Title of Invention

PRE-FORM AND METHOD OF PREPARING A PRE-FORM

Abstract A pre-form comprises a resin and at least three layers of fibre (2), wherein the resin (4) is mainly an uncured thermosetting resin, and a part of said pre-form is formed three- dimensionally so that said part of said pre-form is tapered, characterised in that said at least three layers of fibres are oriented fibre tows (2). A method for preparing a pre-form comprising the steps of: providing layers of fibres (2), providing an adhesive (6) between said layers of fibres (2) to at least partially immobilising the fibres (2), providing a resin (4) in contact with at least one of the layers of fibre (2), wherein a fibre layer is provided off the edge of a preceding fibre layer, thereby realising a tapered part of the pre-form and the resin (4) is an uncured thermosetting resin, characterised in that the layers of the fibres are oriented fibre tows (2).
Full Text PRE-FORM AND METHOD OF PREPARING A PRE-FORM
TECHNICAL FIELD OF THE INVENTION
The invention relates to fibre-reinforced composites. In particular, the invention relates to a
semi-manufacture comprising a resin and several layers of fibre tows.
BACKGROUND OF THE INVENTION
Pre-forms comprising resin and fibres are known in the prior art.
US-patent 6,139,942 discloses a pre-form with a stack of partially impregnated fabric and
un-impregnated fabric. The layers of such a stack may slide before curing and hence be
difficult to handle, it is suggested to use cross-ply stitching to prevent this, however, this
process is tedious and may introduce undesirable restrictions to the shape of the stack
during curing.
EP-patent 0 475 883 also discloses a pre-form with a plurality of oriented fibre layers.
However, the pre-form requires infusion of a resin to cure which may be time-consuming
and to some extent prevent rearranging of the fibres and resin during curing.
WO 02/090089 discloses a moulding material having a ventilating structure in the otherwise
continuous resin layers. The ventilating structure is designed to allow gas to be removed
from the moulding material during processing in the plane of the resin and/or in the plane of
the reinforcement material. As the ground plan of the moulding material increases, this will
become a still less safe way to remove gas from the moulding material due to the increasing
risk of plugging during processing.
EP 0 033 224 concerns a material for forming fibre reinforced structures with a thermoplastic
resin. The thermoplastic resin is provided by passing the fibres through a bath with
thermoplastic resin or by mixing dry fibres with thermoplastic fibres and heat the collection.
From these coated fibres is formed by weaving or knitting. The description specifically
teaches away from the use of thermosetting resins.
EP 1 145 841 concerns a material consisting of "fibre bundle layers". Each fibre bundle
layer consists of apparently fully wetted fibre bundles and thermosetting resin and the
individual layers are oriented so that the fibres of different layers are oriented differently.

DE 198 09 264 concerns a material consisting of a number of fibre layers, each layer having
an individual orientation, and a melting adhesive. The preferred and only described melting
adhesives are thermoplastic adhesives (Schmelzklebergebilde aus thermoplastischem
Polymermaterial, p3, I 3-7).
FR 2794400 concerns a method of manufacturing a composite material from fibrous sheets.
The starting material is prepregs, i.e. impregnated textile sheets of fibres. The sheets are
stacked and knitted together, whereupon the stack is wrapped in a surface layer. Since the
fibres are fixed in a textile and furthermore impregnated prior to the resin infusion, the
mobility of the fibres is limited. Therefore, the ability of the prepreg to form a homogeneous
material during resin infusion, pre-consolidation and curing is considerably lower than pre-
forms based on fibre tows, which is the subject-matter of the present invention.
OBJECTS OF THE INVENTION
It is the object of the invention to provide a pre-form that may be used for manufacture of
reinforced composites and which poses good reproducibility, low porosity and good physical
properties.
It is a further object of the invention to provide a pre-form and a method of production of a
pre-form that are adaptable to automated processing.
DISCLOSURE OF THE INVENTION
The above and more objects are realised by the invention as described and explained with
reference to the accompanying drawings and preferred embodiments.
A pre-form is a composite material comprising fibres and - unless otherwise stated - an
uncured resin. The fibres are preferably provided in layers of oriented fibres like for
example fibre tows or prepregs. Fibre tows are advantageous over prepregs. Furthermore,
fibre tows are more advantageous over prepregs in that they may be provided in
the pre-form with a greater freedom, the price is lower as well as the amount of
waste may be lower. The invention provides a pre-form comprising a resin and at least
two layers of oriented fibre tows, however, the advantage of using a pre-form or a method
according to the present invention will increase as the number of layers of oriented fibre

tows are increased. Hence, the pre-form preferably comprises at least three layers of
oriented fibre tows. A higher number of layers like e.g. 4, 5, 8, 10, 15, 20, 50,100 or more
layers may be used within the scope of the invention.
Besides fibres and resin, a pre-form according to the invention may for example contain one
or more of fillers (e.g. a cheap inert material) and/or solvents and/or diluents and/or
rheological agents and/or viscosity adjusting agent.
The layers of oriented fibres are fibre tows contrary to pre pregs, since this provides a higher
degree of freedom of design and will allow for a lower viscosity and mobility of fibres during
subsequent processing of a pre-form, e.g. pre-consolidation or curing. Furthermore, pre-
forms prepared from fibre tows are advantageous over pre-forms prepared from prepregs in
that the cost of production is lower as well as the amount of waste is typically lower. Fibre
tows are bundles of a large number of individual fibres, e.g. 1,000's, 10,000's or 100,000's of
fibres.
It may be theorised that the strength of a composite depends amongst others on the
strength of the interface between the fibres and the matrix material (i.e. the cured resin). As
the stiffness of the fibre is increased, the sensitivity to the strength of the interface is also
increased. Presence of porosity may weaken the interface but the actual effect of the
porosity depends for example on the positioning and the size of the pores. Generally
speaking, the greater the pores and the greater the amount of pores, the worse. Another
aspect is the wetting of the fibres. The difficulty in getting a good vetting of the fibres
increases as the fibre diameter is decreased. The processes and products of the present
invention are particularly advantageous for pre-forms comprising thin and stiff fibres like for
example carbon fibres, however, these processes and products are also superior to the prior
art when other types of fibres are used as reinforcement like for example glass fibres,
aramid fibres, synthetic fibres (e.g. acrylic, polyester, PAN, PET, PE, PP or PBO-fibres), bio
fibres (e.g. hemp, jute, cellulose fibres etc.), mineral fibres (e.g. Rockwool™), metal fibres
(e.g. steel, aluminium, brass, copper, etc.) or boron fibres.
Traditionally, gas enclosed in the pre-form prior to and during curing has traditionally been
removed in the direction of the fibres, i.e. in the plane of a resin layer. Hence, the larger the
structure, the longer the gas has to travel to be released from the structure. The risk that gas

becomes trapped inside a cured structure is hence increased with the size of the structure. It
appears that the problem with entrapped gas is particularly pronounced when the
reinforcement is unidirectional fibres. It may be speculated that this is due to the very close
packing of the fibres, which may arise in some areas of a composite reinforced by
unidirectional fibres. However, problems concerning entrapped gas may also be present in
other types of fibre orientations e.g. biaxial or random orientations and the inventive idea of
the present invention is hence advantageous for any type of fibre orientation even if the
advantage is greatest when using a unidirectional fibre orientation.
By gas is herein meant entrapped atmospheric air as well as gaseous products, by-products
and starting materials related to the preparation process.
The fibres may be a mixture of more than one type of fibres. For example, a combination of
glass fibres and carbon fibres may be used, but any combination of two or more of the fibre
types mentioned herein are feasible. The mixture may be homogeneous, with different
concentrations in separate fibre layers or with different concentrations of fibres within any
fibre layer. Mixing of fibres may be advantageous, since this opens for tailoring of material
properties, for example from a combined stress/cost-perspective, or parts of a pre-form
particularly suitable for connecting to other materials may be provided. However, in a
preferred embodiment, the fibres are primarily or exclusively carbon fibres.
By carbon fibres is hereinafter meant fibres where the main component is carbon. Hence, by
this definition carbon fibres comprise fibres with graphite, amorphous carbon or carbon
nano-tubes. Thus, carbon fibres produced via for example a polyacrylonitril-route and a
pitch-based route are comprised by this definition.
By fibres are hereinafter meant particles having an aspect ratio (length/equivalent diameter)
of more than 10. By equivalent diameter is meant the diameter of a circle having the same
area as the cross sectional area of the particle. However, in a preferred embodiment, the
fibres are continuous fibres, i.e. fibres that substantially run from one edge of a pre-form to
another.
It is preferred to use thermosetting resin for reasons of chemical and thermal stability as well
as ease of processing. It is further preferred that the resin is an epoxy-based or a polyester-

based resin, most preferably an epoxy-based resin. The resin may comprise more than one
resin system. It may be advantageous to use more than one resin system to be able to
optimise the properties of the resin for the subsequent steps of processing, for example with
respect to viscosity and timing/controlling of the curing process. These systems may or may
not be based on the same type of resin, however, it is preferred that such systems are based
on the same type of resin like for example two or more epoxy-based systems, In another
preferred embodiment, the resin types differ but the resins are compatible.
The method according to the invention is adapted to automated processing. For example,
the layers of oriented fibre tows, the adhesive and the resin may advantageously be
distributed by a robot. The automation is facilitated by an at least partial immobilisation of
fibres by an adhesive, which will prevent or at least greatly reduce disturbance in the layers
of oriented fibre tows. When the adhesive is only applied to selected areas of the ground
plan of the pre-form, time is furthermore saved compared to distribution of resin over the
entire ground plan.
Resin systems may contain components, which may be irritant or harmful when in contact
with naked skin, if ingested or inhaled. Avoidance of direct contact is therefore highly
desirable. Since the products and processes according to the invention are particularly well
suited for automation, the products and processes according to the invention represent a
significant improvement to the working environment.
BRIEF DESCRIPTION OF THE ACCOMPANYING DRAWINGS
Fig. 1 shows a schematic cross sectional view of a pre-form.
Fig. 2 shows a schematic view of preferred geometrical ground plans and fibre orientations
in a pre-form.
Fig. 3 shows a schematic view of preferred configurations of a resin layer.
Fig. 4 shows a schematic view of preferred configurations of an adhesive.
Fig. 5 shows examples of pre forms with tapered parts.
Fig. 6 shows a schematic view of a preferred method of preparing a resin.
Fig. 7 shows an example of a pre-form having tapered parts prepared from fibre layers
having substantially the same size.

Fig. 8 shows an example of a pre-form enhanced for coupling of two composite
members comprising two different types of reinforcement fibres.
DESCRIPTION OF THE DRAWINGS
In Fig. 1 an example of a schematic sectional view of a pre-form is shown Indicating an
example of the order of the components. In a real pre-form, the distance between the
layers would be much smaller and the resin and adhesive would usually be partially
absorbed into the layers of fibres. Layers of oriented fibre 2 are provided with strips of
adhesive 6 (see Fig. 4) at an angle - here about orthogonal - to the layers of oriented
fibre tows 2. Two layers of resin 4 are also provided. The resin 4 is distributed as a
number of lines (see Fig. 3) at an angle - here about orthogonal - to the layers of
oriented fibre tows 2. The resin hence is distributed in a non-continuous layer to allow
for gas to escape from the pre-form orthogonal to the direction of the fibre tows.
In Fig. 1 the resin is provided between twp layers of fibre tows. This is the preferred
positioning of resin and when this positioning is used, it is highly desirable that the
resin is distributed in non-continuous layers. However, the resin may also be provided
in contact with only one layer of fibre tows, i.e. in the top or at the bottom of the pre-
form. In this case, it is preferred to provide the resin at the bottom of the pre-form and
the resin may be provided in a continuous layer as gas will not usually have to escape
through the resin layer. In a preferred embodiment, resin is only provided at top and/or
the bottom of the pre-form, i.e. only adhesive is provided between the layers of fibres.
In another preferred embodiment, resin is only provided at the bottom of the pre-form,
i.e. between the layers of fibres only adhesive is provided.
The adhesive 6 should at least partially immobilise the fibres that are provided on top
of the adhesive. The adhesive may be any type of adhesive, however, the adhesive
should be compatible to the resin, preferably the adhesive is a resin-type adhesive and
related to the resin of the pre-form in the sense that it comprises the same type of
chemistry. For example, the adhesive may comprise at least one of the components of
the resin (e.g. a common epoxy component). One way to ensure compatibility between
the resin and the adhesive is to use substantially the same composition. In a preferred
embodiment, the composition of the adhesive is the same as the composition of the
adhesive. It is within the scope of the invention to use more than one adhesive in a

pre-form. For example some portions of adhesive may have the same composition as
the resin, whereas other portions may have a different composition.
Examples of preferred embodiments of geometrical ground plans 10 of pre-forms are
shown in Fig. 2. The lines 2 indicate the main fibre orientation(s) of a fibre layer. Each
layer of fibres typically comprises a large number (e.g. multiple millions) of fibres
oriented in the main and optionally further orientations. A person skilled in the art will
be able to derive a number of other geometrical ground plans without deriving from the
inventive idea of the invention. Fig. 2A shows a rectangular pre-form, which may be
particularly suitable for flat or cylindrical structures. Fig. 2B - Fig. 2F show pre-forms
with substantially trapezoid ground plans. The angles  and  may be the same or
different, however, it is preferred that these angles are substantially the same, since
the pre-form may then be used for production of for example conical structures.
The ratio of the distance between the parallel sides and the length of any of the
parallel sides is preferably at least 3 and more preferably at least 5, since such pre-
forms are particularly useful for production of long, slightly conical structures like spars
for wind turbine blades. The ground plan in Fig. 2F has a ratio of about 6.
Fig. 2G shows a pre-form with a triangular ground plan. Again, it is preferred that the
angles  and  are substantially the same. Such a pre-form may be particularly useful
for reinforcing a structure with a relatively sharp corner. The pre-form in Fig. 2H has a
more irregular quadrangular ground plan. Such quadrangular ground plans may or
may not have one or two angles of 90°.
In Fig. 21 is an example of a layer having two main fibre orientations. Here, the fibres
are mainly oriented parallel to the longer edges, however, other orientations are
feasible as well as more than two main orientations. Fig. 2J shows an example of a
layer having non-straight fibres. The fibres are preferably oriented to optimise the final,
structure - after shaping and curing - with respect to strength and/or other properties.
The fibres 2 may be provided in any desirable orientation like for example
unidirectional, biaxial or random. However, the fibres should be oriented as to
strengthen areas of the final structure, which will be exposed to a higher stress during
service. Typically, this may be realised by orienting the fibres primarily unidirectionally
and either substantially parallel to or orthogonal to an edge of the pre-form. In Fig. 2A,

C, D, H and I the fibres are placed substantially parallel to at least one edge of the pre-form
and in Fig, 2A, B, E, F, G and H the fibre tows are placed substantially orthogonal to at least
one edge of the pre-form. If the ground plan has two parallel sides and the ratio of the
distance between the parallel sides and the length of any of the parallel sides is very large,
i.e. >5, then unidirectional fibres placed between the two parallel sides may be considered
to be substantially parallel to the longer edges (see e.g. Fig. 2F). Other ways of orientating
the fibres may be derived by a person skilled in the art without departing from the inventive
idea of the invention.
The orientation of fibres may or may not be the same in all the layers of fibres ; however, in
a preferred embodiment the fibres are oriented substantially the same in all the layers of
fibres. When one or more layers of fibres are oriented in another way as other layers, this
may for example be if the stress analysis suggests a multi-axial fibre placing, but
unidirectional fibre placing is favourable for manufacturing reasons.
Another way to strengthen the area of the final structure, which will be exposed to higher
stress during service, is to increase the amount of fibres in these areas. An example of this
is shown in Fig. 2E, where the area near the central part of the pre-form has a greater
amount of fibre tows than the outer parts of the pre-form.
It is preferred that the resin is provided to form a non-continuous layer or layers,
even if this is not a requirement for layers of resin where gas will not escape
through during a subsequent consolidation and/or curing of the pre-form. The
resin may stick to and/or at least partially immobilise fibres of one or more layers. The
discrete dots may for example be formed from a resin provided as a liquid. A liquid resin
may also be provided as a line or several lines, which may be form an oriented pattern, a
random pattern or a combined pattern. An example of an oriented pattern is shown in Fig.
3A, where a resin is distributed as lines of resin 4a orthogonal to a main fibre orientation. As
a variation to the distribution shown in Fig. 3A, the resin may be provided partially over the
edge, i.e. the turning part of the string may be off the ground plan to provide for a more even
density of resin, However, this will result in an undesired waste and should be omitted for
example by controlling the flow of the resin during the applying. An example of
a random pattern is shown in Fig. 3C, where a resin is distributed as curly lines. A

different approach to a non-continuous layer of resin is shown in Fig. 3D where a
sheet of resin 4d having a number of through-going holes 12 are provided. As it is
obvious from these examples of resin patterns, a person skilled in the art will be able
to provide other patterns without departing from the Inventive idea of the invention.
The adhesive 6 may in principle be provided in the same patterns as the resin,
however, it is preferred to provide a less dense pattern for the adhesive to save time.
In Fig. 4 some preferred embodiments of the adhesive distribution are shown. It is
important to keep in mind that the purpose of the adhesive is to ensure that the fibres
are at least partially immobilised to facilitate fibre laying. Furthermore, the adhesive will
often increase the mechanical strength and hence the handieability of an
unconsolidated and uncured pre-form by at least partially fixing adjacent layers of fibre
to each other. One way to ensure a facilitation of the fibre laying is to provide a strip of
adhesive close to or exactly where the fibres are initiated during fibre laying. In Fig. 4A
the direction of the fibre laying is indicated by the arrow 14. Hence, the fibres are
initiated near the adhesive 6a. A preferred way to ensure a relatively good fixation of
the fibres is to provide adhesive 6b near the termination of the fibres. If the adhesive
6a and 6b does not provide sufficient fixation of the fibres, further adhesive 6c may be
provided. In Fig. 4A the adhesive is provided as strips, however, other embodiments
are also feasible like for example dots, broken or curved lines, etc. In some cases,
automation may favour an adhesive pattern, where the adhesive is applied in a
continuous line, for example as a zigzag pattern as shown in Fig. 4B. This is an
example of a pattern where the number of adhesive initiations and terminations are
reduced compared to the pattern in Fig. 4A. A person skilled in the art will appreciate
the advantage of providing only a limited amount of adhesive compared to either a full
or nearly full layer of resin or cross-ply stitching, particularly with respect to the time
saved during processing and ease of automation.
In some applications, the pre-form is intended for reinforcing structures with a non-
circular cross section like for example a spar having a substantially rectangular cross
section where the pre-form should be bent around a relatively sharp edge. The
preferred orientation of fibres in such case is that the main fibre orientation is parallel
to the edge, e.g. in the direction I-I in Fig. 5, It may then be advantageous to form at
least part of the pre-form three-dimensionally to enhance shaping of the pre-form. To
realise a significant outcome of a three-dimensional forming, the pre-form usually
should preferably comprise at least three layers of oriented fibre tows, since if the pre-

form consists of only two layers, the pre-form may usually be bent without three-
dimensional shaping of the pre-form. The higher the number of layers, the greater the
benefit from three-dimensionally forming of the pre-form. In a preferred embodiment, a
pre-form is provided with two tapered sections 22 towards the edges substantially
parallel to the fibre orientation as indicated in Fig. 5; however, a person skilled in the
art may derive a number of variations without deriving from the inventive idea of the
invention. Such variations may for example be using one, three or another number of
tapered parts, using one or more steps instead of tapered parts, placing a tapered part
away from an edge e.g. near the centre etc.
By being formed three-dimensionally is herein meant that the thickness (e.g. the
number of layers or amount of fibres and/or resin) and/or the form of the ground plan is
adjusted for a part (e.g. 20, 22) of the pre-form relative to the bulk (e.g. 24) of the pre-
form.
Three-dimensional forming may also be applied for reducing of the interfacial stress
between a pre-form and an adjacent structure. Examples of such adjacent structures
are other pre-forms and parts of larger structures, e.g. a root of a blade for a wind
turbine. Typically, such three-dimensional forms will involve the creation of a large
contact area orthogonal to the main stress direction in at least one axis. In Fig. 5 a part
20 is an example of a three-dimensional form for reducing the interfacial stress
between the pre-form and an adjacent connected structure. A distance much greater
than the orthogonal distance separates the terminations of the layers of fibres in the
tapered section 20 as seen in the cross section along I-I in Fig. 5 and hence the
interfacial stress will be reduced.
A particular ground plan or three-dimensional form may for example be realised by
selective initiating and/or terminating fibre tows during fibre laying.
The main function of the adhesive is to immobilise the fibres as they are placed on top
of the adhesive. This can be achieved by having a tacky adhesive, whereby the fibres
stick to the tacky adhesive. The adhesive may be any tacky material, or a solid with a
tacky surface and the adhesive may for example comprise polyester, polyurethane,
epoxy or similar compounds or a combination of these. It is within the scope of the
invention to use any material or combination of materials having a tacky surface
including solid materials with tacky surfaces. More than one type of adhesive may be

used within a pre-form. For example, it is within the scope of the invention to use the resin
as an adhesive between the layers of fibre tows where a resin is provided or to use a second
type of resin below the first layer of fibre tows.
The resin may be liquid material. The resin may for example be based on unsaturated
polyester, polyurethane, epoxy, or similar chemical compounds, including combinations of
these.
In a preferred embodiment of the invention, the resin is a liquid and the resin is introduced
by Resin Transfer Moulding, RTM, or Vacuum Assisted Resin Transfer Moulding, VARTM,
into an entity comprising several layers of oriented fibre tows, which were previously
immobilised during fibre laying by an adhesive.
The resin may comprise more than one system, for example the resin may comprise two
systems or even more systems. These systems may be any combination of different or the
same type of systems, however, it is preferred that the resin comprises two substantially
epoxy-based systems. In a preferred embodiment, two epoxy-based systems comprise a
common component. The common component may for example be a common catalyst, a
common amine component or a common epoxy component ; however, it is preferred that
the common component is an epoxy component. A resin comprising two epoxy-based
systems with a common epoxy component may comprise an amine-component of a first
epoxy-based system that will react to the common epoxy component at a first relatively low
temperature, like for example below 50°C, preferably about room temperature. At this first
temperature, a second epoxy-based system is preferably non-reactive or the reaction takes
place at a very low rate. Since the reaction rate of the second epoxy-based system should
be very low, it may advantageously be catalysed by a catalyst, which is non-active until
activated. This activation may for example be by UV-light, addition of a compound or by
heating, however, it is preferred that the catalyst is activated by heating.
In one embodiment sketched in Fig. 6, a pre-mix 36 comprises amine components 30a and
30b and a catalyst 32, preferably for catalysing the curing of a second epoxy-based system.
The pre-mix should be a stable solution or slurry and if the viscosity is too low to prevent
precipitation of a solid component like e.g. a catalyst, a small amount of an epoxy
component preferably a common epoxy component of the systems, may be added.

Typically 0.1 to 5% by weight of epoxy should be sufficient to adjust the viscosity. The pre-
mix and a common epoxy component should be mixed immediately before distribution of the
resin 40. The resin may be heated to decrease the viscosity.
Resins to be used according to the present invention may be prepared in most of the
traditional ways familiar to a person skilled in the art and the embodiment with regard to
preparation of the resin that is disclosed in Fig. 6 should be considered as an example on
how a resin may be prepared. This embodiment should by no means be regarded as a
limitation of the scope of the invention.
Alternatively, a simple three-dimensional shape may be provided as shown, in Fig. 7, where
a number of identical ground plans of oriented fibres 50 are placed on top of each other but
shifted slightly. The lines shown on the ground plans 50 do not indicate the orientation of the
fibre tows but are merely included to enhance distinguishing the different layers when they
are combined. In the middle section of Fig. 7, the layers are placed on top of each other step
by step and hence forming a pre-form in the bottom part of Fig. 7 having parts 52 with a low
number of layers of fibres, parts 54 with an intermediate number of layers of fibres and a
part 56 with a high number of layers of fibres. When a higher number of layers are provided,
then the parts 52 and 54 may be prepared to appear almost taper-like. This method may
simultaneously provide a pre-form having two, three, four or more tapered parts.
The properties of a fibre-reinforced composite depend to a large extent on the
properties of the fibre. However, the properties of different types of fibres vary
considerably. For example, the coefficient of thermal expansion of carbon fibres is
very low, and in some cases even negative. It may therefore be very difficult to
connect carbon fibre-reinforced composites to composites reinforced by other types of fibres

and a pre-form comprising carbon fibres may therefore advantageously be enhanced
for coupling to a composite member comprising a second type fibres and a resin.
Examples of second type fibres are glass fibres, aramid fibres, synthetic fibres (e.g.
acrylic, polyester, PAN, PET, PE, PP or PBO fibres), bio fibres (e.g. hemp, jute,
cellulose fibres, etc.), mineral fibres (e.g. Rockwool™), metal fibres (e.g. steel,
aluminium, brass, copper etc.) or boron fibres.
In a preferred embodiment, the pre-form is enhanced for connecting by providing the
pre-form with second type fibres. These second type fibres should extend beyond the
pre-form to provide a part for connection. The second type fibres as well as the carbon
fibres may be provided in interlaced layers rich in the respective fibres. For example,
the layers may exclusively have only one of the type of fibres. In a preferred
embodiment, the layers comprising second type fibres are provided as prepregs. The
prepregs may be unidirectional prepregs, however, experimental results suggest,
surprisingly, that biaxial prepregs comprising the second type fibres provide a better
basis for connecting of the pre-form to a structure reinforced by second type fibres.
Near the end of a layer of fibres interlaced in a material having different properties, a
stress concentration will build up. To reduce or prevent coupling of stress from the
ends of one layer to the ends of the next layer, the distance of the interlace should be
greater that the extent of the stress concentration. Since the extent of the stress
concentration is difficult to establish, it is preferred to use a safety margin and hence
separate the ends of two adjacent layers by at least 2 times the extent of the stress
concentration-
It is also reasonable to ensure that the distance between the nearest layer end of the
same type of fibre should be separated by a distance corresponding to the extent of a
stress concentration, preferably with a safety margin and hence using a factor of 2.
The extent of the stress concentration depends on a number of factors, like for
example thickness of the layers, the type of fibres, the type of resin, etc., and may be
established by modelling or by empirical methods.
Pre-forms according to the invention and provided by a method according to the
invention are very useful for pre-consolidation, since the escape of gas from the pre-
form is facilitated by the presence of non-continuous layers of resin. The pre-forms

may alternatively be used directly for preparation of composite members by curing.
Particularly, the pre-forms are highly useful for preparation of members for wind
turbine blades, since composites fulfilling the quality requirements and reproducibility
requirements may be produced.
When larger structures comprising pre-forms according to the invention or pre-forms
produced by a method according to the invention are to be prepared, this may follow a
method wherein the pre-form is shaped at least partially plastically. The pre-form may
be connected to further pre-forms before or after shaping to provide a larger structure.
The pre-form may also be connected to other structures. It is preferred but not
required that the connections involve a tapered part or layers comprising second type
fibres. The combined structure may be placed in a vacuum enclosure and provided
with vacuum prior to curing. Finally, the pre-form structure is cured.
Fig. 8 shows an example of a cross section of a pre-form that is enhanced for
connection to a structure or other pre-forms being reinforced by a second type fibres.
More thorough connections are particularly important when the physical properties of
the structures to be connected differ significantly. Typically, the physical properties are
to a high extent dictated by the reinforcement fibres, and examples of relevant physical
properties are the coefficient of thermal expansion, CTE, and Young's modulus.
Hence, these types of connections are for example relevant when a composite
comprising carbon fibres are connected to a composite reinforced by another type of
fibres, since the CTE of carbon fibres are very low and may even be negative.
However, the same type of connections may be used for strong connections between
composites reinforced by other types of fibres. The second type fibres may be any of
the fibre-types mentioned previously in the description and for example this type of
connection may be used for connecting a carbon fibre-reinforced composite to a glass
fibre-reinforced composite. The pre-form in Fig. 8 has layers of second type fibres 62
(e.g. glass fibres) interlaced between the layers of carbon fibres 60 of the bulk pre-
form.
In a preferred embodiment, the overlay distance of the interlace 64 is greater than the
extent of the end condition of the interfacial stress between layers rich in or exclusively
containing carbon fibres and layers rich in or exclusively containing second type fibres,
since this will prevent a coupling or build-up of stress between the interlaced layers.
For the same reason and for reason of introducing a safety margin, it is more preferred

that the distance of the interlace 64 is greater than 2 times the extent of the end condition of
the interfacial stress.
In another preferred embodiment, the distance 66 between the ends of the layers rich in
second type fibres which are interlaced between layers rich in carbon fibres, are separated
by a distance greater than the extent of the end condition of the interfacial stress between
layers rich in carbon fibres and layers rich in second type fibres. Again, this is to prevent a
coupling or build-up of stress between the interlaced layers. For the same reason and for
reason of introducing a safety margin, it is more preferred that the distance between the
ends of the layers rich in second type fibres is greater than 2 times the extent of the end
condition of the interfacial stress.
In a possible use of the pre-form, the pre-form is further treated by pre-consolidation to form
a pre-consolidated pre-form as described in the following section. Pre-consolidation is
particularly useful when the fibres are provided as fibre tows, compared to fibres provided in
prepregs as a lower viscosity during the pre-consolidation process. This will increase the
redistribution of resin and/or fibres, which is highly desirable as it increases the homogeneity
of the resulting product.
By pre-consolidation is herein meant a process, whereby gas inside a pre-form is removed
and a low porosity pre-form is produced. Pre-consolidation involves redistribution of a resin
and optionally a redistribution of fibres. Furthermore, pre-consolidation may involve a limited
curing of the resin. Pre-consolidation is particularly useful as it produces a dense pre-form
(hereinafter named a pre-consolidated pre-form). Pre-consolidated pre-forms and
composites prepared from pre-consolidated pre-forms will be appreciated amongst others
due to good reproducibility, low porosity, high homogeneity, high strength, ability to plastical
shaping of the pre-consolidated pre-form, ability to be connected to other pre-forms and/or
other structures, suitability for automation and long shelf life without premature curing.
When the pre-consolidation involves a limited curing, this limited curing may involve a
release of up to 50% of the energy that will be released by a complete
curing of the resin. However, it is preferred that the extent of curing is limited to an extent
that will allow the pre-form to be deformed plastically. The degree of curing that will allow for
plastical deformation of a pre-consolidated pre-form depends amongst others on
the exact resin as well as on the fibre type and fibre content. Generally, it is preferred that

the limited curing involves less than about 20% of the energy that will be released by a
complete curing of the resin and more preferably that the limited curing involves
between 3 to 15% of the energy that will be released by a complete curing.
Generally speaking, the pre-consolidation process should reduce the porosity of a pre-
form, however, it is preferred that the resulting porosity of the pre-consolidated pre-
form is less than 5% by volume, preferably less than 2% by volume and more
preferably less than 1% by volume. In some cases, a porosity of even 1% may reduce
the properties of a composite considerably. In these cases, it will be appreciated that
the method and the pre-consolidated pre-forms may be produced with porosities well
below 1%. For example, a reproduced porosity of about 0.2% by volume was realised
for a composite with 60% carbon fibres in epoxy. The reduction of the porosity may for
example be a result of exposing the pre-form to a pressure and/or a vacuum in relation
to the pre-consolidation process.
The porosity of the pre-consolidated pre-form can not be established directly, as a
density is not known and may vary throughout the material. Hence, the porosity should
be established by optical method on a materialographic sample. Preparation of
materialographic samples from an uncured pre-consolidated pre-form is very
demanding, since the material comprises both a very soft element (i.e. a resin) and a
very hard element (i.e. the fibre). To establish a reproducible result, it is hence
necessary to cure the pre-form prior to materialographic preparation. This curing
should be pressureless to ensure that the porosity is unaffected by the process.
To ensure handleability, the pre-consolidated pre-form should be substantially
unsticky, i.e. it should be easily releasable from any relevant surface and it should not
leave excessive amounts of resin on a surface when released.
To ensure a long shelf life and/or stability during transportation it is important that the
curing reaction of the bulk of the resin is sufficiently low at room temperature and that
a catalyst - if present - is not activated by accident. For example, if the catalyst is
activated by heating, it should be ensured that the activation temperature is
considerably higher than the expected maximum temperature during storage.
One of the features of the pre-consolidated pre-forms is that they are at least partially
deformable. This may for example be realised through the balanced and limited curing

during the pre-consolidation process. In a preferred embodiment, at least a part of a
pre-consolidated pre-form is capable of being bent around an axis parallel to the main
fibre orientation with a diameter of more than I cm, however, in some cases a pre-
consolidated pre-form may be bent with a diameter of more than 5 cm by plastic
deformation. The low bending diameters may be realised by rearranging of resin
and/or fibres or by three-dimensional forming of a pre-form. By three-dimensional
forming is herein meant that the thickness (e.g. the number of layers or amount of
fibres and/or resin) and/or the form of the ground plan is adjusted for a part of the pre-
form relative to the bulk of the pre-form, Typically, only a part of the pre-consolidated
pre-form is prepared for very sharp bending, whereas bending around an axis with
larger diameters, e.g. 50 cm, may often be realised by all parts of the pre-consolidated
pre-form.
The stiffness of a pre-form realised during a pre-consolidation process should ensure
that the pre-consolidated pre-form is stiff enough to prevent relaxation of the pre-
consolidated pre-form in the length direction of the fibres when placed on a non-flat
surface and yet allow for plastic deformation around an axis parallel to the length
direction of the fibres. In particular, when a pre-consolidated pre-form comprising
carbon fibres is placed on crossing layers of glass fibres or glass fibre pre-pregs with
partial overlay, then the pre-consolidated pre-form should remain substantially flat
during laying and curing, whereas the glass fibres should adjust to the shape/form of
the pre-consolidated pre-form. Hence, the carbon fibres will remain straight leading to
increased strength of the combined structure.
The pre-consolidation process often leads to an increase in viscosity of the resin in the
pre-form, for example by a partial curing. It is preferred that the viscosity at room
temperature is increased by a factor of at least two and more preferably by a factor of
at least five, as an increase in viscosity will enhance handleability, strength and
unstickyness. In some cases, the viscosity may be increased by a much higher factor
like for example 10, 100 or 1000. This is for example the case if part of the resin is
injected into the pre-form as a room temperature liquid. Another way to express the
increase in viscosity is to look at viscosity directly. It is preferred that the viscosity of
the resin in the unconsolidated pre-form is between about 100 to 10,000 cP at the
temperature where the pre-consolidation process is conducted, preferably between
about 500 to 3,000 cP.

The temperature where the pre-consolidation process is conducted may vary
considerably depending particularly on the composition of the resin. Typically, the pre-
consolidation temperatures for epoxy-based resin systems are 50 to 900C and
preferably 60 to 80°C, however, both higher and lower temperatures may be feasible
in some systems.
The pre-consolidation process may lead to an increase in the glass transition
temperature, Tg, of the resin, for example by a partial curing. It is preferred that the Tg
of the resin is increased during pre-consolidation by at least 2°C and preferably by at
least 5°C, as an increase in Tg usually indicates an increase in the average molecular
weight of the resin, which will enhance handleability, strength and unstickyness. In
some cases, Tg may be increased more. This is particularly the case when Tg of the
unconsolidated pre-form is very low.
Generally speaking, a pre-consolidated pre-form according to the invention with an
epoxy-based resin system should typically have a Tg between -10 to +30°C and
preferably a Tg between -5 to 10°C. In a preferred embodiment, Tg of the resin of the
pre-consolidated pre-form is higher than about 0°C and preferably higher than about
3°C. For the unconsolidated pre-form Tg of the resin should be below about 5°C and
preferably below about 2°C.
In some cases, curing of a pre-consolidated pre-form without being exposed to a
vacuum will result in a material with properties equivalent to a vacuum-cured pre-form,
since porosity has been eliminated or greatly reduced during the pre-consolidation
process prior to the curing.
The resin may comprise more than one system, for example the resin may comprise
two systems. These systems may be any combination of different or the same type of
systems, however, it is preferred that the resin comprises two substantially epoxy-
based systems. The systems of a resin should be compatible. In a preferred
embodiment, two epoxy-based systems comprise a common component. The
common component may for example be a common catalyst, a common amine
component or a common epoxy component, however, it is preferred that the common
component is an epoxy component. A resin comprising two epoxy-based systems with
a common epoxy component may comprise an amine component of a first epoxy-
based system that will react to the common epoxy component at a first relatively low

temperature like for example below 50°C, preferably about room temperature. At this
first temperature, a second epoxy-based system is preferably non-reactive or the
reaction takes place at a very low rate. Since the reaction rate of the second epoxy-
based system should be very low, it may advantageously be catalysed by a catalyst,
which is un-active until activated. This activation may for example be by UV-light,
addition of a compound or by heating, however, it is preferred that the catalyst is
activated by heating.
In a preferred method of pre-consolidating a pre-form, a pre-form is placed on a
reactor surface like for example a plate, a mould, etc. It is preferred that the reactor
surface is flat and that it will withstand heating and/or vacuum. Then a pressure is
applied to the pre-form. The pressure may be applied by a press or - preferably - a
vacuum within a vacuum enclosure. If a vacuum is used, then a vacuum enclosure
should be obtained prior to pressing. The vacuum enclosure may for example
comprise a vacuum bag or it may comprise a reactor surface and a flexible cover
connected in a vacuum-tight way to the reactor surface. Gas may for example be
evacuated through the reactor surface or through an opening in the vacuum bag or
flexible cover. The pre-consolidation is activated. The activation may take place before
and/or during and/or after applying of pressure. The activation comprises a reduction
of the viscosity of the resin. This may for example be realised by physical means (e.g..
heating, addition of solvent, pressure etc.) and/or by a chemical reaction. During the
pre-consolidation process, a limited curing may or may not take place. When the
porosity has been reduced to a desired level or another object of the pre-consolidation
is obtained, the pre-consolidation process is terminated. The termination may for
example be a result of exhaustion of a first resin system or cooling of the pre-
consolidated pre-form to a temperature, where the curing reaction is sufficiently slow
and/or the viscosity is sufficiently low for the pre-consolidated pre-form to achieve the
stability needed for the desired shelf life.
In a preferred embodiment, the pre-form to be pre-consolidated is having at least one
non-continuous layer of resin, through which gas may be removed during the pre-
consolidation process. Hence, the gas need not be removed from the pre-form in a
plane of a layer of resin or in a plane of a layer of fibres. The transportation distance
and risk of having trapped gas inside the pre-consolidated pre-form is greatly reduced.
In a more preferred embodiment, ail layers of resin - optionally except from a layer on
top of the top layer of fibres or below the bottom layer of fibres - are non-continuous.

The extent of redistribution depends i.a. on the viscosity of the resin during the
compaction process, i.e. the lower the viscosity, the easier the redistribution of the
elements. By utilising a pre-consolidation process the viscosity of the resin may be
lowered more than what is feasible in the prior art, since the structure is not limited to
support a particular shape during the process. When the pre-consolidation involves a
limited curing of the resin, the viscosity may be further reduced since the curing
increases the handleability and reduces the sticking of the pre-consolidated pre-form.
Hence, pre-consolidation allows for redistribution of resin and/or fibres to a much
greater extent than what may be realised in the prior art. The resulting pre-
consolidated pre-forms may possess very low porosity as well as a more
homogeneous structure. This may for example result in a composite structure having a
less pronounced laminar structure, i.e. where the layers are less pronounced than a
corresponding composite structure comprising only pre-forms that were not pre-
consolidated prior to curing.

An example of a method for securing that gas may continuously be removed from the
pre-form during pre-consolidation involves a gradual activation of the pre-consolidation
process starting either from the centre of the pre-form and moving towards the
surfaces or from a side or edge and moving through the pre-form. For example this
may be realised by heating from the reaction surface only, hence activating gradually
from the side of the pre-form in contact with the reaction surface or by controlled
microwave heating, hence activating gradually from the inside of the pre-form and
moving towards the surfaces.
Pre-forms according to the invention and provided by a method according to the
invention are very useful for preparation of composite members by curing. Particularly,
the pre-forms are highly useful for preparation of members for wind turbine blades and
particularly in spars in a wind turbine blade, since these composites fulfil the quality
requirements and reproducibility requirements.
When larger structures comprising pre-forms according to the invention or pre-forms
produced by a method according to the invention are to be prepared, this may follow a
method wherein the pre-form is shaped at least partially plastically. The pre-form may
be connected to one or more further pre-consolidated pre-forms and/or unconsolidated
pre-forms before or after shaping to provide a larger structure. The pre-form may also
be connected to other structures. It is preferred but not required that the connections
involve a tapered part or layers comprising a second type of fibres. The combined
structure may be placed in a vacuum enclosure and provided with vacuum prior to
curing. Finally, the pre-form structure is cured.
The properties of a laminar structure having layers of oriented fibres depend to a large
extent on the distribution of the main elements of the structure resin, fibres and
porosity. The resin possesses a low strength compared to the fibres and may hence
provide a route for crack propagation through the structure, if too large layers of resin
are present. Porosity may reduce the strength of the structure dramatically but the
adversity depends on the size of pores, the shape and the distribution, i.e. the effect of
small, isolated spherical pores is limited, whereas larger pores positioned in the
interface between resin and fibres may be fatal to the structure. It is hence vital to be
able to control the distribution of the elements.

TABLE FOR IDENTIFICATION
2 Fibres indicating a main fibre orientation
4 Resin
4a Line of resin
4 b Dots or particles of resin
4c Random line of resin
4d Sheet of resin
6 Adhesive
6a Adhesive near fibre initiation
6b Adhesive near fibre termination
6c Adhesive on central part of pre-form
6d Adhesive on central part of pre-form in zigzag pattern
10 Ground plan of pre-form
12 Through-going hole
14 Direction of fibre laying
Y Angle between edges of a ground plan of pre-form
a Angle between edges of a ground plan of pre-form
|3 Angle between edges of a ground plan of pre-form
20 Tapered part of pre-form in the main direction of the fibres
22 Tapered part of pre-form orthogonal to main direction of the fibres
24 Un-tapered part of pre-form
30a Amine of a first epoxy based system
30b Amine of a second epoxy based system
32 Catalyst for a second epoxy based system
34 Epoxy component
36 Pre-mix comprising amine component and catalyst
38 Mix and apply unit
40 Mixed and distributed resin
50 Ground plan of oriented fibres
52 Part having a low number of layers of fibres
54 Part having an intermediate number of layers of fibres
56 Part having a high number of layers of fibres
60 Fibre layer comprising carbon fibres
62 Fibre layer comprising second type fibres
64 Overlay distance of the interlace

66 Distance between the ends of layers comprising second type fibres

WE CLAIM :
1. A pre-form comprising a resin and at least three layers of fibre, wherein the resin is
mainly an uncured thermosetting resin, and a part of said pre-form is formed three-
dimensionally so that said part of said pre-form is tapered, characterised in that said at least
three layers of fibres are oriented fibre tows.
2. A pre-form as claimed in claim 1, wherein the fibres are carbon fibres, glass fibres,
aramide fibres, synthetic fibres (e.g. acrylic, polyester, PAN, PET, PE, PP or PBO-fibres),
bio fibres (e.g. hemp, jute, cellulose fibres etc.), mineral fibres (e.g. Rockwool™), metal
fibres (e.g. steel, aluminium, brass, copper etc.) or boron fibres.
3. A pre-form as claimed in claim 1 or 2, wherein the fibres are continuous fibres.
4. A pre-form as claimed in any of the claims 1 to 3, wherein the resin is mainly an
epoxy-based resin or a polyester-based resin.
5. A pre-form as claimed in claim 4, wherein the resin comprises two resin systems,
preferably two epoxy-based systems.
6. A pre-form as claimed in any of the claims 1 to 5, wherein the ground plan of the pre-
form is substantially rectangular.
7. A pre-form as claimed in any of the claims 1 to 5, wherein the ground plan of the pre-
form is substantially trapezoid, preferably with the angles (, ) being substantially the same.
8. A pre-form as claimed in claim 6 or 7, wherein the distance between the parallel
sides is at least 3 times the length of any of the parallel sides, preferably more than 5 times
the length of any of the parallel sides.
9. A pre-form as claimed in any of the claims 1 to 8, wherein the ground plan of the pre-
form is substantially quadrangular or triangular.

10. A pre-form as claimed in any of the claims 1 to 9, wherein the fibres are oriented
primarily unidirectionally.
11. A pre-form as claimed in any of the claims I to 9, wherein the fibres are oriented
substantial/y orthogonally to an edge of the pre-form.
12. A pre-form as claimed in any of the claims 1 to 9, wherein the fibres are oriented
substantially parallel to an edge of the pre-form.
13. A pre-form as claimed in any of the claims 1 to 12, wherein the fibres are oriented to
strengthen areas of the final element which will be exposed to higher stress during service.
14. A pre-form as claimed in any of the claims 1 to 13, wherein orientation of fibres is
substantially the same in all layers.
15. A pre-form as claimed in any of the claims 1 to 13, wherein orientation of fibres in a
first layer is different from the orientation of fibres in a second layer.
16. A pre-form as claimed in any of the claims 1 to 15, wherein said pre-form comprises
carbon fibres and said pre-form is enhanced for coupling of said pre-form to a composite
member comprising second type fibres and a resin, said second type fibres are preferably
selected from the group of glass fibres, aramid-fibres, synthetic fibres (e.g. acrylic, polyester,
PAN, PET, PE, PP or PBO-fibres), bio fibres (e.g. hemp, jute, cellulose fibres, etc.), mineral
fibres (e.g. Rockwool™), metal fibres (e.g. steel, aluminium, brass, copper, etc.) or boron
fibres, and a part of the said pre-form towards said composite member is provided with
second type fibres and said second type fibres extend beyond said pre-form.
17. A pre-form as claimed in any of the claims 1 to 15, wherein said pre-form comprises
carbon fibres, said pre-form being enhanced for coupling of said pre-form to a composite
member comprising second type fibres and a resin, said second type fibres are preferably
selected from the group of glass fibres, aramid-fibres, synthetic fibres (e.g. acrylic, polyester,
PAN, PET, PE, PP or PBO-fibres), bio fibres (e.g. hemp, jute, cellulose fibres, etc.), mineral
fibres (e.g. Rockwool™), metal fibres (e.g. steel, aluminium, brass, copper, etc.) or boron

fibres, and a part of said pre-form towards said composite member is provided with layers
rich in or exclusively containing second type fibres interlaced between layers rich in or
exclusively containing carbon fibres and said second type fibres extend beyond said pre-
form.
18. A pre-form as claimed in claim 17, wherein an overlay distance of the interlace is
greater than the extent of the end condition of the interfacial stress between layers rich in or
exclusively containing carbon fibres and layers rich in or exclusively containing second type
fibres, preferably the overlay distance of the interlace is greater than 2 times the extent of
the end condition of the interfacial stress between layers rich in or exclusively containing
carbon fibre and layers rich in or exclusively containing second type fibres.
19. A pre-form as claimed in claim 17 or 18, wherein the distance between the ends of
the layers rich in second type fibres interlaced between layers rich in carbon fibres is
separated by a distance greater than the extent of the end condition of the interfacial stress
between layers rich in carbon fibres and layers rich in second type fibres, preferably the
distance between the ends of the layers rich in second type fibres is greater than 2 times the
extent of the end condition of the interfacial stress between layers rich in carbon fibre and
layers rich in second type fibre.
20. A method for preparing a pre-form comprising the steps of:
providing layers of fibres,
providing an adhesive between said layers of fibres to at least partially immobilising
the fibres,
providing a resin in contact with at least one of the layers of fibre,
wherein a fibre layer is provided off the edge of a preceding fibre layer,
thereby realising a tapered part of the pre-form and the resin is an uncured thermosetting
resin, characterised in that the layers of the fibres are oriented fibre tows.
21. A method as claimed in claim 20, wherein the resin is provided between two layers
of fibre tows.

22. A method as claimed in claim 20, wherein said adhesive comprises at least one of
the components of the resin, preferably the adhesive is having substantially the same
composition as the resin.
23. A method as claimed in any of the claims 20 to 22, wherein the resin is provided to
form non-continuous layer or layers.
24. A method as claimed in claim 23, wherein the resin is provided as continuous layers
wherein through-going holes have been introduced, preferably by punching.
25. A method as claimed in claim 23, wherein the resin is provided as liquid, preferably
to form an oriented or random pattern of a line, several lines or dots.
26. A method as claimed in any of the claims 20 to 25, wherein the adhesive is provided
in non-continuous layers, preferably the adhesive is provided in lines having an angle
relative to an orientation of the fibres, more preferably said angle is about 90° relative to an
orientation of the fibres.
27. A method as claimed in any of the claims 20 to 25, wherein the resin is substantially
epoxy-based.
28. A method as claimed in claim 27, wherein the resin comprises two epoxy-based
systems, preferably said epoxy-based systems comprise a common component, and more
preferably said common component is an epoxy component.
29. A method as claimed in claim 27 or 28, wherein said epoxy-based systems comprise
different amine components, preferably an amine component of a first epoxy-based system
will react with an epoxy component at a first temperature, whereas an amine component of a
second epoxy-based system will be mainly un-reactive at said first temperature, preferably
said first temperature is below 50°C, more preferably said first temperature is about room
temperature.

30. A method as claimed in claim 29, wherein said amine component of said second
epoxy-based system will cure upon activation of a corresponding catalyst, preferably said
corresponding catalyst is activated by heating.
31. A method as claimed in any of the claims 28 to 30, which involves the step of
preparing a pre-mix comprising said amine components and catalyst to form a stable fluid or
slurry, optionally the viscosity is adjusted by addition of 0.1 to 5% by weight of an epoxy
component.
32. A method as claimed in claim 31, which involves the step of preparing a resin
mixture comprising said pre-mix and said epoxy component immediately before applying
said resin mixture for preparing a pre-form.
33. A method as claimed in any of the claims 20 to 32, wherein the fibres and optionally
the resin are provided to form a substantially rectangular ground plan of the pre-form.
34. A method as claimed in any of the claims 20 to 32, wherein the fibres and optionally
the resin is distributed to form a substantially trapezoid ground plan of the pre-form,
preferably with the angles (a, 0) being substantially the same.
35. A method as claimed in any of the claims 20 to 32, wherein the fibres and optionally
the resin are distributed to form a substantially quadrangle or triangular ground plan of the
pre-form.
36. A method as claimed in any of the claims 20 to 35, wherein the fibres are provided to
form a desired orientation and/or form of ground plan by selectively cutting and/or initiating
of fibres, preferably during fibre layout.
37. A method as claimed in any of the claims 20 to 36, wherein said fibre layer is
provided within the area defined by said preceding fibre layer, more preferably the fibres are
provided by selectively cutting and/or initiating of fibres.

38. A method as claimed in any of the claims 20 to 36, wherein a fibre layer is provided,
said fibre layer having substantially the same size as a preceding fibre layer off the edge of
a preceding fibre layer, thereby simultaneously realising at least two tapered parts of the
pre-form.
39. A method as claimed in claim 20, wherein the layers of oriented fibres comprise
carbon fibres, said method involving the step of providing layers comprising second type
fibres, preferably said layers comprising second type fibres are extending from inside the
pre-form beyond at least one of the sides of the pre-form.
40. A method as claimed in claim 39, wherein the layers comprising second type fibres
are prepregs, preferably biaxial prepregs.
41. A method as claimed in claim 39 or 40, wherein an overlay distance from the end of
the layers comprising second type fibres inside the pre-form to the ends of the adjacent
layers of oriented fibres comprising carbon fibres is greater than the extent of the end
condition of the interfacial stress between said layers of oriented carbon fibres and said
layers comprising second type fibre, preferably greater than 2 times the extent of the end
condition of the interfacial stress between said layers of oriented carbon fibres and said
layers comprising second type fibre.
42. A method as claimed in any of the claims 39 to 41, wherein the distance between
the end of the layers comprising second type fibres inside the pre-form is separated by a
distance greater than 2 times the extent of the end condition of the interfacial stress between
said layers of oriented carbon fibres and said layers comprising second type fibre.
43. A pre-form whenever prepared by the method as claimed in any of the claims 20
to 42.
44. A pre-consolidated pre-form incorporating a pre-form as claimed in any of the claims
1 to 19 or 43.

45. A composite member incorporating a pre-form as claimed in any of the claims 1 to
19 or 43.
46. A wind turbine blade incorporating pre-form as claimed in any of the claims 1 to 19
or 43.
47. A spar of a wind turbine incorporating a pre-form as claimed in any of the claims 1 to
19 or 43.
48. A method of preparing a composite member comprising the steps of:
-shaping a pre-form as claimed in any one of the claims 1 to 19 plastically to a
desired shape ;
- optionally placing one or more additional pre-forms in connection with said pre-
form ;
- optionally placing the pre-form structure in a vacuum enclosure ; and
- curing the pre-form structure.

A pre-form comprises a resin and at least three layers of fibre (2), wherein the resin
(4) is mainly an uncured thermosetting resin, and a part of said pre-form is formed three-
dimensionally so that said part of said pre-form is tapered, characterised in that said at least
three layers of fibres are oriented fibre tows (2).
A method for preparing a pre-form comprising the steps of:
providing layers of fibres (2),
providing an adhesive (6) between said layers of fibres (2) to at least partially
immobilising the fibres (2),
providing a resin (4) in contact with at least one of the layers of fibre (2),
wherein a fibre layer is provided off the edge of a preceding fibre layer, thereby realising a
tapered part of the pre-form and the resin (4) is an uncured thermosetting resin,
characterised in that the layers of the fibres are oriented fibre tows (2).

Documents:

1800-KOLNP-2005-(28-09-2012)-CORRESPONDENCE.pdf

1800-KOLNP-2005-(28-09-2012)-PA.pdf

1800-KOLNP-2005-(28-09-2012)-PETITION UNDER RULE 137.pdf

1800-KOLNP-2005-(29-03-2012)-CORRESPONDENCE.pdf

1800-KOLNP-2005-(29-03-2012)-FORM-13.pdf

1800-KOLNP-2005-CORRESPONDENCE.pdf

1800-KOLNP-2005-FORM 27.pdf

1800-kolnp-2005-granted-abstract.pdf

1800-kolnp-2005-granted-assignment.pdf

1800-kolnp-2005-granted-claims.pdf

1800-kolnp-2005-granted-correspondence.pdf

1800-kolnp-2005-granted-description (complete).pdf

1800-kolnp-2005-granted-drawings.pdf

1800-kolnp-2005-granted-examination report.pdf

1800-kolnp-2005-granted-form 1.pdf

1800-kolnp-2005-granted-form 13.pdf

1800-kolnp-2005-granted-form 18.pdf

1800-kolnp-2005-granted-form 3.pdf

1800-kolnp-2005-granted-form 5.pdf

1800-kolnp-2005-granted-pa.pdf

1800-kolnp-2005-granted-reply to examination report.pdf

1800-kolnp-2005-granted-specification.pdf


Patent Number 227779
Indian Patent Application Number 1800/KOLNP/2005
PG Journal Number 04/2009
Publication Date 23-Jan-2009
Grant Date 20-Jan-2009
Date of Filing 12-Sep-2005
Name of Patentee VESTAS WIND SYSTEMS A/S
Applicant Address SMED SORENSENS VEJ 5, DK-6950 RINGKOBING
Inventors:
# Inventor's Name Inventor's Address
1 BECH, ANTON RYDBJERGVEJ 2, VELLING DK-6950 RINGKOBING
PCT International Classification Number B29B 11/16
PCT International Application Number PCT/EP2003/00293
PCT International Filing date 2003-03-06
PCT Conventions:
# PCT Application Number Date of Convention Priority Country
1 PCT/EP2003/00293 2003-03-06 IB