° to
+45°), that is, Ψ ranges from -45° to 45°, although Ψ = 0 in

the above experiments. This is because if 6 of the Euler
angles of a LiNbO3 substrate is within a specific range, a
small propagation loss is obtained as described above when Ψ
is 0° or is within the range of -45° to 45°. Not only in
LiNbO3 but also in LiTaO3 used in a second experiment below,
Ψ of Euler angles (0°, θ, Ψ) shows substantially the same
results as those achieved when Ψ = 0°, if Ψ is within the
range of -45° to 45°.
[0056]
When any of ranges shown in Table 12 below is satisfied,
propagation loss can be further reduced.
[0057]

[0058]
In the boundary acoustic wave device 5 of this
embodiment, the electrode layers 3 including IDT electrodes
are formed by filling the grooves 1b, disposed in the upper

surface of the LiNbO3 substrate 1, with the metal material.
According to this structure, the absolute value of a
temperature coefficient of frequency TCF can be reduced and
frequency-temperature characteristic can be improved as
compared to those of comparative examples in which IDT
electrodes are formed on LiNbO3 substrates without filling
grooves with any metal material. This is shown in Fig, 14,
Fig. 14 shows the temperature coefficient of frequency TCF
of the boundary acoustic wave device of this embodiment, the
boundary acoustic wave device being obtained in such a
manner that the grooves are formed in the LiNbO3 substrate
with Euler angles (0°, 103°, 0°), the IDT electrodes with a
thickness of 0.04X are formed by filling the grooves with Au,
and the SiO2 layer with a thickness of 1A, or 2\ is deposited
over the IDT electrodes. For comparison, Fig. 14 also shows
the temperature coefficient of frequency TCF of a boundary
acoustic wave device which is obtained in such a manner that
IDT electrodes made of Au having the same thickness are
formed on a LiNbO3 substrate without forming any grooves and
a SiO2 layer having the thickness of 1λ, or 2λ similar to the
above described embodiment.
[0059]
As is clear from Fig. 14, according to the embodiment,
the absolute value of the thermal coefficient of frequency
TCF can be reduced and can be improved by about 5 ppm/°C as

compared to comparative examples regardless of whether the
normalized thickness H/λ of a dielectric layer made of SiO2
is 1λ or 2λ.
[0060]
In this embodiment, the dielectric layer is formed from
the SiO2 layer 4 and may be made of silicon oxide other than
SiO2.
[0061]
(Second experiment)
Although the LiNbO3 substrates were used in the first
experiment, LiTaO3 substrates were used in a second
experiment. A plurality of grooves lb were formed in the
upper surfaces of the LiTaO3 substrates in the same manner
as that described with reference to Fig. 1, electrode layers
3 were formed by filling the grooves lb with various metal
materials, and SiO2 layers defining dielectric layers were
deposited. Figs. 15 to 19 are graphs illustrating the
relationship between 0 of the Euler angles (0°, θ, 0°) of
the LiTaO3 substrates, which are disposed in boundary
acoustic wave devices obtained as described above, the
thickness of the electrode layers, and the attenuation
constant a of the boundary acoustic wave devices.
[0062]
Fig. 15 shows results obtained using Al as an electrode
material, Fig. 16 shows results obtained using Cu as an

electrode material, and Fig. 17 shows results obtained using
Au as a metal material for forming electrodes.
[0063]
Electromechanical coefficients were determined in such
a manner that LiTaO3 with Euler angles (0°, 126°, 0°) were
used to prepare the LiTaO3 substrates and the thickness of
electrodes and the type of a metal material for forming the
electrodes were varied. The obtained results are shown in
Figs. 20 to 24. Figs. 20 to 24 show results obtained using
Al, Au, Cu, Ta, and Pt as metal materials for forming the
electrodes.
[0064]
As is clear from Figs. 20 to 24, for the use of the
LiTaO3 substrates, an increase in the thickness of SiO2
layers reduces the electromechanical coefficient k2. The
thickness of SiO2 layers may be selected such that an
electromechanical coefficient k2 suitable for the
application is obtained.
[0065]
The results shown in Figs. 15 to 19 and 20 to 24 show
that the use of a LiTaO3 substrate, as well as the LiNbO3
substrates, having Euler angles (0°, θ, -45° to +45°)
provides a boundary acoustic wave device with low loss and
utilizing an SiO-type boundary acoustic wave when θ of the
Euler angles, the thickness of electrodes, and the thickness

of a SiO2 layer are within any of ranges shown in Tables 13
to 22.
[0066]







[0076]
The analysis of data in Tables 13 to 22 shows that such
a boundary acoustic wave device with low loss is obtained if
any of ranges shown in Tables 23 and 24 is satisfied. In
particular, any of ranges shown in Table 24 is preferably
satisfied because the loss thereof is reduced.


[0079]
In the first and second experiments, the IDT electrodes

are made of a single metal such as Al or Au. The IDT
electrodes may each have a multilayer structure in which an
electrode layer principally containing such a metal is
disposed on another electrode layer made of another metal
material.
[0080]
The dielectric layers may be made of another dielectric
material having an acoustic wave velocity of a transverse
wave greater than that of the electrodes. Examples of such
a dielectric material include glass, SixNy, SiC, and Al2O3.
When the dielectric layers are made of any one of these
materials, the thickness thereof may be determined in
inverse proportion to the acoustic wave velocity of a
transverse wave of SiO2.

CLAIMS
1. A boundary acoustic wave device comprising:
a LiNbO3 substrate which has a plurality of grooves
formed in the upper surface thereof and which has Euler
angles (0°, θ, -45° to +45°);
electrodes formed by filling the grooves with a metal
material; and
a dielectric layer formed over the LiNbO3 substrate and
the electrodes,
wherein the upper surface of the dielectric layer is
flat; the metal material used to form the electrodes is at
least one selected from the group consisting of Al, Ti, Ni,
Cr, Cu, W, Ta, Pt, Ag, and Au; Al and Ti are grouped into a
first group; Ni and Cr are grouped into a second group; Cu,
W, Ta, Pt, Ag, and Au are grouped into a third group; and
the thickness of the electrodes made of the metal materials
assigned to each group, 0 of the Euler angles of the LiNbO3
substrate, and the thickness of the dielectric layer are
within any of ranges shown in Table 1 below.


2. The boundary acoustic wave device according to Claim 1,
wherein the thickness of the electrodes, 0 of the Euler
angles of the LiNbO3 substrate, and the thickness of the
dielectric layer are within any of ranges shown in Table 2
below:

3. A boundary acoustic wave device comprising:
a LiTaO3 substrate which has a plurality of grooves
formed in the upper surface thereof and which has Euler

angles (0°, θ, -45° to +45°);
electrodes formed by filling the grooves with a metal
material; and
a dielectric layer formed over the LiTaO3 substrate and
the electrodes,
wherein the upper surface of the dielectric layer is
flat; the metal material used to form the electrodes is at
least one selected from the group consisting of Al, Cu, Au,
Ta, and Pt; and the thickness of the electrodes, θ of the
Euler angles of the LiTaO3 substrate, and the thickness of
the dielectric layer are within any of ranges shown in Table
3 below:

4. The boundary acoustic wave device according to Claim 3,
wherein the thickness of the electrodes, θ of the Euler

angles of the LiTaO3 substrate, and the thickness of the
dielectric layer are within any of ranges shown in Table 4
below:

5. The boundary acoustic wave device according to any one
of Claims 1 to 4, wherein the dielectric layer is made of
silicon dioxide.

Provided is an elastic boundary-wave device, which utilizes
elastic boundary-waves to propagate through a boundary between
LiNbO3 or LiTaO3 and a dielectric layer so that the loss is reduced by
making use of SH-type elastic boundary-waves although the electrode
film is made thin. In the elastic boundary-wave device, a plurality of
grooves (1b) are formed in the upper face of a LiNbO3 substrate (1) and
are filled with a metallic material to form an electrode film (3) including
IDT electrodes. A dielectric layer (4) such as a SiO2 film is formed to
cover the upper face (1a) of the piezoelectric substrate (1) and the electrode
film (3), and is flattened on its surface. The thickness of the electrode
film (3), the Euler's angle (θ) (0 degrees, θ, -45 degrees - +45
degrees) of the LiNbO3 substrate and the thickness of the dielectric layer
(4) are defined within any of the ranges tabulated in the following Table 1.

Documents:

908-KOLNP-2009-(04-05-2012)-CORRESPONDENCE.pdf

908-KOLNP-2009-(04-05-2012)-ENGLISH TRANSLATION.pdf

908-KOLNP-2009-(04-05-2012)-FORM-3.pdf

908-KOLNP-2009-(22-08-2014)-ABSTRACT.pdf

908-KOLNP-2009-(22-08-2014)-ANNEXURE TO FORM 3.pdf

908-KOLNP-2009-(22-08-2014)-CLAIMS.pdf

908-KOLNP-2009-(22-08-2014)-CORRESPONDENCE.pdf

908-KOLNP-2009-(22-08-2014)-DESCRIPTION (COMPLETE).pdf

908-KOLNP-2009-(22-08-2014)-DRAWINGS.pdf

908-KOLNP-2009-(22-08-2014)-FORM-1.pdf

908-KOLNP-2009-(22-08-2014)-FORM-2.pdf

908-KOLNP-2009-(22-08-2014)-PA.pdf

908-KOLNP-2009-(22-08-2014)-PETITION UNDER RULE 137.pdf

908-kolnp-2009-abstract.pdf

908-KOLNP-2009-ASSIGNMENT.pdf

908-kolnp-2009-claims.pdf

908-KOLNP-2009-CORRESPONDENCE 1.1.pdf

908-kolnp-2009-correspondence.pdf

908-kolnp-2009-description (complete).pdf

908-kolnp-2009-drawings.pdf

908-kolnp-2009-form 1.pdf

908-kolnp-2009-form 18.pdf

908-kolnp-2009-form 3.pdf

908-kolnp-2009-form 5.pdf

908-kolnp-2009-gpa.pdf

908-kolnp-2009-international publication.pdf

908-kolnp-2009-international search report.pdf

908-kolnp-2009-others pct form.pdf

908-kolnp-2009-pct priority document notification.pdf

908-kolnp-2009-specification.pdf

abstract-908-kolnp-2009.jpg


Patent Number 265408
Indian Patent Application Number 908/KOLNP/2009
PG Journal Number 09/2015
Publication Date 27-Feb-2015
Grant Date 23-Feb-2015
Date of Filing 09-Mar-2009
Name of Patentee MURATA MANUFACTURING CO., LTD.
Applicant Address 10-1, HIGASHIKOTARI 1-CHOME, NAGAOKAKYO-SHI, KYOTO 6178555
Inventors:
# Inventor's Name Inventor's Address
1 KIMURA, TETSUYA C/O MURATA MANUFACTURING CO., LTD., 10-1, HIGASHIKOTARI 1-CHOME, NAGAOKAKYO-SHI, KYOTO 6178555
2 KADOTA, MICHIO C/O MURATA MANUFACTURING CO., LTD., 10-1, HIGASHIKOTARI 1-CHOME, NAGAOKAKYO-SHI, KYOTO 6178555
PCT International Classification Number H01L 41/18,H03H 9/25
PCT International Application Number PCT/JP2007/067583
PCT International Filing date 2007-09-10
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 2006-278970 2006-10-12 Japan