Indian Patents. 269943:"PROCESS FOR THE MANUFACTURE OF DICHLOROPROPANOL BY CHLORINATION OF GLYCEROL"

Title of Invention	"PROCESS FOR THE MANUFACTURE OF DICHLOROPROPANOL BY CHLORINATION OF GLYCEROL"
Abstract	Process for the manufacture of dischloropropanol in which glycerol is reacted with a chlorinating agent comprising hydrochloric acid in a liquid medium in equilibrium with a vapour phase and in which the condensation of a fraction exhibiting the composition of the vapour phase is prevented.

Full Text	Process for the manufacture of dichloropropanol by chlorination of glycerol The present patent application claims the benefit of provisional US patent application 60/734637 filed on 8 November 2005, the content of which is incorporated herein by reference. The present invention relates to a process for the manufacture of dichloropropanol in which glycerol and a chlorinating agent are reacted optionally in the presence of an organic acid, so as to obtain reaction products comprising dichloropropanol. The dichloropropanol can be separated from the other reaction products and can be subjected to a dehydrochlorination reaction, so as to manufacture epichlorohydrin. Such a process is disclosed in Application WO 2005/054167 of SOLVAY SA, the content of which is incorporated in the present application by reference. A preferred chlorinating agent is hydrogen chloride. In this process, the reaction between glycerol and the chlorinating agent is preferably carried out in a reactor and related ancilliary equipments made of or coated with materials resistant to chlorinating agents and in particular to hydrogen chloride under the reaction conditions. Enamelled (glass-lined) steel is a preferred vessel material. The applicant has found that such materials remain however unsatisfactory, i.e. they are corroded by liquid mixtures containing water, dichloropropanol and hydrogen chloride, resulting from the condensation of rich hydrogen chloride content vapours on the inner walls of the reactor and of related ancilliary equipments. This aim of this invention is to provide a process for manufacturing dichloropropanol which does not exhibit that problem. The invention therefore relates to a process for the manufacture of dichloropropanol in which glycerol is reacted with a chlorinating agent composing hydrogen chloride, wherein, in a vessel, a liquid medium is in equilibrium with a vapour phase and wherein at least one part of the inner wall of the vessel which is above the level of the liquid medium in the vessel is maintained at a temperature lower than 120 °C or at a temperature at least 1 °C higher than the dew temperature of the vapour phase and/or is trickled with a liquid. The part of the inner wall of the vessel which is above the level of the liquid medium in the vessel is maintained at the required temperature continuously or intermittently. The temperature of 120 °C is the temperature at which corrosion of enamelled steel at a rate of at least 0.01 mm/year is observed in the presence of hydrogen chloride/water liquid mixtures containing at least 4 % by weight of hydrogen chloride. The vessel can be any vessel of the process for manufacturing the dichloropropanol where the temperature of the liquid phase is higher than 120 °C, like for instance a reactor, a distillation column, a stripping column or a decantor. It has now been found that by working under such conditions of temperature and/or wetting conditions the corrosion of the inner vessel wall above the level of the liquid medium can be reduced. Without wishing to be bound by any theory, it is believed that when the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is lower than 120 °C, the corrosion rate is reduced even in contact with very corrosive condensed mixtures containing water, hydrogen chloride and dichloropropanol. It is also believed that when the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature at least 1 °C higher than the dew temperature of the vapour phase above the liquid medium, the corrosion rate is reduced due to a reduced condensation of vapours containing water, hydrogen chloride and dichloropropanol. Finally, it is also believed that when the inner wall of the vessel which is above the level of the liquid medium in the vessel is trickled with a liquid, the corrosiveness of condensed mixtures containing water, hydrogen chloride and dichloropropanol is reduced by dilution. The reduction of the corrosion of the constituent materials of the vessel makes it possible to further limit the costs associated with the replacement of the latter. In the liquid corrosive mixtures obtained by condensation of the vapours containing water, hydrogen chloride and dichloropropanol, the hydrogen chloride content is generally higher than or equal to 1 % by weight of the mixture, frequently higher than or equal to 3 % and often greater than or equal to 5 %. The hydrogen chloride content is generally lower than or equal to 80 % by weigh* of the mixture, frequently lower than or equal to 60 % and often lower than or equal to 50 %. In the liquid corrosive mixtures obtained by condensation of the vapours containing water, hydrogen chloride and dichloropropanol, the water content is generally higher than or equal to 4 % by weight of the mixture, frequently higher than or equal to 5 % and often greater than or equal to 10 %. The water content is generally lower than or equal to 80 % by weight of the mixture, frequently lower than or equal to 70 % and often lower than or equal to 60 %. In the liquid corrosive mixtures obtained by condensation of the vapours containing water, hydrogen chloride and dichloropropanol, the dichloropropanol content is generally higher than or equal to 4 % by weight of the mixture, frequently higher than or equal to 5 % and often greater than or equal to 10 %. The dichloropropanol content is generally lower than or equal to 80 % by weight of the mixture, frequently lower than or equal to 70 % and often lower than or equal to 60 %. Others compounds can also be present in the liquid corrosive mixtures containing water, hydrogen chloride and dichloropropanol, like for instance glycerol, monochloropropanediol, and esters thereof. The level of the liquid medium in the vessel is defined as the level of the liquid when the vessel is operating in stationary regime. The inner wall of the vessel which is above the level of the liquid medium in the vessel generally extends above the level of the liquid medium in the vessel to the top of the vessel. According to a first embodiment of the process of the invention, the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature lower than 120 °C, preferably lower than or equal to 110 °C, more preferably lower than or equal to 100 °C and most preferably lower than or equal to 90 °C. According to a first variant of the first embodiment, the internal wall of the vessel which is above the level of the liquid medium in the vessel is cooled down by means of an external cooling system. That system can be for instance a cooling fluid circulating between the inner and outer wall of the part of the vessel (double-walled conventional jacket) which is above the level of the liquid medium in the vessel or a cooling fluid circulating in a serpentine welded on the vessel wall or connected by a thermally conductive cement or located within the protective layer (for instance serpentine flooded in the protective layer or channel drilled in the bulk of the protective layer) or a semi-shell tube (half-pipe jacket) in contact with the outer wall of the vessel which is above the level of the liquid medium in the vessel or by flushing a cooling fluid on the outer wall of the vessel which is above the level of the liquid medium in the vessel. The cooling fluid can be a gas or a liquid. It is preferred to use a gaseous fluid when flushing the outer wall. The gas can be for example dry air or nitrogen. It is preferred to use a liquid fluid when circulating in double-walled envelope and serpentines. The liquid can be an organic liquid, an inorganic liquid or a mixture thereof. It is preferred to use an inorganic liquid, more preferably water. According to a second variant of the first embodiment, the inner wall of the vessel which is above the level of the liquid medium in the vessel is cooled down by flushing a cooling fluid on the inner wall. The fluid can be a gas or a liquid. The gas can for instance be hydrogen chloride or steam. The temperature of the gas is lower than the temperature of the liquid medium. The fluid is preferably a liquid. The liquid can be selected from a cold condensate arising from the treatment of the vapour phase in equilibrium with the liquid medium in a distillation, evaporation or stripping column, or selected from glycerol, water, an aqueous solution of hydrogen chloride, dichloropropanol, monochloropropanediol and mixtures thereof. By cold condensate, one intends to denote a condensate which temperature is lower than the temperature of the vapour phase in equilibrium with the liquid medium. The temperature of the cooling fluid is adjusted to obtain the inner wall temperature mentioned above. According to a second embodiment of the process of the invention, the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature at least 1 °C higher than the dew temperature of the vapour above the liquid medium, preferably at least 3 °C higher, more preferably at least 5 °C higher and most preferably at least 10 °C higher. According to a first variant of that second embodiment, the inner wall of the vessel which is above the level of the liquid medium in the vessel is heated up by means of an external heating system. That system can be for instance a heating fluid circulating between the inner and outer wall (double-walled conventional jacket) of the part of the vessel which is above the level of the liquid medium in the vessel or a heating fluid circulating in a serpentine welded to the vessel wall or connected by a thermally conductive cement or in a semi-shell tube (half-pipe jacket) in contact with the outer wall of the vessel which is above the level of the liquid medium in the vessel or by flushing a heating fluid on the outer wall of the vessel which is above the level of the liquid medium in the vessel. The heating of the part of the vessel which is above the level of the liquid medium in the vessel can also be carried out by using electric tracing or by radiation, such as electro-magnetic radiations like for instance Infra Red radiations. When a heating fluid is used, it can be a gas or a liquid. When a double-walled envelope or a serpentine or a semi-shell system is used for the external heating, it is preferred to use a liquid. The liquid can be an organic, an inorganic liquid or a mixture thereof. An inorganic liquid is preferred, pressurized water being most preferred. When the heating is carried out by flushing a heating fluid, the fluid is preferably a hot gas. By hot gas, one intends to denote a gas with a temperature is higher than the temperature of the liquid medium. The gas can be nitrogen, air or steam. Steam is more preferred. Steam with a pressure lower than 10 absolute bar is the most preferred. According to a second variant of that second embodiment, the internal wall of the vessel which is above the level of the liquid medium in the vessel is heated up by means of an internal heating system and a thermally insulating device can optionally be placed on the external wall of the vessel which is above the level of the liquid medium. The internal heating is carried out by flushing a heating fluid on the-inner wall. By heating fluid, one intends to denote a fluid with a temperature higher than the temperature of the liquid medium. The fluid can for instance be nitrogen, steam, hydrogen chloride or low boiling compounds produced by the reaction between glycerol and hydrogen chloride like for instance dichloropropanol, or mixture thereof. The gas can be introduced in the vessel by any suitable way, like for instance above the level of the liquid medium in the vessel in such a way that a helicoidal stream of gas is produced above that level. The temperature of the heating fluid is adjusted to obtain the inner wall temperature mentioned above. Any kind of thermally insulating device can be used. Insulating material can be made of inorganic material like perlite, of organic material or mixture thereof. According to a third embodiment of the process of the invention, the inner wall of the vessel which is above the level of the liquid medium in the vessel is trickled with a liquid. The liquid can be selected from a cold condensate arising from the treatment of the vapour phase in equilibrium with the liquid medium in a distillation, evaporation or stripping column, or selected from glycerol, water, an aqueous solution of hydrogen chloride, dichloropropanol and monochloropropanediol, and mixtures thereof. By cold condensate, one intends to denote a condensate which temperature is lower than the temperature of the vapour phase in equilibrium with the liquid medium. The liquid can be selected from another part of the process with a low concentration of hydrogen chloride. The various embodiments which have been described above can be combined. According to a fourth embodiment of the process of the invention, the inner wall of the vessel which is above the level of the liquid medium in the vessel* can be heated and trickled with a liquid. In that embodiment, it is preferred to heat the upper part of the inner wall and to trickle the lower of the inner wall which is above the level of the liquid medium in the vessel. The lower part generally extends from the level of the liquid medium in the vessel to 0.1 m above that level. The upper part generally extends from 0.5 m above the level of the liquid medium to the top of the vessel. According to a fifth embodiment of the process of the invention, the inner wall of the vessel which is above the level of the liquid medium in the vessel, can be cooled and trickled with a liquid. The examples below are intended to illustrate the invention without, however, imposing any limitation thereon. Example 1 (not according to the invention) When contacted with a water-hydrogen chloride liquid mixture containing 20 % by weight of hydrogen chloride at 120°C, an enamelled-lined steel sample exhibits a corrosion rate of 0.035 mm/year. Example 2 (according to the invention) When contacted with a water-hydrogen chloride liquid mixture containing 20 % by weight of hydrogen chloride at 50°C, an enamelled-lined steel sample exhibits a corrosion rate of less than 0.010 mm/year. CLAIMS 1. Device (2) for preparing an infused beverage, including: a) an infusion container (6) for containing a liquid (4) and comprising an opening (8) to allow the liquid (4) to flow out of the container (6); b) a receptacle (10) defining a cavity (16) for receiving a cartridge (12) containing infusible matter (14); wherein the infusion container (6) and the receptacle (10) are operable in relation to each other to be arranged in a position wherein the infusion container (6) and the cavity (16) communicate through the opening (8); c) an openable and closable passage (18) communicating with the cavity (16) to allow liquid (4) to flow from the infusion container (6) in the passage (18) through the cavity (16); characterized in that it further includes d) cleaning means for introducing a liquid and/or vapour within the infusion container (6); e) removing means for removing the cartridge (12) from the cavity (16); and f) operating means for operating the cleaning means and the removing means successively. 2. Device (2) according to claim 1, wherein the operating means is adapted for operating the cleaning means, the withdrawing means and the cleaning means anew. 3. Device (2) according to claim 1 or 2, further including introducing means for introducing gas in the infusion container (6) through the cavity (16). 4. Device (2) according to claim 3, wherein the introducing means comprises a protruding nozzle (112) arranged in the cavity (18) and provided with at least one injection opening (113) for introducing the gas. 5. Device (2) according to claim 4, wherein the device comprises automatic reading means (34) for reading preparation parameters from the cartridge (12), the preparation parameters being selected from the group consisting of the infusion temperature, the infusion duration, when the introduction of gas takes place, how long it lasts and a combination of these parameters. 6. Device (2) according to any one of the preceding claims, wherein the passage (18) comprises a spout (19) to allow infused liquid (4) to flow within a cup from the passage (18) directly. 7. Device (2) according to any one of the preceding claims, wherein the device further comprises a first waste container (76) for collecting waste cleaning liquid and/or vapour (22) and a second waste container (78) for receiving the used cartridge (12) removed from the cavity (16). 8. Process for preparing an infused beverage in a device including an infusion container (6) for containing liquid (4) and a receptacle (10) comprising a cavity (16), the infusion container (6) comprising an opening (8) for liquid (4) to flow out, the process including the steps of: a) inserting a cartridge (12) containing infusible matter (14) in the cavity (16), the cartridge (12) comprising a filter (44) to let liquid pass through; b) arranging the container (6) and the receptacle (10) in relation to each other in a position so that the infusion container (6) and the cavity (16) communicate with each other through the opening (8); c) introducing liquid (4) for infusion in the infusion container (6) so that the liquid flows to the cavity (16) immersing infusible matter (14) contained in the cartridge (12); d) opening a passage (18) of the device (2), the passage (18) communicating with the cavity (16), to let the infused liquid (4) flow from the infusion container (6) through the cavity (16) and the filter (44) of the cartridge (12) into the passage (18); characterized in that it further includes the successive steps of e) introducing a liquid and/or vapour in the container (8) for cleaning the container (6); and f) removing the cartridge (12) from the cavity (16). 9. Process according to claim 9, including a further step of introducing a liquid and/or vapour in the container (8). 10. Process according to claims 8 or 9, including, between the step of introducing the liquid (4) for infusion and the step of opening the passage (18), a step of introducing gas through the cavity (16) in the infusion container. 11. Process according to claim 10, wherein the step of introducing gas takes place at 50 to 80 percent, or more particularly at 60 to 70 percent, of the time between the end of the step of introducing the liquid (4) for infusion and the beginning of the step of opening the passage (18) and/or substantially immediately after the step of introducing the liquid (4) for infusion. 12. Cartridge (12) containing dry infusible matter (14) for use in a device (2) for preparing an infused beverage, and comprising: a) a bottom part (42); b) a top part (38) provided with at least one opening (35); and c) at least one side wall (45) joining the bottom part (42) and the top part (38); said cartridge being characterized in that said bottom part (42), top part (38) and at least one side wall (45) enclose a volume between two and five times, preferably around four times, the volume of the dry infusible matter (14).

Full Text

Process for the manufacture of dichloropropanol by chlorination of
glycerol
The present patent application claims the benefit of provisional US patent application 60/734637 filed on 8 November 2005, the content of which is incorporated herein by reference.
The present invention relates to a process for the manufacture of dichloropropanol in which glycerol and a chlorinating agent are reacted optionally in the presence of an organic acid, so as to obtain reaction products comprising dichloropropanol. The dichloropropanol can be separated from the other reaction products and can be subjected to a dehydrochlorination reaction, so as to manufacture epichlorohydrin. Such a process is disclosed in Application WO 2005/054167 of SOLVAY SA, the content of which is incorporated in the present application by reference. A preferred chlorinating agent is hydrogen chloride.
In this process, the reaction between glycerol and the chlorinating agent is preferably carried out in a reactor and related ancilliary equipments made of or coated with materials resistant to chlorinating agents and in particular to hydrogen chloride under the reaction conditions. Enamelled (glass-lined) steel is a preferred vessel material. The applicant has found that such materials remain however unsatisfactory, i.e. they are corroded by liquid mixtures containing water, dichloropropanol and hydrogen chloride, resulting from the condensation of rich hydrogen chloride content vapours on the inner walls of the reactor and of related ancilliary equipments.
This aim of this invention is to provide a process for manufacturing dichloropropanol which does not exhibit that problem.
The invention therefore relates to a process for the manufacture of dichloropropanol in which glycerol is reacted with a chlorinating agent composing hydrogen chloride, wherein, in a vessel, a liquid medium is in equilibrium with a vapour phase and wherein at least one part of the inner wall of the vessel which is above the level of the liquid medium in the vessel is maintained at a temperature lower than 120 °C or at a temperature at least 1 °C higher than the dew temperature of the vapour phase and/or is trickled with a liquid.

The part of the inner wall of the vessel which is above the level of the liquid medium in the vessel is maintained at the required temperature continuously or intermittently.
The temperature of 120 °C is the temperature at which corrosion of enamelled steel at a rate of at least 0.01 mm/year is observed in the presence of hydrogen chloride/water liquid mixtures containing at least 4 % by weight of hydrogen chloride.
The vessel can be any vessel of the process for manufacturing the dichloropropanol where the temperature of the liquid phase is higher than 120 °C, like for instance a reactor, a distillation column, a stripping column or a decantor.
It has now been found that by working under such conditions of temperature and/or wetting conditions the corrosion of the inner vessel wall above the level of the liquid medium can be reduced. Without wishing to be bound by any theory, it is believed that when the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is lower than 120 °C, the corrosion rate is reduced even in contact with very corrosive condensed mixtures containing water, hydrogen chloride and dichloropropanol. It is also believed that when the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature at least 1 °C higher than the dew temperature of the vapour phase above the liquid medium, the corrosion rate is reduced due to a reduced condensation of vapours containing water, hydrogen chloride and dichloropropanol. Finally, it is also believed that when the inner wall of the vessel which is above the level of the liquid medium in the vessel is trickled with a liquid, the corrosiveness of condensed mixtures containing water, hydrogen chloride and dichloropropanol is reduced by dilution. The reduction of the corrosion of the constituent materials of the vessel makes it possible to further limit the costs associated with the replacement of the latter.
In the liquid corrosive mixtures obtained by condensation of the vapours containing water, hydrogen chloride and dichloropropanol, the hydrogen chloride content is generally higher than or equal to 1 % by weight of the mixture, frequently higher than or equal to 3 % and often greater than or equal to 5 %. The hydrogen chloride content is generally lower than or equal to 80 % by weigh* of the mixture, frequently lower than or equal to 60 % and often lower than or equal to 50 %.

In the liquid corrosive mixtures obtained by condensation of the vapours containing water, hydrogen chloride and dichloropropanol, the water content is generally higher than or equal to 4 % by weight of the mixture, frequently higher than or equal to 5 % and often greater than or equal to 10 %. The water content is generally lower than or equal to 80 % by weight of the mixture, frequently lower than or equal to 70 % and often lower than or equal to 60 %.
In the liquid corrosive mixtures obtained by condensation of the vapours containing water, hydrogen chloride and dichloropropanol, the dichloropropanol content is generally higher than or equal to 4 % by weight of the mixture, frequently higher than or equal to 5 % and often greater than or equal to 10 %. The dichloropropanol content is generally lower than or equal to 80 % by weight of the mixture, frequently lower than or equal to 70 % and often lower than or equal to 60 %.
Others compounds can also be present in the liquid corrosive mixtures containing water, hydrogen chloride and dichloropropanol, like for instance glycerol, monochloropropanediol, and esters thereof.
The level of the liquid medium in the vessel is defined as the level of the liquid when the vessel is operating in stationary regime.
The inner wall of the vessel which is above the level of the liquid medium in the vessel generally extends above the level of the liquid medium in the vessel to the top of the vessel.
According to a first embodiment of the process of the invention, the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature lower than 120 °C, preferably lower than or equal to 110 °C, more preferably lower than or equal to 100 °C and most preferably lower than or equal to 90 °C.
According to a first variant of the first embodiment, the internal wall of the vessel which is above the level of the liquid medium in the vessel is cooled down by means of an external cooling system. That system can be for instance a cooling fluid circulating between the inner and outer wall of the part of the vessel (double-walled conventional jacket) which is above the level of the liquid medium in the vessel or a cooling fluid circulating in a serpentine welded on the vessel wall or connected by a thermally conductive cement or located within the protective layer (for instance serpentine flooded in the protective layer or channel drilled in the bulk of the protective layer) or a semi-shell tube (half-pipe jacket) in contact with the outer wall of the vessel which is above the level of the

liquid medium in the vessel or by flushing a cooling fluid on the outer wall of the vessel which is above the level of the liquid medium in the vessel. The cooling fluid can be a gas or a liquid. It is preferred to use a gaseous fluid when flushing the outer wall. The gas can be for example dry air or nitrogen. It is preferred to use a liquid fluid when circulating in double-walled envelope and serpentines. The liquid can be an organic liquid, an inorganic liquid or a mixture thereof. It is preferred to use an inorganic liquid, more preferably water.
According to a second variant of the first embodiment, the inner wall of the vessel which is above the level of the liquid medium in the vessel is cooled down by flushing a cooling fluid on the inner wall. The fluid can be a gas or a liquid. The gas can for instance be hydrogen chloride or steam. The temperature of the gas is lower than the temperature of the liquid medium. The fluid is preferably a liquid. The liquid can be selected from a cold condensate arising from the treatment of the vapour phase in equilibrium with the liquid medium in a distillation, evaporation or stripping column, or selected from glycerol, water, an aqueous solution of hydrogen chloride, dichloropropanol, monochloropropanediol and mixtures thereof. By cold condensate, one intends to denote a condensate which temperature is lower than the temperature of the vapour phase in equilibrium with the liquid medium.
The temperature of the cooling fluid is adjusted to obtain the inner wall temperature mentioned above.
According to a second embodiment of the process of the invention, the temperature of the inner wall of the vessel which is above the level of the liquid medium in the vessel is at a temperature at least 1 °C higher than the dew temperature of the vapour above the liquid medium, preferably at least 3 °C higher, more preferably at least 5 °C higher and most preferably at least 10 °C higher.
According to a first variant of that second embodiment, the inner wall of the vessel which is above the level of the liquid medium in the vessel is heated up by means of an external heating system. That system can be for instance a heating fluid circulating between the inner and outer wall (double-walled conventional jacket) of the part of the vessel which is above the level of the liquid medium in the vessel or a heating fluid circulating in a serpentine welded to the vessel wall or connected by a thermally conductive cement or in a semi-shell tube (half-pipe jacket) in contact with the outer wall of the vessel which is above the level of the liquid medium in the vessel or by flushing a heating fluid

on the outer wall of the vessel which is above the level of the liquid medium in the vessel. The heating of the part of the vessel which is above the level of the liquid medium in the vessel can also be carried out by using electric tracing or by radiation, such as electro-magnetic radiations like for instance Infra Red radiations. When a heating fluid is used, it can be a gas or a liquid. When a double-walled envelope or a serpentine or a semi-shell system is used for the external heating, it is preferred to use a liquid. The liquid can be an organic, an inorganic liquid or a mixture thereof. An inorganic liquid is preferred, pressurized water being most preferred. When the heating is carried out by flushing a heating fluid, the fluid is preferably a hot gas. By hot gas, one intends to denote a gas with a temperature is higher than the temperature of the liquid medium. The gas can be nitrogen, air or steam. Steam is more preferred. Steam with a pressure lower than 10 absolute bar is the most preferred.
According to a second variant of that second embodiment, the internal wall of the vessel which is above the level of the liquid medium in the vessel is heated up by means of an internal heating system and a thermally insulating device can optionally be placed on the external wall of the vessel which is above the level of the liquid medium. The internal heating is carried out by flushing a heating fluid on the-inner wall. By heating fluid, one intends to denote a fluid with a temperature higher than the temperature of the liquid medium. The fluid can for instance be nitrogen, steam, hydrogen chloride or low boiling compounds produced by the reaction between glycerol and hydrogen chloride like for instance dichloropropanol, or mixture thereof. The gas can be introduced in the vessel by any suitable way, like for instance above the level of the liquid medium in the vessel in such a way that a helicoidal stream of gas is produced above that level.
The temperature of the heating fluid is adjusted to obtain the inner wall temperature mentioned above.
Any kind of thermally insulating device can be used. Insulating material can be made of inorganic material like perlite, of organic material or mixture thereof.
According to a third embodiment of the process of the invention, the inner wall of the vessel which is above the level of the liquid medium in the vessel is trickled with a liquid. The liquid can be selected from a cold condensate arising from the treatment of the vapour phase in equilibrium with the liquid medium in a distillation, evaporation or stripping column, or selected from glycerol, water,

an aqueous solution of hydrogen chloride, dichloropropanol and monochloropropanediol, and mixtures thereof. By cold condensate, one intends to denote a condensate which temperature is lower than the temperature of the vapour phase in equilibrium with the liquid medium. The liquid can be selected from another part of the process with a low concentration of hydrogen chloride.
The various embodiments which have been described above can be combined.
According to a fourth embodiment of the process of the invention, the inner wall of the vessel which is above the level of the liquid medium in the vessel* can be heated and trickled with a liquid. In that embodiment, it is preferred to heat the upper part of the inner wall and to trickle the lower of the inner wall which is above the level of the liquid medium in the vessel. The lower part generally extends from the level of the liquid medium in the vessel to 0.1 m above that level. The upper part generally extends from 0.5 m above the level of the liquid medium to the top of the vessel.
According to a fifth embodiment of the process of the invention, the inner wall of the vessel which is above the level of the liquid medium in the vessel, can be cooled and trickled with a liquid.
The examples below are intended to illustrate the invention without, however, imposing any limitation thereon. Example 1 (not according to the invention)
When contacted with a water-hydrogen chloride liquid mixture containing 20 % by weight of hydrogen chloride at 120°C, an enamelled-lined steel sample exhibits a corrosion rate of 0.035 mm/year. Example 2 (according to the invention)
When contacted with a water-hydrogen chloride liquid mixture containing 20 % by weight of hydrogen chloride at 50°C, an enamelled-lined steel sample exhibits a corrosion rate of less than 0.010 mm/year.

CLAIMS
1. Device (2) for preparing an infused beverage, including:
a) an infusion container (6) for containing a liquid (4) and comprising an opening (8) to allow the liquid (4) to flow out of the container (6);
b) a receptacle (10) defining a cavity (16) for receiving a cartridge (12) containing infusible matter (14); wherein the infusion container (6) and the receptacle (10) are operable in relation to each other to be arranged in a position wherein the infusion container (6) and the cavity (16) communicate through the opening (8);
c) an openable and closable passage (18) communicating with the cavity (16) to allow liquid (4) to flow from the infusion container (6) in the passage (18) through the cavity (16);
characterized in that it further includes
d) cleaning means for introducing a liquid and/or vapour within the infusion container (6);
e) removing means for removing the cartridge (12) from the cavity (16); and
f) operating means for operating the cleaning means and the removing means successively.

2. Device (2) according to claim 1, wherein the operating means is adapted for operating the cleaning means, the withdrawing means and the cleaning means anew.
3. Device (2) according to claim 1 or 2, further including introducing means for introducing gas in the infusion container (6) through the cavity (16).
4. Device (2) according to claim 3, wherein the introducing means comprises a protruding nozzle (112) arranged in the cavity (18) and provided with at least one injection opening (113) for introducing the gas.
5. Device (2) according to claim 4, wherein the device comprises automatic reading means (34) for reading preparation

parameters from the cartridge (12), the preparation parameters being selected from the group consisting of the infusion temperature, the infusion duration, when the introduction of gas takes place, how long it lasts and a combination of these parameters.
6. Device (2) according to any one of the preceding claims, wherein the passage (18) comprises a spout (19) to allow infused liquid (4) to flow within a cup from the passage (18) directly.
7. Device (2) according to any one of the preceding claims, wherein the device further comprises a first waste container (76) for collecting waste cleaning liquid and/or vapour (22) and a second waste container (78) for receiving the used cartridge (12) removed from the cavity (16).
8. Process for preparing an infused beverage in a device including an infusion container (6) for containing liquid (4) and a receptacle (10) comprising a cavity (16), the infusion container (6) comprising an opening (8) for liquid (4) to flow out, the process including the steps of:

a) inserting a cartridge (12) containing infusible matter (14) in the cavity (16), the cartridge (12) comprising a filter (44) to let liquid pass through;
b) arranging the container (6) and the receptacle (10) in relation to each other in a position so that the infusion container (6) and the cavity (16) communicate with each other through the opening (8);
c) introducing liquid (4) for infusion in the infusion container (6) so that the liquid flows to the cavity (16) immersing infusible matter (14) contained in the cartridge (12);
d) opening a passage (18) of the device (2), the passage (18) communicating with the cavity (16), to let the infused liquid (4) flow from the infusion container (6) through the cavity (16) and the filter (44) of the cartridge (12) into the passage (18);
characterized in that it further includes the successive steps of

e) introducing a liquid and/or vapour in the container (8) for cleaning
the container (6); and
f) removing the cartridge (12) from the cavity (16).
9. Process according to claim 9, including a further step of
introducing a liquid and/or vapour in the container (8).
10. Process according to claims 8 or 9, including, between
the step of introducing the liquid (4) for infusion and the step of opening
the passage (18), a step of introducing gas through the cavity (16) in the
infusion container.
11. Process according to claim 10, wherein the step of
introducing gas takes place at 50 to 80 percent, or more particularly at 60
to 70 percent, of the time between the end of the step of introducing the
liquid (4) for infusion and the beginning of the step of opening the
passage (18) and/or substantially immediately after the step of
introducing the liquid (4) for infusion.
12. Cartridge (12) containing dry infusible matter (14) for
use in a device (2) for preparing an infused beverage, and comprising:
a) a bottom part (42);
b) a top part (38) provided with at least one opening (35); and
c) at least one side wall (45) joining the bottom part (42) and the top part (38);
said cartridge being characterized in that said bottom part (42), top part (38) and at least one side wall (45) enclose a volume between two and five times, preferably around four times, the volume of the dry infusible matter (14).

Documents:

http://ipindiaonline.gov.in/patentsearch/GrantedSearch/viewdoc.aspx?id=QNN6iZPsaUgFxHDxTwq82Q==&loc=egcICQiyoj82NGgGrC5ChA==

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Patent Number

269943

Indian Patent Application Number

2263/CHENP/2008

PG Journal Number

47/2015

Publication Date

20-Nov-2015

Grant Date

19-Nov-2015

Date of Filing

06-May-2008

Name of Patentee

SOLVAY (SOCIETE ANONYME)

Applicant Address

RUE DU PRINCE ALBERT, 33, B-1050 BRUSSELS

Inventors:

#	Inventor's Name	Inventor's Address
1	KRAFFT, PHILIPPE	AVENUE SIMONNE, 21A, B-1640 RHODE SAINT GENESE
2	FRANCK, CHRISTIAN	PATERS ABELOOSLAAN, 14, B-1933 STERREBEEK
3	DE ANDOLENKO, IVAN	4 RUE AMPERE, F-39500 TAVAUX
4	VEYRAC, ROGER	3, RUE DES VIGNES, F-39350 LOUVATANGE

PCT International Classification Number

C07C29/62

PCT International Application Number

PCT/EP06/68208

PCT International Filing date

2006-11-08

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	60/734, 637	2005-11-08	U.S.A.