Title of Invention

MUSIC STRING AND INSTRUMENT COMPRISING SAID STRING

Abstract The present disclosure relates to a music string comprising precipitation hardening stainless steel. The string has a superior resistance to relaxation and is corrosion resistant, thus improving its tuning stability and maintaining its tone quality, thus prolonging its service life.
Full Text The present invention relates to a music string according to the preamble of claim
1,
Such a string is known from inter alia US 4,333,379 comprising a steel core of
bronzed gray cast iron.
A music string must possess many different properties. The most important is a
high mechanical strength which allows the siting to be loaded to its tuning
frequency, and to resist the variations in tension in the string when played on.
The level of mechanical strength required depends on the diameter of the string.
Finer strings are used for the higher tones and generally, the finer the string the
higher the mechanical strength required. For example, a 0,254 mm (0,010")
guitar string to be used for the tone E must have a tensile strength of at least
1500 Mpa to be tuned. Furthermore, in order to safely withstand the tensions
created when played on by a plectrum, the 0,254 mm string should preferably
have a tensile strength of approximately 2500 MPa.
Another important property is the resistance to relaxation of the string material,
This property basically tells how well the guitar string will maintain its tune. For
example, a toss of force in the magnitude of 1 N in a string of diameter 0,33 mm,
loaded to the tone 8 on a guitar (i.e. 247 Hz), corresponds to a drop of
approximately 2 Hz in frequency. Since the human ear can detect the difference
between, e.g., 440 Hz and 441 Hz, a force loss of 1 N will be well audible for the
human ear, if a drop like this occurs, the string needs to be retuned. Frequent
retuning is disturbing for the musician, and will over time deteriorate the
properties of the string. Hence, eventually the tone quality of the string will be
affected and thereby also the life time of the string.. Consequently, for Improved
tuning stability, tone quality and string life, it is desirable that the string material
has a high resistance to relaxation.

Another essential property of the string material is its ability to be cold drawn to
the required wire dimensions, without becoming too brittle. Furthermore, the
string may constitute a single wire, one or more twisted wires or a wrapped wire.
This in turn requires that the material be sufficiently ductile to allow the string wire
to be twisted.
in case of a string for electrical instruments, such as an electrical guitar, the
sound generated by the string is a result of the electromagnetic properties of the
string. Most electric guitars apply electromagnetic pickups which consist of a coil
with a permanent magnet. The string vibrations cause changes in the magnetic
flux through the coll, thus inducing electrical signals, which are transferred to an
amplifier where the signal is further processed and amplified. The more magnetic
the string, the higher voltage the produced in the coll and the louder the sound
created.
Moreover, a string of a musical instrument is exposed to different types of
corrosion. The corrosion will stain the string, thereby affecting both the
mechanical properties and the tuning properties over time. One type of corrosion
to which a string is subjected is atmospheric corrosion, which can be substantial
on carbon steel in humid and warm conditions or, when the instrument is played
on outdoors. Furthermore, substances such as sweat or grease may be
transferred from the musician to the string, which may constitute a risk of
corrosion of the string. Human sweat contains sodium chloride which is highly
corrosive. Grease on the other hand may collect other substances that corrode
the string lightly and discolor the surface of it permanently.
Ordinary strings are commonly made of high carbon steel drawn to different wire
diameters. Carbon steel has many good qualities, such that it is easy to draw
wire to high strength levels without encountering brittleness. However, a major
drawback of carbon steel when used in strings is that it rusts easily, thus staining

the surface which will affect the tone quality and playing characteristics of the
string. Staining is a common reason for restringing an instrument.
Many attempts to arrest corrosion on carbon steel strings have been done
without success, e.g., coating strings with different materials such as natural and
synthetic polymers. However, coating generally decreases the string vibrations,
thus leading to reduced brightness and an inferior sound quality.
Yet another drawback of carbon steel when used in strings is its tendency to be
stretched when loaded. This effect caused by relaxation of the material is
particularly noticeable the first period after stringing a new instrument or after
restringing an old instrument, both on large, static instruments such as pianos,
and on small, mobile instruments such as guitars and violins. A new string
requires a "setting time" until is reaches a stable tone. Obviously, the instrument
itself accounts for a large portion of the "detuning" as a result of variations in
humidity and temperature, but much of the effect is attributed to the strings. For a
piano producer, for instance, this means a long and costly period of tuning and
retuning before delivery of a new instrument, and for an instrument player it
means frequent retuning until an acceptable stability of tone has been reached.
Therefore, there is a need for a string which will overcome the problems given
above.
Consequently, the object of the invention is to provide a music string with
extended service life.
Summary
The stated object is achieved by a string as initially defined and having the
features of the characterizing portion of claim 1.

By utilizing a precipitation hardening stainless steel In music strings both the
corrosion resistance and the resistance to relaxation are much improved
compared to commonly used carbon steel strings and thereby the life time of the
string is prolonged.
The string is intended for use in acoustic and semi-acoustic instruments as well
as in instruments where the tone is generated by the string vibrating in a
magnetic field such as electric guitars. The string according to the present
disclosure may be used in all kinds of stringed musical instruments, such as
guitars, violins, pianos, harps etc..
Brief description of the drawings
Figure 1 [Illustrates the result of tensile test of strings according to the
invention and strings of comparative examples,
Figure 2 illustrates the result of a relaxation test of wires with a diameter of
0,254 mm.
Figure 3 illustrates the result of a relaxation test of wires with a diameter of
0,33 mm.
Figure 4 illustrates the result of a relaxation test of wires with a diameter of
0,43 mm.
Figure 5 illustrates the result of a magnetic resonance test of a string
according to the present invention.

Figure 6 Illustrates the result of a magnetic resonance lest of a string of a
comparative example.
Detailed description
The different material properties of importance for the performance of a music
string are the yield and tensile strength, the resistance to relaxation, the corrosion
resistance, the shape, the surface finish, and, for electrical instruments, the
electromagnetic properties.
The string in accordance with the present invention has a prolonged service life
compared to commonly used strings. In this context, service life is considered to
be the time up to breakage of the string or the time to when the musician feels
the need to change the string due to deteriorated properties of the string, such as
a toss of tuning stability or tone quality.
Precipitation hardening stainless steels are corrosion resistant ferrous alloys that
have been strengthened by precipitation hardening, The precipitation hardening
produces a multiphase structure resulting in an increased resistance to
dislocation motion and hence greater strength or hardness. These types of steel
can generally be found in applications such as corrosion resistant structural
members.
Resulting from the materials selection, a string according to the present
disclosure has a high mechanical strength, such as a tensile strength of at least
1800 MPa when in a diameter of 0,33 mm and in cold drawn condition. Also, the
tensile strength is at least 2500 when in a diameter of 0,254 mm and in heat
treated condition, i.e. aged. Furthermore, it has a resistance to relaxation which
does not necessitate a retiring more frequently than once every 18 hours when
played on under normal conditions, More specifically, the precipitation hardening

stainless steel has a resistance to relaxation sufficient to necessitate retuning
less than once every 24 hours.
Moreover, the string according to the present disclosure is resistant to corrosion
caused by the environment or substances transferred to the string during its use.
As a consequence, the string does not need to be coated for improved protection
and maintains fts bright surface, and thus its acoustic characteristics over time.
The common methods used to assess the corrosion resistance of carbon steel
and stainless steel differ substantially, which makes a direct comparison difficult
based on lab tests. However, carbon steel rusts strongly in sweat water, and
even more so in chloride containing waters. Stainless steels on the other hand
resist pure water but may be subject to pitting corrosion in chloride containing
water. The corrosion process is accelerated if the chloride content and/or the
higher temperature are high. For its strength level, the precipitation hardening
stainless steel of the invention is quite resistant In aqueous solutions and
performs better than, e.g., stainless steel of type AIS1 304. This also means that It
outperforms carbon steel music strings in this respect.
A uniform shape and a smooth surface finish of the string are important for
achieving a harmonic sound and a good feeling of the string when played. The
acoustic properties of a string are difficult to quantify but are very important for
how the musician and the listener experience the sound of the string. The
perception of the acoustic sound of strings according to the present invention is
similar to that of commonly used carbon steel strings.
Suitable precipitation hardening stainless steels, to be used in music strings in
accordance with the present invention, generally contain 10-20 percent by weight
of Cr and 4-10 percent by weight of Nl.

A precipitation hardening stainless steel suitable for use as music string could, for
example, have the following composition in percent per weight:

Examples of such stainless steels are UNS S48910, UNS S17700, UNS S17400
and UNS S45500. According to a preferred embodiment, the precipitation
hardening stainless steel is UNS S46910.
The precipitation hardening stainless steel may comprise various additions for
accomplishing precipitations. According to an embodiment of the invention, the
precipitation hardening stainless steel comprises 0,5-1 % by weight of Ti such as
in the case of UNS S46910 and UNS $45500. According to another embodiment
of the invention, the stainless steel comprises 0,2-1,5 % by weight of Al such as
in the case of UNS S17700 and UNS S46910. According to yet another
embodiment, the steet comprises 0,1-0,6 % by weight of Ta + Mb as in the case
of UNS S45500 and UNS S17400,
An important criterion when selecting a suitable precipitation hardening stainless
steel for a music string is the ability to manufacture wires of the material in order
to produce the string. It is a prerequisite that the selected composition can be

cold drawn to very fine diameters such as 0,254 mm or 0,33 mm without
becoming brittle.
The string Is produced by means of conventional cold drawing processes for the
manufacturing of wire. The cold drawing process gives rise to formation of
deformation-induced martensite which leads to increased mechanical strength
and 3 more magnetic material, The amount of cold deformation is important for
achieving the desired strength and magnetic properties of the wire.
In order lo further improve the properties of the string, the precipitation hardening
stainless steel may be subjected to a heat treatment at 400-550 °C, normally for
up to 4 hours. This aging heat treatment produces a precipitation hardening of
the material which substantially increases its tensile strength.
The manufacturing processes for producing wire of precipitation hardening
stainless steel result in strings of good surface finish, i.e. strings with a uniform
and harmonious sound that are comfortable to play on.
According to an embodiment, the string comprises a core wrapped with metal
strands. In this embodiment, either the core or the wrapping consists of
precipitation hardening material in accordance with the invention. It is also
possible that both the core and the wrapping comprise precipitation hardening
stainless steel.
The string according to the present disclosure may be used in all kinds of
stringed musical instruments, such as guitars, violins, pianos, harps etc. The
string may be a single wire, but it may also be in the form of a wrapped or
wounded string. The string may also be twisted.

Example 1

This alloy is standardized under US-standard AISl UNS S46910.
Wires were cold drawn to diameters of 0,254 mm, 0,33 mm and 0,43 mm,
respectively. One wire of each diameter was heat treated at a temperature of 475
°C for 10 minutes, resulting in an increased strength and a further improved
resistance to relaxation of the material.
The yield and tensile strengths were measured by a tensile test in accordance
with SS-EN10002-1 and compared to 8 different comparative examples of carbon
steel strings. The approximate compositions and string diameters of the
comparative examples are shown in Table 1, The yield (Rp0.2) and tensile (Rm)
strength values are listed in Table 2 and are illustrated in Figure 1. It appears that
the mechanical properties of the precipitation hardening stainless steel, both in
the as-drawn and the as-aged condition, match well the characteristics of the
conventional strings. The positive effect of aging is clearly shown in Table 2.



Example 2
The relaxation resistance was tested by plucking 0,254, 0,33 mm diameter and
0,43 mm diameter strings approximately 200 times per minute with a pick. The
compositions are those of example 1. The test was performed over a 24 hour
period. The plucking point of the pick was set at 18 cm from a force sensor
connected to a computer. The total length of each string was 65 cm and the
strings rested on two plastic pieces at each end point. The distance between
each end point and its corresponding force sensors was 5 cm. The diameter and
its corresponding tone frequency are given in Table 3 along with the original
tension and the engineering stress of the strings,

The results of the relaxation tests of strings with diameters 0,254 mm, 0,33 mm
and 0,43 mm are shown in Figure 2, Figure 3 and Figure 4 respectively. In Table
4, the same results are listed in the form of the linear Equation 1, wherein y is the
load applied, k is a constant, x is the time and y0 the initial load. The frequency
loss is calculated based on a density of 7700 kg/m3,




The lower the k-value, i.e., the slope of the linear equation for a given string, the
better is its relaxation resistance. The results furthermore show that the
precipitation hardening stainless steel in heat treated condition, i.e, aged, has
better relaxation resistance compared to traditional carbon steel used in music
strings. The strong positive effect of aging on the relaxation resistance is clearly
demonstrated.
The human ear can detect a change in tune frequency of 1 Hz, The string of
Comparetive Example 7 had lost 1,5 N (corresponding to a frequency lost of
approximately 2 Hz) after 24 hours which means that such a string must be
retuned once every 12 hours. On the other hand, a string according to the
Invention having with a corresponding diameter and heat treated condition had
tost 0,6 N corresponding to a frequency lost of approximately 0,8 Hz, which in
turn results in a need for retuning once every 30 hours.
For comparison, a string according to the invention having a diameter of 0,254
mm and being in heal treated condition had lost 0,3 N which corresponds to a
frequency lost of approximately 0,68 Hz. This results in a need for retuning once
every 35 hours,
Example 3
The magnetic resonance of the alloy of Example 1 was tested on a guitar and
compared to that of Comparative Example 7. The strings were plucked ai a
distance of 10 cm from the bridge and subjected to a force corresponding to the
shear-breaking point of a 0,10 mm copper wire. The copper wire was looped
perpendicularly around the plucked string and then pulled until reaching the
breaking point. In this way the same force was applied for every test run. The
breaking point of the copper wire must also be at the point of contact with the

plucked string, if the copper wire broke at any other point the procedure was
repeated. A series of five approved tests were done on each string, and the
results are represented in graphs as per Figures 5 and 6, The result shows that
the ageing process does not affect the magnetic properties of the material.
Example 4
Furthermore the magnetic weight of the material was tested and compared to
Comparative example 4. To measure the amount of magnetic phase, a magnetic
balance was used. The magnetic balance contains two major components, an
electromagnet and a strain gauge. The electromagnet generates a strong
inhomogenic magnetic field between two wedge-shaped poles where the test
sample is placed. A magnetic string will be pulled down by the magnetic force.
The force, which is proportional to the amount of magnetic phase, is then
measured by the strain gauge. This measurement yields the saturation
magnetization of the sample and by calculating the theoretical saturation
magnetization for this steel it is possible to determine the amount of magnetic
phase present in the sample, I.e., the magnetic weight. The values from the
magnetic weight tests are illustrated in Table 5.

It appears that the alloy according to the present Invention has a magnetism that
is comparable to that of commonly used carbon steei wires, thus making the alloy
particularly suitable for applications requiring a magnetic material, i.e., strings for
electromagnetic pick-up instruments such as electric guitars.

WE CLAIM :
1. Music string characterized in that it comprises precipitation hardening
stainless steel.
2. Music string according to claim 1 characterized in that the
precipitation hardening stainless steel comprises 10-20 percent by weight
of Cr and 4-10 percent by weight of Ni.
3. Music string according to claim 2 characterized in that the .
precipitation hardening stainless steel has a composition, all in percent by
weight, of;

Balance Fe and normally occurring impurities.
4, Music string according to claim 3 characterized in that it comprises
0,5-1 % by weight of Ti.
5, Music string according to claim 3 characterized in that it comprises
0,2-1,5% by weight of Al.

6. Music string according to eiairn 3 characterized in that it comprises
0,1-0,6 % by weight of Ta + Nb.
7. Music string according to claim 3 eh a ra ct e ri z ed in that the
precipitation hardening stainless steel is UNS S46910,
8. Music string according to claim 3 characterized in that the
precipitation hardening stainless steel is UNS S174Q0.
9.. Music string according to claim 3 characterized in that the
precipitation hardening stainless steel is UNS S17700,
10.Music string according to claim 3 characterized in that the
precipitation hardening stainless steel is UNS S45500.
11.Music string according to claim 1 characterized in that it has a tensile
strength of at least 1800 MPa when in a diameter of 0,33 mm.
12.Music string according to claim 1 characterized in that it has a
resistance to relaxation such as it will resist a loss of frequency of 2 Hz for
at least 18 hours,
13. Music string according to any of the preceding claims characterized in
that the precipitation hardening stainless steel is in the cold drawn
condition.
14. Music string according to any of claims 1-7 characterized in that the
precipitation hardening stainless steel is in the heat treated condition.

15. Music string according to claim 14 characterized in that it has a
tensile strength of at least 2500 when in a diameter of 0,254 mm.
16.Music string according to claim 1 characterized in comprising a core
of precipitation hardening stainless steel wrapped with metal strands,
17. Music instrument characterized in that it comprises a string according
to any of the proceeding claims.

The present disclosure relates to a music string comprising precipitation hardening
stainless steel. The string has a superior resistance to relaxation and is corrosion resistant,
thus improving its tuning stability and maintaining its tone quality, thus prolonging its
service life.

Documents:

http://ipindiaonline.gov.in/patentsearch/GrantedSearch/viewdoc.aspx?id=mWMrV/JLOOyKn3Jy8dFL2A==&loc=wDBSZCsAt7zoiVrqcFJsRw==


Patent Number 271708
Indian Patent Application Number 2611/KOLNP/2008
PG Journal Number 10/2016
Publication Date 04-Mar-2016
Grant Date 01-Mar-2016
Date of Filing 27-Jun-2008
Name of Patentee SANDVIK INTELLECTUAL PROPERTY AB
Applicant Address MELIN, LINDA, S-811 81 SANDVIKEN
Inventors:
# Inventor's Name Inventor's Address
1 VOSOUGH, SINA SKOGSFRUVÄGEN 27, S-811 41 SANDVIKEN
2 BERGLUND, GÖRAN ODENGATAN 24, S-811 34 SANDVIKEN
PCT International Classification Number G01D 3/10,C22C 38/40
PCT International Application Number PCT/SE2006/050478
PCT International Filing date 2006-11-15
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 0502693-5 2005-12-07 Sweden