Title of Invention	METHOD FOR REDUCING THE EMISSION OF GREEN HOUSE GASES INTO THE ATMOSPHERE
Abstract	A method for reducing the emission of greenhouse gases, such as for example carbon dioxide, into the atmosphere above a ground surface, the method comprising injecting a gas stream comprising one or more than one greenhouse gas into a subsurface injection formation, where the subsurface injection formation comprises a water-laden layer comprising formation water, and where some or all of the greenhouse gases present in the gas stream become dissolved in the formation water in the subsurface injection formation, sequestering the one or more than one greenhouse gas in the subsurface injection formation, separating non-greenhouses gas in situ from the greenhouse gas, venting the non-greenhouse gas from the formation and thereby reducing the emission of greenhouse gases into the atmosphere.

Title of Invention

METHOD FOR REDUCING THE EMISSION OF GREEN HOUSE GASES INTO THE ATMOSPHERE

Abstract

A method for reducing the emission of greenhouse gases, such as for example carbon dioxide, into the atmosphere above a ground surface, the method comprising injecting a gas stream comprising one or more than one greenhouse gas into a subsurface injection formation, where the subsurface injection formation comprises a water-laden layer comprising formation water, and where some or all of the greenhouse gases present in the gas stream become dissolved in the formation water in the subsurface injection formation, sequestering the one or more than one greenhouse gas in the subsurface injection formation, separating non-greenhouses gas in situ from the greenhouse gas, venting the non-greenhouse gas from the formation and thereby reducing the emission of greenhouse gases into the atmosphere.

Full Text	FORM 2 THE PATENTS ACT, 1970 (39 of 1970) & THE PATENTS RULES, 2003 COMPLETE SPECIFICATION [See section 10, Rule 13] METHOD FOR REDUCING THE EMISSION OF GREEN HOUSE GASES INTO THE ATMOSPHERE; BRUNO, MiCHAEL S. AN AMERICAN NATiONAL OF 1105, STARLIT LANE, MONROVIA, CALIFORNIA 91016, U.S.A; BILAK, ROMAN, A CANADIAN NATIONAL OF 49 MACEWAN PARK CLOSE, N.W. CALGARY, AL- BERTA T3K3Z6, CANADA; ROTHENBURG, LEO A CANADIAN NATIONAL OF 188 MOHAWK AVENUE, WATERLOO, ONTARIO N2L 2T3, CANADA & DUSSEAULT, MAURICE B„ A CANADIAN NATIONAL OF 7203 - 87 STREET, OSOYOOS, BRITISH COLUMBIA V0H 1V0, CANADA THE FOLLOWING SPECIFICATION PARTICULARLY DESCRIBES THE INVENTION AND THE MANNER IN WHICH IT IS TO BE PERFORMED. CROSS-REFERENCE TO RELATED APPLICATIONS The present Application claims the benefit of United States Provisional Patent Application No. 60/869,103, titled "Method for Reducing the Emission of Green House Gases into the Atmosphere," filed December 7, 2006, the contents of which are incorporated in this disclosure by reference in their entirety. BACKGROUND In recent years, it has become evident that general climatic warming is occurring due to the "greenhouse effect" caused by the increasing presence of certain greenhouse gases (GHGs) generated from human activities. Among the gaseous components in the atmosphere that contribute to the greenhouse effect are carbon dioxide, methane, nitrous oxide and ozone. By contrast, oxygen, nitrogen and sulfur dioxide do not appear to contribute to the greenhouse effect. In order to mitigate the effects of increasing greenhouse gases generated from human activities, there have been a variety of proposals to reduce the emission of greenhouse gases into the atmosphere. Stationary sources of greenhouse gasses such as fossil fuel-burning thermal power plants, industrial plants, and resource processing facilities (as well as other such sources) present an environmental challenge due to the volumes of greenhouse gasses produced. However, they also present an opportunity to mitigate their harm, in that their stationary nature and in some cases, the ability to site the plant at a variety of locations, permits a variety of approaches to reduction of greenhouse gas emissions. One approach that has been practiced in the prior art to remove greenhouse gases emanating from stationary sources has been to sequester greenhouse gas generated by the source within deep subsurface formations. Typically, concentrated gas such as CO2 is injected under pressure into a subsurface formation. CO2 can be sequestered within a deep saline aquifer or elsewhere, in a variety of physical forms. Once sequestered within a suitably deep formation, greenhouse gasses are expected to reside in the formation for an extremely long time, thereby effectively removing them from the atmosphere. In general, 2 deep subsurface sequestration is seen as a promising solution to the greenhouse gas problem. However, conventional methods are costly in that they require the greenhouse gasses to be separated from the raw gas waste stream prior to subsurface injection. Therefore, there is a need for a new method for reducing the emission of greenhouse gases into the atmosphere. SUMMARY Deep saline aquifers exist in many locations and represent an attractive location to sequester CO2 and other greenhouse gasses. These aquifers are also capable of sequestering certain non-greenhouse gasses such as sulfur dioxide that constitute significant environmental pollutants. Due to their depth, sequestration within suitably selected saline aquifers of this type is usually considered substantially permanent. In these environments (and potentially others), greenhouse gas such as CO as well as some non-greenhouse pollutants such as sulfur dioxide can be differentially sequestered such that the non-polluting non-greenhouse gasses such as nitrogen are either not sequestered or only minimally sequestered. For example, in aqueous environments, in particular saline solutions, CO2 readily dissolves into solution (as does sulfur dioxide), while nitrogen is only minimally soluble. In these environments, a mixture of gasses which contains greenhouse and non-greenhouse gasses may separate, with at least some of the greenhouse gasses being sequestered within the formation (along with sulfur dioxide), while the non-greenhouse gas separates out. To the knowledge of the present inventors, this principle has not previously been employed in the context of deep subsurface greenhouse gas sequestration, so as to permit a raw gaseous waste stream to be injected into a subsurface formation such that the greenhouse gas components are sequestered whilst nitrogen and other non-greenhouse gasses are vented back to the atmosphere. According to one embodiment of the present invention, there is provided a method for reducing the emission of greenhouse gases into the atmosphere. According to one aspect, the method comprises, a) selecting a gas stream from a stationary source of production, the gas stream comprising a mixture of at least one greenhouse gas and nitrogen; b) selecting a subsurface injection formation comprising a deep water-laden layer overlain by one or more layers, said water-laden layer being capable of sequestering at least a portion of the greenhouse gas while allowing the nitrogen to rise to the top of the formation; c) pressurizing 3 the gas stream; d) delivering the pressurized gas stream into an injection well having an inlet communicating with said gas stream and an outlet in communication with said water-laden layer, thereby injecting the gas stream under pressure into the water-laden layer of the subsurface injection formation; e) allowing the gases in the gas stream to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the formation water in the water-laden layer of the subsurface injection formation, ii) displace formation water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the formation water in the water-laden layer of the subsurface injection formation and displace formation water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation and the nitrogen rises to the top of the formation; and f) venting the nitrogen component of the gas stream from the water-laden layer. The conditions within the water-laden layer, and the nature of the greenhouse and non-greenhouse gasses present in the waste stream, permit sequestration of the greenhouse gasses and non-sequestration, or separation, of the nitrogen. Preferably, the water-laden layer consists of a deep saline aquifer. Preferably, at least one of the overlying layers is substantially impermeable to water. The separated nitrogen is permitted to rise within the formation, until blocked by the overlying impermeable layer where it accumulates as a gas cap. This non-greenhouse gas is vented to the ground surface, preferably via a well that reaches into the subsurface region where the non-greenhouse gas accumulates. In another embodiment, the one or more than one type of greenhouse gas is selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane, 1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane. In another embodiment, the source of production is from a human industrial activity. In one embodiment, human industrial activity is selected from the group consisting of an ethylene production plant, a fertilizer production plant, a methanol production plant, a mining operation, a natural gas production operation, a natural gas treatment plant, a petroleum production operation and a petroleum refining operation. In one embodiment, the source is a thermal power plant and the gas consists of raw 4 flue gas from the combustion process. In another embodiment, the water-laden layer of the subsurface injection formation has a salinity of at least 10,000 ppm (10 gin/liter). In another embodiment, the subsurface injection formation has a pH of between 4 and 10. In another embodiment, the subsurface injection formation is at least 100 meters below the ground surface. In another embodiment, the subsurface injection formation is between 100 meters and 1000 meters below the ground surface. In another embodiment, the subsurface injection formation is at least 500 meters below the ground surface. In another embodiment, the subsurface injection formation is between 500 meters and 1000 meters below the ground surface. In one embodiment, the method further comprises performing a geochemical analysis of the formation water in the water-laden layer of the subsurface injection formation to verify that the subsurface injection formation comprises only ancient water, and that the formation water is not in communication with shallower, newer water sources. In another embodiment, the gas stream is injected within a distance from the source of production selected from the group consisting of 5 kilometers, 10 kilometers, 50 kilometers and 100 kilometers. In another embodiment, injecting of the gas stream comprises transporting the gas stream from the source of production to an injection pump at the surface site of injection of the gas stream above the subsurface injection formation. In another embodiment, injecting the gas stream comprises a) providing one or more than one device selected from the group consisting of a compressor, a condenser, a pipeline, a pump and a valve to process and b) transporting the greenhouse gases from the source of production to the surface site of injection of the gas stream above the subsurface injection formation. In another embodiment, the method further comprises modifying one or more than one attribute of the gas stream prior to or during injection, where the one or more than one attribute is selected from the group consisting of pH, pressure, salinity and temperature to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. As will be apparent from the nature of such attributes, the treatment may either modify the one or more of the above attributes of the gas stream itself, or the subsurface environment which contains the sequestered greenhouse gas. In another embodiment, injecting the gas stream comprises transporting the gas stream from the source of production 5 to the surface site of injection of the gas stream above the subsurface injection formation, and the method further comprises compressing the gas stream during transporting the gas stream. In another embodiment, the water-laden layer of the subsurface injection formation comprises a pore pressure and further comprises a fracture pressure, and the method further comprises compressing the gas stream to a pressure value greater than the pore pressure of the subsurface injection formation but less than the fracture pressure of the subsurface injection formation. In one embodiment, the method further comprises adding one or more than one chemical additive to the gas stream to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. In another embodiment, the method further comprises inducing hydraulic fractures into the subsurface injection formation before injecting the gas stream. In another embodiment, the gas stream is the waste stream from a thermal power plant, the thermal power plant comprises a combustion gases stack, and injecting the gas stream comprises diverting greenhouse gases present in a waste stream of the thermal power plant from the combustion gases stack of the thermal power plant to the injection site above the subsurface injection formation. In one embodiment, the percent of greenhouse gases in the gas stream from a source of production is 25 % or more than 25%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production is 50% or more than 50%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production is 95% or more than 95%. In another embodiment, the gas stream consists of greenhouse gases. In another embodiment, the gas stream comprises both greenhouse gases and non-greenhouse gases. In one embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation. In another embodiment, the injection well is a type of well selected from the group consisting of a vertical well, a deviated well and a horizontal well. In another embodiment, the method further comprises performing one or more than one of geological data analyses, geomechanical data analyses, and numerical simulation techniques to determine 6 the optimum injection-disposal well pattern, well spacing, and well configuration to optimize the dissolution of the greenhouse gases in the water-laden layer. In another embodiment, the gas stream comprises nitrogen, the subsurface injection formation comprises a surface side (top) toward the ground surface, the method further comprises, during or after, sequestering the greenhouse gases in the water-laden layer, allowing the nitrogen to rise toward the surface side (top) of the subsurface injection formation or between the subsurface injection formation and the ground surface until some or all of the nitrogen reaches a layer that is relatively impermeable to water, and the method further comprises venting the nitrogen into atmospheric gases above the ground surface. In another embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation, where the injection well is a first well, and where venting comprises providing a second well from the ground surface into the subsurface injection formation. In another embodiment, the method further comprises providing the second well with one or more than one of casing perforations, downhole or surface based water-gas separation systems, and downhole or surface pumps. In another embodiment, injecting the gas stream comprises injecting the gas stream from the source of production continually as the gas stream is produced by the source of production. In another embodiment, injecting the gas stream comprises injecting the gas stream from the source of production continually over a time selected from the group consisting of at least one day, at least one week, at least one month, at least one year, at least five years and at least ten years. In another embodiment, injecting the gas stream comprises injecting the gas stream from the source of production intermittently as the gas stream is produced by the source of production. 7 DESCRIPTION According to one embodiment of the present invention, there is provided a method for reducing the emission of greenhouse gases, such as for example carbon dioxide, into the atmosphere above a ground surface. The method comprises injecting a gas stream comprising one or more than one greenhouse gas into a subsurface injection formation. The gas stream includes nitrogen, a one non-greenhouse gas. The subsurface injection formation comprises a water-laden layer comprising formation water, and some or all of the greenhouse gases present in the gas stream become dissolved in the formation water in the subsurface injection formation sequestering the one or more than one greenhouse gas in the subsurface injection formation. Upon the CO2 being sequestered within the formation, the nitrogen component, which is not sequestered, accumulates within the formation, after which the nitrogen may be vented to the surface by any convenient means. The method thereby reduces the emission of greenhouse gases into the atmosphere. In a preferred embodiment, the method comprises injecting the gas stream near the source of production. Preferably, the gas stream consists of a raw gas stream from an industrial source such as a fossil fuel-burning thermal power plant. The raw gas stream contains CO2 and nitrogen. Typical flue gas effluent from a thermal power plant such as coal-fired plant contains CO2., with most of the balance being nitrogen. This flue gas stream may be introduced directly into the subsurface formation in accordance with the present method, as described in more detail herein. The method will now be disclosed in detail. As used in this disclosure, the terms "greenhouse gas" and "greenhouse gases" are defined as one or more than one gas selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane 1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane. Greenhouse gas should also be understood to include other gases that are identified in the future as contributing to the greenhouse effect. As used in this disclosure, except where the context requires otherwise, the term "comprise" and variations of the term, such as "comprising," "comprises" and "comprised" are not intended to exclude other additives, components, integers or steps. 8 As used in this disclosure, except where the context requires otherwise, the method steps disclosed and shown are not intended to be limiting nor are they intended to indicate that each step is essential to the method or that each step must occur in the order disclosed. As used in this disclosure, the term "near the source of production" is defined as within 100 kilometers of the source of production. As used in this disclosure, the phrase "relatively impermeable to water" means having a permeability to water of less than 10 millidarcy. As used in this disclosure, the phrase "relatively low permeability to water" means having a permeability to water of between 10 millidarcy and 100 millidarcy. As used in this disclosure, the phrase "relatively high permeability to water" means having a permeability to water of greater than 100 millidarcy. As used in this disclosure, the phrase "high porosity" means having a rock formation with an intergranular void space of at least 20% of the total rock formation volume. According to one embodiment of the present invention, there is provided a method for reducing the emission of greenhouse gases into the atmosphere. First, the method comprises selecting a gas stream from a source of production, the gas stream comprising one or more than one type of greenhouse gas selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane, 1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane. In one embodiment, the source is from a human industrial activity. In a preferred embodiment, the human industrial activity is selected from the group consisting of an ethylene production plant, a fertilizer production plant, a methanol production plant, a mining operation, a natural gas production operation, a natural gas treatment plant, a petroleum production operation and a petroleum refining operation, such as for example heavy oil and bitumen upgraders. In another preferred embodiment, the source of production is a thermal power plant, where coal, oil or natural gas are burned to generate steam for electricity generation, where the greenhouse gas is from the gaseous waste stream (also known as "flue gas") generated during the thermal process and coming from the combustion gases stack. The source can, however, be from any suitable facility, as will be understood by those with skill in the art with reference to this disclosure. The gas stream includes nitrogen, a non-greenhouse gas. 9 Next, the method comprises selecting a subsurface injection formation below the ground surface for sequestering the one or more than one greenhouse gas in the gas stream from the source and for permitting the nitrogen within the gas stream to accumulate within the formation separately from the greenhouse gas. In one embodiment, a subsurface injection formation comprises a water-laden layer comprising formation water separated from the ground surface above the subsurface injection formation by one or more than one layer that is relatively impermeable to water (less than 10 millidarcy). For example, in one embodiment, the subsurface injection formation comprises formation water having a high porosity, such as a water-laden layer of a water-saturated sand formation, where the formation water is below a layer comprising shale or comprising other rock types containing clay minerals, or comprising both shale and comprising other rock types containing clay minerals. Another suitable subsurface injection formation is sufficiently deep to ensure that the injected gas will be sequestered and not pose a potential threat to the environment or to water supplies, even without thick and clearly defined layers of relatively high permeability to water layers alternating with relatively low permeability to water/relatively impermeable to water layers. As will be understood by those with skill in the art with reference to this disclosure, a sufficient depth is related to the dissolution rate of the carbon dioxide as compared to the rate of rise due to buoyancy. Once the carbon dioxide is fully absorbed in the water, the carbon dioxide-water mixture is more dense than pure water and will no longer tend to rise to the ground surface. As will be understood by those with skill in the art with reference to this disclosure, the higher the pressure of the water-laden layer and the lower the temperature of the water-laden layer, the greater the solubility of the greenhouse gas such as carbon dioxide being sequestered in the water-laden layer. In one embodiment, the water-laden layer of the subsurface injection formation has an average (median) temperature of between 20 C and 200 C. In another embodiment, the water-laden layer of the subsurface injection formation has an average (median) pressure gradient (pressure per unit of depth, i.e., kilopascals per meter) of between 8 kilopascals (kPa)/meter of depth and 12 kilopascals/meter of depth. In one embodiment, the water-laden layer of the subsurface injection formation has a salinity of at least 10,000 ppm (10 gm/liter), and is therefore unsuitable for human 10 consumption or for industrial use other than the method for reducing the emission of greenhouse gases into the atmosphere disclosed in this disclosure. In another embodiment, the water-laden layer of the subsurface injection formation has a pH of between 4 and 10 to facilitate solubility of the greenhouse gas in the water-laden layer. In a particularly preferred embodiment, the subsurface injection formation is deeper than any groundwater which can be removed for human use. In another preferred embodiment, the subsurface injection formation is separated from any zone of potable groundwater or groundwater suitable for an industrial use nearer the ground surface by at least one layer with relatively high permeability to water adjacent at least one layer with relatively low permeability (or relatively impermeable) to water. In another preferred embodiment, the subsurface injection formation is at least 100 meters below the ground surface. The 100 meter depth is sufficiently deep to insure that the injected greenhouse gas will be sequestered, even without at least one layer with relatively high permeability to water adjacent at least one layer with relatively low permeability (or relatively impermeable) to water, and sufficiently deep to ensure that the injected gas will not pose a potential threat to the environment or to water supplies. In a preferred embodiment, the subsurface injection formation is between 100 meters and 1000 meters below the ground surface, which is a range of depths near enough to the surface to allow injection of the gas in a cost-effective manner. In a particularly preferred embodiment, the subsurface injection formation is at least 500 meters below the ground surface. In another particularly preferred embodiment, the subsurface injection formation is between 500 meters and 1000 meters below the ground surface. In one embodiment, the method comprises selecting a surface site of injection of the gas stream above the subsurface injection formation for accessing the subsurface injection formation. In a preferred embodiment, the surface site of injection of the gas stream, as well as the subsurface injection formation, is selected to additionally protect ground and ocean waters, such as for example by selecting a subsurface injection formation that does not outcrop or interact with formations between the subsurface injection formation and the ground surface. In one embodiment, the method further comprises performing a geochemical analysis of the formation water in the water-laden layer of the subsurface injection formation 11 to verify that the subsurface injection formation comprises only ancient water, and that the formation water is not in communication with non-ancient water sources. The term "ancient water" is well understood by those with skill in this art, and means water deposited within the ground at least one million years ago and not rechargeable from the surface by rain water percolating through the ground, whereas "non-ancient water" means water that was deposited within the ground less than one million of years ago and that is rechargeable from the surface. Then, the method comprises injecting the gas stream comprising the one or more than one greenhouse gas from the source from the surface site of injection above the subsurface injection formation into the water-laden layer of the subsurface injection formation. In one embodiment, the gas stream is injected near the source of production. In one embodiment, the gas stream is injected within 100 kilometers of the source of production. In another embodiment, the gas stream is injected within 50 kilometers of the source of production. In another embodiment, the gas stream is injected within 10 kilometers of the source of production. In another embodiment, the gas stream is injected within 5 kilometers of the source of production. In one embodiment, injecting of the gas stream comprises transporting the gas stream from the source of production to an injection pump at the surface site of injection of the gas stream above the subsurface injection formation. In one embodiment, transporting the gas stream comprises providing one or more than one device selected from the group consisting of a compressor, a condenser, a pipeline, a pump and a valve to process and to move the greenhouse gases from the source of production to the surface site of injection of the gas stream above the subsurface injection formation. In one embodiment, the method further comprises modifying one or more than one attribute of the gas stream prior to or during injection, where the one or more than one attribute is selected from the group consisting of pH, pressure, salinity and temperature to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. For example, in one embodiment, the pressure of the injected gas stream is modified to come closer to or match the pressure of the water-laden layer of the subsurface injection formation. In another 12 embodiment, the temperature of the injected gas stream is modified to come closer to or match the temperature of the water-laden layer of the subsurface injection formation. In another embodiment, the pH of the injected gas stream is modified to come closer to or match the pH of the water-laden layer of the subsurface injection formation. In another embodiment, the salinity of the injected gas stream is modified to come closer to or match the salinity of the water-laden layer of the subsurface injection formation. In one embodiment, modifying one or more than one attribute of the gas stream comprises providing a heat exchanger to decrease the temperature of the gas stream prior to injection during transporting the gas stream. In one embodiment, modifying one or more than one attribute of the gas stream comprises compressing the gas stream during transporting the gas stream. In one embodiment, modifying one or more than one attribute comprises adding one or more than one chemical additive to the gas stream. In a preferred embodiment, the water-laden layer of the subsurface injection formation comprises a pore pressure (the pressure of water in the pore spaces of the subsurface injection formation) and further comprises a fracture pressure (the pressure of injected substance into the subsurface injection formation that is required to surpass the strength of the subsurface injection formation rock and thereby creates fractures/cracks in the subsurface injection formation), and the method comprises compressing the gas stream to a pressure value greater than the pore pressure of the subsurface injection formation (to facilitate injection) but less than the fracture pressure of the subsurface injection formation (to avoid fracturing the subsurface injection formation and risk loss of sequestration of the gas). For example, where the pore pressure of a subsurface injection formation at 500 meter depth is 5 MPa, and where the fracture pressure of the subsurface injection formation at 500 meter depth is 10 MPa, the gas stream would be compressed to a pressure of at least 5 MPa but less than 10 MPa to be injected into the subsurface injection formation. In another embodiment, the method further comprises inducing hydraulic fractures into the subsurface injection formation before injecting the gas stream. Inducing hydraulic fractures into the subsurface injection formation increases the surface area of contact with the formation water in the water-laden layer thereby promoting dissolution of the one or more than one greenhouse gas in the gas stream into the water-laden layer of the subsurface 13 injection formation. Further, inducing hydraulic fractures into the subsurface injection formation decreases resistance within the subsurface injection formation to injection of the gas stream. In one embodiment, the percent of greenhouse gases in the gas stream from a source of production, such as the waste gas stream in the combustion gases stack of a thermal power plant, is 25% or more than 25%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production, such as the waste gas stream in the combustion gases stack of a thermal power plant, is 50% or more than 50%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production, such as the waste gas stream in the combustion gases stack of a thermal power plant, is 95 % or more than 95%. In another embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation. In one embodiment, the injection well is a type of well selected from the group consisting of a vertical well, a deviated well and a horizontal well. In a preferred embodiment, the well is a horizontal well. In one embodiment, the method further comprises performing one or more than one of geological data analyses, geomechanical data analyses, and numerical simulation techniques to determine the optimum injection-disposal well pattern, well spacing, and well configuration to optimize the dissolution of the greenhouse gases in the water-laden layer. Next, the method further comprises allowing the greenhouse gases in the gas stream (and non-greenhouse gases when present) to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the formation water in the water-laden layer of the subsurface injection formation, ii) displace formation water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the formation water in the water-laden layer of the subsurface injection formation and displace formation water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation. In one embodiment, injecting the gas stream comprises injecting the gas stream from the source of production continually as the gas stream is produced by the source of 14 production, such as for example injecting the gas stream continually over a time selected from the group consisting of at least one day, at least one week, at least one month, at least one year, at least five years and at least ten years. In another embodiment, the method comprises injecting the gas stream from the source of production intermittently as the gas stream is produced by the source of production, such as for example injecting the gas stream for 8 hours per day, six days of each week. EXAMPLE I Figure 1 illustrates the method described in Example 1. By way of example only, a reduction of emission of greenhouse gases into the atmosphere above a ground surface is accomplished as follows. First, a gas stream is selected as the waste gas stream (flue gas) generated by a thermal power plant. As an example, a 1000 megawatts coal-fired thermal power plant typically generates about 3.4 million m3 flue gas/hr, where the flue gas comprises about 12% carbon dioxide, thereby generating about 410,000 m3 carbon dioxide/hr of carbon dioxide, or about 10,000,000 m3 carbon dioxide/day. Most of the non-CCh component in the flue gas consists of nitrogen. Next, a subsurface injection formation suitable for sequestering the one or more than one greenhouse gas in the waste gas stream is selected, where the subsurface injection formation is at least 900 meters below the surface site of injection above the subsurface injection formation, and where the subsurface injection formation comprises a water-laden sand layer of relatively high permeability to water below a layer of shale 3 that is relatively impermeable to water. In this example, the subsurface injection formation comprises a water-laden sand layer of about 20 km wide by 20 km long by 100 meters thick with an average porosity of 25 %. Then, the waste gas stream consisting for raw flue gas is removed from the combustion gases stack of the thermal power plant and transported by pipeline to the surface site of injection above the subsurface injection formation. Next, the waste gas stream is pressurized and injected into the subsurface injection formation at a pressure of about 1 x 104 kPa. Carbon dioxide has a solubility in water of about 27 cubic meters (m3) of carbon dioxide per cubic meter water at about 1 x 104 kPa and 55 C. Therefore, the storage capacity of the subsurface injection formation is about 10 15 billion cubic meters of water with a carbon dioxide storage capacity of about 267 billion cubic meters. Assuming the waste gas stream is 12% carbon dioxide and 88% nitrogen, and that the nitrogen is vented back to the atmosphere, the carbon dioxide storage capacity of the subsurface injection formation is about 73 years worth of carbon dioxide production (267 billion m3 divided by 10 million mVday divided by 365 days per year). Finally, the greenhouse gases in the waste gas stream are allowed to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the water in the water-laden layer of the subsurface injection formation, ii) displace water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the water in the water-laden layer of the subsurface injection formation and displace water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation. The subsurface injection formation comprises a surface side (top) toward the ground surface. As described above, the method further comprises, during or after, sequestering the greenhouse gases in the water-laden layer, allowing the nitrogen to rise toward the surface side (the top) of the subsurface injection formation or between the subsurface injection formation and the ground surface until some or all of the nitrogen reaches a layer that is relatively impermeable to water, and the method further comprises venting the nitrogen into atmospheric gases above the ground surface. In one embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation, the injection well is a first well , and venting comprises providing a second well from the ground surface into the subsurface injection formation. In one embodiment, the second well is selected from the group consisting of a vertical well, a deviated well and a horizontal well. In a preferred embodiment, the method further comprises providing the second well with one or more than one of casing perforations, downhole or surface based water-gas separation systems, and downhole or surface pumps, as will be understood by those with skill in the art with reference to this disclosure. Although the present invention has been discussed in considerable detail with reference to certain preferred embodiments, other embodiments are possible. Therefore, the 16 scope of the appended claims should not be limited to the description of preferred embodiments contained in this disclosure. All references cited herein are incorporated by reference in their entirety. 17 We Claim : 1. A method for removing a greenhouse gas from a gas stream emanating from a stationary source of greenhouse gas, comprising: a) selecting a gas stream from a stationary source of production, said gas stream comprising a mixture of greenhouse gas and non-greenhouse gas; b) selecting a subsurface formation comprising a deep water-laden layer overlain by at least one overlying layer, said water-laden layer being capable of sequestering at least a portion of the greenhouse gas; c) pressurizing said gas stream; d) delivering said pressurized gas stream into an injection well having an inlet communicating with said gas stream and an outlet within said water-laden layer, thereby introducing said gas stream under pressure into said water-laden layer; e) permitting at least a portion of said greenhouse gas to be sequestered within the water-laden layer and said non-greenhouse gas separated from said greenhouse gas to accumulate beneath said overlying layer; and f) venting said non-greenhouse gas from said formation. 2. A method as defined in claim 1 wherein said greenhouse gas comprises CO2. 3. A method as defined in claim 1 wherein said gas stream comprises flue gas. 4. A method as defined in any one of claims 1-3 wherein said non-greenhouse gas is permitted to accumulate within said water laden layer at a location immediately beneath said overlying layer following separation from said gas stream within said formation, and said step of venting comprises accessing said accumulated non-greenhouse gas via a well to permit release of said non-greenhouse gas from said water-laden layer. 5. A method as defined in any of claims 1-4 wherein said non-greenhouse gas comprises nitrogen. 18 6. A method for reducing the emission of greenhouse gases into the atmosphere above a ground surface, the method comprising: a) selecting a gas stream from a source of production, the gas stream comprising one or more than one type of greenhouse gas and nitrogen; b) selecting a subsurface injection formation below the ground surface for sequestering the one or more than one greenhouse gas in the gas stream from the source of production, the subsurface injection formation comprising a water-laden layer comprising formation water, said formation comprising a surface side (top) toward the ground surface and the subsurface injection formation is separated from the ground surface above the subsurface injection formation by one or more layers relatively impermeable to water; c) selecting a surface site of injection of the gas stream above the subsurface injection formation for accessing the subsurface injection formation; d) injecting the gas stream comprising the one or more than one greenhouse gas from the source of production from the surface site of injection into the formation water of the water-laden layer of the subsurface injection formation; e) allowing the greenhouse gases in the gas stream to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the formation water in the water-laden layer of the subsurface injection formation, ii) displace formation water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the formation water in the water-laden layer of the subsurface injection formation and displace formation water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation; f) during or after sequestering the greenhouse gases in the water-laden layer, allowing said nitrogen to rise toward the surface side (top) of the subsurface injection formation or between the subsurface injection formation and the ground surface until some or all of the nitrogen reaches a layer that is relatively impermeable to water; and g) venting the nitrogen into atmospheric gases above the ground surface. 19 7. The method of claim 6, where the one or more than one type of greenhouse gas is selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane, 1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane. 8. The method of claim 6, where the water-laden layer of the subsurface injection formation has a salinity of at least 10,000 ppm (10 gm/liter). 9. The method of claim 6 where the method further comprises modifying one or more than one attribute of the gas stream prior to or during injection, where the one or more than one attribute is selected from the group consisting of pressure and temperature to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. 10. The method of claim 6, where the water-laden layer of the subsurface injection formation comprises a pore pressure and further comprises a fracture pressure, and where the method comprises compressing the gas stream prior to injection into the subsurface injection formation to a pressure value greater than the pore pressure of the subsurface injection formation but less than the fracture pressure of the subsurface injection formation. U. The method of claim 6, further comprising adding one or more than one chemical additive to the gas stream to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. 12. The method of claim 6, further comprising inducing hydraulic fractures into the subsurface injection formation before injecting the gas stream. 13. The method of claim 6, further comprising performing one or more than one of geological data analyses, geomechanical data analyses, and numerical simulation techniques to determine the optimum injection-disposal well pattern, well spacing, and well configuration to optimize the dissolution of the greenhouse gases in the water-laden layer. 20 14. The method of claim 6 where injecting the gas stream comprises injecting the gas stream from the source of production continually as the gas stream is produced by the source of production. 15. The method of claim 6, where injecting the gas stream comprises injecting the gas stream from the source of production intermittently as the gas stream is produced by the source of production. For BILAK, Roman; BRUNO, Michael S.; ROTHENBURG, Leo; and DUSSEAULT, Maurice B. By their Agent (SAIMA SAGHIR ANSARI) KRISHNA & SAURASTRI ASSOCIATES 21

Full Text

FORM 2

THE PATENTS ACT, 1970 (39 of 1970)
& THE PATENTS RULES, 2003
COMPLETE SPECIFICATION
[See section 10, Rule 13]
METHOD FOR REDUCING THE EMISSION OF GREEN HOUSE GASES INTO THE ATMOSPHERE;
BRUNO, MiCHAEL S. AN AMERICAN NATiONAL OF 1105, STARLIT LANE, MONROVIA, CALIFORNIA 91016, U.S.A; BILAK, ROMAN, A CANADIAN NATIONAL OF 49 MACEWAN PARK CLOSE, N.W. CALGARY, AL- BERTA T3K3Z6, CANADA; ROTHENBURG, LEO A CANADIAN NATIONAL OF 188 MOHAWK AVENUE, WATERLOO, ONTARIO N2L 2T3, CANADA & DUSSEAULT, MAURICE B„ A CANADIAN NATIONAL OF 7203 - 87 STREET, OSOYOOS, BRITISH COLUMBIA V0H 1V0, CANADA
THE FOLLOWING SPECIFICATION
PARTICULARLY DESCRIBES THE INVENTION AND THE MANNER IN WHICH IT IS TO BE PERFORMED.

CROSS-REFERENCE TO RELATED APPLICATIONS
The present Application claims the benefit of United States Provisional Patent Application No. 60/869,103, titled "Method for Reducing the Emission of Green House Gases into the Atmosphere," filed December 7, 2006, the contents of which are incorporated in this disclosure by reference in their entirety.
BACKGROUND
In recent years, it has become evident that general climatic warming is occurring due to the "greenhouse effect" caused by the increasing presence of certain greenhouse gases (GHGs) generated from human activities. Among the gaseous components in the atmosphere that contribute to the greenhouse effect are carbon dioxide, methane, nitrous oxide and ozone. By contrast, oxygen, nitrogen and sulfur dioxide do not appear to contribute to the greenhouse effect.
In order to mitigate the effects of increasing greenhouse gases generated from human activities, there have been a variety of proposals to reduce the emission of greenhouse gases into the atmosphere. Stationary sources of greenhouse gasses such as fossil fuel-burning thermal power plants, industrial plants, and resource processing facilities (as well as other such sources) present an environmental challenge due to the volumes of greenhouse gasses produced. However, they also present an opportunity to mitigate their harm, in that their stationary nature and in some cases, the ability to site the plant at a variety of locations, permits a variety of approaches to reduction of greenhouse gas emissions.
One approach that has been practiced in the prior art to remove greenhouse gases emanating from stationary sources has been to sequester greenhouse gas generated by the source within deep subsurface formations. Typically, concentrated gas such as CO2 is injected under pressure into a subsurface formation. CO2 can be sequestered within a deep saline aquifer or elsewhere, in a variety of physical forms. Once sequestered within a suitably deep formation, greenhouse gasses are expected to reside in the formation for an extremely long time, thereby effectively removing them from the atmosphere. In general,
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deep subsurface sequestration is seen as a promising solution to the greenhouse gas problem. However, conventional methods are costly in that they require the greenhouse gasses to be separated from the raw gas waste stream prior to subsurface injection.
Therefore, there is a need for a new method for reducing the emission of greenhouse gases into the atmosphere.
SUMMARY
Deep saline aquifers exist in many locations and represent an attractive location to sequester CO2 and other greenhouse gasses. These aquifers are also capable of sequestering certain non-greenhouse gasses such as sulfur dioxide that constitute significant environmental pollutants. Due to their depth, sequestration within suitably selected saline aquifers of this type is usually considered substantially permanent. In these environments (and potentially others), greenhouse gas such as CO as well as some non-greenhouse pollutants such as sulfur dioxide can be differentially sequestered such that the non-polluting non-greenhouse gasses such as nitrogen are either not sequestered or only minimally sequestered. For example, in aqueous environments, in particular saline solutions, CO2 readily dissolves into solution (as does sulfur dioxide), while nitrogen is only minimally soluble. In these environments, a mixture of gasses which contains greenhouse and non-greenhouse gasses may separate, with at least some of the greenhouse gasses being sequestered within the formation (along with sulfur dioxide), while the non-greenhouse gas separates out. To the knowledge of the present inventors, this principle has not previously been employed in the context of deep subsurface greenhouse gas sequestration, so as to permit a raw gaseous waste stream to be injected into a subsurface formation such that the greenhouse gas components are sequestered whilst nitrogen and other non-greenhouse gasses are vented back to the atmosphere.
According to one embodiment of the present invention, there is provided a method for reducing the emission of greenhouse gases into the atmosphere. According to one aspect, the method comprises, a) selecting a gas stream from a stationary source of production, the gas stream comprising a mixture of at least one greenhouse gas and nitrogen; b) selecting a subsurface injection formation comprising a deep water-laden layer overlain by one or more layers, said water-laden layer being capable of sequestering at least a portion of the greenhouse gas while allowing the nitrogen to rise to the top of the formation; c) pressurizing
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the gas stream; d) delivering the pressurized gas stream into an injection well having an inlet communicating with said gas stream and an outlet in communication with said water-laden layer, thereby injecting the gas stream under pressure into the water-laden layer of the subsurface injection formation; e) allowing the gases in the gas stream to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the formation water in the water-laden layer of the subsurface injection formation, ii) displace formation water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the formation water in the water-laden layer of the subsurface injection formation and displace formation water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation and the nitrogen rises to the top of the formation; and f) venting the nitrogen component of the gas stream from the water-laden layer. The conditions within the water-laden layer, and the nature of the greenhouse and non-greenhouse gasses present in the waste stream, permit sequestration of the greenhouse gasses and non-sequestration, or separation, of the nitrogen.
Preferably, the water-laden layer consists of a deep saline aquifer. Preferably, at least one of the overlying layers is substantially impermeable to water.
The separated nitrogen is permitted to rise within the formation, until blocked by the overlying impermeable layer where it accumulates as a gas cap. This non-greenhouse gas is vented to the ground surface, preferably via a well that reaches into the subsurface region where the non-greenhouse gas accumulates. In another embodiment, the one or more than one type of greenhouse gas is selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane, 1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane. In another embodiment, the source of production is from a human industrial activity. In one embodiment, human industrial activity is selected from the group consisting of an ethylene production plant, a fertilizer production plant, a methanol production plant, a mining operation, a natural gas production operation, a natural gas treatment plant, a petroleum production operation and a petroleum refining operation.
In one embodiment, the source is a thermal power plant and the gas consists of raw
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flue gas from the combustion process. In another embodiment, the water-laden layer of the subsurface injection formation has a salinity of at least 10,000 ppm (10 gin/liter). In another embodiment, the subsurface injection formation has a pH of between 4 and 10. In another embodiment, the subsurface injection formation is at least 100 meters below the ground surface. In another embodiment, the subsurface injection formation is between 100 meters and 1000 meters below the ground surface. In another embodiment, the subsurface injection formation is at least 500 meters below the ground surface. In another embodiment, the subsurface injection formation is between 500 meters and 1000 meters below the ground surface.
In one embodiment, the method further comprises performing a geochemical analysis of the formation water in the water-laden layer of the subsurface injection formation to verify that the subsurface injection formation comprises only ancient water, and that the formation water is not in communication with shallower, newer water sources. In another embodiment, the gas stream is injected within a distance from the source of production selected from the group consisting of 5 kilometers, 10 kilometers, 50 kilometers and 100 kilometers. In another embodiment, injecting of the gas stream comprises transporting the gas stream from the source of production to an injection pump at the surface site of injection of the gas stream above the subsurface injection formation. In another embodiment, injecting the gas stream comprises a) providing one or more than one device selected from the group consisting of a compressor, a condenser, a pipeline, a pump and a valve to process and b) transporting the greenhouse gases from the source of production to the surface site of injection of the gas stream above the subsurface injection formation. In another embodiment, the method further comprises modifying one or more than one attribute of the gas stream prior to or during injection, where the one or more than one attribute is selected from the group consisting of pH, pressure, salinity and temperature to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. As will be apparent from the nature of such attributes, the treatment may either modify the one or more of the above attributes of the gas stream itself, or the subsurface environment which contains the sequestered greenhouse gas. In another embodiment, injecting the gas stream comprises transporting the gas stream from the source of production
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to the surface site of injection of the gas stream above the subsurface injection formation, and the method further comprises compressing the gas stream during transporting the gas stream. In another embodiment, the water-laden layer of the subsurface injection formation comprises a pore pressure and further comprises a fracture pressure, and the method further comprises compressing the gas stream to a pressure value greater than the pore pressure of the subsurface injection formation but less than the fracture pressure of the subsurface injection formation.
In one embodiment, the method further comprises adding one or more than one chemical additive to the gas stream to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. In another embodiment, the method further comprises inducing hydraulic fractures into the subsurface injection formation before injecting the gas stream. In another embodiment, the gas stream is the waste stream from a thermal power plant, the thermal power plant comprises a combustion gases stack, and injecting the gas stream comprises diverting greenhouse gases present in a waste stream of the thermal power plant from the combustion gases stack of the thermal power plant to the injection site above the subsurface injection formation.
In one embodiment, the percent of greenhouse gases in the gas stream from a source of production is 25 % or more than 25%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production is 50% or more than 50%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production is 95% or more than 95%. In another embodiment, the gas stream consists of greenhouse gases. In another embodiment, the gas stream comprises both greenhouse gases and non-greenhouse gases.
In one embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation. In another embodiment, the injection well is a type of well selected from the group consisting of a vertical well, a deviated well and a horizontal well. In another embodiment, the method further comprises performing one or more than one of geological data analyses, geomechanical data analyses, and numerical simulation techniques to determine
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the optimum injection-disposal well pattern, well spacing, and well configuration to optimize the dissolution of the greenhouse gases in the water-laden layer.
In another embodiment, the gas stream comprises nitrogen, the subsurface injection formation comprises a surface side (top) toward the ground surface, the method further comprises, during or after, sequestering the greenhouse gases in the water-laden layer, allowing the nitrogen to rise toward the surface side (top) of the subsurface injection formation or between the subsurface injection formation and the ground surface until some or all of the nitrogen reaches a layer that is relatively impermeable to water, and the method further comprises venting the nitrogen into atmospheric gases above the ground surface. In another embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation, where the injection well is a first well, and where venting comprises providing a second well from the ground surface into the subsurface injection formation. In another embodiment, the method further comprises providing the second well with one or more than one of casing perforations, downhole or surface based water-gas separation systems, and downhole or surface pumps.
In another embodiment, injecting the gas stream comprises injecting the gas stream from the source of production continually as the gas stream is produced by the source of production. In another embodiment, injecting the gas stream comprises injecting the gas stream from the source of production continually over a time selected from the group consisting of at least one day, at least one week, at least one month, at least one year, at least five years and at least ten years. In another embodiment, injecting the gas stream comprises injecting the gas stream from the source of production intermittently as the gas stream is produced by the source of production.
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DESCRIPTION
According to one embodiment of the present invention, there is provided a method for reducing the emission of greenhouse gases, such as for example carbon dioxide, into the atmosphere above a ground surface. The method comprises injecting a gas stream comprising one or more than one greenhouse gas into a subsurface injection formation. The gas stream includes nitrogen, a one non-greenhouse gas. The subsurface injection formation comprises a water-laden layer comprising formation water, and some or all of the greenhouse gases present in the gas stream become dissolved in the formation water in the subsurface injection formation sequestering the one or more than one greenhouse gas in the subsurface injection formation. Upon the CO2 being sequestered within the formation, the nitrogen component, which is not sequestered, accumulates within the formation, after which the nitrogen may be vented to the surface by any convenient means. The method thereby reduces the emission of greenhouse gases into the atmosphere. In a preferred embodiment, the method comprises injecting the gas stream near the source of production.
Preferably, the gas stream consists of a raw gas stream from an industrial source such as a fossil fuel-burning thermal power plant. The raw gas stream contains CO2 and nitrogen. Typical flue gas effluent from a thermal power plant such as coal-fired plant contains CO2., with most of the balance being nitrogen. This flue gas stream may be introduced directly into the subsurface formation in accordance with the present method, as described in more detail herein.
The method will now be disclosed in detail.
As used in this disclosure, the terms "greenhouse gas" and "greenhouse gases" are defined as one or more than one gas selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane 1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane. Greenhouse gas should also be understood to include other gases that are identified in the future as contributing to the greenhouse effect.
As used in this disclosure, except where the context requires otherwise, the term "comprise" and variations of the term, such as "comprising," "comprises" and "comprised" are not intended to exclude other additives, components, integers or steps.
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As used in this disclosure, except where the context requires otherwise, the method steps disclosed and shown are not intended to be limiting nor are they intended to indicate that each step is essential to the method or that each step must occur in the order disclosed.
As used in this disclosure, the term "near the source of production" is defined as within 100 kilometers of the source of production.
As used in this disclosure, the phrase "relatively impermeable to water" means having a permeability to water of less than 10 millidarcy.
As used in this disclosure, the phrase "relatively low permeability to water" means having a permeability to water of between 10 millidarcy and 100 millidarcy.
As used in this disclosure, the phrase "relatively high permeability to water" means having a permeability to water of greater than 100 millidarcy.
As used in this disclosure, the phrase "high porosity" means having a rock formation with an intergranular void space of at least 20% of the total rock formation volume.
According to one embodiment of the present invention, there is provided a method for reducing the emission of greenhouse gases into the atmosphere. First, the method comprises selecting a gas stream from a source of production, the gas stream comprising one or more than one type of greenhouse gas selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane, 1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane. In one embodiment, the source is from a human industrial activity. In a preferred embodiment, the human industrial activity is selected from the group consisting of an ethylene production plant, a fertilizer production plant, a methanol production plant, a mining operation, a natural gas production operation, a natural gas treatment plant, a petroleum production operation and a petroleum refining operation, such as for example heavy oil and bitumen upgraders. In another preferred embodiment, the source of production is a thermal power plant, where coal, oil or natural gas are burned to generate steam for electricity generation, where the greenhouse gas is from the gaseous waste stream (also known as "flue gas") generated during the thermal process and coming from the combustion gases stack. The source can, however, be from any suitable facility, as will be understood by those with skill in the art with reference to this disclosure. The gas stream includes nitrogen, a non-greenhouse gas.
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Next, the method comprises selecting a subsurface injection formation below the ground surface for sequestering the one or more than one greenhouse gas in the gas stream from the source and for permitting the nitrogen within the gas stream to accumulate within the formation separately from the greenhouse gas. In one embodiment, a subsurface injection formation comprises a water-laden layer comprising formation water separated from the ground surface above the subsurface injection formation by one or more than one layer that is relatively impermeable to water (less than 10 millidarcy). For example, in one embodiment, the subsurface injection formation comprises formation water having a high porosity, such as a water-laden layer of a water-saturated sand formation, where the formation water is below a layer comprising shale or comprising other rock types containing clay minerals, or comprising both shale and comprising other rock types containing clay minerals. Another suitable subsurface injection formation is sufficiently deep to ensure that the injected gas will be sequestered and not pose a potential threat to the environment or to water supplies, even without thick and clearly defined layers of relatively high permeability to water layers alternating with relatively low permeability to water/relatively impermeable to water layers. As will be understood by those with skill in the art with reference to this disclosure, a sufficient depth is related to the dissolution rate of the carbon dioxide as compared to the rate of rise due to buoyancy. Once the carbon dioxide is fully absorbed in the water, the carbon dioxide-water mixture is more dense than pure water and will no longer tend to rise to the ground surface.
As will be understood by those with skill in the art with reference to this disclosure, the higher the pressure of the water-laden layer and the lower the temperature of the water-laden layer, the greater the solubility of the greenhouse gas such as carbon dioxide being sequestered in the water-laden layer. In one embodiment, the water-laden layer of the subsurface injection formation has an average (median) temperature of between 20 C and 200 C. In another embodiment, the water-laden layer of the subsurface injection formation has an average (median) pressure gradient (pressure per unit of depth, i.e., kilopascals per meter) of between 8 kilopascals (kPa)/meter of depth and 12 kilopascals/meter of depth.
In one embodiment, the water-laden layer of the subsurface injection formation has a salinity of at least 10,000 ppm (10 gm/liter), and is therefore unsuitable for human
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consumption or for industrial use other than the method for reducing the emission of greenhouse gases into the atmosphere disclosed in this disclosure. In another embodiment, the water-laden layer of the subsurface injection formation has a pH of between 4 and 10 to facilitate solubility of the greenhouse gas in the water-laden layer. In a particularly preferred embodiment, the subsurface injection formation is deeper than any groundwater which can be removed for human use. In another preferred embodiment, the subsurface injection formation is separated from any zone of potable groundwater or groundwater suitable for an industrial use nearer the ground surface by at least one layer with relatively high permeability to water adjacent at least one layer with relatively low permeability (or relatively impermeable) to water.
In another preferred embodiment, the subsurface injection formation is at least 100 meters below the ground surface. The 100 meter depth is sufficiently deep to insure that the injected greenhouse gas will be sequestered, even without at least one layer with relatively high permeability to water adjacent at least one layer with relatively low permeability (or relatively impermeable) to water, and sufficiently deep to ensure that the injected gas will not pose a potential threat to the environment or to water supplies. In a preferred embodiment, the subsurface injection formation is between 100 meters and 1000 meters below the ground surface, which is a range of depths near enough to the surface to allow injection of the gas in a cost-effective manner. In a particularly preferred embodiment, the subsurface injection formation is at least 500 meters below the ground surface. In another particularly preferred embodiment, the subsurface injection formation is between 500 meters and 1000 meters below the ground surface.
In one embodiment, the method comprises selecting a surface site of injection of the gas stream above the subsurface injection formation for accessing the subsurface injection formation. In a preferred embodiment, the surface site of injection of the gas stream, as well as the subsurface injection formation, is selected to additionally protect ground and ocean waters, such as for example by selecting a subsurface injection formation that does not outcrop or interact with formations between the subsurface injection formation and the ground surface. In one embodiment, the method further comprises performing a geochemical analysis of the formation water in the water-laden layer of the subsurface injection formation
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to verify that the subsurface injection formation comprises only ancient water, and that the formation water is not in communication with non-ancient water sources. The term "ancient water" is well understood by those with skill in this art, and means water deposited within the ground at least one million years ago and not rechargeable from the surface by rain water percolating through the ground, whereas "non-ancient water" means water that was deposited within the ground less than one million of years ago and that is rechargeable from the surface.
Then, the method comprises injecting the gas stream comprising the one or more than one greenhouse gas from the source from the surface site of injection above the subsurface injection formation into the water-laden layer of the subsurface injection formation. In one embodiment, the gas stream is injected near the source of production. In one embodiment, the gas stream is injected within 100 kilometers of the source of production. In another embodiment, the gas stream is injected within 50 kilometers of the source of production. In another embodiment, the gas stream is injected within 10 kilometers of the source of production. In another embodiment, the gas stream is injected within 5 kilometers of the source of production.
In one embodiment, injecting of the gas stream comprises transporting the gas stream from the source of production to an injection pump at the surface site of injection of the gas stream above the subsurface injection formation. In one embodiment, transporting the gas stream comprises providing one or more than one device selected from the group consisting of a compressor, a condenser, a pipeline, a pump and a valve to process and to move the greenhouse gases from the source of production to the surface site of injection of the gas stream above the subsurface injection formation.
In one embodiment, the method further comprises modifying one or more than one attribute of the gas stream prior to or during injection, where the one or more than one attribute is selected from the group consisting of pH, pressure, salinity and temperature to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation. For example, in one embodiment, the pressure of the injected gas stream is modified to come closer to or match the pressure of the water-laden layer of the subsurface injection formation. In another
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embodiment, the temperature of the injected gas stream is modified to come closer to or match the temperature of the water-laden layer of the subsurface injection formation. In another embodiment, the pH of the injected gas stream is modified to come closer to or match the pH of the water-laden layer of the subsurface injection formation. In another embodiment, the salinity of the injected gas stream is modified to come closer to or match the salinity of the water-laden layer of the subsurface injection formation. In one embodiment, modifying one or more than one attribute of the gas stream comprises providing a heat exchanger to decrease the temperature of the gas stream prior to injection during transporting the gas stream. In one embodiment, modifying one or more than one attribute of the gas stream comprises compressing the gas stream during transporting the gas stream. In one embodiment, modifying one or more than one attribute comprises adding one or more than one chemical additive to the gas stream.
In a preferred embodiment, the water-laden layer of the subsurface injection formation comprises a pore pressure (the pressure of water in the pore spaces of the subsurface injection formation) and further comprises a fracture pressure (the pressure of injected substance into the subsurface injection formation that is required to surpass the strength of the subsurface injection formation rock and thereby creates fractures/cracks in the subsurface injection formation), and the method comprises compressing the gas stream to a pressure value greater than the pore pressure of the subsurface injection formation (to facilitate injection) but less than the fracture pressure of the subsurface injection formation (to avoid fracturing the subsurface injection formation and risk loss of sequestration of the gas). For example, where the pore pressure of a subsurface injection formation at 500 meter depth is 5 MPa, and where the fracture pressure of the subsurface injection formation at 500 meter depth is 10 MPa, the gas stream would be compressed to a pressure of at least 5 MPa but less than 10 MPa to be injected into the subsurface injection formation.
In another embodiment, the method further comprises inducing hydraulic fractures into the subsurface injection formation before injecting the gas stream. Inducing hydraulic fractures into the subsurface injection formation increases the surface area of contact with the formation water in the water-laden layer thereby promoting dissolution of the one or more than one greenhouse gas in the gas stream into the water-laden layer of the subsurface
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injection formation. Further, inducing hydraulic fractures into the subsurface injection formation decreases resistance within the subsurface injection formation to injection of the gas stream.
In one embodiment, the percent of greenhouse gases in the gas stream from a source of production, such as the waste gas stream in the combustion gases stack of a thermal power plant, is 25% or more than 25%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production, such as the waste gas stream in the combustion gases stack of a thermal power plant, is 50% or more than 50%. In another embodiment, the percent of greenhouse gases in the gas stream from a source of production, such as the waste gas stream in the combustion gases stack of a thermal power plant, is 95 % or more than 95%.
In another embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation. In one embodiment, the injection well is a type of well selected from the group consisting of a vertical well, a deviated well and a horizontal well. In a preferred embodiment, the well is a horizontal well.
In one embodiment, the method further comprises performing one or more than one of geological data analyses, geomechanical data analyses, and numerical simulation techniques to determine the optimum injection-disposal well pattern, well spacing, and well configuration to optimize the dissolution of the greenhouse gases in the water-laden layer.
Next, the method further comprises allowing the greenhouse gases in the gas stream (and non-greenhouse gases when present) to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the formation water in the water-laden layer of the subsurface injection formation, ii) displace formation water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the formation water in the water-laden layer of the subsurface injection formation and displace formation water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation.
In one embodiment, injecting the gas stream comprises injecting the gas stream from the source of production continually as the gas stream is produced by the source of
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production, such as for example injecting the gas stream continually over a time selected from the group consisting of at least one day, at least one week, at least one month, at least one year, at least five years and at least ten years. In another embodiment, the method comprises injecting the gas stream from the source of production intermittently as the gas stream is produced by the source of production, such as for example injecting the gas stream for 8 hours per day, six days of each week.
EXAMPLE I
Figure 1 illustrates the method described in Example 1. By way of example only, a reduction of emission of greenhouse gases into the atmosphere above a ground surface is accomplished as follows. First, a gas stream is selected as the waste gas stream (flue gas) generated by a thermal power plant. As an example, a 1000 megawatts coal-fired thermal power plant typically generates about 3.4 million m3 flue gas/hr, where the flue gas comprises about 12% carbon dioxide, thereby generating about 410,000 m3 carbon dioxide/hr of carbon dioxide, or about 10,000,000 m3 carbon dioxide/day. Most of the non-CCh component in the flue gas consists of nitrogen.
Next, a subsurface injection formation suitable for sequestering the one or more than one greenhouse gas in the waste gas stream is selected, where the subsurface injection formation is at least 900 meters below the surface site of injection above the subsurface injection formation, and where the subsurface injection formation comprises a water-laden sand layer of relatively high permeability to water below a layer of shale 3 that is relatively impermeable to water. In this example, the subsurface injection formation comprises a water-laden sand layer of about 20 km wide by 20 km long by 100 meters thick with an average porosity of 25 %.
Then, the waste gas stream consisting for raw flue gas is removed from the combustion gases stack of the thermal power plant and transported by pipeline to the surface site of injection above the subsurface injection formation.
Next, the waste gas stream is pressurized and injected into the subsurface injection formation at a pressure of about 1 x 104 kPa. Carbon dioxide has a solubility in water of about 27 cubic meters (m3) of carbon dioxide per cubic meter water at about 1 x 104 kPa and 55 C. Therefore, the storage capacity of the subsurface injection formation is about 10
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billion cubic meters of water with a carbon dioxide storage capacity of about 267 billion cubic meters. Assuming the waste gas stream is 12% carbon dioxide and 88% nitrogen, and that the nitrogen is vented back to the atmosphere, the carbon dioxide storage capacity of the subsurface injection formation is about 73 years worth of carbon dioxide production (267 billion m3 divided by 10 million mVday divided by 365 days per year).
Finally, the greenhouse gases in the waste gas stream are allowed to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the water in the water-laden layer of the subsurface injection formation, ii) displace water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the water in the water-laden layer of the subsurface injection formation and displace water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation.
The subsurface injection formation comprises a surface side (top) toward the ground surface. As described above, the method further comprises, during or after, sequestering the greenhouse gases in the water-laden layer, allowing the nitrogen to rise toward the surface side (the top) of the subsurface injection formation or between the subsurface injection formation and the ground surface until some or all of the nitrogen reaches a layer that is relatively impermeable to water, and the method further comprises venting the nitrogen into atmospheric gases above the ground surface. In one embodiment, injecting the gas stream comprises installing an injection well into the subsurface injection formation from the surface site of injection above the subsurface injection formation, the injection well is a first well , and venting comprises providing a second well from the ground surface into the subsurface injection formation. In one embodiment, the second well is selected from the group consisting of a vertical well, a deviated well and a horizontal well. In a preferred embodiment, the method further comprises providing the second well with one or more than one of casing perforations, downhole or surface based water-gas separation systems, and downhole or surface pumps, as will be understood by those with skill in the art with reference to this disclosure.
Although the present invention has been discussed in considerable detail with reference to certain preferred embodiments, other embodiments are possible. Therefore, the
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scope of the appended claims should not be limited to the description of preferred embodiments contained in this disclosure. All references cited herein are incorporated by reference in their entirety.
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We Claim :
1. A method for removing a greenhouse gas from a gas stream emanating from a stationary source of greenhouse gas, comprising:
a) selecting a gas stream from a stationary source of production, said gas stream
comprising a mixture of greenhouse gas and non-greenhouse gas;
b) selecting a subsurface formation comprising a deep water-laden layer overlain by at least one overlying layer, said water-laden layer being capable of sequestering at least a portion of the greenhouse gas;
c) pressurizing said gas stream;
d) delivering said pressurized gas stream into an injection well having an inlet communicating with said gas stream and an outlet within said water-laden layer, thereby introducing said gas stream under pressure into said water-laden layer;
e) permitting at least a portion of said greenhouse gas to be sequestered within the water-laden layer and said non-greenhouse gas separated from said greenhouse gas to accumulate beneath said overlying layer; and
f) venting said non-greenhouse gas from said formation.

2. A method as defined in claim 1 wherein said greenhouse gas comprises CO2.
3. A method as defined in claim 1 wherein said gas stream comprises flue gas.
4. A method as defined in any one of claims 1-3 wherein said non-greenhouse gas is permitted to accumulate within said water laden layer at a location immediately beneath said overlying layer following separation from said gas stream within said formation, and said step of venting comprises accessing said accumulated non-greenhouse gas via a well to permit release of said non-greenhouse gas from said water-laden layer.
5. A method as defined in any of claims 1-4 wherein said non-greenhouse gas comprises nitrogen.
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6. A method for reducing the emission of greenhouse gases into the atmosphere above a ground surface, the method comprising:
a) selecting a gas stream from a source of production, the gas stream comprising one or more than one type of greenhouse gas and nitrogen;
b) selecting a subsurface injection formation below the ground surface for sequestering the one or more than one greenhouse gas in the gas stream from the source of production, the subsurface injection formation comprising a water-laden layer comprising formation water, said formation comprising a surface side (top) toward the ground surface and the subsurface injection formation is separated from the ground surface above the subsurface injection formation by one or more layers relatively impermeable to water;
c) selecting a surface site of injection of the gas stream above the subsurface injection formation for accessing the subsurface injection formation;
d) injecting the gas stream comprising the one or more than one greenhouse gas from the source of production from the surface site of injection into the formation water of the water-laden layer of the subsurface injection formation;
e) allowing the greenhouse gases in the gas stream to remain in the subsurface injection formation until at least some or all of the greenhouse gases either, i) dissolve into the formation water in the water-laden layer of the subsurface injection formation, ii) displace formation water in the water-laden layer of the subsurface injection formation, or both iii) dissolve into the formation water in the water-laden layer of the subsurface injection formation and displace formation water in the water-laden layer of the subsurface injection formation, thereby sequestering some or all of the greenhouse gases in the subsurface injection formation;
f) during or after sequestering the greenhouse gases in the water-laden layer, allowing said nitrogen to rise toward the surface side (top) of the subsurface injection formation or between the subsurface injection formation and the ground surface until some or all of the nitrogen reaches a layer that is relatively impermeable to water; and
g) venting the nitrogen into atmospheric gases above the ground surface.
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7. The method of claim 6, where the one or more than one type of greenhouse gas is
selected from the group consisting of carbon dioxide, hexafluoroethane, methane, nitrous
oxide, sulfur hexafluoride, tetrafluoromethane (carbon tetrafluoride), trifluoromethane,
1,1,1,2-tetrafluoroethane, and 1,1-difluoroethane.
8. The method of claim 6, where the water-laden layer of the subsurface injection formation has a salinity of at least 10,000 ppm (10 gm/liter).
9. The method of claim 6 where the method further comprises modifying one or more than one attribute of the gas stream prior to or during injection, where the one or more than one attribute is selected from the group consisting of pressure and temperature to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation.
10. The method of claim 6, where the water-laden layer of the subsurface injection formation comprises a pore pressure and further comprises a fracture pressure, and where the method comprises compressing the gas stream prior to injection into the subsurface injection formation to a pressure value greater than the pore pressure of the subsurface injection formation but less than the fracture pressure of the subsurface injection formation.
U. The method of claim 6, further comprising adding one or more than one chemical additive to the gas stream to promote dissolution of the one or more than one greenhouse gas present in the gas stream into the water-laden layer of the subsurface injection formation.
12. The method of claim 6, further comprising inducing hydraulic fractures into the subsurface injection formation before injecting the gas stream.
13. The method of claim 6, further comprising performing one or more than one of geological data analyses, geomechanical data analyses, and numerical simulation techniques to determine the optimum injection-disposal well pattern, well spacing, and well configuration to optimize the dissolution of the greenhouse gases in the water-laden layer.
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14. The method of claim 6 where injecting the gas stream comprises injecting the gas stream from the source of production continually as the gas stream is produced by the source of production.
15. The method of claim 6, where injecting the gas stream comprises injecting the gas stream from the source of production intermittently as the gas stream is produced by the source of production.

For BILAK, Roman; BRUNO, Michael S.;
ROTHENBURG, Leo; and DUSSEAULT, Maurice B.
By their Agent
(SAIMA SAGHIR ANSARI) KRISHNA & SAURASTRI ASSOCIATES
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Documents:

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Patent Number

269052

Indian Patent Application Number

1272/MUMNP/2009

PG Journal Number

40/2015

Publication Date

02-Oct-2015

Grant Date

29-Sep-2015

Date of Filing

06-Jul-2009

Name of Patentee

BRUNO MICHAEL S.

Applicant Address

1105, STARLIT LANE, MONROVIA, CALIFORNIA 91016,

Inventors:

#	Inventor's Name	Inventor's Address
1	BRUNO MICHAEL S.	1105, STARLIT LANE, MONROVIA, CALIFORNIA 91016,
2	BILAK ROMAN	49 MACEWAN PARK CLOSE, N.W. CALGARY, AL-BERTA T3K 3Z6,
3	ROTHENBURG LEO	188 MOHAWK AVENUE, WATERLOO, ONTARIO N2L 2T3,
4	DUSSEAULT MAURICE B.	7203-87 STREET, OSOYOOS, BRITISH COLUMBIA V0H 1V0,

PCT International Classification Number

C01B31/20

PCT International Application Number

PCT/US2007/086411

PCT International Filing date

2007-12-04

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	60/869,103	2006-12-07	U.S.A.