Title of Invention

A SOIL AND/OR MOISTURE RESISTANT SECURE DOCUMENT

Abstract A soil and/or moisture resistant secure document and a method for producing such a secure document, are provided. The inventive method preferably employs a size press or other similar device to force a soil and/or moisture resistant formulation into the pores of the substrate and to remove excess formulation from opposing surfaces thereof. Soil and/or moisture resistant formulations when applied this way instead of by way of standard coating techniques do not obscure optically variable effects generated by non-porous OVDs that may be employed on or within these secure documents. In addition, thin layers of fibers (e.g., papermaking fibers) overlying and thus embedding portions of security devices in windowed secure documents that have been rendered soil and/or moisture resistant in accordance with this invention demonstrate increased durability.
Full Text A SOIL AND/OR MOISTURE RESISTANT SECURE DOCUMENT
RELATED APPLICATION
[0001] This application claims the benefit of U.S. Provisional Patent Application Serial
No. 60/863,246, filed October 27, 2006, which is fully incorporated herein by reference.
TECHNICAL FIELD
[0002] The present invention generally relates to a soil and/or moisture resistant
secure document and to a method for producing such a secure document.
BACKGROUND AND SUMMARY OF THE INVENTION
[0003] Optically variable security devices such as thin films, holograms, gratings,
micro-prisms, photochromics, and more recently, microlens-based film structures
(hereinafter collectively referred to as OVDs), are recognized as valued additions to secure
documents such as banknotes. These devices allow for a variety of self-authenticating
optical effects while rendering the secure document more resistant to counterfeiting.
[0004] Microlens-based OVDs are described in U.S. Patent Application Publication
No. 2005/0180020 A1 to Steenblik et a/. The film material or structure described in this
reference employs a regular two-dimensional array of non-cylindrical lenses to enlarge
micro-images and, in one embodiment, comprises (a) an optical spacer; (b) a regular
periodic planar array of image icons positioned on one surface of the optical spacer; and (c)
a regular periodic array of lenses positioned on an opposing surface of the optical spacer.
The images projected by this film structure show a number of visual effects including
orthoparallactic movement.
[0005] OVDs in the form of security patches, are mounted on one or both surfaces of
a security document (e.g., banknote), while OVDs in the form of security strips or threads,
are partially embedded within the document, with the OVDs being visible in one or more
clearly defined windows on one or both surfaces of the document.
[0006] One of the primary requirements of banknotes and other secure documents is
that the document must resist the effects of circulation. These documents must be durable
(i.e., resistant to fold damage, tearing and soiling) and resistant to moisture and chemical
absorption. In addition, the print which is applied to the document must adhere well,
especially under severe conditions such as mechanical abrasion and accidental laundering.
[0007] In order to render banknotes and other secure documents more resistant to
the effects of circulation; manufacturers and printers have coated the documents with certain

varnishes and polymeric coatings. These varnishes and coatings, which consist of either
ultraviolet (UV) radiation-crosslinkable prepolymers (100% solids), or resin mixtures with
different host solvents (resin solids content ranging from 30 to 50 % by weight), serve to seal
the surface of the document increasing its resistance to soiling and moisture. Typically
applied in a final, or near final step in the document's production using standard coating
techniques (e.g., roller coating, gravure coating, air knife coating, roll coating, blade coating),
these surface coatings are generally referred to as post-print varnishes. Coat weights
applied to each side of the document surface range from 0.5 grams per square meter (g/m2)
to 5.0 g/m2.
[0008] A more recent trend has been to apply a coating to substrates used in the
production of these secure documents either during or immediately following manufacture.
These surface coatings, commonly referred to as pre-print coatings, may be described as
aqueous resin binder systems that serve to render the document resistant to moisture and
soiling. Pre-print coatings may constitute or make up 1 to 15% of the document's finished
mass.
[0009] Unfortunately, OVDs in secure documents subjected to one or both of these
prior art techniques are at least partially obscured or otherwise adversely affected as a result
of the overlying varnish or coating. As will be readily appreciated by those skilled in the art,
OVDs rely on unique surface topographies in order to produce novel and specifically
engineered visual and machine verifiable effects. Covering these surfaces with coatings and
varnishes can cloud, mute, distort or otherwise diminish the features' effect.
[0010] ' As the requirement for resistance to soiling and moisture increases, generally
the amount of pre-print coatings and/or post-print varnishes applied to the substrate is
likewise increased. A trade-off then occurs in the form of increased substrate durability in
exchange for reduced performance and effectiveness of some security features. In addition,
some types of varnishes contain light scattering or light diffusing additives to reduce an
appearance of glossiness on the finished, varnished documents. These additives can
further decrease the effects of some security features.
[0011] In an effort to avoid these detrimental effects on the optically variable effects
generated by OVDs, certain manufacturers (i) use very light coat weights of pre-print
coatings or post-print varnishes, which reduces the document's ability to resist moisture and
soiling, (ii) avoid the combination of pre-print coatings or post-print varnishes with certain
OVD security features, or (iii) block the areas on the document surface prior to applying the
pre-print coating or post-print varnish, which leaves significant areas of the document
surface unprotected and unduly complicates the application process.

[0012] It has been discovered by the present inventors that the optical effect of these
OVDs can be preserved without compromising soil and/or moisture resistance by applying a
soil and/or moisture resistant formulation by way of a size press or other similar device
instead of by way of standard coating techniques. It has also been discovered that thin
layers of fibers (e.g., papermaking fibers) overlying and thus embedding portions of security
devices in windowed secure documents rendered soil and/or moisture resistant in this way
demonstrate increased durability.
[0013] The present invention therefore generally provides a method for imparting soil
and/or moisture resistance to a porous substrate used in the manufacture of secure
documents, the porous substrate having a thickness. The inventive method comprises (a)
applying a soil and/or moisture resistant formulation to opposing surfaces of the porous
substrate, (b) forcing the soil and/or moisture resistant formulation into the pores of the
substrate, the formulation thereby penetrating and extending throughout at least a portion of
the thickness of the substrate, and (c) removing excess formulation from opposing surfaces
of the substrate. Preferably, a size press (e.g., puddle or metering) or other similar device is
used to force the soil and/or moisture resistant formulation into the pores of the substrate
and to remove excess formulation from opposing surfaces thereof.
[0014] In a first contemplated embodiment, the inventive method imparts soil and/or
moisture resistance to the porous substrate without obscuring optically variable effects
generated by non-porous OVDs contained (or exposed) on a surface thereof, the method
comprising:
(a) applying a soil and/or moisture resistant formulation to opposing
surfaces of the porous substrate, the substrate supporting one or more non-porous
OVDs; and
(b) employing a size press or other similar device to force the soil and/or
moisture resistant formulation into the pores of the substrate and to remove excess
formulation from opposing surfaces thereof, thereby leaving exposed surfaces of the
non-porous OVDs substantially free of the soil and/or moisture resistant formulation.
The term "non-porous OVDs", as used herein, includes those OVDs having substantially or
essentially non-porous surfaces, and those OVDs having surfaces that are substantially or
essentially non-porous only in areas contained (or exposed) on a surface of the porous
substrate.
[0015] In a second contemplated embodiment, the inventive method imparts soil
and/or moisture resistance to a windowed porous substrate supporting one or more security
devices while increasing the durability of the substrate in areas overlying the security

device(s), those areas of the substrate framing the device(s) and forming at least one
window through which the security device(s) is exposed, the method comprising:
(a) applying a soil and/or moisture resistant formulation to opposing
surfaces of the porous substrate having the one or more security devices partially
embedded therein and visible in one or more windows on at least one surface
thereof; and
(b) employing a size press or other similar device to force the soil and/or
moisture resistant formulation into the pores of the porous substrate and to remove
excess formulation from opposing surfaces thereof.
[0016] The present invention also generally provides a soil and/or moisture resistant
secure document, which comprises at least one porous substrate having a thickness, and an
effective amount of a soil and/or moisture resistant formulation contained within the pores
and on opposing surfaces of the porous substrate(s), wherein the soil and/or moisture
resistant formulation is distributed throughout at least a.portion of the thickness of the porous
substrate(s).
[0017] In a first contemplated embodiment, the inventive soil and/or moisture
resistant secure document further comprises one or more non-porous OVDs contained on
and/or partially within the substrate(s), wherein the one or more non-porous OVDs have
exposed surfaces that are substantially free of the soil and/or moisture resistant formulation.
The phrase "substantially free", as used herein, means that the non-porous OVDs have only
residual or trace amounts of formulation on exposed surfaces thereof.
[0018] In a second contemplated embodiment, the inventive soil and/or moisture
resistant secure document is a windowed secure document having one or more security
devices partially embedded therein and exposed in one or more windows, those areas of the
secure document overlying the one or more security devices demonstrating increased
durability. Preferably, the one or more security devices are non-porous, optically variable,
security strips or threads having surfaces that are substantially free of the soil and/or
moisture resistant formulation.
[0019] Other features and advantages of the invention will be apparent to one of
ordinary skill from the following detailed description. Unless otherwise defined, all technical
and scientific terms used herein have the same meaning as commonly understood by one of
ordinary skill in the art to which this invention belongs. All publications, patent applications,
patents and other references mentioned herein are incorporated by reference in their
entirety. In case of conflict, the present specification, including definitions, will control. In

addition, the materials, methods, and examples are illustrative only and not intended to be
limiting.
BEST MODE FOR CARRYING OUT THE INVENTION
[0020] By way of the present invention, it has been discovered that soil and/or
moisture resistant materials when applied by way of a size press or other similar device
instead of by way of standard coating techniques do not obscure the optically variable
effects generated by OVDs employed on or within banknotes and other secure documents.
It has also been discovered that the durability of thin fibrous layers overlying a security strip
or thread embedded in a windowed banknote or other secure document is increased when
soil and/or moisture resistant materials are applied during manufacture by way of a size
press or other similar device.
[0021] Practice of the present invention allows for improved process economics
where the inventive method represents a more time-efficient, streamlined pathway to
providing soil and/or moisture resistance to secure documents by obviating the need for pre-
print coating and post-print varnishing processes and the concomitant capital investment in
the necessary coating and varnishing equipment.
[0022] Although the soil and/or moisture resistant secure document of the present
invention will be described herein mainly 'for use in the manufacture of banknotes, the
invention is not so limited. The inventive secure document can be used to prepare a variety
of different items including checks, identity cards, lottery tickets, passports, postage stamps,
stock certificates, and the like.
[0023] As noted above, the soil and/or moisture resistant secure document of the
present invention comprises at least one porous substrate having a thickness, and an
effective amount of a soil and/or moisture resistant formulation contained within the pores
and on opposing surfaces of the substrate(s), wherein the soil and/or moisture resistant
formulation is distributed throughout at least a portion of the thickness of the porous
substrate(s).
[0024] Substrates suitable for use in the present invention are paper or paper-like
sheet materials having a porosity of from about 2 to about 100 milliliters per minute (ml/min),
preferably from about 5 to about 50 ml/min. Porosity is defined as the air permeability as
determined according to ISO standard 5636-3 (September 15, 1992). This test can be
performed with an L&W Bendtsen Tester of AB Lorentzen & Wettre, Kista, Sweden.
[0025] These sheet materials, which are single or multi-ply sheet materials, may be
made from a variety of fibers such as abaca, cotton, linen, wood pulp, and blends thereof.

As is well known to those skilled in the art, cotton and cotton/linen blends are preferred for
banknotes, while wood pulp is commonly used in non-banknote security documents.
[0026] The soil and/or moisture resistant formulation contemplated for use in the
present invention is preferably prepared as an aqueous formulation (e.g., dispersion)
containing components, at least some of which are found in prior art pre-print coatings and
post-print varnishes. Included among these components are thermoplastic resins such as
resins having an ester bond (e.g., polyester resins, polyether resins), polyurethane resins,
functionalized polyurethane resins (e.g., carboxylated polyurethane resins), and copolymers
(e.g., urethane-acrylic resins, polyether-urethane resins, styrene acrylate resins) and
mixtures thereof.
[0027] In addition to the above components, the soil and/or moisture resistant
formulation of the present invention may advantageously contain other solvents, cosolvents
or diluents as well as additives including (but not limited to) antimicrobial agents, catalysts,
crosslinking agents (e.g., silane crosslinking agents), defoaming agents, pigments (e.g.,
titanium dioxide), plasticizers, stabilizers, surfactants or wetting agents, and viscosity
modifiers, provided any such solvent, cosolvent, diluent, or additive does not adversely
impact upon the desirable properties of the resulting secure document.
[0028] In a preferred embodiment, the soil and/or moisture resistant formulation is an
aqueous polymer dispersion, the average particle size of the dispersed particles found in the
polymer dispersion ranging from about 50 to about 150 nanometers (nm) (preferably, from
about 70 to about 140 nm).
[0029] In a more preferred embodiment, the soil and/or moisture resistant aqueous
polymer dispersion contains particles or solids of polyurethane resins, polyether-urethane
resins, and/or urethane-acrylic resins (resin solids content of dispersion ranging from 30 to
50 % by dry weight, preferably from about 35 to about 45 % by dry weight). In yet a more
preferred embodiment, the soil and/or moisture resistant aqueous polymer dispersion further
contains one or more pigments such as titanium dioxide pigment, and optionally one or more
crosslinking agents. An example of one such polyurethane dispersion (without a pigment
and crosslinking agent(s)) is available from Roymal, Inc., Newport, New Hampshire, U.S.A.,
under the trade designation NOTEGUARD PRIMER polyurethane dispersion.
[0030] The soil and/or moisture resistant formulation is made by mixing the
component(s) with water so as to obtain an aqueous formulation having a total solids content
ranging from about 10 to about 40 % by dry weight (preferably, from about 15 to about 30 %
by dry weight, and more preferably from about 20 to about 25 % by dry weight), based on

the total dry weight of the formulation. The pH of the aqueous formulation is between 5.5
and 9.5, and preferably is between 6.0 and 8.0.
[0031] Preferably, pigment is added to the formulation just prior to applying it to the
porous substrate. Pigment is used to counteract the transparentizing effect of resin pickup
and incorporation into the porous substrate or base sheet. Adding pigment to the
formulation just prior to its application to the base sheet obviates the need for stabilizers to
assure homogeneity. It also allows for these formulations to be customized for different
paper grades with different requirements, and even allows for batch-to-batch adjustments
during production of a particular grade.
[0032] The inventive method for imparting soil and/or moisture resistance to a
porous substrate comprises (a) applying the above-described soil and/or moisture resistant
formulation to opposing surfaces of the porous substrate, (b) forcing the soil and/or moisture
resistant formulation into the pores of the substrate, the formulation thereby penetrating and
extending throughout at least a portion of the thickness of the substrate, and (c) removing
excess formulation from opposing surfaces of the substrate. Preferably, a size press or
other similar device is used to force the soil and/or moisture resistant formulation into the
pores of the substrate and to remove excess formulation from opposing surfaces thereof.
[0033] As is well known to those skilled in the art, upon leaving the "wet-end" of a
papermaking machine, a fibrous web containing a considerable amount of water is directed
toward a press section (e.g., a series of heavy rotating cylinders), which serves to press the
water from the web, further compacting it and reducing its water content, typically to about
70% by weight.
[0034] Following pressing, the paper web is dried in the main dryer section of the
papermaking machine. In the drying section, which is typically the longest section of the
papermaking machine, hot air or steam-heated cylinders contact both sides of the web,
substantially drying the web by evaporating the water to a level of approximately 5% by
weight of the paper.
[0035] The dried web or substrate is then surface sized at a size press. By way of
the present invention, the size press is used to force an effective amount (i.e., from about 5
to about 20 % by dry weight, preferably from about 7.5 to about 12.5 % by dry weight, based
on the total dry weight of the size press-treated substrate) of the soil and/or moisture
resistant formulation into the interstices of the substrate from both sides of the substrate.
The size press is also used to remove excess formulation from opposing surfaces of the
substrate. Penetration and distribution of the formulation is thus achieved throughout at
least a portion of the thickness of the substrate.

[0036] The size press-treated substrate is then dried in a secondary dryer section of
the papermaking machine to a moisture level of from about 4 to about 6 %.
[0037] The Gurley porosity of the resulting secure document preferably ranges from
about 15,000 to about 300.000 seconds, and more preferably ranges from about 40,000 to
about 150,000 seconds. Gurley porosity values are determined using TAPPl Test Method
No. T-460 om-06 (2006).
[0038] The soil and/or moisture resistant formulation provides the resulting secure
document with superior durability. Moreover, the printability of the secure document is not
adversely affected and in fact may be improved.
[0039] For secure documents employing one or more non-porous OVDs, the soil
and/or moisture resistant formulation provides the resulting secure document with superior
durability without diminishing the optically variable effects generated by the OVDs. More
specifically, in those areas of the substrate in which a non-porous OVD is present, the OVD
causes the formulation to be rejected from the surface of the OVD as the hydraulic pressure
of the size press increases. The surface of the OVD is left substantially free of the
formulation that now resides within the pores and on opposing surfaces of the substrate.
[0040] For windowed secure documents, those portions of the secure document
overlying partially embedded security devices demonstrate increased durability in the form of
a reduced tendency to tear and crack.
[0041] As is well known to those skilled in the art, a security strip or thread that is
partially embedded within and partially exposed on the surface of a banknote or other secure
document is commonly referred to as a windowed thread. The embedded areas of the
thread are covered with a thin layer of paper that serves to frame the thread and form at
least one window through which the thread is exposed. This thin layer of paper can be the
result of any technique employed in the paper-making industry. By way of example, the
thread may be fed into a cylinder mold papermaking machine, cylinder vat machine,
fourdrinier papermaking machine, or similar machine of known type, upon which a
suspension of papermaking fibers or papermaking stock is deposited (or selectively
deposited) onto the security thread; or is formed around it; or is displaced from an already
formed web. By way of further example, laminating or wet laminating techniques, as well as
techniques involving spraying of fibrous suspensions over select areas of the thread, can be
employed to achieve partial embedment. The overlying borders and bridges that result not
only cover a portion of the security thread, but are an integrated rather than separately
attached part of the paper structure.

[0042] One method of simulating the degradation effects that a secure document or
banknote endures in circulation is described in the publication: Bartz, W.J., and Crane, T.T,
The Circulation Simulator Method for Evaluating Bank Note and Optical Feature Durability",
SPIE Vol. 6075, San Jose, CA, January 2006. This publication describes a test method
developed by Crane & Co., Inc. that simulates the deterioration observed in actual circulated
banknotes - i.e. soiling, creasing, tearing, edge tatteredness and limpness. The test method
described, which is hereinafter referred to as "the Circulation Simulator Method", utilizes a
tumbler mounted on a lathe. Banknote specimens are weighted on each corner and are
tumbled in a medium of glass beads, metal discs and a synthetic soil mixture for three, 30-
minute cycles, during which physical degradation of the note specimens occurs. Durability is
judged by how well a note retains its initial optical and physical properties after being
subjected to the conditions of the Circulation Simulator Method.
[0043] Banknotes containing security threads that have been subjected to the
described conditions of the Circulation Simulator Method can in some circumstances display
weakness in the thin paper layer that covers the security thread. This weakness is
exemplified by cracking or tearing of this paper layer. One observation that has been made
about windowed banknotes containing non-porous, microlens-based, optically variable
security threads that have been produced in accordance with the present invention is that
. the thin paper layer that covers the security thread better resists the degradation effects
imposed by way of the Circulation Simulator Method. This improved strength or increased
durability is visually apparent, exemplified by the thin paper layer remaining intact and free
from tearing and cracking.
[0044] While various embodiments of the present invention have been described
above, it should be understood that they have been presented by way of example only, and
not limitation. Thus, the breadth and scope of the present invention should not be limited by
any of the exemplary embodiments.
[0045] Having thus described the invention, what is claimed is:

CLAIMS
1. A method for imparting soil and/or moisture resistance to a porous substrate
used in the production of secure documents and having a thickness, the method comprising:
5 applying a soil and/or moisture resistant formulation to opposing surfaces of the porous
substrate; forcing the soil and/or moisture resistant formulation into the pores of the
substrata, the formulation thereby penetrating and extending throughout at least a portion of
the thickness of tha substrate; and removing excess formulation from opposing surfaced of
the substrata.
10 2. The method of claim 1, wherein prior to the soil and/or moisture resistant
formulation being applied to opposing surfaces of the porous substrate, tha porous substrate
has a porosity ranging from about 2 to about 100 milliliters per minute, determined in
accordance with ISO Standard 5636-3 (1992).
3. The method of claim 2, wherein the porous substrate has a porosity ranging
15 from about 5 to about SO miilliters per minute,
4. The method of claim 1, wherein a Size press or other similar device is used to
fores the soil and/or moisture resistant formutertlon Into the porss of the substrate and to
remove excess formulation from opposing surfaces thereof.
5. The method of claim 1, wherein the soil and/or moisture resistant formulation
20 is an aqueous formulation containing one or more thermoplastic resins selected from the
group of resins having an ester bond, polyurethane resins, functtonaiized polyurethane
resins, and copolymers and mixtures thereof.
6\ The method of daim 5, wherein the soil and/or moisture resistant formulation
Is an aqueous polymer dispersion comprising dispersed particles having average particle
25 sizes ranging from about 50 to about 150 nanometers.
7, The method of daim 6, wherein the aqueous polymer dispersion comprises
from about 10 to about 40 % by dry weight of resin particles or solids selected from Una
group qf polyurethane resins, polyefher-urethane resins, urethane-acrylic resins, and
natures thereof.
30 8. The method of claim 7, wherein the aqueous polymer dispersion further
comprises one or more pigments, and optionally one or more orosslinking agents.
9. The method of claim 1, wherein from about 6 to about 20 % by dry weight,
based on the total dry weight of the treated substrate, of the soil and/or moisture resistant
formulation fs forced Into the pores of tha substrate from both sides thereof.

10. The method of clafm 1, whereln the porous substrate has one or more non-
porous, optically variable.

security devices contained an, or exposed through one or more windows in, at least one
surface of the substrate, the method comprising:
(a) applying a soil and/or moisture resistant formulation to opposing
surfaces of the porous substrate; and
$ (b) employing a size press or other similar device to force the soil and/or
moisture resistant formulation Into the pores of the substrata and to remove excess
formulation from opposing surfaces of the substrate, thereby leaving exposed
surfaces of the one or more non-porous, optically variable, security devices
substantially free of the soil and/or moisture resistarrtformulation.
w 11. Trie method of claim 1, wherein Hie porous substrata is a windowed porous
substrate' having one or more security devices partially embedded therein end visible in one
or more windows on at least one surface thereof, the method comprising;
(a) applying a soil and/or moisture resistant formulation to opposing
surfaces of the parous substrate; and
' is (b) employing a size press or other similar device to force the soil and/or
moisture resistant formulation Into the pores of the porous substrate and to remove
excess formulation from opposing surfaces thereof, thereby increasing the durability
In areas of the porous substrate overtying the one or more security devices, those
areas framing the devtaefs) and forming at (east one window through which the
zo device(s) is exposed.
12, A soil end/or moisture resistant secure document, which comprises at least
one porous substrate having a thickness, and an effective amount of a soil end/or moisture
resistant formulation contained within the pores and on opposing surfaces of tne. porous
substrate®, wherein the soil and/or moisture resistant formulation is distributed throughout
25 at least a portion of the thickness of the porous substrate(s).
13. The soil and/or moisture resistant secure document of claim 12, which further
comprises one or more non-porous, optically variable, security devices contained on and/or
partially within the substrate(s), 'wherein the one or more non-porous devices have exposed
surfaces that are substantially free of the soil and/or moisture resistant formulation.
30. 14. The soil and/or moisture resistant secure document of claim 12, wherein the
secure document Is a windowed secure document having one or more security devices
partially embedded therein and exposed In one or more windows, wherein areas of trie
secure document overlying the one or more security devices demonstrate increased
durability.

16. The sol) and/or moisture resistant secure document of claim 12, which has a
porosity ranging from about 15,000 to about 300,000 seconds, determined fn accordance
with TAPPI Test Method No. T-460 orn-OS (2008).
16. The soli and/or moisture resistant secure document of claim 15, which has a
5 porosity ranging from about 40,000 to about 150,000 seconds.
17. The soli and/or moisture resistant secure document of claim 13, wherein the
one or more non-porous, optically variable, security devices Is selected from the group of
thin films, holograms, gratings, micro-prisms, photochromies, and microlene-baeed film
structures.
10 18. The soil and/or moisture resistant secure document of claim 17, wherein the
one or more non-porous, optically variable, security devices Is a mlcrolens-based film
structure in the form of a security strip or thread that is partially embedded within the
document, with the film structure being visible in one or more clearly defined windows on
one or both surfaces of the document.
15 19. The soil and/or moisture resistant secure document of claim 12, wherein the
soil and/or moisture resistant formulation Is an aqueous formulation containing thermoplastic
resins selected from the group of resins having an ester bond, polyurethane resins,
functlonaiized polyurethane resins, and copolymers and mixtures thereof.
20. The soil and/or moisture resistant secure document of claim 19, wherein the
20 soil and/or moisture resistant formulation Is an aqueous polymer dispersion, comprising
dispersed particles having average particle sizes ranging from about 50. to about 150
nanometera.
21. The soil and/or moisture resistant secure document of claim 20, wherein the
aqueous polymer dispersion comprises from about 10 to about 40 % by dry weight of resin
23 particles or solids selected from the group of polyurethane resins, poiyetjier-urethane resins,
urethano-acrylic resins, and mixtures thereof.
22. The son and/or moisture resistant secure document of claim 21, wherein the
aqueous polymer dispersion further comprises one or more pigments, and optionally one or
more crossiinking agents.
30 23. The secure document of claim 14, wherein the one or more security devices
are one or more non-porous, optically variable, security strips or threads having surfaces
that are substantially free of the soil and/or moisture resistant formulation,

A soil and/or moisture resistant secure document and a method for producing such a secure document, are provided. The inventive method preferably employs a size press or other similar device to force a soil and/or moisture resistant formulation into the pores of the substrate and to remove excess formulation from opposing surfaces thereof. Soil and/or moisture resistant formulations when applied this way instead of by way of standard coating techniques do not obscure optically variable effects generated by
non-porous OVDs that may be employed on or within these secure documents. In addition, thin layers of fibers (e.g., papermaking fibers) overlying and thus embedding portions of security devices in windowed secure documents that have been rendered soil and/or moisture resistant in accordance with this invention demonstrate increased durability.

Documents:

http://ipindiaonline.gov.in/patentsearch/GrantedSearch/viewdoc.aspx?id=vua1iGBb3Njczjr6r0MrYQ==&loc=wDBSZCsAt7zoiVrqcFJsRw==


Patent Number 272876
Indian Patent Application Number 1971/KOLNP/2009
PG Journal Number 19/2016
Publication Date 06-May-2016
Grant Date 29-Apr-2016
Date of Filing 26-May-2009
Name of Patentee CRANE & CO., INC.
Applicant Address 30 SOUTH STREET, DALTON, MA 01226
Inventors:
# Inventor's Name Inventor's Address
1 CRANE, TIMOTHY T. 860 CRANE ROAD, WINDSOR, MA 01270
2 MORCK-HAMILTON, KARIN RENSTIERNAS GATA 14, S-11628 STOCKHOLM
3 NIEDECK, TOD, L. 14 VETERANS ROAD, AMHERST, NH 03031
4 MARASCHI, MARCO UPPLANDSGATEN 54E, S-11328 STOCKHOLM
5 DARROCH, MICHAEL 16 ELM STREET, DALTON, MA 01226
PCT International Classification Number D21H 21/16
PCT International Application Number PCT/US2007/020571
PCT International Filing date 2007-09-24
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 60/863,246 2006-10-27 U.S.A.