Title of Invention	NON SYMMETRICAL ETHYLENE DIAMINO HYDROXYPHENYL ACETIC ACID DERIVATIVES FOR THE TREATMENT OF IRON CHLOROSIS
Abstract	The present invention consists on the synthesis of new products for the treatment of the iron chlorosis. These products may have improved properties regarding the currently known treatments. The new products are non-symmetrical ethylene diamino hidroxyphenyl acetic acid derivatives possessing only five coordination sites able to chelate metals.

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New products for the treatment of the iron chlorosis Field of the invention This invention relates to new non-symmetrical ethylene diamino hidroxyphenyl acetic acid derivatives. These products are useful for the treatment of iron chlorosis. BACKGROUND ART Iron chlorosis is a nutritional plant disorder which results in a decrease in the amount of chlorophyll and in the yellowing or whitening of normally green plant tissue. It is a widespread problem in agriculture that affects the development of many crops provoking a decrease yield. Attempts have long been made to correct this iron deficiency by feeding the plants with iron in assimilable form, originally in the form of ferric salts. Ferric salts act to a certain extent by foliar penetration, but are substantially ineffectual when used for soil treatment. It is through the roots that the penetration of iron is at its most effective in controlling chlorosis. In this connection, simple iron salts have been replaced by iron chelates which are hydrosoluble complexes consisting of an iron atom attached to several points of a single organic molecule known as chelates or co-ordinates. Some of these products known as hexadentates, such as complexes of iron with ethylene diamine tetracetic acid (EDTA) or with diethylene triamine pentacetic acid (DTPA) or with N,N'-ethylene-bis-(hydroxyphenyl)glycines (EDDHA), have been successfully used against chlorosis. N,N'-ethylene-bis(2-hydroxyphenyl)glycine (o,o-EDDHA) is often described as one of the most favorable compounds for complexing metals, and being most suitable for the use as a plant nutrient or fertilizer because the complexation affinity to iron is particularly strong. The ferric chelate of o,o-EDDHA shows a coordination number of 6 and is widely used for agrochemical purposes as a plant nutrient or plant fertilizer, and for the treatment of chlorosis in crop plants. The N,N'-ethylene-(2-hydroxyphenyl)-glycinyl-(4-hydroxyphenyl)glycine (o,p- EDDHA) is also known in the art. Contrary to o,o-EDDHA, in the o,p-EDDHA isomer one of the hydroxy groups is in the para- position of the benzene ring. For this reason, the ferric chelate of o,p-EDDHA shows a coordination number of 5 and its complexation affinity to iron is weaker than that of 0,0- EDDHA. This compound has often being regarded as an undesired by- product being incurred by the manufacturing process of 0,0-EDDHA. Gomez-Gallego et al, (c.f. Chem.Eur.J. 2005, 77,5997-6005) propose a model for explaining the reduction of the Fe(lll)-o,o-EDDHA chelate by a ferric chelate reductase. According to it, the reduction of said chelate does not take place on the complex in the octahedral closed form, wherein the 6 chelating points of 0,0-EDDHA are coordinated to the Fe(lll), but on a hexacoordinate open species formed at the acid pH of the rhizosphere. As showed in Scheme 5 of said report, one of the hydroxy groups in the ortho- position would not be coordinated with the Fe(lll), thus generating a vacant coordination site that would be filed with a water molecule. The complex Fe(lll)-o,p-EDDHA, wherein one of the hydroxy groups is in the para- position, would already be in the required open form and could be reduced directly by the enzyme. WO2005/095305 discloses isomeric mixtures comprising both (0,0-EDDHA) and (o,p-EDDHA) , wherein the molar ratio of (o,p-EDDHA) to (0,0-EDDHA) is higher than 0.8 : 1, as nutrients for agricultural crop plants and agents for treatment of chlorosis in such plants. SUMMARY OF THE INVENTION The properties of the commercially available chelating agents currently used for the treatment of iron deficiency related plant diseases (e.g. iron chlorosis), such as those based in EDDHA and known derivatives thereof, are still not completely satisfactory. For instance, it has been observed that current chlorosis treatments based on 0,0-EDDHA show a delayed effect in plants. WO2005/095305 proposes to solve this problem by employing isomeric mixtures of 0,0-EDDHA and o,p-EDDHA, as said above. However, o,p- EDDHA/Fe3+ shows lower stability than o,o-EDDHA/Fe3+. (Yunta et al. Journal of Agricultural and Food Chemistry, 2003, 51, 5391-5399) so it is quite reactive in soils. Properties that are desirable in a compound useful for the treatment of iron chlorosis are described in Lucena, J.J. Iron Fertilizers in Correcting Iron Deficiencies in Plants. Chapter 5, In Iron Nutrition in Plants and Rhizospheric Microorganism 2006, pp 103-127, Springer-Verlag Academic Publishers. The problem to be solved by the present invention is to provide alternative products that may be useful for the treatment of iron deficiency related plant diseases. These products may have improved properties regarding the currently known treatments. The solution is based on the fact that the present inventors have identified that by eliminating one of the carboxylic groups of EDDHA and maintaining or modulating the hydroxyphenyl groups, the chelating affinity for polyvalent metals, particularly for iron, is retained, while some other properties may be improved, particularly those that make them useful for the treatment of iron chlorosis. See working examples 1 -7 herein for a further description. Accordingly, a first aspect of the invention relates to a compound of formula (I): wherein X1 is a C6 or a C10 aromatic system having a hydroxy group in the alpha position, being optionally substituted by up to four substituents independently selected from the group consisting of: phospho, sulfo, halo, carboxy, acetoxy, C1-C4 alkoxy or linear or branched C1-C4 alkyl. X2 is a C6 or a C10 aromat ic system having a hydroxy group in the alpha position, or a five or six membered heterocycle having in the alpha position a heteroatom selected from the group consisting of N, O and S, optionally comprising other N, O or S atoms in their structure, and having from 0-3 double bonds, said aromatic, or heterocyclic system being optionally substituted by up to four substituents independently selected from the group consisting of: phospho, sulfo, halo, carboxy, acetoxy, C1-C4 alkoxy, linear or branched C1-C4 alkyl. Y is (CH2)n or is a xylylene group of formula: n is an integer selected from 2, 3 and 4, R1, R2 are independently selected from the group consisting of H, linear or branched C1-C4 alkyl, C6 or C10 aryl. In a second aspect the invention relates to a process for preparing a compound of formula (I) as defined in the first aspect of the invention and in its corresponding embodiments, which process comprises the step of reducing a compound of formula (II): wherein X1, X2 and Y are as defined above, in an appropriate solvent system, in the presence of a reducing agent. In a third aspect the invention relates to the use of a compound of formula (I), as defined in the first aspect of the invention and its corresponding embodiments, as a complex forming agent for polyvalent metals. In a fourth aspect the invention relates to a chelate of a compound of the formula (I), as defined in the first aspect of the invention and its corresponding embodiments, with one or more polyvalent metals. In a fifth aspect the invention relates to an agrochemical composition comprising a compound of formula (I), as defined in the first aspect of the invention and its corresponding embodiments, or a polivalent metal chelate thereof. In a sixth aspect the invention relates to the use of a compound, as defined in the first aspect of the invention and its corresponding embodiments, or a polyvalent metal chelate thereof, for the preparation of a composition for treating an iron deficiency related plant disease. In a seventh aspect the invention relates to an intermediate of formula (II): wherein X1, X2 and Y are as defined above, in solid form. In a eighth aspect the invention relates to the use of the intermediate of formula (II) as defined in the seventh aspect of the invention and its corresponding embodiments, for the preparation of a compound of formula (I), as defined in the first aspect of the invention and its corresponding embodiments. Without whishing to be bound by theory, as reported in Chem. Eur. J. 2005, 11, 5997, the effectiveness of Fe(lll)-o,o-EDDHA to relief iron chlorosis requires the generation of a vacant coordination site. This fact explains the high efficiency of o,p-EDDHA a compound in which one of the phenolic groups is unable to coordinate the metal. Advantageously the new compounds described in the invention have only five groups able to coordinate with the metal. This point should be essential for their activity. Furthermore, most of the derivatives of EDDHA known in the art and employed for the treatment of iron deficiency related plant diseases are symmetrical compounds, except for the o,p-EDDHA, which is an isomer of EDDHA. On the contrary, all the compounds of formula (I) are non- symmetrical compounds, since they lack one of the two carboxylic groups of EDDHA. Therefore, the known methods for the preparation of EDDHA derivatives were not directly applicable to the compounds of the invention. This has forced the inventors to develop a new method of synthesis for preparing the said compounds of formula (I). Throughout the description and claims the word "comprise" and variations of the word, such as "comprising", is not intended to exclude other technical features, additives, components, or steps. The content of the application from which priority is claimed, as well as the contents of the abstracts of the priority application and the present application, are incorporated herein as reference. Additional objects, advantages and features of the invention will become apparent to those skilled in the art upon examination of the description or may be learned by practice of the invention. The following examples are provided by way of illustration, and it is not intended to be limiting of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 shows the SPAD index of the fourth level, represented versus the days of treatment, for plants grown on soil treated with each of the tested compounds and the control. Figure 2 shows the dry weight of shoots (expressed in grams) in the soil experiment, with the tested compounds and the control, at three sampling times. Figure 3 shows the iron concentration in leaves of the plants treated with the tested compounds and the control, at three sampling times. Definitions By linear or branched C1-C4 alkyl, is taken to mean herein a linear or branched alkyl group which contains up to 4 atoms of carbon. Thus it includes, for example, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec- butyl and tert-butyl. By C1-C4 alkoxy it is meant herein the alkyl groups mentioned above bound through oxygen, examples of which include methoxy, ethoxy, isopropoxy, tert- butoxy, and the like. The term halo, in this invention, refers to F, CI, Br, I, preferably CI. A C6 or a C10 aromatic system or a C6 or a C10 aryl group include phenyl and naphtyl. DETAILED DESCRIPTION OF PARTICULAR EMBODIMENTS As defined above, X2 in the compounds of formula (I) is a C6 or a C10 aromatic system having a hydroxy group in the alpha position, or a five or six membered heterocycle having in the alpha position a heteroatom selected from the group consisting of N, O and S, optionally comprising other N, O or S atoms in their structure, and having from 0-3 double bonds, said aromatic, or heterocyclic system being optionally substituted by up to four substituents independently selected from the group consisting of: phospho, sulfo, halo, carboxy, acetoxy, C1-C4 alkoxy, linear or branched C1-C4 alkyl. Heterocycle as meant herein includes both non-aromatic heterocycles (e.g. 2-azetidinyl, 2- pyrrolidyl, 2-piperidinyl), and heteroaromatic rings. Preferably said heterocycle is heteroaromatic. Preferred compounds of formula (I) are those wherein X2 is selected from the group consisting of 2-hydroxyphenyl, 2-hydroxy-naphthyl, 2-furyl, 2-thienyl, 2- pyrrolyl, 2-pyridyl, 4-pyridimidinyl, 2-pyrazinyl optionally substituted by 2 or 1 substituents independently selected from the group consisting of: phospho, sulfo, halogen, C1-C4 alkoxy, carboxy, acetoxy, linear or branched C1-C4 alkyl. Preferred optional substituents include methyl, phenyl, phospho, sulfo, carboxy, acetyl. More preferred compounds of formula (I) are those wherein X1 is 2- hydroxyphenyl or 2-hydroxynaphthyl, optionally substituted by 2 or 1 substituents independently selected from the group consisting of methyl or methoxy. Yet more preferred are those wherein X1 is 2-hydroxyphenyl. In the compounds of formula (I), preferably Y is (CH2)n, and more preferably n is 2. When Y is a xylylene group as defined above, preferably both R1 and R2 are H. In a preferred embodiment, compounds of formula (I) are those wherein Y is (CH2)n, and more preferably n is 2, X1 is 2-hydroxyphenyl, X2 is selected from the group consisting of 2-hydroxyphenyl, 2-hydroxynaphthyl, 2-furyl, 2-thienyl, 2-pyrrolyl, 2-pyridyl, 4-pyridmidinyl, 2-pyrazinyl, optionally substituted by 2 or 1 substituents independently selected from the group consisting of: C1-C4 alkyl, C1-C4 alkoxy, carboxy, sulfo, acetoxy . The most particularly preferred compounds are selected from the group consisting of: 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2-hydroxyphenyl)aceticacid, 2-(2-((2-hydroxy-1 -naphtyl)methylamino)ethylamino)-2-(2 - hydroxyphenyl)acetic acid, 2-(2-((pyridin-2-yl)methylamino)ethylamino)-2-(2-hydroxyphenyl)aceticacid, 2-(2-((1H-pyrrol-2-yl)methylamino)ethylamino)-2-(2-hydroxyphenyl)acetic acid. Preferred methods include, but are not limited to, those described below. The reactions are carried out in the solvents appropriate for the reagents and materials used and suited for the transformations carried out. An expert in organic synthesis will understand that the functional groups present in the molecule must be consistent with the proposed transformations. This may in some cases require modifying the order of the synthesis steps or selecting one particular method rather than another, in order to obtain the desired compound of the invention. Moreover, in some of the procedures described below it may be desirable or necessary to protect the reagent functional groups present in the compounds or intermediates of this invention with conventional protecting groups. Various protecting groups and procedures for introducing them and removing them are described in Greene and Wuts (Protective Groups in Organic Synthesis, Wiley and Sons, 1999). All the references cited herein are incorporated integrally by reference. The compounds of formula (I) as defined above, can be prepared by a process which comprises the step of reducing a compound of formula (II): wherein X1, X2 and Y are as defined above, in an appropriate solvent system, in the presence of a reducing agent. The reaction may be carried out in different solvent systems. Suitable solvent systems include C1-C4 alcohols such as methanol and ethanol, acetic acid, water and mixtures thereof. Preferably the reaction is carried out in methanol. Suitable reducing agents are hydrides and hydrogen with a metal catalyst. Preferably, the reducing agent is selected from the group consisting of borohydrides, such as sodium cyanoborohydride, sodium triacetoxyborohydride, sodium borohydride. Better results are obtained when the reducing agent used is sodium borohydride or Pd hydrogenation. The reaction is preferably carried out at temperature ranging from 15°C to 40°C. Better results are obtained when carried out from 18°C to 25°C. In a preferred embodiment, the process for preparing a compound of formula (I) according to the second aspect of the invention, further previously comprises the step of preparing said compound of formula (II) by reacting a compound of formula (III) with a compound of formula (IV): wherein X1, X2 and Y are as defined above, in an appropriate solvent system. The reaction between a compound of formula (III) with a compound of formula (IV) may be carried out in different solvent systems. Suitable solvent systems include C1-C4 alcohols such as methanol and ethanol,-water; nitriles such as acetonitrile; ketones such as 2-butanone; and mixtures thereof. Preferably the reaction is carried out in methanol, ethanol, water or mixtures thereof. In a preferred embodiment, the reaction between a compound of formula (III) with a compound of formula (IV), and the subsequent reduction of the compound of formula (II) obtained to prepare a compound of formula (I) is carried out as a one pot reaction. The best conditions to carry out the process vary according to the parameters considered by the person skilled in the art, such as the starting materials, temperature and similar. Such reaction conditions may be easily determined by the person skilled in the art by routine tests, and with the teaching of the examples included in this document. Compounds of formula (III) are described in the literature and/or can be prepared by methods analogous to those known in the state of the art (e.g. in US 5,679,704, DE3329028 A1 and WO-2006045852 A1) from products commercially available. A compound of formula (I) as defined above may be used as a complex forming agent for polyvalent metals. Preferably, said polyvalent metal is at least one polyvalent metal selected from the group consisting of iron, nickel, zinc, manganese, yterbium, gadolinium, cobalt and copper. More preferably, said metal is iron. A compound of the formula (I) as defined above may form chelates with one or more polyvalent metals. Preferably, said polyvalent metal is at least one polyvalent metal selected from the group consisting of iron, nickel, zinc, manganese, yterbium, gadolinium, cobalt, copper, palladium, platinum and, gold. More preferably, said metal is iron. Such iron chelates may further contain e.g. an alkali-or alkaline earth metal, like sodium, potassium, calcium or magnesium, particularly sodium. Chelates according to the invention may be used as active component in agriculturally acceptable compositions, as sole active component or in combination with other agriculturally active components, such as plant nutrients or plant fertilizers. Thus, agrochemical compositions according to the invention comprise a compound of formula (I) as defined above, or a metal chelate thereof. Said compositions may further comprise agriculturally acceptable carriers. The composition is preferably applied in the form of a solution or suspension by injecting into the soil. The other agriculturally acceptable active ingredients may be additional fertilizers, micronutrient donors or other preparations that influence plant growth and development or plant protection products like selective herbicides or insecticides, fungicides, bactericides, nematicides, molluscicides, or mixtures of several of such preparations, if desired. Agriculturally acceptable active ingredients also include other chelating agents. Said chelating agents include ethylene diamine tetracetic acid (EDTA), diethylene triamine pentacetic acid (DTPA), o,o-EDDHA and o,p- EDDHA. In one embodiment, the agrochemical compositions of the invention also comprise o,o-EDDHA. Agriculturally acceptable carriers may be natural or regenerated mineral substances, solvents, dispersants, wetting agents, tackifiers, thickeners or binders. Such carriers and additives are described, for example, in WO 95/30651. The compounds of formula (I) according to the invention are useful for treating an iron deficiency related plant disease. Preferably, said disease is iron chlorosis. Preferred intermediates of formula (II) are those wherein X1 is 2- hydroxyphenyl. EXAMPLES Example 1: 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2- hydroxyphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, Y=(CH2)2, X2= 2- hydroxybenzyl) To a solution of the 2-(2-aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride in water at pH 7.3, was added an equimolar amount of salicylaldehyde in ethanol. After stirring for 1 h at room temperature, the title Schiff base was filtered and obtained as a solid in 80% yield. 1H-NMR (300 MHz, DMSO-d6, 2.5, ppm): δ = 8.54 (s, 1H, CH=N), 7.48 (d, 1H, J= 7.5 Hz, Ar), 7.34 (t, 1H, J= 7.62 Hz, Ar), 7.30 (d, 1H, J =7.32 Hz, Ar), 7.18 (m, 1H, Ar), 6.92-6.70 (m, 4H, Ar), 4.62 (s, 1H, CH), 3.83 (m, 4H, CH2), 3.15 (m, 1H, CH2), 3.02 (m, 1H,CH2). Step 2. 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2-hydroxyphenyl)acetic acid The hydrogenation of the of the Schiff base obtained in Step 1 in MeOH (10 % Pd/C) at room temperature yielded the title product as brown solid (80%). 1H-NMR (500 MHz, D2O, 4.8(HDO), ppm): δ = 7.20-7 (m, 4H, Ar), 6.79-6.66 (m, 4H, Ar), 4.36 (s, CH), 3.87 (s, 2H, CH2), 2.84-2.69 (m, 4H, CH2). Example 2: 2-(2-((2-hydroxy-1 -naphtyl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid. Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, Y=(CH2)2, X2=2- hydroxy-1-naphtyl) Following Example 1, but starting from equimolar amounts of 2-(2- aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride and 1- formyl-B-naphtol the the Schiff base of the title was obtained as yellow solid in 70% yield. 1H-NMR (300 MHz.DMSO, 2.5, ppm): δ = 9.11 (s, 1H, CH-N), 8.055 (d, 1H, J = 8.35 Hz, Ar), 7.72 (d, 1H, J = 9.44 Hz, Ar), 7.63 (d, 1H, J = 7.10 Hz, Ar), 7.42 (d, 2H, J = 7.07 Hz, Ar), 7.25 (d, 1H, J = 9.44 Hz, Ar), 7.17 (d, 2H, J = 7.11 Hz, Ar), 6.75-6.67 (m, 2H, Ar), 4.43 (s, 1H), 3.86-3.78 (m, 2H, CH2), 3.2- 3.02 ( m, 1H CH2), 2.92-2.8 (m, 1H, CH2). Step 2. 2-(2-((2-hydroxy-1-naphtyl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid A mixture of equimolar amounts of the Schiff base obtained in Step 1, NaBH3CN and a catalytic amount of Zn2CI in MeOH was stirred at room temperature for 3 h. The solvent was removed by evaporation and the title product was obtained as brown solid (85% yield). 1H-NMR (500 MHz, D2O, 4.8 (HDO), ppm): δ = 7.7-7.55 (m, 3H, Ar), 7.45-7.37 (m, 1H, Ar), 7.3-7.15 (m, 2H, Ar), 7.06 (d, 1H, J = 5.67 Hz, Ar), 6.95 (d, 1H, J = 9.17 Hz, Ar), 6.8-7.2 (m, 2H, Ar), 5.02 (s, 1H), 4.23(s, 2H), 3.22-3.073 (m, 4H). Example 3: 2-(2-((pyridin-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, Y=(CH2)2, X2- pyridin-2-yl) The procedure of Example 1 is followed, but starting from equimolar amounts of 2-(2-aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride and 2-pyridinecarboxaldehyde at pH 7. After 20 h at room temperature the solvent was removed and the title Schiff base was obtained as yellow solid in 90% yield. 1H-NMR (300 MHz,DMSO, 2.5, ppm): δ = 8.63 (bs, 1H, J = 4.77 Hz, CH=N), 8.5-8.1 (m, 1H, Ar), 8.0-7.84 (m, 2H, Ar), 7.46 (t, 1H, Ar J = 6.58 Hz,), 7.21- 7.1 (m, 1H, Ar), 7.05-6.95 (m, 1H, Ar), 6.88-6.73 (m, 2H, Ar), 4.59 (s, 1H, CH), 3.9 (m, 2H, CH2), 3.1-3.0 (m, 2H, CH2). Step 2. 2-(2-((pyridin-2-yl)methylamino)ethylamino)-2-(2-hydroxyphenyl)acetic acid A mixture of equimolar amounts of the Schiff base obtained in Step 1 and NaBH4 in MeOH was stirred at room temperature for 20 h. The solvent was removed by evaporation and the title product was obtained as white solid (95% yield). 1H-NMR (300 MHz, D2O, 4.8 (HDO) ppm): δ = 8.4-8.36 (m, 1H, Ar), 7.82 (td, 1 H, J, = 7.65 Hz, J2 = 1.38 Hz, Ar), 7.77-7.72 (m, 2H, Ar), 7.36-7.25 (m, 2H, Ar), 7.2-7.0 (m, 1H, Ar), 6.74-6.65 (m, 1H, Ar), 4.38 (s, CH), 3.76 (s, 2H, CH2), 2.78-2.6 (m, 4H, CH2). Example 4: 2-(2-((1H-pyrrol-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, Y=(CH2)2, X2=1H- pyrrol-2-yl) Following the procedure of Example 1, but starting from equimolar amounts of 2-(2-aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride and pyrrole-2-carboxaldehyde, the title Schiff base was obtained after stirring at room temperature for 20 h as orange solid in 90% yield. 1H-NMR (300 MHz.DMSO, 2.5, ppm): δ = 8.09 (s, 1H, CH=N), 7.35-7.20 (m, 1H, Ar), 7.0-6.95 (m, 1H, Ar), 6.87 (s, 1H, Ar), 6.75-6.65 (m, 1H, Ar), 6.5-6.4 (m, 1H, Ar), 6.3-6.2 (m, 1H, Ar), 6.115-6.05 (m, 1H, Ar), 4.11 (s, 1H , CH), 3.65-3.5 (m, 2H, CH2), 2.9-2.6 (m, 2H, CH2). Step 2. 2-(2-((1H-pyrrol-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid A mixture of equimolar amounts of the Schiff base obtained in Step 1 and NaBH4 in MeOH was stirred at room temperature for 20 h. The solvent was removed by evaporation and the title product was obtained as orange solid (94% yield). 1H-NMR (500 MHz, D2O, 4.8(HDO), ppm): δ = 7.2-7.1. (m, 2H, Ar), 6.80-6.69 (m, 3H, Ar), 6.15-6.25 (m, 2H, Ar), 4.44 (s, 1H), 3.70 (s, 2H, CH2), 2.85-2.6 (m,4H,CH2). Example 5: 2-(2-((imidazol-4(5)-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, V=(CH2J2, X2=imidazol-4(5)-yl) To a solution of the 2-(2-aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride in water at pH 7.2, was added an equimolar amount of 4(5)- formylimidazole in methanol. After stirring for 24 h at room temperature, the title Schiff base was filtered and obtained as a solid in quantitative yield. 1H-NMR (300 MHz, CD3OD, 3.31 ppm): δ = 8.21 (broad s, 1H, CH=N), 7.76 (s, 1H, CH=N), 7.49 (s, 1H, CH=N), 7.23 (dt, 1H, J, = 7.56 Hz, J2 = 1.35 Hz, Ar), 7.10 (td, 1H, J, = 1.38 Hz, J2 = 7.56 Hz, Ar), 6.77 (m, 2H, Ar), 5.74 (1H, NH), 4.44 (s, 1H, CH), 3.72-3.70 (m, 2H, CH2), 3.08-3.0 (m, 1H, CH2), 2.95-2.34 (m, 1H, CH2). Step 2. 2-(2-((imidazol-4(5)-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid The hydrogenation of the Schiff base obtained in Step 1 in MeOH (10 % Pd/C) at room temperature yielded the title product as a solid (35%). 1H-NMR (500 MHz, D2O, 4.8 (HDO) ppm): δ = 7.55 (s, 1H, C=N), 7.06-7.0.3 (m, 2H, Ar), 6.88 (s, 1H, C=N), 6.68-6.64 (m, 2H, Ar), 4.33 (s, 1H, CH), 3.59 (s, 2H, CH2), 2.76-2.56 (m, 4H, CH2). Example 6: 2-(2-((1 H-imidazol-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, Y=(CH2)2, X2=1H- imidazol-2-yl) To a solution of the 2-(2-aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride in water at pH 7.2, was added an equimolar amount of 2- formylimidazole in methanol. After stirring for 24 h at room temperature, the title Schiff base was filtered and obtained as a solid in quantitative yield. 1H-RMN (500 MHz, CD3OD, 3.31 ppm) δ = 8.24 (broad s, 1H, CH=N), 7.18 (s, 2H, CH=N), 7.10-6.97 (m, 2H, Ar), 6.79-6.73 (m, 2H, Ar), 5.72 (broad s, 1H, NH), 4.36 (s, 1H, CH), 3.79-3.75 (m, 2H, CH2), 3.03-2.94 (m, 1H, CH2), 2.89- 2.84 (m, 1H,CH2). Step 2. 2-(2-((1H-imidazol-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid The hydrogenation of the of the Schiff base obtained in Step 1 in MeOH (10 % Pd/C) at room temperature yielded the title product as a solid (34%). 1H-RMN (500 MHz, D2O, 4.8 (HDO) ppm) δ = 7.55 (s, 1H, C=N), 7.06-7.03 (m, 2H, Ar), 6.88 (s, 1H, C=N), 6.68-6.64 (m, 2H, Ar), 4.33 (s, 1H, CH), 3.59 (s, 2H, CH2), 2.76-2.56 (m, 4H, CH2). Example 7: 2-(2-((piperidin-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, Y=(CH2)2, X2- piperidin-2-yl) To a solution of the 2-(2-aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride in water at pH 7.2, was added an equimolar amount of 2-formyl- N-terbutoxycarbonyl-piperidine in methanol. After stirring for 24 h at room temperature, the title Schiff base was filtered and obtained as a solid in quantitative yield. 1H-NMR (300 MHz, DMSO-d6, 2.5, ppm): δ = 7.57 (s, 1H, C=N), 7.28-7.26 (m, 2H, Ar), 7.0- 6.96 (m, 2H, Ar), 4.5 (s, 1H, CH), 4.14-4.05 (m, 1H, CH), 3.3- 2.80 (m, 6H, CH2), 1.49-1.36 (m, 6H, CH2), 1.36 (s, 9H, CH3). Step 2. 2-(2-((piperidin-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid The hydrogenation of the of the Schiff base obtained in Step 1 in MeOH (10 % Pd/C) at room temperature, followed by removal of the terbutoxycarbonyl (BOC) group with 1 mL of 10% H2SO4 in 10 mL dioxane, 24 h at room temperature, yielded the title product as a solid (60%). 1H-RMN (500 MHz, D2O, 4.8 (HDO) ppm): δ = 7.21-7.16 (m, 2H, Ar), 6.72- 6.67 (m, 2H, Ar), 4.35 (s,1H, CH), 3.56-3.51 (m, 1H, CH), 3.1-2.52 (m, 8H, CH2), 1.49-1.45 (m, 2H, CH2), 1.13-1.03 (m, 4H, CH2). Example 8: 2-(2-((pyrrolidin-2-yl)methylamino)ethylamino)-2-(2- hydroxyphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxyphenyl, Y=(CH2)2, X2= pyrrolidin-2-yl) To a solution of the 2-(2-aminoethylamino)-2-(2-hydroxyphenyl)acetic acid hydrochloride in water at pH 7.2, was added an equimolar amount of 2-formyl- N-terbutoxycarbonyl-pyrrolidine in methanol. After stirring for 24 h at room temperature, the title Schiff base was filtered and obtained as a solid in quantitative yield. 1H-RMN (500 MHz, DMSO-d6, 2.5, ppm): δ = 7.57 (broad s, 1H, C=N), 7.27 (d, 1H, J = 7.35 Hz, Ar), 7.01 - 6.91 (m, 1H, Ar), 6.66- 6.59 (m, 2H, Ar), 4.6 (m, 1H, CH), 3.92 (s, 1H, CH), 2.71-2.6 (m, 1H, CH2), 2.59-2.45 (m, 1H, CH2), 1.99-1.75 (m, 4H, CH2), 1.38-1.37 (m, 2H, CH2), 1.37 (s, 9H, CH3). Step 2. 2-(2-((pyrrolidin-2-yl)methylamino) ethylamino) -2-{2- hydroxyphenyl)acetic acid The hydrogenation of the of the Schiff base obtained in Step 1 in MeOH (10 % Pd/C) at room temperature, followed by removal of the BOC group with 1 mL of 10% H2SO4 in 10 mL dioxane, 24 h at room temperature, yielded the title product as a solid (50%). 1H-RMN (500 MHz, D2O, 4.8 (HDO) ppm): δ = 7.31-7.26 (m, 2H, Ar), 6.91- 6.87 (m, 2H, Ar), 5.1 (s, 1H, CH), 3.9-3.83 (m, 1H, CH), 3.44-3.20 (m, 8 H, CH2), 1.96-1.65 (m, 4 H, CH2). Example 9: 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2-hydroxy-4- methylphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxy-4-methylphenyl, Y=(CH2)2, X2= 2-hydroxybenzyl) To a solution of the 2-(2-aminoethylamino)-2-(2-hydroxy-4- methylphenyl)acetic acid hydrochloride in water at pH 7.2, was added an equimolar amount of salicylaldehyde in ethanol. After stirring for 1 h at room temperature, the title Schiff base was filtered and obtained as yellow solid in 65% yield. 1H-NMR (300 MHz, DMSO-d6, 2.5, ppm): δ = 8.54 (s, 1H, CH=N), 7.45 (d, 1H, J = 7.78 Hz, Ar), 7.33 (td, 1H, J, = 1.63 Hz, J2 = 8.2 Hz, Ar), 7.08 (d, 1H, J =7.7 Hz, Ar), 6.9 (t, 2H J = 7.27 Hz Ar), 6.61-6.58 (m, 2H, Ar), 4.56 (s, 1H, CH), 3.85-3.81 (m, 2H, CH2), 3.17-3.09 (m, 1H, CH2), 3.09-2.95 (m, 1H, CH2), 2.18 (s, 3H,CH3). Step 2. 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2-hydroxy-4- methylphenyl)acetic acid The hydrogenation of the of the Schiff base obtained in Step 1 in MeOH (10 % Pd/C) at room temperature yielded the title product as brown solid (75%). 1H-NMR (500 MHz, D2O, 4.8 (HDO), ppm): δ = 7.22-7.1 (m, 3H, Ar), 6.72-6.64 (m, 4H, Ar), 4.37 (s, 1H, CH), 3.92 (s, 2H, CH2), 2.59-2.81 (m, 4H, CH2), 2.23 (s, 3H, CH3). Example 10: 2-(2-((2-hydroxybenzyl)amlno)ethylamino)-2-(2-hydroxy-5- methylphenyl)acetic acid Step 1. Intermediate of formula (II) (X1= 2-hydroxy-5-methylphenyl, Y=(CH2)2, X2= 2-hydroxybenzyl) To a solution of the 2-(2-aminoethylarnino)-2-(2-hydroxy-5- methylphenyl)acetic acid hydrochloride in water at pH 7.2, was added an equimolar amount of salicylaldehyde in ethanol. After stirring for 1 h at room temperature, the title Schiff base was filtered and obtained as yellow solid in 52% yield. 1H-NMR (300 MHz, DMSO-d6, 2.5, ppm): δ = 8.55 (s, 1H, C=N), 7.45 (d, 1H, J = 7.6 Hz, Ar), 7.32 (t, 1H, J = 8.81 Hz, Ar), 7.02 (s, 1H, Ar), 6.90 (t, 3H, J = 7.56 Hz, Ar), 6.68 (d, 1H, J = 8.13, Ar), 4.52 (s, 1H, CH), 3.85-3.80 (m, 2H, CH2), 3.2.-3.12 (m, 1H, CH2), 3.01-2.94 (s, 1H, CH2), 2.17 (s, 3H, CH3). Step 2. 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2-hydroxy-5- methylphenyl)acetic acid The hydrogenation of the of the Schiff base obtained in Step 1 in MeOH (10 % Pd/C) at room temperature yielded the title product as brown solid (70%). 1H-NMR (500 MHz, D2O, 4.8 (HDO), ppm): δ = 7.18 (t, 1H, J = 6.14 Hz, Ar), 7.2-7.15 (m, 2H, Ar), 6.92-6.89 (s, 1H, Ar), 6.89-6.68 (m, 3H, Ar), 5.15 (s, 1H, CH), 4.16 (s, 2H, CH2), 3.36-3.19 (m, 4H, CH2), 2.19 (s, 3H, CH3). Example 11: Preparation of ferric chelates The general procedure used for preparing the ferric chelates of the invention is the following: To a solution of the ligand of formula (I) in NaOH (1:3 ligand:NaOH molar ratio), is added a solution of the equimolar amount of FeCI3-6H2O in water. During the addition, the pH of the solution should be maintained between 6.0- 8.0 by addition of NaOH or HCI, and finally adjusted to 7. The final solution is filtered through 0.45 urn cellulose membranes before use. Example 12: Determination of Titrimetric purity of the chelating agent Photometric titration Chelating agent solution was prepared by dissolving an amount of chelating agent in the necessary amount of NaOH solution. Then pH is adjusted to 6 by the addition of MES biological buffer [2-(N-morpholino) ethanesulfonic acid] and maintaining at this pH with NaOH solution during the titration. Ionic strength is fixed at 0.1 M with NaCI and upper atmosphere was N2free of C02 The test solution was placed in a thermostated jacketed reaction vessel (i.e.100 ml or 150 ml capacity) with an airtight cap fitted with gas inlet and outlet tubes, the combined pH glass electrode, the photometric detector and two piston burettes, tip extending below the surface of the solution, and a magnetic stirrer. The photometric titration consisted of the addition of a Fe(lll) standard solution, previously standardized by Atomic Absorption Spectroscopy, to the chelating agent until the absorbance at 480 nm presents no changes. End-point titration could be calculated for two linear segments' intersection and also using smoothed second derivative method. Potentiometric titration The chelating agent purities could also be determined by potentiometric titrations with a Cu2+ ion selective electrode in the same conditions as before. The chelating agent solution is titrated with Cu(ll) solution using selective Cu(ll) electrode and reference electrode, Cu2+ free cation is measured with the selective electrode. The end-point of the potentiometric titrations could be determined by Gran equation method or using the first derivative method. Previously, the Cu(ll) solution used as titrant solution is standardize with EDTA-Na2 solution and the selective electrode slope is determined by titration of NaCI solution fixed at pH=6 with Cu(ll) as titrant solution. Example 13: Determination of agrochemical activity Efficacy of Fe chelates to provide Fe to soybean plants in hydroponics. Soybean seeds (Glycine max L. cv. Stine 0480) were germinated at 30 °C and 60% RH on paper moistened with 1 M CaSO4 in dark for 2 days. Afterwards, seedlings were placed in 10 L containers (50 seedlings per container) filled with a 1/5 diluted EDTA buffered nutrient solution (macronutrients (mM)- 1.0 Ca(NO3)2j 0.9 KNO3, 0.3 MgSO4> 0.1 KH2PO4; cationic micronutrients (uM)- 5.0 EDTA/Fe3+, 2.5 MnSO4, 1.0 CuSO4, 10 ZnSO4, 1.0 CoSO4, 1.0 NiCI2, 11.5.5 Na2EDTA; anionic micronutrients (μM)- 35 NaCI, 10 H3B03, 0.05 Na2Mo04; 0.1 mM HEPES) for 6 days. On the 7th day, in order to induce Fe chlorosis, seedlings were transferred to 12 L polypropylene buckets containing aerated full strength EDTA buffered nutrient solution but without Fe3+-chelate. Plants were grown under these conditions until clear symptoms of Fe deficiency were observed (7 days) and then plants were placed in 2 L pots (6 plants per pot) covered with black plastic to avoid light exposure. The effect of different Fe chelates and doses were compared as Fe sources. Chelates used in the treatments were 0,0- EDDHA/Fe3+, o,p-EDDHA/Fe3\ EDTA/Fe3+ and Example 1/Fe3+. The last one is the Fe chelate of the compound of the example 1: 2-(2-((2- hydroxybenzyl)amino)ethylamino)-2-(2-hydroxyphenyl)acetic acid (DCHA). Nutrient solution contained macronutrients and anionic imicronutrients as for the seedling period and the following cationic micronutrients composition: OiM) 1.0 MnSO4, 0.5 CuSO4, 0.5 ZnSO4l 0.1 NiCI2 and 0.1 CoSO4. Also, 1g-L" 1 of CaC03 was added to the nutrient solution to buffer pH at 7.5 and to simulate conditions of a calcareous soil. Plants were grown for 21 days in this nutrient solution in a growth chamber provided with fluorescent and sodium vapour lamps with a 16 h/30 °C and 50% humidity day and 8 h/25 °C and 70% humidity night regime. Water was added every 2 days and the nutrient solution was renewed every 7 days. Treatments were replicated four times in a completely randomised design. Plants were harvested after 7, 14 and 21 days. During the experiment, SPAD readings with a chlorophyll-meter (Minolta SPAD-502) were taken for all leaf stages (average of two or three readings per stage) every second day. Only values measured for the youngest fully open leaves (the 2nd stage at the 2nd day, the third at the 10th day and the fourth at the 20th day) are here presented (Table 1) Table 1. Effects of Fe chelates treatments on the SPAD index measured. Different letters in the columns denote significant differences (α=0.05) among treatments according to the Duncan Test The chlorophyll and the recovery of plants after the treatments application were estimated by the SPAD index. Table 1 shows the time course of this parameter. Two days after the treatment application, plants treated with 10 uM o,p-EDDHA/Fe3+ showed the highest SPAD index values but it only showed significant differences with 5 uM o,o-EDDHA/Fe3+, 5 uM EDTA/Fe3+ and -Fe treatments. Ten days after, plants treated with 5 uM and 10 uM Example 1/Fe3+ and 10uM o,p-EDDHA/Fe3+ had significantly regreened in relation to 5 uM o,o-EDDHA/Fe3+, 5 uM and 10uM EDTA/Fe3+and -Fe treatments. At the end of the experiment (20 days after the treatments application), regardless of the doses, plants treated with Example 1, o,o- EDDHA and o,p-EDDHA Fe chelates (T1, T2, T3, T4, T5 and T6) had completely regreened showing significant SPAD index values concerning 5 μM and 10 uM doses of EDTA/Fe3+ and -Fe treatments. Considering the low doses applied and the trend observed, we can conclude that the product obtained in Example 1 presents a fast action to correct iron chlorosis, similar to o,p-EDDHA, but higher than o,o-EDDHA. Root and shoot were separated and washed using Tween 80 (Merck) and HCI solution and fresh and dry (after oven dry procedure) weights were determined. Samples were ground and after dry digestion in a muffle furnace (480 °C), ashes are dissolved in HCI. Fe, Mn, Cu and Zn were analysed by atomic absorption spectrometry. In Table 2 the Fe content in the plants in each sampling time for the treatments with the lower Fe application is presented. It can be observed that the novel compound Example 1/Fe3+ is able to provide significantly higher amounts of iron and faster in this experimental conditions than the other treatments, even more than o,p-EDDHA in the third sampling time. However, when a large doses of Fe is used (10 uM, table 3) differences are only significant respect the treatment with EDTA/Fe3+. It can be concluded that Example 1/Fe3+ can be used in lower concentration than other chelates to correct the iron chlorosis. Table 2 Fe content (ug Fe per plant) in plants treated with the low doses of chelates Different letters in the columns denote significant differences (a =0.05) among treatments according to the Duncan Test. Table 3 Fe content (ug Fe per plant) in plants treated with the high doses of chelates Different letters in the columns denote significant differences (a =0,.05) among treatments according to the Duncan Test. Efficacy of Fe chelates to provide Fe to soybean plants in soil conditions Soybean seeds (Glycine max L. cv. Stine 0480) were germinated at 30 °C and 60% RH on paper moistened with 1 M CaSO4 in dark for 2 days. Afterwards, seedlings were placed in 10 L containers (50 seedlings per container) filled with a 1/5 diluted EDTA buffered nutrient solution (macronutrients (mM)- 1.0 Ca(NO3)2, 0.9 KNO3, 0.3 MgSO4, 0.1 KH2PO4; cationic micronutrients (μM)- 5.0 EDTA/Fe3+, 2.5 MnSO4, 1.0 CuSO4, 10 ZnSO4, 1.0 CoSO4> 1.0 NiCI2, '115.5 Na2EDTA; anionic micronutrients (uM)- 35 NaCI, 10 H3BO3, 0.05 Na2MoO4; 0.1 mM HEPES) for 4 days. Then, in order to induce Fe chlorosis, nutrient solution without iron was used for two more days and then plants were transplanted in 1 L pots (3 plants per pot) containing 700 g of a calcareous soil (380 mg-Kg-1 calcium carbonate, 89 g Kg-1 CaCO 3 active, pH 7.70) and 300 g of lime sand covered with black plastic to avoid light exposure. The effect of different Fe chelates were compared as Fe sources: o,o-EDDHA/Fe3+, o,p-EDDHA/Fe3+, EDTA/Fe3+ and Example 1/Fe3+. The last one is the Fe chelate of the compound of the example 1: 2-(2-((2-hydroxybenzyl)amino)ethylamino)-2-(2- hydroxyphenyl)acetic acid. Plants were grown for 21 days in this soil conditions in a growth chamber provided with fluorescent and sodium vapour lamps with a 16 h/30 °C and 50% humidity day and 8 h/25 °C and 70% humidity night regime. Treatments were replicated five times in a completely randomised design. Single plants were harvested after 2, 7 and 21 days. During the experiment, SPAD readings with a chlorophyll-meter (Minolta SPAD-502) were taken for all leaf stages (average of two or three readings per stage) every second day. Values measured for the 2nd stage at the 2nd day, the third at the 12th day and the fourth and fifth at the 22th day) are here presented (Table 4). Table 4. Effects of Fe chelates treatments on the SPAD index measured in the soil experiment Different letters in the columns denote significant differences (a=0.05) among treatments according to the Duncan Test. All chelate treatments present higher SPAD indexes than control, as shown in Figure 1. This and the visual symptoms indicate that the recovery from chlorosis using these chelates was complete. Two days after the treatment application, plants treated with o,p-EDDHA/Fe3+ and Example 1/Fe3+ presented the better recovery, due to the fast action of these compounds, and after that it is the treatment with the o,o-EDDHA/Fe3+ the one which gives the highest values but similar to Example 1/Fe3+. In each sampling time shoots were separated and washed using Tween 80 (Merck) and HCI solution and fresh and dry (after oven dry procedure) weights were determined. Samples were ground and after dry digestion in a muffle furnace (480 °C), ashes were dissolved in HCI. Fe, Mn, Cu and Zn were analysed by atomic absorption spectrometry. In Figure 2 the dry weight obtained for the shoots is presented. Again the Example 1/Fe3+ revealed as an efficient Fe chlorosis corrector. Also in Figure 3 the iron concentration in leaves is shown for the three sampling times. The three iron chelates considerably increase the Fe concentration with respect to the control. From this experiment, with only one treatment application, we can conclude that the product obtained in Example 1 is efficient to solve iron chlorosis in highly calcareous conditions. Its efficacy is related with its fast action mechanism. CLAIMS 1. A compound of formula (I): wherein X1 is a C6 or a C10 aromatic system having a hydroxy group in the alpha position, being optionally substituted by up to four substituents independently selected from the group consisting of: phospho, sulfo, halo, carboxy, acetoxy, C1-C4 alkoxy, linear or branched C1-C4 alkyl. X2 is a C6 or a C10 aromatic system having a hydroxy group in the alpha position, or a five or six membered heterocycle having in the alpha position a heteroatom selected from the group consisting of N, O and S, optionally comprising other N, O or S atoms in their structure, and having from 0-3 double bonds, said aromatic, or heterocyclic system being optionally substituted by up to four substituents independently selected from the group consisting of: phospho, sulfo, halo, carboxy, acetoxy, C1-C4 alkoxy, linear or branched C1-C4 alkyl. Y is (CH2)n or is a xylylene group of formula: n is an integer selected from 2, 3 and 4, R1, R2 are independently selected from the group consisting of H, linear or branched C1-C4 alkyl, C6 or C10 aryl. 2. The compound according to claim 1, wherein X2 is selected from the group consisting of 2-hydroxyphenyl, 2-hydroxy-naphthyl, 2-furyl, 2-thienyl, 2- pyrrolyl, 2-pyridyl, 4-pyridimidinyl, 2-pyrazinyl optionally substituted by 2 or 1 substituents independently selected from the group consisting of: phospho, sulfo, halogen, C1-C4 alcoxy carboxy, acetoxy, linear or branched C1-C4 alkyl. 3. The compound according to claim 2, wherein X1 is 2-hydroxyphenyl or 2- hydroxynaphthyl, optionally substituted by 1 or 2 substituents independently selected from the group consisting of methyl or methoxy. 4. The compound according to claim 3, wherein X1 is 2-hydroxyphenyl. 5. The compound according to any one of claims 1 to 4, wherein Y is (CH2)n 6. The compound according to claim 5, wherein n is 2. 7. A process for preparing a compound of formula (I) as defined in claims 1 to 6, which process comprises the step of reducing a compound of formula (II): wherein X1, X2 and Y are as defined above, in an appropriate solvent system, in the presence of a reducing agent. 8. The process according to claim 7, further previously comprising the step of preparing said compound of formula (II) by reacting a compound of formula (III) with a compound of formula (IV): wherein X1, X2 and Y are as defined above, in an appropriate solvent system. 9. Use of a compound of formula (I) as defined in claims 1 to 6 as a complex forming agent for polyvalent metals. 10. A chelate of a compound of the formula (I) as defined in any of claims 1 to 6 with one or more polyvalent metals. 11. A chelate according to claim 10, wherein said polyvalent metal is at least one polyvalent metal from the group consisting of iron, nickel, zinc, manganese, yterbium, gadolinium, cobalt, copper, palladium, platinum and, gold. 12. The chelate according to claim 11, wherein said polyvalent metal is iron. 13. An agrochemical composition comprising a compound of formula (I) as defined in any of claims 1 to 6 or a polyvalent metal chelate thereof. 14. The agrochemical composition according to claim 13, further comprising a chelating agent selected from the group consisting of ethylene diamine tetracetic acid (EDTA), diethylene triamine pentacetic acid (DTPA), N,N'- ethylene-bis(2-hydroxyphenyl)glycine (o,o-EDDHA) and N,N'-ethylene-(2- hydroxyphenyl)-glycinyl-(4-hydroxyphenyl)glycine (o,p-EDDHA). 15. Use of a compound as defined in claims 1 to 6 or a polyvalent metal chelate thereof for the preparation of a composition for treating an iron deficiency related plant disease. 16. The use according to claim 15, wherein said disease is iron chlorosis. 17. An intermediate of formula (II): > wherein X1, X2 and Y are as defined above, in solid form. 18. The intermediate of formula (II) according to claim 17, wherein X1 is 2- hydroxyphenyl. 19. The intermediate of formula (II) according to claim 18, wherein Y is (CH2)2- 20. Use of the intermediate of formula (II) as defined in any of claims 17 to 19, for the preparation of a compound of formula (I), as defined in any of claims 1 to 6. The present invention consists on the synthesis of new products for the treatment of the iron chlorosis. These products may have improved properties regarding the currently known treatments. The new products are non-symmetrical ethylene diamino hidroxyphenyl acetic acid derivatives possessing only five coordination sites able to chelate metals.

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