Title of Invention	COATING SYSTEM, COATED WORKPIECE AND METHOD FOR MANUFACTURING THE SAME
Abstract	The coating system comprises: at least one layer of type A, a layer of type A substantially consisting of (AlyCrl-y) X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y describing the stoichiometric composition of the metallic phase fraction; and at least one layer of type B, a layer of type B substantially consisting of (AluCr1-u- v-wSivMew) X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts one of the group consisting of W, Nb, Mo and Ta or a mixture of two or more of the constituents of that group, u, v and w describing the stoichiometric composition of the metallic phase fraction. A thickness ratio of said layer of type A to said layer of type B is higher than 1. The workpiece comprises such a coating system. Through this, an excellent wear-protection is provided, and the coating system and workpieces can be used for a broad range of different applications. The coating system can be deposited very efficiently in a PVD process using two types of targets, wherein targets of one type are active during depositing a layer of type A and during depositing a layer of type B.

Title of Invention

COATING SYSTEM, COATED WORKPIECE AND METHOD FOR MANUFACTURING THE SAME

Abstract

The coating system comprises: at least one layer of type A, a layer of type A substantially consisting of (AlyCrl-y) X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y describing the stoichiometric composition of the metallic phase fraction; and at least one layer of type B, a layer of type B substantially consisting of (AluCr1-u- v-wSivMew) X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts one of the group consisting of W, Nb, Mo and Ta or a mixture of two or more of the constituents of that group, u, v and w describing the stoichiometric composition of the metallic phase fraction. A thickness ratio of said layer of type A to said layer of type B is higher than 1. The workpiece comprises such a coating system. Through this, an excellent wear-protection is provided, and the coating system and workpieces can be used for a broad range of different applications. The coating system can be deposited very efficiently in a PVD process using two types of targets, wherein targets of one type are active during depositing a layer of type A and during depositing a layer of type B.

Full Text	COATING SYSTEM, COATED WORKPIECE AND METHOD FOR MANUFACTURING THE SAME Technical Field The invention relates to the field of coated workpieces and the manufacture thereof. More particularly, it relates to wear protection of workpieces by wear protective coatings and to the deposition of such coatings. Background of the Invention TiAIN coatings are widely used as physical vapor deposition (PVD) coatings for wear protective applications. The AlCrN system is reported to exhibit superior mechanical properties such as hardness and hot hardness, thermal and tribological properties resulting in superior application lifetime of coated parts. As commonly understood in the art, stoichiometric indices are not explicitely quoted, e.g., AlCrN stands, more precisely, for (AlyCr1_y)N (0 US 7 226 670 discloses a workpiece coated with a system of film layers comprising at least one film composed of (AlyCri_y)X where [ = N, C, B, CN, BN, CBN, NO, CO, BO, CNO, BNO or BNCO, the Irorkpiece being a milling tool, a hob, a ball nose mill, a planar or a profiling cutter, a clearing tool, a reamer, an insert for turning and milling, a die or an injection mold, showing a superior wear protective performance. US 7 348 074 discloses coating concepts consisting of a multilayer structure with 10 layer packets. These concepts show good protective performance in drilling applications. US patent application US 2008/0229891 discloses a multilayered coating which comprises at least one layer A comprising as material (TiAl)X, where X = N, CN, CNO or NO, or of (AlCr)X, where X = N, CN, CNO or NO, and comprising at least one layer B with (AlCrSiMe)X where X = N, CN, CNO or NO, wherein Me stands f,or Nb, Mo, Ta or W.. Furthermore, said US 2008/0229891 discloses that the layer structure of said at least one layer B is designed to consist of at least of two different crystalline phases. This could be for example a cubic and a hexagonal phase fraction. In said US 2008/0229891, it is further disclosed that the thickness ratio between layer A and layer B is an important issue in the sense that coatings with thickness ratios of layer A to layer B above 1 seem to exhibit inferior performance. All these prior art coatings show good wear protective performance for more or less special applications. It remains therefore a need to provide a wear protective coating for a broad range of different applications. ummary of the Invention Therefore, one object of the invention is to create a coating system that does not have the disadvantages mentioned above. In particular, a coating system shall be provided, which can be used for a broad range of different applications. In addition, the respective coated workpiece and the corresponding method for manufacturing such a workpiece shall be provided. Another object of the invention is to provide a coating system, a correspondingly coated workpiece and a method for manufacturing such a workpiece providing improved wear protective and/or wear resistant properties. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece which provide an increased tool lifetime for a very broad range of applications. Therein, said applications may comprise continuous and interrupted cutting applications including, but not limited to drilling, milling, reaming, turning, tapping, threading and hobbing applications. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece, wherein said workpieces are workpieces for machining parts which can be made of various materials such as, e.g., ferrous and non-ferrous metals as well as composite materials. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece, wherein said workpieces may be used under various working conditions, such as, lor example, dry cutting, cutting with emulsion and/or liquid coolants, cutting with minimal quantity lubrication (MQL) and cutting with gaseous coolants. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece, wherein said workpiece is a drill, an endmill, an insert, or a hob. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece, wherein said workpiece substrate is substantially made of steel, in particular high- speed steel, cemented carbide, cubic boron nitride, cermet or a ceramic material. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece, wherein said workpiece is suitable for application in machining of at least one of, preferably most of: ferrous and nonferrous materials, preferably hardened steel, annealed steel, alloyed steel, low carbon steel, stainless steel, titanium-based alloys, nickel-based alloys and composite materials. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece, wherein the coating shall have superior mechanical and thermal properties, in particular with respect to hardness, hot hardness and oxidation resistance. Another object of the invention is to provide a coating system for coating a workpiece, a correspondingly coated workpiece and a method for manufacturing such a workpiece, wherein the coating shall provide superior protection of the work piece at low and ?iigh temperature application conditions. Another object of the invention is to provide a method for manufacturing a coated workpiece, in particular a workpiece as mentioned above, which can be carried out particulary time- efficiently. Another object of the invention is to provide a method for manufacturing a coated workpiece, in particular a workpiece as mentioned above, which is particulary simple to carry out. Further objects emerge from the description and embodiments below. At least one of these objects is at least partially achieved by coating systems, workpieces and/or methods according to the patent claims. The coating system is a multilayer coating comprising at least one layer A essentially consisting of (AlyCri_y)X, wherein X = N, CN, BN, NO, CNO, CBN, BNO or GNBO, and y describes the stoichiometric composition of the metallic phase fraction. Said multilayer coating further is proposed to comprise at least one layer B essentially consisting of (AluCri-u-v-wSivMew)X, wherein X = N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me = W, Nb, Mo, Ta or a mixture thereof, and wherein u, v, w describe the stoichiometric composition of the metallic phase fraction. Through this, a wear-protective coating system can be provided, which can be used for a broad range of different applications. • Index y stands, more precisely and as agreed in the art, for a number with 0 the art, u is a number with 0 0 u + v + w = 1. Furthermore, more precisely and as agreed in the art, the stoichiometric value of X is always 1, i.e. in case X ^comprises more than one chemical element, the sum of the stoichiometric indices of these elements is one, e.g., in case of X = BNO, X depicts Bi_a_bNaOb (and 0 In one embodiment, a thickness ratio of layer A to layer B higher than 1, and more preferably higher than about 1.5 is realized. Through this, particularly good wear-protection can be achieved. A thicker layer of type A in combination with a thinner layer of type B yields excellent results. In one embodiment which may be combined with one or more of the before-addressed embodiments, said at least one layer of type B is designed to comprise at least two crystalline phases, more particularly said at least one layer of type B substantially comprises exactly two crystalline phases. In this embodiment, a first crystalline phase of said at least one layer of type B is a cubic phase and the second crystalline phase of said at least one layer of type B is a hexagonal phase. In this case, in a special embodiment, the hexagonal phase content is of type B, and more particularly amounts to between 5% and 40%. In one embodiment which may be combined with one or more of the before-addressed embodiments, said at least one layer of type A essentially is of cubic structure. In one embodiment which may be combined with one or more of the before-addressed embodiments, the stoichiometric composition of the metallic fraction of said at least one layer of type A is characterized by 0.5 In one embodiment which may be combined with one or more of the before-addressed embodiments, the stoichiometric composition of the metallic fraction of said at least one layer of type B is ^characterized by 0.5 ^K).OO2 In one embodiment which may be combined with one or more of the before-addressed embodiments, a layer of type B is directly deposited onto a layer of type A. In one embodiment which may be combined with one or more of the before-addressed embodiments, a layer of type B is sandwiched between a first layer of type A and a second layer of type A. In one embodiment which may be combined with one or more of the before-addressed embodiments, a layer of type A and a layer of type B form a period, and said coating system is a coating system with mulitple such periods. In one embodiment which may be combined with one or more of the before-addressed embodiments, said coating system comprises another layer, in particular said other layer forming a functional layer. E.g., said other layer being an adhesion layer, more particularly deposited directly onto a substrate, and in particular immediately below the first layer of type A; or, e.g., said other layer being a top layer, i.e. the layer is deposited as last layer, in particular is a decorative top layer. The workpiece according to the invention comprises a coating system according to the invention. The workpiece benefits from the advantages of the coating system in an analogous way. In one embodiment (which actually is an enumeration of various possible embodiments), said workpiece is at least one of the group consisting of: a tool, a machining tool, a milling tool, a cutting tool, a turning tool, a tapping tool, a threading tool, a reamer, an end mill, a drill, a cutting insert, a gear cutting tool, an insert, a hob, a clearing tool, an insert for turning and milling. In one embodiment which may be combined with one or more of the fcfcefore-addressed embodiments (and which actually is an enumeration of various possible embodiments), said workpiece has a body substantially made of at least one of the group consisting of: a ferrous metal, non-ferrous metal, a composite material, a cemented carbide, a cermet, a cubic boron nitride, a ceramic material, a steel, a high speed steel. In one aspect, the invention comprises a method for manufacturing a coated workpiece, more particularly, a PVD (physical vapor deposition) process which allows to synthesize a coating system, more particularly a coating system according to the invention, not only in separate deposition processes but also within one deposition process. The method for manufacturing a coated workpiece comprises the steps of a) depositing on said workpiece at least one layer of a type A; and b) depositing on said workpiece at least one layer of a type B different from said type A; wherein — said at least one layer of a type A is deposited using nx targets of a type X; and — said at least one layer of a type B is deposited using nY targets of a type Y different from said type X and simultaneously using nXy targets of said type X; wherein nx, nY, and nXy are integers ^ 1, and at least one of said targets of said type X is active during both, step a) and step b). This way, significantly reduced deposition times can be realized. One or more targets can be active during both, the deposition of a layer of type B and the deposition of a layer of ^£ype A. This can also be advantageous in terms of process stability. The deposition can be carried out in little time, and the depositing steps can be carried out in the same vacuum chamber without breaking the vacuum. In one embodiment, nx ^ nxy applies. In one embodiment, nx = nXy applies. In this case, all targets of type X active during depositon of said at least one layer of type A are also active during depositon of said at least one layer of type B. In one embodiment of the method which may be combined with one or more of the before-addressed method embodiments, a layer of type A substantially consists of (AlyCri-y)X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y describing the stoichiometric composition of the metallic phase fraction; and a layer of type B substantially consists of (AluCri_u_v_wSivMew)X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts one of the group consisting of W, Nb, Mo and Ta or a mixture of two or more of the constituents of that group, u, v and w describing the stoichiometric composition of the metallic phase fraction. In one embodiment of the method which may be combined with one or more of the before-addressed method embodiments, a thickness ratio of said layer of type A to said layer of type B is higher than 1, in particular higher than about 1.5. In other words, steps a) and b) are carried out such that a thickness of the layer of type A is larger, in particular larger by a factor of more than about 1.5, than a thickness of the layer of type B. In one embodiment of the method which may be combined with one or ^ftore of the before-addressed method embodiments, a target of said type X comprises Al and Cr, and a target of type Y comprises Al, Cr, Si and said Me provided in said layer of type B. In one embodiment of the method which may be combined with one or more of the before-addressed method embodiments, steps a) and b) are carried out using a physical vapor deposition process, in particular a cathodic arc evaporation process. In one embodiment of the method which may be combined with one or more of the before-addressed method embodiments, the deposition process is characterized by a deposition temperature preferably at or below about 500°C, and/or by a reactive gas atmosphere comprising predominantly N and/or with a total gas pressure situated between 0.5 and 10 Pa, preferably > 2Pa, and/or by a bias voltage of between 40 and 200 V and/or where the bias voltage during the deposition of said at least one layer of type A is lower than during the deposition of said at least one layer of type B in the multilayered structure. The invention comprises methods with features of corresponding coating systems and workpieces according to the invention, and vice versa. The advantages of the methods correspond to the advantages of corresponding coating systems and workpieces and vice versa. Further embodiments and advantages emerge from the dependent claims and the figures. Brief Description of the Drawings Below, the invention is described in more detail by means of examples and the included drawings. The figures show: Fig. 1 an SEM (scanning electron microscopy) image showing the structure of a coating according to an embodiment of th present invention; Fig. 2 XRD (X-ray diffraction) patterns of single layers of type A and type B, respectively; Fig. 3 a schematized detail of an exemplary configured vacuum deposition chamber, in a top view; Fig. 4 a schematized detail of an exemplary configured vacuum deposition chamber, in a top view; Fig. 5 a layer structure of a coating system; Fig. 6 a layer structure of a coating system; Fig. 7 a layer structure of a coating system; Fig. 8 a schematized detail of an exemplary configured vacuum deposition chamber, in a top view; Fig. 9 a layer structure of a coating system, comprising an additional top layer (e.g., a decorative top layer), as can be deposited in a vacuum deposition chamber configured as shown in Fig. 8. The reference symbols used in the figures and their meaning are summarized in the list of reference symbols. The described embodiments are meant as examples and shall not confine the invention. etailed Description of the Invention In the following, the invention will be explained more closely in conjunction with some application examples. As mentioned above, it is one possible object of the present invention to present a coating system (or shortly a "coating") showing excellent protective wear resistance for a very broad range of applications. In order to demonstrate the superiority of coatings according to the invention over prior art coatings, we firstly introduce a number of prior art coatings together with a number of different coatings according to the invention by describing how they are produced. Then we will discuss different application examples with highly differing machining conditions representing applications such as for example drilling or milling of soft, annealed or hard material, and discuss the performance of the coatings according to the invention as compared to the prior art coatings. All of the following coatings have been synthesized using cathodic arc evaporation in an arc evaporation equipment. The workpieces are placed into a chamber (vacuum chamber) of suitable arc evaporation equipment. In such a coating equipment, targets are used as for example those shown in table 1. Table 1 indicates for each of six samples (coatings) the elemental composition (in atomic percent) of the targets used and the elemental composition of respectively deposited layers. Finally, table 1 shows application test results for four different applications (appl 1 to appl 4). Layer thicknesses are in the usual thickness range for wear- protective coatings. The overall thickness of the coating system will usually not exceed about 20 urn. Samples No. 1, 2 and 3 are coatings as known in the art. Prior art coating No. 1 describes a monolayer of AlCrN deposited with six equal AlCr targets with the composition of 70% Al and 30% Cr as shown in table 1. The deposition was conducted in a pure N2-atmosphere at a gas pressure of 3.5 Pa and a bias voltage of -40 to -100V at 500°C at the substrate. Prior art coating No. 2 was, differing from example No. 1, conducted using four AlCr targets and two TiSi targets. The compositions of the targets are shown in table 1. The evaporation was conducted in a pure N2-atmosphere at a pressure of 3.5 Pa and a bias voltage of -40V at about 500°C at the substrate. Prior art coating No. 2 was synthesized as a multilayered coating having a bottom layer of AlCrN followed by 10 layer packages (AlCrN, TiSiN, AlCrTiSiN) and a TiSiN top layer. Prior art coating No. 3 was deposited using four AlCrSiW targets and two TiAl targets with the compositions mentioned in the corresponding line in table 1. Firstly, a TiAIN support layer was deposited which was followed by an AlCrSiWN main layer. The thickness relation between the main layer and the support layer is in the range of 1 : 2.5. The evaporation was conducted in a pure N2 atmosphere at 3.5 Pa, and the bias voltage was adjusted between -40V and -100V at about 600°C at the substrate. The deposition of the coatings No. 4, 5 and 6 has been carried out at a deposition temperature of 500°C and a total pressure of 4 Pa in a nitrogen atmosphere, using the respective target compositions as shown in table 1. All three coatings comprise a first layer (also referred to "layer I" or as layer of type A or as layer A) and a second layer (also referred to "layer II" or as layer of type B or as layer B). Coating No. 4 is a coating according to a first embodiment of the invention. Here, for the first layer four AlCr targets with the composition as shown in table 1 in the X- target column were used, while a low bias voltage between -40 V and -100 V was applied to the sample. This may be constant, or it may be varied. For the second layer, the four AlCr targets and, in addition, two AlCrSiW targets with the composition as shown in table 1 in the Y-target column were used, while a higher bias voltage of -100 V to -200V was applied to the sample. The absolute value of the bias voltage during deposition of the second layer was at least 50 V, or preferably 100 V higher than the bias voltage during deposition of the first layer. The resulting concentration of Al together with the chosen bias leads to a fraction of hexagonal phase in the second layer, as it has been described above for a particular embodiment of the invention in which the second layer (layer B, more precisely layer of type B) comprises at least two cristalline phases (usually cubic and hexagonal). Coating 5 is a coating according to a second embodiment of the invention. Compared to coating No. 4, it has a higher tungsten content, while the aluminum content did not dramatically decrease and still remains well above 60% (see table 1). In contrast to this, coating No. 6 shows an aluminum percentage of 60% or below. No tungsten was used, i.e. the targets did not contain tungsten, see table 1. In this configuration, no hexagonal fraction was realized. The last four columns of table 1 show the results of the different application tests. Application test nr 1 ("appl 1") is defined as follows: Milling conditions: Workpiece (to be milled): DIN 1.2344 (45 HRC) Cutting tool: 4-fluted end-mill, 0 10 mm, micro grain carbide grade Cutting speed: 120 mmin'1 Feed rate: 0.1 mm/tooth Radial depth of cut: 0.5 mm Axial depth of cut: 10 mm Coolant: lubricant 6% emulsion Milling operation: side milling Length of single pass: 15 m End of lifetime: wear measurement after each single pass: criterion for end of lifetime: Vbmax > 120 urn at the end a single pass Application test nr 2 ("appl 2") is defined as follows: Milling conditions: Workpiece (to be milled): DIN 1.1191 (190 HB) Cutting tool (coated): 4-fluted end-mill, 0 10 mm, micro grain carbide grade Cutting speed: 400 mmin"1 Feed rate: 0.2 mm/tooth Radial depth of cut: 0.5 mm Axial depth of cut: 10 mm Coolant: dry cutting Milling operation: side milling Length of single pass: 50 m End of lifetime: wear measurement after each single pass: criterion for end of lifetime: vbmax > 120 urn at the end a single pass Application test nr 3 ("appl 3") is defined as follows: Milling conditions: Workpiece (to be milled) : DIN GGG50 Cutting tool (coated): 2-fluted drills, 0 6 mm, micro grain carbide grade Cutting speed: 120 mmin"1 Feed rate: 0.25 mm/tooth Depth of cut: 6 x diameter Coolant: internal cooling - lubricant 6% emulsion Milling operation: drilling Length of single pass: 200 holes End of lifetime: wear measurement after each single pass: criterion for end of lifetime: Vbmax > 250 pm at the end a single pass Application test nr 4 ("appl 4") is defined as follows: Milling conditions: Workpiece (to be milled): DIN 1.2344 (52 HRC) Cutting tool (coated): 2-fluted ballnose endmill, 0 10 mm, micro grain carbide grade Cutting speed: 147 mmin"1 Feed rate: 0.15 mm/tooth Radial depth of cut: 4 mm Axial depth of cut: 0.8 mm Coolant: compressed air Milling operation: side milling Length of single pass: 15 m End of lifetime: wear measurement after each single pass: criterion for end of lifetime: Vbmax > 200 urn at the end a single pass Vbmax represents, as common in the art, the maximum allowable flank wear. As can be seen from the last four columns of table 1, the coatings 4 and 5 show the best and the second best results in all four application tests. Accordingly, these coatings are not only applicable in a broad range of applications, but can also be deposited on a variety of workpieces. Furthermore, as can be seen from the columns in table 1 related to the first application test, third test and forth test, the non-prior-art coatings provide significantly better results than prior art coatings. It is to be noted, that the coating time required for preparing coatings No. 4 and 5 (namely 270min) is significantly below the time required for preparing coating No. 2 (340min) and No. 3 (410min) and well within the range of the coating time of coating No. 1 (namely 240min). This is basically due to the concurrent use of different targets as done for the second layer (layer B, referred to as layer II in table 1). Targets X can be active during the whole deposition process (at least as long as a layer I (layer A) or a layer II (layer B) is deposited), whereas targets Y are activated (in addition to the targets X) only when a layer II (layer B) is deposited. Fig. 1 shows an SEM (scanning electron microscopy) image showing the structure of a coating according to an embodiment of the present invention. As can be seen, the overall thickness of the coating system in Fig. 1 is about 3 um, and the thickness ratio of layer A to layer B is about 2. Fig. 2 shows XRD (X-ray diffraction) patterns of single layers of type A and type B, respectively. The hexagonal phase shows peaks with lower intensity but higher mean indicating the lower grain size of hexagonal crystal grains. Fig. 3 shows a schematized detail of an exemplary configured vacuum deposition chamber, in a top view. Six targets are indicated, two of type Y and four of type X. Workpieces to be coated are located on a sample carousel symbolized by the circle and the circular arrow. The six workpieces are schematically shown as rectangles. Such a configuration is suitable for manufacturing coatings such as coatings No. 4, 5 or 6 discussed above. Fig. 4 shows, in the manner of Fig. 3, a schematized detail of an exemplary configured vacuum deposition chamber, in a top view. Fig. 5 shows a layer structure of a coating system. The coating system consists of a layer of type A deposited on a substrate (dashed in Fig. 5) and a layer of type B deposited on said layer of type A, as is the case for the coatings No. 4, 5, and 6 discussed above (cf. table 1). Note also that layer A is thicker than layer B. For depositing layer A, targets of type X are activated, and for depositing layer B, said targets of type X and, in addition, targets of type Y are activated, cf. also Figs. 3 and 4. Furthermore, it is possible, when using two types X and Y of targets, to deposit also a third type of layer, namely a layer of type C, which is deposited using solely one or more targets of type Y. Such a layer could, e.g., be arranged between layer A and the substrate such as to form, e.g., an adhesion layer, or it could be deposited on top of layer B, such as to form a top layer, e.g., a decorative top layer. Fig. 6 shows a layer structure of a coating system. In this case, the coating system is a multilayer system with six layers, consisting of three pairs of a layer of type A and a layer of type B each; one layer A and one layer B forming one layer period which repeatedly occurs. It is possible, as shown in Fig. 6, to provide that in each layer period, the thickness of the layer A is greater than the thickness of the layer B. Fig. 7 shows a layer structure of a coating system. In this case, three layers are provided on the substrate. One layer B is sandwiched between two layers A. Fig. 8 shows, in the manner of Figs. 3 and 4, a schematized detail of an exemplary configured vacuum deposition chamber, in a top view. In this case, three types of targets are provided: type X, type Y, type Z. This allows to deposit three different layer types or even four different layer types while using two or all three target types at least partially simultaneously. Considering also using each target type alone, it is possible to deposit up to seven different layer types; and considering activating and deactivating one or more targets of the same type, even more different layer types can be deposited. In a simple case, a configuration as shown in Fig. 8 can be used for depositing a coating system as shown in Fig. 9. Fig. 9 shows a layer structure of a coating system, comprising an additional top layer (e.g., a decorative top layer), as can be deposited in a vacuum deposition chamber configured as shown in Fig. 8. E.g., for depositing layer A, only targets X are activated; for depositing layer B, targets X and, in addition, targets Y are activated; and for depositing layer D, e.g., only targets Z are activated, or some combination of target Z with one or more targets of one or both other target types. Patent-Claims: 1. Coating system, comprising — at least one layer of type A, a layer of type A substantially consisting of (AlyCri_y)X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y describing the stoichiometric composition of the metallic phase fraction; — at least one layer of type B, a layer of type B substantially consisting of (AluCri-u-v-wSivMew)X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts one of the group consisting of W, Nb, Mo and Ta or a mixture of two or more of the constituents of that group, u, v and w describing the stoichiometric composition of the metallic phase fraction; wherein a thickness ratio of said layer of type A to said layer of type B is higher than 1. 2. The coating system according to claim 1, wherein said thickness ratio is higher than about 1.5. 3. The coating system according to claim 1 or claim 2, said at least one layer of type B comprising at least two crystalline phases. 4. The coating system according to one of the preceding claims, said at least one layer of type B comprising a cubic phase and a hexagonal phase. 5. The coating system according to claim 4, a content of said at least one layer of type B of said hexagonal phase is 6. The coating system according to claim 4 or claim 5, wherein a content of said at least one layer of type B of said hexagonal phase is > 5 % by volume of said at least one layer of type B and one layer of type B. 7. The coating system according to one of the preceding claims, said at least one layer of type A substantially being of cubic structure. 8. The coating system according to one of the preceding claims, wherein 0.5 9. The coating system according to one of the preceding claims, wherein 0.5 0.002 10. The coating system according to one of the preceding claims, wherein said at least one layer of type B is deposited directly onto said at least one layer of type A. 11. The coating system according to one of the preceding claims, comprising a layer of type B sandwiched between a first layer of type A and a second layer of type A. 12. The coating system according to one of the preceding claims, comprising multiple layer periods, wherein one such layer period is formed by one layer of type A and one layer of type B. 13. Workpiece, comprising a coating system according to one of the preceding claims. 14. The workpiece according to claim 13, wherein said workpiece is at least one of the group consisting of — a tool; — a machining tool; — a milling tool; — a cutting tool; — a turning tool; — a tapping tool; — a threading tool; — a reamer; — an end mill; — a drill; — a cutting insert; — a gear cutting tool; — an insert; — a hob; — a clearing tool; — an insert for turning and milling. 15. The workpiece according to claim 13 or claim 14, said workpiece having a body substantially made of at least one of the group consisting of — a ferrous metal; — non-ferrous metal; — a composite material; — a cemented carbide; — a cermet; — a cubic boron nitride; — a ceramic material; — a steel; — a high speed steel. 16. Method for manufacturing a coated workpiece, comprising the steps of a) depositing on said workpiece at least one layer of a type A; and b) depositing on said workpiece at least one layer of a type B different from said type A; wherein — said at least one layer of a type A is deposited using nx targets of a type X; and — said at least one layer of a type B is deposited using nY targets of a type Y different from said type X and simultaneously using nXy targets of said type X; wherein nX/ nY, and nXy are integers ^ 1, and at least one of said targets of said type X is active during both, step a) and step b). 17. The method according to claim 16, wherein — a layer of type A substantially consists of (AlyCri-y)X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y describing the stoichiometric composition of the metallic phase fraction; and — a layer of type B substantially consists of (AluCri-u-v-wSivMew)X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts one of the group consisting of W, Nb, Mo and Ta or a mixture of two or more of the constituents of that group, u, v and w describing the stoichiometric composition of the metallic phase fraction. 18. The method according to claim 17, wherein a thickness ratio of said layer of type A to said layer of type B is higher than 1, in particular higher than about 1.5. 19. The method according to claim 17 or claim 18, wherein a target of said type X comprises Al and Cr, and a target of type Y comprises Al, Cr, Si and said Me provided in said layer of type B. 20. The method according to one of claims 16 to 19, wherein steps a) and b) are carried out using a physical vapor deposition process, in particular a cathodic arc evaporation process. 21. The method according to one of claims 16 to 20, comprising holding said workpiece at a temperature below approximately 650°C, in particular at or below approximately 500°C, during carrying out steps a) and b). 22. The method according to one of claims 16 to 21, comprising exposing said workpiece to a reactive gas atmosphere with a total gas pressure between 0.5 Pa and 10 Pa, in particular > 2Pa, during carrying out steps a) and b) . 23. The method according to claim 23, said reactive gas atmosphere comprising predominantly N. 24. The method according to one of claims 16 to 23, comprising applying a bias voltage between 40 V and 200 V to said workpiece during carrying out steps a) and b). 25. The method according to one of claims 16 to 24, comprising applying a bias voltage to said workpiece during carrying out step a) and applying a lower bias voltage to said workpiece during carrying out step b). The coating system comprises: at least one layer of type A, a layer of type A substantially consisting of (AlyCrl-y) X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y describing the stoichiometric composition of the metallic phase fraction; and at least one layer of type B, a layer of type B substantially consisting of (AluCr1-u- v-wSivMew) X, wherein X depicts one of the group consisting of N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts one of the group consisting of W, Nb, Mo and Ta or a mixture of two or more of the constituents of that group, u, v and w describing the stoichiometric composition of the metallic phase fraction. A thickness ratio of said layer of type A to said layer of type B is higher than 1. The workpiece comprises such a coating system. Through this, an excellent wear-protection is provided, and the coating system and workpieces can be used for a broad range of different applications. The coating system can be deposited very efficiently in a PVD process using two types of targets, wherein targets of one type are active during depositing a layer of type A and during depositing a layer of type B.

Full Text

COATING SYSTEM, COATED WORKPIECE AND METHOD FOR MANUFACTURING THE
SAME
Technical Field
The invention relates to the field of coated workpieces and the
manufacture thereof. More particularly, it relates to wear
protection of workpieces by wear protective coatings and to the
deposition of such coatings.
Background of the Invention
TiAIN coatings are widely used as physical vapor deposition (PVD)
coatings for wear protective applications. The AlCrN system is
reported to exhibit superior mechanical properties such as
hardness and hot hardness, thermal and tribological properties
resulting in superior application lifetime of coated parts. As
commonly understood in the art, stoichiometric indices are not
explicitely quoted, e.g., AlCrN stands, more precisely, for
(AlyCr1_y)N (0 US 7 226 670 discloses a workpiece coated with a system of film
layers comprising at least one film composed of (AlyCri_y)X where
[ = N, C, B, CN, BN, CBN, NO, CO, BO, CNO, BNO or BNCO, the
Irorkpiece being a milling tool, a hob, a ball nose mill, a planar
or a profiling cutter, a clearing tool, a reamer, an insert for
turning and milling, a die or an injection mold, showing a
superior wear protective performance.
US 7 348 074 discloses coating concepts consisting of a
multilayer structure with 10 layer packets. These concepts show
good protective performance in drilling applications.
US patent application US 2008/0229891 discloses a multilayered
coating which comprises at least one layer A comprising as
material (TiAl)X, where X = N, CN, CNO or NO, or of (AlCr)X,
where X = N, CN, CNO or NO, and comprising at least one layer B
with (AlCrSiMe)X where X = N, CN, CNO or NO, wherein Me stands
f,or Nb, Mo, Ta or W..
Furthermore, said US 2008/0229891 discloses that the layer
structure of said at least one layer B is designed to consist of
at least of two different crystalline phases. This could be for
example a cubic and a hexagonal phase fraction.
In said US 2008/0229891, it is further disclosed that the
thickness ratio between layer A and layer B is an important issue
in the sense that coatings with thickness ratios of layer A to
layer B above 1 seem to exhibit inferior performance.
All these prior art coatings show good wear protective
performance for more or less special applications. It remains
therefore a need to provide a wear protective coating for a broad
range of different applications.
ummary of the Invention
Therefore, one object of the invention is to create a coating
system that does not have the disadvantages mentioned above. In
particular, a coating system shall be provided, which can be used
for a broad range of different applications. In addition, the
respective coated workpiece and the corresponding method for
manufacturing such a workpiece shall be provided.
Another object of the invention is to provide a coating system, a
correspondingly coated workpiece and a method for manufacturing
such a workpiece providing improved wear protective and/or wear
resistant properties.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece which provide an
increased tool lifetime for a very broad range of applications.
Therein, said applications may comprise continuous and
interrupted cutting applications including, but not limited to
drilling, milling, reaming, turning, tapping, threading and
hobbing applications.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece, wherein said
workpieces are workpieces for machining parts which can be made
of various materials such as, e.g., ferrous and non-ferrous
metals as well as composite materials.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece, wherein said
workpieces may be used under various working conditions, such as,
lor example, dry cutting, cutting with emulsion and/or liquid
coolants, cutting with minimal quantity lubrication (MQL) and
cutting with gaseous coolants.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece, wherein said workpiece
is a drill, an endmill, an insert, or a hob.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece, wherein said workpiece
substrate is substantially made of steel, in particular high-
speed steel, cemented carbide, cubic boron nitride, cermet or a
ceramic material.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece, wherein said workpiece
is suitable for application in machining of at least one of,
preferably most of: ferrous and nonferrous materials, preferably
hardened steel, annealed steel, alloyed steel, low carbon steel,
stainless steel, titanium-based alloys, nickel-based alloys and
composite materials.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece, wherein the coating
shall have superior mechanical and thermal properties, in
particular with respect to hardness, hot hardness and oxidation
resistance.
Another object of the invention is to provide a coating system
for coating a workpiece, a correspondingly coated workpiece and a
method for manufacturing such a workpiece, wherein the coating
shall provide superior protection of the work piece at low and
*?iigh temperature application conditions.
Another object of the invention is to provide a method for
manufacturing a coated workpiece, in particular a workpiece as
mentioned above, which can be carried out particulary time-
efficiently.
Another object of the invention is to provide a method for
manufacturing a coated workpiece, in particular a workpiece as
mentioned above, which is particulary simple to carry out.
Further objects emerge from the description and embodiments
below.
At least one of these objects is at least partially achieved by
coating systems, workpieces and/or methods according to the
patent claims.
The coating system is a multilayer coating comprising at least
one layer A essentially consisting of (AlyCri_y)X, wherein X = N,
CN, BN, NO, CNO, CBN, BNO or GNBO, and y describes the
stoichiometric composition of the metallic phase fraction. Said
multilayer coating further is proposed to comprise at least one
layer B essentially consisting of (AluCri-u-v-wSivMew)X, wherein X =
N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me = W, Nb, Mo,
Ta or a mixture thereof, and wherein u, v, w describe the
stoichiometric composition of the metallic phase fraction.
Through this, a wear-protective coating system can be provided,
which can be used for a broad range of different applications.
•
Index y stands, more precisely and as agreed in the art, for a
number with 0 the art, u is a number with 0 0 u + v + w = 1. Furthermore, more precisely and as agreed in the
art, the stoichiometric value of X is always 1, i.e. in case X
^comprises more than one chemical element, the sum of the
stoichiometric indices of these elements is one, e.g., in case of
X = BNO, X depicts Bi_a_bNaOb (and 0 In one embodiment, a thickness ratio of layer A to layer B higher
than 1, and more preferably higher than about 1.5 is realized.
Through this, particularly good wear-protection can be achieved.
A thicker layer of type A in combination with a thinner layer of
type B yields excellent results.
In one embodiment which may be combined with one or more of the
before-addressed embodiments, said at least one layer of type B
is designed to comprise at least two crystalline phases, more
particularly said at least one layer of type B substantially
comprises exactly two crystalline phases.
In this embodiment, a first crystalline phase of said at least
one layer of type B is a cubic phase and the second crystalline
phase of said at least one layer of type B is a hexagonal phase.
In this case, in a special embodiment, the hexagonal phase
content is of type B, and more particularly amounts to between 5% and 40%.
In one embodiment which may be combined with one or more of the
before-addressed embodiments, said at least one layer of type A
essentially is of cubic structure.
In one embodiment which may be combined with one or more of the
before-addressed embodiments, the stoichiometric composition of
the metallic fraction of said at least one layer of type A is
characterized by 0.5 In one embodiment which may be combined with one or more of the
before-addressed embodiments, the stoichiometric composition of
the metallic fraction of said at least one layer of type B is
^characterized by 0.5 ^K).OO2 In one embodiment which may be combined with one or more of the
before-addressed embodiments, a layer of type B is directly
deposited onto a layer of type A.
In one embodiment which may be combined with one or more of the
before-addressed embodiments, a layer of type B is sandwiched
between a first layer of type A and a second layer of type A.
In one embodiment which may be combined with one or more of the
before-addressed embodiments, a layer of type A and a layer of
type B form a period, and said coating system is a coating system
with mulitple such periods.
In one embodiment which may be combined with one or more of the
before-addressed embodiments, said coating system comprises
another layer, in particular said other layer forming a
functional layer. E.g., said other layer being an adhesion layer,
more particularly deposited directly onto a substrate, and in
particular immediately below the first layer of type A; or, e.g.,
said other layer being a top layer, i.e. the layer is deposited
as last layer, in particular is a decorative top layer.
The workpiece according to the invention comprises a coating
system according to the invention. The workpiece benefits from
the advantages of the coating system in an analogous way.
In one embodiment (which actually is an enumeration of various
possible embodiments), said workpiece is at least one of the
group consisting of: a tool, a machining tool, a milling tool, a
cutting tool, a turning tool, a tapping tool, a threading tool, a
reamer, an end mill, a drill, a cutting insert, a gear cutting
tool, an insert, a hob, a clearing tool, an insert for turning
and milling.
In one embodiment which may be combined with one or more of the
fcfcefore-addressed embodiments (and which actually is an
enumeration of various possible embodiments), said workpiece has
a body substantially made of at least one of the group consisting
of: a ferrous metal, non-ferrous metal, a composite material, a
cemented carbide, a cermet, a cubic boron nitride, a ceramic
material, a steel, a high speed steel.
In one aspect, the invention comprises a method for manufacturing
a coated workpiece, more particularly, a PVD (physical vapor
deposition) process which allows to synthesize a coating system,
more particularly a coating system according to the invention,
not only in separate deposition processes but also within one
deposition process.
The method for manufacturing a coated workpiece comprises the
steps of
a) depositing on said workpiece at least one layer of a type A;
and
b) depositing on said workpiece at least one layer of a type B
different from said type A;
wherein
— said at least one layer of a type A is deposited using nx
targets of a type X; and
— said at least one layer of a type B is deposited using nY
targets of a type Y different from said type X and
simultaneously using nXy targets of said type X;
wherein nx, nY, and nXy are integers ^ 1, and at least one of said
targets of said type X is active during both, step a) and
step b). This way, significantly reduced deposition times can be
realized. One or more targets can be active during both, the
deposition of a layer of type B and the deposition of a layer of
^*£ype A. This can also be advantageous in terms of process
stability. The deposition can be carried out in little time, and
the depositing steps can be carried out in the same vacuum
chamber without breaking the vacuum.
In one embodiment, nx ^ nxy applies.
In one embodiment, nx = nXy applies. In this case, all targets of
type X active during depositon of said at least one layer of
type A are also active during depositon of said at least one
layer of type B.
In one embodiment of the method which may be combined with one or
more of the before-addressed method embodiments, a layer of
type A substantially consists of (AlyCri-y)X, wherein X depicts one
of the group consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO,
y describing the stoichiometric composition of the metallic phase
fraction; and a layer of type B substantially consists of
(AluCri_u_v_wSivMew)X, wherein X depicts one of the group consisting
of N, CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts
one of the group consisting of W, Nb, Mo and Ta or a mixture of
two or more of the constituents of that group, u, v and w
describing the stoichiometric composition of the metallic phase
fraction.
In one embodiment of the method which may be combined with one or
more of the before-addressed method embodiments, a thickness
ratio of said layer of type A to said layer of type B is higher
than 1, in particular higher than about 1.5. In other words,
steps a) and b) are carried out such that a thickness of the
layer of type A is larger, in particular larger by a factor of
more than about 1.5, than a thickness of the layer of type B.
In one embodiment of the method which may be combined with one or
^ftore of the before-addressed method embodiments, a target of said
type X comprises Al and Cr, and a target of type Y comprises Al,
Cr, Si and said Me provided in said layer of type B.
In one embodiment of the method which may be combined with one or
more of the before-addressed method embodiments, steps a) and b)
are carried out using a physical vapor deposition process, in
particular a cathodic arc evaporation process.
In one embodiment of the method which may be combined with one or
more of the before-addressed method embodiments, the deposition
process is characterized by a deposition temperature preferably at or below about 500°C, and/or by a reactive gas
atmosphere comprising predominantly N and/or with a total gas
pressure situated between 0.5 and 10 Pa, preferably > 2Pa, and/or
by a bias voltage of between 40 and 200 V and/or where the bias
voltage during the deposition of said at least one layer of type
A is lower than during the deposition of said at least one
layer of type B in the multilayered structure.
The invention comprises methods with features of corresponding
coating systems and workpieces according to the invention, and
vice versa.
The advantages of the methods correspond to the advantages of
corresponding coating systems and workpieces and vice versa.
Further embodiments and advantages emerge from the dependent
claims and the figures.
Brief Description of the Drawings
Below, the invention is described in more detail by means of
examples and the included drawings. The figures show:
Fig. 1 an SEM (scanning electron microscopy) image showing the
structure of a coating according to an embodiment of th
present invention;
Fig. 2 XRD (X-ray diffraction) patterns of single layers of
type A and type B, respectively;
Fig. 3 a schematized detail of an exemplary configured vacuum
deposition chamber, in a top view;
Fig. 4 a schematized detail of an exemplary configured vacuum
deposition chamber, in a top view;
Fig. 5 a layer structure of a coating system;
Fig. 6 a layer structure of a coating system;
Fig. 7 a layer structure of a coating system;
Fig. 8 a schematized detail of an exemplary configured vacuum
deposition chamber, in a top view;
Fig. 9 a layer structure of a coating system, comprising an
additional top layer (e.g., a decorative top layer), as
can be deposited in a vacuum deposition chamber
configured as shown in Fig. 8.
The reference symbols used in the figures and their meaning are
summarized in the list of reference symbols. The described
embodiments are meant as examples and shall not confine the
invention.
etailed Description of the Invention
In the following, the invention will be explained more closely in
conjunction with some application examples.
As mentioned above, it is one possible object of the present
invention to present a coating system (or shortly a "coating")
showing excellent protective wear resistance for a very broad
range of applications. In order to demonstrate the superiority of
coatings according to the invention over prior art coatings, we
firstly introduce a number of prior art coatings together with a
number of different coatings according to the invention by
describing how they are produced.
Then we will discuss different application examples with highly
differing machining conditions representing applications such as
for example drilling or milling of soft, annealed or hard
material, and discuss the performance of the coatings according
to the invention as compared to the prior art coatings.
All of the following coatings have been synthesized using
cathodic arc evaporation in an arc evaporation equipment. The
workpieces are placed into a chamber (vacuum chamber) of suitable
arc evaporation equipment. In such a coating equipment, targets
are used as for example those shown in table 1.
Table 1 indicates for each of six samples (coatings) the
elemental composition (in atomic percent) of the targets used and
the elemental composition of respectively deposited layers.
Finally, table 1 shows application test results for four
different applications (appl 1 to appl 4).
Layer thicknesses are in the usual thickness range for wear-
protective coatings. The overall thickness of the coating system
will usually not exceed about 20 urn.
Samples No. 1, 2 and 3 are coatings as known in the art.
Prior art coating No. 1 describes a monolayer of AlCrN
deposited with six equal AlCr targets with the composition
of 70% Al and 30% Cr as shown in table 1. The deposition
was conducted in a pure N2-atmosphere at a gas pressure of
3.5 Pa and a bias voltage of -40 to -100V at 500°C at the
substrate.
Prior art coating No. 2 was, differing from example No. 1,
conducted using four AlCr targets and two TiSi targets. The
compositions of the targets are shown in table 1. The
evaporation was conducted in a pure N2-atmosphere at a
pressure of 3.5 Pa and a bias voltage of -40V at about
500°C at the substrate. Prior art coating No. 2 was
synthesized as a multilayered coating having a bottom layer
of AlCrN followed by 10 layer packages (AlCrN, TiSiN,
AlCrTiSiN) and a TiSiN top layer.
Prior art coating No. 3 was deposited using four AlCrSiW
targets and two TiAl targets with the compositions
mentioned in the corresponding line in table 1. Firstly, a
TiAIN support layer was deposited which was followed by an
AlCrSiWN main layer. The thickness relation between the
main layer and the support layer is in the range of
1 : 2.5. The evaporation was conducted in a pure N2
atmosphere at 3.5 Pa, and the bias voltage was adjusted
between -40V and -100V at about 600°C at the substrate.
The deposition of the coatings No. 4, 5 and 6 has been
carried out at a deposition temperature of 500°C and a
total pressure of 4 Pa in a nitrogen atmosphere, using the
respective target compositions as shown in table 1. All
three coatings comprise a first layer (also referred to
"layer I" or as layer of type A or as layer A) and a second
layer (also referred to "layer II" or as layer of type B or
as layer B).
Coating No. 4 is a coating according to a first embodiment
of the invention. Here, for the first layer four AlCr
targets with the composition as shown in table 1 in the X-
target column were used, while a low bias voltage between
-40 V and -100 V was applied to the sample. This may be
constant, or it may be varied. For the second layer, the
four AlCr targets and, in addition, two AlCrSiW targets
with the composition as shown in table 1 in the Y-target
column were used, while a higher bias voltage of -100 V to
-200V was applied to the sample. The absolute value of the
bias voltage during deposition of the second layer was at
least 50 V, or preferably 100 V higher than the bias
voltage during deposition of the first layer. The resulting
concentration of Al together with the chosen bias leads to
a fraction of hexagonal phase in the second layer, as it
has been described above for a particular embodiment of the
invention in which the second layer (layer B, more
precisely layer of type B) comprises at least two
cristalline phases (usually cubic and hexagonal).
Coating 5 is a coating according to a second embodiment of
the invention. Compared to coating No. 4, it has a higher
tungsten content, while the aluminum content did not
dramatically decrease and still remains well above 60% (see
table 1).
In contrast to this, coating No. 6 shows an aluminum
percentage of 60% or below. No tungsten was used, i.e. the
targets did not contain tungsten, see table 1. In this
configuration, no hexagonal fraction was realized.
The last four columns of table 1 show the results of the
different application tests.
Application test nr 1 ("appl 1") is defined as follows:
Milling conditions:
Workpiece (to be milled): DIN 1.2344 (45 HRC)
Cutting tool: 4-fluted end-mill, 0 10 mm, micro
grain carbide grade
Cutting speed: 120 mmin'1
Feed rate: 0.1 mm/tooth
Radial depth of cut: 0.5 mm
Axial depth of cut: 10 mm
Coolant: lubricant 6% emulsion
Milling operation: side milling
Length of single pass: 15 m
End of lifetime: wear measurement after each
single pass: criterion for end of
lifetime: Vbmax > 120 urn at the
end a single pass
Application test nr 2 ("appl 2") is defined as follows:
Milling conditions:
Workpiece (to be milled): DIN 1.1191 (190 HB)
Cutting tool (coated): 4-fluted end-mill, 0 10 mm, micro
grain carbide grade
Cutting speed: 400 mmin"1
Feed rate: 0.2 mm/tooth
Radial depth of cut: 0.5 mm
Axial depth of cut: 10 mm
Coolant: dry cutting
Milling operation: side milling
Length of single pass: 50 m
End of lifetime: wear measurement after each
single pass: criterion for end of
lifetime: vbmax > 120 urn at the
end a single pass
Application test nr 3 ("appl 3") is defined as follows:
Milling conditions:
Workpiece (to be milled) : DIN GGG50
Cutting tool (coated): 2-fluted drills, 0 6 mm, micro
grain carbide grade
Cutting speed: 120 mmin"1
Feed rate: 0.25 mm/tooth
Depth of cut: 6 x diameter
Coolant: internal cooling - lubricant 6%
emulsion
Milling operation: drilling
Length of single pass: 200 holes
End of lifetime: wear measurement after each
single pass: criterion for end of
lifetime: Vbmax > 250 pm at the
end a single pass
Application test nr 4 ("appl 4") is defined as follows:
Milling conditions:
Workpiece (to be milled): DIN 1.2344 (52 HRC)
Cutting tool (coated): 2-fluted ballnose endmill,
0 10 mm, micro grain carbide
grade
Cutting speed: 147 mmin"1
Feed rate: 0.15 mm/tooth
Radial depth of cut: 4 mm
Axial depth of cut: 0.8 mm
Coolant: compressed air
Milling operation: side milling
Length of single pass: 15 m
End of lifetime: wear measurement after each
single pass: criterion for end of
lifetime: Vbmax > 200 urn at the
end a single pass
Vbmax represents, as common in the art, the maximum
allowable flank wear.
As can be seen from the last four columns of table 1, the
coatings 4 and 5 show the best and the second best results
in all four application tests. Accordingly, these coatings
are not only applicable in a broad range of applications,
but can also be deposited on a variety of workpieces.
Furthermore, as can be seen from the columns in table 1
related to the first application test, third test and forth
test, the non-prior-art coatings provide significantly
better results than prior art coatings.
It is to be noted, that the coating time required for
preparing coatings No. 4 and 5 (namely 270min) is
significantly below the time required for preparing coating
No. 2 (340min) and No. 3 (410min) and well within the range
of the coating time of coating No. 1 (namely 240min). This
is basically due to the concurrent use of different targets
as done for the second layer (layer B, referred to as layer
II in table 1). Targets X can be active during the whole
deposition process (at least as long as a layer I (layer A)
or a layer II (layer B) is deposited), whereas targets Y
are activated (in addition to the targets X) only when a
layer II (layer B) is deposited.
Fig. 1 shows an SEM (scanning electron microscopy) image
showing the structure of a coating according to an
embodiment of the present invention. As can be seen, the
overall thickness of the coating system in Fig. 1 is about
3 um, and the thickness ratio of layer A to layer B is
about 2.
Fig. 2 shows XRD (X-ray diffraction) patterns of single
layers of type A and type B, respectively. The hexagonal
phase shows peaks with lower intensity but higher mean
indicating the lower grain size of hexagonal crystal
grains.
Fig. 3 shows a schematized detail of an exemplary
configured vacuum deposition chamber, in a top view. Six
targets are indicated, two of type Y and four of type X.
Workpieces to be coated are located on a sample carousel
symbolized by the circle and the circular arrow. The six
workpieces are schematically shown as rectangles. Such a
configuration is suitable for manufacturing coatings such
as coatings No. 4, 5 or 6 discussed above.
Fig. 4 shows, in the manner of Fig. 3, a schematized detail
of an exemplary configured vacuum deposition chamber, in a
top view.
Fig. 5 shows a layer structure of a coating system. The
coating system consists of a layer of type A deposited on a
substrate (dashed in Fig. 5) and a layer of type B
deposited on said layer of type A, as is the case for the
coatings No. 4, 5, and 6 discussed above (cf. table 1).
Note also that layer A is thicker than layer B. For
depositing layer A, targets of type X are activated, and
for depositing layer B, said targets of type X and, in
addition, targets of type Y are activated, cf. also Figs. 3
and 4. Furthermore, it is possible, when using two types X
and Y of targets, to deposit also a third type of layer,
namely a layer of type C, which is deposited using solely
one or more targets of type Y. Such a layer could, e.g., be
arranged between layer A and the substrate such as to form,
e.g., an adhesion layer, or it could be deposited on top of
layer B, such as to form a top layer, e.g., a decorative
top layer.
Fig. 6 shows a layer structure of a coating system. In this
case, the coating system is a multilayer system with six
layers, consisting of three pairs of a layer of type A and
a layer of type B each; one layer A and one layer B forming
one layer period which repeatedly occurs. It is possible,
as shown in Fig. 6, to provide that in each layer period,
the thickness of the layer A is greater than the thickness
of the layer B.
Fig. 7 shows a layer structure of a coating system. In this
case, three layers are provided on the substrate. One
layer B is sandwiched between two layers A.
Fig. 8 shows, in the manner of Figs. 3 and 4, a schematized
detail of an exemplary configured vacuum deposition
chamber, in a top view. In this case, three types of
targets are provided: type X, type Y, type Z. This allows
to deposit three different layer types or even four
different layer types while using two or all three target
types at least partially simultaneously. Considering also
using each target type alone, it is possible to deposit up
to seven different layer types; and considering activating
and deactivating one or more targets of the same type, even
more different layer types can be deposited.
In a simple case, a configuration as shown in Fig. 8 can be
used for depositing a coating system as shown in Fig. 9.
Fig. 9 shows a layer structure of a coating system,
comprising an additional top layer (e.g., a decorative top
layer), as can be deposited in a vacuum deposition chamber
configured as shown in Fig. 8. E.g., for depositing
layer A, only targets X are activated; for depositing
layer B, targets X and, in addition, targets Y are
activated; and for depositing layer D, e.g., only targets Z
are activated, or some combination of target Z with one or
more targets of one or both other target types.
Patent-Claims:
1. Coating system, comprising
— at least one layer of type A, a layer of type A
substantially consisting of (AlyCri_y)X, wherein X
depicts one of the group consisting of N, CN, BN, NO,
CNO, CBN, BNO and CNBO, y describing the
stoichiometric composition of the metallic phase
fraction;
— at least one layer of type B, a layer of type B
substantially consisting of (AluCri-u-v-wSivMew)X,
wherein X depicts one of the group consisting of N,
CN, BN, NO, CNO, CBN, BNO or CNBO, and wherein Me
depicts one of the group consisting of W, Nb, Mo and
Ta or a mixture of two or more of the constituents of
that group, u, v and w describing the stoichiometric
composition of the metallic phase fraction;
wherein a thickness ratio of said layer of type A to said
layer of type B is higher than 1.
2. The coating system according to claim 1, wherein said
thickness ratio is higher than about 1.5.
3. The coating system according to claim 1 or claim 2,
said at least one layer of type B comprising at least two
crystalline phases.
4. The coating system according to one of the preceding
claims, said at least one layer of type B comprising a
cubic phase and a hexagonal phase.
5. The coating system according to claim 4, a content of
said at least one layer of type B of said hexagonal phase
is 6. The coating system according to claim 4 or claim 5,
wherein a content of said at least one layer of type B of
said hexagonal phase is > 5 % by volume of said at least
one layer of type B and one layer of type B.
7. The coating system according to one of the preceding
claims, said at least one layer of type A substantially
being of cubic structure.
8. The coating system according to one of the preceding
claims, wherein 0.5 9. The coating system according to one of the preceding
claims, wherein 0.5 0.002 10. The coating system according to one of the preceding
claims, wherein said at least one layer of type B is
deposited directly onto said at least one layer of type A.
11. The coating system according to one of the preceding
claims, comprising a layer of type B sandwiched between a
first layer of type A and a second layer of type A.
12. The coating system according to one of the preceding
claims, comprising multiple layer periods, wherein one such
layer period is formed by one layer of type A and one layer
of type B.
13. Workpiece, comprising a coating system according to
one of the preceding claims.
14. The workpiece according to claim 13, wherein said
workpiece is at least one of the group consisting of
— a tool;
— a machining tool;
— a milling tool;
— a cutting tool;
— a turning tool;
— a tapping tool;
— a threading tool;
— a reamer;
— an end mill;
— a drill;
— a cutting insert;
— a gear cutting tool;
— an insert;
— a hob;
— a clearing tool;
— an insert for turning and milling.
15. The workpiece according to claim 13 or claim 14, said
workpiece having a body substantially made of at least one
of the group consisting of
— a ferrous metal;
— non-ferrous metal;
— a composite material;
— a cemented carbide;
— a cermet;
— a cubic boron nitride;
— a ceramic material;
— a steel;
— a high speed steel.
16. Method for manufacturing a coated workpiece,
comprising the steps of
a) depositing on said workpiece at least one layer of a
type A; and
b) depositing on said workpiece at least one layer of a
type B different from said type A;
wherein
— said at least one layer of a type A is deposited using
nx targets of a type X; and
— said at least one layer of a type B is deposited using
nY targets of a type Y different from said type X and
simultaneously using nXy targets of said type X;
wherein nX/ nY, and nXy are integers ^ 1, and at least one
of said targets of said type X is active during both,
step a) and step b).
17. The method according to claim 16, wherein
— a layer of type A substantially consists of
(AlyCri-y)X, wherein X depicts one of the group
consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y
describing the stoichiometric composition of the
metallic phase fraction; and
— a layer of type B substantially consists of
(AluCri-u-v-wSivMew)X, wherein X depicts one of the group
consisting of N, CN, BN, NO, CNO, CBN, BNO or CNBO,
and wherein Me depicts one of the group consisting of
W, Nb, Mo and Ta or a mixture of two or more of the
constituents of that group, u, v and w describing the
stoichiometric composition of the metallic phase
fraction.
18. The method according to claim 17, wherein a thickness
ratio of said layer of type A to said layer of type B is
higher than 1, in particular higher than about 1.5.
19. The method according to claim 17 or claim 18, wherein
a target of said type X comprises Al and Cr, and a target
of type Y comprises Al, Cr, Si and said Me provided in said
layer of type B.
20. The method according to one of claims 16 to 19,
wherein steps a) and b) are carried out using a physical
vapor deposition process, in particular a cathodic arc
evaporation process.
21. The method according to one of claims 16 to 20,
comprising holding said workpiece at a temperature below
approximately 650°C, in particular at or below
approximately 500°C, during carrying out steps a) and b).
22. The method according to one of claims 16 to 21,
comprising exposing said workpiece to a reactive gas
atmosphere with a total gas pressure between 0.5 Pa and
10 Pa, in particular > 2Pa, during carrying out steps a)
and b) .
23. The method according to claim 23, said reactive gas
atmosphere comprising predominantly N.
24. The method according to one of claims 16 to 23,
comprising applying a bias voltage between 40 V and 200 V
to said workpiece during carrying out steps a) and b).
25. The method according to one of claims 16 to 24,
comprising applying a bias voltage to said workpiece during
carrying out step a) and applying a lower bias voltage to
said workpiece during carrying out step b).

The coating system comprises: at least one layer of type A, a layer of type A
substantially consisting of (AlyCrl-y) X, wherein X depicts one of the group
consisting of N, CN, BN, NO, CNO, CBN, BNO and CNBO, y describing
the stoichiometric composition of the metallic phase fraction; and at least
one layer of type B, a layer of type B substantially consisting of (AluCr1-u-
v-wSivMew) X, wherein X depicts one of the group consisting of N, CN,
BN, NO, CNO, CBN, BNO or CNBO, and wherein Me depicts one of the
group consisting of W, Nb, Mo and Ta or a mixture of two or more of the
constituents of that group, u, v and w describing the stoichiometric
composition of the metallic phase fraction. A thickness ratio of said layer of
type A to said layer of type B is higher than 1. The workpiece comprises
such a coating system. Through this, an excellent wear-protection is
provided, and the coating system and workpieces can be used for a broad
range of different applications. The coating system can be deposited very
efficiently in a PVD process using two types of targets, wherein targets of
one type are active during depositing a layer of type A and during depositing
a layer of type B.

Documents:

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Patent Number

279287

Indian Patent Application Number

366/KOLNP/2011

PG Journal Number

03/2017

Publication Date

20-Jan-2017

Grant Date

17-Jan-2017

Date of Filing

24-Jan-2011

Name of Patentee

OERLIKON TRADING AG, TRUEBBACH

Applicant Address

HAUPTSTRASSE, CH-9477, TRUEBBACH, SWIZERLAND

Inventors:

#	Inventor's Name	Inventor's Address
1	LECHTHALER, MARKUS	AM BREITEN WASEN 1, A-6800, FELDKIRCH, AUSTRIA

PCT International Classification Number

C23C 14/00

PCT International Application Number

PCT/EP2009/058423

PCT International Filing date

2009-07-03

PCT Conventions:

#	PCT Application Number	Date of Convention	Priority Country
1	61/079,230	2008-07-09	U.S.A.