Title of Invention | "3-HETARYL-PYRROLIDIN -2,4-DIONE COMPOUNDS OF THE FORMULA ( I )" |
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Abstract | 3-hetaryl-pyrrolidin-2,4-dione Compounds of the formula (I) A O-G in which W represents N-D(1), oxygen (2) or sulphur (3), Het represents in each case optionally substituted thiazolyl, oxazolyl or pyrazolyl, A represents hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, saturated or unsaturated optionally substituted cycloalkyl in which optionally at least one ring atom is replaced by a heteroatom, or in each case optionally halogen-, alkyl-, halogenoalkyl, alkoxy-, halogenoalkoxy-, cyano- or nitro-substituted aryl, arylalkyl or hetaryl, B represents hydrogen, alkyl or alkoxyalkyl, or A and B together with the carbon atom to which they are attached represent a saturated or unsaturated unsubstituted or substituted cycle which optionally contains at least one heteroatom, D represents hydrogen or represents an optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, saturated or unsaturated cycloalkyl in which optionally one or more ring members are replaced by heteroatoms, arylalkyl, aryl, hetarylalkyl or hetaryl or A and D together with the atoms to which they are attached represent a saturated or unsaturated cycle which is unsubstituted OT substituted in the A,D moiety and optionally contains at least one heteroatom, G represents hydrogen (a) or represents one of the groups in which E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur, M represents oxygen or sulphur, R1 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen-, alkyl-or alkoxy-substituted cycloalkyl which may be interrupted by at least one heteroatom, in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, R2 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or represents in each case optionally substituted cycloalkyl, phenyl or benzyl, or in the case of Het=thiazolyl ((I-l-A) to (I-3-A)) also represents. |
Full Text | FORM 2 THE PATENTS ACT, 1970 [39 OF 1970] COMPLETE SPECIFICATION [See Section 10; Rule 13] "3-HETARYL-PYRROLIDIN-2,4-DIONE COMPOUNDS OF THE FORMULA (I)" BAYER CROPSCIENCE AG, a German company of Alfred-Nobel-Strasse 50, 40789 Monheim, Germany, The following specification particularly describes the nature of the invention and the manner in which it is to be performed:- 3 JAN 2007 The present invention relates to a 3-hetaryl-pyrrolidin-2,4-dione compounds of the formula (I). The present invention relates to novel hetaryl-substituted heterocycles, to a plurality of processes for their preparation and to their use as pesticides and herbicides. 4-Thiazolyl-3-hydroxy-3-pyrroline-2,5-diones are known as glycolic acid oxidase inhibitors; US 4,296,237; US 4,377,588; EP-A-025 232; Rooney C.S. et al., J. Med. Chem. 26 700-714 (1983); Guzel Y. et al. THEOCHEM 366 131-137 (1996). The present invention provides novel compounds of the formula (I) (I). in which W represents N-D (1). oxygen (2) or sulphur (3), Het represents in each case optionally substituted thiazolyl, oxazolyl or pyrazolyl, A represents hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, saturated or unsaturated optionally substituted cycloalkyl in which optionally at least one ring atom is replaced by a heteroatom, or in each case optionally halogen-, alkyl-, halogenoalkyl, alkoxy-, halogenoalkoxy-, cyano- or nitro-substituted aryl, arylalkyl or hetaryl, B represents hydrogen, alkyl or alkoxyalkyl, or Le A 34 460-Foreign Countries A and B together with the carbon atom to which they are attached represent a saturated or unsaturated unsubstituted or substituted cycle which optionally contains at least one heteroatom, D represents hydrogen or represents an optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, saturated or unsaturated cycloalkyl in which optionally one or more ring members are replaced by heteroatoms, arylalkyl, aryl, hetarylalkyl or hetaryl or A and D together with the atoms to which they are attached represent a saturated or unsaturated cycle which is unsubstituted or substituted in the A,D moiety and optionally contains at least one heteroatom, G represents hydrogen (a) or represents one of the groups E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur, M represents oxygen or sulphur, Le A 34 460-Foreign Countries 10 R1 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen-, alkyl- or alkoxy-substituted cycloalkyl which may be interrupted by at least one heteroatom, in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, R2 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or represents in each case optionally substituted cycloalkyl, phenyl or benzyl, R3 represents alkyl, halogenoalkyl or represents in each case optionally substituted phenyl or benzyl, R4 and R5 independently of one another each represent in each case 15 optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio and represent in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio, 20 R6 and R7 independently of one another each represent hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, represent optionally substituted phenyl, represent optionally substituted benzyl, or together with the N atom to which they are attached represent a cycle which is optionally interrupted by 25 oxygen or sulphur. Depending inter alia on the nature of the substituents, the compounds of the formula (I) can be present as geometrical and/or optical isomers or isomer mixtures in varying composition which may, if desired, be separated in a customary manner. The present 30 invention provides both the pure isomers and the isomer mixtures, their preparation and use, and compositions comprising them. However, hereinbeiow, compounds of Le A 34 460-Foreign Countries the formula (I) are always referred to for the sake of simplicity, although what is meant are both the pure compounds and, if appropriate, also mixtures with varying proportions of isomeric compounds. 5 Including W = N-D^\ oxygen^2) or sulphur^3), the following principal structures (I- 1) to (1-3) result: in which 10 A, B, D and G are each as defined above and Het represents thiazolyl or oxazolyl. 15 Including the various meanings of Het, the following principal structures result: (I-l-A) to (I-3-B) if W represents N-D(1), oxygen(2) or sulphur (3) Le A 34 460-Foreign Countries in which A, B, D and G are each as defined above and X represents hydrogen, halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkenyloxy, haloalkenyloxy, nitro, cyano or optionally substituted phenyl, 10 represents halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphoxinyl, alkylsulphonyl or represents in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio. 15 Including the various meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-l-A-a) to (I-l-A-g) result if W represents N-D(1) Le A 34 460-Foreign Countries in which A, B, D, E, L, M, X, Y, R1, R2, R3, R4, R5, R6 and R7 are each as defined above. Le A 34 460-Foreign Countries Including the various meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-l-B-a) to (I-l-B-g) result if W represents N-D(1) Le A 34 460-Foreign Countries A, B, D, E, L, M, X, Y, Rl, R2, R3, R45 R5> R6 and R7 ^ each as defined above. 5 Including the various meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-2-A-a) to (I-2-A-g) result if W represents oxygen^2) Le A 34 460-Foreign Countries in which A, B, E, L, M, X, Y, R1, R2, R3, R4, R5, R6 and R7 are each as defined above. Including the various meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-2-B-a) to (I-2-B-g) result if W represents oxygen(2) in which A, B, E, L, M, X, Y, Rl, R2, R3, R4, R5, R6 and R7 are each as defined above. Including the various meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-3-A-a) to (I-3-A-g) result if W represents sulphur (3) Le A 34 460-Foreign Countries in which 5 A, B, E, L, M, X, Y, R1, R2, R3, R4, R5, R6 and R7 and each as defined above. Le A 34 460-Foreign Countries Including the various meanings (a), (b), (c), (d), (e), (f) and (g) of the group G, the following principal structures (I-3-B-a) to (I-3-B-g) result if W represents sulphur (3) Le A 34 460-Foreign Countries in which A, B, E, L, M, X, Y, R1, R2, R3, R4, R5, R6 and R7 are each as defined above. 5 Furthermore, it has been found that the novel compounds of the formula (I) are obtained by one of the processes described below: (A) Substituted 3-hetaryl-pyrrolidine-2,4-diones or enols thereof of the formulae (I-l-A-a) to (I-l-B-a) 10 15 in which A, B, D and Het are each as defined above are obtained when N-acylamino acid esters of the formula (II) 20 in which A, B, D and Het are each as defined above Le A 34 460-Foreign Coiffltries and R8 represents alkyl (preferably Ci-Cg-alkyl) are condensed intramolecularly in the presence of a diluent and in the presence of a base* (B) Moreover, it has been found that substituted 3-hetaryl-4-hydroxy-A3-di-hydrofuranone derivatives of the formulae (I-2-A-a) to (1-2-B-a) (I-2-A-a) to (I-2-B-a) in which A, B and Het are each as defined above are obtained when carboxylic esters of the formula (III) A, B, Het and R8 are each as defined above are condensed intramolecularly in the presence of a diluent and in the presence of a base. Le A 34 460-Foreign Countries (C) Furthermore, it has been found that substituted 3-hetaryl-4-hydroxy-Δ3-di-hydrothiophene-2-one derivatives of the formulae (I-3-A-a) to (I-3-B-a) (I-3-A-a) to (I-3-B-a) in which A, B and Het are each as defined above 10 are obtained when B-ketocarboxylic esters of the formula (IV) (IV) 15 in which A, B, Het and R8 are each as defined above and W1 represents hydrogen, halogen, alkyl (preferably C1-C6-alkyl) or 20 alkoxy (preferably C1-C8-alkoxy) are cyclized intramolecularly, if appropriate in the presence of a diluent and in the presence of an acid. Le A 34 460-Foreign Countries Moreover, it has been found (D) that the compounds of the formulae (I-l-A-b) to (I-3-B-b) shown above, in which A, B, D, R1 and Het are each as defined above, are obtained when 5 compounds of the formulae (I-l-A-a) to (I-3-B-a) shown above, in which A, B, D and Het are each as defined above, are in each case reacted (a) with acyl halides of the formula (V) 10 (V) in which Rl is as defined above and 15 Hal represents halogen (in particular chlorine or bromine) or (6) with carboxylic anhydrides of the formula (VI) 20 RJ-CO-O-CO-R1 (VI) in which 25 R1 is as defined above. if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder; Le A 34 460-Foreign Countries (E) that the compounds of the formulae (I-l-A-c) to (I-3-B-c) shown above, in which A, B, D, R2, M and Het are each as defined above and L represents oxygen, are obtained when compounds of the formulae (I-l-A-a) to (I-3-B-a) shown above, in which A B, D and Het are each as defined above, are in each 5 case reacted with chloroformic esters or chloroformic thioesters of the formula (VII) R2-M-CO-Cl 10 in which R2 and M are each as defined above, 15 if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder; (F) that the compounds of the formulae (I-l-A-c) to (I-3-B-c) shown above, in which A, B, D, R2, M and Het are each as defined above and L represents 20 sulphur, are obtained when compounds of the formulae (I-l-A-a) to (I-3-B-a) shown above, in which A, B, D and Het are each as defined above, are in each case reacted with chloromonothioformic esters or chlorodithioformic esters of the formula 25 (VIII) in which M and R2 are each as defined above, 30 Le A 34 460-Foreign Countries if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder, and (G) that compounds of the formulae (I-l-A-d) to (I-3-B-d) shown above, in which A, B, D, R3 and Het are each as defined above, are obtained when compounds of the formulae (I-l-A-a) to (I-3-B-a) shown above, in which A, B, D and Het are each as defined above, are in each case reacted with sulphonyl chlorides of the formula (IX) R3-S02-C1 (IX) in which R3 is as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder, (H) that compounds of the formulae (I-l-A-e) to (I-3-B-e) shown above, in which A, B, D, L, R4, R5 and Het are each as defined above, are obtained when compounds of the formulae (I-l-A-a) to (I-3-B-a) shown above, in which A, B, D and Het are each as defined above, are in each case reacted with phosphorous compounds of the formula (X) (X) in which Le A 34 460-Foreign Countries L, R4 and R5 are each as defined above and Hal represents halogen (in particular chlorine or bromine), if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder, (I) that compounds of the formulae (I-l-A-f) to (I-3-B-f) shown above, in which A, B, D, E and Het are each as defined above, are obtained when compounds of the formulae (I-l-A-a) to (I-3-B-a), in which A, B, D and Het are each as defined above, are in each case reacted with metal compounds or amines of the formula (XI) or (XII) in which Me represents a mono- or divalent metal (preferably an alkali metal or alkaline earth metal, such as lithium, sodium, potassium, magnesium or calcium), t represents the number 1 or 2 and Rl0, Rl1, Rl2 independently of one another each represent hydrogen or alkyl (preferably C1-C8-alkyl), if appropriate in the presence of a diluent, Le A 34 460-Foreign Countries (J) that compounds of the formulae (I-l-A-g) to (I-3-B-g) shown above, in which A, B, D, L, R6, R7 and Het are each as defined above, are obtained when compounds of the formulae (I-l-A-a) to (I-3-B-a) shown above, in which A, B, D and Het are each as defined above, are in each case reacted (a) with isocyanates or isothiocyanates of the formula (XIII) R6-N=C=L (XIII) in which R6 and L are each as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of a catalyst, or (B) with carbamoyl chlorides or thiocarbamoyl chlorides of the formula (XIV) in which L, R6 and R7 are each as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. Furthermore, it has been found that the novel compounds of the formula (I) are highly active as pesticides, preferably as insecticides, acaricides and herbicides. Le A 34 460-Foreign Countries The formula (I) provides a general definition of the compounds according to the invention. Preferred substituents or ranges of the radicals listed in the formulae mentioned above and below are illustrated below: Het preferably represents X preferably represents hydrogen, halogen, C1-C6-alkyl, C1-C4-halogenoalkyl, 10 C1-C6-alkoxy, C3-C6-alkenyloxy, nitro or cyano, Y preferably represents halogen, C1-C6-alkyl, C1-C6-halogenoalkyl, C1-C6-alkoxy, C1C6-halogenoalkoxy, C1-C6-alkylthio, C1-C6-alkylsulphonyl, C1-C6-alkylsulphoxinyl or represents the group 15 or in the case of Het - thiazolyl ((I-l-A) to (I-3-A)) also represents 20 Le A 34 460-Foreign Countries V1 preferably represents hydrogen, halogen, C1-C12-alkyl, C1C6-alkoxy, Ci-C6-alkylthio, C1-C6-alkylsulphinyl, C1-C6-alkylsulphonyl, C1C4halogenoalkyl, C1-C4-halogenoalkoxy, nitro, cyano, phenoxy or represents phenyl, phenoxy, phenoxy-C1-C4-alkyl, phenyl-C1-C4-alkoxy, 5 phenylthio-C1-C4-alkyl or phenyl-C1-C4-alkylthio, each of which is optionally mono- or polysubstituted by halogen, C1-C6-aIkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, nitro or cyano, V2 and V3 independently of one another each preferably represent hydrogen, 10 halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl or C 1 -C4-halogenoalkoxy, V1 and V2 together with the carbon atoms to which they are attached preferably represent an optionally C1-C4-alkyl- or halogen-substituted saturated or 15 unsaturated 5- or 6-membered cycle in which optionally one to three carbon atoms may be replaced by oxygen, sulphur or nitrogen, W preferably represents N-D (1), oxygen (2) or sulphur (3) 20 A preferably represents hydrogen or in each case optionally fluorine- or chlorine-substituted C1-C12-alkyl, C3-C8-alkenyl, C1-C6-alkoxy-C1-C6-alkyl, poly-C1 -C6-alkoxy-C1-C6-alkyl, C1-C10-alkylthio-C1-C6-alkyl, optionally fluorine-, chlorine-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-Cg-cycloalkyl in which optionally one or two not directly adjacent ring 25 members are replaced by oxygen and/or sulphur or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-halogenoalkyl-, C1-C6-alkoxy-, C1-C6-halogenoalkoxy-, cyano- or nitro-substituted C6- or C10-aryl (phenyl or naphthyl), hetaryl having 5 or 6 ring atoms (for example furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl, thiazolyl or thienyl) or C6- or C10- 30 aryl-C1-C6-alkyl (phenyl-C1-C6-alkyl or naphthyl-C1-C6-alkyl), Le A 34 460-Foreign Countries B preferably represents hydrogen, C1-C6-alkyl or C1-C4-alkoxy-C1-C4-alkly, or A, B and the carbon atom to which they are attached preferably represent saturated 5 C3-C10-cycloalkyl or unsaturated C5-C10-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which are optionally mono- or disubstituted by C1-C6-alkyl, C3-Cg-cycloalkyl, C1-C4- halogenoalkyl, C1-C6-alkoxy, C1-C6alkylthio, halogen or phenyl or 10 A, B and the carbon atom to which they are attached preferably represent C5-C6-cycloalkyl which is substituted by an alkylenediyl group which optionally contains an oxygen or sulphur atom, or by an alkylenedioxyl or by an alkylenedithioyl group which, together with the carbon atom to which it is attached, forms a further five- or six-membered ring which may optionally be 15 mono- to tetrasubstituted by C1-C4-aIkyl, or A, B and the carbon atom to which they are attached preferably represent C3-C8-cycloalkyl or C5-C8-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent in each case 20 optionally C1-C6-alkyl-, C1-C6-alkoxy- or halogen-substituted C2-C6- alkanediyl, C2-C6-alkenediyI or C4-C6-a1kanedienediyl in which optionally one methylene group is replaced by oxygen or sulphur, D preferably represents hydrogen, in each case optionally halogen- or 25 cyano-substituted C1-C12-alkyl, C3-C8-alkenyl, C3-C8-alkinyl, C1-C10- alkoxy-C2-Cg-alkyl, poly-C1-C8-alkoxy-C2-C8-alkyl, C1-C10-alkylthio-C2- C8-alkyl, optionally halogen-, C1-C4-alkyl-, C1-C4-alkoxy- or C1-C4- halogenoalkyl-substituted C3-Cg-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur or in each case optionally halogen-, 30 C1-C6-alkyl-, C1-C6-halogenoalkyl, C1-C6-alkoxy-, C1-C6- halogenoalkoxy-, cyano- or nitro-substituted phenyl, hetaryl having 5 or Le A 34 460-Foreign Countries 6 ring atoms (for example furanyl, imidazolyl, pyridyl, thiazolyl, pyrazolyl, pyrimidyl, pyrrolyl, thienyl or triazolyl), phenyl-C1-C8-alkyl or hetaryl-C1-C6-alkyl having 5 or 6 ring atoms (for example furanyl, imidazolyl, pyridyl, thiazolyl, pyrazolyl, pyrimidyl, pyrrolyl, thienyl or triazolyl), or 5 A and D together preferably represent in each case optionally substituted C3-C6-alkanediyl or C3-C6-alkenediyl in which optionally one methylene group is replaced by a carbonyl group, oxygen or sulphur, possible substituents being in each case: 10 halogen, hydroxyl, mercapto or in each case optionally halogen-substituted C1-C10-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C3-C7-cycloalkyl, phenyl or benzyloxy, or a further C3-C6-alkanediyl grouping, C3-C6-alkenediyl grouping or a butadienyl grouping which is optionally substituted by C1-C6-alkyl or in which optionally two adjacent substituents together with the 15 carbon atoms to which they are attached form a further saturated or unsaturated cycle having 5 or 6 ring atoms (in the case of the compounds of the formula (I-l-A) to (I-l-B), A and D together with the atoms to which they are attached in this case represent, for example, the groups AD-1 to AD-10 mentioned further below) which may contain oxygen or sulphur, or which 20 optionally contains one of the groups below Le A 34 460-Foreign Countries G preferably represents hydrogen (a) or represents one of the groups in which E represents a metal ion equivalent or an ammonium ion, 10 L represents oxygen or sulphur and M represents oxygen or sulphur. Le A 34 460-Foreign Countries R1 preferably represents in each case optionally halogen-substituted C1-C20- alkyl, C2-C20-alkenyl, C1-C8-alkoxy-C1-C8-alkyl, C1-C8-alkylthio-C1-C8- alkyl, poly-C1-C8-alkoxy-C1-C8-alkyl or optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl in which optionally one or 5 more (preferably not more than two) not directly adjacent ring members are replaced by oxygen and/or sulphur, represents optionally halogen-, cyano-, nitro-, C1-C6-alkyl, C1-C6-alkoxy-, C1-C6-halogenoalkyl-, C1-C6-halogenoalkoxy-, C1-C6-alkylthio- or C1-C6- 10 alkylsulphonyl-substituted phenyl, represents optionally halogen-, nitro-, cyano-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-halogenoalkyl- or C1-C6-halogenoalkoxy-substituted phenyl-C1-C6-alkyl, 15 represents optionally halogen-, C1-C6-aIkyl-, C1C2-halogenoalkyl- or C1 C4-alkoxy-substituted 5- or 6-membered hetaryl (for example pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl orthienyl), 20 represents optionally halogen- or C1C6-alkyl-substituted phenoxy-C1-C6- alkyl or represents optionally halogen-, amino- or C1-C6-alkyl-substituted 5-or 6- membered hetaryloxy-C1-C6-alkyl (for example pyridyloxy-C1-C6-alkyl, 25 pyrimidyloxy-C1-C6-alkyl or thiazolyloxy-C1-C6-alkyl), R2 preferably represents in each case optionally halogen-substituted C1-C20-alkyl, C2-C20-alkenyl, C1-C8-alkoxyC2-C8-alkyl, poly-C1-C8-alkoxy-C2-C8-alkyl, 30 Le A 34 460-Foreign Countries represents optionally halogen-, C1-C6-alkyl or C1-C6-alkoxy-substituted C3-C8-cycloalkyl in which optionally one ring atom is replaced by oxygen, or represents in each case optionally halogen-, cyano-, nitro-, Ci-Cg-alkyl-, 5 C1-C6-alkoxy-, C1-C6-halogenoalkyl- or C1-C6-halogenoalkoxy-substituted phenyl or benzyl, R3 preferably represents optionally halogen-substituted C1-C8-alkyl or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, 10 C1-C4-halogenoalkyl-, C1-C4-halogenoalkoxy-, cyano- or nitro-substituted phenyl or benzyl, R4 and R5 independently of one another each preferably represent in each case optionally halogen-substituted C1-C8-alkyl, C1-C8-alkoxy, 15 C1-C8-alkylamino, di-(C1-C8-alkyI)amino, C1-C8-alkylthio, C2-C8-alkenylthio, C3-C7-cycloa!kylthio or represent in each case optionally halogen-, nitro-, cyano-, C1-C4-Alkoxy-, C1-C4-halogenoalkoxy-, C1-C4-alkylthio-, C1-C4-halogenoalkylthio-, C1-C4-alkyl- or C1-C4-halogenoalkyl-substituted phenyl, phenoxy or phenylthio, 20 R6 and R7 independently of one another each preferably represent hydrogen, represent in each case optionally halogen-substituted Ci-Cg-alkyl, C3-C8-cycloalkyl, C1C8-alkoxy, C3-C8-alkenyl, C1-C8-alkoxy-C1-C8-alkyl, represent optionally halogen-, C1-C8-halogenoalkyl-, C1-C8-alkyl- or 25 C1-C8-alkoxy-substituted phenyl, optionally halogen-, C1-C8-alkyl-, C1-C8- halogenoalkyl- or C1-C8-alkoxy-substituted benzyl or together represent an optionally C1-C4-alkyl-substituted C3-C6-alkylene radical in which optionally one carbon atom is replaced by oxygen or sulphur, 30 Rl3 preferably represents hydrogen, represents in each case optionally halogen- substituted C1-C8-alkyl or C1-C8-alkoxy, represents optionally halogen-, C1- Le A 34 460-Foreign Countries C4-alkyl- or C1-C4-alkoxy-substituted C3-Cg-cycloalkyl, in which optionally one methylene group is replaced by oxygen or sulphur, or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4- halogenoalkyl-, C1-C4-halogenoalkoxy-, nitro- or cyano-substituted phenyl, 5 phenyl-C1 -C4-alkyl or phenyl-C1 -C4-alkoxy, R14 preferably represents hydrogen or C1-C8-alkyl or Rl3 and Rl4 together preferably represent C4-C6-aIkanediyl, 10 Rl5and R16 are identical or different and each preferably represent C1-C6-alkyl or R15 and R16 together preferably represent a C2-C4-alkanediyl radical which is optionally substituted by C1-C6-alkyl, C1-C6-halogenoalkyl or by optionally 15 halogen-, C1-C6-alkyl-, C1-C4-halogenoalkyl-, C1-C6-alkoxy-, C1-C4- halogenoalkoxy-, nitro- or cyano-substituted phenyl, Rl7 and R18 independently of one another each preferably represent hydrogen, represent optionally halogen-substituted C1-C8-alkyl or represent optionally 20 halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4-halogenoalkyl-, C1-C4- halogenoalkoxy-, nitro- or cyano-substituted phenyl or R17 and R18 together with the carbon atom to which they are attached preferably represent a carbonyl group or represent optionally halogen-, C1-C4-alkyl or 25 C1-C4-alkoxy-substituted C5-C7-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur, Rl9 and R20 independently of one another each preferably represent C1-C10-alkyl, C2-C10-alkenyl, C1-C10-alkoxy, C1-C10-alkylamino, 30 C3-C10-alkenylamino, di-(C1-C10-alkyl)amino or di- (C3-C10-alkenyl)amino. Le A 34 460-Foreign Countries In the radical definitions mentioned as being preferred, halogen represents fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and bromine. Het particularly preferably represents X particularly preferably represents hydrogen, chlorine, bromine, C1-C4-alkyl, 10 C1-C2-halogenoalkyl, nitro or cyano, Y particularly preferably represents chlorine, bromine, C1-C4-alkyl, C1-C4-halogenoalkyl, C1-C4-alkoxy, C1-C4-halogenoalkoxy, C1-C4-alkylthio, C1-C4-alkylsulphonyl or represents the group 15 or in the case of Het = thiazolyl ((I-l-A) to (I-3-A)) also represents 20 V1 particularly preferably represents hydrogen, fluorine, chlorine, bromine, C1- C6-alkyl, C1C4-alkoxy, C1C2-halogenoalkyl, C1-C2-halogenoalkoxy, nitro, cyano, phenoxy or represents phenyl, phenoxy, phenoxy-C1-C2-alkyl, phenyl- 25 C1C2-alkoxy, phenylthio-C1C2-alkyl or phenyl-C1C2-alkylthio, each of Le A 34 460-Foreign Countries which is optionally mono- or disubstituted by fluorine, chlorine, bromine, C1-C4alkyl, C1-C4-alkoxy, C1-C2-halogenoalkyl, C1-C2-halogenoalkoxy, nitro or cyano, V2 particularly preferably represents hydrogen, fluorine, chlorine, bromine, C1-C4-alkyl, C1-C4-alkoxy, C1-C2-halogenoalkyl or C1-C2-halogenoalkoxy, or V1 and V2 together with the carbon atoms to which they are attached particularly 10 preferably represent an optionally fluorine- or methyl-substituted 5- or 6-membered cycle in which optionally one or two carbon atoms may be replaced by oxygen, W particularly preferably represents N-D(1) oxygen(2) or sulphur(3) 15 A particularly preferably represents hydrogen, in each case optionally fluorine-substituted C1-C10-alkyl, C1-C4alkoxy-C1-C4alkyl, optionally fluorine-, chlorine-, C1-C4alkyl- or C1-C4-alkoxy-substituted C3-C7- cycloalkyl in which optionally one ring member is replaced by oxygen or 20 sulphur or in each case optionally fluorine-, chlorine-, bromine-, C1-C4- alkyl-, C1-C4-halogenoalkyl-, C1-C4-alkoxy- or C1-C4-halogenoalkoxy-substituted phenyl or phenyl-C1-C2-alkyl, B particularly preferably represents hydrogen or C1-C4-alkyl, or 25 A, B and the carbon atom to which they are attached particularly preferably represent saturated C5-C7-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally mono- or disubstituted by C1-C6-alkyl, C5-C6-cycIoalkyl, C1-C2-halogenoalkyI, C1-C6-alkoxy, 30 fluorine, chlorine or phenyl or Le A 34 460-Foreign Countries A, B and the carbon atom to which they are attached particularly preferably represent C5-C6-cycIoalkyl which is substituted by an alkylenediyl group which optionally contains an oxygen or sulphur atom or by an alkylenedioxyl or by an alkylenedithioyl group which together with the carbon atom to which 5 it is attached forms a further five- or six-membered ring which may optionally be mono- to trisubstituted by C1-C3-alkyl, or A, B and the carbon atom to which they are attached particularly preferably represent C5-C6-cycloalkyl or C5-C6-cycloalkenyl in which two substituents 10 together with the carbon atoms to which they are attached represent in each case optionally C1-C5-alkyl-, C1-C5-alkoxy-, fluorine-, chlorine- or bromine-substituted C2-C4alkanediyl, C1-C4alkenediyl in which optionally one methylene group is replaced by oxygen or sulphur or represent butadienediyl, 15 D particularly preferably represents hydrogen, represents in each case optionally fluorine-substituted C1-C10-alkyl, C3-C5-alkenyI, C1-C6-alkoxy-C2-C4-alkyl or C2-C6-alkylthio-C2-C4-alkyl, represents optionally fluorine-, C1-C4-alkyl, C1-C4-alkoxy or C1-C2-halogenoalkyl-substituted C3-C7-cycloalkyl, 20 in which optionally one methylene group is replaced by oxygen or sulphur or represents in each case optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C2-halogenoaIkyl-, C1-C4-alkoxy- or C1C2-halogenoalkoxy-substituted phenyl or phenyl-C1-C4-alkyl, or 25 A and D together particularly preferably represent optionally substituted C3-C5- alkanediyl in which optionally one methylene group may be replaced by a carbonyl group, oxygen or sulphur, possible substituents being hydroxyl, C1-C6-alkyl or C1-C4-alkoxy, or 30 A and D together with the atoms to which they are attached particularly preferably represent one of the groups AD-1 to AD-10: Le A 34 460-Foreign Countries Le A 34 460-Foreign Countries E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur and 5 M represents oxygen or sulphur, Rl particularly preferably represents in each case optionally fluorine- or chlorine- substituted C1-C16-alkyl, C2-C16-alkenyl, C1-C6-alkoxy-C1-C4-alkyl, C1-C6-alkylthio-C1-C4-alkyl or optionally fluorine-, chlorine-, C1-C5-alkyl- 10 or C1-C5-alkoxy-substituted C3-C7-cycloalkyl in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur, represents optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4- 15 alkyl-, C1-C4-alkoxy-, C1-C3-halogenoalkyl-, C1-C3-halogenoalkoxy-, C1- C4-alkylthio- or C1-C4-alkylsulphonyl-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, C1-C4-aIkyl-, C1-C4- alkoxy-, C1-C3-halogenoalkyI- or C1-C3-halogenoalkoxy-substituted phenyl- 20 C1-C4-alkyl, represents in each case optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, trifluoromethyl- or C1-C2-alkoxy-substituted pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl or thienyl, 25 R2 particularly preferably represents in each case optionally fluorine-substituted C1-C16-alkyl, C2-C16-alkenyl or C1-C6-alkoxy-C1-C6-alkyl, represents optionally fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy- 30 substituted C3-C7-cycloalkyl or Le A 34 460-Foreign Countries represents in each case optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4-alkyl-, C1-C3-alkoxy-, C1-C2-halogenoalkyl- or C1-C2-halogenoalkoxy-substituted phenyl or benzyl, 5 R3 particularly preferably represents optionally fluorine-substituted C1-C6-alkyl or represents optionally fluorine-, chlorine-, bromine-, C1-C4alkyl-, C1-C4-alkoxy-, C1-C3-halogenoalkyl-, C1-C3-halogenoalkoxy-, cyano- or nitro-substituted phenyl, 10 R4 particularly preferably represents C1-C6-alkyl, C1-C6-alkoxy, C1-C6- alkylamino, di-(C1-C6-alkyl)amino, C1-C6-alkylthio, C3-C4-alkenylthio, C3-C6-cycloalkylthio or represents in each case optionally fluorine-, chlorine-, bromine-, nitro-, cyano-, C1-C3-aIkoxy-, C1-C3-halogenoalkoxy-, C1-C3-alkylthio-, C1-C3-halogenoalkylthio-, C1-C3-alkyl- or C1-C3- 15 halogenoalkyl-substituted phenyl, phenoxy or phenylthio, R5 particularly preferably represents C1C6-alkoxy or C1-C6-alkylthio, R6 particularly preferably represents C1-C6-alkyl, C3-C6-cycloalkyl, C1-C6- 20 alkoxy, C3-C6-alkenyl, C1-C6-alkoxy-C1-C6-alkyl, represents optionally fluorine-, chlorine-, bromine-, Ci-C3-halogenoalkyl-, C1-C4-alkyl- or C1-C4-alkoxy-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C3-halogenoalkyl- or C1-C4alkoxy-substituted benzyl, 25 R.7 particularly preferably represents hydrogen, C1-C6-alkyl, C3-C6-alkenyl, or R6 and R7 together particularly preferably represent an optionally methyl- or ethyl- substituted C4-C5-alkylene radical in which optionally one methylene group is 30 replaced by oxygen or sulphur. Le A 34 460-Foreign Countries In the radical definitions mentioned as being particularly preferred, halogen represents fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and bromine. Het very particularly preferably represents X very particularly preferably represents hydrogen, chlorine, bromine, methyl, 10 ethyl, n-propyl, iso-propyl, n-butyl or iso-butyl, Y very particularly preferably represents methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, tert-butyl, trifluoromethyl or represents the group 15 or in the case of Het = thiazolyl ((I-l-A) to (I-3-A)) also represents 20 V1 very particularly preferably represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, tert-butyl, methoxy, ethoxy, n-propoxy, iso-propoxy, trifluoromethyl, trifluoromethoxy, nitro, cyano, phenoxy or phenyl which is optionally mono- or disubstituted by 25 fluorine, chlorine, methyl, methoxy, trifluoromethyl or trifluoromethoxy, Le A 34 460-Foreipn Countries V2 very particularly preferably represents hydrogen, fluorine, chlorine, methyl, ethyl, n-propyl, iso-propyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy, or 5 V1 and V2 together very particularly preferably represent -0-CH2-0-, -O-CF2-O- or -O-CF2-CF2-0-, W very particularly preferably represents N-D(1), oxygen(2) or sulphur (3), 10 A very particularly preferably represents hydrogen, represents in each case optionally fluorine-substituted C1-C8-alkyl or C1-C4-alkoxy-C1-C2-alkyl, optionally fluorine-, methyl-, ethyl- or methoxy-substituted C3-C6-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur or represents in each case optionally fluorine-, chlorine-, bromine-, methyl-, 15 ethyl-, n-propyl-, iso-propyl-, tert-butyl-, methoxy-, ethoxy-, trifluoromethyl-, trifluoromethoxy-, cyano- or nitro-substituted phenyl or benzyl, B very particularly preferably represents hydrogen, methyl or ethyl, or 20 A, B and the carbon atom to which they are attached very particularly preferably represent saturated C5-C6-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally mono- or disubstituted by methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, propoxy, iso-propoxy, butoxy or iso-butoxy 25 or A, B and the carbon atom to which they are attached very particularly preferably represent C6-cycloalkyl which is substituted by an alkylenedioxyl group which is optionally mono- or disubstituted by methyl or ethyl and which 30 together with the carbon atom to which it is attached forms a further five- or six-membered ring or Le A 34 460-Foreign Countries A, B and the carbon atom to which they are attached very particularly preferably represent C5-C6-cycloalkyl or C5-C6-cycloaIkenyl in which two substituents together with the carbon atoms to which they are attached represent C2-C4- 5 alkanediyl or C2-C4-alkenediyl in which in each case optionally one methylene group is replaced by oxygen or sulphur, or represent butadienediyl, D very particularly preferably represents hydrogen, represents in each case optionally fluorine-substituted C1-C6-alkyl, C3-C4-alkenyl, C1-C4- 10 alkoxy-C2-C3-alkyl, C1-C4-alkylthio-C2-C3-alkyl or C3-C6-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur or represents in each case optionally fluorine-, chlorine-, methyl-, ethyl-, n-propyl-, iso-propyl-, methoxy-, ethoxy-, trifluoromethyl- or trifluoromethoxy-substituted phenyl or benzyl, 15 or 20 A and D together very particularly preferably represent optionally substituted C3-C4-alkanediyl in which optionally one carbon atom is replaced by oxygen or sulphur and which is optionally substituted by methyl or A and D together with the atoms to which they are attached very particularly preferably represent one of the groups AD below: Le A 34 460-Foreign Countries 5 in particular (a), (b) or (c), in which E represents a metal ion equivalent or an ammonium ion, 10 L represents oxygen or sulphur and M represents oxygen or sulphur, Rl very particularly preferably represents in each case optionally 15 fluorine-substituted C1-C14-alkyl, C2-C14-alkenyl, C1-C4-alkoxy-C1-C2- alkyl, C1-C4-alkylthio-C1-C2-alkyl or in each case optionally fluorine-, chlorine-, methyl-, ethyl- or methoxy-substituted cyclopropyl, cyclopentyl or cyclohexyl, Le A 34 460-Foreign Countries represents phenyl which is optionally mono- or disubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, tert-butyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy, 5 represents thienyl or pyridyl, each of which is optionally monosubstituted by fluorine, chlorine, bromine or methyl, R2 very particularly preferably represents in each case optionally 10 fluorine-substituted C1-C8-alkyl, C2-C8-alkenyl or C1-C4-alkoxy-C2-C3- alkyl, represents optionally fluorine-, chlorine-, methyl-, ethyl-, n-propyl-, iso-propyl- or methoxy-substituted cyclohexyl, 15 or represents in each case optionally fluorine-, chlorine-, cyano-, nitro-, methyl-, ethyl-, methoxy-, trifluoromethyl- or trifluoromethoxy-substituted phenyl or benzyl, 20 R3 very particularly preferably represents methyl, ethyl, n-propyl or represents phenyl which is optionally monosubstituted by fluorine, chlorine, bromine, methyl, tert-butyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro, R4 very particularly preferably represents C1-C4alkyl, C1-C4-alkoxy, C1-C4- 25 alkylamino, di-(C1-C4-alkyl)amino, C1-C4-alkylthio or represents in each case optionally fluorine-, chlorine-, bromine-, nitro-, cyano-, C1-C2-alkoxy-, C1-C2-fluoroaIkoxy-, C1-C2-alkylthio-, C1-C2-fluoroalkylthio- or C1-C3- alkyl-substituted phenyl, phenoxy or phenylthio, 30 R5 very particularly preferably represents methoxy, ethoxy, methylthio or ethylthio, Le A 34 460-Foreign Countries R6 very particularly preferably represents C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-alkoxy, C3-C4-alkenyl, C1-C4-alkoxy-C1-C4-alkyl, represents optionally fluorine-, chlorine-, bromine-, trifluoromethyl-, methyl- or methoxy-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, methyl-, trifluoromethyl- or methoxy-substituted benzyl, R7 very particularly preferably represents hydrogen, methyl, ethyl, propyl or allyl, or R6 and R7 together very particularly preferably represent a C5-C6-alkylene radical in which optionally one methylene group is replaced by oxygen or sulphur. Het with particular preference represents X with particular preference represents hydrogen, chlorine, bromine, methyl, ethyl, n-propyl, or iso-propyl, Y with particular preference represents methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, tert-butyl, trifluoromethyl or represents the group or in the case of Het = thiazolyl ((I-l-A) or (I-3-A)) also represents Le A 34 460-Foreign Countries V1 with particular preference represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, tert-butyl, methoxy, 5 ethoxy, n-propoxy, iso-propoxy, trifluoromethyl, trifluoromethoxy, phenoxy, represents optionally chlorine- or trifluoromethyl-substituted phenyl, V2 with particular preference represents hydrogen, fluorine, chlorine, methyl, ethyl, methoxy or trifluoromethyl, or 10 V1 and V2 together with particular preference represent -O-CH2-O- or -0-CF2-0-, W with particular preference represents N-D(1)', oxygen(2) or sulphur (3), 15 A with particular preference represents hydrogen or C1-C4-alkyl or cyclopropyl, B with particular preference represents hydrogen or methyl, or A, B and the carbon atom to which they are attached with particular preference 20 represent saturated C5-C6-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur, and which is optionally mono- or disubstituted by methyl, ethyl, propyl, isopropyl, trifluoromethyl, methoxy, ethoxy, propoxy, butoxy or iso-butoxy, or represents C5-C6-cycloalkyl in which two not directly adjacent carbon atoms form a further five-membered ring. 25 D with particular preference represents hydrogen, D also with particular preference represents i-propyl, Le A 34 460-Foreign Countries A and D together with the atoms to which they are attached with particular preference represent cyclohexyl in which one ring atom may be replaced by sulphur, G with particular preference represents hydrogen (a) or in the case of Het = thiazolyl ((I-l-A) to (I-3-A)) (represents) one of the groups 10 in which 15 20 L represents oxygen and M represents oxygen, Rl with particular preference represents in each case optionally fluorine- or chlorine-substituted C1-C4-alkyl, C2-C4-alkenyl, C1-C4-alkoxy-C1-C2-alkyl, C1-C4-alkylthio-C1-C2-alkyl or optionally fluorine-, chlorine-, methyl-, ethyl- or methoxy-substituted cyclopropyl or cyclohexyl, represents phenyl which is optionally monosubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, n-propyl, i-propyl, tert-butyl, methoxy, ethoxy, i-propoxy, tert-butoxy, trifluoromethyl or trifluoromethoxy, 25 represents thienyl or pyridyl, each of which is optionally monosubstituted by chlorine or methyl, R2 with particular preference represents optionally in each case fluorine-substituted C1-C4-alkyl, C2-C4-alkenyl or C1-C4-alkoxy-C2-C3- 30 alkyl, Le A 34 460-Foreign Countries represents optionally methyl-, ethyl-, n-propyl-, iso-propyl- or methoxy-substituted cyclohexyl, or represents phenyl or benzyl, each of which is optionally monosubstituted by fluorine, chlorine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy, Het especially preferably represents X especially preferably represents methyl, ethyl, n-propyl, i-propyl, chlorine or bromine, Y especially preferably represents methyl, ethyl, n-propyl or i-propyl or represents the groups in which V1 especially preferably represents hydrogen, bromine, chlorine, methyl, trifluoromethyl, phenoxy or t-butyl or represents optionally chlorine- or trifluoromethyl-substituted phenyl, V1- especially preferably represents hydrogen, chlorine, fluorine or methoxy or Le A 34 460-Foreign Countries V1 and V2 together especially preferably represent -O-CH2-O- or -O-CF2-O-, W especially preferably represents N-D(1), oxygen(2) or sulphur (3), 5 D especially preferably represents hydrogen or i-propyl (especially hydrogen), A especially preferably represents methyl, ethyl, n- or i-propyl or cyclopropyl or hydrogen (especially methyl), 10 B especially preferably represents hydrogen or methyl, or A and B and the carbon atom to which they are attached especially preferably represent cyclohexyl in which optionally one ring atom is replaced by oxygen 15 and which is optionally mono- or disubstituted by methyl, ethyl, methoxy or ethoxy, or represent cyclohexyl in which two not directly adjacent carbon atoms form a further 5-membered C ring, A and D together with the atoms to which they are attached especially preferably 20 represent cyclohexyl in which one ring atom may be replaced by sulphur, G especially preferably represents hydrogen (a) or represents one of the groups 25 in which R1 especially preferably represents methyl, ethyl, n-propyl or i-propyl or represents in each case optionally chlorine-substituted phenyl or pyridyl, 30 R2 especially preferably represents methyl, ethyl, phenyl, benzyl, n- or i-propyl, Le A 34 460-Forei^n Countries Het especially preferably represents X especially preferably represents methyl or ethyl, Y especially preferably represents optionally chlorine-substituted phenyl, A especially preferably represents methyl, ethyl, n- or i-propyl, B especially preferably represents methyl, or A and B and the carbon atom to which they are attached together especially preferably represent cyclohexyl which is optionally substituted by methoxy or methyl, W especially preferably represents N-D or oxygen, D especially preferably represents hydrogen, G especially preferably represents hydrogen. The abovementioned general or preferred radical definitions or illustrations can be combined with one another as desired, i.e. including combinations between the respective ranges and preferred ranges. They apply both to the end products and, correspondingly, to the precursors and intermediates. Le A 34 460-Foreign Countries Preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings listed above as being preferred (preferable). 5 Particular preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings listed above as being particularly preferred. Very particular preference according to the invention is given to the compounds of 10 the formula (I) which contain a combination of the meanings listed above as being very particularly preferred. Particular preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings listed above as being with 15 particular preference. A special preference according to the invention is given to the compounds of the formula (I) which contain a combination of the meanings listed above as being especially preferred. 20 Saturated or unsaturated hydrocarbon radicals, such as alkyl or alkenyl, can in each case be straight-chain or branched as far as this is possible, including in combination with heteroatoms, such as, for example, in alkoxy. 25 Unless indicated otherwise, optionally substituted radicals can be mono- or polysubstituted, where in the case of polysubstitutions, the substituents can be identical or different. In addition to the compounds mentioned in the Preparation Examples, the following 30 compounds of the formula (I-l-a) may, for example, be mentioned specifically: Le A 34 460-Foreign Countries X = CH3, V1 = 3-C1, V2 = H. Le A 34 460-Foreign Countries Table 1: Le A 34 460-Foreign Countries Table 1 (continued): Le A 34 460-Foreign Countries Table 1 (continued): Le A 34 460-Foreign Countries Table 1 (continued): Table 2: A, B and D are as stated in Table 1 X = CH3:V1=4-C1;V2 = H. ^ Table 3: A, B and D are as stated in Table 1 X = CH1;V1=3-CF3;V^ = H. 10 Table 4: A, B and D are as stated in Table 1 X = CH3:V1=4-CF3; V2= H. Table 5: A, B and D are as stated in Table 1 X = CH3;V1=4-C1;V2 = 2-C1. 15 Table 6: A, B and D are as stated in Table 1 X = CH3;V1=4-Cl:V2 = 3-Cl. Table 7: A, B and D are as stated in Table 1 X = CH3; V1 = 4-CH3; V2 = H. Le A 34 460-Foreign Countries Table 8: A, B and D are as stated in Table 1 X = CH3; V1 = 2-C1; V1 = 6-OCH3. Table 9: A, B and D are as stated in Table 1 5 X = C2H5;Vl=4-Cl;V2 = H. Table 10: A, B and D are as stated in Table 1 X = C3H7; Vl = 4-C1; V2 = H. 10 Table 11: A, B and D are as stated in Table 1 X = C2H5; V* = 3-C1; V? = H 15 20 Table 14: A, B and D are as stated in Table 1 X = C2H5; V1 = 3-CF3; V2 = H. Table 15: A, B and D are as stated in Table 1 X = C3H7;V1=4-CF3;V2 = H. 25 Table 16: A, B and D are as stated in Table 1 X = C3H7;V1 = 3-CF3;V2 = H. Table 17: A, B and D are as stated in Table 1 X = C1;V1=4-C1;V2 = H. 30 Le A 34 460-Foreign Countries Table 18: A, B and D are as stated in Table 1 X = Br; V1 = 4-C1; V2 = H. Table 19: A, B and D are as stated in Table 1 5 X = C2H5;Vl=3-Cl;V2 = 4-Cl. Table 20: A, B and D are as stated in Table 1 X = C3H7; Vl = 3-C1; V2 = 4-C1. 10 Table 21: A, B and D are as stated in Table 1 X = CH3; Vl = 4-Br; V2 = H. In addition to the compounds mentioned in the Preparation Examples, the following compounds of the formula (I-2-a) may, for example, be mentioned specifically: OH X Table 22: X = CH3, Vl = 3-C1, V2 = H. Le A 34 460-Foreign Countries Table 22 (continued): Le A 34 460-Foreign Countries Table 22 (continued): Table 23: A and B are as stated in Table 22 X = CH3;Vl=4-Cl;V2 = H. Table 24: A and B are as stated in Table 22 X = CH3; V1 = 3-CF3; V2 =H. Le A 34 460-Foreign Countries Table 25: A and B are as stated in Table 22 X = CH3; Vl = 4-CF3; V2 = H. Table 26: A and B are as stated in Table 22 5 X = CH3;V1=4-C1;V2 = 2-C1. Table 27: A and B are as stated in Table 22 X = CH3;V1=4-C1;V2 = 3-C1. 10 Table 28: A and B are as stated in Table 22 X = CH3;V1=4-CH3;V2 = H. 15 Table 29: A and B are as stated in Table 22 X = CH3; V1 = 2-C1; V2 = 6-OCH3. Table 30: A and B are as stated in Table 22 X = C2H5;Vl=4-Cl:V2 = H. 20 Table 31: A and B are as stated in Table 22 X = C3H7;Vl=4-Cl;V2 = H. Table 32: A and B are as stated in Table 22 X = C2H5;V1=3-C1;V2 = H. 25 Table 33: A and B are as stated in Table 22 X = C3H7;V1 = 3-C1;V2 = H. 30 Table 34: A and B are as stated in Table 22 X = C2H5-, Vl = 4-CF3-, V2 = H Table 35: A and B are as stated in Table 22 Le A 34 460-Foreign Countries X = C3tt7; \^ = 4-CP3; V> = H. Table 36: A and B are as stated in Table 22 X = C2H5; V = 3-CF3; V* = H. Table 37: A and B are as stated in Table 22 X = C3H7; V1 = 3-CF3; V2 = H. Table 38: A and B are as stated in Table 22 X = Cl;Vl=4-Cl;V2 = H. Table 39-. A. axvd B are as stated \xv Table 22 X = Br; V1 = 4-C1; V2 = H. Table 40: A and B are as stated in Table 22 X = C2H5; V1 = 3-C1; V2 = 4-C1. Table 41: A and B are as stated in Table 22 X = C3H7; V1 = 3-C1; V2 = 4-C1. Table 42: A and B are as stated in Table 22 X = CH3;V1=4-Br;V2 = H. Using, according to process (A), ethyl N-[4-(5-methyl-2-phenyl)-thiazolylacetyl]-l-amino-cyclohexane-carboxylate as starting material, the course of the process according to the invention can be represented by the following equation: Le A 34 460-Foreign Countries Using, according to process (B), ethyl 0-[4-(5-metriy)-2-(4-chloro-phenyl)-thiazoly]-acetyl]-2-hydroxyisobutyrate as starting material, the course of the process according to the invention can be represented by the following equation: Using, according to process (C), ethyl 2-[4-(5-methyl-2-phenyl)-thiazolyl]-4-(4-methoxy)-benzylmercapto-4-methyl-3-oxo-valerate as starting material, the course of the process according to the invention can be represented by the following equation: 10 15 Using, according to process (Da), 3-[4-(5-methyl-2-(3-chloro-phenyl)-thiazolyl]-5,5-dimethylpyrrolidine-2,4-dione and pivaloyl chloride as starting materials, the course of the process according to the invention can be represented by the following equation: Le A 34 460-Foreign Countries Using, according to process (DB), 3-[4-(5-ethyl-2-(4-methoxy-phenyl))-thiazolyl]-4-hydroxy-5-phenyl-Δ3-dihydrofuran-2-one and acetic anhydride as starting materials, the course of the process according to the invention can be represented by the following equation: Using, according to process (E), 3-[4-(5-methyl-2-phenyl)-thiazolyl]- 10 5,5-dimethylpyrrolidine-2,4-dione and ethoxyethyl chloroformate as starting materials, the course of the process according to the invention can be represented by the following equation: Le A 34 460-Foreign Countries Using, according to process (F), 3-[4-(5-methyl-2-(4-fluoro-phenyl))-thiazolyl]-4-hydroxy-5,5-dimethyl-Δ3-dihydrofuran-2-one and methyl chloromonothioformate as starting materials, the course of the reaction can be represented as follows: Using, according to process (G), 3-[4-(5-methyl-3-(4-methyl-phenyl))-thiazolyl]-5,5-pentamethylene-pyrrolidine-2,4-dione and methanesulphonyl chloride as starting materials, the course of the reaction can be represented by the following equation: 10 Using, according to process (H), 3-[4-(5-methyl-2-phenyl)-thiazolyl]-4-hydroxy-5,5-dimethyl-Δ3-dihydrofuran-2-one and 2,2,2-trifluoroethyl methanethio-phosphonyl chloride as starting materials, the course of the reaction can be represented by the following equation: Le A 34 460-Foreign Countries Using, according to process (I), 3-[4-(5-methyl-2-(4-trifluoromethyl-phenyl))-thiazolyl]-5-cyclopropyl-5-methyl-pyrrolidine-2,4-dione and NaOH as components, the course of the process according to the invention can be represented by the following equation: 10 Using, according to process (Jo), 3-[4-(5-methyl-2-(3-trifluoromethyl-phenyl))-thiazolyl]-4-hydroxy-5-tetramethylene-Δ3-dihydro-furan-2-one and ethyl isocyanate as starting materials, the course of the reaction can be represented by the following equation: Le A 34 460-Foreign Countries Vising, according to process (JB), 3-l4-(5-methyl-2-phenyl)-thiazoly]]-5-methyI-pyrrolidine-2,4-dione and dimethylcarbamoyl chloride as starting materials, the course of the reaction can be represented by the following scheme: in which 10 A, B, D, Het and R8 are each as defined above required as starting materials in the process (a) according to the invention are novel. The acylammo acid eslevs of me formula (II) ate obtained, for example, when ammo 15 acid derivatives of the formula (XV) in which 20 A, B, R8 and D are each as defined above Le A 34 460-Foreign Countries are acylated with substituted hetarylacetic acid derivatives of the formula (XVI) in which Het is as defined above and W represents a leaving group introduced by reagents for activating carboxylic acids, such as carbonyldiimidazole, carbonyldiimides (such as, for example, dicyclohexylcarbodiimide), phosphorylating agents (such as, for example, POCI3, BOP-C1), halogenating agents, for example thionyl chloride, oxalyl chloride, phosgene or chloroformic esters (Chem. Reviews 52, 237-416 (1953); Bhattacharya, Indian J. Chem. 6, 341-5, 1968) or when acylamino acids of the formula (XVII) Le A 34 460-Foreign Countries in which A, B, D and Het are each as defined above are novel. The compounds of the formula (XVII) are obtained when amino acids of the formula (XVIII) in which A, B and D are each as defined above are acylated with substituted hetarylacetic acid derivatives of the formula (XVI) in which W and Het are each as defined above, for example according to Schotten-Baumann (Organikum, VEB Deutscher Verlag der Wissenschaften, Berlin 1977, p. 505). Le A 34 460-Foreign Countries Some of the compounds of the formula (XVI) are novel. They can be prepared by processes known in principle (see, for example, H. Henecka, Houben-Weyl, Methoden der Organischen Chemie [Methods of Organic Chemistry], vol. 8, pp. 467-469 (1952)). The compounds of the formula (XVI) are obtained, for example, by reacting substituted hetarylacetic acids of the formula (XIX) 10 in which X and Y are each as defined above with halogenating agents (for example thionyl chloride, thionyl bromide, oxalyl 15 chloride, phosgene, phosphorous trichloride, phosphorous tribromide or phosphorous pentachloride), if appropriate in the presence of a diluent (for example optionally chlorinated aliphatic or aromatic hydrocarbons, such as toluene or methylene chloride) at temperatures of from -20°C to 150°C, preferably from -10°C to 100°C. 20 Some of the hetarylacetic acids of the formula (XIX) are commercially available, some are known, or they can be prepared by processes known in principle a) thiazolylacetic acids: C.S. Rooney et al. J. Med. Chem. 26, 700-714 (1983); EP-A-368 592; M.S. Malamas et al. J. Med. Chem. 39, 237-246 (1996); J. L. Collins et al. J. Med. Chem. 41., 5037-5054 (1998); NL-A-66 14 130; 25 b) Oxazolylacetic acids: K. Meguro et al., Chem. Pharm. Bull, 34. 2840-2851 (1986), M. Sehi et al., Chem. Pharm. Bull. 36, 4435-4440 (1988), Malmas et al., J. Med. Chem. 39, 237-245 (1996), EP 0 177 353 A2, WO 87/03 807, WO 95/18 125, B. Hulin, J. Med. Chem. 35, 1853-1864 (1992), EP 0 389 699 A 1. Le A 34 460-Foreign Countries Some of the compounds of the formulae (XV) and (XVIII) are commercially available and/or are know'n and/or they can be prepared by known processes (see, for example, Compagnon, Miocque Ann. Chim. (Paris) [14] 5, pp. 11-22,23-27 (1970)). The substituted cyclic aminocarboxylic acids of the formula (XVIIIa), in which A and B form a ring are generally obtainable by the Bucherer-Bergs synthesis or by the Strecker synthesis, where they are in each case obtained in different isomeric forms. Thus, the conditions of the Bucherer-Bergs synthesis give mainly the isomers (hereinbelow for the sake of simplicity referred to as 6) in which the radicals R and the carboxyl group are in equatorial positions, whereas the conditions of the Strecker synthesis give mainly the isomers (hereinbelow for the sake of simplicity referred to as a) in which the amino group and the radicals R are in equatorial positions. (L. Munday, J. Chem. Soc- 4372 (1961); J.T. Eward, C. Jitrangeri, Can. J. Chem. 53, 3339 (1975). Furthermore, the starting materials of the formula (II) in which Le A 34 460-Foreign Countries A, B, D, Het and R8 are each as defined above used in the above process (A) can be prepared by reacting amino nitriles of the formula (XX) 5 10 15 in which A, B and D are each as defined above with substituted hetarylacetic acid derivatives of the formula (XVI) (XVI) in which W and Het are each as defined above to give compounds of the formula (XXI) 20 in which A, B, D and Het are each as defined above which are subsequently subjected to an acidic alcoholysis. 25 Le A 34 460-Foreign Countries The compounds of the formula (XXI) are likewise novel. The compounds of the formula (HI) A, B, Het and R8 are each as defined above required as starting materials in the process (B) according to the invention are novel. They can be prepared by methods known in principle. Thus, the compounds of the formula (III) are obtained, for example, when 2-hydroxycarboxylic esters of the formula (XXII) in which A, B and R8 are each as defined above are acylated with substituted hetarylacetic acid derivatives of the formula (XVI) Le A 34 460-Foreign Countries in which W and Het are each as defined above 5 (Chem. Reviews 52, 237-416 (1953). Furthermore, compounds of the formula (HI) are obtained when substituted hetarylacetic acids of the formula (XIX) 10 15 in which Het is as defined above are alkylated with oc-halogenocarboxylic esters of the formula (XXIII) in which 20 A, B and R° are each as defined above and Hal represents chlorine or bromine. 25 The compounds of the formula (IV) Le A 34 460-Foreign Countries in which 5 A, B, W1, Het and R8 are each as defined above and W1 represents hydrogen, halogen, alkyl (preferably CrC6-alkyl) or alkoxy (preferably C1C6-alkoxy) required as starting materials in the above process (C) are novel. 10 They can be prepared by methods known in principle. The compounds of the formula (IV) are obtained, for example, when 15 compounds of the formula (XXIV) in which 20 Het and R8 are each as defined above are acylated with 2-benzylthio-carbonyl halides of the formula (XXV) Le A 34 460-Foreign Countries 5 W1 in which A, B and W1 are each as defined above and Hal represents halogen (in particular chlorine or bromine) in the presence of strong bases (see, for example, M.S. Chambers, E.J. Thomas, D.J. Williams, J. Chem. Soc. Chem. Commun., (1987), 1228). 10 Some of the compounds of the formula (XXIV) are commercially available, some are known, or they can be prepared by known processes: a) thiazolyl acetic esters: C.S. Rooney et al., J. Med. Chem. 26. 700-714 (1983), EP-A-368 592), M.S. Malmas et al., J. Med. Chem. 39, 237-246 (1996); J. C. 15 Collins et al., J. Med. Chem. 41, 5037-5054 (1998); NL-A-6 614 130. b) oxazolyl acetic acids: K. Meguro et al., Chem. Pharm. Bull. 34. 2840-2851 (1986), M. Sehi et al., Chem. Pharm. Bull. 36, 4435-4440 (1988), Malmas et al., J. Med. Chem. 39, 237-245 (1996), EP 0 177 353 A2, WO 87/03 807, WO 95/18 125, B. Hulin, J. Med. Chem. 35, 1853-1864 (1992), EP 0 389 699 20 A l. The acyl halides of the formula (V), carboxylic anhydrides of the formula (VI), chloroformic esters or chloroformic thioesters of the formula (VII), chloromonothioformic esters or chlorodithioformic esters of the formula (VIII), 25 sulphonyl chlorides of the formula (IX), phosphorus compounds of the formula (X) and metal hydroxides, metal alkoxides or amines of the formulae (XI) and (XII) and isocyanates of the formula (XIII) and carbamoyl chlorides of the formula (XIV) furthermore required as starting materials for carrying out the processes (D), (E), (F), Le A 34 460-Foreign Countries (G), (H), (I) and (J) according to the invention are generally known compounds of organic or inorganic chemistry. Some of the compounds of the formulae (XV), (XVIII), (XX), (XXO), (XXIH) and 5 (XXV) are commercially available, some are known, and/or they can be prepared by methods known in principle. The process (A) is characterized in that compounds of the formula (II) in which A, B, D, Het and R8 are each as defined above are subjected to an intramolecular 10 condensation in the presence of a base. Suitable diluents for the process (A) according to the invention are all inert organic solvents. Preference is given to using hydrocarbons, such as toluene and xylene, furthermore ethers, such as dibutyl ether, tetrahydrofuran, dioxane, glycol dimethyl 15 ether and diglycol dimethyl ether, moreover polar solvents, such as dimethyl sulphoxide, sulpholane, dimethyl formamide and N-methylpyrrolidone, and also alcohols, such as methanol, ethanol, propanol, iso-propanol, butanol, iso-butanol and tert-butanol. 20 Suitable bases (deprotonating agents) for carrying out the process (A) according to the invention are all customary proton acceptors. Preference is given to using alkali metal and alkaline earth metal oxides, hydroxides and carbonates, such as sodium hydroxide, potassium hydroxide, magnesium oxide, calcium oxide, sodium carbonate, potassium carbonate and calcium carbonate, which can also be employed 25 in the presence of phase-transfer catalysts, such as, for example, triethylbenzylammonium chloride, tetrabutylammonium bromide, Adogen 464 (= methyltrialkyl(C8-C10)ammomium chloride) or TDA 1 (= tris-(methoxyethoxyethyl)-amine). Alkali metals such as sodium and potassium can also be used. Furthermore, alkali metal and alkaline earth metal halides and hydrides, 30 such as sodium amide, sodium hydride and calcium hydride, and additionally also Le A 34 460-Foreign Countries alkali metal alkoxides, such as sodium methoxide, sodium ethoxide and potassium tert-butoxide can be employed. When carrying out the process (A) according to the invention, the reaction 5 temperatures can be varied within a relatively wide range. In general, the reaction is carried out at temperatures between -80°C and 180°C, preferably between -50°C and 120°C. The process (A) according to the invention is generally carried out under atmospheric 10 pressure. When carrying out the process (A) according to the invention, the reaction components of the formula (II) and the deprotonating bases are generally employed in approximately double-equimolar amounts. However, it is also possible to use a 15 relatively large excess (up to 3 mol) of one component or the other. The process (B) is characterized in that compounds of the formula (III) in which A, B, Het and R8 are each as defined above are subjected to an intramolecular condensation in the presence of a diluent and in the presence of a base. 20 Suitable diluents for the process (B) according to the invention are all inert organic solvents. Preference is given to using hydrocarbons, such as toluene and xylene, furthermore ethers such as dibutyl ether, tetrahydrofuran, dioxane, glycol dimethyl ether and diglycol dimethyl ether, moreover polar solvents, such as dimethyl 25 sulphoxide, sulpholane, dimethyl formamide and N-methylpyrrolidone, and also alcohols, such as methanol, ethanol, propanol, iso-propanol, butanol, iso-butanol and tert-butanol. Suitable bases (deprotonating agents) for carrying out the process (B) according to 30 the invention are all customary proton acceptors. Preference is given to using alkali metal and alkaline earth metal oxides, hydroxides and carbonates, such as sodium Le A 34 460-Foreign Countries hydroxide, potassium hydroxide, magnesium oxide, calcium oxide, sodium carbonate, potassium carbonate and calcium carbonate, which can also be employed in the presence of phase-transfer catalysts, such as, for example, triethylbenzylammonium chloride, tetrabutyl ammonium bromide, Adogen 464 5 (=methyltrialkyl(C8-C10)ammonium chloride) or TDA1 (= tris- (methoxyethoxyethyl)-amine). Alkali metals such as sodium and potassium can also be used. Furthermore, alkali metal and alkaline earth metal amides and hydrides, such as sodium amide, sodium hydride and calcium hydride, and additionally also alkali metal alkoxides, such as sodium methoxide, sodium ethoxide and potassium 10 tert-butoxide can be employed. When carrying out the process (B) according to the invention, the reaction temperatures can be varied within a relatively wide range. In general, the reaction is carried out at temperatures between -80°C and 180°C, preferably between -50°C and 15 120°C. The process (B) according to the invention is generally carried out under atmospheric pressure. 20 When carrying out the process (B) according to the invention, the reaction components of the formula (III) and the deprotonating bases are generally employed in approximately equimolar amounts. However, it is also possible to use a relatively large excess (up to 3 mol) of one component or the other. 25 The process (C) is characterized in that compounds of the formula (IV) in which A, B, Het and R8 are each as defined above are cyclized intramolecularly in the presence of an acid and, if appropriate, in the presence of a diluent. Suitable diluents for the process (C) according to the invention are all inert organic 30 solvents. Preference is given to using hydrocarbons, such as toluene and xylene, furthermore halogenated hydrocarbons, such as dichloromethane, chloroform, Le A 34 460-Foreign Countries ethylene chloride, chlorobenzene, dichlorobenzene, moreover polar solvents, such as dimethyl sulphoxide, sulpholane, dimethylformamide and N-methyl-pyrrolidone. Furthermore, it is possible to employ alcohols such as methanol, ethanol, propanol, iso-propanol, butanol, isobutanol, tert-butanol. 5 If appropriate, the acid used can also serve as diluent. Suitable acids for the process (C) according to the invention are all customary inorganic and organic acids, such as, for example, hydrohalic acids, sulphuric acid, 10 alkyl-, aryl- and haloalkylsulphonic acids, in particular halogenated alkylcarboxylic acids, such as, for example, trifluoroacetic acid. When carrying out the process (C) according to the invention, the reaction temperatures can be varied within a relatively wide range. In general, the reaction is 15 carried out at temperatures between -30°C and 250°C, preferably between 0°C and 150°C. The process (C) according to the invention is generally carried out under atmospheric pressure. 20 When carrying out the process (C) according to the invention, the reaction components of the formula (IV) and the acid are employed, for example, in equimolar amounts. However, it is also possible, if appropriate, to use the acid as solvent or as catalyst. 25 The process (D-a) is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are in each case reacted with carbonyl halides of the formula (V), if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. Le A 34 460-Foreign Countries Suitable diluents for the process (D-a) according to the invention are all solvents which are inert towards the acyl halides. Preference is given to using hydrocarbons such as benzine, benzene, toluene, xylene and tetraline, furthermore halogenated hydrocarbons, such as methylene chloride, chloroform, carbon tetrachloride, 5 chlorobenzene and o-dichlorobenzene, moreover ketones, such as acetone and methyl isopropyl ketone, furthermore ethers, such as diethyl ether, tetrahydrofuran and dioxane, additionally carboxylic esters, such as ethyl acetate, nitriles, such as acetonitrile, and also strongly polar solvents, such as dimethylformamide, dimethylacetamide, dimethyl sulphoxide and sulpholane. The hydrolytic stability of 10 the acyl halide permitting, the reaction can also be carried out in the presence of water. Suitable acid binders for the reaction according to the process (D-a) according to the invention are all customary acid acceptors. Preference is given to using tertiary 15 amines, such as triethylamine, pyridine, diazabicyclooctane (DABCO), diazabicycloundecene (DBU), diazabicyclononene (DBN), Hiinig base and N,N-dimethyl-aniline, furthermore alkaline earth metal oxides, such as magnesium oxide and calcium oxide, moreover alkali metal and alkaline earth metal carbonates, such as sodium carbonate, potassium carbonate and calcium carbonate, and also 20 alkali metal hydroxides, such as sodium hydroxide and potassium hydroxide. The reaction temperatures in the process (D-a) according to the invention can be varied within a relatively wide range. In general, the reaction is carried out at temperatures between -20°C and +150°C, preferably between 0°C and 100°C. 25 When carrying out the process (D-a) according to the invention, the starting materials of the formulae (I-l-A-a) to (I-3-B-a) and the carbonyl halide of the formula (V) are generally in each case employed in approximately equivalent amounts. However, it is also possible to employ a relatively large excess (up to 30 5 mol) of the carbonyl halide. Work-up is carried out by customary methods. Le A 34 460-Foreign Countries The process (D-B) is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are reacted with carboxylic anhydrides of the formula (VI), if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. 5 Preferred diluents for the process (D-B) according to the invention are those diluents which are also preferred when acyl halides are used. Otherwise, it is also possible for a carboxylic anhydride employed in excess to act simultaneously as diluent. In the process (D-B), acid binders which are added, if appropriate, are preferably 10 those acid binders which are also preferred when acyl halides are used. In the process (D-B) according to the invention, the reaction temperatures can be varied within a relatively wide range. In general, the reaction is carried out at temperatures between -20°C and +150°C, preferably between 0°C and 100°C. 15 When carrying out the process (D-B) according to the invention, the starting materials of the formulae (I-l-A-a) to (I-3-B-a) and the carboxylic anhydride of the formula (VI) are generally each employed in approximately equivalent amounts. However, it is also possible to use a relatively large excess (up to 5 mol) of the carboxylic 20 anhydride. Work-up is carried out by customary methods. In general, the adopted procedure is to remove diluent and excess carboxylic anhydride and also the carboxylic acid formed by distillation or by washing with an organic solvent or with water. 25 The process (E) is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are in each case reacted with chloroformic esters or chloroformic thioesters of the formula (VII), if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. 30 Le A 34 460-Foreign Countries Suitable acid binders for the reaction according to process (E) according to the invention are all customary acid acceptors. Preference is given to using tertiary amines, such as triethylamine, pyridine, DABCO, DBU, DBA, Hiinig base and N,N- dimethyl-aniline, furthermore alkaline earth metal oxides, such as magnesium oxide 5 and calcium oxide, moreover alkali metal carbonates and alkaline earth metal carbonates, such as sodium carbonate, potassium carbonate and calcium carbonate, and also alkali metal hydroxides, such as sodium hydroxide and potassium hydroxide. 10 Suitable diluents for the process (E) according to the invention are all solvents which are inert towards the chloroformic esters or chloroformic thioesters. Preference is given to using hydrocarbons, such as benzine, benzene, toluene, xylene and tetraline, furthermore halogenated hydrocarbons, such as methylene chloride, chloroform, carbon tetrachloride, chlorobenzene and o-dichlorobenzene, moreover ketones, such 15 as acetone and methyl isopropyl ketone, furthermore ethers, such as diethyl ether, tetrahydrofuran and dioxane, additionally carboxylic esters, such as ethyl acetate, nitriles, such as acetonitrile, and also strongly polar solvents, such as dimethylformamide, dimethylacetamide, dimethyl sulphoxide and sulpholane. 20 When carrying out the process (E) according to the invention, the reaction temperatures can be varied within a relatively wide range. If the reaction is carried out in the presence of a diluent and an acid binder, the reaction temperatures are generally between -20°C and +100°C, preferably between 0°C and 50°C. 25 The process (E) according to the invention is generally carried out under atmospheric pressure. When carrying out the process (E) according to the invention, the starting materials of the formulae (I-l-A-a) to (I-3-B-a) and the appropriate chloroformic ester or 30 chloroformic thioester of the formula (VII) are generally in each case employed in approximately equivalent amounts. However, it is also possible to employ a relatively Le A 34 460-Foreign Countries large excess (up to 2 mol) of one component or the other. Work-up is carried out by customary methods. In general, precipitated salts are removed and the reaction mixture that remains is concentrated by stripping the diluent. 5 The process (F) according to the invention is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are in each case reacted with compounds of the formula (VIII) in the presence of a diluent and, if appropriate, in the presence of an acid binder. 10 In the preparation process (F), approximately 1 mole of chloromonothioformic ester or chlorodithioformic ester of the formula (VIII) is reacted per mole of starting material of the formulae (I-l-A-a) to (I-3-B-a), at from 0 to 120°C, preferably from 20 to 60°C. 15 Suitable diluents which are added, if appropriate, are all inert polar organic solvents, such as nitriles, esters, ethers, amides, sulphones, sulphoxides, but also halogenoalkanes. Preference is given to using acetonitrile, ethyl acetate, dimethylsulphoxide, 20 tetrahydrofuran, dimethylformamide or methylene chloride. If, in a preferred embodiment, the enolate salt of the compounds (I-l-A-a) to (I-3-B- a) is prepared by addition of strong deprotonating agents, such as, for example, sodium hydride or potassium tert-butoxide, it is not necessary to add further acid 25 binders. If acid binders are employed, these are customary inorganic or organic bases, for example sodium hydroxide, sodium carbonate, potassium carbonate, pyridine, triethylamine. 30 Le A 34 460-Foreign Countries The reaction can be carried out at atmospheric pressure or under elevated pressure and is preferably carried out at atmospheric pressure. Work-up is carried out by customary methods. 5 The process (G) according to the invention is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are in each case reacted with sulphonyl chlorides of the formula (IX), if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. 10 In the preparation process (G), approximately 1 mole of sulphonyl chloride of the formula (IX) is reacted per mole of starting material of the formulae (I-l-A-a) to (I-3-B-a) at from -20 to 150°C, preferably at from 20 to 70°C. Suitable diluents which are added if appropriate are all inert polar organic solvents, 15 such as nitriles, esters, ethers, amides, sulphones, sulphoxides or halogenated hydrocarbons, such as methylene chloride. Preference is given to using acetonitrile, ethyl acetate, dimethyl sulphoxide, tetrahydrofuran, dimethylformamide, methylene chloride. 20 If, in a preferred embodiment, the enolate salt of the compounds (I-l-A-a) to (I-3-B-a) is prepared by addition of strong deprotonating agents (such as, for example, sodium hydride or potassium tert-butoxide), it is not necessary to add further acid binders. 25 If acid binders are employed, these are customary inorganic or organic bases, for example sodium hydroxide, sodium carbonate, potassium carbonate, pyridine, triethylamine. Le A 34 460-Foreign Countries The reaction can be carried out at atmospheric pressure or under elevated pressure and is preferably carried out at atmospheric pressure. Work-up is carried out by customary methods. 5 The process (H) according to the invention is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are in each case reacted with phosphorus compounds of the formula (X), if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. 10 In the preparation process (H), 1 to 2, preferably 1 to 1.3, mol of the phosphorus compound of the formula (X) are reacted per mole of the compounds (M-A-a) to (I-3-B-a), at temperatures between -40°C and 150°C, preferably between -10 and 110°C, to give compounds of the formulae (I-l-A-e) to (I-3-B-e). 15 Suitable solvents which are added, if appropriate, are all inert polar organic solvents, such as ethers, amides, nitriles, alcohols, sulphides, sulphones, sulphoxides, etc. Preference is given to using acetonitrile, dimethyl sulphoxide, tetrahydrofuran, dimethylformamide, methylene chloride. 20 Suitable acid binders which are added, if appropriate, are customary inorganic or organic bases, such as hydroxides, carbonates or amines. Examples include sodium hydroxide, sodium carbonate, potassium carbonate, pyridine, triethylamine. 25 The reaction can be carried out at atmospheric pressure or under elevated pressure and is preferably carried out at atmospheric pressure. Work-up is carried out by customary methods of organic chemistry. The resulting end products are preferably purified by crystallization, chromatographic purification or by so-called "incipient distillation", i.e. removal of the volatile components under reduced pressure. 30 Le A 34 460-Foreign Countries The process (I) is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are reacted with metal hydroxides or metal alkoxides of the formula (XI) or amines of the formula (XII), if appropriate in the presence of a diluent. 5 Preferred diluents for the process (I) according to the invention are ethers, such as tetrahydrofuran, dioxane, diethyl ether, or else alcohols, such as methanol, ethanol, isopropanol, but also water. The process (I) according to the invention is generally carried out under atmospheric 10 pressure. The reaction temperatures are generally between -20°C and 100°C, preferably between 0°C and 50°C 15 The process (J) according to the invention is characterized in that compounds of the formulae (I-l-A-a) to (I-3-B-a) are in each case reacted (J-a) with compounds of the formula (XIII), if appropriate in the presence of a diluent and if appropriate in the presence of a catalyst, or (J-B) with compounds of the formula (XIV), if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. 20 In the preparation process (J-a), approximately 1 mole of isocyanate of the formula (XIII) is reacted per mole of starting material of the formulae (I-l-A-a) to (I-3-B-a), at from 0 to 100°C, preferably at from 20 to 50°C. 25 Suitable diluents which are added, if appropriate, are all inert organic solvents, such as ethers, amides, nitriles, sulphones, sulphoxides. If appropriate, catalysts may be added to accelerate the reaction. Very advantageously, the catalysts which are employed are organotin compounds, such as, 30 for example, dibutyltin dilaurate. The reaction is preferably carried out at atmospheric pressure. Le A 34 460-Foreign Countries In the preparation process (J-B), approximately 1 mole of carbamoyl chloride of the formula (XIV) is reacted per mole of starting material of the formulae (I-l-A-a) to (I-3-B-a), at from -20 to l50°C, preferably from 0 to 70°C.z 5 Suitable diluents which are added, if appropriate, are all inert polar organic solvents, such as nitriles, esters, ethers, amides, sulphones, sulphoxides or halogenated hydrocarbons. 10 Preference is given to using acetonitrile, ethyl acetate, dimethyl sulphoxide, tetrahydrofuran, dimethylformamide or methylene chloride. If, in a preferred embodiment, the enolate salt of the compounds (M-A-a) to (I-3-B-a) is prepared by addition of strong deprotonating agents (such as, for 15 example, sodium hydride or potassium tert-butoxide), it is not necessary to add further acid binders. If acid binders are employed, these are customary inorganic or organic bases, for example sodium hydroxide, sodium carbonate, potassium carbonate, triethylamine or 20 pyridine. The reaction can be carried out at atmospheric pressure or under elevated pressure and is preferably carried out at atmospheric pressure. Work-up is carried out by customary methods. 25 The active compounds are suitable for controlling animal pests, in particular insects, arachnids and nematodes, which are encountered in agriculture, in forestry, in the protection of stored produces and of materials, and in the hygiene sector, and have good plant tolerance and favourable toxicity to warm-blooded animals. They may be 30 preferably employed as plant protection agents. They are active against normally Le A 34 460-Foreign Countries sensitive and resistant species and against all or some stages of development. The abovementioned pests include: From the order of the Isopoda, for example, Oniscus asellus, Armadillidium vulgare 5 and Porcellio scaber. From the order of the Diplopoda, for example, Blaniulus guttulatus. From the order of the Chilopoda, for example, Geophilus carpophagus and Scutigera spp. From the order of the Symphyla, for example, Scutigerella immaculata. 10 From the order of the Thysanura, for example, Lepisma saccharina. From the order of the Collembola, for example, Onychiurus armatus. From the order of the Orthoptera, for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp. and Schistocerca gregaria. From the order of the Blattaria, for example, Blatta orientalis, Periplaneta americana, 15 Leucophaea maderae, Blattella germanica. From the order of the Dermaptera, for example, Forficula auricularia. From the order of the Isoptera, for example, Reticulitermes spp. From the order of the Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp. and Damalinia spp. 20 From the order of the Thysanoptera, for example, Hercinothrips femoralis, Thrips tabaci, Thrips palmi and Frankliniella accidentalis. From the order of the Heteroptera, for example, Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus and Triatoma spp. From the order of the Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, 25 Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium comi, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella 30 aurantii, Aspidiotus hederae, Pseudococcus spp. and Psylla spp. Le A 34 460-Foreign Countries From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., 5 Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus 10 spp., Oulema oryzae. From the order of the Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus 15 surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra 20 zealandica and Lissorhoptrus oryzophilus. From the order of the Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis and Vespa spp. From the order of the Diptera, for example, Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia 25 spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp. and Liriomyza spp. From the order of the Siphonaptera, for example, Xenopsylla cheopis and 30 Ceratophyllus spp. Le A 34 460-Foreign Countries From the class of the Arachnida, for example, Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Omithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., 5 Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp. The phytoparasitic nematodes include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera 10 spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp. If appropriate, the compounds according to the invention can, at certain concentrations or application rates, also be used as herbicides or microbicides, for 15 example as fungicides, antimycotics and bactericides. If appropriate, they can also be employed as intermediates or precursors for the synthesis of other active compounds. All plants and plant parts can be treated in accordance with the invention. Plants are to be understood as meaning in the present context all plants and plant populations 20 such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional plant breeding and optimization methods or by biotechnological and recombinant methods or by combinations of these methods, including the transgenic plants and inclusive of the plant cultivars protectable or not protectable by plant 25 breeders' rights. Plant parts are to be understood as meaning all parts and organs of plants above and below the ground, such as shoot, leaf, flower and root, examples which may be mentioned being leaves, needles, stalks, stems, flowers, fruit bodies, fruits, seeds, roots, tubers and rhizomes. The plant parts also include harvested material, and vegetative and generative propagation material, for example cuttings,, 30 tubers, rhizomes, offsets and seeds. Le A 34 460-Foreign Countries Treatment according to the invention of the plants and plant parts with the active compounds is carried out directly or by allowing the compounds to act on the surroundings, environment or storage space by the customary treatment methods, for example by immersion, spraying, evaporation, fogging, scattering, painting on and, in 5 the case of propagation material, in particular in the case of seeds, also by applying one or more coats. As already mentioned above, it is possible to treat all plants and their parts according to the invention. In a preferred embodiment, wild plant species and plant cultivars, or 10 those obtained by conventional biological breeding, such as crossing or protoplast fusion, and parts thereof, are treated. In a further preferred embodiment, transgenic plants and plant cultivars obtained by genetical engineering, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated. The term "parts" or "parts of plants" or "plant parts" has been 15 explained above. Particularly preferably, plants of the plant cultivars which are in each case commercially available or in use are treated according to the invention. 20 Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention may also result in superadditive ("synergistic") effects. Thus, for example, reduced application rates and/or a widening of the activity spectrum and/or an increase in the activity of the substances and compositions to be used according to 25 the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated maturation, higher harvest yields, better quality and/or a higher nutritional value of the harvested products, better storage stability and/or processability of the harvested products are possible which exceed the 30 effects which were actually to be expected. Le A 34 460-Foreign Countries The transgenic plants or plant cultivars (i.e. those obtained by genetical engineering) which are preferably to be treated according to the invention include all plants which, in the genetic modification, received genetic material which imparted particularly advantageous useful properties ("traits") to these plants. Examples of such properties 5 are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated maturation, higher harvest yields, better quality and/or a higher nutritional value of the harvested products, better storage stability and/or processability of the harvested products. Further and particularly emphasized 10 examples of such properties are a better defence of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and/or viruses, and also increased tolerance of the plants to certain herbicidally active compounds. Examples of transgenic plants which may be mentioned are the important crop plants, such as cereals (wheat, rice), maize, soya beans, potatoes, 15 cotton, oilseed rape and also fruit plants (with the fruits apples, pears, citrus fruits and grapes), and particular emphasis is given to maize, soya beans, potatoes, cotton and oilseed rape. Traits that are emphasized are in particular increased defence of the plants against insects by toxins formed in the plants, in particular those formed in the plants by the genetic material from Bacillus thuringiensis (for example by the genes 20 CrylA(a), CrylA(b), CrylA(c), CryIIA, CryIIIA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and also combinations thereof) (hereinbelow referred to as "Bt plants"). Traits that are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulphonylureas, glyphosate or phosphinotricin (for example the "PAT" gene). The 25 genes which impart the desired traits in question can also be present in combination with one another in the transgenic plants. Examples of "Bt plants" which may be mentioned are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD® (for example maize, cotton, soya beans), KnockOut® (for example maize), StarLink® (for example 30 maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato). Examples of herbicide-tolerant plants which may be mentioned are maize varieties, cotton Le A 34 460-Foreign Countries varieties and soya bean varieties which are sold under the trade names Roundup Ready® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link® (tolerance to phosphinotricin, for example oilseed rape), IMI® (tolerance to imidazolinones) and STS® (tolerance to sulphonylurea, for example maize). 5 Herbicide-resistant plants (plants bred in a conventional manner for herbicide tolerance) which may be mentioned include the varieties sold under the name Clearfield® (for example maize). Of course, these statements also apply to plant cultivars having these genetic traits or genetic traits still to be developed, which plants will be developed and/or marketed in the future. 10 The plants listed can be treated according to the invention in a particularly advantageous manner with the compounds of the formula (I). The preferred ranges stated above for the active compounds also apply to the treatment of these plants. Particular emphasis is given to the treatment of plants with the mixtures specifically 15 mentioned in the present text. The active compounds can be converted to the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials 20 impregnated with active compound and microencapsulations in polymeric substances. These formulations are produced in a known manner, for example by mixing the active compounds with extenders, that is, liquid solvents, and/or solid carriers, optionally with the use of surfactants, that is emulsifiers and/or dispersants, and/or foam-formers. 25 If the extender used is water, it is also possible to employ for example organic solvents as auxiliary solvents. Essentially, suitable liquid solvents are: aromatics such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic 30 hydrocarbons such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and also their ethers and Le A 34 460-Foreign Countries esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulphoxide, and also water. 5 As solid carriers there are suitable: for example ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as highly disperse silica, alumina and silicates; as solid carriers for granules there are suitable: for example crushed and fractionated natural rocks such as 10 calcite, marble, pumice, sepiolite and dolomite, and also synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; as emulsifiers and/or foam-formers there are suitable: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, 15 alkylsulphonates, alkyl sulphates, arylsulphonates and also protein hydrolysates; as dispersants there are suitable: for example lignin-sulphite waste liquors and methylcellulose. Tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the 20 form of powders, granules or latices, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, as well as natural phospholipids such as cephalins and lecithins, and synthetic phospholipids, can be used in the formulations. Other additives can be mineral and vegetable oils. 25 It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc. 30 The formulations generally comprise between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%. Le A 34 460-Foreign Countries The active compound according to the invention can be present in its commercially available formulations and in the use forms, prepared from these formulations, as a mixture with other active compounds, such as insecticides, attractants, sterilizing 5 agents, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides. The insecticides include, for example, phosphoric acid esters, carbamates, carboxylates, chlorinated hydrocarbons, phenylureas and substances produced by microorganisms, inter alia. 10 Particularly favourable examples of co-components in mixtures are the following compounds: Fungicides: aldimorph, ampropylfos, ampropylfos-potassium, andoprim, anilazine, azaconazole, 15 azoxystrobin, benalaxyl, benodanil, benomyl, benzamacril, benzamacryl-isobutyl, bialaphos, binapacryl, biphenyl, bitertanol, blasticidin-S, bromuconazole, bupirimate, buthiobate, calcium polysulphide, capsimycin, captafol, captan, carbendazim, carboxin, carvon, quinomethionate, chlobenthiazone, chlorfenazole, chloroneb, chloropicrin, 20 chlorothalonil, chlozolinate, clozylacon, cufraneb, cymoxanil, cyproconazole, cyprodinil, cyprofuram, debacarb, dichlorophen, diclobutrazole, diclofluanid, diclomezine, dicloran, diethofencarb, difenoconazole, dimethirimol, dimethomorph, diniconazole, diniconazole-M, dinocap, diphenylamine, dipyrithione, ditalimfos, dithianon, 25 dodemorph, dodine, drazoxolon, edifenphos, epoxiconazole, etaconazole, ethirimol, etridiazole, famoxadon, fenapanil, fenarimol, fenbuconazole, fenfuram, fenitropan, fenpiclonil, fenpropidin, fenpropimorph, fentin acetate, fentin hydroxide, ferbam, ferimzone, fluazinam, flumetover, fluoromide, fluquinconazole, flurprimidol, flusilazole, 30 flusulfamide, flutolanil, flutriafol, folpet, fosetyl-aluminium, fosetyl-sodium, fthalide, Le A 34 460-Foreign Countries fuberidazole, furalaxyl, furametpyr, furcarbonil, furconazole, furconazole-cis, furmecyclox, guazatine, hexachlorobenzene, hexaconazole, hymexazole, 5 imazalil, imibenconazole, iminoctadine, iminoctadine albesilate, iminoctadine triacetate, iodocarb, ipconazole, iprobenfos (IBP), iprodione, irumamycin, isoprothiolane, isovaledione, kasugamycin, kresoxim-methyl, copper preparations, such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulphate, copper oxide, oxine-copper and 10 Bordeaux mixture, mancopper, mancozeb, maneb, meferimzone, mepanipyrim, mepronil, metalaxyl, metconazole, methasulfocarb, methfuroxam, metiram, metomeclam, metsulfovax, mildiomycin, myclobutanil, myclozolin, nickel dimethyldithiocarbamate, nitrothal-isopvopyl, nuarimol, 15 ofurace, oxadixyl, oxamocarb, oxolinic acid, oxycarboxim, oxyfenthiin, paclobutrazole, pefurazoate, penconazole, pencycuron, phosdiphen, pimaricin, piperalin, polyoxin, polyoxorim, probenazole, prochloraz, procymidone, propamocarb, propanosine-sodium, propiconazole, propineb, pyrazophos, pyrifenox, pyrimethanil, pyroquilon, pyroxyfur, 20 quinconazole, quintozene (PCNB), sulphur and sulphur preparations, tebuconazole, tecloftalam, tecnazene, tetcyclasis, tetraconazole, thiabendazole, thicyofen, thifluzamide, thiophanate-methy], thiram, tioxymid, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triazbutil, triazoxide, trichlamide, tricyclazole, 25 tridemorph, triflumizole, triforine, triticonazole, uniconazole, validamycin A, vinclozolin, viniconazole, zarilamide, zineb, ziram and also Dagger G, 30 OK-8705, OK-8801, Le A 34 460-Foreign Countries a-( 1, l-dimethylethyl)-β-(2-phenoxyethyl)- 1H-1,2,4-triazole-1 -ethanol, a-(2,4-dichlorophenyl)-β-fluoro-β-propyl-lH-l,2,4-triazole-l-ethanol, a-(2,4-dichlorophenyl)-β-methoxy-a-methyl-lH-l,2,4-triazole-l-ethanol, a-(5-methyl-l,3-dioxan-5-yl)-β-[[4-(trifluoromethyl)-phenyl]-methylene]-lH-l,2,4- 5 triazole-1-ethanol, (5RS,6RS)-6-hydroxy-2,2,7,7-tetramethyl-5-(lH-l,2,4-triazol-l-yl)-3-octanone, (E)-a-(methoxyimino)-N-methyl-2-phenoxy-phenylacetarnide, 1 -isopropyl {2-methyl-1 -[[[ l-(4-methylphenyl)-ethyl]-amino]-carbonyl]-propyl} - carbamate, 10 1 -(2,4-dichlorophenyl)-2-( 1H-1,2,4-triazol-1 -yl)-ethanone-0-(phenylmethyl)-oxime, 1 -(2-methyl-1 -naphthalenyl)-1 H-pyrrol-2,5-dione, l-(3,5-dichlorophenyl)-3-(2-propenyl)-2,5-pyrrolidmdione, l-[(diiodomethyl)-sulphonyl]-4-methyl-benzene, l-[[2-(2,4-dichlorophenyl)-l,3-dioxolan-2-yl]-methyl]-lH-imidazole, 15 1 -[[2-(4-chlorophenyl)-3-phenyloxiranyl]-rnethyl]- 1H-1,2,4-triazole, l-[l-[2-[(2,4-dichlorophenyl)-methoxy]-phenyl]-ethenyl]-lH-imidazole, l-methyl-5-nonyl-2-(phenylmethyl)-3-pyrrolidinole, 2',6'-dibromo-2-methyl-4'-trifluoromethoxy-4'-trifluoro-methyl-l,3-thiazole-5- carboxanilide, 20 2,2-dichloro-N-[l-(4-chlorophenyl)-ethyl]-l-ethyl-3-methyl-cycIopropanecarboxamide, 2,6-dichloro-5-(methylthio)-4-pyrimidinyl-thiocyanate, 2,6-dichloro-N-(4-trifluoromethylbenzyl)-benzamide, 2,6-dichloro-N-[[4-(trifluoromethyl)-phenyl]-methyl]-benzamide, 2-(2,3,3-triiodo-2-propenyl)-2H-tetrazole, 25 2-[(l-methylethyl)-sulphonyl]-5-(trichloromethyl)-l,3,4-thiadiazole, 2-[[6-deoxy-4-0-(4-0-methyl-β-D-glycopyranosyl)-a-D-glucopyranosyl]-amino]-4- methoxy-lH-pyrrolo[2,3-d]pyrimidine-5-carbonitrile, 2-aminobutane, 2-bromo-2-(bromomethyl)-pentanedinitrile, 30 2-chloro-N-(2,3-dihydro-l,l,3-trimethyl-lH-inden-4-yl)-3-pyridinecarboxamide, 2-chloro-N-(2,6-dimethylphenyl)-N-(isothiocyanatomethyl)-acetamide, Le A 34 460-Foreign Countries 2-phenylphenol (OPP), 3,4-dichloro-l-[4-(difluoromethoxy)-phenyl]-lH-pyrrol-2,5-dione, 3,5-dichIoro-N-[cyano[(l-methy]-2-propynyl)-oxy]-methy]]-benzamide, 3-( 1,1 -dimethylpropyl-1 -oxo-1 H-indene-2-carbonitrile, 5 3-[2-(4-chlorophenyl)-5-ethoxy-3-isoxazolidinyl]-pyridine, 4-chloro-2-cyano-N,N-dimethyl-5-(4-methylphenyl)-1 H-imidazole-1 -sulphonamide, 4-methyl-tetrazolo[ 1,5-a]quinazolin-5(4H)-one, 8-( 1,1 -dimethylethyl)-N-ethyl-N-propyl-1,4-dioxaspiro[4.5]decane-2-methanamine, 8-hydroxyquinoline sulphate, 10 9H-xanthene-2-[(phenylamino)-carbonyl]~9-carboxyIic hydrazide, bis-(l-methylethyl)-3-methyl-4-[(3-methylbenzoyl)-oxy]-2,5-thiophenedicarboxylate, cis-1 -(4-chlorophenyl)-2-( 1 H-l ,2,4-triazol-1 -yl)-cycloheptanol, cis-4-[3-[4-(l,l-dimethylpropyl)-phenyl-2-methylpropyl]-2,6-dimethyl-morpholine hydrochloride, 15 ethyl [(4-chlorophenyl)-azo]-cyanoacetate, potassium bicarbonate, methanetetrathiol-sodium salt, methyl l-(2,3-dihydro-2,2-dimethyl-lH-inden-l-yl)-lH-imidazole-5-carboxylate, methyl N-(2,6-dimethylphenyl)-N-(5-isoxazolylcarbonyl)-DL-alaninate, 20 methyl N-(chloroacetyl)-N-(2,6-dimethylphenyl)-DL-alaninate, N-(2,3-dichloro-4-hydroxyphenyl)-l-methyl-cyclohexanecarboxamide. N-(2,6-dimethylphenyl)-2-methoxy-N-(tetrahydro-2-oxo-3-furanyl)-acetamide, N-(2,6-dimethylphenyl)-2-methoxy-N-(tetrahydro-2-oxo-3-thienyl)-acetamide, N-(2-chloro-4-nitrophenyl)-4-methyl-3-nitro-benzenesulphonamide, 25 N-(4-cyclohexylphenyl)-l,4,5,6-tetrahydro-2-pyrimidinamine, N-(4-hexylphenyl)-l,4,5,6-tetrahydro-2-pyrimidinamine, N-(5-chloro-2-methylphenyl)-2-methoxy-N-(2-oxo-3-oxazolidinyl)-acetamide, N-(6-methoxy)-3-pyridinyl)-cyclopropanecarboxamide, N-[2,2,2-trichloro-l-[(chloroacetyI)-amino]-ethyl]-benzamide, 30 N-[3-chloro-4,5-bis(2-propinyloxy)-phenyl]-N'-methoxy-methanimidamide, N-formyl-N-hydroxy-DL-alanine-sodiurn salt, Le A 34 460-Foreign Countries 0,0-diethyl [2-(dipropylamino)-2-oxoethyl]-ethylphosphoramidothioate, O-methyl S-phenyl phenylpropylphosphoramidothioate, S-methyl 1,2,3-benzothiadiazole-7-carbothioate, spiro[2H]-l-benzopyrane-2,r(3'H)-isobenzofuran]-3'-one, 5 Bactericides: bronopol, dichlorophen, nitrapyrin, nickel dimethyldithiocarbamate, kasugamycin, octhilinone, furancarboxylic acid, oxytetracyclin, probenazole, streptomycin, tecloftalam, copper sulphate and other copper preparations. 10 Insecticides / acaricides / nematicides: abamectin, acephate, acetamiprid, acrinathrin, alanycarb, aldicarb, aldoxycarb, alpha- cypermethrin, alphamethrin, amitraz, avermectin, AZ 60541, azadirachtin, azamethiphos, azinphos A, azinphos M, azocyclotin, 15 Bacillus popilliae, Bacillus sphaericus, Bacillus subtilis, Bacillus thuringiensis, baculoviruses, Beauveria bassiana, Beauveria tenella, bendiocarb, benfuracarb, bensultap, benzoximate, betacyfluthrin, bifenazate, bifenthrin, bioethanomethrin, biopermethrin, BPMC, bromophos A, bufencarb, buprofezin, butathiofos, butocarboxim, butylpyridaben, 20 cadusafos, carbaryl, carbofuran, carbophenothion, carbosulfan, cartap, chloethocarb, chlorethoxyfos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chlorpyrifos, chlorpyrifos M, chlovaporthrin, cis-resmethrin, cispermethrin, clocythrin, cloethocarb, clofentezine, cyanophos, cycloprene, cycloprothrin, cyfluthrin, cyhalothrin, cyhexatin, cypermethrin, cyromazine, 25 deltamethrin, demeton M, demeton S, demeton-S-methyl, diafenthiuron, diazinon, dichlorvos, diflubenzuron, dimethoate, dimethylvinphos, diofenolan, disulfoton, docusat-sodium, dofenapyn, eflusilanate, emamectin, empenthrin, endosulfan, Entomopfthora spp., esfenvalerate, ethiofencarb, ethion, ethoprophos, etofenprox, etoxazole, etrimfos, 30 fenamiphos, fenazaquin, fenbutatin oxide, fenitrothion, fenothiocarb, fenoxacrim, fenoxycarb, fenpropathrin, fenpyrad, fenpyrithrin, fenpyroximate, fenvalerate, Le A 34 460-Foreign Countries fipronil, fluazinam, fluazuron, flubrocythrinate, flucycloxuron, flucythrinate, flufenoxuron, flutenzine, fluvalinate, fonophos, fosmethilan, fosthiazate, fubfenprox, furathiocarb, granulosis viruses, 5 halofenozide, HCH, heptenophos, hexaflumuron, hexythiazox, hydroprene, imidacloprid, isazofos, isofenphos, isoxathion, ivermectin, nuclear polyhedrosis viruses, lambda-cyhalothrin, lufenuron, malathion, mecarbam, metaldehyde, methamidophos, Metharhizium anisopliae, 10 Metharhizium flavoviride, methidathion, methiocarb, methomyl, methoxyfenozide, metolcarb, metoxadiazone, mevinphos, milbemectin, monocrotophos, naled, nitenpyram, nithiazine, novaluron, omethoate, oxamyl, oxydemethon M, Paecilomyces fumosoroseus, parathion A, parathion M, permethrin, phenthoate, 15 phorate, phosalone, phosmet, phosphamidon, phoxim, pirimicarb, pirimiphos A, pirimiphos M, profenofos, promecarb, propoxur, prothiofos, prothoate, pymetrozine, pyraclofos, pyresmethrin, pyrethrum, pyridaben, pyridathion, pyrimidifen, pyriproxyfen, quinalphos, 20 ribavirin, salithion, sebufos, silafluofen, spinosad, sulfotep, sulprofos, tau-fluvalinate, tebufenozide, tebufenpyrad, tebupirimiphos, teflubenzuron, tefluthrin, temephos, temivinphos, terbufos, tetrachlorvinphos, theta-cypermethrin, thiamethoxam, thiapronil, thiatriphos, thiocyclam hydrogen oxalate, thiodicarb, 25 thiofanox, thuringiensin, tralocythrin, tralomethrin, triarathene, triazamate, triazophos, triazuron, trichlophenidine, trichlorfon, triflumuron, trimethacarb, vamidothion, vaniliprole, Verticillium lecanii, YI 5302, zeta-cypermethrin, zolaprofos, 30 (lR-cis)-[5-(phenyImethyl)-3-furanyl]-methyl-3-[(dihydro-2-oxo-3(2H)- furanylidene)-methyl]-2,2-dirnethylcyclopropanecarboxyIate, Le A 34 460-Foreign Countries (3-phenoxyphenyl)-methyl-2,2,3,3-tetramethylcyclopropanecarboxylate, l-[(2-chloro-5-thiazolyl)methyl]tetrahydro-3,5-dimethyl-N-nitro-l,3,5-triazine- 2(lH)-imine, 2-(2-chloro-6-fluorophenyl)-4-[4-(l,l-dimethylethyl)phenyI]-4,5-dihydro-oxazole, 5 2-(acetyloxy)-3-dodecyl-1,4-naphthalenedione, 2-chloro-N-[[[4-(l-phenylethoxy)-phenyl]-amino]-carbonyl]-benzamide, 2-chloro-N-[[[4-(2,2-dichloro-l,l-difluoroethoxy)-phenyl]-amino]-carbonyl]- benzamide, 3-methylphenyl propylcarbamate. 10 4-[4-(4-ethoxyphenyl)-4-methylpentyl]-l-fluoro-2-phenoxy-benzene, 4-chloro-2-(l,l-dimethylethyl)-5-[[2-(2,6-dimethyl-4-phenoxyphenoxy)ethyl]thio]- 3(2H)-pyridazinone, 4-chloro-2-(2-chloro-2-methylpropyl)-5-[(6-iodo-3-pyridinyl)methoxy]-3(2H)- pyridazinone, 15 4-chloro-5-[(6-chloro-3-pyridinyl)methoxy]-2-(3,4-dichlorophenyl)-3(2H)- pyridazinone, Bacillus thuringiensis strain EG-2348, [2-benzoyl-1 -(1,1 -dimethylethyl)-hydrazinobenzoic acid, 2,2-dimethyl-3-(2,4-dichlorophenyl)-2-oxo-l-oxaspiro[4.5]dec-3-en-4-yl butanoate, 20 [3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]-cyanamide, dihydro-2-(nitromethylene)-2H-l,3-thiazine-3(4H)-carboxaldehyde, ethyl [2-[[l,6-dihydro-6-oxo-l-(phenylmethyl)-4-pyridazinyl]oxy]ethyl]-carbamate, N-(3,4,4-trifluoro-l-oxo-3-butenyl)-glycine, N-(4-chlorophenyl)-3-[4-(difluoromethoxy)phenyl]-4,5-dihydro-4-phenyl-lH- 25 pyrazole-1-carboxamide, N-[(2-chloro-5-thiazolyl)methyl]-N'-methyl-N"-nitro-guanidine, N-methyl-N'-(l-methyl-2-propenyl)-l,2-hydrazinedicarbothioamide, N-methyI-N'-2-propenyl-l,2-hydrazinedicarbothioamide, 0,0-diethyl [2-(dipropylamino)-2-oxoethyl]-ethylphosphoramidothioate. 30 Le A 34 460-Foreign Countries It is also possible to admix other known active compounds, such as herbicides, fertilizers and growth regulators. When used as insecticides, the active compounds according to the invention can 5 furthermore be present in their commercially available formulations and in the use forms, prepared from these formulations, as a mixture with synergistic agents. Synergistic agents are compounds which increase the action of the active compounds, without it being necessary for the synergistic agent added to be active itself. 10 The active compound content of the use forms prepared from the commercially available formulations can vary within wide limits. The active compound concentration of the use forms can be from 0.0000001 to 95% by weight of active compound, preferably between 0.0001 and 1% by weight. 15 The compounds are employed in a customary manner appropriate for the use forms. When used against hygiene pests and pests of stored products, the active compound is distinguished by an excellent residual action on wood and clay as well as a good Stability to alkali on limed substrates. 20 The active compounds according to the invention act not only against plant, hygiene and stored product pests, but also in the veterinary medicine sector against animal parasites (ectoparasites), such as hard ticks, soft ticks, mange mites, leaf mites, flies (biting and licking), parasitic fly larvae, lice, hair lice, feather lice and fleas. These 25 parasites include: From the order of the Anoplurida, for example, Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp. and Solenopotes spp. From the order of the Mallophagida and the suborders Amblycerina and 30 Ischnocerina, for example, Trimenopon spp., Menopon spp., Trinoton spp., Bovicola Le A 34 460-Foreign Countries spp., Wemeckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp. and Felicola spp. From the order of the Diptera and the suborders Nematocerina and Brachycerina, for example, Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., 5 Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca 10 spp., Lipoptena spp. and Melophagus spp. From the order of the Siphonapterida, for example Pulex spp., Ctenocephalides spp., Xenopsylla spp. and Ceratophyllus spp. From the order of the Heteropterida, for example, Cimex spp., Triatoma spp., Rhodnius spp. and Panstrongylus spp. 15 From the order of the Blattarida, for example Blatta orientalis, Periplaneta americana, Blattela germanica and Supella spp. From the subclass of the Acaria (Acarida) and the orders of the Meta- and Mesostigmata, for example, Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., 20 Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp. and Varroa spp. From the order of the Actinedida (Prostigmata) und Acaridida (Astigmata), for example, Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., 25 Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp. and Laminosioptes spp. The active compounds of the formula (I) according to the invention are also suitable 30 for controlling arthropods which infest agricultural productive livestock, such as, for example, cattle, sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, Le A 34 460-Foreign Countries chickens, turkeys, ducks, geese and bees, other pets, such as, for example, dogs, cats, caged birds and aquarium fish, and also so-called test animals, such as, for example, hamsters, guinea pigs, rats and mice. By controlling these arthropods, cases of death and reduction in productivity (for meat, milk, wool, hides, eggs, honey etc.) should 5 be diminished, so that more economic and easier animal husbandry is possible by use of the active compounds according to the invention. The active compounds according to the invention are used in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, 10 capsules, potions, drenches, granules, pastes, boluses, the feed-through process and suppositories, by parenteral administration, such as, for example, by injection (intramuscular, subcutaneous, intravenous, intraperitoneal and the like), implants by nasal administration, by dermal use in the form, for example, of dipping or bathing, spraying, pouring on and spotting on, washing and powdering, and also with the aid 15 of molded articles containing the active compound, such as collars, ear marks, tail marks, limb bands, halters, marking devices and the like. When used for cattle, poultry, pets and the like, the active compounds of the formula (I) can be used as formulations (for example powders, emulsions, free-flowing 20 compositions), which comprise the active compounds in an amount of 1 to 80% by weight, directly or after 100 to 10 000-fold dilution, or they can be used as a chemical bath. It has furthermore been found that the compounds of the formula (I) according to the 25 invention also have a strong insecticidal action against insects which destroy industrial materials. The following insects may be mentioned as examples and as preferred - but without a limitation: 30 Beetles, such as Le A 34 460-Foreign Countries Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticomis, Dendrobium pertinex, Emobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron 5 spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus. Hymenopterons, such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur. 10 Termites, such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus. 15 Bristletails, such as Lepisma saccarina. Industrial materials in the present connection are to be understood as meaning non-living materials, such as, preferably, plastics, adhesives, sizes, papers and cards, leather, wood and processed wood products and coating compositions. 20 Wood and processed wood products are materials to be protected, especially preferably, from insect infestation. Wood and processed wood products which can be protected by the agents according 25 to the invention or mixtures comprising these are to be understood as meaning, for example: building timber, wooden beams, railway sleepers, bridge components, boat jetties, wooden vehicles, boxes, pallets, containers, telegraph poles, wood panelling, wooden windows and doors, plywood, chipboard, joinery or wooden products which are used quite generally in house-building or in building joinery. 30 Le A 34 460-Foreign Countries The active compounds can be used as such, in the form of concentrates or in generally customary formulations, such as powders, granules, solutions, suspensions, emulsions or pastes. 5 The formulations mentioned can be prepared in a manner known per se, for example by mixing the active compounds with at least one solvent or diluent, emulsifier, dispersing agent and/or binder or fixing agent, a water repellent, if appropriate siccatives and UV stabilizers and if appropriate dyestuffs and pigments, and also other processing auxiliaries. 10 The insecticidal compositions or concentrates used for the preservation of wood and wood-derived timber products comprise the active compound according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight. 15 The amount of the compositions or concentrates employed depends on the nature and occurrence of the insects and on the medium. The optimum amount employed can be determined for the use in each case by a series of tests. In general, however, it is sufficient to employ 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of 20 the active compound, based on the material to be preserved. Solvents and/or diluents which are used are an organic chemical solvent or solvent mixture and/or an oily or oil-like organic chemical solvent or solvent mixture of low volatility and/or a polar organic chemical solvent or solvent mixture and/or water, 25 and if appropriate an emulsifier and/or wetting agent. Organic chemical solvents which are preferably used are oily or oil-like solvents having an evaporation number above 35 and a flashpoint above 30°C, preferably above 45°C. Substances which are used as such oily or oil-like water-insoluble 30 solvents of low volatility are appropriate mineral oils or aromatic fractions thereof, or Le A 34 460-Foreign Countries solvent mixtures containing mineral oils, preferably white spirit, petroleum and/or alkylbenzene. Mineral oils having a boiling range from 170 to 220°C, white spirit having a boiling 5 range from 170 to 220°C, spindle oil having a boiling range from 250 to 350°C, petroleum and aromatics having a boiling range from 160 to 280°C, terpentine oil and the like, are advantageously employed. In a preferred embodiment, liquid aliphatic hydrocarbons having a boiling range from 10 180 to 210°C or high-boiling mixtures of aromatic and aliphatic hydrocarbons having a boiling range from 180 to 220°C and/or spindle oil and/or monochloronaphthalene, preferably a-monochloronaphthalene, are used. The organic oily or oil-like solvents of low volatility which have an evaporation 15 number above 35 and a flashpoint above 30°C, preferably above 45°C, can be replaced in part by organic chemical solvents of high or medium volatility, providing that the solvent mixture likewise has an evaporation number above 35 and a flashpoint above 30°C, preferably above 45°C, and that the insecticide/fungicide mixture is soluble or emulsifiable in this solvent mixture. 20 According to a preferred embodiment, some of the organic chemical solvent or solvent mixture is replaced by an aliphatic polar organic chemical solvent or solvent mixture. Aliphatic organic chemical solvents containing hydroxy! and/or ester and/or ether groups, such as, for example, glycol ethers, esters or the like, are preferably 25 used. Organic chemical binders which are used in the context of the present invention are the synthetic resins and/or binding drying oils which are known per se, are water- dilutable and/or are soluble or dispersible or emulsifiable in the organic chemical 30 solvents employed, in particular binders consisting of or comprising an acrylate resin, a vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation or Le A 34 460-Foreign Countries polyaddition resin, polyurettfane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin, such as indene-cumarone resin, silicone resin, drying vegetable oils and/or drying oils and/or physically drying binders based on a natural and/or synthetic resin. 5 The synthetic resin used as the binder can be employed in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances can also be used as binders in an amount of up to 10% by weight. Dyestuffs, pigments, water-repelling agents, odour correctants and inhibitors or anticorrosive agents and the like which are known 10 per se can additionally be employed. It is preferred according W the invention for the composition or concentrate to comprise, as the organic chemical binder, at least one alkyd resin or modified alkyd resin and/or one drying vegetable oil. Alkyd resins having an oil content of more than 15 45% by weight, preferably 50 to 68% by weight, are preferably used according to the invention. All or some of the binder mentioned can be replaced by a fixing agent (mixture) or a plasticizer (mixture). These additives are intended to prevent evaporation of the 20 active compounds and crystallization or precipitation. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder employed). The plasticizers originate from the chemical classes of phthalic acid esters, such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters, such as tributyl 25 phosphate, adipic acid esters, such as di-(2-ethylhexyl) adipate, stearates, such as butyl stearate or amyl stearate. oleates, such as butyl oleate, glycerol ethers or higher molecular weight glycol ethers, glycerol esters and p-toluenesulphonic acid esters. Fixing agents are based chemically on polyvinyl alkyl ethers, such as, for example, 30 polyvinyl methyl ether or ketones, such as benzophenone or ethylenebenzophenone. Le A 34 460-Foreign Countries Possible solvents or diluents are, in particular, also water, if appropriate as a mixture with one or more of the abovementioned organic chemical solvents or diluents, emulsifiers and dispersing agents. 5 Particularly effective preservation of wood is achieved by impregnation processes on a large industrial scale, for example vacuum, double vacuum or pressure processes. The ready-to-use compositions can also comprise other insecticides, if appropriate, and also one or more fungicides, if appropriate. 10 Possible additional mixing partners are, preferably, the insecticides and fungicides mentioned in WO 94/29 268. The compounds mentioned in this document are an explicit constituent of the present application. 15 Especially preferred mixing partners which may be mentioned are insecticides, such as chlorpyriphos, phoxim, silafluofin, alphamethrin, cyfluthrin, cypermethrin, deltamethrin, permethrin, imidacloprid, NI-25, flufenoxuron, hexaflumuron, transfluthrin, thiacloprid, methoxyfenozide and triflumuron, and also fungicides, such as epoxyconazole, hexaconazole, azaconazole, 20 propiconazole, tebuconazole, cyproconazole, metconazole, imazalil, dichlorfluanid, tolylfluanid, 3-iodo-2-propinyl-butyl carbamate, N-octyl-isothiazolin-3-one and 4,5-dichloro-N-octylisothiazolin-3-one. The compounds according to the invention can at the same time be employed for 25 protecting objects which come into contact with saltwater or brackish water, such as hulls, screens, nets, buildings, moorings and signalling systems, against fouling. Fouling by sessile Oligochaeta, such as Serpulidae, and by shells and species from the Ledamorpha group (goose barnacles), such as various Lepas and Scalpellum 30 species, or by species from the Balanomorpha group (acorn barnacles), such as Balanus or Pollicipes species, increases the frictional drag of ships and, as a Le A 34 460-Foreign Countries consequence, leads to a marked increase in operation costs owing to higher energy consumption and additionally frequent residence in the dry dock. Apart from fouling by algae, for example Ectocarpus sp. and Ceramium sp., fouling 5 by sessile Entomostraka groups, which come under the generic term Cirripedia (cirriped crustaceans), is of particular importance. Surprisingly, it has now been found that the compounds according to the invention, alone or in combination with other active compounds, have an outstanding 10 antifouling action. Using the compounds according to the invention, alone or in combination with other active compounds, allows the use of heavy metals such as, for example, in bis(trialkyltin) sulphides, tri-n-butyltin laurate, tri-n-butyltin chloride, copper(I) 15 oxide, triethyltin chloride, tri-n-butyI(2-phenyl-4-chlorophenoxy)tin, tributyltin oxide, molybdenum disulphide, antimony oxide, polymeric butyl titanate, phenyl- (bispyridine)-bismuth chloride, tri-7?-butyltin fluoride, manganese ethylenebisthiocarbamate, zinc dimethyldithiocarbamate, zinc ethylenebisthiocarbamate, zinc salts and copper salts of 2-pyridinethiol 1-oxide, 20 bisdimethyldithiocarbamoylzinc ethylene-bisthiocarbamate, zinc oxide, copper(I) ethylene-bisdithiocarbamate, copper thiocyanate, copper naphthenate and tributyltin halides to be dispensed with, or the concentration of these compounds substantially reduced. 25 If appropriate, the ready-to-use antifouling paints can additionally comprise other active compounds, preferably algicides, fungicides, herbicides, molluscicides, or other antifouling active compounds. Preferably suitable components in combinations with the antifouling compositions 30 according to the invention are: Le A 34 460-Foreign Countries algicides such as 2-tert-butylamino-4-cyclopropylamino-6-methylthio-l,3,5-triazine, dichlorophen, diuron, endothal, fentin acetate, isoproturon, methabenzthiazuron, oxyfluorfen, quinoclamine and terbutryn; 5 fungicides such as benzo[b]thiophenecarboxylic acid cyclohexylamide S,S-dioxide, dichlofluanid, fluorfolpet, 3-iodo-2-propinyl butylcarbamate, tolylfluanid and azoles such as azaconazole, cyproconazole, epoxyconazole, hexaconazole, metconazole, 10 propiconazole and tebuconazole; molluscicides such as fentin acetate, metaldehyde, methiocarb, niclosamid, thiodicarb and trimethacarb; or conventional antifouling active compounds such as 15 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatryl sulfone, 2-(N,N- dimethylthiocarbamoylthio)-5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinethiol 1-oxide, pyridine-triphenylborane, tetrabutyldistannoxane, 2,3,5,6- tetrachloro-4-(methylsulfonyl)-pyridine, 2.4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4.6-trichlorophenylmaleiimide. 20 The antifouling compositions used comprise the active compound according to the invention of the compositions according to the invention in a concentration of 0.001 to 50% by weight, in particular 0.01 to 20% by weight. 25 Moreover, the antifouling compositions according to the invention comprise the customary components such as, for example, those described in Ungerer, Chem. ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973. Le A 34 460-Foreign Countries Besides the algicidal, fungicidal, molluscicidal active compounds and insecticidal active compounds according to the invention, antifouling paints comprise, in particular, binders. 5 Examples of recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, in particular in an aqueous system, vinyl chloride/vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene/styrene/acrylonitrile rubbers, drying oils such as linseed oil, resin esters or 10 modified hardened resins in combination with tar or bitumens, asphalt and epoxy compounds, small amounts of chlorine rubber, chlorinated polypropylene and vinyl resins. If appropriate, paints also comprise inorganic pigments, organic pigments or 15 colorants which are preferably insoluble in salt water. Paints may furthermore comprise materials such as colophonium to allow controlled release of the active compounds. Furthermore, the paints may comprise plasticizers, modifiers which affect the rheological properties and other conventional constituents. The compounds according to the invention or the abovementioned mixtures may also be incorporated 20 into self-polishing antifouling systems. The active compounds are also suitable for controlling animal pests, in particular insects, arachnids and mites, which are found in enclosed spaces such as, for example, dwellings, factory halls, offices, vehicle cabins and the like. They can be 25 employed alone or in combination with other active compounds and auxiliaries in domestic insecticide products for controlling these pests. They are active against sensitive and resistant species and against all developmental stages. These pests include: 30 From the order of the Scorpionidea, for example, Buthus occitanus. Le A 34 460-Foreign Countries From the order of the Acarina, for example, Argas persicus, Argas reflexus, Bryobia spp., Dermanyssus gallinae, Glyciphagus domesticus, Omithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae. 5 From the order of the Araneae, for example, Aviculariidae, Araneidae. From the order of the Opiliones, for example, Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium. From the order of the Isopoda, for example, Oniscus asellus, Porcellio scaber. From the order of the Diplopoda, for example, Blaniulus guttulatus, Polydesmus spp. 10 From the order of the Chilopoda, for example, Geophilus spp. From the order of the Zygentoma, for example, Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus. From the order of the Blattaria, for example, Blatta orientalies, Blattella germanica, 15 Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Penplaneta australasiae, Penplaneta americana, Penplaneta brunnea, Penplaneta fuliginosa, Supella longipalpa. From the order of the Saltatoria, for example, Acheta domesticus. From the order of the Dermaptera, for example, Forficula auricularia. 20 From the order of the Isoptera, for example, Kalotermes spp., Reticulitermes spp. From the order of the Psocoptera, for example, Lepinatus spp., Liposcelis spp. From the order of the Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum. 25 From the order of the Diptera, for example, Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga camaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa. 30 From the order of the Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella. Le A 34 460-Foreign Countries From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis. From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula 5 spp., Tetramorium caespitum. From the order of the Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis. From the order of the Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans. 10 In the field of household insecticides, they are used alone or in combination with other suitable active compounds, such as phosphoric acid esters, carbamates, pyrethroids, growth regulators or active compounds from other known classes of insecticides. 15 They are used as aerosols, pressure-free spray products, for example pump and atomizer sprays, automatic fogging systems, foggers, foams, gels, evaporator products with evaporator tablets made of cellulose or polymer, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-free, or passive, 20 evaporation systems, moth papers, moth bags and moth gels, as granules or dusts, in baits for spreading or in bait stations. The active compounds according to the invention can be used as defoliants, desiccants, haulm killers and, especially, as weed killers. Weeds in the broadest sense 25 are understood to mean all plants which grow in locations where they are undesired. Whether the substances according to the invention act as total or selective herbicides depends essentially on the amount used. The active compounds according to the invention can be used, for example, in 30 connection with the following plants: Le A 34 460-Foreign Countries Dicotyledonous weeds of the genera: Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Hibiscus, Ipomoea, Kochia, Lamium, 5 Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium. 10 Dicotyledonous crops of the genera: Arachis, Beta, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiarva, Phaseolus, Pisum, Solanum, Vicia Monocotvledonous weeds of the genera: Aegilops, Agropyron, Agrostis, Alopecurus, 15 Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina, Cynodon, Cyperus, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum. 20 Monocotvledonous crops of the genera: Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorghum, Triticale, Triticum, Zea. However, the use of the active compounds according to the invention is in no way 25 restricted to these genera, but also extends in the same manner to other plants. The active compounds according to the invention are suitable, depending on the concentration, for the total control of weeds, for example on industrial terrain and rail tracks, and on paths and areas with and without tree plantings. Similarly, the active 30 compounds according to the invention can be employed for controlling weeds in perennial crops, for example forests, decorative tree plantings, orchards, vineyards, Le A 34 460-Foreign Countries citrus groves, nut orchards, banana plantations, coffee plantations, tea plantations, rubber plantations, oil palm plantations, cocoa plantations, soft fruit plantings and hop fields, on lawns, turf and pastureland, and for the selective control of weeds in annual crops. 5 The compounds according to the invention have strong herbicidal activity and a broad active spectrum when used on the soil and on above-ground parts of plants. To a certain extent they are also suitable for the selective control of monocotyledonous and dicotyledonous weeds in monocotyledonous and dicotyledonous crops, both by 10 the pre-emergence and by the post-emergence method. At certain concentrations or application rates, the active compounds according to the invention can also be employed for controlling animal pests and fungal or bacterial plant diseases. If appropriate, they can also be used as intermediates or precursors for 15 the synthesis of other active compounds. The active compounds can be converted into the customary formulations such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials 20 impregnated with active compound, and microencapsulations in polymeric materials. These formulations are produced in a known manner, for example by mixing the active compounds with extenders, that is, liquid solvents and/or solid carriers, optionally with the use of surfactants, that is, emulsifiers and/or dispersants, and/or 25 foam formers. If the extender used is water, it is also possible, for example, to use organic solvents as cosolvents. The following are essentially suitable as liquid solvents: aromatics such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated 30 aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, for example Le A 34 460-Foreign Countries mineral oil fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulphoxide, or else water. 5 Suitable solid carriers are: for example ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic materials such as highly-disperse silica, alumina and silicates; suitable solid carriers for granules are: for example crushed 10 and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, or else synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; suitable emulsifiers and/or foam formers are: for example nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for 15 example alkylaryl polyglycol ethers, alkylsulphonates, alkyl sulphates, arylsulphonates, or else protein hydrolysates; suitable dispersants are: for example lignin-sulphite waste liquors and methylcellulose. Tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the 20 form of powders, granules or latices, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, or else natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations. Other additives can be mineral and vegetable oils. 25 It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic colorants such as alizarin colorants, azo colorants and metal phthalocyanine colorants, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc. 30 The formulations generally comprise between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%. Le A 34 460-Foreign Countries For controlling weeds, the active compounds according to the invention, as such or in their formulations, can also be used as mixtures with known herbicides and/or substances which improve the compatibility with crop plants ("safeners"), finished 5 formulations or tank mixes being possible. Also possible are mixtures with weed- killers comprising one or more known herbicides and a safener. Possible components for the mixtures are known herbicides, for example 10 acetochlor, acifluorfen (-sodium), aclonifen, alachlor, alloxydim (-sodium), ametryne, amicarbazone, amidochlor, amidosulfuron, anilofos, asulam, atrazine, azafenidin, azimsulfuron, BAS-662H, beflubutamid, benazolin (-ethyl), benfuresate, bensulfuron (-methyl), bentazon, benzfendizone, benzobicyclon, benzofenap, benzoylprop(-ethyl), bialaphos, bifenox, bispyribac (-sodium), bromobutide, 15 bromofenoxim, bromoxynil, butachlor, butafenacil (-allyl), butroxydim, butylate, cafenstrole, caloxydim, carbetamide, carfentrazone (-ethyl), chlomethoxyfen, chloramben, chloridazon, chlorimuron (-ethyl), chlomitrofen, chlorsulfuron, chlortoluron, cinidon (-ethyl), cinmethylin, cinosulfuron, clefoxydim, clethodim, clodinafop (-propargyl), clomazone, clomeprop, clopyralid, clopyrasulfuron 20 (-methyl), cloransulam (-methyl), cumyluron, cyanazine, cybutryne, cycloate, cyclosulfamuron, cycloxydim, cyhalofop (-butyl), 2,4-D, 2,4-DB, desmedipham, diallate, dicamba, dichlorprop (-P), diclofop (-methyl), diclosulam, diethatyl (-ethyl), difenzoquat, diflufenican, diflufenzopyr, dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimexyflam, dinitramine, diphenamid, diquat, 25 dithiopyr, diuron, dymron, epropodan, EPTC, esprocarb, ethalfluralin, ethametsulfuron (-methyl), ethofumesate, ethoxyfen, ethoxysulfuron, etobenzanid, fenoxaprop (-P-ethyl), fentrazamide, flamprop (-isopropyl, -isopropyl-L, -methyl), flazasulfuron, florasulam, fluazifop (-P-butyl), fluazolate, flucarbazone (-sodium), flufenacet, flumetsulam, flumiclorac (-pentyl), flumioxazin, flumipropyn, 30 flumetsulam, fluometuron, fluorochloridone, fluoroglycofen (-ethyl), flupoxam, flupropacil, flurpyrsulfuron (-methyl, -sodium), flurenol (-butyl), fluridone, Le A 34 460-Foreign Countries fluroxypyr (-butoxypropyl, -meptyl), flurprimidol, flurtamone, fluthiacet (-methyl), fluthiamide, fomesafen, foramsulfuron, glufosinate (-ammonium), glyphosate (-isopropylammonium), halosafen, haloxyfop (-ethoxyethyl, -P-methyl), hexazinone, imazamethabenz (-methyl), imazamethapyr, imazamox, imazapic, imazapyr, 5 imazaquin, imazethapyr, imazosulfuron, iodosulfuron (-methyl, -sodium), ioxynil, isopropalin, isoproturon, isouron, isoxaben, isoxachlortole, isoxaflutole, isoxapyrifop, lactofen, lenacil, linuron, MCPA, mecoprop, mefenacet, mesotrione, metamitron, metazachlor, methabenzthiazuron, metobenzuron, metobromuron, (alpha-) metolachlor, metosulam, metoxuron, metribuzin, metsulfuron (-methyl), 10 molinate, monolinuron, naproanilide, napropamide, neburon, nicosulfuron, norflurazon, orbencarb, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefone, oxyfluorfen, paraquat, pelargonic acid, pendimethalin, pendralin, pentoxazone, phenmedipham, picolinafen, piperophos, pretilachlor, primisulfuron (-methyl), profluazol, prometryn, propachlor, propanil, propaquizafop, propisochlor, 15 propoxycarbazone (-sodium), propyzamide, prosulfocarb, prosulfuron, pyraflufen (-ethyl), pyrazogyl, pyrazolate, pyrazosulfuron (-ethyl), pyrazoxyfen, pyribenzoxim, pyributicarb, pyridate, pyridatol, pyriftalid, pyriminobac (-methyl), pyrithiobac (-sodium), quinchlorac, quinmerac, quinoclamine, quizalofop (-P-ethyl, -P-tefuryl), rimsulfuron, sethoxydim, simazine, simetryn, sulcotrione, sulfentrazone, 20 sulfometuron (-methyl), sulfosate, sulfosulfuron, tebutam, tebuthiuron, tepraloxydim, terbuthylazine, terbutryn, thenylchlor, thiafluamide, thiazopyr, thidiazimin, thifensulfuron (-methyl), thiobencarb, tiocarbazil, tralkoxydim, triallate, triasulfuron, tribenuron (-methyl), triclopyr, tridiphane, trifluralin, trifloxysulfuron, triflusulfuron (-methyl), tritosulfuron. 25 A mixture with other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellents, plant nutrients and agents which improve soil structure, is also possible. 30 The active compounds can be used as such, in the form of their formulations or in the use forms prepared therefrom by further dilution, such as ready-to-use solutions, Le A 34 460-Foreign Countries suspensions, emulsions, powders, pastes and granules. They are used in a customary manner, for example by watering, spraying, atomizing or broadcasting. The active compounds according to the invention can be applied both before and 5 after emergence of the plants. They can also be incorporated into the soil before sowing. The amount of active compound used can vary within a relatively wide range. It depends essentially on the nature of the desired effect. In general, the amounts used 10 are between 1 g and 10 kg of active compound per hectare of soil surface, preferably between 5 g and 5 kg per ha. The preparation and the use of the active compounds according to the invention is illustrated by the examples below. Le A 34 460-Foreign Countries Preparation Examples Example I-l-A-a-1 At 0°C, 3.70 g (0.031 mol) of potassium tert-butoxide are initially charged in 26 ml of anhydrous DMF, and 6 g of the compound according to Example U-l in 12 ml of anhydrous DMF are added. The mixture is stirred at 20°C for 1 h. 10 The reaction solution is added to 200 ml of ice-water and acidified at 0-10°C. The precipitate is then filtered off with suction and recrystallized. Yield: 4.66 g (∆83% of theory), m.p.. > 260°C. 15 DMF (dimethylformamide) Le A 34 460-Foreign Countries The following compounds of the formula (I-l-A-a) are obtained similarly to Example (I-l-A-a-1) and in accordance with the general statements on the preparation Lc A 34 460-Foreign Countries Le A 34 460-Foreign Countries Le A 34 460-Foreign Countries Le A 34 460-Foreign Countries Le A 34 460-Foreign Countries 0.81 g of the compound according to Example I-l-a-2 is initially charged in 10 ml of anhydrous ethyl acetate and heated at reflux with 0.3 ml (2.2 mmol) of triethylamine. 5 0.25 ml (0.0022 mol) of isobutyryl chloride in 5 ml of anhydrous ethyl acetate is then added, and the mixture is heated at reflux. After the reaction has ended (TLC), the solvent is distilled off and the residue is taken up in dichloromethane, washed twice with 10 ml of 0.5 N NaOH, dried and 10 concentrated using a rotary evaporator. The residue is purified by silica gel column chromatography (dichloromethane/ethyl acetate, 3:1). Yield: 0.2 g (∆ 21% of theory) m.p. 208°C. Le A 34 460-Foreign Countries The following compounds of the formula (I-l-A-b) are obtained similarly to Example (I-I-A-b-1) and in accordance with the general statements on the preparation Le A 34 460-Foreign Countries Example I-l-A-c-1 0.69 g of the compound according to Example I-l-a-2 is initially charged in 10 ml of anhydrous dichloromethane and, at 10°C, admixed with 0.24 ml (1.7 mmol) of 5 triethylamine. 0.17 ml (1.7 mmol) of ethyl chloroformate in 1 ml of anhydrous dichloromethane is then added, and the mixture is stirred at room temperature. 10 After the reaction has ended (TLC), the solvent is distilled off and the residue is taken up in dichloromethane, washed twice with 10 ml of 0.5 N NaOH, dried and concentrated using a rotary evaporator. The residue is purified by silica gel column chromatography (dichloromethane/ethyl acetate, 3:1). 15 Yield: 0.58 g (∆ 71% of theory), m.p. 211°C. Le A 34 460-Forcign Countries The following compounds of the formula (I-l-A-c) are obtained similarly to Example (I-l-A-c-1) and in accordance with the general statements on the preparation Le A 34 460-Foreign Countries 6.6 ml of triethylamine are added to 4.61 g of methyl 4-methyl-l-amino-cyclohexane-1-carboxylate hydrochloride in 80 ml of anhydrous tetrahydrofuran, and the mixture is stirred for 3 min. 5.3 g of 4-[2-(4-chlorophenyl)-5-methyl]-thiazolyl-acetic acid are added. The mixture is stirred at room temperature for another 15 min. 4.4 ml of triethylamine are then added, followed immediately by dropwise addition of 1.12 ml of phosphorus oxychloride such that the solution boils moderately. The solution is heated at reflux for 30 min. The reaction solution is poured into 200 ml of ice-water, extracted with dichloromethane and dried. The solvent is distilled off and the residue is recrystallized. Yield: 6.19 g (∆ 73% of theory), m.p.: 150°C. Le A 34 460-Foreign Countries The following compounds of the formula (II-A) are obtained similarly to Examples (H-A-l) and (II-A-48) and in accordance with the general statements on the preparation Le A 34 460-Foreign Countries Le A 34 460-Forci|gn Countries Le A 34 460-Foreign Countries Le A 34 460-Forcign Countries Le A 34 460-Foreign Countries 10 7.4 g (0.075 mol) of concentrated sulphuric acid are initially charged, and 5.37 g of the compound according to Preparation Example XXI-A-1 in 30 ml of methylene chloride are then added dropwise at an internal temperature of from 30 to 40oC. The mixture is then stirred at from 30 to 40°C for 2 hours. 11 ml of absolute methanol are added dropwise such that an internal temperature of 40°C results. Stirring is continued at from 40 to 70°C for 6 hours. The reaction solution is poured onto 0.08 kg of ice. The mixture is extracted with dichloromethane, the extract is washed with NaHC03 solution and dried and the solvent is distilled off. The residue is then purified by silica gel column chromatography (dichloromethane/ethyl acetate, 5:1). 15 This gives 0.42 g (A 7% of theory), m.p. 131°C. Le A 34 460-Foreign Countries Example XXI-A-1 10 3.7 g of 2-amino-2-cyclopropyl-propionitrile in 60 ml of absolute tetrahydrofuran and 4.92 ml of triethylamine are stirred for 5 min. 8.03 g of 5-methyl-2-(4-chloro-phenyl)-thiazolylacetic acid are then added, and the mixture is stirred at room temperature for 15 min. 6.6 ml of triethylamine are added, followed immediately by dropwise addition of 1.68 ml of phosphorus oxychloride such that the solution boils moderately. The solution is stirred at reflux for 30 min. The solvent is then distilled off and the residue is purified by silica gel column chromatography (n-hexane/ethyl acetate, 2:1). 15 Yield: 5.37 g (49% of theory), m.p. 114°C. Le A 34 460-Foreign Countries The following compounds of the formula (XXI-A) are obtained similarly to Example (XXI-A-i) and in accordance with the genera! statements on the preparation Le A 34 460-Foreign Countries ^T3o^ Example I-2-A-a-l H'c'°"n /* 5 With ice-cooling, 6.6 ml of 1 M potassium tert-butoxide solution are added to 2.48 g (5.49 mmol) of the compound according to Example ITJ-1 in 10 ml of anhydrous DMF, and the mixture is stirred at room temperature overnight. The solvent is distilled off and the residue is dissolved in water, acidified slowly with cone. HC1, filtered off with suction and dried. Yield: 2 g (A 89% of theory), m.p. 117-120°C. Le A 34 460-Foreign Countries The following compounds of the formula (I-2-A-a) are obtained similarly to Example (I-2-A-a-l) and in accordance with the general statements on the preparation o lH-NMR (CDCb) Ex. No. I-2-A-a-3 8 = 1.45-2.25 (m, 8H), 2.90/3.00 (2s, 3H), 3.30/3.40 (2s, 3H), 3.25/3.50 (2m, IH), 7.35-8.25 (m, 5H). 5 Ex. No. I-2-A-a-4 5 = 1.60 (s, 6H), 2.95 (s, 3H), 7.45 (m, 3H), 7.80 (m, 2H). Le A 34 460-Foreign Countries Example I-2-A-b-l 10 At from 0 to 10°C, 0.244 g (2.3 mmol) of isobutyryl chloride is added to 0.7 g (2.1 mmol) of the compound according to Preparation Example m-A-2 in absolute dichloromethane and 0.232 g (2.3 mmol) of triethyiamine, and the mixture is stirred at room temperature for 8 hours. The reaction solution is washed with 10% citric acid and 10% NaOH solution. The organic phase is separated off, dried and concentrated. The-residue is purified by silica gel column chromatography (dichloromethane/ethyl acetate, 20/1). Yield: 0.1 g A 11.8% of theory, m.p. 95-98°C. Le A 34 460-Foreign Countries 10 At from 0 to 10°C, isopropyl chloroformate (0.249 g, 2 mmol, 1 M in toluene) is added to 0.75 g (1.85 mmol) of Example I-2-A-1 in absolute dichloromethane and 0.206 g (2 mmol) of triethylamine. The mixture is stirred at room temperature for 8 hours and then washed with 10% citric acid solution and with 10% strength NaOH solution. The organic phase is separated off and dried, and the solvent is removed by distillation. The residue is purified by silica gel column chromatography (dichloromethane/ethyl acetate, 20/1). 15 Yield: 0.37 g ∆ 40% of theory, m.p. 140-145°C. Le A 34 460-Foreign Countries Example III-A-1 10 1.11 g (5.49 mmol) of ethyl 4-methoxy-l-hydroxy-cyclohexane-l-carboxylate and 1.57 g (5.49 mmol) of the compound according to Example XVI-1 are stirred at 140°C for 6 h, the mixture is cooled and the HCl gas is flushed out using argon. Yield: 2.4 g (A 41.62% of theory), logP (acidic) 4.54 (HPLC; acetonitrile). Le A 34 460-Foreign Countries The following compounds of the formula (I1I-A) are prepared analogously to Example (III-A-1) and in accordance with the general statements on the preparation Le A 34 460-Foreign Countries Example I-3-A-a-l 5 15 g (20 mmol) of the compound according to Example (IV-A-1) are initially charged in 22 ml of trifluoroacetic acid (TFA) and 51 ml of toluene, and the mixture is heated at reflux overnight. The solvent and the TFA are distilled off and the residue is taken up in 200 ml of water and 200 ml of methyl tert-butyl ether. The organic phase is extracted with alkali, the aqueous phase is acidified and extracted 10 with dichloromethane, the organic extract is dried and the solvent is distilled off. The residue is purified by silica gel column chromatography (dichloromethane/ethyl acetate, 10:1 —>5:1). 15 Yield: 1.6 g (23% of theory), m.p. 132-135°C. Le A 34 460-Foreign Countries Example I-3-A-c-l 5 500 mg (1.4 mmol) of the compound according to Example (I-3-A-a-l) are initially charged in 5 ml of absolute dichloromethane and mixed with 0.29 ml (2.1 mmol, 1.5 eq) of tri ethyl amine, and 0.2 g (1.8 mmol, 1.3 eq) of ethyl chloroformate are added with ice-cooling. 10 The mixture is stirred at room temperature for 2 hours, washed with 10% strength citric acid, extracted with dichloromethane, washed with 1 N NaOH and extracted with dichloromethane. The extract is dried and the solvent is distilled off. Yield: 0.55 g (93% of theory) oil. 15 !H-NMR (de-DMSO, 400 MHz): 5 = 0.93 (t, 3H, CHrCH2), 1.75 (s, 6H, 2 CH3-C), 2.37 (s, 3H, CH3-C arom.), 3.98 (q, 2H, CH3-CH2), 7.55 (d, 2H, 2 CH arom.), 7.87 (d, 2H, 2 CH arom.) ppm. Le A 34 460-Foreign Countries 4.8 g (20.0 mmol) of 2-(4-methoxy-benzylthio)-2-methyl-propionic acid are initially charged in 40 ml of anhydrous toluene and 1 drop of DMF, and 7.2 g (60 mmol, 5 4 ml) of thionyl chloride are added. The mixture is stirred at room temperature for 5 min and then at 100°C until evolution of gas has ceased. The solvent is distilled off and the residue is taken up in 10 ml of anhydrous tetrahydrofuran (solution A). 17.1ml of lithium diisopropylamide are initially charged at 0°C in 40 ml of 10 anhydrous tetrahydrofuran, and 10.1 g (32.7 mmol) of methyl 4-[5-methyl-2-(4- chloro-phenyl)]-thiazolylacetate in 10 ml of anhydrous tetrahydrofuran are added dropwise at 0°C, and the mixture is stirred for another 30 min. Solution A is then added dropwise at 0°C, and the mixture is stirred at room temperature for 1 h. The reaction mixture is then admixed with 100 ml of MTB ether and a few drops of water 15 and washed 2 x with in each case 100 ml of 10% strength NH4CI solution. The organic phase is dried and the solvent is distilled off. The crude product is reacted without further purification. Yield: 15.2 g (100% of theory). 20 !H-NMR (DMSO, 400 MHz): 6 = 1.43 (s, 3H, CH3-C aliph.), 1.50 (s, 3H, CH3-C aliph.), 2.40 (s, 3H, CH3-C heteroatom.), 3.31 (s, 2H, CH2), 3.61 (s, 3H, CH3-OCO), 3.82 (s, 3H, CH3-O) ppm. Le A 34 460-Foreign Countries Example XVI-1 5 3g (11.21 mmol) of 4-[2-(4-chlorophenyl)-5-methyl]-thiazolyl-acetic acid are initially charged in 50 ml of absolute dichloromethane. With ice-cooling, 2.13 g (16.81 mmol) of oxalyl chloride are slowly added dropwise, the mixture is stirred at room temperature overnight and then heated at reflux for 2 h, and the solvent is distilled off. 10 Yield: 3.19 g (96% of theory). Le A 34 460-Foreign Countries Example I-l-B-a-1 5 At 20°C, 3.59 g of the compound according to Preparation Example II-B-l in 7 ml of anhydrous DMF are added dropwise to 2.41 g (0.020 mol) of potassium tert-butoxide in 17 ml of anhydrous dimethylformamide (DMF), and the mixture is stirred at 40°C for 1 hour. 10 The reaction solution is stirred into 100 ml of ice-water and, at from 0 to 10°C, acidified with hydrochloric acid. The precipitate is filtered off with suction and chromatographed on silica gel using methylene chloride/acetone 5:1. Yield: 1.2 g (36% of theory), m.p. >240°C Le A 34 460-Forcign Countries The following compounds of the formula (1-1-B-a) are obtained similarly to Example (I-l-B-a-1) and in accordance with the general statements on the preparation Le A 34 460-Foreign Countries Example II-B-1 5 4.56 g (20 mmol) of methyl l-amino-4-methoxy-cyclohexanecarboxylate hydrochloride are initially charged in 60 ml of absolute THF, admixed with 6 ml of triethylamine and stirred for 5 min. 3.27 g of 4-(2-phenyl-5-methyl)-oxazolyl-acetic acid are added, and the mixture is stirred at room temperature for 15 min. 3.3 ml of triethylamine are added and 0.84 ml of phosphorus oxychloride is added dropwise 10 such that the solution boils moderately. The mixture is stirred at reflux for 30 min. The solvent is distilled off and the precipitate is purified by silica gel column 15 chromatography (dichloromethane/ethyl acetate, 3:1). Yield: 3.5 g (61% of theory), m.p. 125°C. Le A 34 460-Foreian Countries The following compounds of the formula (Il-B) are obtained similarly to Example (II-B-1) and in accordance with the general statements on the preparation a X II V-O (II-B) D N 5 In the absence of a solvent, 1.01 g (5 mmol) of ethyl 4-methoxy-l-hydroxy- cyclohexane-1-carboxylate and 1.095 g (5 mmol) of 2-phenyl-4-methyl-isoxazol-3-acetyl chloride were heated at 140°C overnight and then briefly degassed under reduced pressure. The resulting crude product was dissolved in 10 ml of DMF. 6 ml of a 1M solution of KOtBu in DMF were metered in over a period of 10 min, the 10 mixture was stirred at room temperature overnight and then evaporated to dryness using a rotary evaporator, the residue was dissolved in water and extracted 1 x with ethyl acetate to remove impurities, 10 ml of IN hydrochloric acid were slowly metered in (until the mixture was acidic) and the precipitated product was filtered off with suction. Further purification was carried out by preparative HPLC 15 (acetonitrile/water on RP-18): Yield: 0.33 g (19% of theory), m.p. 65°C. "H-NMR MHz (CDCI3) : 5 = 1.60-2.30 (m, 8H), 2.85 (s, 3H), 3.30/3.40 (2s, 3H), 20 3.30/3.60 (2 m, 1H), 7.40-8.00 (m, 5H). Le A 34 460-Foreign Countries The following compounds of the formula (I-2-B-a) are obtained similarly to Example (I-2-B-a-l) and in accordance with the general statements on the preparation Le A 34 460-Foreign Countries Use Examples: Example A Meloidogyne test Solvent: 30 parts by weight of dimethylformamide Emulsifier. 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration. Containers are filled with sand, solution of active compound, Meloidogyne incognita egg/larvae suspension and lettuce seeds. The lettuce seeds germinate and the plants develop. On the roots, galls are formed. After the desired period of time, the nematicidal action in % is determined using the formation of galls as a measure. 100% means that no galls have been found; 0% means that the number of galls on the treated plants corresponds to that on the untreated control. In this test, for example, the following compounds of the Preparation Examples show good activity: I-2-a-l and I-2-a-2. Le A 34 460-Foreign Countries Example B Myzus test Solvent: 30 parts by weight of dimethylformamide 5 Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration. 10 Cabbage leaves (Brassica oleracea) which are heavily infested by the peach aphid (Myzus persicae) are treated by being dipped into the preparation of active compound of the desired concentration. 15 After the desired period of time, the kill in % is determined. 100% means that all aphids have been killed; 0% means that none of the aphids have been killed. In this test, for example, the following compounds of the Preparation Examples show good activity: I-2-a-l, I-l-a-5,1-l-a-6 and I-l-a-8. 20 Le A 34 460-Foreign Countries Example C Phaedon larvae test Solvent: 30 parts by weight of dimethylformamide 5 Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration. 10 Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with the larvae of the mustard beetle (Phaedon cochleariae) while the leaves are still moist. 15 After the desired period of time, the kill in % is determined. 100% means that all beetle larvae have been killed; 0% means that none of the beetle larvae have been killed. In this test, for example, the following compounds of the Preparation Examples show 20 good activity: I-2-a-l, I-2-a-2,1-l-a-3,1-l-a-4,1-l-a-5,1-l-a-6,1-l-a-2,1-l-a-1,I-l-c- 1 and I-l-a-8. Le A 34 460-Foreign Countries Example P Spodoptera frugiperda test Solvent: 30 parts by weight of dimethylformamide 5 Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration. 10 Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with caterpillars of the army worm (Spodoptera frugiperda) while the leaves are still moist. 15 After the desired period of time, the kill in % is determined. 100% means that all caterpillars have been killed; 0% means that none of the caterpillars have been killed. In this test, for example, the following compounds of the Preparation Examples showed good activity: I-2-a-l, I-l-a-4,1-l-a-5,I-l-a-6,1-l-a-2,1-l-a-1 and I-l-c-1. Le A 34 460-Foreign Countries Example E Tetranychus test (OP-resistant/dip treatment) Solvent: 30 parts by weight of dimethylformamide 5 Emulsifier: 1 part by weight of alkylaryl polyglycol ether To oroduce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration. 10 Bean plants (Phaseolus vulgaris) which are heavily infested by all stages of the greenhouse red spider mite (Tetranychus urticae) are dipped into a preparation of active compound of the desired concentration. 15 After the desired period of time, the effect in % is determined. 100% means that all spider mites have been killed. 0% means that none of the spider mites have been killed. In this test, for example, the following compounds of the Preparation Examples show 20 good activity: I-2-a-2,1-1-3-4,1-l-a-5 and I-l-a-6. Le A 34 460-Foreign Countries Example F Post-emergence test Solvent: 5 parts by weight of acetone 5 Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired 10 concentration. Test plants of a height of 5 to 15 cm are sprayed with the preparation of active compound such that the particular amounts of active compound desired are applied per unit area. The concentration of the spray liquor is chosen such that the particular 15 amounts of active compound desired are applied in 1000 1 of water/ha. After three weeks, the degree of damage to the plants is rated in % damage in comparison to the development of the untreated control. 20 The figures denote: 0% = no effect (like untreated control) 100% = total destruction Le A 34 460-Foreign Countries Example G Pre-emergence test Solvent: 5 parts by weight of acetone 5 Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired 10 concentration. Seeds of the test plants are sown in normal soil. After about 24 hours, the soil is sprayed with the preparation of active compound such that the particular amounts of active compound desired are applied per unit area. The concentration of the spray 15 liquor is chosen such that the particular amounts of active compound desired are applied in 1000 1 of water/ha. After three weeks, the degree of damage to the plants is rated in % damage in comparison to the development of the untreated control. 20 The figures denote: 0% = no effect (like untreated control) 100% = total destruction Le A 34 460-Foreign Countries pre-emergence g ai/ha sugar beet oilseed rape Alopecurus Avena fatua Lolium Setaria Matricaria Ex. I-2-a-l 125 0 0 90 100 100 100 100 post-emergence g ai/ha oilseed rape Alopecurus Avena Fatua Echino¬chloa Setaria Amaran¬thus Cheno-podium Ex. I-2-a-l 250 20 80 95 100 100 70 70 pre-emergence g ai/ha sugar beet oilseed rape Avena fatua Bromus Lolium Setaria Ex. I-2-a-2 250 0 0 90 90 100 100 post- o o sugar Soy Avena Dimtaria Echinochloa Setaria emergence ai/ha beet a bean fatua Ex. I-2-a-2 250 0 0 90 90 100 95 post-emergence g ai/ha Alopecurus Echinochloa Amaranthus Ex. M-a-5 250 80 100 90 post-emergence g ai/ha sugar beet Alopecurus Avena fatua Digitaria Echinochloa Ex. I-l-a-6 125 0 90 90 95 90 post-emergence g ai/ha Alopecurus Echinochloa Setaria Amaranthus Ex. I-l-a-2 250 70 90 95 90 Le A 34 460-Foreign Countries post-emergence gai/ha Alopecurus Avena fatua Echinochloa Amaranthus Sinapis Ex. I-l-a-1 250 80 80 95 70 80 post-emergence g ai/ha rice Avena fatua Digitaria Echinochloa Stellaria Ex. I-l-a-3 250 10 100 100 100 90 post-emergence g ai/ha Alopecurus Avena fatua Echinochloa Setaria Ex. I-l-c-1 250 80 95 95 90 post-emergence g ai/ha Alopecurus Avena fatua Echinochloa Setaria Abutilon Amaranthus Ex. I-l-a-4 250 95 100 100 100 80 95 Ex. I-l-b-1 250 95 100 100 100 80 80 Le A 34 460-Foreign Countries Example H Critical concentration test/soil insects - treatment of transgenic plants Test insect: Diabrotica balteata - Larvae in soil Solvent: 7 parts by weigjht of acetone Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration. The preparation of active compound is poured onto the soil. Here, the concentration of the active compound in the preparation is virtually irrelevant, only the amount by weight of active compound per volume unit of soil, which is stated in ppm (mg/1), matters. The soil is filled into 0.25 1 pots and these are allowed to stand at 20°C. Immediately after preparation, 5 pre-germinated maize corns of the variety YIELD GUARD (trademark of Monsanto Comp., USA) are placed into each pot. After 2 days, the test insects concerned are placed into the treated soil. After a further 7 days, the efficacy of the active compound is determined by counting the maize plants that have emerged (1 plant = 20% efficacy). Le A 34 460-Foreign Countries Example I Heliothis virescens test - treatment of transgenic plants 5 Solvent: 7 parts by weight of acetone Emulsifier: 1 part by weight of alkylaryl polyglycol ether To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent and the stated amount of 10 emulsifier, and the concentrate is diluted with water to the desired concentration. Soya bean shoots (Glycine max) of the variety Roundup Ready (trademark of Monsanto Comp. USA) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with the tobacco budworm 15 Heliothis virescens while the leaves are still moist. After the desired period of time, the kill of the insects is determined. WE CLAIM; 1. 3-hetaryl-pyrrolidin-2,4-dione Compounds of the formula (I) A O-G in which W represents N-D(1), oxygen (2) or sulphur (3), Het represents in each case optionally substituted thiazolyl, oxazolyl or pyrazolyl, A represents hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, saturated or unsaturated optionally substituted cycloalkyl in which optionally at least one ring atom is replaced by a heteroatom, or in each case optionally halogen-, alkyl-, halogenoalkyl, alkoxy-, halogenoalkoxy-, cyano- or nitro-substituted aryl, arylalkyl or hetaryl, B represents hydrogen, alkyl or alkoxyalkyl, or A and B together with the carbon atom to which they are attached represent a saturated or unsaturated unsubstituted or substituted cycle which optionally contains at least one heteroatom, D represents hydrogen or represents an optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, saturated or unsaturated cycloalkyl in which optionally one or more ring members are replaced by heteroatoms, arylalkyl, aryl, hetarylalkyl or hetaryl or A and D together with the atoms to which they are attached represent a saturated or unsaturated cycle which is unsubstituted OT substituted in the A,D moiety and optionally contains at least one heteroatom, G represents hydrogen (a) or represents one of the groups in which E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur, M represents oxygen or sulphur, R1 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen-, alkyl-or alkoxy-substituted cycloalkyl which may be interrupted by at least one heteroatom, in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, R2 represents in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or represents in each case optionally substituted cycloalkyl, phenyl or benzyl, or in the case of Het=thiazolyl ((I-l-A) to (I-3-A)) also represents. in which V1 represents hydrogen, halogen, C1-C12-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulphinyl, C1-C6-alkylsulphonyl, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, nitro, cyano, phenoxy or represents phenyl, phenoxy, phenoxy-C1-C4-alkyl, phenyl Ci-C4-alkoxy, phenylthio-C1-C4-alkyl or phenyl-C1-C4-alkylthio, each of which is optionally mono- or polysubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, nitro or cyano, V2- and V3 independently of one another each represent hydrogen, halogen, C1-C6-alkyl, C1C6-alkoxy, C1-C4-halogenoaIkyl or C1-C4-halogenoalkoxy, V1 and V2 together with the carbon atoms to which they are attached represent an optionally C1C4-aIkyl- or halogen-substituted saturated or unsaturated 5- or 6-membered cycle in which optionally one to three carbon atoms may be replaced by oxygen, sulphur or nitrogen, W represents N-D(1), oxygen (2) or sulphur (3), A represents hydrogen or in each case optionally fluorine- or chlorine- substituted C1-C12-alkyl, C3-C8~alkenyl, C1-C6-alkoxy-C1-C6-alky!, poly-C1-C6-alkoxy-C1-C6-alkyl, C1-C10-alkylthio-C1-C6-alkyl, optionally fluorine-, chlorine-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycIoalkyl in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur or represents in each case optionally halogen-, Ci-C0-alkyl~, C1-C6-halogenoalkyl-, C1-C6-alkoxy-, C1-C6-halogenoalkoxy-, cyano- or nitro-substituted C6- or C10-aryl, hetaryl having 5 or 6 ring atoms or C6- or C10-aryl-C1-C6-alky], B represents hydrogen, C1-C6-alkyl or C1-C4-alkoxy-C1-C4-alkyl, or A, B and the carbon atom to which they are attached represent saturated C3-C10-cycloalkyl or unsaturated C5-C10-cycIoalkyl in which optionally one ring member is replaced by oxygen or sulphur and which are optionally mono- or disubstituted by C1-C6-alkyl, C3-C8-cycloalkyl, C1-C4-halogenoalkyI, C1-C6-alkoxy, C1-C6-alkyIthio, halogen or phenyl or A, B and the carbon atom to which they are attached represent C5-C6-cycloalkyI which is substituted by an alkylenediyl group which optionally contains an oxygen or sulphur atom, or by an alkylenedioxyl or by an alkylenedithioyl group which, together with the carbon atom to which it is attached, forms a further five- or six-membered ring which may optionally be mono- to tetrasubstituted by C1-C4alkyl, or A, B and the carbon atom to which they are attached represent C3-C8-cycloalkyI or C5-C8-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent in each case optionally C1-C6-alkyI-, C1-C6-alkoxy- or halogen- substituted C2-C6-alkanediyl, C2-C6-alkenediyl or C4-C6-alkanedienediyl in which optionally one methylene group is replaced by oxygen or sulphur, D represents hydrogen, in each case optionally halogen- or cyano-substituted C1-C12-alkyl, C3-C8-aIkenyl, C3-C8-alkinyl, C 1 -C 10-aIkoxy-C2-C8-a!kyI, poly-C1-C8-alkoxy-C2-C8-alkyl, C1-C10-alkylthio-C2-C8-alkyl, optionally halogen-, C1-C4-alkyl-, C1-C4-alkoxy- or C1-C4-halogenoalkyl-substituted C3-C8-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur or in each case optionally halogen-, C1-C6-alkyl-, C1-C6-halogenoalkyl, C1-C6-alkoxy-, C1-C6-halogenoalkoxy-, cyano- or nitro-substituted phenyl, hetaryl having 5 or 6 ring atoms, phenyl-C1-C6-alkyl or hetaryl-C1-C6-alkyl having 5 or 6 ring atoms, or A and D together represent in each case optionally substituted C3-C6-alkanediyl or C3-C6-alkenediyl in which optionally one methylene group is replaced by a carbonyl group, oxygen or sulphur, possible substituents being in each case: halogen, hydroxyl, mercapto or in each case optionally halogen-substituted C1-C10-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C3-C7-cycloalkyl, phenyl or benzyloxy, or a further C3-C6~alkanediyl grouping, C3-C6-alkenediyl grouping or a butadienyl grouping which is optionally substituted by C1-C6-alkyI or in which optionally t\ adjacent substituents together with the carbon atoms to which they i attached form a further saturated or unsaturated cycle having 5 6 ring atoms (in the case of the compound of the formula (I-l-A) to 1-B), A and D together with the atoms to which they are attached this case, represent, for example, the gtoups, A.D-1 to AD-10 mention further below) which may contain oxygen or sulphur, or whin optionally contains one of the groups below G represents hydrogen (a) or represents one of the groups in which E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur and M represents oxygen or sulphur, R1 represents in each case optionally halogen-substituted C1-C20-alkyl, C2-C20-alkenyl, C1-C8-alkoxy-C1-C8-alkyl, C1-C8-alkylthio-C1-C8-alkyl, poly-C1-C8-alkoxy-C1-C8-alkyl or optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl in which optionally one or more not directly adjacent ring members are replaced by oxygen and/or sulphur, represents optionally halogen-, cyano-, nitro-, C1-C6-aIkyl, C1-C6-alkoxy-, C1-C6-halogenoalkyl-, C1-C6-halogenoalkoxy-, C1-C6-alkylthio- or C1-C6-alkylsulphonyl-substituted phenyl, represents optionally halogen-, nitro-, cyano-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-halogenoalkyl- or C1-C6- halogenoalkoxy-substitutedphenyl-C1-C6-alkyl, represents optionally halogen-, C1-C6-alkyl-, C1-C2-halogenoalkyl- or C1-C4-alkoxy-substituted 5- or 6-membered hetaryl, represents optionally halogen- or C1-C6-alkyl-substituted phenoxy-C1-C6-alkyl or represents optionally halogen-, amino- or C1-C6-alkyl-substituted 5- or 6-membered hetaryloxy-C1-C6-alkyl, R2 represents in each case optionally halogen-substituted C1-C20-alkyl, C2-C20-a!kenyl, C1-C8-alkoxy-C2-C8-aIkyl, po!y~C1-C8-alkoxy-C2-C8-alkyl, represents optionally halogen-, C1-C6-alkyl or C1-C6-alkoxy-substituted C3-C8-cycloalkyl in which optionally one ring atom is replaced by oxygen, or represents in each case optionally halogen-, cyano-, nitro-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-halogenoalkyl- or C1-C6-halogenoalkoxy-substituted phenyl or benzyl, R3 represents optionally halogen-substituted C1-C8-alkyl or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4-halogenoalkyl-, C1-C4-halogenoalkoxy-, cyano- or nitro-substituted phenyl or benzyl, R4 and R5 independently of one another each represent in each case optionally halogen-substituted C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylamino, di-(C1-C8-alkyl)amino, C1-C8-alkylthio, C2-C8-alkenylthio, C3-C7-cycloalkylthio or represent in each case optionally halogen-, nitro-, cyano-, C1-C4-Alkoxy-, C1-C4-halogenoalkoxy-, C1-C4-alkylthio-, C1-C4-halogenoalkylthio-, C1-C4-aIkyl- or C1-C4-halogenoalkyl-substituted phenyl, phenoxy or phenylthio, R6 and R7 independently of one another each represent hydrogen, represent in each case optionally halogen-substituted C1-C8-alkyl, C3-C8-cycloalkyl, C1-C8-alkoxy, C3-C8-alkenyl, C1-C8-alkoxy-C1-C8-alkyl, represent optionally halogen-, C1-C8-halogenoalkyl-, C1-C8-aIkyl- or C1-C8-alkoxy-substituted phenyl, optionally halogen-, C1-C8-alkyl-, C1-C8-halogenoalkyl- or C1-C8-alkoxy-substituted benzyl or together represent an optionally C1C4-aIkyl-substituted C3-C6-alkylene radical in which optionally one carbon atom is replaced by oxygen or sulphur, Rl3 represents hydrogen, represents in each case optionally halogen- substituted C1-C8-alkyl or C1-C8-alkoxy, represents optionally halogen-, C1-C4-alkyl- or C1-C4alkoxy-substituted C3-C8-cycloalkyl, in which optionally one methylene group is replaced by oxygen or sulphur, or represents in each case optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4halogenoalkyl-, C1-C4-halogenoalkoxy-, nitro- or cyano-substituted phenyl, phenyl-C1-C4-alkyl or phenyl-C1-C4-alkoxy, R14 represents hydrogen or C1-C8-alkyl or Rl3 and R14 together represent C4-C6-alkanediyl, R15 and Rl6 are identical or different and each represent C1-C6-alkyl or Rl5 and R16 together represent a C2-C4-alkanediyl radical which is optionally substituted by C1-C6-alkyl, C1-C6-halogenoalkyl or by optionally halogen-, C1-C6-alkyl-, C1-C4-halogenoalkyl-, C1-C6-alkoxy-, C1-C4-halogenoalkoxy-, nitro- or cyano-substituted phenyl, R17 and R18 independently of one another each represent hydrogen, represent optionally halogen-substituted C1-C8-alkyl or represent optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4-halogeno-alkyl-, C1-C4-halogenoalkoxy-, nitro- or cyano-substituted phenyl or R17 and R18 together with the carbon atom to which they are attached represent a carbonyl group or represent optionally halogen-, C1-C4-alkyl or C1C4-alkoxy-substituted C5-C7-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur, R19 and R20 independently of one another each represent C1C10akyl, C2C10 alkenyl, C1C10lkoxy, C1C10 alkylamino C3-C10 alkenylamino, di-(C1C10 alkyl)amino or di- (C3C10 alkenyl)amino. i. Compounds of the formula (I) as claimed in claim 1 in which Het represents represents hydrogen, chlorine, bromine, C1-C4-alkyl, C1-C2-halogenoalkyl, nitro orcyano, represents chlorine, bromine, C1-C4-alkyl, C1-C4-halogenoalky], C1-C4-alkoxy, C1-C4-halogenoalkoxy, C1C4-alkylthio, C1C4-alkylsulphonyl or represents the group or in the case of Het = thiazolyl ((I-l-A) to (I-3-A)) also represents in which V1 represents hydrogen, fluorine, chlorine, bromine, C1C6-aIkyI, C1-C4-alkoxy, C1C2-halogenoalkyl, C1C2~haIogenoalkoxy, nitro, cyano, phenoxy or represents phenyl, phenoxy, phenoxy-C1C2-alkyI, phenyl-C1-C2-alkoxy, phenylthio-C1-C2-alkyl or phenyl-C1-C2-alkylthio, each of which is optionally mono- or disubstituted by fluorine, chlorine, bromine, C1C4-alkyI, C1-C4-alkoxy, C1-C2-haiogenoalkyl, C1-C2-halogenoalkoxy, nitro or cyano, V2 represents hydrogen, fluorine, chlorine, bromine, C1-C4-alkyl, C1C4-alkoxy, C1-C2-halogenoalkyl orC1-C2-halogenoalkoxy, or V1 and V2 together with the carbon atoms to which they are attached represent an optionally fluorine- or methyl-substituted 5- or 6-membered cycle in which optionally one or two carbon atoms may be replaced by oxygen, W represents N-D(1), oxygen(2) or sulphur (3), A represents hydrogen, in each case optionally fluorine-substituted C1-C10-alkyl, C1-C4-alkoxy-C1-C4-alkyl, optionally fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy-substituted C3-C7- cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur or in each case optionally fluorine-, chlorine-, bromine-, C1-C4-alkyI-, C1-C4-halogenoalkyl-, C1-C4-alkoxy- or C1-C4-halogenoalkoxy-substituted phenyl or phenyl-C1-C2-aIkyl, B represents hydrogen of C1-C4-alkyl, or A, B and the carbon atom to which they are attached represent saturated C5-C7-cycloaIkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally mono- or disubstituted by C1-C6-alkyl, C5-C6-cydoaIkyl, C1-C2-halogenoalkyl, C1-C6-alkoxy, fluorine, chlorine or phenyl or A, B and the carbon atom to which they are attached represent C5-C6-cycloalkyl which is substituted by an alkylenediyl group which optionally contains an oxygen or sulphur atom or by an alkylenedioxyl or by an alkylenedithioyl group which together with the carbon atom to which it is attached forms a further five- or six-membered ring which may optionally be mono- to trisubstituted by C1C3-alkyl, or A, B and the carbon atom to which they are attached represent C5-C6-cycloalkyl or C5-C6-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent in each case optionally C1-C5-alkyI-, C1-C5-alkoxy-, fluorine-, chlorine-or bromine-substituted C2-C4-alkanediyl, C2-C4-alkenediyl in which optionally one methylene group is replaced by oxygen or sulphur or represent butadienediyl, D represents hydrogen, represents in each case optionally fluorine-substituted C1-C10-alkyl. C3-C6-alkenyl, C1-C6-alkoxy-C2-C4-alkyl or C1-C6-alkylthio-C2-C4-alkyl, represents optionally fluorine-, C1-C4-alkyl, C1-C4-alkoxy or C1-C2-haIogenoaIkyl-substituted C3-C7-cycIoalkyl, in which optionally one methylene group is replaced by oxygen or sulphur or represents in each case optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, C1-C2-halogenoalkyI-, C1-C4-alkoxy- or C1-C2-haIogenoalkoxy-substituted phenyl or phenyl-C1-C4-alkyl, or A and D together represent optionally substituted C3-C5-alkanediyl in which optionally one methylene group may be replaced by a carbonyl group, oxygen or sulphur, possible substituents being hydroxyl, C1-C6-alkyl or C1-C4-al koxy, or A and D together with the atoms to which they are attached represent one of the groups AD-1 to AD-10: in which E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur and M represents oxygen or sulphur, Rl represents in each case optionally fluorine- or chlorine-substituted C1-C16-alkyl, C2-C16-alkenyl, C1-C6-alkoxy-C1-C4-alkyl, C1-C6-alkylthio-C1-C4-alkyl or optionally fluorine-, chlorine-, C1-C5-alkyl- or C1-C5-alkoxy-substituted C3-C7-cycloalkyI in which optionally one or two not directly adjacent ring members are replaced by oxygen and/or sulphur, represents optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4-alkyl-, C1-C4-alkoxy-, C1-C3-halogenoalkyl-, C1-C3-halogenoalkoxy-, C1-C4-alkylthio- or C1-C4- alkylsulphonyl-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, C1-C4alkyl-, C1-C4-alkoxy-, C1-C3-halogenoalkyl- or C1-C3-halogenoalkoxy-substituted phenyl-C1-C4-alkyl, represents in each case optionally fluorine-, chlorine-, bromine-, C1-C4-alkyl-, trifluoromethyl- or C1-C2-alkoxy-substituted pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl or thienyl, R2 represents in each case optionally fluorine-substituted C1-C16-alkyl, C2-C16-aJkeny1 or C1-C6-alkoxy-C2-C6-alkyl, represents optionally fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy-substituted C3-C7-cycloalkyl or represents in each case optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C1-C4-alkyl-, C1-C3-alkoxy-, C1-C2-halogenoalkyl- or C1-C2-halogenoalkoxy-substituted phenyl or benzyl, R3 represents optionally fluorine-substituted C1-C6-alkyl or represents optionally fluorine , chlorine-, bromine-, C1-C4-alkyl-, C1-C4-alkoxy-, C1-C3-halogenoalkyl-, C1-C3-halogenoalkoxy-, cyano- or nitro-substituted phenyl, R4 represents C1-C6-alkyl, C1-C6-alkoxy, C1-C6-aIkylamino, di- (C1-C6-alkyOamino, C1-C6-alkylthio, C3-C4-alkenylthio, C3-C6-cycloalkylthio or represents in each case optionally fluorine-, chlorine-, bromine-, nitro-, cyano-, Cj-C3-aIkoxy-, Cj-C3-halogenoalkoxy- C1-C3-alkylthio-, C1-C3-halogenoalkylthio-, C1-C3-alkyl- or C1-C3-halogenoalkyl-substituted phenyl, phenoxy or phenylthio. R5 represents C1C6-alkoxy or C1-C6-alkylthio, R6 represents C1-C6-alkyl, C3-C6-cycloalkyI, C1-C6-alkoxy, C3-C6-alkenyl; C1-C6-alkoxy-C1-C6-alkyl, represents optionally fluorine-, chlorine-, bromine-, C1C3-halogenoalkyI-, C1C4-alkyl- or C1-C4alkoxy-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, C1C4-alkyl-, C1C3-halogenoalkyl- or C1C4-alkoxy-substituted benzyl, R7 represents hydrogen, C1-C6-alkyl, C3-C6-alkenyl, or R6 and R7 together represent an optionally methyl- or ethyl-substituted C4-C5-aIkylene radical in which optionally one methylene group is replaced by oxygen or sulphur. Compounds of the formula (I) as claimed in claim 1 in which Het represents X represents hydrogen, chlorine, bromine, methyl, ethyl, n-propyl, iso-propyl, n-butyl or iso-butyl, Y represents methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, tert-butyl, trifluoromethyl or represents the group or in the case of Het = thiazolyl ((I-l-A) to (I-3-A)) also represents in which V1 represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, tert-butyl, methoxy, ethoxy, n-propoxy, iso-propoxy, trifluoromethyl, trifluoromethoxy, nitro, cyano, phenoxy or phenyl which is optionally mono- or disubstituted by fluorine, chlorine, methyl, methoxy, trifluoromethyl or trifl uoromethoxy, V2 represents hydrogen, fluorine, chlorine, methyl, ethyl, n-propyl, iso-propyl, methoxy, ethoxy, trifluoromethyl or trifluoromethoxy, or V1 and V2 together represent ~0-CH2-0-, -0-CF2-0- or -0-CF2-CF2-0-, W represents N-D(1). oxygen(2) or sulphur (3), A represents hydrogen, represents in each case optionally fluorine-substituted C1-C8-alkyl or C1-C4-alkoxy-C1-C2-alkyl, optionally fluorine-, methyl-, ethyl- or methoxy-substituted C3-C6-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur or represents in each case optionally fluorine-, chlorine-, bromine-, methyl-, ethyl-, n-propyl-, iso-propyl-, tert-butyl-, methoxy-, ethoxy-, trifluoromethyl-, trifluoromethoxy-, cyano- or nitro-substituted phenyl or benzyl, B represents hydrogen, methyl or ethyl, or A, B and the carbon atom to which they are attached represent saturated C5-C6-cycIoaIkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally mono- or disubstituted by methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, trifluoromethyl, methoxy, ethoxy, propoxy, iso-propoxy, butoxy or iso-butoxy or A, B and the carbon atom to which they are attached represent C6-cycloaikyl which is substituted by an alkylenedioxyl group which is optionally mono- or disubstituted by methyl or ethyl and which together with the carbon atom to which it is attached forms a further five- or six-membered ring or A, B and the carbon atom to which they are attached represent C5-C6-cycloalkyI or C5-C6-cycloalkenyl in which two substituents together with the carbon atoms to which they are attached represent C2-C4-alkanediyl or C2-C4alkenediyl in which in each case optionally one methylene group is replaced by oxygen or sulphur, or represent butadienediyl, D represents hydrogen, represents in each case optionally fluorine-substituted C1-C6-alkyl, C3-C4-alkenyl, C1-C4- alkoxy-C2-C3-alkyl, C1-C4-alkylthio-C2-C3-alkyl or C3-C6-cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur or represents in each case optionally fluorine-, chlorine-, methyl-, ethyl-, n-propyl-, iso-propyl-, methoxy-, ethoxy-, trifluoromethyl- or trifluoromethoxy-substituted phenyl or benzyl, A and D together represent optionally substituted C3-C4-alkanediyl in which optionally one carbon atom is replaced by oxygen or sulphur and which is optionally substituted by methyl or A and D (in the case of the compounds of the formula (I-l)) together with the atoms to which they are attached represent one of the groups AD below: E represents a metal ion equivalent or an ammonium ion, L represents oxygen or sulphur and M represents oxygen or sulphur, R1 represents in each case optionally fluorine-substitutede C1-C14-alkyl), C2-C14-aIkenyl, C1-C4-alkoxy-C1-C2-aIkyl, C1-C4-alkylthio-C1-C2-alkyl or in each case optionally fluorine-, chlorine-, methyl-, ethyl- or methoxy-substituted cyclopropyl, cyclopentyl or cyclohexyl, represents phenyl which is optionally mono- or disubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, tert-butyl, methoxy, ethoxy, trifluorornethyl or trifluoromethoxy, represents thienyl or pyridyl, each of which is optionally monosubstituted by fluorine, chlorine, bromine or methyl, R2 represents in each case optionally fluorine-substituted C1-C8-alkyI, C2-C8-alkenyl or C1-C4-alkoxy-C2-C3-alkyl, represents optionally fluorine-, chlorine-, methyl-, ethyl-, n-propyl-, iso-propyl- or methoxy-substituted cyclohexyl, or represents in each case optionally fluorine-, chlorine-, cyano-, nitro-, methyl-, ethyl-, methoxy-, trifluorornethyl- or trifluoromethoxy-substituted phenyl or benzyl, R3 represents methyl, ethyl, n-propyl or represents phenyl which is optionally monosubstituted by fluorine, chlorine, bromine, methyl, tert-butyl, methoxy, trifluorornethyl, trifluoromethoxy, cyano or nitro, R4 represents C1-C4-alkyl, C1-C4-alkoxy, C1-G4-alkylamino, di-(C1-C4-alkyl)amino, C1-C4-alkylthio or represents in each case optionally fluorine-, chlorine-, bromine-, nitro-, cyano-, C1-C2-alkoxy-, C1-C2-fluoroaIkoxy-, C1-C2-alkylthio-, C1-C2-fluoroalkylthio- or C1-C3-alkyI-substituted phenyl, phenoxy or phenylthio, R5 represents methoxy, ethoxy, methylthio or ethylthio, R6 represents C1-C4-alkyl, C3-C6-cycloaIkyl, C1-C4-aIkoxy, C3-C4-alkenyl, C1-C4-alkoxy-C1-C4-alkyl, represents optionally fluorine-, chlorine-, bromine-, trifluoromethyl-, methyl- or methoxy-substituted phenyl, represents optionally fluorine-, chlorine-, bromine-, methyl-, trifluoromethyl- or methoxy-substituted benzyl, R7 represents hydrogen, methyl, ethyl, propyl or allyl, or R6 and R7 together represent a C5-C6-alkylene radical in which optionally one methylene group is replaced by oxygen or sulphur. 5. Compounds of the formula (I) as claimed in claim 1 in which Het represents Y represents methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, tert-buiyl, trifluoromethyl or represents the group or in the case of Het = thiazolyl ((I-l-A) or (I-3-A)) also represents "^ in which V1 represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, tert-butyl, methoxy, ethoxy, n-propoxy, iso-propoxy, trifluoromethyl, trifluoromethoxy, phenoxy, represents optionally chlorine- or trifluoromethyl-substituted phenyl, V2 represents hydrogen, fluorine, chlorine, methyl, ethyl, methoxy or trifluoromethyl, or Vl and V2 together represent -0-CH2-0- or -0-CF2-0-, W represents N-D(1), oxygen(2) or sulphur (3) A represents hydrogen or C1-C4-alkyl or cyclopropyl, B represents hydrogen or methyl, or A, B and the carbon atom to which they are attached represent saturated C5-C6-cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur, and which is optionally mono- or disubstituted by methyl, ethyl, propyl, isopropyl, trifluoromethyl, methoxy, ethoxy, propoxy, butoxy or iso-butoxy, or represents C5-C6-cycloalkyl in which two not directly adjacent carbon atoms form a further five-membered ring, D represents hydrogen, D also represents i-propyl, A and D together with the atoms to which they are attached represent cyclohexyl in which one ring atom may be replaced by sulphur, G represents hydrogen (a) or in the case of Het = thiazolyl ((M-A) to (I-3-A)) represents one of the groups in which L represents oxygen and M represents oxygen, R1 represents in each case optionally fluorine- or chlorine-substituted C1-C4alkyl, C2-C4-alkenyl, C1-C4-alkoxy-C1-C2-alkyl, C1-C4-alkyIthio-C1-C2-alkyI or optionally fluorine-, chlorine-, methyl-, ethyl- or methoxy-substituted cyclopropyl or cyclohexyl. represents phenyl which is optionally monosubstituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, n-propyl, i-propyl, tert-butyl, methoxy, ethoxy, i-propoxy, tert-butoxy, trifluoromethyl or trifluoromethoxy, represents thienyl or pyridyl, each of which is optionally monosubstituted by chlorine or methyl, represents optionally in each case fluorine-substituted C1-C4-alkyl, C2-C4-alkenyl or C1-C4-alkoxy-C2-C3-alkyl, represents optionally methyl-, ethyl-, n-propyl-, iso-propyl- or methoxy-substituted cyclohexyl, or represents phenyl or benzyl, each of which is optionally monosubstituted by fluorine, chlorine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy. Compounds of the formula (I) as claimed in claim 1 in which represents represents methyl, ethyl, n-propyl, i-propyl, chlorine or bromine, represents methyl, ethyl, n-propyl or i-propyl or represents the groups in which V1 represents hydrogen, bromine, chlorine, methyl, trifluoromethyl, phenoxy or t-butyl or represents optionally chlorine- or trifluoromethyl-substituted phenyl, V2 represents hydrogen, chlorine, fluorine or methoxy or V1 and V2 together represent -0-CH2-0- or -0-CF2-0-, W represents N-D(1), oxygen(2) or sulphur (3), D represents hydrogen or i-propyl, A represents methyl, ethyl, n- or i-propyl or cyclopropyl or hydrogen, B represents hydrogen or methyl, or A and B and the carbon atom to which they are attached represent cyclohexyl in which optionally one ring atom is replaced by oxygen and which is optionally mono- or disubstituted by methyl, ethyl, methoxy or ethoxy, or represent cyclohexyl in which two not directly adjacent carbon atoms form a further 5-membered C ring, A and D together with the atoms to which they are attached represent cyclohexyl in which one ring atom may be replaced by sulphur. G represents hydrogen (a) or represents one of the groups in which R1 represents methyl, ethyl, n-propyl or i-propyl or represents in each case optionally chlorine-substituted phenyl or pyridyl, R2 represents methyl, ethyl, phenyl, benzyl, n- or i-propyl. 7. Compounds of the formula (I) as claimed in claim 1 in which Het represents X represents methyl or ethyl, Y represents optionally chlorine-substituted phenyl, A represents methyl, ethyl, n- or i-propyl, B represents methyl, or A and B and the carbon atom to which they are attached together represent cyclohexyl which is optionally substituted by methoxy or methyl, W represents N-D or oxygen, D represents hydrogen, G represents hydrogen. 8. Process for preparing compounds of the formula (I) as claimed in claim 1, characterized in that compounds of the formulae (I-l-A-a) to (I-l-Ba) in which A, B, D and Het are each as defined above are obtained when compounds of the formula (II) in which A, B, D and Het are each as defined above and R8 represents alkyl are condensed intramolecularly in the presence of a diluent and in the presence of a base, compounds of the formulae (I-2-A-a) to (I-2-B-a) in which A, B and Het are each as defined above are obtained when in which A, B, Het and R.8 are each as defined above are condensed intramolecularly in the presence of a diluent and in the presence of a base, (C) compounds of the formulae (I-3-A-a) to (I-3-B-a) in which A, B and Het are each as defined above, are obtained when compounds of the formula (IV) in which A, B, Het and R8 are each as defined above and W1 represents hydrogen, halogen, alkyl or alkoxy, are cyclized intramolecularly, if appropriate in the presence of a diluent and in the presence of an acid, and, if appropriate, the resulting compounds of the formulae (I-l-A-a) to (I-3-B-a), in which A, B, D and Het are each as defined above are in each case reacted (a) with acyl halides of the formula (V) in which R1 is as defined above and Hal represents halogen or (8) with carboxylic anhydrides of the formula (VI) Rl-CO-O-CO-R1 (VI) in which Rl is as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder; with chloroforrnic esters or chloroformic thioesters of the formula (VII) R2-M-CO-C1 (VII) in which R2 and M are each as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder; with chloromonothioformic esters, or chiorodithioformic esters of the formula (VIII) in which M and R2 are each as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder with sulphonyl chlorides of the formula (IX) R3-SC2-C1 (IX) in which R3 is as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder, (H) with phosphorus compounds of the formula (X) in which L, R4 and R5 are each as defined above and Hal represents halogen, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder, (I) with metal compounds or amines of the formula (XI) or (XII) in which Me represents a mono- or divalent metal, t represents the number 1 or 2 and R10, R11, R12 independently of one another each represent hydrogen or alkyl, if appropriate in the presence of a diluent, (J) (a) with isocyanates or isothiocyanates of the formula (XIII) in which R6 and L are each as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of a catalyst, or (B) with carbamoyl chlorides or thiocarbamoyl chlorides of the formula (XIV) in which L, R6 and R7 are each as defined above, if appropriate in the presence of a diluent and if appropriate in the presence of an acid binder. 9. Pesticides and herbicides, wherein that they comprise at least one compound of the formula (I) as claimed in claim 1. 10. Method for controlling pests and weeds, wherein compounds of the formula (I) as claimed in claim 1 are allowed to act on pests and/or their habitat or on weeds and/or their habitat. |
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in-pct-2002-01715-mum-cancelled pages(5-9-2007).pdf
in-pct-2002-01715-mum-claims(granted)(05-09-2007).doc
in-pct-2002-01715-mum-claims(granted)-(5-9-2007).pdf
in-pct-2002-01715-mum-correspondence(14-9-2007).pdf
in-pct-2002-01715-mum-form 18(3-12-2005).pdf
in-pct-2002-01715-mum-form 1a(3-1-2007).pdf
in-pct-2002-01715-mum-form 2(granted)(05-09-2007).doc
in-pct-2002-01715-mum-form 2(granted)-(05-09-2007).pdf
in-pct-2002-01715-mum-form 3(3-1-2007).pdf
in-pct-2002-01715-mum-form 5(3-1-2007).pdf
in-pct-2002-01715-mum-form-pct-ipea-409(5-9-2007).pdf
in-pct-2002-01715-mum-form-pct-isa-210(5-9-2007).pdf
in-pct-2002-01715-mum-petition under rule 137(3-1-2007).pdf
in-pct-2002-01715-mum-petition under rule 138(3-1-2007).pdf
in-pct-2002-01715-mum-power of authority(23-10-2002).pdf
in-pct-2002-01715-mum-power of authority(3-1-2007).pdf
Patent Number | 216988 | ||||||||||||||||||||||||||||||
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Indian Patent Application Number | IN/PCT/2002/01715/MUM | ||||||||||||||||||||||||||||||
PG Journal Number | 13/2008 | ||||||||||||||||||||||||||||||
Publication Date | 28-Mar-2008 | ||||||||||||||||||||||||||||||
Grant Date | 24-Mar-2008 | ||||||||||||||||||||||||||||||
Date of Filing | 02-Dec-2002 | ||||||||||||||||||||||||||||||
Name of Patentee | BAYER CROPSCIENCE AG | ||||||||||||||||||||||||||||||
Applicant Address | ALFRED-NOBEL-STRASSE 50, 40789 MONHEIM, GERMANY. | ||||||||||||||||||||||||||||||
Inventors:
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PCT International Classification Number | C 07 D 417/04 | ||||||||||||||||||||||||||||||
PCT International Application Number | PCT/EP01/06174 | ||||||||||||||||||||||||||||||
PCT International Filing date | 2002-12-02 | ||||||||||||||||||||||||||||||
PCT Conventions:
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